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Baymod A 52 e - LANXESS

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TITLE:<br />

<strong>Baymod</strong> ® A <strong>52</strong><br />

TEXT:<br />

<strong>Baymod</strong> ® A <strong>52</strong> is a highly effective modifier for<br />

improving the notched impact strength and<br />

processability of rigid PVC. If PVC modified with<br />

<strong>Baymod</strong> A <strong>52</strong> is used to produce thin-walled<br />

unpigmented articles, their transparency is<br />

similar to those modified with standard MBS.<br />

Used in combination with <strong>Baymod</strong> A 80 (bulk<br />

SAN), <strong>Baymod</strong> A <strong>52</strong> can also be used to modify<br />

halogen- and plasticiser-free semi-rigid<br />

thermoforming film. A typical field of application<br />

is decorative film for the lower part of vehicle<br />

interiors where it is less exposed to light and<br />

heat.<br />

Chemical composition<br />

Physical form<br />

Health and safety information<br />

acrylonitrile butadiene styrene grafted copolymer<br />

(ABS)<br />

white powder<br />

Relevant safety data and references as well as<br />

possible necessary warning labels are to be found<br />

in the safety data sheet.<br />

Product Properties<br />

Property Nominal Value Unit Test Method<br />

Density at 23 °C 0.98 g/cm 3 DIN 53 479<br />

Bulk density 280 g/l method based on<br />

DIN EN ISO 60<br />

Ignition residue<br />

(4 h at 600 °C)<br />

≤ 0.2 % method based on<br />

ISO 3451/1<br />

Volatiles ≤ 1.2 % method based on<br />

DIN/ISO 1269<br />

Technical Information<br />

2008-05-26, Page 1 of 4


Storage<br />

<strong>Baymod</strong> A <strong>52</strong> keeps for at least 2 years if<br />

stored in a cool, dry place and protected from<br />

light.<br />

Packaging<br />

Paper bag, capacity 15 kg<br />

Pallet size: 50 bags, 750 kg<br />

These raw material properties are typical properties and, unless specifically indicated<br />

otherwise, are not to be considered as delivery specification.<br />

1. Use of <strong>Baymod</strong> A <strong>52</strong> as an impact<br />

modifier in rigid PVC<br />

Processing and compound properties<br />

Blends of PVC and <strong>Baymod</strong> A <strong>52</strong> are prepared<br />

and processed by the usual methods employed<br />

for PVC. Processing aids are necessary, the<br />

usual combinations of stabilisers and lubricants<br />

being suitable.<br />

Notched impact strength (kJ/m 2 )<br />

acc. to DIN 53 453 (r=0.1 mm)<br />

80<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

+23°C<br />

+ 0°C<br />

- 20°C<br />

After compounding in a high-speed mixer, the<br />

dry blend can be processed straight away on<br />

suitable equipment, e.g. twin-screw extruders.<br />

For injection moulding and single-screw<br />

extrusion, however, the processing of granules<br />

has proved more suitable.<br />

Rigid PVC modified with <strong>Baymod</strong> A <strong>52</strong> is<br />

characterised by:<br />

- very high toughness even with small<br />

additions of modifier<br />

- improved melting characteristics<br />

- good surface finish<br />

- good transparency and thermoforming of<br />

film in comparison with standard MBS<br />

modifiers.<br />

Figures 1 and 2 show the mechanical<br />

properties of laboratory compounds comprising<br />

PVC and <strong>Baymod</strong> A <strong>52</strong>.<br />

10<br />

0<br />

2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27<br />

pbw <strong>Baymod</strong> A <strong>52</strong><br />

Fig. 1: Blends of PVC and <strong>Baymod</strong> A <strong>52</strong>,<br />

notched impact test according to DIN 53 453<br />

Notched impact strength (kJ/m 2 )<br />

acc. to ISO 179/1eA<br />

140<br />

130<br />

+ 23°C<br />

120<br />

110<br />

+ 0°C<br />

100<br />

90<br />

80<br />

-20°C<br />

70<br />

60<br />

50<br />

40<br />

30<br />

20<br />

10<br />

0<br />

2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26<br />

pbw <strong>Baymod</strong> A <strong>52</strong><br />

Fig. 2: Blends of PVC and <strong>Baymod</strong> A <strong>52</strong>,<br />

Charpy notched impact test according to ISO<br />

179/1eA<br />

Technical Information<br />

2008-05-26, Page 2 of 4


Formulation (Fig. 1 and 2) * ) :<br />

97 - 75 pbw S-PVC (k-value 68)<br />

3 - 25 pbw <strong>Baymod</strong> A <strong>52</strong><br />

1.0 pbw Irgastab ® T 22 M [1]<br />

0.2 pbw Loxiol ® G 70 [2]<br />

Processing:<br />

Mixing roll 10' 180 °C<br />

Press 10' 190 °C<br />

2. Use of <strong>Baymod</strong> A <strong>52</strong> in semi-rigid,<br />

halogen- and plasticiser-free film<br />

Processing and compound properties<br />

Blends of <strong>Baymod</strong> A <strong>52</strong> and <strong>Baymod</strong> 80, are<br />

