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Chapter 38 Workbook Solutions

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<strong>38</strong>.5 Bohr's Model of Atomic Quantization<br />

<strong>38</strong>.6 The Bohr Hydrogen Atom<br />

<strong>38</strong>.7 The Hydrogen Spectrum<br />

Quantization . cHAPTER <strong>38</strong> <strong>38</strong>-9<br />

30. J. J. Thomson studied the ionization of atoms in collisions with electrons. He accelerated electrons<br />

through a potential difference, shot them into a gas of atoms, then used a mass spectrometer to detect<br />

any ions produced in the collisions. By using different gases, he found that he could produce singly<br />

ionized atoms of allthe elements that he tried. When he used higher accelerating voltages, he was able<br />

to produce doubly ionized atorns of all elements except hydrogen.<br />

a. Why did Thornson have to use higher accelerating voltages to detect doubly ionized atoms than to<br />

detect singly ionized atoms?<br />

To ..,o*" a sinq\y ioniznd dto,^.n, otto gleJco"' **t b" aor'.ouuJ<br />

4.o,- the 61*oua. A'do*b!1 ionizoA oto- fcq.rirqg Jhc re,v,novq.l of<br />

*vro. c\e.g*cons ylhich **kls rnoec. onergY qnd'thorttoce highar<br />

$,Cce\ege.{i r,q vo\to,qtS.<br />

b. What conclusion-or conclusions about hydrogen atoms can you draw from these observations? Be<br />

specific as to how your conclusions are related to the observations.<br />

H"lroo.or. e,r.,.st not hqv" two e-\sctrons tho.t can bc nc,vro{el<br />

to lrcjct.- o, do.^b\y ionizeA a*ov"r. ll1Aeolc^ hos o".\1 oylo<br />

g\q,*r o'n .<br />

3 1. If an electron is in a stationary state of an atom, is the electron at rest? If not, what does the term<br />

mean?<br />

No , th. e\q-ctron ,"tron is \^ot o* rc-s+. T+ is in o\n o\lot^tol orbi+'<br />

ott"*"a , or 1. *t"li.f 'or bi{s are, co"lloA stotton4rY<br />

\c. o",\*,<br />

stalcs. '<br />

32. The diagram shows the energy level diagram of element X.<br />

a. Wliat is the ionization energy of element X?<br />

lE,l = '1 uv<br />

E = o eV<br />

-leV-ll=3 i I 240 nnr<br />

-2cV - n=2<br />

g b. An atom in the ground state absorbs a photon, then emits a photon with a wavelength of 1240 nm.<br />

What conclusion can you draw about the energy of the photon that was absorbed?<br />

5<br />

r!<br />

o.<br />

O<br />

N<br />

ErU,oto'.,= 3c\<br />

@ c. An atom in the ground state has a collision with an electron, then emits a photon with a wavelength<br />

of 1240 nm. What conclusion can you draw about the initial kinetic energy of the electron?<br />

Eur."= 3 oV<br />

--4 eV

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