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Desmodur®/Desmophen® Bayhydrol®/Bayhydur® Roskydal®

Desmodur®/Desmophen® Bayhydrol®/Bayhydur® Roskydal®

Desmodur®/Desmophen® Bayhydrol®/Bayhydur® Roskydal®

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EMEA – Europe, Middle East, Africa<br />

Raw Materials for<br />

Automotive Refinish Systems<br />

Desmodur ® / Desmophen ®<br />

Bayhydrol ® / Bayhydur ®<br />

Roskydal ®


2<br />

Desmodur ® / Desmophen ® – Bayhydrol ® / Bayhydur ® – Roskydal ®<br />

Raw Materials for Automotive Refinish Systems<br />

This brochure provides information on<br />

automotive refinishing as<br />

• coating build-up<br />

• development of 2K PUR systems<br />

• VOC legislation<br />

• chemical and physical aspects<br />

• coating raw material data and<br />

application properties<br />

Bayer MaterialScience AG<br />

markets the product ranges<br />

Desmodur ® /Desmophen ® ,<br />

Bayhydrol ® /Bayhydur ® and<br />

Roskydal ® .<br />

Bayer MaterialScience AG –<br />

one of the world’s leading<br />

producers of coating raw<br />

materials – therefore possesses<br />

a comprehensive portfolio of<br />

high-grade building blocks for<br />

polyurethane coating systems.


Overview<br />

1. Introduction Page 4<br />

- Historical development of car refinish systems<br />

- Reasons for the success of 2K-PUR in car refinish<br />

- Chemistry of 2K polyurethane systems<br />

2. VOC compliant systems Page 6<br />

- VOC-legislation for car refinish in europe<br />

- Bayer MaterialScience VOC compliant raw materials for car refinish<br />

3. Desmodur ® polyisocyanate hardeners Page 7<br />

- Aliphatic polyisocyanate hardeners for 2K-PUR coatings<br />

- HDI-Biuret hardeners<br />

- HDI-Isocyanurate hardeners<br />

- IPDI-based hardeners<br />

- Low viscous HDI-based hardeners<br />

- Reactivity of different aliphatic polyisocyanate hardeners<br />

- Functionality versus viscosity for different HDI based hardeners<br />

4. Desmophen ® polyols and reactive diluents Page 12<br />

- Polyols for primers, surfacers, top and clearcoats<br />

- Applications and properties<br />

- Relationship between drying and VOC-value<br />

- Reactive diluents for very high solids<br />

5. Bayhydrol ® /Bayhydur ® for waterborne systems Page 16<br />

- Waterborne 2K-PUR systems<br />

- Polyols for waterborne 2K-PUR systems<br />

- Hydrophilic polyisocyanates<br />

- Polyisocyanates for waterborne 2K-PUR systems<br />

New technologies for car refinish systems Page 19<br />

6. Roskydal ® unsaturated putty-polyesters Page 20<br />

- Unsaturated polyesters for refinish & marble putties<br />

- Unsaturated polyesters for spray & industrial putties<br />

3


4<br />

1. Introduction<br />

NC-Top Coat<br />

NC-Primer<br />

NC-Putties<br />

1920<br />

Historical development of car refinish systems<br />

Medium-Oil-Alkyd-<br />

or TPA-Top Coat<br />

NC- or<br />

Short-Oil-Alkyd-Primer<br />

NC-Putties<br />

1950<br />

Driven by Technology: • Film Quality • Optical Properties • Efficiency<br />

few spray-cycles<br />

(≤ 2 passes)<br />

2K-PUR-Top Coat<br />

Alkyd- or<br />

2K-PUR Surfacer<br />

Wash Primer<br />

UPE-Putties<br />

1970<br />

Reasons for the success of 2K-PUR in car refinish<br />

➔<br />

➔<br />

Quality<br />

of OEM • DOI<br />

• Resistance<br />

• Durability<br />

broad variety of<br />

raw materials<br />

➔<br />

Higher Efficiency<br />

➔<br />

Car leaves the<br />

refinish shop ≤ 1 d<br />

➔<br />

➔<br />

2K-PUR<br />

Clear Coat<br />

Base coat<br />

2K-PUR<br />

Primer/Surfacer<br />

Wash Primer<br />

UPE-Putties<br />

since 1980<br />

high gloss<br />

without polishing<br />

low bake (≤ 60° C)<br />

short drying cycles<br />

(≤ 30 min)


