Desmodur®/Desmophen® Bayhydrol®/Bayhydur® Roskydal®
Desmodur®/Desmophen® Bayhydrol®/Bayhydur® Roskydal®
Desmodur®/Desmophen® Bayhydrol®/Bayhydur® Roskydal®
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EMEA – Europe, Middle East, Africa<br />
Raw Materials for<br />
Automotive Refinish Systems<br />
Desmodur ® / Desmophen ®<br />
Bayhydrol ® / Bayhydur ®<br />
Roskydal ®
2<br />
Desmodur ® / Desmophen ® – Bayhydrol ® / Bayhydur ® – Roskydal ®<br />
Raw Materials for Automotive Refinish Systems<br />
This brochure provides information on<br />
automotive refinishing as<br />
• coating build-up<br />
• development of 2K PUR systems<br />
• VOC legislation<br />
• chemical and physical aspects<br />
• coating raw material data and<br />
application properties<br />
Bayer MaterialScience AG<br />
markets the product ranges<br />
Desmodur ® /Desmophen ® ,<br />
Bayhydrol ® /Bayhydur ® and<br />
Roskydal ® .<br />
Bayer MaterialScience AG –<br />
one of the world’s leading<br />
producers of coating raw<br />
materials – therefore possesses<br />
a comprehensive portfolio of<br />
high-grade building blocks for<br />
polyurethane coating systems.
Overview<br />
1. Introduction Page 4<br />
- Historical development of car refinish systems<br />
- Reasons for the success of 2K-PUR in car refinish<br />
- Chemistry of 2K polyurethane systems<br />
2. VOC compliant systems Page 6<br />
- VOC-legislation for car refinish in europe<br />
- Bayer MaterialScience VOC compliant raw materials for car refinish<br />
3. Desmodur ® polyisocyanate hardeners Page 7<br />
- Aliphatic polyisocyanate hardeners for 2K-PUR coatings<br />
- HDI-Biuret hardeners<br />
- HDI-Isocyanurate hardeners<br />
- IPDI-based hardeners<br />
- Low viscous HDI-based hardeners<br />
- Reactivity of different aliphatic polyisocyanate hardeners<br />
- Functionality versus viscosity for different HDI based hardeners<br />
4. Desmophen ® polyols and reactive diluents Page 12<br />
- Polyols for primers, surfacers, top and clearcoats<br />
- Applications and properties<br />
- Relationship between drying and VOC-value<br />
- Reactive diluents for very high solids<br />
5. Bayhydrol ® /Bayhydur ® for waterborne systems Page 16<br />
- Waterborne 2K-PUR systems<br />
- Polyols for waterborne 2K-PUR systems<br />
- Hydrophilic polyisocyanates<br />
- Polyisocyanates for waterborne 2K-PUR systems<br />
New technologies for car refinish systems Page 19<br />
6. Roskydal ® unsaturated putty-polyesters Page 20<br />
- Unsaturated polyesters for refinish & marble putties<br />
- Unsaturated polyesters for spray & industrial putties<br />
3
4<br />
1. Introduction<br />
NC-Top Coat<br />
NC-Primer<br />
NC-Putties<br />
1920<br />
Historical development of car refinish systems<br />
Medium-Oil-Alkyd-<br />
or TPA-Top Coat<br />
NC- or<br />
Short-Oil-Alkyd-Primer<br />
NC-Putties<br />
1950<br />
Driven by Technology: • Film Quality • Optical Properties • Efficiency<br />
few spray-cycles<br />
(≤ 2 passes)<br />
2K-PUR-Top Coat<br />
Alkyd- or<br />
2K-PUR Surfacer<br />
Wash Primer<br />
UPE-Putties<br />
1970<br />
Reasons for the success of 2K-PUR in car refinish<br />
➔<br />
➔<br />
Quality<br />
of OEM • DOI<br />
• Resistance<br />
• Durability<br />
broad variety of<br />
raw materials<br />
➔<br />
Higher Efficiency<br />
➔<br />
Car leaves the<br />
refinish shop ≤ 1 d<br />
➔<br />
➔<br />
2K-PUR<br />
Clear Coat<br />
Base coat<br />
2K-PUR<br />
Primer/Surfacer<br />
