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ACTA PALAEONTOLOGICA ROMANIAE V. 7 (2011), P. 87-92<br />

CALCAREOUS NANNOFOSSILS AT THE PALEOGENE <strong>–</strong> NEOGENE BOUNDARY IN BUCOVINA,<br />

ROMANIA: RÂŞCA <strong>–</strong> VATRA MOLDOVIŢEI AREA<br />

CARMEN M. CHIRA 1 , DORU T. JURAVLE 2 , ALIN IGRIŢAN 1 & MIRELA V. POPA 1<br />

Abstract. A new section was investig<strong>at</strong>ed in order to establish <strong>the</strong> Paleogene/Neogene <strong>boundary</strong> in nor<strong>the</strong>rn Moldavia,<br />

Bucovina, i.e. Loba Valley section, loc<strong>at</strong>ed between Raşca and V<strong>at</strong>ra Moldoviţei localities. The new section was<br />

compared with <strong>the</strong> one from Dumbravnic Brook, nearby V<strong>at</strong>ra Moldoviţei. The presence of Sphenolithus conicus (NP23-<br />

NN2), which proves <strong>the</strong> presence of Lower Miocene, was remarked starting with <strong>the</strong> second part of <strong>the</strong> section besides<br />

Helicosphaera scissura, Coccolithus pelagicus, Reticulofenestra spp. etc.<br />

Triquetrorhabdulus carin<strong>at</strong>us (NN1), Discoaster drugii (NN2) and Helicosphaera cf. ampliaperta were also<br />

identified;,thus, <strong>the</strong> Lower Miocene age for <strong>the</strong>se deposits could be well documented.<br />

Keywords: Nannofossils, Paleogene-Neogene Boundary, nor<strong>the</strong>rn Eastern Carp<strong>at</strong>hians, Romania.<br />

INTRODUCTION<br />

Calcareous <strong>nannofossils</strong> include <strong>calcareous</strong><br />

nannoplankton, <strong>calcareous</strong> dinoflagell<strong>at</strong>es and ascidian<br />

spicules. The <strong>calcareous</strong> nannoplankton is represented by<br />

unicellular, micron-sized golden-brown algae belonging to<br />

Haptophyte, and it constitutes <strong>the</strong> <strong>calcareous</strong><br />

phytoplankton th<strong>at</strong> provides <strong>the</strong> largest amounts of<br />

calcified organisms.<br />

This study is focused on <strong>the</strong> <strong>calcareous</strong> <strong>nannofossils</strong><br />

identified across <strong>the</strong> Paleogene<strong>–</strong>Neogene <strong>boundary</strong> (PNB)<br />

in <strong>the</strong> sediments of <strong>the</strong> Loba Valley section (Fig. 1). The<br />

results were compared with <strong>the</strong> Dumbravnic Valley section<br />

(placed in <strong>the</strong> same area of <strong>the</strong> nor<strong>the</strong>rn Eastern<br />

Carp<strong>at</strong>hians), one of <strong>the</strong> currently most detailed studied<br />

section for <strong>the</strong> remarkable results obtained concerning <strong>the</strong><br />

Paleogene<strong>–</strong>Neogene <strong>boundary</strong> in <strong>the</strong> nor<strong>the</strong>rn Romanian<br />

province of Moldavia (Chira et al, in press).<br />

The investig<strong>at</strong>ed area, situ<strong>at</strong>ed between Raşca and<br />

V<strong>at</strong>ra Moldoviţei localities (Figs. 1, 2), belongs to <strong>the</strong><br />

nor<strong>the</strong>rn Paleogene<strong>–</strong>Early Miocene flysch units of <strong>the</strong><br />

Eastern Carp<strong>at</strong>hians, respectively to <strong>the</strong> Tarcău Nappe,<br />

part of <strong>the</strong> Moldavidian Realm (Săndulescu, 1984).<br />

CALCAREOUS NANNOFOSSIL ASSEMBLAGES<br />

ACROSS THE PALEOGENE<strong>–</strong>NEOGENE BOUNDARY IN<br />

MOLDAVIA, ROMANIA<br />

Calcareous <strong>nannofossils</strong> across <strong>the</strong> Paleogene<strong>–</strong>Neogene<br />

