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(A) Only the sulphides of second group get<br />
precipitated<br />
(B) Only the sulphides of fourth group get<br />
precipitated<br />
(C) Neither of the sulphides of second and fourth<br />
groups get pricipitated<br />
(D) Sulphides of both the groups second and fourth<br />
get precipitated<br />
2. The geometrical shapes of XeF + 2–<br />
5 , XeF 6 and XeF 8<br />
respectively are -<br />
(A) trigonal bipyramidal, octahedral and square<br />
planar<br />
(B) square based pyramidal, distorted octahedral and<br />
octahedral<br />
(C) planar pentagonal, octahedral and square anti<br />
prismatic<br />
(D) square based pyramidal, distorted octahedral and<br />
square anti prismatic<br />
3. Regarding graphite the following informations are<br />
available :<br />
3.35Å<br />
Top view<br />
5. The difference between ortho and para hydrogen<br />
is/are -<br />
(A) they are electron spin isomer, where the spins of<br />
electrons are opposite<br />
(B) ortho hydrogen is more stable at lower<br />
temperature<br />
(C) they are nuclear spin isomer, where the spins of<br />
protons are same in para and different in ortho<br />
isomer<br />
(D) they are nuclear spin isomers, where the spins of<br />
protons are opposite in para but same in ortho<br />
isomer<br />
6. NGP assistance support for S N 2 reaction will be seen<br />
in -<br />
(A)<br />
(C)<br />
OH<br />
Cl<br />
OH<br />
Θ<br />
COO<br />
(B) CH 3 –S–CH 2 –CH 2 –Cl<br />
(D)<br />
OH<br />
7. When the compound called isoborneol is heated with<br />
50% sulfuric acid the product of the reaction is/are ?<br />
HO<br />
Cl<br />
Isoborneol<br />
The density of graphite = 2.25 gm/cm 3 . What is C–C<br />
bond distance in graphite ?<br />
(A) 1.68Å (B) 1.545Å<br />
(C) 2.852 Å (D) 1.426Å<br />
(A)<br />
(C)<br />
(B)<br />
(D)<br />
4. The molecular formula of a non-stoichiometric tin<br />
oxide containing Sn(II) and Sn (IV) ions is Sn 4.44 O 8 .<br />
Therefore, the molar ratio of Sn(II) to Sn(IV) is<br />
approximately -<br />
(A) 1 : 8 (B) 1 : 6<br />
(C) 1 : 4 (D) 1 : 1<br />
Questions 5 to 9 are multiple choice questions. Each<br />
question has four choices (A), (B), (C) and (D), out of<br />
which MULTIPLE (ONE OR MORE) is correct.<br />
8. Regarding the radial probability distribution<br />
(4nr 2 R 2 nl) vs r plot which of the following is/are<br />
correct ?<br />
(A) The number of maxima is (n-l)<br />
(B) The number of nodal points is (n-l-1)<br />
(C) The radius at which the radial probability density<br />
reaches to maxima is 3s < 3p < 3d<br />
(D) The number of angular nodes is l<br />
XtraEdge for <strong>IIT</strong>-<strong>JEE</strong> 59 DECEMBER 2009