Chemistry of 2K polyurethane systems<br />

R –N =C =O + R’–OH<br />

Main reaction:<br />

Side reactions:<br />

R –N =C =O + H –OH<br />

R –NH2 + CO 2<br />

R<br />

H<br />

N O<br />

Isocyanate + Alcohol Urethane<br />

Polyisocyanate + Polyol Polyurethane<br />

Isocyanate + Water Amine + Carbondioxide<br />

R –N =C =O + R° –NH2<br />

Isocyanate + Amine Urea/Polyurea<br />

R –N =C =O<br />

+<br />

R’–COOH<br />

Isocyanate + Carboxylic Acid Amide<br />

R<br />

R<br />

H<br />

N<br />

H<br />

N<br />

O<br />

O<br />

O<br />

H<br />

N<br />

R’ +<br />

R°<br />

R’<br />

CO 2<br />

5


6<br />

2. VOC compliant systems<br />

Putties<br />

Primer/Surfacer<br />

Base Coat<br />

VOC-legislation for car refinish in europe<br />

Automotive Refinish Current VOC 1) VOC 1) Value 2010 Technology<br />

250 g/l<br />

540 g/l<br />

420 g/l<br />

Clear Coat 420 g/l<br />

High Solids<br />

Waterborne<br />

250 g/l<br />

250 g/l<br />

420 g/l<br />

Depending on the<br />

“state of the art”<br />

Uni Topcoat 420 g/l 420 g/l<br />

1) VOC = Volatile Organic Compounds<br />

2) VHS = Very High Solids: VOC ≤ 250 g/l<br />

3) HS = High Solids: VOC ≤ 420 g/l<br />

2K-PUR<br />

Clear Coat<br />

2K-PUR<br />

Primer/Surfacer<br />

Putty<br />

• Standard UPE<br />

• Styrene free systems<br />

• 2K-PUR HS 3) /-VHS 2)<br />

• 2K-PUR-waterborne<br />

• 1K-PUR-waterborne<br />

• 1K-Acrylicwaterborne<br />

• 2K-PUR-HS 3) (VHS 2) )<br />

• (2K-PURwaterborne)<br />

• 2K-PUR-HS 3)<br />

• (2K-PURwaterborne)<br />

Bayer VOC compliant raw materials for car refinish<br />

High Solids Desmophen ® / Desmodur ®<br />

Waterborne Bayhydrol ® / Bayhydur ®<br />

Styrene-Free<br />

Desmophen ® / Desmodur ®<br />

Bayhydrol ® / Bayhydur ®<br />

Roskydal ®


3. Desmodur ® polyisocyanate hardeners<br />

OCN<br />

Desmodur ®<br />

N 100<br />

N 75<br />

N 3200<br />

Aliphatic polyisocyanate hardeners for 2K PUR coatings*<br />

R<br />

O<br />

HDI Biuret<br />

OCN<br />

N<br />

Type<br />

R<br />

NH<br />

O<br />

Standard<br />

HDI-Biuret<br />

Standard<br />

HDI-Biuret<br />

Low viscous<br />

HDI-Biuret<br />

NCO<br />

H<br />

N<br />

R<br />

NCO<br />

R =C 6H 12<br />

NCO<br />

O<br />

N<br />

O<br />

R<br />

R<br />

N N R<br />

O<br />

NCO<br />

R =C 6H 12<br />

Supply<br />

form [%]<br />

NCO<br />

NCO-<br />

Content [%]<br />

OCN<br />

O<br />

*one possible structure (ideal)<br />

HDI Isocyanurate (Trimer) IPDI Isocyanurate (Trimer)<br />

HDI-Biuret hardeners<br />

* also in butyl acetate<br />

MPA – methoxy propyl acetate<br />

X – xylene<br />

O<br />

N N<br />

N<br />

Viscosity<br />

[mPa·s]<br />

at 23° C<br />

NCO<br />

NCO-<br />

Functionality<br />

Equivalent<br />

weight<br />

TSCA<br />

100 22.0 10,000 F = 3.8 191 Yes<br />

75 MPA/X* 16.5 225 F = 3.8 255 Yes<br />

100 23.0 2,500 F = 3.5 183 Yes<br />

O<br />

7


8<br />

3. Desmodur ® polyisocyanate hardeners<br />

HDI-Isocyanurate hardeners<br />

Desmodur ®<br />

N 3790<br />

N 3300<br />

N 3390<br />

N 3600<br />

Type<br />

High viscosity,<br />

fast drying<br />

Standard type,<br />

solvent free<br />

Standard type,<br />

solution<br />

Low viscosity,<br />

for high solids<br />

Supply<br />

form [%]<br />

NCO-<br />

Content [%]<br />

* also in BA – butyl acetate, SN – solvent naphta 100<br />

Desmodur ® N 3790, N 3300, N 3390 and N 3600 are all TSCA listed<br />

3 R–NCO<br />

R =OCN–(CH2) 6–<br />

n = number of monomeric units incorporated<br />

Voltage [V]<br />

O<br />

Viscosity<br />

[mPa·s]<br />

at 23° C<br />