<strong>boundary</strong> were previously studied from o<strong>the</strong>r Eastern<br />

Carp<strong>at</strong>hian areas, situ<strong>at</strong>ed south from <strong>the</strong> section of<br />

Moldoviţa Valley Basin investig<strong>at</strong>ed by us, such as Tarcău<br />

Basin (Martini & Lebenzon, 1971, Lebenzon, 1973),<br />

Tazlău Basin (Ionesi & Gheţa, 1978; Dicea & Dicea,<br />

1980), or Trotuş Valley (Melinte-Dobrinescu & Brustur,<br />

2008), a.o.<br />

Around <strong>the</strong> Oligocene<strong>–</strong>Miocene <strong>boundary</strong> interval,<br />

shaly turbidites <strong>–</strong> i.e. <strong>the</strong> Vineţişu Form<strong>at</strong>ion in <strong>the</strong> inner<br />

facies, and <strong>the</strong> Podu Morii Form<strong>at</strong>ion in <strong>the</strong> outer facies<br />

(Melinte & Brustur, 2008), were deposited. The Oligocene-<br />

Miocene <strong>boundary</strong> was identified based on <strong>calcareous</strong><br />

nannoplankton investig<strong>at</strong>ions, towards <strong>the</strong> base of <strong>the</strong> two<br />

above-mentioned units (Melinte, 1988; Ionesi & Mészàros,<br />

1989; Ionesi et al., 1999; Mărunţeanu, 1999; Melinte &<br />

Brustur, 2008, Chira et al., in press, a.o.), within <strong>the</strong> NN1<br />

Nannofossil Zone of Martini (1971). In <strong>the</strong> sou<strong>the</strong>rn and<br />

central areas of <strong>the</strong> Eastern Carp<strong>at</strong>hians, Melinte &<br />

Brustur (2008) identified <strong>the</strong> NN1 biozone based on <strong>the</strong><br />

concurrent ranges of Sphenolithus capricornutus and<br />

Sphenolithus delphix.<br />

Mărunţeanu (1999) considered th<strong>at</strong> in Romania, in<br />

general, <strong>the</strong> Oligocene<strong>–</strong>Miocene <strong>boundary</strong> is<br />

represented by <strong>the</strong> FO of Helicosphaera mediterranea.<br />

Species with Oligocene<strong>–</strong>Miocene distribution ranges<br />

have been remarked in <strong>the</strong> Outer Moldavides:<br />

Coccolithus pelagicus, C. eopelagicus, Cyclicargolithus<br />

abisectus, C. floridanus, Discoaster adamanteus, D.<br />

deflandrei, Helicosphaera euphr<strong>at</strong>is, H. intermedia, H.<br />

paleocarteri, Sphenolithus conicus, Reticulofenestra<br />

minuta, R. minutula (Mărunţeanu, 1999).<br />

The <strong>calcareous</strong> <strong>nannofossils</strong> from Moldoviţa Basin<br />

had been previously investig<strong>at</strong>ed (Ionesi & Mészàros,<br />

1989), but from ano<strong>the</strong>r area - <strong>the</strong> Izvor Brook section,<br />

nearby Gura Humorului locality.<br />

In <strong>the</strong> Moldoviţa Basin, <strong>the</strong> Oligocene/Miocene<br />

<strong>boundary</strong> was remarked in <strong>the</strong> nor<strong>the</strong>rn part of <strong>the</strong><br />

Tarcău Nappe, within <strong>the</strong> Vineţişu Form<strong>at</strong>ion.<br />

The studied (Ionesi & Mészàros, 1989) <strong>calcareous</strong><br />

<strong>nannofossils</strong> from <strong>the</strong> Izvor Brook were separ<strong>at</strong>ed from<br />

