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Exergy saving and exergy production in municipal wastewater ...

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<strong>Exergy</strong> <strong>sav<strong>in</strong>g</strong> <strong>and</strong> <strong>exergy</strong> <strong>production</strong> <strong>in</strong> <strong>municipal</strong> <strong>wastewater</strong> treatment<br />

TABLE OF CONTENT<br />

Summary <strong>in</strong> Swedish<br />

iii<br />

acknowledgements<br />

v<br />

abstract 1<br />

1. Introduction 1<br />

1.1. Energy enter<strong>in</strong>g the plant 1<br />

1.2. Energy consumed <strong>in</strong> the plant 2<br />

1.3. Parameters affect<strong>in</strong>g the energy ga<strong>in</strong> from the plant 3<br />

1.4. Anaerobic digestion 4<br />

1.5. Laws of thermodynamics 5<br />

1.6. Thermodynamic view of the treatment plant 7<br />

1.7. Thermodynamic <strong>in</strong>dicators 8<br />

1.8. Emergy 8<br />

1.9. Entropy 9<br />

1.10. <strong>Exergy</strong> 9<br />

1.11. Def<strong>in</strong>ition <strong>in</strong> natural science 10<br />

1.12. Def<strong>in</strong>ition <strong>in</strong> thermodynamic 11<br />

1.13. Def<strong>in</strong>ition <strong>in</strong> ecological system 12<br />

1.14. Forth law of thermodynamics 14<br />

1.15. Calorimetry 14<br />

1.16. Bomb calorimeter 15<br />

1.17. Relation between growth yield <strong>and</strong> energy available 16<br />

1.18. Application of thermodynamic orientors 17<br />

1.19. Thermodynamic of growth 17<br />

1.20. <strong>Exergy</strong> calculation for a treatment plant us<strong>in</strong>g environmental data based<br />

on COD measurements 20<br />

1.21. COD removal <strong>in</strong> anoxic processes 22<br />

1.22. Nitrogen as nitrate <strong>in</strong> the sludge phase 22<br />

1.23. Nitrogen removed as gas (no COD consumption) 23<br />

1.24. <strong>Exergy</strong> calculation for a treatment plant us<strong>in</strong>g environmental data based<br />

on BOD measurements 23<br />

1.25. Microbial Fuel Cell 24<br />

1.26. How to measure the amount of electricity be<strong>in</strong>g produced 25<br />

1.27. Electron transfer process 26<br />

1.28. Mediators 26<br />

1.29. Suitable mediators 27<br />

1.30. Activation polarization 27<br />

1.31. Geobactersulfurreducens 27<br />

1.32. Measur<strong>in</strong>g MFC efficiency 27<br />

1.33. Columbic efficiency 28<br />

1.34. MFC application 29<br />

1.35. MFC for electricity <strong>production</strong> 31<br />

1.36. Benchmark<strong>in</strong>g 32<br />

2. Material <strong>and</strong> methods 32<br />

2.1. COD measurements of food products 35<br />

vii

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