NCO-<br />

Functionality<br />

90 BA 18.0 2,000 F = 4.1<br />

˜<br />

30 20<br />

50 236<br />

˜<br />

100 21.8 3,000 F = 3.5 ˜ 50 20 30 193<br />

90 BA/SN* 19.6 550 F = 3.5 ˜ 50 20 30 216<br />

100 23.0 1,200 F = 3.2<br />

Oligomer distribution in technical HDI-Isocyanurates<br />

R<br />

+ 2 R–NCO<br />

[Cat.] [Cat.]<br />

R R<br />

O<br />

O<br />

Monomer (n=1) Trimer (n=3) Pentamer (n=5)<br />

GPC of a technical HDI hardener<br />

Heptamer<br />

Pentamer<br />

O<br />

R<br />

R<br />

O<br />

Oligomer distribution<br />

[%]<br />

n=3 5 7<br />

˜<br />

elution volume [ml]<br />

Equivalent<br />

weight<br />

70 20 15 180<br />

O<br />

Trimer<br />

^ ^<br />

^<br />

^<br />

O<br />

(CH2) 6<br />

^<br />

^ ^<br />

^<br />

R<br />

O<br />

O<br />

R


➔<br />

●<br />

●<br />

●<br />

➔<br />

●<br />

●<br />

IPDI-based hardeners<br />

HDI-Trimer IPDI-Trimer<br />

T g – glass temperature approx. – 60° C approx. +60° C<br />

Viscosity 3,000 mPas solid (2,000 mPas at 70 % in SN*)<br />

SN – solvent naphta 100<br />

IPDI-Trimers have:<br />

a significant faster physical drying<br />

also secondary NCO groups<br />

➔ lower reactivity<br />

a significant higher viscosity<br />

➔ higher VOC<br />

compromise:<br />

use of IPDI hardeners in combination<br />

with HDI-based hardeners<br />

use of lower viscous IPDI allophanate<br />

Desmodur ® XP 2565<br />

Desmodur ®<br />

Z 4470<br />

XP 2565<br />

NZ 1<br />

Type<br />

Standard IPDI-<br />

Trimer<br />

Low viscous IPDI-<br />

Allophanate<br />

Solventfree IPDI/<br />

HDI-combination<br />

MPA – methoxy propyl acetate<br />

X – xylene<br />

SN – solvent naphta 100<br />

BA – butyl acetate<br />

Supply<br />

form [%]<br />

70 MPA/X<br />

70 SN<br />

NCO-<br />

Content [%]<br />

11.9<br />

IPDI-Trimer (one possible structure)<br />

Viscosity<br />

[mPa·s]<br />

at 23° C<br />

NCO<br />

1,500<br />

2,000<br />

O<br />

OCN<br />

O<br />

N N<br />

N O<br />

NCO-<br />

Functionality<br />

NCO<br />

Equivalent<br />

weight<br />

F = 3.3 360 Yes<br />

80 BA 12.0 2.800 F = 2.5 350 Yes<br />

100 % 20.0 3,000 F = 2.8 210 Yes<br />

TSCA<br />

9


10<br />

3. Desmodur ® polyisocyanate hardeners<br />

Low viscous HDI-based hardeners<br />

Desmodur ®<br />

N 3600<br />

XP 2410<br />

N 3400<br />

OCN<br />

R =C 6H 12<br />

<br />

O<br />

R<br />

R<br />

OCN<br />

R =C 6H 12<br />

NCO<br />

R<br />

O<br />

O<br />

R<br />

NCO<br />

R<br />

O<br />

NCO<br />

R<br />

*Desmodur ® N 3600<br />

OCN<br />

1,200 mPas*<br />

NCO<br />

700 mPas* 170 mPas*<br />

R–N N–R<br />

Asymmetric Trimer: *Desmodur ® XP 2410 HDI-Uretdione: *Desmodur ® N 3400<br />

Type<br />

Low viscous<br />

HDI-Trimer<br />

Very low viscous<br />

asymmetric<br />

HDI-Trimer<br />

Very low viscous<br />

HDI-Uretdione<br />

O<br />

Supply<br />

form [%]<br />

100<br />

100<br />

100<br />

NCO-<br />

Content [%]<br />

23.0<br />

24.0<br />

21.8<br />

O<br />

R =C 6H 12<br />

Viscosity<br />

[mPa·s]<br />

at 23° C<br />

1,200<br />

700<br />

170<br />

<br />

O<br />

O<br />

NCO-<br />

Functionality<br />

F = 3.2<br />

F = 3.1<br />

F = 2.5<br />

Equivalent<br />

weight<br />

180<br />

175<br />

193<br />

NCO<br />

TSCA<br />

Yes<br />

Yes<br />

Yes


Relative<br />

NCO-Content<br />

[%]<br />

90<br />

80<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

50 100 150 200 250 300<br />

time at room temperature [h]<br />

*High Solids Clear Coat based on Desmophen ® A VP LS 2350 – cured at 23° C/50 % humidity; NCO/OH=1:1<br />