<strong>the</strong> pelitic intervals of <strong>the</strong> limestones belonging to <strong>the</strong><br />

Jaslo Limestone. The presence of <strong>the</strong> NP25 Biozone <strong>–</strong><br />

with Sphenolithus ciperoensis was documented. In <strong>the</strong><br />

succession from Izvor Brook th<strong>at</strong> crosses <strong>the</strong> Dîlma<strong>–</strong><br />

Deia and Palamania<strong>–</strong>Ascuţita synclines, <strong>the</strong> subsequent<br />

biozone is represented by NN1 - with Triquetrorhabdulus<br />

carin<strong>at</strong>us (Ionesi & Mészàros, 1989, Juravle, 2007). The<br />

previous studies mainly focused on <strong>the</strong> Upper Member<br />

of <strong>the</strong> Jaslo Limestone and on <strong>the</strong> Vineţişu Form<strong>at</strong>ion<br />

from <strong>the</strong> Tarcău Nappe <strong>–</strong> Moldoviţa Lithofacies.<br />

From <strong>the</strong> Upper Member of <strong>the</strong> Jaslo Limestone, an<br />

assemblage with Sphenolithus ciperoensis, typical for<br />

<strong>the</strong> NP25 Biozone was identified.<br />

From <strong>the</strong> Vineţişu Form<strong>at</strong>ion, <strong>the</strong> studied <strong>calcareous</strong><br />

<strong>nannofossils</strong> assemblages provided <strong>the</strong> following<br />

biozones:<br />

1<br />

Babeş-Bolyai University, Department of Geology, 1 Kogălniceanu St., 400084 Cluj-Napoca, Romania. e-mail: carmen.chira@ubbcluj.ro<br />

2<br />

Al. I. Cuza University, Faculty of Geography and Geology, Carol I St., 700506 Iaşi, Romania.e-mail: jdorut@yahoo.com<br />

87


CARMEN M. CHIRA, DORU T. JURAVLE, ALIN IGRIŢAN & MIRELA V. POPA<br />

Fig. 1 - Geological map of Suceviţa-Moldoviţa area, with loc<strong>at</strong>ion of <strong>the</strong> studied section.<br />

- Sphenolithus ciperoensis Biozone - NP25 <strong>–</strong> in <strong>the</strong><br />

lower part, and an assemblage with Helicosphaera<br />

euphr<strong>at</strong>is, H. recta, Reticulofenestra bisecta,<br />

Pontosphaera enormis (NP25 or NN1);<br />

- NN1 Biozone, with Triquetrorhabdulus carin<strong>at</strong>us in<br />

<strong>the</strong> middle part;<br />

- no specific<strong>at</strong>ions were identified in <strong>the</strong> upper part.<br />

Thus, <strong>the</strong> Oligocene<strong>–</strong>Miocene <strong>boundary</strong> was<br />

evidenced in <strong>the</strong> top of <strong>the</strong> lower part of <strong>the</strong> Vineţişu<br />

Form<strong>at</strong>ion (Ionesi & Mészàros, 1989).<br />

The Vinetişu Form<strong>at</strong>ion represents <strong>the</strong> last term of <strong>the</strong><br />

Moldoviţa Lithofacies and it consists of sandstones and<br />

clays, 100<strong>–</strong>120 m thick. The <strong>calcareous</strong> sandstones form<br />

30<strong>–</strong>40 m-thick beds (Grasu et al., 2007).<br />

MATERIALS AND METHODS<br />

A number of 68 samples were investig<strong>at</strong>ed from Loba<br />

Valley<strong>–</strong>Raşca for <strong>the</strong>ir <strong>calcareous</strong> <strong>nannofossils</strong> content.<br />

About 130 vertical meters were sampled, <strong>the</strong> resolution of<br />

sampling being about one meter. A more detailed<br />

sampling for <strong>the</strong> Vinetişu Form<strong>at</strong>ion, <strong>at</strong> <strong>the</strong> Paleogene-<br />

