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Theory of the Fireball

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causes <strong>of</strong> absorption are <strong>the</strong> molecular bands <strong>of</strong><br />

N (first positive) from about 1 to 2-1/4 ev<br />

2<br />

N: (first negative) " 2-1/2 to 3-3/4 ev<br />

NO (e bands)<br />

11<br />

" 2-1/2 to 6 ev<br />

and <strong>the</strong> continuous absorption due to 0- photodetachment from about 1-1/2<br />

ev up. The N2 second positive, and 0 Schumann-Runge, although <strong>the</strong>y con-<br />

2<br />

tribute, are . .<br />

usually weaker than <strong>the</strong> combination <strong>of</strong> N+ first negative and<br />

2<br />

NO and cover <strong>the</strong> same region <strong>of</strong> <strong>the</strong> spectrum (or less) 0- photodetach-<br />

ment is mostly important at <strong>the</strong> higher density, p/p = 1.<br />

0<br />

There is comonly a %Window" <strong>of</strong> low absorption below 1 ev, between<br />

free-free absorption and N2(lf), and ano<strong>the</strong>r at about 2-1/2 ev, between<br />

N2 and <strong>the</strong> o<strong>the</strong>r bands (Table IV) . The latter window is filled in by 0-<br />

photodetachment. At higher temperature, such as 12,000°, <strong>the</strong> photoelectric<br />

effect on N and 0 becomes important and <strong>the</strong>.molecular bands almost dis-<br />

appear; <strong>the</strong> absorption coefficient is <strong>the</strong>n almost uniform over <strong>the</strong> entire<br />

spectrum.<br />

The table by Meyerott et al. should be consulted for details. Apart<br />

from <strong>the</strong> free-free transitions, this table seems to be in error on <strong>the</strong><br />

N2( 1') absorption at 8000°, which should be increased by a factor <strong>of</strong> 4.<br />

With <strong>the</strong>se corrections, Table IV gives <strong>the</strong> absorption coefficients at<br />

8000' for a few frequencies and densities, mentioning in each case only<br />

<strong>the</strong> most important species <strong>of</strong> absorbers. For p/po = 0.1 and 0.01, <strong>the</strong><br />

contribution <strong>of</strong> NO and O2 in <strong>the</strong> wave length region considered is negli-<br />

gible. The windows at 1 and above 2 ev are noticeable in <strong>the</strong> table; beyond<br />

3 ev <strong>the</strong>re is a rapid increase in absorption.<br />

35<br />

J<br />

L. -~

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