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UN 3480 - ExtraEnergy.org

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The importance of the Selection of Li-ion<br />

Batteries for Vehicle Manufacturer‘s View<br />

International Seminar of Lithium-ion Batteries Technology Applied to Electric-Bike<br />

Hannes Neupert, President <strong>ExtraEnergy</strong> e.V. ,<br />

Treasurer EnergyBus e.V. and independent Consultant<br />

Shanghai 27th of April 2008


Table of contents<br />

- Battery types used in the european pedelec market<br />

- Transport rules by the United-Nations are binding law!<br />

- 8 key factors for battery selection<br />

- Potential danger of batteries - safety first!<br />

- How to know if a battery is safe!<br />

- BATSO tests a worldwide solution!<br />

Non chinese speakers please refer for most of the<br />

following slides to the print provided - most of the<br />

presentation will be for time reasons only presented in<br />

chinese!<br />

3


Battery types used in the european pedelec<br />

market:<br />

5


Kano-Model: Today’s batteries in pedelecs<br />

Customer wishes for batteries are light weight and small volume!<br />

1.6<br />

Li-Ion<br />

customer expectation<br />

unfulfilled<br />

satisfied customer<br />

exalted<br />

unexpected requirement<br />

spoken requirement<br />

expected<br />

dissatisfied customer<br />

4.2<br />

NiMHd<br />

unspoken requirement<br />

satisfied<br />

customer expectation<br />

fulfilled<br />

NiCd<br />

Lead acid PB<br />

10.1 5.3<br />

7


Kano-Model: Future batteries in pedelecs<br />

Customer wishes for batteries are light weight and small volume!<br />

1.6 ?<br />

customer expectation<br />

unfulfilled<br />

satisfied customer<br />

exalted<br />

unexpected requirement<br />

spoken requirement<br />

expected<br />

dissatisfied customer<br />

4.2<br />

unspoken requirement<br />

satisfied<br />

customer expectation<br />

fulfilled<br />

Li-Ion<br />

9


Lithium-batterie sales in general:<br />

more then 2500 Mio Li cells will be ruffly shipped in 2007 / worldwide sales of Li-Ion will exceed 5bn USD 2007 / this will be<br />

doubled 2010, pot. double digit rated growing 2010 with mobile/Automotive, source: Takeshida/JP IILP + other)<br />

11


Transport rules by the United-Nations are<br />

binding law:<br />

- All LEV‘s which use Lithium batteries have to be shipped<br />

according to <strong>UN</strong>-transport rules with proper marking<br />

- All batteries need to be tested for <strong>UN</strong>-T Test, the test is<br />

only valid for exactly the tested pack, it it will be modified<br />

the test has to be repeated!<br />

13


Why does the <strong>UN</strong>-T regulation exist?<br />

You all know about the reports about burning laptops and<br />

the recalls affected millions of battery sets!<br />

15


Example about a serious incident: UPS cargo Flight 1307,<br />

Feb 7 2006 Philadelphia, Pennsylvania USA:<br />

16


Good luck nobody was hurt - but would you like to sit in a<br />

airplane together with some lithium batteries?<br />

Lithium Batteries carried at<br />

cargo position 3 and 14<br />

17


International penal or criminal codes:<br />

For all parties involved in handling lithium batteries which<br />

do not fulfill the <strong>UN</strong>-T regulations (not proper tested/not<br />

correctly labeled and shipped,... )<br />

- It is a serious criminal offense<br />

- Esp. traffic offense<br />

- terms of imprisonment are claimed: …3 to…max. 5<br />

years…! Personal ignorance is no excuse!<br />

20


<strong>UN</strong> 3090/<strong>UN</strong>3091 Lithium batteries/ Equipment<br />

