Brochure Alipre - Italcementi Group
Brochure Alipre - Italcementi Group
Brochure Alipre - Italcementi Group
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<strong>Italcementi</strong> <strong>Group</strong><br />
ALIPRE ®<br />
Calcium Sulfoaluminates
Innovation and Environment<br />
Introduction<br />
ALIPRE ® is <strong>Italcementi</strong> brand for its Calcium Sulfoaluminate clinker (CSA) based<br />
binders, to be used in high performance cement systems. It is available as straight<br />
CSA, namely ALIPRE ® , or blended with high quality Anhydrite, that is ALIPRE ®<br />
CEMENT. The former is delivered in bulk or one ton big bags, whereas the latter<br />
in bulk, one ton big bags or 25 kg bags, according to local availability.<br />
Depending on the technical requirements and the applications of the final products,<br />
ALIPRE ® can be used as main component or as secondary constituent to adjust<br />
workability time, setting time and mechanical strength and achieve special products<br />
performances such as rapid setting, high early strength, increased sulfate resistance<br />
and shrinkage compensation.<br />
Sustainable Development<br />
ALIPRE ® is the result of advanced research combined with the latest state of the<br />
art production processes as well as a sophisticated quality control system,<br />
representing an example of a highly technical product, which has a minor impact<br />
on the environment. Its production cycle has levels of CO 2<br />
emission, fuel and<br />
electricity consumption for the burning and grinding phases lower than those<br />
required for the production of ordinary Portland clinker.<br />
Society<br />
LOW CO 2<br />
EMISSIONS<br />
Economy<br />
Environment<br />
In recognition of its longstanding commitment to sustainability, <strong>Italcementi</strong><br />
has been admitted to the Dow Jones Sustainability World Index, tracking the<br />
performance of the leading sustainability-driven companies worldwide out of<br />
the 2,500 international Companies in the Dow Jones Global indexes.<br />
The evaluation is carried out on the basis of economic, environmental, and<br />
social criteria. Of the Italian Companies listed in this prestigious sustainability<br />
rating, <strong>Italcementi</strong> is currently the only construction Company.<br />
For more information, please visit the www.italcementigroup.com website.
®<br />
ALIPRE<br />
ALIPRE ® is a ground sulfoaluminate-belite clinker, which main phases are: Calcium Sulfoaluminate, Belite and<br />
Calcium Sulfate.<br />
Mineralogical Composition<br />
C 4<br />
A 3<br />
S – C 2<br />
S CS<br />
ALIPRE 60 18 9<br />
It is usually used in ternary mixtures with calcium sulfate and Portland cement in order to obtain:<br />
• Varied Setting Time within a wide time range by changing the mix proportions of the three components<br />
• Rapid Early Strength Development<br />
• Progressive Strength Increase, exceeding top-performing Portland cements<br />
The Hydration Process<br />
ALIPRE ® composition enables the development of an hydration process, that differs substantially from the one<br />
of ordinary Portland cements, being characterized by the formation of regular and compact primary ettringite,<br />
which affects the subsequent hardening process.<br />
In ALIPRE ® based ternary systems, the main reaction of ettringite formation is the following<br />
Where:<br />
C 4<br />
A 3<br />
S – + 8CS – H 2<br />
+ 6CH + 74H → 3C 6<br />
AS – 3 H 32<br />
C 4<br />
A 3<br />
S – - Calcium Sulfoaluminate<br />
It is ALIPRE ® basic component and promotes early strength development (thanks to primary ettringite formation).<br />
CS – H n<br />
- Calcium Sulfate<br />
(n=0 anhydrite, n=1/2 hemihydrate, n=2 dihydrate or gypsum)<br />
It causes ettringite to form from C 4<br />
A 3<br />
S – during the hydration phase (generally n=0 anhydrite)<br />
CH - Calcium Hydroxide<br />
