Synthesis and Applications - The Anderson Research Group
Synthesis and Applications - The Anderson Research Group
Synthesis and Applications - The Anderson Research Group
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Alkynes - Hydrosilylation<br />
Terminal Alkynes<br />
β-cis vinyl silanes<br />
β-trans β-cis α<br />
Cl<br />
Cl Ru<br />
Ru Cl<br />
Cl<br />
Ruthenium-based catalysts mediate the anti-hydrosilylation of terminal alkynes.<br />
Regio- <strong>and</strong> stereoselectivities are influenced by Si substituents <strong>and</strong> the proximity<br />
of free hydroxyl groups.<br />
[RuCl 2 (p-cymene)] 2<br />
aka magic dust<br />
[RuCl 2 (p-cymene)] 2 catalyst: Chang, S.; Na, Y. Org. Lett. 2000, 2, 1887-1889.<br />
Grubbs 1 st generation catalyst: Maifield, S.V.; Tran, M.N.; Lee, D. Tetrahedron Lett. 2005, 46, 105-108.
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