NA-LUBE® BL-1232 EL - King Industries, Inc.
NA-LUBE® BL-1232 EL - King Industries, Inc.
NA-LUBE® BL-1232 EL - King Industries, Inc.
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<strong>NA</strong>-LUBE ® <strong>BL</strong>-<strong>1232</strong> <strong>EL</strong><br />
Environmentally Friendly Ashless Additive Package<br />
for Ester Based Systems<br />
For information about the<br />
European Ecolabel, visit<br />
www.Ecolabel.eu
NEW <strong>NA</strong>-LUBE ® <strong>BL</strong>-<strong>1232</strong> <strong>EL</strong><br />
Environmentally Driven...Performance Proven<br />
Throughout the world, environmentally friendly lubricants are being developed to replace<br />
older technologies that are non-renewable and are contaminates when released<br />
into soil or water. Almost universally, the challenge formulators face when developing<br />
these new, replacement products is maintaining or surpassing the performance<br />
characteristics of the original.<br />
A particular area of focus for new greener lubricants has been hydraulic fluids, given<br />
their propensity to leak and the ensuing ground and water contamination. Here too,<br />
the challenge has been finding additives and additive packages that are eco-friendly<br />
and deliver the performance needed. In that regard <strong>King</strong> <strong>Industries</strong> is proud to introduce<br />
<strong>NA</strong>-LUBE <strong>BL</strong>-<strong>1232</strong> <strong>EL</strong>, an ashless, multifunctional additive package specifically<br />
designed for use in ester based systems including hydraulic fluids. Additive Package<br />
<strong>NA</strong>-LUBE <strong>BL</strong>-<strong>1232</strong> <strong>EL</strong> has been evaluated against the European Ecolabel criteria for<br />
lubricants (Commission Decision 2011/381/EU). Based on that evaluation, <strong>NA</strong>-LUBE<br />
<strong>BL</strong>-<strong>1232</strong> <strong>EL</strong>, when used as a single additive, qualifies for use in a final product eligible<br />
for the European Eco-Label in a concentration up to 1.8% by weight.<br />
<strong>NA</strong>-LUBE ® <strong>BL</strong>-<strong>1232</strong> <strong>EL</strong> Classification<br />
E<strong>EL</strong><br />
Classification<br />
% based on maximum treat<br />
rate of 1.8% by weight*<br />
Biodegradation C 1.80%<br />
Aquatic toxicity D 0.58%<br />
Aquatic toxicity E 0.38%<br />
Aquatic toxicity F 0.52%<br />
Substances not required to be<br />
assessed<br />
Renewability<br />
0.33%<br />
0%<br />
C = Non-Biodegradable and Non-Bioaccumulative<br />
D = Not Toxic<br />
E = Harmful<br />
F = Toxic<br />
* When used in combination with other additives, then the maximum treat level needs<br />
to be redefined.<br />
Eco-Label: Formulators of final products will need to provide additional information (e.g.<br />
performance test results, toxicity and biodegradability data on base oils and any other<br />
additives, components) in order to use the European Eco-Label on the final product.<br />