Desmodur ®<br />

*100% version of Desmodur ® N 3790, not commercial available<br />

Reactivity of different aliphatic polyisocyanate hardeners*<br />

Functionality versus viscosity for different HDI-based hardeners<br />

N 3400<br />

XP 2410<br />

N 3600<br />

N 3300<br />

N 3700*<br />

100 300 700 1,200 3,000 15,000<br />

viscosity [mPas]<br />

Desmodur ® Z 4470<br />

HDI-Trimers:<br />

Desmodur ® N 3790<br />

Desmodur ® N 3390<br />

Desmodur ® N 3600<br />

Desmodur ® XP 2410<br />

HDI Uretdione<br />

Desmodur ® N 3400<br />

NCO Decrease<br />

detected by<br />

IR Spectroscopy<br />

4<br />

3.5<br />

3<br />

2.5<br />

functionality<br />

11


12<br />

4. Desmophen ® polyols and reactive diluents<br />

Desmophen ® Type Supply Form [%] OH-Content [%]<br />

supply form/solid<br />

A160<br />

A170<br />

Polyacrylate<br />

60 in X<br />

70 in BA<br />

1.6 / 2.6<br />

1.8 / 2.6<br />

1,800<br />

3,500<br />

A 265 Polyacrylate 65 in BA 2.0 / 3.1 2,300<br />

A 365 Polyacrylate 65 in BA/X 3:1 2.9 / 4.5 3,000<br />

A 450 Polyacrylate<br />

50 in MPA/X<br />

50 in BA<br />

1.0 / 2.0<br />

5,000<br />

4,000<br />

A 665 Polyacrylate 65 in BA/X 3:1 3.0 / 4.6 2,400<br />

A 870 Polyacrylate 70 in BA 3.0 / 4.3 3,500<br />

VP LS 2350 Polyacrylate 70 in BA 2.8 / 4.0 1,200<br />

VP LS 2383 Polyacrylate 60 in BA 2.5 / 4.2 4,500<br />

RD 181 Polyester<br />

75 in BA<br />

75 in MPA<br />

75 in X<br />

3.7 / 4.9<br />

4,500<br />

7,900<br />

7,500<br />

670 Polyester 80 in BA 3.4 / 4.3 2,800<br />

680 Polyester<br />

60 in X<br />

70 in BA<br />

1.9 / 3.1<br />

2.1 / 3.1<br />

Viscosity [mPa . s]<br />

at 23° C<br />

2,750<br />

3,000<br />

1150 Polyester 100 4.7 3,500<br />

BA – butyl acetate<br />

X – xylene<br />

MPA – methoxy propyl acetate<br />

SN 100 – solvent naphta 100<br />

Polyols for primers, surfacers, top and clearcoats


Applications Primer/<br />

Surfacer<br />

A160<br />

A170<br />

●<br />

A265 ●<br />

Top<br />

Coats<br />

Clear<br />

Coats<br />

High<br />

Solids<br />

● ● ●<br />

Standard resin for 540 g/l<br />

VOC primer/surfacers<br />

Fast drying<br />

universal resin<br />

A 365 ●<br />

Universal resin 585<br />

A 450 ●*<br />

A 665<br />

A 870<br />

VP LS 2350<br />

VP LS 2383<br />

RD 181 ●<br />

670 ●*<br />

●* ●* ●<br />

● ●<br />

● ● ●<br />

● ● ●<br />

● ● ●<br />

●<br />

●* ●*<br />

Combination resin<br />

for improved drying<br />

Outstanding QUV<br />

UV-B resistance<br />

Suitable for 480 g/l<br />

top- and clear coats<br />

Suitable for 420 g/l<br />

clear- and top coats<br />

For fastest drying<br />

clear- and top coats<br />

Grinding resin for<br />

pigment pastes<br />

Combination resin<br />

for flexibilisation<br />

680 ● ● ●<br />

Universal resin<br />

1150 ●*<br />

* = in combination with other resins<br />

Applications and properties<br />

●<br />

Very fast<br />

Drying<br />

Special applications<br />

and properties<br />

VHS in combination<br />

with reactive diluents<br />

Equivalent<br />

weight<br />

1,060<br />

945<br />

850<br />

1,700<br />

