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Nomenclature and Chemical Reactions - Oakland Schools

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Oakl<strong>and</strong> <strong>Schools</strong> Chemistry Resource Unit<br />

<strong>Nomenclature</strong> &<br />

<strong>Chemical</strong> <strong>Reactions</strong><br />

Lynn Hensley<br />

South Lyon High School<br />

South Lyon Community <strong>Schools</strong><br />

1


Content Statements:<br />

C4.2 <strong>Nomenclature</strong><br />

<strong>Nomenclature</strong> <strong>and</strong> <strong>Chemical</strong> <strong>Reactions</strong><br />

All compounds have unique names that are determined systematically<br />

C4.2x <strong>Nomenclature</strong><br />

All molecular <strong>and</strong> ionic compounds have unique names that are determined<br />

systematically.<br />

C3.4 Endothermic <strong>and</strong> Exothermic <strong>Reactions</strong><br />

<strong>Chemical</strong> interactions either release energy to the environment (exothermic) or absorb<br />

energy from the environment (endothermic).<br />

C5.2 <strong>Chemical</strong> Changes<br />

<strong>Chemical</strong> changes can occur when two substances, elements, or compounds interact<br />

<strong>and</strong> produce one or more different substances whose physical <strong>and</strong> chemical properties<br />

are different from the interacting substances. When substances undergo chemical<br />

change, the number of atoms in the reactants is the same as the number of atoms in<br />

the products. This can be shown through simple balancing of chemical equations. Mass<br />

is conserved when substances undergo chemical change. The total mass of the<br />

interacting substances (reactants) is the same as the total mass of the substances<br />

produced (products).<br />

C5.5 <strong>Chemical</strong> Bonds-Trends<br />

An atom’s electron configuration, particularly of the outermost electrons, determines<br />

how the atom can interact with other atoms. The interactions between atoms that hold<br />

them together in molecules or between oppositely charged ions are called chemical<br />

bonds.<br />

C5.6x Reduction/Oxidation <strong>Reactions</strong><br />

<strong>Chemical</strong> reactions are classified according to the fundamental molecular or sub<br />

molecular changes that occur. <strong>Reactions</strong> that involve electron transfer are known as<br />

oxidation/reduction (or “redox”).<br />

2


Content Expectations:<br />

C4.2A - Name simple binary compounds using their formulae.<br />

C4.2B - Given the name, write the formula of simple binary compounds.<br />

C4.2c - Given a formula, name the compound.<br />

C4.2d - Given the name, write the formula of ionic <strong>and</strong> molecular compounds.<br />

C3.4A - Use the terms endothermic <strong>and</strong> exothermic correctly to describe chemical<br />

reactions in the laboratory.<br />

C5.2A - Balance simple chemical equations applying the conservation of matter.<br />

C5.5B - Predict the formula for binary compounds of main group elements.<br />

C5.6b - Predict single replacement reactions.<br />

3


Instructional Background Information:<br />

<strong>Nomenclature</strong>/<strong>Chemical</strong> Bonds:<br />

<strong>Nomenclature</strong> involves the naming <strong>and</strong> formula writing for molecular <strong>and</strong> ionic<br />

compounds. Molecular compounds are limited to two nonmetals using the first 20<br />

elements. Ionic compounds are limited to the first 20 elements plus copper, iron, lead,<br />

<strong>and</strong> mercury <strong>and</strong> common ions. Common ions are limited to: acetate, hydroxide,<br />

sulfate, sulfite, nitrate, nitrite, carbonate, <strong>and</strong> ammonium. See examples below:<br />

Ionic Compounds<br />

Type 1<br />

Name the metal, then name the nonmetal-but change ending to ide<br />

Ex. NaCl<br />

AlF 3<br />

sodium chloride<br />

aluminum fluoride<br />

Type 2<br />

Name the metal, <strong>and</strong> then name the polyatomic ion<br />

Ex. NaNO 3 sodium nitrate<br />

Li 3 (PO 4 ) lithium phosphate<br />

Type 3<br />

Transition metals must include charge as a Roman numeral. This is the stock<br />

system.<br />

Ex. Fe 2 O 3<br />

CuCl<br />

CuCl 2<br />

iron (III) oxide<br />

copper (I) chloride<br />

copper (II) chloride<br />

4


Binary Molecular Compounds<br />

Usually consists of 2 nonmetals. Names use prefixes to indicate subscripts.<br />

