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Max-04-4<br />

School of Public Health, UC Berkeley<br />

<strong>Tracer</strong> <strong>Decay</strong> <strong>for</strong> <strong>Determ<strong>in</strong><strong>in</strong>g</strong> <strong>Kitchen</strong> <strong>Ventilation</strong> <strong>Rates</strong> <strong>in</strong> <strong>San</strong><br />

Lorenzo, Guatemala<br />

Shannon C. Cowl<strong>in</strong><br />

School of Public Health<br />

University of Cali<strong>for</strong>nia, Berkeley<br />

Maxwell Chair Student Projects (Max-04-4): Summer 2004<br />

Published April 2005<br />

Citation<br />

Cowl<strong>in</strong> SC, 2005, “<strong>Tracer</strong> <strong>Decay</strong> <strong>for</strong> <strong>Determ<strong>in</strong><strong>in</strong>g</strong> <strong>Kitchen</strong> <strong>Ventilation</strong> <strong>Rates</strong> <strong>in</strong> <strong>San</strong> Lorenzo,<br />

Guatemala,” Maxwell Student Projects, Max-04-4, EHS, School of Public Health, University of<br />

Cali<strong>for</strong>nia, Berkeley.<br />

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Max-04-4<br />

School of Public Health, UC Berkeley<br />

Acknowledgements<br />

Completion of this study relied heavily on the support of the field team members at MERTU <strong>in</strong><br />

<strong>San</strong> Lorenzo. I would particularly like to thank Anaite Diaz and Expedita Marroquín <strong>for</strong> their<br />

substantial contributions to make the sampl<strong>in</strong>g ef<strong>for</strong>t a success. Eduardo Canuz Castro, John<br />

McCracken, Lisa Thompson, Janet Diaz, and Gabrielle Mart<strong>in</strong>ez provided additional valuable<br />

support <strong>in</strong> <strong>San</strong> Lorenzo. I would also like to extend heartfelt thanks to Kirk Smith, who provided<br />

the access and opportunity, and The Brian and Jennifer Maxwell Endowed Chair <strong>in</strong> Public<br />

Health <strong>for</strong> fund<strong>in</strong>g the study. I would also like to thank William Nazaroff and Zohir Chowdhury<br />

<strong>for</strong> their <strong>in</strong>sights on ventilation and measurement techniques, Seema Bhangar <strong>for</strong> shar<strong>in</strong>g her<br />

experiences measur<strong>in</strong>g ventilation <strong>in</strong> India, and Asheena Khalakd<strong>in</strong>a <strong>for</strong> provid<strong>in</strong>g pre-departure<br />

support.<br />

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Max-04-4<br />

School of Public Health, UC Berkeley<br />

1. Introduction<br />

In homes burn<strong>in</strong>g solid fuels <strong>in</strong>doors as cook<strong>in</strong>g and heat<strong>in</strong>g sources, pollution can reach levels<br />

that exceed standards set to protect human health. Indoor pollutant concentrations <strong>in</strong> these<br />

homes are largely dom<strong>in</strong>ated by the rate at which emissions are released to the <strong>in</strong>door<br />

environment and the rate at which pollutants are removed by ventilation. As such, to understand<br />

the full range of potential of <strong>in</strong>terventions to reduce human exposure, both <strong>in</strong>door emissions and<br />

ventilation need to be considered along with other factors.<br />

One approach to reduc<strong>in</strong>g human exposure to combustion byproducts is to reduce emissions<br />

from the source. This can be accomplished by chang<strong>in</strong>g fuels, such as transition<strong>in</strong>g primary use<br />

from biomass to cleaner-burn<strong>in</strong>g gaseous fuels. Other ways to reduce emissions without<br />

chang<strong>in</strong>g fuel type are to modify the stove type to promote more effective combustion and/or add<br />

a chimney to emit the bulk of emissions to the outdoor environment.<br />

The strategies discussed above to reduce human exposure do not take <strong>in</strong>to account the character<br />

of home construction, specifically the rate at which polluted <strong>in</strong>door air is exchanged with lesspolluted<br />

outdoor air. In homes with relatively low <strong>in</strong>door emission rates, pollutants can still<br />

build to unsafe levels if the ventilation rates are also low. It follows that <strong>in</strong>creas<strong>in</strong>g the<br />

ventilation rates can potentially reduce <strong>in</strong>door exposure to harmful pollutants. This can be<br />

accomplished by open<strong>in</strong>g doors or w<strong>in</strong>dows while cook<strong>in</strong>g or by leav<strong>in</strong>g open eaves <strong>for</strong> the<br />

pollutants to escape. Un<strong>for</strong>tunately, this may not be feasible <strong>for</strong> many households due such<br />

factors as weather, security, privacy, and pest control. Nevertheless, it is desirable to understand<br />

the ventilation properties of a home when assess<strong>in</strong>g human exposure.<br />