Regulatory Labeling: The incorporation of this additive into a formulation does not require<br />
any additional regulatory labeling.<br />
For more information about the EU Ecolabel, visit www.Ecolabel.eu
<strong>NA</strong>-LUBE ® <strong>BL</strong>-<strong>1232</strong> <strong>EL</strong> Typical Properties<br />
Environmentally friendly multifunctional, ashless additive package<br />
Appearance<br />
Clear amber, slightly viscous liquid<br />
Sulfur Content 8.20%<br />
Nitrogen Content 2.75%<br />
Phosphorus Content 0.90%<br />
Viscosity @ 40°C<br />
ASTM D 445, DIN 51 550<br />
Viscosity @ 100° C<br />
ASTM D 445, DIN 51 550<br />
Density @ 25°C<br />
ASTM D 4052<br />
Weight per Gallon @ 25°C<br />
Flash Point, COC<br />
ASTM D 92, DIN 51376<br />
Mineral Oil Content<br />
180 mm 2 /s (cSt)<br />
11 mm 2 /s (cSt)<br />
0.99 g/ml<br />
8.25 lbs.<br />
170°C<br />
None<br />
NOTE: The above data are not specifications.<br />
<strong>NA</strong>-LUBE ® <strong>BL</strong>-<strong>1232</strong> <strong>EL</strong> Applications<br />
<strong>NA</strong>-LUBE <strong>BL</strong>-<strong>1232</strong> <strong>EL</strong> is a multifunctional, ashless additive package that<br />
imparts excellent antiwear and anti-corrosion protection. It was specifically<br />
designed for use in ester based hydraulic systems where corrosion protection<br />
and filterability are key performance requirements. Examples of its performance<br />
in both saturated and unsaturated esters follow.<br />
<strong>NA</strong>-LUBE <strong>BL</strong>-<strong>1232</strong> <strong>EL</strong> is recommended for use in “total loss lubricants”, including<br />
chain saw oils, hydraulic fluids and concrete release agents.<br />
<strong>NA</strong>-LUBE ® <strong>BL</strong>-<strong>1232</strong> <strong>EL</strong> Advantages<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
<br />
Confirmed by SMK to be in compliance for use in a final product eligible for<br />
the EU Ecolabel<br />
Low impact to water and soil during usage<br />
Requires no labeling risk-phrases<br />
Excellent antiwear performance<br />
Outstanding anti-corrosion protection<br />
Exceptional filterability<br />
Extended elastomer compatibility<br />
Complete additive package
<strong>NA</strong>-LUBE ® <strong>BL</strong>-<strong>1232</strong> <strong>EL</strong> Performance With Saturated Esters<br />
The test data that follow show the performance improvements and seal compatibility<br />
with a number of common elastomers when <strong>NA</strong>-LUBE <strong>BL</strong>-<strong>1232</strong> <strong>EL</strong> was tested in two<br />
different saturated esters.<br />
Typical performance results are shown below:<br />
Base Fluid<br />
Specification<br />
DIN ISO 15380<br />
Priolube 1973<br />
Saturated Ester<br />
Radialube ® 7588<br />
Saturated Ester<br />
Treat Level, % Neat With 1.8%<br />
<strong>BL</strong>-<strong>1232</strong> <strong>EL</strong><br />
Steel Corrosion<br />
(ASTM D665 - 24 hours, 60°C)<br />
Procedure A (distilled H 2O)<br />
Procedure B (synthetic sea water)<br />
Pass<br />