Names still use –ide endings<br />

1=mono 2=di 3=tri 4=tetra 5=penta etc.<br />

Ex. CO<br />

N 2 O 4<br />

PCl 3<br />

SCl 6<br />

N 2 O 3<br />

carbon monoxide<br />

dinitrogen tetraoxide<br />

phosphorus trichloride<br />

sulfur hexachloride<br />

dinitrogen trioxide<br />

Writing Formulas – Ionic Compounds<br />

Steps:<br />

1) Write symbols for each ion.<br />

2) Determine charge of each ion.<br />

3) Add more of either ion, as needed in order to get a neutral charge on the<br />

compound.<br />

4) Put parentheses around polyatomic ions.<br />

5) Subscripts indicate the number of each ion used.<br />

EX: calcium iodide<br />

Ca I Ca +2 I -1 CaI 2<br />

EX: aluminum sulfate<br />

Al SO 4 Al +3 SO 4<br />

-2<br />

Al 2 (SO 4 ) 3<br />

Endothermic <strong>and</strong> Exothermic <strong>Reactions</strong>:<br />

Use the terms endothermic <strong>and</strong> exothermic to describe chemical reactions in which heat<br />

is transferred between the system <strong>and</strong> surroundings. Possible demos/reactions include<br />

zinc or magnesium with hydrochloric acid or steel wool with vinegar for exothermic.<br />

Endothermic reactions would be vinegar with baking soda or ammonium chloride with<br />

barium hydroxide.<br />

<strong>Reactions</strong> either release or absorb energy based on the net energy change of the<br />

bonds.<br />

5


<strong>Chemical</strong> Changes:<br />

Balance chemical equations using coefficients to obey the law of conservation of matter.<br />

Teacher tip: Use the acronym MINOH for ordering of balancing. Order: Metals,<br />

polyatomic Ions, Nonmetals, Oxygen, Hydrogen. Draw representations of chemical<br />

equations using shapes to map out the reactants <strong>and</strong> products.<br />

EX: 2 H 2 + O 2 2 H 2 O<br />

□□ + □□ + ●● □●□ + □●□<br />

Reduction/Oxidation <strong>Reactions</strong>:<br />

These reactions involve the transfer of electrons between two elements. Single<br />

replacement reactions are prime examples of these. The use or development of an<br />

activity series to predict which reactions actually occur is necessary. Keep in mind that<br />

metals replace metals <strong>and</strong> nonmetals replace nonmetals. The element higher on the<br />

activity series can replace any element under it. Teacher tip: You can use the analogy<br />

that ionic compounds have to be a “boy” <strong>and</strong> a “girl”. This is why a metal replaces a<br />

metal or a nonmetal replaces a nonmetal.<br />

Examples:<br />

Zn + CuCl 2 Cu + ZnCl 2 zinc replaces Cu because Zn is higher on the activity series<br />

F 2 + 2 NaCl 2 NaF + Cl 2 fluorine replaces Cl because F is higher than Cl<br />

Cu + LiF no reaction because Cu is lower than Li on the activity series<br />

6


Terms <strong>and</strong> Concepts:<br />

Binary compound Ionic compound Molecular compound<br />

Polyatomic ions Naming compounds Writing chemical formulas<br />

Reactants Products Yields<br />

Single replacement Oxidation numbers Double replacement<br />

Endothermic Exothermic Activity series<br />

<strong>Chemical</strong> reactions Word equations Law of conservation of<br />

matter<br />

Instructional Resources<br />

www.pogil.org Inquiry based activities - You will need to sign up for a password.<br />

Go to the curriculum materials tab, select downloadable activities, go to bottom of page<br />

<strong>and</strong> click on selected activities<br />

www.ChemistryInquiry.com Inquiry based activities, sample ones can be printed or<br />

entire collection can be ordered.<br />

www.Flinnsci.com - Great source for MSDS sheets <strong>and</strong> safety information, along with<br />

links to other teacher resources.<br />

7


<strong>Nomenclature</strong> <strong>and</strong> <strong>Chemical</strong> <strong>Reactions</strong><br />

Activity #1 – Balancing Equations with Manipulatives.<br />

Questions to be investigated<br />

Objectives<br />

How do I balance equations?<br />

The student will be able to balance equations using coefficients <strong>and</strong> following the<br />

law of conservation of matter.<br />

Teacher Notes<br />

Materials<br />

Sources<br />

The teacher will need to print copies of the “cards” to have enough for each<br />

group of students (extra hint – laminate the cards). Groups of 2 are<br />

recommended.<br />

Worksheet for each student <strong>and</strong> a set of cards for each student.<br />

www.middleschoolscience.com<br />

Procedure/Description of Lesson<br />

Students will use cards with symbols of elements <strong>and</strong> compounds <strong>and</strong><br />

coefficients to learn how to balance equations <strong>and</strong> apply the law of conservation<br />

of matter. The cards can be made by h<strong>and</strong> as explained below or cards can be<br />

printed on a color printer from the website. Student <strong>and</strong> teacher h<strong>and</strong>outs are<br />

following.<br />

8


Balancing <strong>Chemical</strong> Equations Activity<br />

Objectives:<br />

by Liz LaRosa<br />

www.middleschoolscience.com<br />

• to read chemical equations<br />

• to identify elements by their chemical symbol<br />

• to count atoms<br />

• to identify the coefficients <strong>and</strong> subscripts in a chemical equation.<br />

• to label the reactants <strong>and</strong> products of a chemical equation<br />