Rules Packaging rules<br />

<strong>UN</strong> 3090<br />

(<strong>UN</strong> <strong>3480</strong>)<br />

Special<br />

regulations<br />

Packaging rules<br />

<strong>UN</strong> 3091<br />

(<strong>UN</strong> 3481)<br />

Special<br />

regulations<br />

ADR P 903 188, 230, 310, 636 P 903 188, 230, 636<br />

IMDG-Code P 903 188, 230, 310 P 903 188, 230<br />

ICAO-TI /<br />

IATA-DGR<br />

PAX-A/C CAO-A/C<br />

903 903<br />

max. 5 kg br. max. 35 kg br.<br />

A45, A88, A99 912 A45, A48<br />

Orange Book P 903 188, 230, 310 P 903 188, 230<br />

22


ELECT RICALLY POWERED VEHICLES / EQUIPMENT<br />

<strong>UN</strong> 3171 Battery Powered Vehicle, Class 9,<br />

24


Executive summary<br />

Various Dangerous-Goods (DG)-regulations for different<br />

battery systems.<br />

Batteries as DG`s can be shipped as Class 9 DG`s<br />

worldwide accordingly to regulations.<br />

Lithium batteries have to pass <strong>UN</strong> 38.3 safety tests prior<br />

shipping.<br />

A lot of detailed material about correct shipping is<br />

available at www.<strong>ExtraEnergy</strong>.<strong>org</strong><br />

26


Executive summary<br />

Various Dangerous-Goods (DG)-regulations for different<br />

battery systems.<br />

Batteries as DG`s can be shipped as Class 9 DG`s<br />

worldwide accordingly to regulations.<br />

Lithium batteries have to pass <strong>UN</strong> 38.3 safety tests prior<br />

shipping.<br />

A lot of detailed material about correct shipping is<br />

available at www.<strong>ExtraEnergy</strong>.<strong>org</strong><br />

28


8 key factors for battery selection:<br />

29


Known example of pay by use: Why are cell phones so cheap to by?<br />

Many people never think about that since it was ever like that since they<br />

use a cell phone. When I remember that the first mobile phones in the<br />

80‘s have cost more than a small car it was out of imagination that a cell<br />

phone will be such a consumer item as of today!<br />

The key to it was to my observation that the payment system has been<br />

changed from an upfront payment to a pay by usage payment combined<br />

with some monthly payments.<br />

This has made the cell phone affordable to much more user groups who<br />

have never imagined how much the cell phone would change their<br />

lifestyle - you all know it the break through has happened but it has taken<br />

huge investments into the infrastructure by the operators.


Similar approach is common practice for purchasing printers:<br />

All printer companies sell their printers usually below their costs and<br />

recover their losses and create their profits by selling the ink refills with<br />

high margins added.<br />

This scheme seems to be well accepted by the consumers. Even some<br />

ink refills are more expensive than printers...


How would it work for a pedelec from the business?<br />

There are 3 players needed - a comparison to the cell phone business again:<br />

monthly payment by the user Many service providers available radio network infrastructure<br />

??<br />

monthly payment by the user Who will be the Service provider? Battery and charger infrastructure


How would it work for a pedelec from the technology?<br />

Function based on common standards - a comparison to the cell phone again:<br />

Mechanical standardization of SIM card<br />

one size used by all providers and phone<br />

makers!<br />

Standardized secure communication<br />

between the SIM card and the cell phone<br />

Mechanical standardization of Battery case<br />

and connector together with the standard<br />

EnergyBus protocol allow full<br />

interchangeability between pedelecs of<br />

different manufacturers!<br />

Standardized Battery-Safety-Test BATSO<br />

allow to select only safe Batteries<br />

standardized radio bands are used for cell<br />

phones to communicate with the radio<br />

towers and roam to stations of other<br />

providers if no own available<br />

Standardized identification procedures<br />

allow the network to identify the user<br />

Mechanical standardization of Battery<br />

case, exchange station interface and<br />

connector together with the standard<br />

EnergyBus protocol allow full<br />

interchangeability between exchange<br />

stations of different manufacturers as well<br />

privately owned chargers!<br />

The public rental scheme like proposed in Stuttgart can only work due to the existence of a non proprietary<br />

communication protocol as well a worldwide recognized safety test protocol which allows to identify safe battery<br />

packs to be used in such a system


Common Battery for rental systems may change LEV‘s!<br />

Mechanical standardization of Battery case<br />

and connector together with the standard<br />

EnergyBus protocol allow full<br />

interchangeability between pedelecs of<br />

different manufacturers!<br />

Standardized Battery-Safety-Test BATSO<br />

allow to select only safe Batteries<br />

Batteries may fit to many different pedelecs<br />

Mechanical standardization of Battery<br />

case, exchange station interface and<br />

connector together with the standard<br />

EnergyBus protocol allow full<br />

interchangeability between exchange<br />

stations of different manufacturers as well<br />

privately owned chargers!