Wash Primer<br />
UPE-Putties<br />
since 1980<br />
high gloss<br />
without polishing<br />
low bake (≤ 60° C)<br />
short drying cycles<br />
(≤ 30 min)
Chemistry of 2K polyurethane systems<br />
R –N =C =O + R’–OH<br />
Main reaction:<br />
Side reactions:<br />
R –N =C =O + H –OH<br />
R –NH2 + CO 2<br />
R<br />
H<br />
N O<br />
Isocyanate + Alcohol Urethane<br />
Polyisocyanate + Polyol Polyurethane<br />
Isocyanate + Water Amine + Carbondioxide<br />
R –N =C =O + R° –NH2<br />
Isocyanate + Amine Urea/Polyurea<br />
R –N =C =O<br />
+<br />
R’–COOH<br />
Isocyanate + Carboxylic Acid Amide<br />
R<br />
R<br />
H<br />
N<br />
H<br />
N<br />
O<br />
O<br />
O<br />
H<br />
N<br />
R’ +<br />
R°<br />
R’<br />
CO 2<br />
5
6<br />
2. VOC compliant systems<br />
Putties<br />
Primer/Surfacer<br />
Base Coat<br />
VOC-legislation for car refinish in europe<br />
Automotive Refinish Current VOC 1) VOC 1) Value 2010 Technology<br />
250 g/l<br />
540 g/l<br />
420 g/l<br />
Clear Coat 420 g/l<br />
High Solids<br />
Waterborne<br />
250 g/l<br />
250 g/l<br />
420 g/l<br />
Depending on the<br />
“state of the art”<br />
Uni Topcoat 420 g/l 420 g/l<br />
1) VOC = Volatile Organic Compounds<br />
2) VHS = Very High Solids: VOC ≤ 250 g/l<br />
3) HS = High Solids: VOC ≤ 420 g/l<br />
2K-PUR<br />
Clear Coat<br />
2K-PUR<br />
Primer/Surfacer<br />
Putty<br />
• Standard UPE<br />
• Styrene free systems<br />
• 2K-PUR HS 3) /-VHS 2)<br />
• 2K-PUR-waterborne<br />
• 1K-PUR-waterborne<br />
• 1K-Acrylicwaterborne<br />
• 2K-PUR-HS 3) (VHS 2) )<br />
• (2K-PURwaterborne)<br />
• 2K-PUR-HS 3)<br />
• (2K-PURwaterborne)<br />
Bayer VOC compliant raw materials for car refinish<br />
High Solids Desmophen ® / Desmodur ®<br />
Waterborne Bayhydrol ® / Bayhydur ®<br />
Styrene-Free<br />
Desmophen ® / Desmodur ®<br />
Bayhydrol ® / Bayhydur ®<br />
Roskydal ®
3. Desmodur ® polyisocyanate hardeners<br />
OCN<br />
Desmodur ®<br />
N 100<br />
N 75<br />
N 3200<br />
Aliphatic polyisocyanate hardeners for 2K PUR coatings*<br />
R<br />
O<br />
HDI Biuret<br />
OCN<br />
N<br />
Type<br />
R<br />
NH<br />
O<br />
Standard<br />
HDI-Biuret<br />
Standard<br />
HDI-Biuret<br />
Low viscous<br />
HDI-Biuret<br />
NCO<br />
H<br />
N<br />
R<br />
NCO<br />
R =C 6H 12<br />
NCO<br />
O<br />
N<br />
O<br />
R<br />
R<br />
N N R<br />
O<br />
NCO<br />
R =C 6H 12<br />
Supply<br />
form [%]<br />
NCO<br />
NCO-<br />
Content [%]<br />
OCN<br />
O<br />
*one possible structure (ideal)<br />
HDI Isocyanurate (Trimer) IPDI Isocyanurate (Trimer)<br />
HDI-Biuret hardeners<br />
* also in butyl acetate<br />
MPA – methoxy propyl acetate<br />
X – xylene<br />
O<br />
N N<br />
N<br />
Viscosity<br />
[mPa·s]<br />
at 23° C<br />
NCO<br />
NCO-<br />
Functionality<br />
Equivalent<br />
weight<br />
TSCA<br />
100 22.0 10,000 F = 3.8 191 Yes<br />
75 MPA/X* 16.5 225 F = 3.8 255 Yes<br />
100 23.0 2,500 F = 3.5 183 Yes<br />
O<br />
7
8<br />
3. Desmodur ® polyisocyanate hardeners<br />
HDI-Isocyanurate hardeners<br />
Desmodur ®<br />
N 3790<br />
N 3300<br />
N 3390<br />
N 3600<br />
Type<br />
High viscosity,<br />
fast drying<br />
Standard type,<br />
solvent free<br />
Standard type,<br />
solution<br />
Low viscosity,<br />
for high solids<br />
Supply<br />
form [%]<br />
NCO-<br />
Content [%]<br />
* also in BA – butyl acetate, SN – solvent naphta 100<br />
Desmodur ® N 3790, N 3300, N 3390 and N 3600 are all TSCA listed<br />