• to balance chemical equations<br />

Materials: These account for one complete set. Color scheme is VERY important<br />

for visualization during the activity.<br />

on 3x5 Index<br />

Cards<br />

2 orange 6's<br />

4 red 2's 2 black 7's<br />

1 red<br />

"Reactants"<br />

on 5x8 Index<br />

Cards<br />

CO 2 Fe N 2 Na 2 SO 4<br />

CH 4 Fe 3 O 4 NH 3 O 2<br />

4 blue 3's 2 blue "+" Al C 2 H 6 H 2 Na P 4<br />

4 green 4's<br />

2 purple 5's<br />

1 black<br />

"yield" sign<br />

---><br />

1 purple<br />

"Products"<br />

Al 2 O 3 CaCl 2 H 2 O NaCl P 4 O 10<br />

C CaSO 4 H 2 O 2 Na 2 O<br />

9


Pre Lab Questions:<br />

Answer the following before you begin the activity:<br />

5H 2<br />

1. What number represents the Coefficient?<br />

_____<br />

2. What number represents the Subscript?<br />

_____<br />

3. What element is represented by the letter "H"?<br />

_____<br />

4. How many "H's" do you have? _____<br />

Procedure:<br />

1. Using your set of index cards, replicate the chemical equation onto your desk.<br />

2. Label the reactant side <strong>and</strong> the product side.<br />

Record the following information into Table 1:<br />

3. Identify the elements on the reactant side.<br />

4. Count the number of atoms for each element.<br />

5. Identify the elements on the product side.<br />

6. Count the number of atoms on the product side.<br />

7. Are the 2 sides equal? If not, the equation is not balanced.<br />

8. The index cards numbered 2 - 7 are your coefficients. They can ONLY be<br />

placed in front of the elements. You can not change the subscripts.<br />

9. Choose an element that is not balanced <strong>and</strong> begin to balance the equations.<br />

10. Continue until you have worked through all the elements.<br />

11. Once they are balance, count the final number of Reactants <strong>and</strong> Products.<br />

12. Write the balanced equation.<br />

13. Can your equation be simplified?<br />

10


Data:<br />

Table 1: <strong>Chemical</strong> Equations (whole page, large boxes, sideways into lab book)<br />

Make the following<br />

Equations on your<br />

desk<br />

H 2 + O 2 --> H 2 O<br />

H 2 O 2 --> H 2 0 + O 2<br />

Na + O 2 --> Na 2 O<br />

N 2 + H 2 --> NH 3<br />

P 4 + O 2 --> P 4 O 10<br />

Fe + H 2 O --> Fe 3 O 4<br />

+ H 2<br />

C + H 2 --> CH 4<br />

Na 2 SO 4 + CaCl 2 --><br />

CaSO 4 + NaCl<br />

C 2 H 6 + O 2 --> CO 2 +<br />

H 2 O<br />

Al 2 O 3 --> Al + O 2<br />

Reactants Products Reactants<br />

- Final<br />

Products<br />

- Final<br />

Balanced<br />

Equation<br />

Analysis/Results:<br />

1. What does "-->" mean?<br />

2. What side of the equation are the reactants found? products?<br />

3. Why must all chemical equations be balanced?<br />

4. Why can't the subscripts be changed?<br />

5. What does it mean to "simplify" the equation?<br />

Conclusion:<br />

2-3 sentences on what you learned.<br />

11


TEACHER NOTES:<br />

The index cards are a bit time consuming to create. I had some students help at lunch<br />

time for a few days. Once done, you can laminate them <strong>and</strong> have them forever! The<br />

materials account for one complete set which is good for 2-3 students to use.<br />

Print activity cards on card stock instead of making index cards for quicker set up.<br />

The color coding is very important for visualization. It is easier <strong>and</strong> quicker to locate<br />

the elements that you are trying to balance. If everything is in black ink, it’s harder to<br />