Neogene <strong>boundary</strong>, was also accomplished meanwhile.<br />

The smear slides were studied under <strong>the</strong> optical<br />

microscope, with 1000x magnific<strong>at</strong>ion.<br />

RESULTS AND DISCUSSIONS CONCERNING THE<br />

CALCAREOUS NANNOFOSSIL ASSEMBLAGES<br />

ACROSS THE PALEOGENE<strong>–</strong>NEOGENE BOUNDARY<br />

FROM LOBA VALLEY SECTION<br />

Our previous study was realised in Moldoviţa Basin,<br />

nearby <strong>the</strong> locality with <strong>the</strong> same name, along<br />

Dumbravnic Brook, an affluent of Secrăieş Valley, which<br />

is tributary of Moldoviţa Valley (Fig. 1).<br />

In <strong>the</strong> Dumbravnic Brook section th<strong>at</strong> crosses <strong>the</strong><br />

Dilma<strong>–</strong>Deia and Palamina<strong>–</strong>Ascutita synclinal structures,<br />

<strong>the</strong> sediments belong to <strong>the</strong> Vineţişu Form<strong>at</strong>ion.<br />

About 100 samples were investig<strong>at</strong>ed in order to<br />

establish <strong>the</strong> Paleogene/Neogene <strong>boundary</strong> along<br />

Dumbravnic Brook (Chira et al., 2008; Chira et al., in<br />

press).<br />

In <strong>the</strong> first part of <strong>the</strong> section, almost all taxa of <strong>the</strong><br />

<strong>calcareous</strong> <strong>nannofossils</strong> assemblages have a large<br />

distribution in <strong>the</strong> Eocene and Oligocene.<br />

The most frequent Paleogene species, present in <strong>the</strong><br />

oldest part of <strong>the</strong> succession, are basically<br />

represent<strong>at</strong>ive for <strong>the</strong> Lower Oligocene: NP21<strong>–</strong>22 zones<br />

of Martini (1971): Reticulofenestra umbilica, Lanternitus<br />

minutus, Coccolithus formosus, Cyclicargolithus<br />

floridanus and Upper Oligocene NP23<strong>–</strong> 24 zones of<br />

Martini (1971): Helicosphaera ethologa, H. compacta, H.<br />

cf. wilcoxonii, a.o.<br />

In <strong>the</strong> youngest part of <strong>the</strong> section, <strong>the</strong> <strong>calcareous</strong><br />

<strong>nannofossils</strong> assemblages contain species th<strong>at</strong> are<br />

present also on <strong>the</strong> top of <strong>the</strong> Oligocene/Miocene<br />

<strong>boundary</strong>, which are frequent in <strong>the</strong> Lower Miocene:<br />

Helicosphaera scissura (NP24 <strong>–</strong> NN4), H. recta (NP24 <strong>–</strong><br />

NN4), Discoaster deflandrei (NP11 <strong>–</strong> NN7), Sphenolithus<br />

moriformis (NP12 <strong>–</strong> NN9), a.o.; also Paleogene species<br />

are present.<br />

88


CALCAREOUS NANNOFOSSILS AT THE PALEOGENE <strong>–</strong> NEOGENE BOUNDARY IN BUCOVINA, ROMANIA<br />

Fig. 2 - The Paleogene<strong>–</strong>Lower Neogene lithostr<strong>at</strong>igraphic units of <strong>the</strong> Tarcău and Vrancea Nappes.<br />

Fig. 3 - Lithologic succession of <strong>the</strong> Loba section, with samples loc<strong>at</strong>ion.<br />

89


CARMEN M. CHIRA, DORU T. JURAVLE, ALIN IGRIŢAN & MIRELA V. POPA<br />

The presence of Triquetrorhabdulus carin<strong>at</strong>us was<br />

remarked in <strong>the</strong> youngest part of <strong>the</strong> section, while<br />

topmost also Helicosphaera ampliaperta was present.<br />

Thus, <strong>the</strong> presence of <strong>the</strong> Paleogene/Neogene<br />