This study seeks to test the appropriateness of us<strong>in</strong>g a tracer decay method of measur<strong>in</strong>g<br />

ventilation <strong>in</strong> a rural develop<strong>in</strong>g-world sett<strong>in</strong>g. This study took place <strong>in</strong> villages near <strong>San</strong><br />

Lorenzo, Guatemala, the site of a large, randomized stove-<strong>in</strong>tervention trial<br />

(http://ehs.sph.berkeley.edu/guat/page.aspid=1 ). The participants <strong>in</strong> this study were a subset of<br />

those participat<strong>in</strong>g <strong>in</strong> the randomized trial. Measurements were made <strong>in</strong> kitchens conta<strong>in</strong><strong>in</strong>g<br />

improved plancha woodstoves, which vents most of the cookfire smoke outdoors through a<br />

chimney. These had been given to the households on a random basis to replace the open<br />

(unvented) firewood stoves traditionally used <strong>in</strong> the region.<br />

II. Description of Method<br />

The tracer decay method assumes the environment be<strong>in</strong>g studied is well approximated by a wellmixed<br />

box model. The method <strong>in</strong>volves releas<strong>in</strong>g a conserved pollutant at a known emission<br />

rate and observ<strong>in</strong>g the concentration over time.<br />

Choice of tracer gas<br />

To be appropriate <strong>for</strong> this method, the pollutant must not react to <strong>for</strong>m secondary pollutants,<br />

deposit on surfaces, or be removed <strong>in</strong> any manner other than removal by ventilation. In this<br />

study, the tracer pollutant used was carbon monoxide (CO), which meets these criteria, and,<br />

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School of Public Health, UC Berkeley<br />

importantly, is easily and cheaply produced <strong>in</strong> quantity by burn<strong>in</strong>g wood or other simple solid<br />

fuels.<br />

2. Well-mixed box model with <strong>in</strong>door emission source<br />

In <strong>in</strong>door environments with <strong>in</strong>door combustion sources, the concentration of pollutants can be<br />

def<strong>in</strong>ed by employ<strong>in</strong>g mass conservation laws. For a pollutant that does not react with surfaces<br />

or other airborne species, this description is simplified. Figure 1 presents a well-mixed box<br />

model of an <strong>in</strong>door environment with non-react<strong>in</strong>g pollutant contributions from outside air and<br />

<strong>in</strong>door emissions. By def<strong>in</strong>ition, pollutant concentrations are equal <strong>in</strong> all air parcels with<strong>in</strong> this<br />

well-mixed box.<br />

Figure 1. Well-mixed box model of an <strong>in</strong>door environment with an <strong>in</strong>door<br />

emission source and pollutant contribution and removal by ventilation.<br />

C <strong>in</strong> (mass volume -1 )<br />

V (volume)<br />

Q*C out<br />

(mass time -1 )<br />

Q*C <strong>in</strong><br />

(mass time -1 )<br />

E (mass time -1 )<br />

The rate of change <strong>in</strong> pollutant mass <strong>in</strong> the <strong>in</strong>door environment presented <strong>in</strong> Figure 1 is described<br />

by (1), where C <strong>in</strong> and C out are the concentrations <strong>in</strong> the <strong>in</strong>door and outdoor air (mass volume -1 ), E<br />

is the mass emission rate from <strong>in</strong>door sources (mass time -1 ), V is the volume of the <strong>in</strong>door<br />

environment (volume), and Q is the ventilation rate (volume time -1 ).<br />

d(<br />

C<strong>in</strong>V<br />

)<br />

= E + CoutQ<br />

− C<strong>in</strong>Q<br />

(1)<br />

dt<br />

Assum<strong>in</strong>g that <strong>in</strong>door concentrations are much greater than outdoor concentrations (C <strong>in</strong> >> C out )<br />

<strong>in</strong> the presence of an <strong>in</strong>door source, the quantity (C out -C <strong>in</strong> ) is well approximated by (-C <strong>in</strong> ).<br />

Apply<strong>in</strong>g this assumption and divid<strong>in</strong>g through by V yields (2), which describes the time rate of<br />

change <strong>in</strong> concentration.<br />

dC<strong>in</strong><br />

E Q<br />

= − C<strong>in</strong><br />

(2)<br />

dt V V<br />

In the absence of emissions, (2) simplifies to (3) where all pollutant losses from the <strong>in</strong>door<br />

environment are due to removal by ventilation.<br />

dC<strong>in</strong><br />

Q<br />

= − C<strong>in</strong><br />

(3)<br />

dt V<br />

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School of Public Health, UC Berkeley<br />

