Baymod A 52 e - LANXESS
Baymod A 52 e - LANXESS
Baymod A 52 e - LANXESS
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TITLE:<br />
<strong>Baymod</strong> ® A <strong>52</strong><br />
TEXT:<br />
<strong>Baymod</strong> ® A <strong>52</strong> is a highly effective modifier for<br />
improving the notched impact strength and<br />
processability of rigid PVC. If PVC modified with<br />
<strong>Baymod</strong> A <strong>52</strong> is used to produce thin-walled<br />
unpigmented articles, their transparency is<br />
similar to those modified with standard MBS.<br />
Used in combination with <strong>Baymod</strong> A 80 (bulk<br />
SAN), <strong>Baymod</strong> A <strong>52</strong> can also be used to modify<br />
halogen- and plasticiser-free semi-rigid<br />
thermoforming film. A typical field of application<br />
is decorative film for the lower part of vehicle<br />
interiors where it is less exposed to light and<br />
heat.<br />
Chemical composition<br />
Physical form<br />
Health and safety information<br />
acrylonitrile butadiene styrene grafted copolymer<br />
(ABS)<br />
white powder<br />
Relevant safety data and references as well as<br />
possible necessary warning labels are to be found<br />
in the safety data sheet.<br />
Product Properties<br />
Property Nominal Value Unit Test Method<br />
Density at 23 °C 0.98 g/cm 3 DIN 53 479<br />
Bulk density 280 g/l method based on<br />
DIN EN ISO 60<br />
Ignition residue<br />
(4 h at 600 °C)<br />
≤ 0.2 % method based on<br />
ISO 3451/1<br />
Volatiles ≤ 1.2 % method based on<br />
DIN/ISO 1269<br />
Technical Information<br />
2008-05-26, Page 1 of 4
Storage<br />
<strong>Baymod</strong> A <strong>52</strong> keeps for at least 2 years if<br />
stored in a cool, dry place and protected from<br />
light.<br />
Packaging<br />
Paper bag, capacity 15 kg<br />
Pallet size: 50 bags, 750 kg<br />
These raw material properties are typical properties and, unless specifically indicated<br />
otherwise, are not to be considered as delivery specification.<br />
1. Use of <strong>Baymod</strong> A <strong>52</strong> as an impact<br />
modifier in rigid PVC<br />
Processing and compound properties<br />
Blends of PVC and <strong>Baymod</strong> A <strong>52</strong> are prepared<br />
and processed by the usual methods employed<br />
for PVC. Processing aids are necessary, the<br />
usual combinations of stabilisers and lubricants<br />
being suitable.<br />
Notched impact strength (kJ/m 2 )<br />
acc. to DIN 53 453 (r=0.1 mm)<br />
80<br />
70<br />
60<br />
50<br />
40<br />
30<br />
20<br />
+23°C<br />
+ 0°C<br />
- 20°C<br />
After compounding in a high-speed mixer, the<br />
dry blend can be processed straight away on<br />
suitable equipment, e.g. twin-screw extruders.<br />
For injection moulding and single-screw<br />
extrusion, however, the processing of granules<br />
has proved more suitable.<br />
Rigid PVC modified with <strong>Baymod</strong> A <strong>52</strong> is<br />
characterised by:<br />
- very high toughness even with small<br />
additions of modifier<br />
- improved melting characteristics<br />
- good surface finish<br />
- good transparency and thermoforming of<br />
film in comparison with standard MBS<br />
modifiers.<br />
Figures 1 and 2 show the mechanical<br />
properties of laboratory compounds comprising<br />
PVC and <strong>Baymod</strong> A <strong>52</strong>.<br />
10<br />
0<br />
2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27<br />
pbw <strong>Baymod</strong> A <strong>52</strong><br />
Fig. 1: Blends of PVC and <strong>Baymod</strong> A <strong>52</strong>,<br />
notched impact test according to DIN 53 453<br />
Notched impact strength (kJ/m 2 )<br />
acc. to ISO 179/1eA<br />
140<br />
130<br />
+ 23°C<br />
120<br />
110<br />
+ 0°C<br />
100<br />
90<br />
80<br />
-20°C<br />
70<br />
60<br />
50<br />
40<br />
30<br />
20<br />
10<br />
0<br />
2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26<br />
pbw <strong>Baymod</strong> A <strong>52</strong><br />
Fig. 2: Blends of PVC and <strong>Baymod</strong> A <strong>52</strong>,<br />
Charpy notched impact test according to ISO<br />
179/1eA<br />
Technical Information<br />
2008-05-26, Page 2 of 4
Formulation (Fig. 1 and 2) * ) :<br />
97 - 75 pbw S-PVC (k-value 68)<br />
3 - 25 pbw <strong>Baymod</strong> A <strong>52</strong><br />
1.0 pbw Irgastab ® T 22 M [1]<br />
0.2 pbw Loxiol ® G 70 [2]<br />
Processing:<br />
Mixing roll 10' 180 °C<br />
Press 10' 190 °C<br />