Pass<br />
Demulsibility<br />
(ASTM D 1401) @ 130°F (54°C)<br />
Oil-Water-Emulsion<br />
Time (minutes) 30<br />
Fail<br />
Fail<br />
43-37-0<br />
15<br />
Pass<br />
Pass<br />
40-40-0<br />
15<br />
Neat With 1.8%<br />
<strong>BL</strong>-<strong>1232</strong> <strong>EL</strong><br />
Fail<br />
Fail<br />
43-37-0<br />
25<br />
Pass<br />
Pass<br />
41-38-0<br />
25<br />
FZG A/8.3/90<br />
(ASTM D 5182, DIN 51 354 Part 2)<br />
Damage Load Stage 10 min. n/d >12 n/d 12<br />
Four Ball Wear (ASTM D 4172)<br />
1 hour, 22°C, 15kg, 1500rpm (mm)<br />
1 hour, 22°C, 30kg, 1500rpm (mm)<br />
1 hour, 75°C, 40kg, 1500rpm (mm)<br />
n/d<br />
0.49<br />
0.57<br />
0.48<br />
n/d<br />
0.54<br />
0.59<br />
0.40<br />
V 104C Vane Pump<br />
(DIN EN ISO 20 763)<br />
Reported Wear Loss Ring (mg)<br />
Wear Loss Vanes (mg)<br />
120 max.<br />
30 max.<br />
n/d 4.6<br />
7.5<br />
n/d<br />
n/d<br />
Copper Corrosion (ASTM D 130)<br />
3 hours, 100°C 2 max. 1b 1a 1b 1a<br />
AFNOR Filtration Dry (E 68690)<br />
FI 1.05 1.04 1.09 1.08<br />
AFNOR Filtration Wet (E 68691)<br />
FI 1.28 1.08 1.33 1.12<br />
Filterability Dry (DIN ISO 13357-2)<br />
FI1 (%)<br />
FI2 (%)<br />
80 min.<br />
60 min.<br />
99.5<br />
98.9<br />
95.4<br />
87.7<br />
99.1<br />
96.3<br />
96.9<br />
84.8<br />
Filterability Wet (DIN ISO 13357-2)<br />
FI1 (%)<br />
FI2 (%)<br />
70 min.<br />
50 min.<br />
92.5<br />
83.6<br />
93.8<br />
85.9<br />
95.0<br />
82.0<br />
91.7<br />
79.1<br />
Hydrolytic Stability<br />
(Beverage Bottle) (ASTM D 2619)<br />
Copper Loss (mg/cm 2 )<br />
Total Acidity-Water Layer (mg/KOH)<br />
Copper Appearance (ASTM D 130)<br />
0.05<br />
1.2<br />
1b<br />
0.01<br />
2.9<br />
3a<br />
0.05<br />
1.5<br />
1b<br />
-0.03<br />
2.9<br />
2c<br />
RPVOT (ASTM D 2272)<br />
150°C, H 2O, O 2, Cu Catalyst<br />
Lifetime (minutes)
Base Fluid<br />
Specification<br />
DIN ISO 15380<br />
Priolube 1973<br />
Saturated Ester<br />
Treat Level, % Neat With 1.8%<br />
<strong>BL</strong>-<strong>1232</strong> <strong>EL</strong><br />
Radialube ® 7588<br />
Saturated Ester<br />
Neat With 1.8%<br />
<strong>BL</strong>-<strong>1232</strong> <strong>EL</strong><br />
Air Release Properties (DIN 51381)<br />
50°C (minutes) 10 max. 4 4 4 4<br />
Foam Test* (ASTM D 892)<br />
Sequence I 25°C<br />
Sequence II 93°C<br />
Sequence III 25°C<br />
* <strong>NA</strong>-LUBE <strong>BL</strong>-<strong>1232</strong> <strong>EL</strong> does not contain a<br />
foam inhibitor<br />
150-0<br />
75-0<br />
150-0<br />
20-0<br />
0-0<br />
20-0<br />
140-0<br />
10-0<br />
20-0<br />
365-0<br />
30-0<br />
300-0<br />
110-0<br />
20-0<br />
290-0<br />
Seal Compatibility<br />
(DIN 53521 / 53538, Part 1)<br />
SRE-NBR / 7 days / 100°C<br />
Relative Volume Change, %<br />
Relative Change Shore A Hardness<br />
Change in Elongation at Break,%<br />
Chg. In Tensile Strength at Break, %<br />
Linde Corrosion Test<br />
(VDMA 24570)<br />
Metal Loss (g/m 2 )<br />
Brass CuZn35Mn2Si<br />
Guss Bronze CuPb15Sn8<br />
Sinter Bronze CuPbSn8<br />