distinguish the equation contents.<br />

© Copyright 2000, E. S. Belasic<br />

12


Balancing Equations Lab: TEACHER ANSWER KEY<br />

Table 1: <strong>Chemical</strong> Equations<br />

Make the following<br />

Equations on your desk Reactants Products Reactants -<br />

Final<br />

H 2 + O 2 --> H 2 O<br />

H 2 O 2 --> H 2 0 + O 2<br />

Na + O 2 --> Na 2 O<br />

N 2 + H 2 --> NH 3<br />

P 4 + O 2 --> P 4 O 10<br />

Fe + H 2 O --> Fe 3 O 4 +<br />

H 2<br />

C + H 2 --> CH 4<br />

2<br />

hydrogen<br />

2 oxygen<br />

2 hydrogen<br />

2 oxygen<br />

1 sodium<br />

2 oxygen<br />

2 nitrogen<br />

2 hydrogen<br />

4<br />

phosphorus<br />

2 oxygen<br />

1 iron<br />

2 hydrogen<br />

1 oxygen<br />

1 carbon<br />

2 hydrogen<br />

2sodium<br />

2<br />

hydrogen<br />

1 oxygen<br />

2<br />

hydrogen<br />

3 oxygen<br />

2 sodium<br />

1 oxygen<br />

1 nitrogen<br />

3 hydrogen<br />

4<br />

phosphorus<br />

10 oxygen<br />

3 iron<br />

2<br />

hydrogen<br />

4 oxygen<br />

1 carbon<br />

4 hydrogen<br />

1 sodium<br />

4<br />

hydrogen<br />

2 oxygen<br />

4<br />

hydrogen<br />

4 oxygen<br />

4 sodium<br />

2 oxygen<br />

2 nitrogen<br />

6<br />

hydrogen<br />

4<br />

phosphorus<br />

10 oxygen<br />

3 iron<br />

8 hydrogen<br />

4 oxygen<br />

1 carbon<br />

4<br />

hydrogen<br />

2 sodium<br />

Products<br />

- Final<br />

same as<br />

final<br />

reactants<br />

same as<br />

final<br />

reactants<br />

same as<br />

final<br />

reactants<br />

same as<br />

final<br />

reactants<br />

same as<br />

final<br />

reactants<br />

same as<br />

final<br />

reactants<br />

same as<br />

final<br />

reactants<br />

Balanced<br />

Equation<br />

2 H 2 + O 2 --><br />

2 H 2 O<br />

2 H 2 O 2 --><br />

2 H 2 0 + O 2<br />

4Na + O 2 --><br />

2 Na 2 O<br />

N 2 + 3H 2 --><br />

2 NH 3<br />

P 4 + 5O 2 --><br />

P 4 O 10<br />

3Fe + 4H 2 O -<br />

-> Fe 3 O 4 +<br />

4H 2<br />

C + 2 H 2 --><br />

CH 4<br />

Na 2 SO 4 + CaCl 2 --><br />

CaSO 4 + NaCl<br />

1 sulfur<br />

4 oxygen<br />

1 calcium<br />

1 sulfur<br />

4 oxygen<br />

1 calcium<br />

1 sulfur<br />

4 oxygen<br />

1 calcium<br />

same as<br />

final<br />

reactants<br />

Na 2 SO 4 +<br />

CaCl 2 --><br />

CaSO 4 +<br />

2 NaCl<br />

13


2 chlorine 1 chlorine 2 chlorine<br />

C 2 H 6 + O 2 --> CO 2 +<br />

H 2 O<br />

2 carbon<br />

6 hydrogen<br />

2 oxygen<br />

1 carbon<br />

2 hydrogen<br />

3 oxygen<br />

4 carbon<br />

12<br />

hydrogen<br />

14 oxygen<br />

same as<br />

final<br />

reactants<br />

2 C 2 H 6 + 7O 2<br />

--> 4CO 2 +<br />

6H 2 O<br />

Al 2 O 3 --> Al + O 2<br />

2<br />

aluminum<br />

3 oxygen<br />

1<br />

aluminum<br />

2 oxygen<br />

4<br />

aluminum<br />

6 oxygen<br />

same as<br />

final<br />

reactants<br />

2 Al 2 O 3 --><br />

4Al + 3O 2<br />

Assessment Ideas<br />

Give students a quiz on the parts of an equation <strong>and</strong> a quiz on balancing<br />

equations before moving on. Summative assessment would be balancing<br />

equations <strong>and</strong> answering questions on a unit test.<br />

14


<strong>Nomenclature</strong> <strong>and</strong> <strong>Chemical</strong> <strong>Reactions</strong><br />

Activity #2 – Creating Ionic Compounds<br />

Questions to be investigated<br />

Objectives<br />

How do I name ionic compounds <strong>and</strong> write correct chemical formulas?<br />

The student will be able to name ionic compounds <strong>and</strong> write correct chemical<br />

formulas by building compounds from cards.<br />

Teacher Notes<br />

Materials<br />

Teacher will need to make a set of cards for each group of students. Laminating<br />

<strong>and</strong> storing cards in Ziploc bags is suggested.<br />

Worksheet per student <strong>and</strong> one set of cards per group of 2 students.<br />

Real-World Connections<br />

Sources<br />

By knowing how to read, name <strong>and</strong> write chemical compounds, students will be<br />

able to read labels on food item, cleaning products, health <strong>and</strong> beauty products,<br />

etc.<br />

ESC Region XIII<br />

http://www.5.esc13.net/science/docs/ion%20ionic%20manipulatives.pdf<br />

http://www.esc13.net/science/docs/creating%20ionic%20compounds.pdf<br />

Procedure/Description of Lesson<br />

Students will use cards to building molecules <strong>and</strong> from that determine the correct<br />

chemical formula, then name the compound. See next page for student<br />

h<strong>and</strong>out.<br />

15


Assessment Ideas<br />

Lab Activity – Ionic Compounds <strong>and</strong> <strong>Nomenclature</strong><br />