3 R–NCO<br />
R =OCN–(CH2) 6–<br />
n = number of monomeric units incorporated<br />
Voltage [V]<br />
O<br />
Viscosity<br />
[mPa·s]<br />
at 23° C<br />
NCO-<br />
Functionality<br />
90 BA 18.0 2,000 F = 4.1<br />
˜<br />
30 20<br />
50 236<br />
˜<br />
100 21.8 3,000 F = 3.5 ˜ 50 20 30 193<br />
90 BA/SN* 19.6 550 F = 3.5 ˜ 50 20 30 216<br />
100 23.0 1,200 F = 3.2<br />
Oligomer distribution in technical HDI-Isocyanurates<br />
R<br />
+ 2 R–NCO<br />
[Cat.] [Cat.]<br />
R R<br />
O<br />
O<br />
Monomer (n=1) Trimer (n=3) Pentamer (n=5)<br />
GPC of a technical HDI hardener<br />
Heptamer<br />
Pentamer<br />
O<br />
R<br />
R<br />
O<br />
Oligomer distribution<br />
[%]<br />
n=3 5 7<br />
˜<br />
elution volume [ml]<br />
Equivalent<br />
weight<br />
70 20 15 180<br />
O<br />
Trimer<br />
^ ^<br />
^<br />
^<br />
O<br />
(CH2) 6<br />
^<br />
^ ^<br />
^<br />
R<br />
O<br />
O<br />
R
➔<br />
●<br />
●<br />
●<br />
➔<br />
●<br />
●<br />
IPDI-based hardeners<br />
HDI-Trimer IPDI-Trimer<br />
T g – glass temperature approx. – 60° C approx. +60° C<br />
Viscosity 3,000 mPas solid (2,000 mPas at 70 % in SN*)<br />
SN – solvent naphta 100<br />
IPDI-Trimers have:<br />
a significant faster physical drying<br />
also secondary NCO groups<br />
➔ lower reactivity<br />
a significant higher viscosity<br />
➔ higher VOC<br />
compromise:<br />
use of IPDI hardeners in combination<br />
with HDI-based hardeners<br />
use of lower viscous IPDI allophanate<br />
Desmodur ® XP 2565<br />
Desmodur ®<br />
Z 4470<br />
XP 2565<br />
NZ 1<br />
Type<br />
Standard IPDI-<br />
Trimer<br />
Low viscous IPDI-<br />
Allophanate<br />
Solventfree IPDI/<br />
HDI-combination<br />
MPA – methoxy propyl acetate<br />
X – xylene<br />
SN – solvent naphta 100<br />
BA – butyl acetate<br />
Supply<br />
form [%]<br />
70 MPA/X<br />
70 SN<br />
NCO-<br />
Content [%]<br />
11.9<br />
IPDI-Trimer (one possible structure)<br />
Viscosity<br />
[mPa·s]<br />
at 23° C<br />
NCO<br />
1,500<br />
2,000<br />
O<br />
OCN<br />
O<br />
N N<br />
N O<br />
NCO-<br />
Functionality<br />
NCO<br />
Equivalent<br />
weight<br />
F = 3.3 360 Yes<br />
80 BA 12.0 2.800 F = 2.5 350 Yes<br />
100 % 20.0 3,000 F = 2.8 210 Yes<br />
TSCA<br />
9
10<br />
3. Desmodur ® polyisocyanate hardeners<br />
Low viscous HDI-based hardeners<br />
Desmodur ®<br />
N 3600<br />
XP 2410<br />
N 3400<br />
OCN<br />
R =C 6H 12<br />
<br />
O<br />
R<br />
R<br />
OCN<br />
R =C 6H 12<br />
NCO<br />
R<br />
O<br />
O<br />
R<br />
NCO<br />
R<br />
O<br />
NCO<br />
R<br />
*Desmodur ® N 3600<br />
OCN<br />
1,200 mPas*<br />
NCO<br />
700 mPas* 170 mPas*<br />
R–N N–R<br />
Asymmetric Trimer: *Desmodur ® XP 2410 HDI-Uretdione: *Desmodur ® N 3400<br />
Type<br />
Low viscous<br />
HDI-Trimer<br />
Very low viscous<br />
asymmetric<br />
HDI-Trimer<br />
Very low viscous<br />
HDI-Uretdione<br />
O<br />
Supply<br />
form [%]<br />
100<br />
100<br />
100<br />
NCO-<br />
Content [%]<br />
23.0<br />
24.0<br />
21.8<br />
O<br />
R =C 6H 12<br />
Viscosity<br />
[mPa·s]<br />
at 23° C<br />
1,200<br />
700<br />
170<br />
<br />
O<br />
O<br />
NCO-<br />
Functionality<br />
F = 3.2<br />
F = 3.1<br />
F = 2.5<br />
Equivalent<br />
weight<br />
180<br />
175<br />
193<br />
NCO<br />
TSCA<br />
Yes<br />
Yes<br />
Yes
Relative<br />
NCO-Content<br />
[%]<br />
90<br />
80<br />
70<br />
60<br />
50<br />
40<br />
30<br />
20<br />
10<br />
0<br />
50 100 150 200 250 300<br />