If Q and V are constant, (3) can be <strong>in</strong>tegrated from time t 0 = 0 to time t * to obta<strong>in</strong> an equation <strong>for</strong><br />

the <strong>in</strong>door concentration at time t * . This solution is shown <strong>in</strong> (4), where C 0 is the concentration<br />

at time t 0 .<br />

* ⎛ Q ⎞<br />

( ) = ⎜ −<br />

*<br />

C <strong>in</strong><br />

t C0<br />

exp t ⎟ (4)<br />

⎝ V ⎠<br />

The air exchange rate, often reported as air changes per hour (ACH), is the quantity (Q/V) and<br />

has the units of <strong>in</strong>verse time. If the t * and the <strong>in</strong>itial and f<strong>in</strong>al concentrations are known, the<br />

ventilation rate, <strong>in</strong> terms of ACH, can be calculated accord<strong>in</strong>g to (5).<br />

*<br />

V ln[ C0 ] − ln[ C( t )]<br />

ACH = =<br />

(5)<br />

*<br />

Q t<br />

3. Experimental Design<br />

At time of enrollment <strong>in</strong> the larger stove <strong>in</strong>tervention trial, all homes were assigned to a<br />

qualitative ventilation category based on observed home characteristics, such as construction<br />

type, open or closed eaves, and number of w<strong>in</strong>dows. The ventilation categories used were<br />

abierto, parcialmente, or cerrado (open, partially open, or closed). The project field office <strong>in</strong><br />

<strong>San</strong> Lorenzo selected potential homes <strong>for</strong> this study. Field team members visited the homes to<br />

assess will<strong>in</strong>gness to participate and to ensure that the previously assigned ventilation<br />

classifications were still applicable. The f<strong>in</strong>al study size <strong>in</strong>volved two homes from each<br />

ventilation category, and all participat<strong>in</strong>g homes had planchas. As planchas were supplied to<br />

households on a random basis, however, other household characteristics should reflect those of<br />

the community as a whole. Each home was visited on one afternoon and one morn<strong>in</strong>g, and two<br />

experiments were conducted at each visit.<br />

Equipment used <strong>in</strong>cluded 4 HOBO CO monitors (Onset Corporation, Bourne, MA), 1 Dräger CO<br />

monitor (Drägerwerk AG, Lübeck, Germany), one computer, two fire-resistant buckets, wood,<br />

and a self-support<strong>in</strong>g post with nails protrud<strong>in</strong>g at heights of 0.5, 1, 1.5, and 2 meters from the<br />

base. The HOBO monitors were launched <strong>in</strong> the morn<strong>in</strong>g prior to travel to the homes accord<strong>in</strong>g<br />

to manufacturer <strong>in</strong>structions and set to collect CO concentrations at 1-m<strong>in</strong>ute <strong>in</strong>tervals. After the<br />

first few days of experiments, the collection <strong>in</strong>terval was shortened to 15-seconds. . Upon<br />

arrival at the home, all wood, coal, and ash were removed from <strong>in</strong>side the plancha, put <strong>in</strong> one of<br />

the fire-resistant buckets, and placed outside at downw<strong>in</strong>d location. In the other fire-resistant<br />

bucket, wood was ignited to create an emission source that could easily be removed once the<br />

<strong>in</strong>door CO levels were sufficiently high. The bucket was placed at the end of the plancha on the<br />

ground.<br />

While the emissions were be<strong>in</strong>g allowed to accumulate <strong>in</strong> the kitchen, the HOBO monitors were<br />

attached to the post. The post was positioned at a lateral distance of 0.5 m from the emission<br />

source, as this is approximately the distance a cook would stand from the centerl<strong>in</strong>e of the<br />

plancha. The monitor heights of 0.5 and 1.5 meters were chosen to approximate squatt<strong>in</strong>g and<br />

stand<strong>in</strong>g breath<strong>in</strong>g heights, respectively. The two monitor<strong>in</strong>g heights of 1 and 2 meters were<br />

<strong>in</strong>cluded to collect additional <strong>in</strong><strong>for</strong>mation that might allow <strong>for</strong> better understand<strong>in</strong>g of airflow <strong>in</strong><br />

the kitchen.<br />

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School of Public Health, UC Berkeley<br />