Teacher sets up clear vials with tops with a few grams of solid. The vial is<br />

labeled EITHER with the name OR the formula. The students are to determine<br />

the missing piece. Teachers can set up as many or as few sets as they wish <strong>and</strong><br />

choose which ever compounds they have available. Suggestion: use a variety of<br />

colored compounds <strong>and</strong> compounds with different crystal size. If you are<br />

worried about students opening the vials, then place 2 or 3 in a Ziploc bag.<br />

See attached worksheet.<br />

Game – Salty Eights<br />

A card game by Key Curriculum Press (www.keypress.com) from their Living by<br />

Chemistry program, Unit 1: Alchemy. The idea behind the game is for students<br />

to make compounds from the cards which have a variety of elements with their<br />

valence states. Points are awarded based on the complexity of the molecule.<br />

21


Ionic Compounds <strong>and</strong> <strong>Nomenclature</strong><br />

Activity<br />

Name_____________<br />

Date______Hour____<br />

There are 5 sets of vials. Each vial contains a different ionic compound. The vial either<br />

has the name, or the formula, but not both.<br />

You need to complete the data chart. You may use a periodic table.<br />

Name Formula Color Description<br />

Set #1<br />

Set #2<br />

Set #3<br />

Set #4<br />

Set #5<br />

22


<strong>Nomenclature</strong> <strong>and</strong> <strong>Chemical</strong> <strong>Reactions</strong><br />

Activity #3 – <strong>Chemical</strong> Reaction Equations<br />

Questions to be investigated<br />

Objectives<br />

How do I balance equations <strong>and</strong> use the coefficients to do mole ratios?<br />

The student will learn how to balance equations <strong>and</strong> draw reactions <strong>and</strong> then<br />

apply the coefficients to mole ratios.<br />

Teacher Notes<br />

Materials<br />

Teacher may want to have magnets or bingo chips of different colors/shapes to<br />

use on the board to show balancing <strong>and</strong> rearranging of atoms <strong>and</strong> to help<br />

modeling the drawing of reactions.<br />

Worksheets<br />

Real World Connections<br />

Sources<br />

Can discuss how industrial processes <strong>and</strong> the manufacture of pharmaceuticals<br />

rely on ratios <strong>and</strong> balanced equations to acquire the desired amounts.<br />

www.pogil.org<br />

Go to curriculum materials <strong>and</strong> click on downloadable items, then go towards<br />

bottom of page <strong>and</strong> click on collected activities, you will need to sign up for a<br />

password, activities are useable for one year from time of download<br />

Procedure/Description of Lesson<br />

Students will write their own definitions, analyze a balanced equation <strong>and</strong> draw a<br />

diagram of it, then use the mole ratios to solve mole-mole or mole-mass problems.<br />

Student h<strong>and</strong>out is on next page.<br />

23


Assessment Ideas<br />

Give students a set of blocks or colored bingo chips <strong>and</strong> ask them to a balance<br />

an equation by diagram. Then using simple numbers for mental math have them<br />

do mole-mole <strong>and</strong> mass-mass problems (formative).<br />

Give students a worksheet with practice problems (formative).<br />

Variety of test questions, multiple choice <strong>and</strong> working out (summative).<br />

28


<strong>Nomenclature</strong> <strong>and</strong> <strong>Chemical</strong> <strong>Reactions</strong><br />

Activity #4 – <strong>Chemical</strong> <strong>Reactions</strong> Lab<br />

Questions to be investigated<br />

Objectives<br />

How do I predict the products of a reaction?<br />

The student will observe <strong>and</strong> perform several chemical reactions. They will be<br />

able to predict the products, balance the equations, <strong>and</strong> in some cases decide if<br />

the reaction was endothermic or exothermic. C3.4A, C3.4B, C5.2A, C5.6b<br />

Teacher Notes<br />

The reactions in this lab could be done via demonstration if lab facilities or<br />

quantity of materials are an issue. If done via demonstration then students<br />

should write down what the instructor is doing <strong>and</strong> some observations. If no<br />

fume hood is available, omit station 7.<br />

Materials<br />

Magnesium ribbon<br />

Bunsen burner<br />

Silver nitrate solution (0.1M)<br />

Sodium chloride solution (0.1M)<br />

Zinc metal<br />

Hydrochloric acid (1.0 M)<br />

Copper (II) sulfate solution (0.1M)<br />

Barium chloride solution (0.1M)<br />

Sodium sulfate solution (0.1M)<br />

Hydrogen peroxide (3%)<br />

Manganese (IV) oxide<br />

Sulfur<br />

Copper (II) sulfate hydrate<br />

Matches<br />

Alcohol burner with ethanol or methanol<br />

29


Safety Concerns<br />

Students must wear goggles <strong>and</strong> aprons at all times.<br />

Station 1: DO NOT look directly at the burning magnesium – it can damage your<br />

eyes<br />

Station 2: Silver nitrate can stain skin <strong>and</strong> clothing.<br />

Station 3: Hydrochloric acid is corrosive to skin, use caution. Have baking soda<br />