time at room temperature [h]<br />
*High Solids Clear Coat based on Desmophen ® A VP LS 2350 – cured at 23° C/50 % humidity; NCO/OH=1:1<br />
Desmodur ®<br />
*100% version of Desmodur ® N 3790, not commercial available<br />
Reactivity of different aliphatic polyisocyanate hardeners*<br />
Functionality versus viscosity for different HDI-based hardeners<br />
N 3400<br />
XP 2410<br />
N 3600<br />
N 3300<br />
N 3700*<br />
100 300 700 1,200 3,000 15,000<br />
viscosity [mPas]<br />
Desmodur ® Z 4470<br />
HDI-Trimers:<br />
Desmodur ® N 3790<br />
Desmodur ® N 3390<br />
Desmodur ® N 3600<br />
Desmodur ® XP 2410<br />
HDI Uretdione<br />
Desmodur ® N 3400<br />
NCO Decrease<br />
detected by<br />
IR Spectroscopy<br />
4<br />
3.5<br />
3<br />
2.5<br />
functionality<br />
11
12<br />
4. Desmophen ® polyols and reactive diluents<br />
Desmophen ® Type Supply Form [%] OH-Content [%]<br />
supply form/solid<br />
A160<br />
A170<br />
Polyacrylate<br />
60 in X<br />
70 in BA<br />
1.6 / 2.6<br />
1.8 / 2.6<br />
1,800<br />
3,500<br />
A 265 Polyacrylate 65 in BA 2.0 / 3.1 2,300<br />
A 365 Polyacrylate 65 in BA/X 3:1 2.9 / 4.5 3,000<br />
A 450 Polyacrylate<br />
50 in MPA/X<br />
50 in BA<br />
1.0 / 2.0<br />
5,000<br />
4,000<br />
A 665 Polyacrylate 65 in BA/X 3:1 3.0 / 4.6 2,400<br />
A 870 Polyacrylate 70 in BA 3.0 / 4.3 3,500<br />
VP LS 2350 Polyacrylate 70 in BA 2.8 / 4.0 1,200<br />
VP LS 2383 Polyacrylate 60 in BA 2.5 / 4.2 4,500<br />
RD 181 Polyester<br />
75 in BA<br />
75 in MPA<br />
75 in X<br />
3.7 / 4.9<br />
4,500<br />
7,900<br />
7,500<br />
670 Polyester 80 in BA 3.4 / 4.3 2,800<br />
680 Polyester<br />
60 in X<br />
70 in BA<br />
1.9 / 3.1<br />
2.1 / 3.1<br />
Viscosity [mPa . s]<br />
at 23° C<br />
2,750<br />
3,000<br />
1150 Polyester 100 4.7 3,500<br />
BA – butyl acetate<br />
X – xylene<br />
MPA – methoxy propyl acetate<br />
SN 100 – solvent naphta 100<br />
Polyols for primers, surfacers, top and clearcoats
Applications Primer/<br />
Surfacer<br />
A160<br />
A170<br />
●<br />
A265 ●<br />
Top<br />
Coats<br />
Clear<br />
Coats<br />
High<br />
Solids<br />
● ● ●<br />
Standard resin for 540 g/l<br />
VOC primer/surfacers<br />
Fast drying<br />
universal resin<br />
A 365 ●<br />
Universal resin 585<br />
A 450 ●*<br />
A 665<br />
A 870<br />
VP LS 2350<br />
VP LS 2383<br />
RD 181 ●<br />
670 ●*<br />
●* ●* ●<br />
● ●<br />
● ● ●<br />
● ● ●<br />
● ● ●<br />
●<br />
●* ●*<br />
Combination resin<br />
for improved drying<br />
Outstanding QUV<br />
UV-B resistance<br />
Suitable for 480 g/l<br />
top- and clear coats<br />
Suitable for 420 g/l<br />
clear- and top coats<br />
For fastest drying<br />
clear- and top coats<br />
Grinding resin for<br />
pigment pastes<br />
Combination resin<br />
for flexibilisation<br />
680 ● ● ●<br />
Universal resin<br />
1150 ●*<br />
* = in combination with other resins<br />
Applications and properties<br />
●<br />
Very fast<br />
Drying<br />
Special applications<br />
and properties<br />
VHS in combination<br />
with reactive diluents<br />
Equivalent<br />
weight<br />
1,060<br />
945<br />
850<br />
1,700<br />
567<br />
575<br />
607<br />
680<br />
460<br />
485<br />
945<br />
775<br />
354<br />
13
14<br />
4. Desmophen ® polyols and reactive diluents<br />
OH content [%]<br />
on solids<br />
4<br />
3<br />
2<br />
1<br />
Relationship between drying and VOC-value (Hardener: Desmodur ® N 3390)<br />
VOC-value [g/l]<br />