567<br />

575<br />

607<br />

680<br />

460<br />

485<br />

945<br />

775<br />

354<br />

13


14<br />

4. Desmophen ® polyols and reactive diluents<br />

OH content [%]<br />

on solids<br />

4<br />

3<br />

2<br />

1<br />

Relationship between drying and VOC-value (Hardener: Desmodur ® N 3390)<br />

VOC-value [g/l]<br />

580<br />

560<br />

540<br />

520<br />

500<br />

480<br />

460<br />

440<br />

420<br />

Hydroxyacrylates for Medium Solid 2K PUR Systems<br />

A 450<br />

faster<br />

2<br />

LS 2383<br />

A 160<br />

A 265<br />

Clear Coats<br />

Primer/Surfacer<br />

Drying (tackfree)<br />

LS 2383<br />

A265<br />

A 870<br />

A 365<br />

A 665<br />

Size of bubbles: durability<br />

slower<br />

A 365<br />

A 665<br />

A 870<br />

LS 2350<br />

4 6 8 10 12<br />

Drying time [h] till touchability


Reactive diluents for very high solids<br />

1)<br />

2)<br />

3)<br />

Very High Solids Systems<br />

(< 250 g/l VOC)<br />

Very low<br />

viscous<br />

polyols<br />

Very low<br />

viscous<br />

hardener<br />

Very slow<br />

drying<br />

Polyaspartates:<br />

● sterically hindered<br />

● electron deficient<br />

● secondary aliphatic amines<br />

no blocking agent<br />

very low odour<br />

good compatibility<br />

low colour value<br />

Desmophen ®<br />

VP LS 2142<br />

VP LS 2965<br />

NH 1521<br />

(VP LS 2973)<br />

Low viscous<br />

polyols<br />

Low viscous<br />

hardener<br />

Reactive<br />

diluent<br />

Fast drying<br />

Type<br />

Aldimine<br />

Ketimine<br />

EtO<br />

EtO<br />

Polyaspartate<br />

Synthesis and Chemical Structure of Polyaspartates<br />

90 in BA<br />

~25<br />

~80<br />

~150<br />

Equivalent<br />

weight<br />

4) NH 1520<br />

Polyaspartate 100 ~1200<br />

290<br />

O<br />

O<br />

R I<br />

R I<br />

N<br />

X = H 3 C<br />

N<br />

100<br />

100<br />

R<br />

Supply<br />

form [%]<br />

Crosslinking-Reaction of Aldimines and Ketimines via Hydrolysis<br />

R<br />

X<br />

R<br />

N<br />

R I<br />

+2H 2 O<br />

-2H 2 O<br />

Reaction via Imin-Enamin Tautomerie<br />

X<br />

R<br />

N<br />

H 2 N X<br />

CH 2<br />

R I<br />

NH 2<br />

Viscosity at<br />

23° C [mPas]<br />

catalyst<br />

CH 3<br />

O<br />

O<br />

139<br />

167<br />

356<br />

OEt<br />

OEt<br />

H 2 N<br />

H<br />

R I<br />

N<br />

CH 2<br />

X<br />

R<br />

Reactivity<br />

++<br />

++ (+)<br />

+<br />

+<br />

X<br />

R<br />

OEt<br />

NH 2<br />

N<br />

O<br />

H<br />

R I<br />

H<br />

N<br />

+2<br />

O<br />

OEt<br />

R<br />

O<br />

R I<br />

crosslinking with<br />

Polyisocyanate<br />

X<br />

Applications<br />

O<br />

clear & top coats in<br />

comb. with 3+5<br />

primers & fillers in<br />

comb. with polyols<br />

clear & top coats in<br />

comb. with 1+5;<br />

top coats in comb.<br />

with polyacrylate<br />

polyols<br />

N<br />

H<br />

OEt<br />

O<br />

TSCA<br />

EINECS<br />

clear coats & fillers in<br />

5) NH 1420 Polyaspartate 100 ~1500<br />

279<br />

++<br />

Yes*<br />

comb. with 1+3<br />

