Synthesis and Applications - The Anderson Research Group

More documents

Recommendations

Info

Synthesis of Alkenyl Silanes Alkynes Hydrosilylation Silylformylation (Carbonylative) Silylcarbocyclisation Silyl Alkynes Terminal Vinyl Silanes Aldehydes
Alkynes - Hydrosilylation Terminal Alkynes Platinum-based catalysts (Speier’s, H 2 (PtCl 6 ).6H 2 O and Karstedt’s) effect synhydrosilylation of terminal alkynes to provide trans-vinyl silanes exclusively. β-trans vinyl silanes β-trans β-cis α López and co-workers have demonstrated the tolerance of Karstedt’s catalyst to a wide variety of Si substituents in the synthesis of silyl dienes. • Improved reactivity and regioselectivity compared to H 2 (PtCl 6 ).xH 2 O • < 1 mol% loading For the synthesis of Karstedt’s catalyst: Chandra, G.; Lo, P.Y.; Hitchcock, P.B.; Lappert, M.F. Organomet. 1987, 6, 191-192. Montenegro, J.; Bergueiro, J.; Saá, C.; López, S. Org. Lett. 2009, 11, 141-144.
Page 1 and 2: Alkenyl Silanes - Synthesis and App
Page 3: Introduction SiR' 3 R Advantages of
Page 7 and 8: Alkynes - Hydrosilylation Terminal
Page 9 and 10: Alkynes - Hydrosilylation Internal
Page 11 and 12: Alkynes - (Carbonylative) Silylcarb
Page 13 and 14: Silyl Alkynes Preparation of Silyl
Page 15 and 16: Silyl Alkynes - Hydrometallation Hy
Page 17 and 18: Silyl Alkynes - Carbometallation Al
Page 19 and 20: Synthesis of Alkenyl Silanes Alkyne
Page 21 and 22: Terminal Vinyl Silanes - Heck Coupl
Page 23 and 24: Synthesis of Alkenyl Silanes Alkyne
Page 25 and 26: Aldehyes - Peterson-Type Olefinatio
Page 27 and 28: Carbon-Oxygen Bond Formations Epoxi
Page 29 and 30: Carbon-Oxygen Bond Formations Tamao
Page 31 and 32: Applications of Alkenyl Silanes Car
Page 33 and 34: Carbon-Carbon Bond Formations Hiyam
Page 35 and 36: Carbon-Carbon Bond Formations Hiyam
Page 37 and 38: Carbon-Carbon Bond Formations Other
Page 39 and 40: Carbon-Carbon Bond Formations Cu(I)
Page 41: Thank you!

Synthesis and Applications - The Anderson Research Group

You also want an ePaper? Increase the reach of your titles

Delete template?

Save as template?