prepared and processed by standard methods<br />

such as compounding in a plough-share mixer,<br />

melting and homogenisation, such as in a twinscrew<br />

extruder or compounder, and<br />

thermoforming on a calender.<br />

Usually, ABS film is imparted a surface decor<br />

with the aid of a hot embossing roller (at<br />

approx. 200 °C) and later processed into<br />

moulded parts (e.g. glove compartment covers,<br />

kneepads etc.) by thermoforming.<br />

Film based on <strong>Baymod</strong> A <strong>52</strong> is characterised<br />

by:<br />

- outstanding processability on the calender<br />

- good thermoforming properties<br />

- good grain stability<br />

- favourable price/performance ratio<br />

- very good recyclability of, for example,<br />

ABS moulded parts.<br />

Table 1: Blends with <strong>Baymod</strong> A <strong>52</strong><br />

Sample manufacture:<br />

Mixing roll: 180 °C, 5 min<br />

Press: 190 °C, 10 min<br />

Formulation * ) :<br />

0.3 pbw Loxiol ® G 70 [2]<br />

5.0 pbw PCL granules [3]<br />

plus<br />

*1<br />

pbw<br />

Tensile<br />

strength<br />

DIN 53 504<br />

MPa<br />

Elongation<br />

DIN 53 504<br />

%<br />

Tear<br />

strength<br />

DIN 53 515<br />

N/mm<br />

Shore<br />

hardness<br />

DIN 53 505<br />

D<br />

15"<br />

Vicat<br />

A 50<br />

DIN 53 460<br />

°C<br />

<strong>Baymod</strong> ® A <strong>52</strong> 100 11.6 228 27 28 50<br />

<strong>Baymod</strong> ® A <strong>52</strong><br />

<strong>Baymod</strong> ® A 80<br />

<strong>Baymod</strong> ® A <strong>52</strong><br />

<strong>Baymod</strong> ® A 80<br />

*2<br />

*2<br />

90<br />

10 14.4 224 46 40 61<br />

80<br />

20 17.0 210 65 48 75<br />

*1<br />

= polycaprolactone<br />

*2<br />

= SAN granules<br />

*<br />

Technical Information<br />

2008-05-26, Page 3 of 4


Registered Trademarks of Lanxess Deutschland GmbH:<br />

<strong>Baymod</strong><br />

List of Manufacturers:<br />

[1] Irgastab ® T 22 M made Witco Vinyl Additives<br />

GmbH, D-68607 Lampertheim<br />

[3] Capa ® 650 made by Interox Chem. Ltd.,<br />

Warrington, Great Britain<br />

[2] Loxiol ® G 70 made by Henkel KGaA,<br />

D-40191 Düsseldorf<br />

Ausgabe: 2008-05-26<br />

The above formulation is intended solely as a guide for our business partners and others interested in our products. As the conditions of use and application<br />

of the suggested formulation are beyond our control, it is imperative that it be tested to determine, to your satisfaction, whether it is suitable for your intended<br />

use(s) and application(s). This application-specific analysis at least must include testing to determine suitability from a technical, as well as health, safety and<br />

environmental standpoints. Further, although the ingredients, quantities thereof and properties of compounds or finished goods mentioned herein reflect our<br />

recommendation at the time of publication, this guide may not be subject to continuous review and/or updating, and you agree that use is undertaken at your<br />

sole risk. All information is given without warranty or guarantee, and it is expressly understood and agreed that you assume, and hereby expressly release us<br />

from, all liability, in tort, contract or otherwise, incurred in connection with the use of this guide.<br />

This information and our technical advice - whether verbal, in writing or by the way of trials - are given in good faith but without warranty, and this also applies<br />

where proprietary rights of third parties are involved. Our advice does not release you from the obligation to check its validity and to test our products as to<br />

their suitability for the intended processes and uses. The application, use and processing of our products manufactured by you on the basis of our technical<br />

advice are beyond our control and, therefore, entirely your own responsibility. Our products are sold in accordance with the current version of our General<br />

Conditions of Sale and Delivery.<br />

_________________________________________________________________________________________________________________________<br />

Lanxess, D-51369 Leverkusen<br />

Functional Chemicals Polymer Additives<br />

Technical Information<br />

2008-05-26, Page 4 of 4

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