580<br />
560<br />
540<br />
520<br />
500<br />
480<br />
460<br />
440<br />
420<br />
Hydroxyacrylates for Medium Solid 2K PUR Systems<br />
A 450<br />
faster<br />
2<br />
LS 2383<br />
A 160<br />
A 265<br />
Clear Coats<br />
Primer/Surfacer<br />
Drying (tackfree)<br />
LS 2383<br />
A265<br />
A 870<br />
A 365<br />
A 665<br />
Size of bubbles: durability<br />
slower<br />
A 365<br />
A 665<br />
A 870<br />
LS 2350<br />
4 6 8 10 12<br />
Drying time [h] till touchability
Reactive diluents for very high solids<br />
1)<br />
2)<br />
3)<br />
Very High Solids Systems<br />
(< 250 g/l VOC)<br />
Very low<br />
viscous<br />
polyols<br />
Very low<br />
viscous<br />
hardener<br />
Very slow<br />
drying<br />
Polyaspartates:<br />
● sterically hindered<br />
● electron deficient<br />
● secondary aliphatic amines<br />
no blocking agent<br />
very low odour<br />
good compatibility<br />
low colour value<br />
Desmophen ®<br />
VP LS 2142<br />
VP LS 2965<br />
NH 1521<br />
(VP LS 2973)<br />
Low viscous<br />
polyols<br />
Low viscous<br />
hardener<br />
Reactive<br />
diluent<br />
Fast drying<br />
Type<br />
Aldimine<br />
Ketimine<br />
EtO<br />
EtO<br />
Polyaspartate<br />
Synthesis and Chemical Structure of Polyaspartates<br />
90 in BA<br />
~25<br />
~80<br />
~150<br />
Equivalent<br />
weight<br />
4) NH 1520<br />
Polyaspartate 100 ~1200<br />
290<br />
O<br />
O<br />
R I<br />
R I<br />
N<br />
X = H 3 C<br />
N<br />
100<br />
100<br />
R<br />
Supply<br />
form [%]<br />
Crosslinking-Reaction of Aldimines and Ketimines via Hydrolysis<br />
R<br />
X<br />
R<br />
N<br />
R I<br />
+2H 2 O<br />
-2H 2 O<br />
Reaction via Imin-Enamin Tautomerie<br />
X<br />
R<br />
N<br />
H 2 N X<br />
CH 2<br />
R I<br />
NH 2<br />
Viscosity at<br />
23° C [mPas]<br />
catalyst<br />
CH 3<br />
O<br />
O<br />
139<br />
167<br />
356<br />
OEt<br />
OEt<br />
H 2 N<br />
H<br />
R I<br />
N<br />
CH 2<br />
X<br />
R<br />
Reactivity<br />
++<br />
++ (+)<br />
+<br />
+<br />
X<br />
R<br />
OEt<br />
NH 2<br />
N<br />
O<br />
H<br />
R I<br />
H<br />
N<br />
+2<br />
O<br />
OEt<br />
R<br />
O<br />
R I<br />
crosslinking with<br />
Polyisocyanate<br />
X<br />
Applications<br />
O<br />
clear & top coats in<br />
comb. with 3+5<br />
primers & fillers in<br />
comb. with polyols<br />
clear & top coats in<br />
comb. with 1+5;<br />
top coats in comb.<br />
with polyacrylate<br />
polyols<br />
N<br />
H<br />
OEt<br />
O<br />
TSCA<br />
EINECS<br />
clear coats & fillers in<br />
5) NH 1420 Polyaspartate 100 ~1500<br />
279<br />
++<br />
Yes*<br />
comb. with 1+3<br />
putties & elastomers<br />
6) NH 1220 Polyaspartate 100 ‹100<br />
230<br />
++++<br />
Yes*<br />
in comb. with 5<br />
BA – butyl acetate<br />
Yes<br />
Yes<br />
Yes*<br />
Yes*<br />
OEt<br />
*: registered “New Stuff” in Europe<br />
15
16<br />
5. Bayhydrol ® /Bayhydur ® for waterborne systems<br />
VP LS 2290<br />
Waterborne 2K-PUR systems<br />
Waterborne coatings with highest quality: ➔ Waterborne 2K-PUR Coatings<br />
Aqueous Polyol<br />
PES: Polyester, PAC: Polyacrylate, *: % on solids, °: % on supply form<br />
DMEA – dimethyl ethanolamin<br />
BG – butylglycol<br />
PnB – propylenglycol butyl ether<br />
SN 100 – solvent naphta 100<br />
+<br />
Polyisocyanate<br />
Polyols for waterborne 2K-PUR systems<br />
Bayhydrol ®<br />
VP LS 2139/2<br />
XP 2469<br />
A 145<br />
XP 2470<br />
Type<br />
PES/PAC<br />
secondary<br />
