Synthesis and Applications - The Anderson Research Group

More documents

Recommendations

Info

Synthesis of Alkenyl Silanes Alkynes Silyl Alkynes Hydrogenation Hydrometallation Carbometallation Ring-Closing Metathesis Terminal Vinyl Silanes Aldehydes
Silyl Alkynes Preparation of Silyl Alkynes • Wide variety of commercially available chlorosilanes • Commercially available and readily prepared terminal alkynes • Double functionalisation from alkynyl Grignard reagent Hydro- and Carbometallation via 1-[M]-1-silyl alkene syn addition syn addition anti addition anti addition [M] = Alk 2 BH, DiBAl-H, i-BuMgBr/Cp 2 TiCl 2 , t-BuZrCp 2 Cl [M] = MeMgBr, (allyl)ZnBr, Me 2 AlCl/Cp 2 TiCl 2 Ley, S.V. Comprehensive Organic Functional Group Transformations Vol.2, 1 st Ed.; Cambridge University Press, 1995.
Page 1 and 2: Alkenyl Silanes - Synthesis and App
Page 3 and 4: Introduction SiR' 3 R Advantages of
Page 5 and 6: Alkynes - Hydrosilylation Terminal
Page 7 and 8: Alkynes - Hydrosilylation Terminal
Page 9 and 10: Alkynes - Hydrosilylation Internal
Page 11: Alkynes - (Carbonylative) Silylcarb
Page 15 and 16: Silyl Alkynes - Hydrometallation Hy
Page 17 and 18: Silyl Alkynes - Carbometallation Al
Page 19 and 20: Synthesis of Alkenyl Silanes Alkyne
Page 21 and 22: Terminal Vinyl Silanes - Heck Coupl
Page 23 and 24: Synthesis of Alkenyl Silanes Alkyne
Page 25 and 26: Aldehyes - Peterson-Type Olefinatio
Page 27 and 28: Carbon-Oxygen Bond Formations Epoxi
Page 29 and 30: Carbon-Oxygen Bond Formations Tamao
Page 31 and 32: Applications of Alkenyl Silanes Car
Page 33 and 34: Carbon-Carbon Bond Formations Hiyam
Page 35 and 36: Carbon-Carbon Bond Formations Hiyam
Page 37 and 38: Carbon-Carbon Bond Formations Other
Page 39 and 40: Carbon-Carbon Bond Formations Cu(I)
Page 41: Thank you!

Synthesis and Applications - The Anderson Research Group

Create successful ePaper yourself

Delete template?

Save as template?