available to neutralize spills.<br />

Station 4: Copper (II) sulfate is a skin irritant.<br />

Station 5: None, but see disposal note.<br />

Station 6: Don’t get hydrogen peroxide in cuts.<br />

Station 7: MUST BE DONE IN FUME HOOD.<br />

Station 8: Copper (II) sulfate hydrate can be a skin irritant. Do not breathe<br />

fumes while heating.<br />

Station 9: Alcohol burners do get warm. Methanol is very hot <strong>and</strong> burns nearly<br />

invisible. Ethanol burns with a blue flame <strong>and</strong> is safer.<br />

Disposal: Dispose of all substances per MSDS sheet or disposal methods in the<br />

Flinn Scientific <strong>Chemical</strong> Catalog. MSDS sheets <strong>and</strong> safety information can be<br />

found at www.FlinnSci.com .<br />

Real-World Connections<br />

Can relate reactions to the fact that many items (foods, pharmaceuticals) are<br />

made through chemical reactions. Discuss that your body works because of<br />

many chemical processes <strong>and</strong> reactions.<br />

Sources<br />

http://staff.imsa.edu/science/chemistry/web/<strong>Chemical</strong>%20<strong>Reactions</strong>%20Labrevised.pdf<br />

Procedure/Description of Lesson<br />

Students will perform a series of chemical reactions, make observations, <strong>and</strong><br />

balance the equations they performed. Students will identify types of reactions,<br />

parts of an equation, <strong>and</strong> give evidence of a chemical reaction.<br />

See Lab H<strong>and</strong>out below:<br />

30


<strong>Chemical</strong> <strong>Reactions</strong> Lab<br />

Purpose: to become more familiar with different types of chemical reactions by<br />

conducting several reactions, noting the results, <strong>and</strong> discussing observations with<br />

colleagues.<br />

Procedure: At each of the nine stations, there are directions for you to followincluding<br />

directions for waste disposal – FOLLOW ALL DIRECTIONS<br />

CAREFULLY!<br />

You should visit only six of the nine stations. You MUST visit stations 6, 8 <strong>and</strong> 9.<br />

You will then choose one station from stations 1 <strong>and</strong> 7, one station from stations 2 <strong>and</strong><br />

5 <strong>and</strong> one station from stations 3 <strong>and</strong> 4. You do not need to move through the stations<br />

in any particular order. You MUST wear your safety goggles at ALL TIMES!<br />

At each station, answer the following questions in your lab notebook or on your<br />

paper:<br />

a. How did you know a chemical reaction took place?<br />

b. Formula of reactant(s)<br />

c. Formula of product(s)<br />

d. Type of chemical reaction<br />

e. Write the balanced equation for the reaction (including all physical states).<br />

Station 1:<br />

1. Get a strip of magnesium ribbon (about 2.5 cm long). Holding it with forceps,<br />

ignite the ribbon in a Bunsen burner flame. Do not look directly at the<br />

burning magnesium! Looking directly at the burning magnesium could<br />

damage your eyes.<br />

2. Hold the burning ribbon over a glass plate so that no burning magnesium l<strong>and</strong>s<br />

on the lab bench.<br />

Word equation: Magnesium reacts with oxygen to produce magnesium oxide.<br />

Station 2:<br />

1. Place 10 drops of silver nitrate into a small test tube. Add 10 drops of sodium<br />

chloride to the same test tube.<br />

Word equation: Aqueous silver nitrate reacts with aqueous sodium chloride to produce<br />

solid silver chloride <strong>and</strong> aqueous sodium nitrate.<br />

31


Station 3:<br />

1. Place a small piece of zinc into a small test tube. Add enough dilute hydrochloric<br />

acid (HCl) to just cover the piece of zinc.<br />

Word Equation: Zinc reacts with aqueous hydrochloric acid to produce aqueous zinc (II)<br />

chloride <strong>and</strong> hydrogen gas.<br />

Station 4:<br />

1. Place a small piece of magnesium ribbon (about 10 mm long) into a small test<br />

tube.<br />

2. Add enough copper (II) sulfate to just cover the ribbon. Set aside for 15<br />

minutes. Examine the contents of the test tube. If no change is observed, notify<br />

your teacher.<br />

Word equation: Aqueous Copper (II) sulfate reacts with magnesium to produce<br />

aqueous magnesium sulfate <strong>and</strong> copper.<br />

Station 5:<br />

1. Place 10 drops of barium chloride into a small test tube. Add 10 drops of sodium<br />

sulfate to the same test tube.<br />

Word equation: Aqueous barium chloride reacts with aqueous sodium sulfate to make<br />

barium sulfate <strong>and</strong> aqueous sodium chloride.<br />

Station 6:<br />

1. Place 20 drops of hydrogen peroxide into a small test tube.<br />

2. Add a small amount of manganese (IV) oxide to the tube (just enough to cover<br />

the bottom of the test tube). HINT: manganese (IV) oxide is a catalyst. It is not<br />

a reactant or product, but it speeds up the rate of the reaction. A catalyst is<br />

indicated in a chemical reaction by writing the formula of the catalyst over the<br />

arrow.<br />

Word equation: Aqueous hydrogen peroxide produces water <strong>and</strong> oxygen.<br />