<strong>boundary</strong> could be certainly documented in <strong>the</strong> section<br />

from <strong>the</strong> Dumbravnic Brook in <strong>the</strong> Moldoviţa Basin.<br />

Our present study was realised north from Dumbravnic<br />

Brook, along Loba Valley, which is a left affluent of<br />

Moldoviţa Valley in <strong>the</strong> surroundings of Raşca locality.<br />

These results are only preliminary, meanwhile <strong>the</strong> section<br />

has been studied in detail for <strong>the</strong> Paleogene-Neogene<br />

<strong>boundary</strong>.<br />

The Loba Valley section (Fig. 3) was studied starting<br />

from <strong>the</strong> confluence of Loba and Moldoviţa valleys, which<br />

is loc<strong>at</strong>ed in Raşca locality (Fig. 1).<br />

In <strong>the</strong> oldest deposits of <strong>the</strong> investig<strong>at</strong>ed Loba Brook<br />

section, <strong>the</strong> nannofossil assemblages are rich in Upper<br />

Oligocene taxa: reticulofenestrids, sphenoliths,<br />

Zygrablithus bijug<strong>at</strong>us a.o.<br />

The presence of Sphenolithus conicus (NP23-NN2)<br />

was until now remarked starting with <strong>the</strong> second part of <strong>the</strong><br />

section, besides Helicosphaera scissura, Coccolithus<br />

pelagicus, Reticulofenestra spp., etc., proving <strong>the</strong><br />

presence of Lower Miocene (between samples 32 and 33).<br />

Triquetrorhabdulus carin<strong>at</strong>us (NN1), Discoaster drugii<br />

(NN2) and Helicosphaera cf. ampliaperta were also<br />

identified, thus <strong>the</strong> presence of Lower Miocene deposits<br />

could be well documented.<br />

Sometimes also coccospheres of Reticulofenestra<br />

were observed. Very frequent are ascidian spicules, and in<br />

same cases also taxa of <strong>the</strong> <strong>calcareous</strong> dinoflagell<strong>at</strong>e<br />

genus Thoracosphera.<br />

Holcova (2005) has studied <strong>the</strong> rel<strong>at</strong>ive abundances of<br />

seventeen <strong>calcareous</strong> nannoplankton species around <strong>the</strong><br />

Oligocene/Miocene <strong>boundary</strong> interval (NP25<strong>–</strong>NN2 Zones)<br />

in <strong>the</strong> nor<strong>the</strong>rn part of <strong>the</strong> Buda Basin (Central<br />

Par<strong>at</strong>ethys). She has documented a succession of four<br />

bioevents present in all <strong>the</strong> studied sections, as follows:<br />

first appearance d<strong>at</strong>um (FAD) of Helicosphaera carteri,<br />

FAD of Reticulofenestra cf. pseudoumbilica, and FADs of<br />

Discoaster druggii and Helicosphaera scissura, followed<br />

by FAD of Helicosphaera ampliaperta. The<br />

Oligocene/Miocene <strong>boundary</strong> was established between<br />

<strong>the</strong> FAD of Reticulofenestra cf. pseudoumbilica and FADs<br />

of Discoaster druggii and Helicosphaera scissura. O<strong>the</strong>r<br />

nannofossil events known to approxim<strong>at</strong>e this limit, such<br />

as <strong>the</strong> total range of Sphenolithus delphix and <strong>the</strong> last<br />

occurrence of Sphenolithus capricornutus, were not<br />

recognized.<br />

CONCLUSIONS<br />

The Loba Valley section was investig<strong>at</strong>ed starting from <strong>the</strong><br />

confluence of Loba and Moldoviţa valleys, loc<strong>at</strong>ed in<br />

Raşca locality (Fig. 1).<br />

In <strong>the</strong> first part of <strong>the</strong> investig<strong>at</strong>ed Loba Brook section,<br />

