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IIT-JEE 2010 - Career Point

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(A) Only the sulphides of second group get<br />

precipitated<br />

(B) Only the sulphides of fourth group get<br />

precipitated<br />

(C) Neither of the sulphides of second and fourth<br />

groups get pricipitated<br />

(D) Sulphides of both the groups second and fourth<br />

get precipitated<br />

2. The geometrical shapes of XeF + 2–<br />

5 , XeF 6 and XeF 8<br />

respectively are -<br />

(A) trigonal bipyramidal, octahedral and square<br />

planar<br />

(B) square based pyramidal, distorted octahedral and<br />

octahedral<br />

(C) planar pentagonal, octahedral and square anti<br />

prismatic<br />

(D) square based pyramidal, distorted octahedral and<br />

square anti prismatic<br />

3. Regarding graphite the following informations are<br />

available :<br />

3.35Å<br />

Top view<br />

5. The difference between ortho and para hydrogen<br />

is/are -<br />

(A) they are electron spin isomer, where the spins of<br />

electrons are opposite<br />

(B) ortho hydrogen is more stable at lower<br />

temperature<br />

(C) they are nuclear spin isomer, where the spins of<br />

protons are same in para and different in ortho<br />

isomer<br />

(D) they are nuclear spin isomers, where the spins of<br />

protons are opposite in para but same in ortho<br />

isomer<br />

6. NGP assistance support for S N 2 reaction will be seen<br />

in -<br />

(A)<br />

(C)<br />

OH<br />

Cl<br />

OH<br />

Θ<br />

COO<br />

(B) CH 3 –S–CH 2 –CH 2 –Cl<br />

(D)<br />

OH<br />

7. When the compound called isoborneol is heated with<br />

50% sulfuric acid the product of the reaction is/are ?<br />

HO<br />

Cl<br />

Isoborneol<br />

The density of graphite = 2.25 gm/cm 3 . What is C–C<br />

bond distance in graphite ?<br />

(A) 1.68Å (B) 1.545Å<br />

(C) 2.852 Å (D) 1.426Å<br />

(A)<br />

(C)<br />

(B)<br />

(D)<br />

4. The molecular formula of a non-stoichiometric tin<br />

oxide containing Sn(II) and Sn (IV) ions is Sn 4.44 O 8 .<br />

Therefore, the molar ratio of Sn(II) to Sn(IV) is<br />

approximately -<br />

(A) 1 : 8 (B) 1 : 6<br />

(C) 1 : 4 (D) 1 : 1<br />

Questions 5 to 9 are multiple choice questions. Each<br />

question has four choices (A), (B), (C) and (D), out of<br />

which MULTIPLE (ONE OR MORE) is correct.<br />

8. Regarding the radial probability distribution<br />

(4nr 2 R 2 nl) vs r plot which of the following is/are<br />

correct ?<br />

(A) The number of maxima is (n-l)<br />

(B) The number of nodal points is (n-l-1)<br />

(C) The radius at which the radial probability density<br />

reaches to maxima is 3s < 3p < 3d<br />

(D) The number of angular nodes is l<br />

XtraEdge for <strong>IIT</strong>-<strong>JEE</strong> 59 DECEMBER 2009

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