Station 7: USE THE FUME HOOD FOR THIS PROCEDURE!!<br />

1. Place a small amount of sulfur into a deflagration spoon. Heat over a Bunsen<br />

burner until the sulfur begins to burn.<br />

Word equation: Sulfur reacts with oxygen to yield sulfur dioxide gas.<br />

32


Station 8:<br />

1. Place a small amount (a small scoop) of hydrated copper (II) sulfate into a small<br />

test tube. Heat the hydrate over a Bunsen burner until the chemical reaction is<br />

complete (the reaction should be obvious). NOTE: A hydrate is a compound that<br />

contains water. The formula of a hydrate is written a little differently than<br />

formulas for other compounds. The formula for the hydrate of copper (II) sulfate<br />

is written CuSO 4 . 5H 2 O. This means there are five water molecules bound to one<br />

CuSO 4 molecule. (The correct name for this compound is copper (II) sulfate<br />

pentahydrate).<br />

Word equation: When copper (II) sulfate pentahydrate is heated, anhydrous copper (II)<br />

sulfate <strong>and</strong> water vapor are produced. (Anhydrous means “no water”)<br />

Station 9:<br />

1. Use the matches/lighter to ignite the methanol in the lamp by lighting the wick.<br />

2. Extinguish the flame by putting the cap over the wick.<br />

Word equation: Methanol reacts with oxygen to produce carbon dioxide gas <strong>and</strong> water.<br />

Questions to answer in your lab notebook or on paper for the next class:<br />

1. Name five types of chemical reactions.<br />

2. What is a reactant in a chemical reaction?<br />

3. What is a product in a chemical reaction?<br />

4. Name four ways you can tell a chemical reaction has taken place.<br />

5. What does the symbol mean in a chemical equation?<br />

6. Give the four symbols for physical states of reactants <strong>and</strong> products, <strong>and</strong> tell what<br />

each means.<br />

7. Why must chemical equations be balanced?<br />

Conclusion: Was the purpose of this lab achieved? What evidence do you have to<br />

support your answer?<br />

Revised January 11, 2008<br />

http://staff.imsa.edu/science/chemistry/web/<strong>Chemical</strong>%20<strong>Reactions</strong>%20Labrevised.pdf<br />

Assessment Ideas<br />

Give students a worksheet with equations. Have the students predict the<br />

products, balance the equations, <strong>and</strong> identify the type of reaction (formative).<br />

Do the same for a unit test (summative).<br />

33


<strong>Nomenclature</strong> <strong>and</strong> <strong>Chemical</strong> <strong>Reactions</strong><br />

Activity #5 – Metal/Metal Ions Lab Simulation<br />

Questions to be investigated<br />

Objectives<br />

How do I predict products of a single replacement reaction? What is an activity<br />

series? How do I draw representations of reactions?<br />

The student will perform an online lab simulation of single replacement reactions<br />

to create an activity series. Then the student will predict which reactions occur<br />

<strong>and</strong> what the products are. Lastly, they will draw diagrams to represent the<br />

reactions.<br />

Teacher Notes<br />

Materials<br />

This is an online simulation. There is an accompanying worksheet to print for<br />

the students to fill while they do the simulation.<br />

Worksheet packet for each student.<br />

Real-World Connections<br />

Sources<br />

Discuss electroplating <strong>and</strong> reactivity of metals. A lot of jewelry is made of silver,<br />

gold, or copper because these metals are very unreactive.<br />

www.chem.iastate.edu/group/Greenbowe/sections/projectfolder/animationsindex<br />

.htm<br />

Procedure/Description of Lesson<br />

Students will complete an online lab simulation from the above site. After<br />

clicking the link, select <strong>Reactions</strong> of Metals <strong>and</strong> Metal Ions Simulation. The<br />

h<strong>and</strong>out can be printed from the item below the simulation which is labeled as a<br />

tutorial.<br />

Assessment Ideas<br />

Give students an activity series to use <strong>and</strong> have them predict if a reaction will<br />

occur <strong>and</strong> if so, what the products would be (formative).<br />

Give the students a scenario related to extracting metals or reactivity <strong>and</strong> ask<br />

them to explain what happened based on the activity of metals <strong>and</strong> single<br />

replacement reactions (summative).<br />

Have students perform “wet” lab doing four single replacement reactions.<br />

Students will predict products, balance equations, <strong>and</strong> create an activity series<br />

for the four metals used <strong>and</strong> hydrogen. See h<strong>and</strong>out below. Wear goggles, use<br />