It results from the hydration of Portland cement, and at later ages from the hydration of ALIPRE ® belitic phase.<br />
C 2<br />
S - Belite<br />
It is responsible for strength development at later ages.<br />
Chemical Main Components<br />
CaO SiO 2<br />
Al 2<br />
O 3<br />
Fe 2<br />
O 3<br />
SO 3<br />
ALIPRE 39 ÷ 43 ≤ 7.5 31 ÷ 43 ≤ 1.5 12.5 ÷ 17.5<br />
Fineness<br />
Specific Surface (Blaine) 4,500 (±250) cm 2 /g
ALIPRE<br />
®<br />
C E M E N T<br />
ALIPRE ® CEMENT is a blend of ALIPRE ® and high quality Anhydrite<br />
Physical Properties<br />
Soundness:<br />
0 mm<br />
Setting Time<br />
Initial (min) Final (min)<br />
25 ± 10 50 ± 20<br />
The test to measure the initial and final setting time has been carried out according to standard EN 196-3, but<br />
with a different w/c ratio (w/c = 0.35).<br />
Mechanical Properties<br />
The strength development, which is rapid at early ages, progresses across time following the same trend as in<br />
conventional Portland cements.<br />
70<br />
Compressive strenght [MPa]<br />
60<br />
50<br />
40<br />
30<br />
20<br />
10<br />
0<br />
8h 1d 2d 7d 28d<br />
The strength test has been carried out on standard mortars according to standard EN 196-1.<br />
Use with Admixtures<br />
The addition of admixtures does not adversely affect ALIPRE ® :<br />
Test carried out with ALIPRE ® and commonly used admixtures, e.g. retarders, set/hardening accelerators,<br />
water-retaining agents, superplasticizers, etc., showed no detrimental effects, with all test parameters<br />
successfully met.<br />
Fineness<br />
Specific Surface (Blaine) 4,500 (±250) cm 2 /g
Versatility<br />
Cement based Binders for Specific Products and Applications<br />
Products<br />
ALIPRE ® is a highly versatile and practical product for the building material industry in terms of setting time<br />
and strength development and can be used to formulate specific products according to the type of applications<br />
required, with ordinary Portland cement and admixtures.<br />
Various tested formulations were defined for the sole purpose of assessing ALIPRE ® potential applications.<br />
Setting time and hardening time can be easily adjusted by varying mix design parameters.<br />
Applications<br />
Growing demand for fast setting, high early strength and shrinkage compensating products for specific<br />
applications requires increasingly complex formulations.<br />
ALIPRE ® is the ideal constituent in the preparation of such formulations for:<br />
• Tile Adhesives and Grouts<br />
• Repair Concretes (i.e. bridges, airport runaways and parking apron, etc.)<br />
• Technical Rapid-Setting Mortars (e.g. for restoration and repairs, etc.)<br />
• Self-Levelling Floor Screeds<br />
• Sprayed Concretes and Shotcretes<br />
• Mining Products<br />
• Waste Encapsulation<br />
• Plasters & Mortars (i.e. Joints, Sulfate Resistance, No-Shrinkage, etc.)<br />
• Rapid or semi-rapid sealants<br />
• Special adhesives<br />
• Precast (1)<br />
Physical & Mechanical Properties<br />
• Highly adjustable setting times<br />
• High early strength, gradually increasing over time<br />
• Light in Color, highly suitable for both light and pigmented formulations.<br />
Durability Properties<br />
• High Sulfate Resistance<br />
• Dimensional Stability<br />
• Low Shrinkage Effect<br />
(1)<br />
The possibility of using ALIPRE ® in structural precast has to be evaluated by taking into account local legislation.
www.italcementigroup.com<br />
I-MKTG@itcgr.net<br />
Note: The indications and information about our products characteristics, even if they reflects the latest product tests and technological, cannot be considered as warranty on the final<br />
result of the works using the products themselves. Therefore, it is up to the user to verify, by taking the consequent exclusive responsibility, the compatibility of the ordered products<br />
with their foreseen usage, their correct placing and curing in order not to affect negatively their performance.<br />
ALIPRE-Eng.ww-Mar.09