2. Use of <strong>Baymod</strong> A <strong>52</strong> in semi-rigid,<br />
halogen- and plasticiser-free film<br />
Processing and compound properties<br />
Blends of <strong>Baymod</strong> A <strong>52</strong> and <strong>Baymod</strong> 80, are<br />
prepared and processed by standard methods<br />
such as compounding in a plough-share mixer,<br />
melting and homogenisation, such as in a twinscrew<br />
extruder or compounder, and<br />
thermoforming on a calender.<br />
Usually, ABS film is imparted a surface decor<br />
with the aid of a hot embossing roller (at<br />
approx. 200 °C) and later processed into<br />
moulded parts (e.g. glove compartment covers,<br />
kneepads etc.) by thermoforming.<br />
Film based on <strong>Baymod</strong> A <strong>52</strong> is characterised<br />
by:<br />
- outstanding processability on the calender<br />
- good thermoforming properties<br />
- good grain stability<br />
- favourable price/performance ratio<br />
- very good recyclability of, for example,<br />
ABS moulded parts.<br />
Table 1: Blends with <strong>Baymod</strong> A <strong>52</strong><br />
Sample manufacture:<br />
Mixing roll: 180 °C, 5 min<br />
Press: 190 °C, 10 min<br />
Formulation * ) :<br />
0.3 pbw Loxiol ® G 70 [2]<br />
5.0 pbw PCL granules [3]<br />
plus<br />
*1<br />
pbw<br />
Tensile<br />
strength<br />
DIN 53 504<br />
MPa<br />
Elongation<br />
DIN 53 504<br />
%<br />
Tear<br />
strength<br />
DIN 53 515<br />
N/mm<br />
Shore<br />
hardness<br />
DIN 53 505<br />
D<br />
15"<br />
Vicat<br />
A 50<br />
DIN 53 460<br />
°C<br />
<strong>Baymod</strong> ® A <strong>52</strong> 100 11.6 228 27 28 50<br />
<strong>Baymod</strong> ® A <strong>52</strong><br />
<strong>Baymod</strong> ® A 80<br />
<strong>Baymod</strong> ® A <strong>52</strong><br />
<strong>Baymod</strong> ® A 80<br />
*2<br />
*2<br />
90<br />
10 14.4 224 46 40 61<br />
80<br />
20 17.0 210 65 48 75<br />
*1<br />
= polycaprolactone<br />
*2<br />
= SAN granules<br />
*<br />
Technical Information<br />
2008-05-26, Page 3 of 4
Registered Trademarks of Lanxess Deutschland GmbH:<br />
<strong>Baymod</strong><br />
List of Manufacturers:<br />
[1] Irgastab ® T 22 M made Witco Vinyl Additives<br />
GmbH, D-68607 Lampertheim<br />
[3] Capa ® 650 made by Interox Chem. Ltd.,<br />
Warrington, Great Britain<br />
[2] Loxiol ® G 70 made by Henkel KGaA,<br />
D-40191 Düsseldorf<br />
Ausgabe: 2008-05-26<br />
The above formulation is intended solely as a guide for our business partners and others interested in our products. As the conditions of use and application<br />
of the suggested formulation are beyond our control, it is imperative that it be tested to determine, to your satisfaction, whether it is suitable for your intended<br />
use(s) and application(s). This application-specific analysis at least must include testing to determine suitability from a technical, as well as health, safety and<br />
environmental standpoints. Further, although the ingredients, quantities thereof and properties of compounds or finished goods mentioned herein reflect our<br />
recommendation at the time of publication, this guide may not be subject to continuous review and/or updating, and you agree that use is undertaken at your<br />
sole risk. All information is given without warranty or guarantee, and it is expressly understood and agreed that you assume, and hereby expressly release us<br />
from, all liability, in tort, contract or otherwise, incurred in connection with the use of this guide.<br />
This information and our technical advice - whether verbal, in writing or by the way of trials - are given in good faith but without warranty, and this also applies<br />
where proprietary rights of third parties are involved. Our advice does not release you from the obligation to check its validity and to test our products as to<br />
their suitability for the intended processes and uses. The application, use and processing of our products manufactured by you on the basis of our technical<br />
advice are beyond our control and, therefore, entirely your own responsibility. Our products are sold in accordance with the current version of our General<br />
Conditions of Sale and Delivery.<br />
_________________________________________________________________________________________________________________________<br />
Lanxess, D-51369 Leverkusen<br />
Functional Chemicals Polymer Additives<br />
Technical Information<br />
2008-05-26, Page 4 of 4