<strong>the</strong> nannofossil assemblages are rich in Upper Oligocene<br />

forms: reticulofenestrids, sphenoliths, Zygrablithus<br />

bijug<strong>at</strong>us a.o.<br />

The presence of Sphenolithus conicus (NP23-NN2)<br />

which proves <strong>the</strong> presence of Lower Miocene was until<br />

now remarked starting only from <strong>the</strong> second part of <strong>the</strong><br />

section, besides Helicosphaera scissura, Coccolithus<br />

pelagicus, Reticulofenestra spp., etc. Thus, <strong>the</strong><br />

Paleogene-Neogene <strong>boundary</strong> in this section could be<br />

established between samples 32 and 33.<br />

Acknowledgments<br />

This work was supported by CNCSIS <strong>–</strong>UEFISCSU,<br />

project number 382 PNII <strong>–</strong> IDEI 496/2007.<br />

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Melinte-Dobrinescu, M. & Brustur, T., 2008. Oligocene<strong>–</strong>Lower<br />

Miocene events in Romania. In: Tabără, D & Olaru, L.<br />

(eds), Acta Palaeontologica Romaniae, VI: 203-215.<br />

Perch-Nielsen, K., 1985. Cenozoic <strong>calcareous</strong> <strong>nannofossils</strong>. In:<br />

90


CALCAREOUS NANNOFOSSILS AT THE PALEOGENE <strong>–</strong> NEOGENE BOUNDARY IN BUCOVINA, ROMANIA<br />

H.M. Bolli, K. Perch-Nielsen & J.B. Saunders (eds.). Plankton<br />

str<strong>at</strong>igraphy. Cambridge University Press, Cambridge, 599 p.<br />

Săndulescu M., 1984, Geotectonica României. Ed. Tehnică,<br />

Bucureşti, 334 p.<br />

PLATE CAPTIONS<br />

PLATE I<br />

Calcareous <strong>nannofossils</strong> from Loba section.<br />

1. Helicosphaera ethologa BOWN, 2005<br />

2. Helicosphaera scissura MILLER, 1981<br />

3. Helicosphaera cf. ampliaperta BRAMLETTE & WILCOXON, 1967<br />

4a, 4b. Helicosphaera recta (HAQ, 1966) JAFAR & MARTINI, 1975<br />

5,6,7. Cyclicargolithus floridanus (ROTH et al., 1967) BUKRY, 1971<br />

8. Coccolithus pelagicus (WALLICH, 1877) SCHILLER, 1930<br />

9. Coccolithus eopelagicus (BRAMLETTE & RIEDEL, 1954) BRAMLETTE & SULLIVAN, 1961<br />

10. Reticulofenestra bisecta (HAY ET AL., 1966) ROTH, 1970<br />

11. Reticulofenestra lockeri MÜLLER, 1970<br />

12,13. Reticulofenestra minuta ROTH, 1970<br />

14. Reticulofenestra umbilica (LEVIN, 1965) MARTINI & RITZKOWSKI, 1968<br />

15. Reticulofenestra dictyoda (DEFLANDRE IN DEFLANDRE & FERT, 1954) STRADNER IN STRADNER & EDWARDS, 1968<br />

16. Sphenolithus spiniger BUKRY, 1971<br />

17,18,19. Sphenolithus conicus BUKRY, 1971<br />

20a,20b. Triquetrorhabdulus carin<strong>at</strong>us MARTINI, 1965<br />

21. Discoaster druggii BRAMLETTE & WILCOXON, 1967<br />

22. Discoaster sp.<br />

23. Coccosphere of Reticulofenestra sp.<br />

24. Ascidian spicules<br />

25,26,27,28. Calcispheres.<br />

91


CARMEN M. CHIRA, DORU T. JURAVLE, ALIN IGRIŢAN & MIRELA V. POPA<br />

PLATE I<br />

92

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