emulsion<br />
PES/PAC<br />
secondary<br />
emulsion<br />
Polyacrylate<br />
secondary<br />
emulsion<br />
Polyacrylate<br />
secondary<br />
emulsion<br />
Polyacrylate<br />
secondary<br />
emulsion<br />
Supply<br />
form [%]<br />
45<br />
45<br />
45<br />
45<br />
*OH-<br />
Content<br />
[%]<br />
3.8<br />
3.8<br />
2.5<br />
3.3<br />
°Co-Solvents<br />
[%]<br />
2.5<br />
Butyldiglycol<br />
8 BG<br />
8 PnB<br />
4 BG<br />
4 SN 100<br />
Polyacrylate, Polyester or<br />
Polyurethane Emulsion or Solution<br />
Hydrophilic and/or<br />
Low Viscous Hydrophobic Type<br />
Viscosity<br />
[mPa·s]<br />
at 23° C<br />
~2,000<br />
~1,500<br />
~1,500<br />
~800<br />
pHvalue<br />
7.5<br />
7.0<br />
8.4<br />
8.0<br />
4 PnB<br />
45 3.9<br />
~2,000 7.8<br />
4 SN 100<br />
*acid<br />
number<br />
27<br />
29<br />
18<br />
22<br />
24<br />
neutralized<br />
with<br />
DMEA<br />
DMEA<br />
DMEA<br />
DMEA<br />
Triethanolamin<br />
DMEA<br />
T G [°C]<br />
6<br />
45<br />
30<br />
28<br />
50<br />
Applications<br />
solid colour top<br />
coat primer surfacer<br />
top coat<br />
clear coat<br />
primer/surfacer<br />
top coat<br />
primer/surfacer<br />
solid colour top<br />
coat primer,<br />
clear coat<br />
top coat<br />
clear coat
Hydrophilic polyisocyanates<br />
Hydrophilic<br />
Polyisocyanates<br />
External emulsification<br />
State of the art:<br />
polyether modified trimer<br />
Bayhydur ® 3100<br />
New:<br />
sulfonic acid<br />
modified trimer<br />
Bayhydur ® XP 2487/1<br />
Bayhydur ® XP 2570<br />
Emulsifier in the PIC Migration of Emulsifier<br />
Internal emulsification<br />
(Bayhydur types) chemically linked not possible<br />
polyether modified<br />
allophanate/trimer<br />
Bayhydur ® VP LS 2319<br />
not chemically linked<br />
OCN<br />
OCN<br />
Bayer MaterialScience approach<br />
O<br />
O<br />
N N<br />
N O<br />
out of the film is<br />
possible<br />
Chemical structures of hydrophilic polyisocyanate hardeners<br />
OCN<br />
OCN<br />
OCN<br />
OCN<br />
OCN<br />
OCN<br />
O<br />
O<br />
O<br />
N N<br />
N O<br />
O<br />
O<br />
N N<br />
O<br />
N N<br />
N O<br />
N O<br />
H<br />
N<br />
H<br />
N<br />
N<br />
O<br />
O<br />
O<br />
H<br />
N<br />
O O<br />
O<br />
O O<br />
O<br />
O<br />
N N X SO3<br />
- +<br />
NR3H<br />
O<br />
Blistering,<br />
reduction of water resistance<br />
and gloss possible<br />
Less blistering,<br />
better properties<br />
➔ Benefits to hydrophobic polyisocyanates:<br />
– improved dispersibility<br />
➔ Benefits to polyether modified trimers (state of the art):<br />
– higher functionality<br />
– low water sensitivity of the film<br />
O<br />
➔ Benefits to polyether modified polyisocyanates:<br />
– lower amount of hydrophilic moieties<br />
– higher NCO-content and drying speed<br />
– increased hardness<br />
– improved chemical resistance<br />
O<br />
O<br />
O<br />
O<br />
O<br />
O<br />
CH3<br />
CH3<br />
ideal structures<br />
17
18<br />
Hydrophilic types Bayhydur ®<br />
Hydrophobic, low viscous types Desmodur ®<br />
Desmodur ®<br />
N 3600<br />
Desmodur ®<br />
XP 2410<br />
Desmodur ®<br />
N 3400<br />
Bayhydur ®<br />
VP LS 2319<br />
Bayhydur ®<br />
3100<br />
Bayhydur ®<br />
XP 2487/1<br />
Bayhydur ®<br />
XP 2570<br />
Desmodur ®<br />
XP 2565<br />
Bayhydur ®<br />
VP LS 2150<br />
BA – butyl acetate<br />
MPA – methoxy propyl acetate<br />
X – xylene<br />
Polyisocyanates for waterborne 2K PUR systems<br />