Steel 100Cr6<br />
-3 to 10<br />
+/- 10<br />
30 max.<br />
30 max.<br />
8.2<br />
-4<br />
-60.6<br />
60.7<br />
Priolube is a trademark of Croda International, Radia is a trademark of Oleon NV.<br />
n/d<br />
9.3<br />
-6<br />
-18.8<br />
-24.0<br />
1<br />
1<br />
1<br />
0<br />
26.0<br />
-15<br />
-25.0<br />
-16.4<br />
n/d<br />
28.0<br />
-14<br />
-32.7<br />
26.8<br />
2<br />
2<br />
2<br />
0<br />
Extended Seal Compatibility<br />
Base Fluid<br />
Specification<br />
DIN ISO 15380<br />
Priolube 1973<br />
Saturated Ester<br />
Radialube 7588<br />
Saturated Ester<br />
Treat Level, % Neat With 1.8%<br />
<strong>BL</strong>-<strong>1232</strong> <strong>EL</strong><br />
Neat With 1.8%<br />
<strong>BL</strong>-<strong>1232</strong> <strong>EL</strong><br />
Seal Compatibility<br />
FKM 2 / 42 days / 80°C<br />
Relative Volume Change, %<br />
Relative Change Shore A Hardness<br />
Change in Elongation at Break,%<br />
Chg. in Tensile Strength at Break, %<br />
-3 to 10<br />
+/- 10<br />
30 max.<br />
30 max.<br />
1.4<br />
0<br />
-2.4<br />
2.76<br />
1.7<br />
0<br />
3.2<br />
12.8<br />
3.2<br />
-3<br />
-4.8<br />
11<br />
3.3<br />
-2<br />
-4.8<br />
12.1<br />
Seal Compatibility<br />
NBR 1 / 42 days / 80°C<br />
Relative Volume Change, %<br />
Relative Change Shore A Hardness<br />
Change in Elongation at Break,%<br />
Chg. in Tensile Strength at Break, %<br />
-3 to 10<br />
+/- 10<br />
30 max.<br />
30 max.<br />
7.2<br />
-4<br />
-21.9<br />
-32.1<br />
9.2<br />
-7<br />
-8<br />
-6.2<br />
25.3<br />
-16<br />
-28.4<br />
-20.1<br />
26.5<br />
-16<br />
-20.9<br />
-9.6<br />
Seal Compatibility<br />
NBR 2 / 42 days / 80°C<br />
Relative Volume Change, %<br />
Relative Change Shore A Hardness<br />
Change in Elongation at Break,%<br />
Chg. in Tensile Strength at Break, %<br />
-3 to 10<br />
+/- 10<br />
30 max.<br />
30 max.<br />
1.5<br />
-1<br />
-3.4<br />
-12.8<br />
2.8<br />
-2<br />
-12.5<br />
-22.7<br />
11.8<br />
-8<br />
-12.5<br />
-22.7<br />
12.9<br />
-8<br />
-16.3<br />
-14.1<br />
Seal Compatibility<br />
EPDM 1 / 42 days / 80°C<br />
Relative Volume Change, %<br />
Relative Change Shore A Hardness<br />
Change in Elongation at Break,%<br />
Chg. in Tensile Strength at Break, %<br />
-3 to 10<br />
+/- 10<br />
30 max.<br />
30 max.<br />
77.2<br />
-19<br />
-55.4<br />
-32.2<br />
72.7<br />
-18<br />
-48.6<br />
-3<br />
19.7<br />
-10<br />
-22.6<br />
-4.3<br />
20.3<br />
-10<br />
-20.3<br />
-0.9<br />
Seal Compatibility<br />
HNBR 1 / 42 days / 80°C<br />
Relative Volume Change, %<br />
Relative Change Shore A Hardness<br />
Change in Elongation at Break,%<br />
Chg. in Tensile Strength at Break, %<br />
-3 to 10<br />
+/- 10<br />
30 max.<br />
30 max.<br />
9<br />
-5<br />
-38.3<br />
-48.3<br />
9.5<br />
-5<br />
-2.9<br />
-1.7<br />
20.8<br />
-10<br />
-8<br />
-4.2<br />
22.1<br />
-12<br />
-9.1<br />
-3.9
<strong>NA</strong>-LUBE ® <strong>BL</strong>-<strong>1232</strong> <strong>EL</strong> Performance:<br />
