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Practical Solutions to Air Pollution Control Challenges

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<strong>Practical</strong> <strong>Solutions</strong> <strong>to</strong> <strong>Air</strong> <strong>Pollution</strong><br />

<strong>Control</strong> <strong>Challenges</strong><br />

By Weerasak Suthapong<br />

email address: wsuthapong@nalco.com<br />

CLEANER COAL<br />

WORK SHOP<br />

Aug 18-21,2008<br />

Ha Long City , Vietnam


“Cradle <strong>to</strong> Grave” Approach<br />

DRY MULTI- POLLUTIONS<br />

REDUCTION<br />

EMISSION REDUCTION<br />

& COMBUSTION ENHANCEMENT


What are the components of<br />

the technology?<br />

Integrated approaches that<br />

complement each other<br />

– ROFA ® – Rotating Opposed Fire <strong>Air</strong><br />

• Induced turbulence and rotation for<br />

superior mixing <strong>to</strong> reduce NOX, SO3,<br />

CO, PM and fly ash LOI<br />

– ROTAMIX ®<br />

• Rotary mixing of chemicals and or<br />

additional fuel <strong>to</strong> optimize NOx<br />

reduction<br />

– ROFA ® FSI<br />

• Superior mixing of chemicals <strong>to</strong><br />

capture SO2, SO3, mercury


ROFA – Rotating Opposed Fire<br />

<strong>Air</strong><br />

• High velocity air from a boost fan is<br />

introduced in<strong>to</strong> the boiler through ROFA<br />

boxes<br />

• ROFA boxes – placed asymmetrically<br />

Confidential and Proprietary<br />

Information<br />

4<br />

4


ROFA<br />

Confidential and Proprietary<br />

Information<br />

5<br />

5


ROFA Box<br />

Confidential and Proprietary<br />

Information<br />

6<br />

6


Mixing


Advantages of the<br />

technology<br />

• Brings practicality <strong>to</strong> environmental<br />

compliance strategies<br />

– Offers practical NOx, SOx, CO, fly ash<br />

LOI and mercury solutions<br />

• Low capital cost<br />

• Low operating cost<br />

• Flexible<br />

– Fuel<br />

– Incremental investment<br />

– Future regula<strong>to</strong>ry change<br />

– Least amount of downtime<br />

– Maximizes the efficiency of current<br />

assets<br />

• Reduces CO 2 generation<br />

8


ROTAMIX – 3 rd Generation<br />

SNCR<br />

• High velocity air<br />

• High kinetic<br />

energy promotes<br />

chemical mixing<br />

• Better chemical<br />

utilization reduces<br />

costs<br />

• Better NOx<br />

reduction than<br />

other SNCR<br />

systems<br />

Confidential and Proprietary<br />

Information<br />

9


ROTAMIX<br />

Injection Port<br />

Blowers<br />

Confidential and Proprietary<br />

Information<br />

10


NOx Technologies<br />

• ROFA<br />

– Boosted OFA<br />

– 50% - 65% NOx reduction<br />

• Rotamix (urea)<br />

– SNCR system<br />

– 72% - 82% NOx reduction<br />

• SCR<br />

– Small In-Duct Catalyst<br />

– 80% - 90% NOx reduction<br />

Step one<br />

Step two<br />

Step three<br />

11


ROFA FSI<br />

Furnace Sorbent Injection<br />

• SOx<br />

• Mercury<br />

Uses ROFA mixing <strong>to</strong> effectively<br />

introduce furnace sorbents<br />

(chemicals)<br />

Confidential and Proprietary<br />

Information<br />

12


SOx Technologies<br />

• Furnace Sorbent Injection<br />

(FSI) Step one<br />

– Injection Lime / Hydrate /<br />

Limes<strong>to</strong>ne in the Furnace<br />

– 50% - 75% SOx reduction<br />

13


Conventional Add-On <strong>Pollution</strong> <strong>Control</strong><br />

30 Yr old Plant<br />

Nalco Mobotec’s low capital<br />

integrated solution for NOx, SO 2<br />

and Hg<br />

Add-on Wet<br />

SO2 Scrubber<br />

+SCR<br />

2007<br />

70- 100% Increase in capital employed<br />

Original<br />

Generating Plant<br />

1974<br />

Nalco Mobotec<br />

Integrated <strong>Pollution</strong> <strong>Control</strong><br />

8- 12% Increase in capital employed<br />

Original<br />

Generating Plant<br />

No Add-on Wet<br />

SO2 Scrubber<br />

or SCR Required<br />

14


The MagMill Technology<br />

DRY MULTI- POLLUTIONS REDUCTION<br />

To Burner<br />

Mill Feed<br />

Clean Coal<br />

• Dry magnetic separation technology<br />

which combines the existing pulverizer<br />

with a magnetic separa<strong>to</strong>r<br />

Pulverizer Mill<br />

Separa<strong>to</strong>r<br />

• Remove mineral contaminants from coal<br />

more efficiently and economically<br />

MagMill Reject<br />

• Offers retrofit opportunity <strong>to</strong> change the<br />

design of new coal combustion or<br />

gasification plants which will have lower<br />

capital and operational costs.


MagMill<br />

Technology<br />

Advantages<br />

Removes<br />

abrasive minerals<br />

No water<br />

No additives<br />

Rapid<br />

coal quality<br />

control<br />

Granular waste<br />

Benefits<br />

Mill<br />

Reduces wear &<br />

power draw<br />

Burners & Boilers<br />

Reduces slagging<br />

Less water wall wastage<br />

Pollutants<br />

Reduces sulfur<br />

Reduces mercury<br />

Less arsenic <strong>to</strong> SCR<br />

Plant<br />

Increases generation<br />

Lowers pollutants<br />

Lowers costs


Ash & Sulfur Reductions, Lb/MBtu %<br />

8 × 100 Mesh Cholla Coal<br />

40<br />

5<br />

4<br />

30<br />

3<br />

Ash<br />

20<br />

10<br />

Ash<br />

Sulfur<br />

2<br />

1<br />

SO2<br />

0<br />

70 80 90 100<br />

Btu Recovery, %<br />

0


Ash & Sulfur Reductions, Lb/MBtu %<br />

8 × 100 Mesh Lee Ranch Coal<br />

20<br />

25<br />

Ash<br />

15<br />

10<br />

Ash<br />

Sulfur<br />

20<br />

15<br />

10<br />

SO2<br />

5<br />

5<br />

0<br />

75 80 85 90 95 100<br />

Btu Recovery, %<br />

0


NALCO MOBOTEC<br />

• THANK YOU<br />

• QUESTIONS<br />

19

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