Type Supply<br />
Form<br />
[%]<br />
HDI-Trimer,<br />
low viscious<br />
HDI-Trimer,<br />
very low viscious<br />
HDI-Uretdione,<br />
very low viscious<br />
HDI-Trimer,<br />
slightly hydrophilic<br />
HDI-Trimer,<br />
hydrophilic<br />
HDI-Trimer,<br />
ionically modified<br />
HDI-Trimer,<br />
ionically modified<br />
IPDI-Allophanate,<br />
low viscious<br />
IPDI-Trimer,<br />
hydrophilic<br />
100<br />
NCO-<br />
Content<br />
[%]<br />
23.4<br />
Viscosity<br />
[mPa . s]<br />
at 23° C<br />
1,200<br />
NCO- Hand<br />
Functionality mixable<br />
F = 3.2<br />
100 20.5 6,000 F = 3.4 + Yes<br />
100 20.5 3,500 F = 3.0 ++ Yes<br />
- -<br />
TSCA<br />
Yes<br />
100 24.0 700 F = 3.1 - Yes<br />
100 21.8 170 F = 2.5 - Yes<br />
100 18.0 4,500 F = 3.8 + Yes<br />
100 17.4 3,300 F = 3.2 + No<br />
80 BA 12.0 2,800 F = 2.5 - - Yes<br />
70 MPA/X 13.4 600 F = 3.0 + Yes
New technologies for car refinish systems<br />
Main technology trends driven by ecological reasons<br />
2K-PUR Clear Coat<br />
CAB-Base Coat<br />
2K-PUR Primer/Surfacer<br />
Wash Primer<br />
Putty<br />
New technology trend driven by economical* reasons<br />
2K-PUR Clear Coat<br />
CAB-Base Coat<br />
2K-PUR Primer/Surfacer<br />
Wash Primer<br />
Putty<br />
High Solids 1<br />
Waterborne 2<br />
Very High Solids 3<br />
Waterborne 2<br />
1K UV curing 4<br />
Styrene free UPE 4<br />
2K PUR putties 4<br />
Fast Drying 2K PUR 1<br />
1K UV or Dual Cure 4<br />
Fast Drying 2K PUR 1<br />
1K UV curing 4<br />
2K PUR putties 4<br />
1K UV curing 4<br />
*economical reasons can be: – faster drying speed to reduce overall process time<br />
– 1K instead of 2K system to improve degree of efficiency<br />
1 ® ® based on Desmophen A/Desmodur N<br />
2 ® ® ®<br />
based on Bayhydrol /Bayhydur /Desmodur<br />
3 ® ® based on Desmophen NH reactive diluents/Desmodur N<br />
4<br />
Bayer MaterialScience products under development.<br />
For further information please contact our Technical Service.<br />
19
20<br />
6. Roskydal ® unsaturated putty-polyesters<br />
Roskydal ® Supply Form<br />
[%]<br />
in styrene<br />
K 14M 64<br />
Unsaturated polyesters for refinish and marble putties<br />
Viscosity<br />
[mPa . s]<br />
at 23° C<br />
825<br />
K 27/1 70 2,200<br />
K 30 65 500<br />
K 36 62 400<br />
K 45 65 575<br />
K 40T 65 Thixotropic<br />
XP 2519 66 650<br />
K 65 67 725<br />
K 68 65 750<br />
Characteristics<br />
Very high reactive,<br />
very hard<br />
High reactive,<br />
very hard<br />
High reactive,<br />
medium hard<br />
Very high reactive,<br />
medium flexible<br />
High reactive,<br />
medium flexible<br />
Medium reactive,<br />
highly flexible<br />
Fields of<br />
application<br />
Knifing<br />
fillers/putties<br />
for marble<br />
and stone<br />
Highly filled<br />
cours and<br />
fine fillers/<br />
putties for<br />
industrial or<br />
DIY car body<br />
repair, wood<br />
and metal<br />
applications<br />
Special Properties<br />
Very good mechanical<br />
properties, high gloss<br />
after polishing; hard<br />
resins for combination<br />
with other<br />
Roskydal ® K-types<br />
Ideal sole-binder for a<br />
wide range of fillers and<br />
putties.<br />
Formulation in all<br />
standard mixing<br />
equipment<br />
Thixotropic binder.<br />
Production with Dissolver<br />
or Butterfly-mixer up to<br />
55° C possible<br />
Sole-binder with good<br />
adhesion properties on all<br />
galvanised car panel<br />