Saturated vs. Unsaturated Esters<br />
Using the baseline data obtained from the previous example in saturated esters,<br />
<strong>NA</strong>-LUBE <strong>BL</strong>-<strong>1232</strong> <strong>EL</strong> was further evaluated using an unsaturated ester. As shown,<br />
here too, its addition improved a number of critical performance characteristics.<br />
Base Fluid<br />
Specification<br />
DIN ISO 15380<br />
Priolube 1973<br />
Saturated Ester<br />
Priolube 2089<br />
Unsaturated Ester<br />
Treat Level, % Neat With 1.8%<br />
<strong>BL</strong>-<strong>1232</strong> <strong>EL</strong><br />
Neat With 1.8%<br />
<strong>BL</strong>-<strong>1232</strong> <strong>EL</strong><br />
Steel Corrosion<br />
(ASTM D665 - 24 hours, 60°C)<br />
Procedure A (distilled H 2O)<br />
Procedure B (synthetic sea water)<br />
Pass<br />
Pass<br />
Demulsibility<br />
(ASTM D 1401) @ 130°F (54°C)<br />
Oil-Water-Emulsion<br />
Time (minutes) 30<br />
Fail<br />
Fail<br />
43-37-0<br />
15<br />
Pass<br />
Pass<br />
40-40-0<br />
15<br />
Fail<br />
Fail<br />
44-34-2<br />
30<br />
Pass<br />
Pass<br />
41-39-0<br />
20<br />
FZG A/8.3/90<br />
(ASTM D 5182, DIN 51 354 Part 2)<br />
Damage Load Stage 10 min. n/d >12 n/d 12<br />
Four Ball Wear (ASTM D 4172)<br />
1 hour, 22°C, 15kg, 1500rpm (mm)<br />
1 hour, 22°C, 30kg, 1500rpm (mm)<br />
1 hour, 75°C, 40kg, 1500rpm (mm)<br />
n/d<br />
0.49<br />
0.57<br />
0.48<br />
n/d<br />
0.55<br />
0.60<br />
0.52<br />
V 104C Vane Pump<br />
(DIN EN ISO 20 763)<br />
Reported Wear Loss Ring (g)<br />
Wear Loss Vanes (g)<br />
120 max.<br />
30 max.<br />
n/d 4.6<br />
7.5<br />
n/d<br />
n/d<br />
Copper Corrosion (ASTM D 130)<br />
3 hours, 100°C 2 max. 1b 1a 1b 1a<br />
AFNOR Filtration Dry (E 68690)<br />
FI 1.05 1.04 1.08 1.12<br />
AFNOR Filtration Wet (E 68691)<br />
FI 1.28 1.08 1.35 1.18<br />
Filterability Dry (DIN ISO 13357-2)<br />
FI1 (%)<br />
FI2 (%)<br />
80 min.<br />
60 min.<br />
99.5<br />
98.9<br />
95.4<br />
87.7<br />
96.8<br />
94.0<br />
96.7<br />
85.8<br />
Filterability Wet (DIN ISO 13357-2)<br />
FI1 (%)<br />
FI2 (%)<br />
70 min.<br />
50 min.<br />
92.5<br />
83.6<br />
93.8<br />
85.9<br />
86.8<br />
82.5<br />
92.5<br />
83.1<br />
Hydrolytic Stability<br />
(Beverage Bottle) (ASTM D 2619)<br />
Copper Loss (mg/cm 2 )<br />
Total Acidity-Water Layer (mg/KOH)<br />
Copper Appearance (ASTM D 130)<br />
0.05<br />
1.2<br />
1b<br />
0.01<br />
2.9<br />
3a<br />
0.06<br />
1.9<br />
1b<br />
0.01<br />
13.3<br />
3b<br />
RPVOT (ASTM D 2272)<br />
150°C, H 2O, O 2, Cu Catalyst<br />
Lifetime (minutes)
Base Fluid<br />
Specification<br />
DIN ISO 15380<br />
Priolube 1973<br />
Saturated Ester<br />
Treat Level, % Neat With 1.8%<br />
<strong>BL</strong>-<strong>1232</strong> <strong>EL</strong><br />
Priolube 2089<br />
Unsaturated Ester<br />
Neat With 1.8%<br />
<strong>BL</strong>-<strong>1232</strong> <strong>EL</strong><br />
Air Release Properties (DIN 51381)<br />
50°C (minutes) 10 max. 4 4 3 4<br />
Foam Test* (ASTM D 892)<br />
Sequence I 25°C<br />
