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PhD Thesis, 2010 - University College Cork

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Distinguishing peaks from background emission of nitrous oxide<br />

Unfortunately, we were not able to conduct such a test due to relatively low accuracy<br />

of the management data.<br />

4.5.2. Peak event<br />

The notion of an emission/uptake event implies long and continuous peak flux,<br />

extending for days or even weeks. However, this understanding was developed<br />

primarily for the daily-averaged flux time series. In our analysis of half-hourly time<br />

series we did not observe events of such long duration (see Validation subsection for<br />

details regarding daily series analysis). Figure 4.4 presents a few examples of emission<br />

and uptake events that we were able to identify. Typically, an emission or uptake event<br />

appears to have an almost bell-curve shape with rising and falling limbs, in terms of<br />

absolute values. It can be seen, that overall a bell shape curve of the event extends<br />

beyond immediately adjacent periods, i.e., there is a visible trend among close peak<br />

periods that are separated by non-peak periods. The explanation for this variation may<br />

lie in the variability of the wind direction that might transport low flux from nonemitting<br />

fields to the sensor. When breaks and shape are taken into account, sustained<br />

events with durations up to 18 hours can be identified. The duration of uptake events is<br />

shorter on average and does not exceed 6.5 hours.<br />

28

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