putties & elastomers<br />

6) NH 1220 Polyaspartate 100 ‹100<br />

230<br />

++++<br />

Yes*<br />

in comb. with 5<br />

BA – butyl acetate<br />

Yes<br />

Yes<br />

Yes*<br />

Yes*<br />

OEt<br />

*: registered “New Stuff” in Europe<br />

15


16<br />

5. Bayhydrol ® /Bayhydur ® for waterborne systems<br />

VP LS 2290<br />

Waterborne 2K-PUR systems<br />

Waterborne coatings with highest quality: ➔ Waterborne 2K-PUR Coatings<br />

Aqueous Polyol<br />

PES: Polyester, PAC: Polyacrylate, *: % on solids, °: % on supply form<br />

DMEA – dimethyl ethanolamin<br />

BG – butylglycol<br />

PnB – propylenglycol butyl ether<br />

SN 100 – solvent naphta 100<br />

+<br />

Polyisocyanate<br />

Polyols for waterborne 2K-PUR systems<br />

Bayhydrol ®<br />

VP LS 2139/2<br />

XP 2469<br />

A 145<br />

XP 2470<br />

Type<br />

PES/PAC<br />

secondary<br />

emulsion<br />

PES/PAC<br />

secondary<br />

emulsion<br />

Polyacrylate<br />

secondary<br />

emulsion<br />

Polyacrylate<br />

secondary<br />

emulsion<br />

Polyacrylate<br />

secondary<br />

emulsion<br />

Supply<br />

form [%]<br />

45<br />

45<br />

45<br />

45<br />

*OH-<br />

Content<br />

[%]<br />

3.8<br />

3.8<br />

2.5<br />

3.3<br />

°Co-Solvents<br />

[%]<br />

2.5<br />

Butyldiglycol<br />

8 BG<br />

8 PnB<br />

4 BG<br />

4 SN 100<br />

Polyacrylate, Polyester or<br />

Polyurethane Emulsion or Solution<br />

Hydrophilic and/or<br />

Low Viscous Hydrophobic Type<br />

Viscosity<br />

[mPa·s]<br />

at 23° C<br />

~2,000<br />

~1,500<br />

~1,500<br />

~800<br />

pHvalue<br />

7.5<br />

7.0<br />

8.4<br />

8.0<br />

4 PnB<br />

45 3.9<br />

~2,000 7.8<br />

4 SN 100<br />

*acid<br />

number<br />

27<br />

29<br />

18<br />

22<br />

24<br />

neutralized<br />

with<br />

DMEA<br />

DMEA<br />

DMEA<br />

DMEA<br />

Triethanolamin<br />

DMEA<br />

T G [°C]<br />

6<br />

45<br />

30<br />

28<br />

50<br />

Applications<br />

solid colour top<br />

coat primer surfacer<br />

top coat<br />

clear coat<br />

primer/surfacer<br />

top coat<br />

primer/surfacer<br />

solid colour top<br />

coat primer,<br />

clear coat<br />

top coat<br />

clear coat


Hydrophilic polyisocyanates<br />

Hydrophilic<br />

Polyisocyanates<br />

External emulsification<br />

State of the art:<br />

polyether modified trimer<br />

Bayhydur ® 3100<br />

New:<br />

sulfonic acid<br />

modified trimer<br />

Bayhydur ® XP 2487/1<br />

Bayhydur ® XP 2570<br />

Emulsifier in the PIC Migration of Emulsifier<br />

Internal emulsification<br />

(Bayhydur types) chemically linked not possible<br />

polyether modified<br />

allophanate/trimer<br />

Bayhydur ® VP LS 2319<br />

not chemically linked<br />

OCN<br />

OCN<br />

Bayer MaterialScience approach<br />

O<br />

O<br />

N N<br />

N O<br />

out of the film is<br />

possible<br />

Chemical structures of hydrophilic polyisocyanate hardeners<br />

OCN<br />

OCN<br />

OCN<br />

OCN<br />

OCN<br />

OCN<br />

O<br />

O<br />

O<br />

N N<br />

N O<br />

O<br />

O<br />

N N<br />