Sequence II 93°C<br />
Sequence III 25°C<br />
* <strong>NA</strong>-LUBE <strong>BL</strong>-<strong>1232</strong> <strong>EL</strong> does not contain a<br />
foam inhibitor<br />
150-0<br />
75-0<br />
150-0<br />
20-0<br />
0-0<br />
20-0<br />
140-0<br />
10-0<br />
20-0<br />
10-0<br />
0-0<br />
10-0<br />
60-0<br />
10-0<br />
10-0<br />
Seal Compatibility<br />
(DIN 53521 / 53538, Part 1)<br />
SRE-NBR / 7 days / 100°C<br />
Relative Volume Change, %<br />
Relative Change Shore A Hardness<br />
Change in Elongation at Break,%<br />
Chg. Tensile Strength at Break, %<br />
-3 to 10<br />
+/- 10<br />
30 max.<br />
30 max.<br />
8.2<br />
-4<br />
-60.6<br />
60.7<br />
9.3<br />
-6<br />
-18.8<br />
-24.0<br />
8.5<br />
-6<br />
-44.7<br />
-44.3<br />
9.9<br />
-7<br />
-24.5<br />
-28.5<br />
Priolube is a trademark of Croda International, Radialube ® is a registered trademark of Oleon NV.<br />
Contact Information:<br />
Visit Us At: www.kingindustries.com<br />
USA/Headquarters:<br />
<strong>King</strong> <strong>Industries</strong>, <strong>Inc</strong>., Science Road, Norwalk, CT 06852<br />
(203) 866-5551 lad@kingindustries.com<br />
Europe Technical Sales Office<br />
<strong>King</strong> International, Noordkade 64, 2741 EZ Waddinxveen, The Netherlands<br />
+31-182-631360 info@kingintl.nl<br />
Asia - Pacific Rim Technical Support<br />
Dr. Zhiqiang Alex He, 42 JLYY - Rich Mond Hill, Bo Ai 7th Road,<br />
Zhongshan, Guangdong, China 528403<br />
+760-88229866 alex.he@kingindustries.com<br />
The conditions of your use and application of our products, technical assistance and information (whether verbal, written or by way of product evaluations),<br />
including any suggested formulations and recommendations, are beyond our control. Therefore, it is imperative that you test our products, technical assistance<br />
and information to determine to your own satisfaction whether they are suitable for your intended uses and applications. Such testing has not necessarily been<br />
done by <strong>King</strong> <strong>Industries</strong>, <strong>Inc</strong>. ("<strong>King</strong>"). The facts, recommendations and suggestions herein stated are believed to be reliable; however, no guaranty or warranty<br />
of their accuracy is made. EXCEPT AS STATED, THERE ARE NO WARRANTIES, EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS OR OTHER-<br />
WISE. KING SHALL NOT BE H<strong>EL</strong>D LIA<strong>BL</strong>E FOR SPECIAL, INCIDENTAL, CONSEQUENTIAL OR EXEMPLARY DAMAGES. Any statement inconsistent<br />
herewith is not authorized and shall not bind <strong>King</strong>. Nothing herein shall be construed as a recommendation to use any product(s) in conflict with patents covering<br />
any material or its use. No license is implied or granted under the claims of any patent. Sales or use of all products are pursuant to Standard Terms and<br />
Conditions stated in <strong>King</strong> sales documents.
LAD <strong>NA</strong>-LUBE <strong>BL</strong>-<strong>1232</strong><strong>EL</strong> feb2011