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Transport Phenomena.pdf

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244 Chapter 8 Polymeric Liquids<br />

EXAMPLE 8.3-3<br />

Rework Example 3.6-3 for a power law fluid.<br />

Tangential Annular<br />

f<br />

SOLUTION<br />

r1<br />

,^4J Equations 3.6-20 and 3.6-22 remain unchanged for a non-Newtonian fluid, but in lieu of Eq.<br />

Fluid 4 ' 5<br />

3.6-21 we write the ^-component of the equation of motion in terms of the shear stress by<br />

using Table B.5:<br />

0= -\4-(r 2 r r0<br />

) (8.3-15)<br />

r 2<br />

dr<br />

For the postulated velocity profile, we get for the power law model (with the help of Table B.I)<br />

_ - ... d (<br />

( d he\\ n ~ l d ho<br />

(8.3-16)<br />

Combining Eqs. 8.3-15 and 16 we get<br />

(8.3-17)<br />

Integration gives<br />

(8.3-18)<br />

Dividing by r 2<br />

and taking the nth root gives a first-order differential equation for the angular<br />

velocity<br />

л / 71<br />

\ -i (C \\ln<br />

(8.3-19)<br />

dr\rj r\ r<br />

2 /<br />

This may be integrated with the boundary conditions in Eqs. 3.6-27 and 28 to give<br />

v e<br />

1 - ( K<br />

R/r) 2/n<br />

(8.3-20)<br />

2/п<br />

_<br />

The (z-component of the) torque needed<br />

Ц/<br />

on<br />

"<br />

the<br />

1<br />

outer<br />

- к<br />

cylinder to maintain the motion is then<br />

2TTRL<br />

• R<br />

(8.3-21)<br />

Combining Eqs. 8.3-20 and 21 then gives<br />

T 7<br />

=<br />

(2/n)<br />

(8.3-22)<br />

The Newtonian result can be recovered by setting n = 1 and m = /JL. Equation 8.3-22 can be used<br />

along with torque versus angular velocity data to determine the power law parameters m and n.<br />

§8.4 ELASTICITY AND THE LINEAR VISCOELASTIC MODELS<br />

Just after Eq. 1.2-3, in the discussion about generalizing Newton's "law of viscosity/' we<br />

specifically excluded time derivatives and time integrals in the construction of a linear<br />

expression for the stress tensor in terms of the velocity gradients. In this section, we

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