O<br />

N N<br />

N O<br />

N O<br />

H<br />

N<br />

H<br />

N<br />

N<br />

O<br />

O<br />

O<br />

H<br />

N<br />

O O<br />

O<br />

O O<br />

O<br />

O<br />

N N X SO3<br />

- +<br />

NR3H<br />

O<br />

Blistering,<br />

reduction of water resistance<br />

and gloss possible<br />

Less blistering,<br />

better properties<br />

➔ Benefits to hydrophobic polyisocyanates:<br />

– improved dispersibility<br />

➔ Benefits to polyether modified trimers (state of the art):<br />

– higher functionality<br />

– low water sensitivity of the film<br />

O<br />

➔ Benefits to polyether modified polyisocyanates:<br />

– lower amount of hydrophilic moieties<br />

– higher NCO-content and drying speed<br />

– increased hardness<br />

– improved chemical resistance<br />

O<br />

O<br />

O<br />

O<br />

O<br />

O<br />

CH3<br />

CH3<br />

ideal structures<br />

17


18<br />

Hydrophilic types Bayhydur ®<br />

Hydrophobic, low viscous types Desmodur ®<br />

Desmodur ®<br />

N 3600<br />

Desmodur ®<br />

XP 2410<br />

Desmodur ®<br />

N 3400<br />

Bayhydur ®<br />

VP LS 2319<br />

Bayhydur ®<br />

3100<br />

Bayhydur ®<br />

XP 2487/1<br />

Bayhydur ®<br />

XP 2570<br />

Desmodur ®<br />

XP 2565<br />

Bayhydur ®<br />

VP LS 2150<br />

BA – butyl acetate<br />

MPA – methoxy propyl acetate<br />

X – xylene<br />

Polyisocyanates for waterborne 2K PUR systems<br />

Type Supply<br />

Form<br />

[%]<br />

HDI-Trimer,<br />

low viscious<br />

HDI-Trimer,<br />

very low viscious<br />

HDI-Uretdione,<br />

very low viscious<br />

HDI-Trimer,<br />

slightly hydrophilic<br />

HDI-Trimer,<br />

hydrophilic<br />

HDI-Trimer,<br />

ionically modified<br />

HDI-Trimer,<br />

ionically modified<br />

IPDI-Allophanate,<br />

low viscious<br />

IPDI-Trimer,<br />

hydrophilic<br />

100<br />

NCO-<br />

Content<br />

[%]<br />

23.4<br />

Viscosity<br />

[mPa . s]<br />

at 23° C<br />

1,200<br />

NCO- Hand<br />

Functionality mixable<br />

F = 3.2<br />

100 20.5 6,000 F = 3.4 + Yes<br />

100 20.5 3,500 F = 3.0 ++ Yes<br />

- -<br />

TSCA<br />

Yes<br />

100 24.0 700 F = 3.1 - Yes<br />

100 21.8 170 F = 2.5 - Yes<br />

100 18.0 4,500 F = 3.8 + Yes<br />

100 17.4 3,300 F = 3.2 + No<br />

80 BA 12.0 2,800 F = 2.5 - - Yes<br />

70 MPA/X 13.4 600 F = 3.0 + Yes


New technologies for car refinish systems<br />

Main technology trends driven by ecological reasons<br />

2K-PUR Clear Coat<br />

CAB-Base Coat<br />

2K-PUR Primer/Surfacer<br />

Wash Primer<br />

Putty<br />

New technology trend driven by economical* reasons<br />

2K-PUR Clear Coat<br />

CAB-Base Coat<br />

2K-PUR Primer/Surfacer<br />

Wash Primer<br />

Putty<br />

High Solids 1<br />

Waterborne 2<br />

Very High Solids 3<br />

Waterborne 2<br />

1K UV curing 4<br />

Styrene free UPE 4<br />

2K PUR putties 4<br />

Fast Drying 2K PUR 1<br />

1K UV or Dual Cure 4<br />

Fast Drying 2K PUR 1<br />

1K UV curing 4<br />

2K PUR putties 4<br />

1K UV curing 4<br />

*economical reasons can be: – faster drying speed to reduce overall process time<br />