caution with acid, metals may NOT go down the drain.<br />

34


Single Replacement <strong>Reactions</strong><br />

Background Information:<br />

In nature, elements can occur either free, meaning uncombined with other elements, or<br />

chemically combined in a compound. The tendency of a particular element to combine<br />

with other substances is a measure of the activity of that element. The more active an<br />

element is, the more likely it is to combine. In a single replacement reaction, an<br />

uncombined element replaces a less active element that is combined in a chemical<br />

compound. The less active element is then freed from the compound.<br />

For example, in the reaction<br />

Zinc + copper sulfate zinc sulfate + copper<br />

Zinc replaces the less active copper, combines with sulfate, <strong>and</strong> frees the copper from<br />

the compound.<br />

In this investigation, you will observe how various metals undergo single replacement<br />

reactions when placed in acid. If the metal is more active than the hydrogen in the acid,<br />

it will replace the hydrogen <strong>and</strong> hydrogen will be released as a gas.<br />

Problem: How does a single replacement reaction occur?<br />

Materials: (per group)<br />

Safety goggles,<br />

1M hydrochloric acid<br />

Graduated cylinder<br />

Copper (cut wire in to pieces of 1-cm length)<br />

Iron (nail)<br />

5 test tubes<br />

test-tube rack<br />

Zinc<br />

Aluminum<br />

Magnesium (cut into 1-cm lengths)<br />

Procedure:<br />

1. Label your test tubes with the names of the metals listed in the materials.<br />

2. Put on your safety goggles. Carefully pour approximately 5 mL of HCl into each<br />

test tube. (Make sure the amount of HCl is the same in each test tube.<br />

3. One at a time, place the appropriate metal in each test tube. Record your<br />

observations for each metal. Feel each test tube as the reaction proceeds <strong>and</strong><br />

record your observations.<br />

4. When you have completed the investigation, carefully pour off the acid, rinse the<br />

metal several times with water, <strong>and</strong> put it into a container provided by your<br />

teacher. Do not put any unused metal in the sink.<br />

35


Observations:<br />

1. What did you observe in the test tube with the acid <strong>and</strong><br />

a. magnesium_______________________________________________________<br />

b. aluminum________________________________________________________<br />

c. iron_____________________________________________________________<br />

d. copper___________________________________________________________<br />

e. zinc_____________________________________________________________<br />

Conclusions:<br />

1. Write <strong>and</strong> balance the single replacement reaction that has occurred between the<br />

acid <strong>and</strong> each metal.<br />

a. magnesium<br />

b. aluminum<br />

c. iron<br />

d. copper<br />

e. zinc<br />

2. Were these reactions endothermic or exothermic? _______________________<br />

Explain__________________________________________________________<br />

________________________________________________________________<br />

36


Critical Thinking <strong>and</strong> Application<br />

1. Which of the metals are more active than hydrogen? _________________<br />

2. Which of the metals are less active than hydrogen? _____________________<br />

3. What could you do to prove that hydrogen gas was produced as a result of these<br />

reactions? ________________________________________________________<br />

______________________________________________________________<br />

4. The rate at which hydrogen gas is produced is a result of these single<br />

replacement reactions is an indication of the relative activity of the metals. List<br />

the order of their activity from most active to least active.<br />

________________________________________________________________<br />

______________________________________________________________<br />

5. Nonmetals can also be involved in single replacement reactions. If chlorine is<br />

more active than bromine, write the equation for the reaction between chlorine<br />

<strong>and</strong> potassium bromide.<br />

________________________________________________________________<br />

________________________________________________________________<br />

37


<strong>Nomenclature</strong> <strong>and</strong> <strong>Chemical</strong> <strong>Reactions</strong><br />

Activity #6 – ChemQuest<br />

Questions to be investigated<br />

Objectives<br />

Materials<br />

Sources<br />

How to balance equations, identify types of reactions, <strong>and</strong> predict products of a<br />

reaction.<br />

The student will be able to label the parts of an equation, balance equations,<br />

predict the products of reactions, <strong>and</strong> identify the type of reactions.<br />

Worksheet packet for each student.<br />

www.ChemistryInquiry.com<br />

These Chemquests are being used with permission of Jason Neil. The entire set<br />

of Chemquests, answer keys, <strong>and</strong> skill practice worksheets are on a CD-rom that<br />

can be purchased from the website.<br />

Procedure/Description of Lesson<br />

Chemquests are designed to be an inquiry learning cooperative group activity.<br />

Instead of lecturing on the topic, the instructor gives a short introduction to the<br />

topic, <strong>and</strong> then places the students in groups of 2-3. The students then work<br />

through the Chemquest to discover <strong>and</strong> figure out the concept. Go over<br />

answers/discuss when students are done, then re-teach if necessary.<br />

See student h<strong>and</strong>outs below.<br />

38


Assessment Ideas<br />

Give a formative quiz the next day on labeling the parts of an equation <strong>and</strong> just<br />

balancing. Predicting products <strong>and</strong> more complicated balancing can be on a<br />

summative unit test.<br />

47

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