Potential danger of batteries - safety first:<br />

Exploding and/or burning lithium-batteries have caused<br />

several electric bike businesses to go bankrupt or suffer<br />

heavy loss of customers.<br />

To take it easy is like playing with a fire in a wooden<br />

house!<br />

<strong>ExtraEnergy</strong> is very concerned about that some severe<br />

incident could stop the growth of the european LEV<br />

market.<br />

38


Potential danger of batteries - safety first:<br />

Battery safety test developed for Deutsche Post AG by Mo-<br />

Hua Yang and Hannes Neupert 2003/04<br />

40


First Battery-Safety-Laboratory of <strong>ExtraEnergy</strong> build in 2004<br />

41


2005 sell 50% of<br />

the first lab to<br />

BMZ battery<br />

packing company<br />

located near<br />

Frankfurt/M<br />

Germany<br />

42<br />

Still jointly owned<br />

used mainly for<br />

safety test of BMZ


Enax Safety Movie: Example of a Successful Test:<br />

43


Example of a Non Successful Overcharge Test:<br />

44


2006 new improved test-laboratory<br />

joint project by <strong>ExtraEnergy</strong> and IT RI<br />

Installed in spring 2007 at<br />

IT RI facility Hsinchu Taiwan


Batteries which have passed the test have<br />

been delivered by the following companies:<br />

Sanyo NiCd 5 Ah 24 V<br />

Panasonic NiMhd 9 Ah 36 V<br />

Enax 16 Ah 24V<br />

LG Li-Ion 10 Ah 36 V<br />

Phylion 10 Ah 24 V<br />

Panasonic NEC-Tokin 8 Ah 24V<br />

AEE Energy 10 Ah 36V<br />

Phylion 10 Ah 36V<br />

Please consider that if you find a battery of one of the listed makers that this<br />

statement just mean that the battery which was tested by <strong>ExtraEnergy</strong> was<br />

safe and that similar batteries in different packs or after some of the common<br />

modification may behave much different.<br />

78


Paris: January 26, 2006<br />

Lithium Is The Promising Technology! Taiwanese DIY electric bike<br />

kit customers garage fire!<br />

40 000 Euro damage only<br />

But Lithium Technology is potentially dangerous and several Lithium Batteries on<br />

the market should not be sold anymore.<br />

A accident with a EU customer of a Taiwanes electric bike system has<br />

experienced in January 06 a tremendous fire in his bicycle garage. Fortunately<br />

due to good luck! Since<br />

Customer was still awake<br />

and fire department was<br />

called immediately!<br />

79


Lithium Is The Promising Technology!<br />

But Lithium Technology is potentially dangerous and several Lithium Batteries on<br />

the market should not be sold anymore.<br />

A accident with a EU customer of a Taiwanes electric bike system has<br />

experienced in January 06 a tremendous fire in his bicycle garage. Fortunately<br />

81


A serious incident could destroy the LEV market very quickly!<br />

82


How to know if a battery is safe?<br />

The <strong>UN</strong>-T Test does only check it a battery behaves safely<br />

during transportation not during usage!<br />

Reference to other battery packs even to some of the same<br />

supplier may not be correct since the history show that<br />

sometimes even previous safe tested cells become like a<br />

bomb when packed in a different way or just in a different<br />

casing!<br />

84


BATSO Test a worldwide solution!<br />

The BATSO Test which was released 18th of March 2008<br />

offers a unique opportunity to the LEV industry to prove<br />

the safety of the used lithium-battery-system as well as to<br />

communicate it to all involved parties.<br />

Please check out for the full test manual www.BATSO.<strong>org</strong><br />

it is available free of charge for download.<br />

86


BATSO Test a worldwide solution!<br />

- Battery types used in the European Pedelec market<br />

- Transport rules by the United Nations are binding law!<br />

- 8 key factors for battery selection<br />

- Potential danger of batteries - Safety first!<br />

- How to know if a battery is safe!<br />

- BATSO Tests and their history<br />

90


Thank you for your time!<br />

91


Hannes Neupert<br />

hannes.neupert@extraenergy.<strong>org</strong><br />

http://www.batso.<strong>org</strong><br />

<strong>ExtraEnergy</strong> e.V.<br />

Koskauer Straße 98<br />

07922 Tanna<br />

Germany<br />

Tel. +49 36646 27094<br />

Fax. +49 36646 27095<br />

info@extraenergy.<strong>org</strong><br />

93

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