– 1K instead of 2K system to improve degree of efficiency<br />

1 ® ® based on Desmophen A/Desmodur N<br />

2 ® ® ®<br />

based on Bayhydrol /Bayhydur /Desmodur<br />

3 ® ® based on Desmophen NH reactive diluents/Desmodur N<br />

4<br />

Bayer MaterialScience products under development.<br />

For further information please contact our Technical Service.<br />

19


20<br />

6. Roskydal ® unsaturated putty-polyesters<br />

Roskydal ® Supply Form<br />

[%]<br />

in styrene<br />

K 14M 64<br />

Unsaturated polyesters for refinish and marble putties<br />

Viscosity<br />

[mPa . s]<br />

at 23° C<br />

825<br />

K 27/1 70 2,200<br />

K 30 65 500<br />

K 36 62 400<br />

K 45 65 575<br />

K 40T 65 Thixotropic<br />

XP 2519 66 650<br />

K 65 67 725<br />

K 68 65 750<br />

Characteristics<br />

Very high reactive,<br />

very hard<br />

High reactive,<br />

very hard<br />

High reactive,<br />

medium hard<br />

Very high reactive,<br />

medium flexible<br />

High reactive,<br />

medium flexible<br />

Medium reactive,<br />

highly flexible<br />

Fields of<br />

application<br />

Knifing<br />

fillers/putties<br />

for marble<br />

and stone<br />

Highly filled<br />

cours and<br />

fine fillers/<br />

putties for<br />

industrial or<br />

DIY car body<br />

repair, wood<br />

and metal<br />

applications<br />

Special Properties<br />

Very good mechanical<br />

properties, high gloss<br />

after polishing; hard<br />

resins for combination<br />

with other<br />

Roskydal ® K-types<br />

Ideal sole-binder for a<br />

wide range of fillers and<br />

putties.<br />

Formulation in all<br />

standard mixing<br />

equipment<br />

Thixotropic binder.<br />

Production with Dissolver<br />

or Butterfly-mixer up to<br />

55° C possible<br />

Sole-binder with good<br />

adhesion properties on all<br />

galvanised car panel<br />

Sole-binder or in combination<br />

with Roskydal ® k14M<br />

for flexible putties with<br />

good adhesion on all<br />

galvanised car panel<br />

Special for overbaking<br />

resistant fillers up to<br />

180° C and plastification of<br />

other Roskydal ® K-types


Roskydal ® Supply Form<br />

[%]<br />

in styrene<br />

Unsaturated polyesters for spray and industrial putties<br />

Viscosity<br />

[mPa . s]<br />

at 23° C<br />

500 A 76 1,800<br />

620 69 850<br />

E 65 65 600<br />

E 70 65 950<br />

XP 2465 68 900<br />

Characteristics<br />

High reactive,<br />

medium hard<br />

High reactive,<br />

hard<br />

Medium reactive,<br />

elastic<br />

Low reactive,<br />

very elastic,<br />

soft<br />

High reactive,<br />

medium flexible<br />

Fields of<br />

application<br />

All kinds of<br />

knifing and<br />

spray fillers<br />

for car body<br />

and industrial<br />

application<br />

(regulation of<br />

potlife with<br />

addition of<br />

different amounts<br />

of inhibitor)<br />

Special Properties<br />

Very good air drying<br />

properties in combination<br />

withRoskydal ® E-types<br />

Good storage stability<br />

with Co-salts, especially<br />

in combination with<br />

Roskydal ® E-types<br />

Universal, air drying<br />

combination resin with<br />

good storage stability,<br />

even with Co-salts<br />

Soft resin used for<br />

plastification of all<br />

Roskydal ® K-types<br />

Sole binder for UPE<br />

fillers with longer potlife<br />

and spray fillers<br />

21


22<br />

Technical Service Contacts<br />

Europe, Middle East, Africa:<br />

Car Refinish Systems:<br />

Jörg Schmitz<br />

+49-214-30-57054<br />

Holger Mundstock<br />

+49-214-30-55578<br />

Michael Ehlers<br />

+49-214-30-56473<br />

Waterborne Systems:<br />

Martin Melchiors<br />

+49-214-30-52435<br />

NAFTA:<br />

Car Refinish Systems:<br />

Scott Grace<br />

+1-412-777-7657<br />

Dave Zielinski<br />

+1-412-777-7652<br />

South America:<br />

Car Refinish Systems:<br />

Alberto Hassessian<br />

+50-11-5694-5148<br />

Asia:<br />

Car Refinish Systems:<br />

Osamu Kirihara<br />

+81-6-6497-2166


If you have any questions<br />

regarding the technical details<br />

presented in this brochure,<br />

please contact us at:<br />

info@bayercoatings.com<br />

Additional information is available on the Internet at:<br />

www.bayercoatings.com<br />

23


www.bayercoatings.com<br />

Bayer MaterialScience AG<br />

Coatings, Adhesives & Sealants<br />

51368 Leverkusen<br />

Germany<br />

www.bayermaterialscience.com<br />

info@bayercoatings.com<br />

This information and our technical advice – whether verbal,<br />

in writing or by way of trials – are given in good faith but<br />

without warranty, and this also applies where proprietary<br />

rights of third parties are involved. Our advice does not<br />

release you from the obligation to verify the information<br />

currently provided – especially that contained in our safety<br />

data and technical information sheets – and to test our<br />

products as to their suitability for the intended processes<br />

and uses. The application, use and processing of our products<br />

and the products manufactured by you on the<br />

basis of our technical advice are beyond our control and,<br />

therefore, entirely your own responsibility. Our products are<br />

sold in accordance with the current version of our General<br />

Conditions of Sale and Delivery.<br />

Edition: 2005-02-MH<br />

Printed in Germany · E

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