Sole-binder or in combination<br />
with Roskydal ® k14M<br />
for flexible putties with<br />
good adhesion on all<br />
galvanised car panel<br />
Special for overbaking<br />
resistant fillers up to<br />
180° C and plastification of<br />
other Roskydal ® K-types
Roskydal ® Supply Form<br />
[%]<br />
in styrene<br />
Unsaturated polyesters for spray and industrial putties<br />
Viscosity<br />
[mPa . s]<br />
at 23° C<br />
500 A 76 1,800<br />
620 69 850<br />
E 65 65 600<br />
E 70 65 950<br />
XP 2465 68 900<br />
Characteristics<br />
High reactive,<br />
medium hard<br />
High reactive,<br />
hard<br />
Medium reactive,<br />
elastic<br />
Low reactive,<br />
very elastic,<br />
soft<br />
High reactive,<br />
medium flexible<br />
Fields of<br />
application<br />
All kinds of<br />
knifing and<br />
spray fillers<br />
for car body<br />
and industrial<br />
application<br />
(regulation of<br />
potlife with<br />
addition of<br />
different amounts<br />
of inhibitor)<br />
Special Properties<br />
Very good air drying<br />
properties in combination<br />
withRoskydal ® E-types<br />
Good storage stability<br />
with Co-salts, especially<br />
in combination with<br />
Roskydal ® E-types<br />
Universal, air drying<br />
combination resin with<br />
good storage stability,<br />
even with Co-salts<br />
Soft resin used for<br />
plastification of all<br />
Roskydal ® K-types<br />
Sole binder for UPE<br />
fillers with longer potlife<br />
and spray fillers<br />
21
22<br />
Technical Service Contacts<br />
Europe, Middle East, Africa:<br />
Car Refinish Systems:<br />
Jörg Schmitz<br />
+49-214-30-57054<br />
Holger Mundstock<br />
+49-214-30-55578<br />
Michael Ehlers<br />
+49-214-30-56473<br />
Waterborne Systems:<br />
Martin Melchiors<br />
+49-214-30-52435<br />
NAFTA:<br />
Car Refinish Systems:<br />
Scott Grace<br />
+1-412-777-7657<br />
Dave Zielinski<br />
+1-412-777-7652<br />
South America:<br />
Car Refinish Systems:<br />
Alberto Hassessian<br />
+50-11-5694-5148<br />
Asia:<br />
Car Refinish Systems:<br />
Osamu Kirihara<br />
+81-6-6497-2166
If you have any questions<br />
regarding the technical details<br />
presented in this brochure,<br />
please contact us at:<br />
info@bayercoatings.com<br />
Additional information is available on the Internet at:<br />
www.bayercoatings.com<br />
23
www.bayercoatings.com<br />
Bayer MaterialScience AG<br />
Coatings, Adhesives & Sealants<br />
51368 Leverkusen<br />
Germany<br />
www.bayermaterialscience.com<br />
info@bayercoatings.com<br />
This information and our technical advice – whether verbal,<br />
in writing or by way of trials – are given in good faith but<br />
without warranty, and this also applies where proprietary<br />
rights of third parties are involved. Our advice does not<br />
release you from the obligation to verify the information<br />
currently provided – especially that contained in our safety<br />
data and technical information sheets – and to test our<br />
products as to their suitability for the intended processes<br />
and uses. The application, use and processing of our products<br />
and the products manufactured by you on the<br />
basis of our technical advice are beyond our control and,<br />
therefore, entirely your own responsibility. Our products are<br />
sold in accordance with the current version of our General<br />
Conditions of Sale and Delivery.<br />
Edition: 2005-02-MH<br />
Printed in Germany · E