The Drager has screen that displays real-time CO concentrations. This monitor was placed<br />

approximately 1 meter from the emission source and 0.5 meters from the post. Once the<br />

emissions had been allowed to accumulate <strong>in</strong> the kitchen <strong>for</strong> approximately 30 m<strong>in</strong>utes, the<br />

Drager output was monitored until the <strong>in</strong>door CO concentration exceeded 30 ppm. At that time,<br />

the emission source was removed from the kitchen and placed at a downw<strong>in</strong>d location, and the<br />

start time of the experiment was noted. After the second experiment was complete, the wood<br />

was returned to the plancha and the data were downloaded from the monitors <strong>for</strong> analysis.<br />

4. Results<br />

For each experiment, the air exchange rates were calculated us<strong>in</strong>g 10 consecutive CO<br />

concentration measurements taken at evenly spaced time <strong>in</strong>tervals. The natural log of each CO<br />

concentration was regressed aga<strong>in</strong>st time, and the negative of the slope of this l<strong>in</strong>e is the<br />

computed air exchange rate. These values were computed <strong>for</strong> each monitor height <strong>for</strong> all<br />

experiments.<br />

Table 1 shows the mean of computed air exchange rates <strong>for</strong> each home and monitor height. Air<br />

exchange rates from the <strong>in</strong>dividual experiments are attached as Appendix A. Table 2 shows air<br />

exchange rates by household ventilation classification where the values reported are the average<br />

of all experiments and monitor heights.<br />

Table 1. Air exchange rates calculated us<strong>in</strong>g tracer decay <strong>in</strong> a well-mixed box model. ACH values are<br />

averages over all experiments and the values <strong>in</strong> parentheses are the coefficients of variation (SD/mean).<br />

ACH [hour -1 ] (COV)<br />

Monitor Height (m)<br />

<strong>Ventilation</strong> Classification and<br />

House Number 0.5 1 1.5 2<br />

Cerrado<br />

Parcialmente<br />

Casa 90 18 (0.55) 15 (0.11) 16 (0.12) 18 (0.25)<br />

Casa 328 11 (.50) 13 (0.09) 15 (0.10) 21 (0.11)<br />

Casa 247 18 (0.11) 17 (0.34) 22 (0.40) 20 (0.91)<br />

Casa 237 21 (0.50) * 16 (0.23) 15 (0.16) 17 (0.31)<br />

Abierto<br />

Casa 29 21 (0.27) 26 (0.25) 31 (0.24) 38 (0.37)<br />

Casa 37 18 (0.39) 26 (0.17) 41 (0.53) 50 (0.80)<br />

*For Casa 237, monitor height 0.5 m, the reported value is the mean of<br />

calculations from three experiments due to equipment failure. All other<br />

reported values are the mean of calculations from four experiments.<br />

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School of Public Health, UC Berkeley<br />

Table 2. Mean air exchange rates by household ventilation classification.<br />

Averages are over all experiments and monitor heights.<br />

6. Discussion<br />

Household <strong>Ventilation</strong><br />

Classification<br />

ACH (COV)<br />

Abierto 29<br />

Abierto 34<br />

Parcialmente 17<br />

Parcialmente 19<br />

Cerrado 17<br />

Cerrado 15<br />

The quality of construction varied significantly between the homes, but all kitchens had open<br />

eaves. The cerrado homes tended to have more solidly constructed walls with no visible gaps,<br />

the abierto homes had significant fractions of the walls miss<strong>in</strong>g, and the walls of the<br />

parcialmente homes were between these two extremes. Though CO is a colorless and odorless<br />

gas, the wood fire also released significant amounts of particulate matter (PM), which allowed<br />

<strong>for</strong> visualization of plume dispersion. In all homes, the bulk of the plume was observed to rise<br />

and exit the home through the open eaves. The bulk plume removal via the eaves made the task<br />

of accumulat<strong>in</strong>g CO <strong>in</strong> the kitchen difficult, and it also resulted <strong>in</strong> the CO levels dropp<strong>in</strong>g below<br />

the HOBO limit of detection <strong>in</strong> under 10 m<strong>in</strong>utes, the <strong>in</strong>itially planned sampl<strong>in</strong>g duration. To<br />

ensure 10 data output read<strong>in</strong>gs <strong>for</strong> each experiment, the data-logg<strong>in</strong>g <strong>in</strong>terval was shortened to<br />

15 seconds.<br />

Observable uneven distribution of PM <strong>in</strong> the kitchen suggested that the air was not well mixed.<br />

This observation is well supported by the differences <strong>in</strong> mean air exchange rates at various<br />

monitor heights shown <strong>in</strong> Table 1. For <strong>in</strong>dividual experiments, the difference <strong>in</strong> calculated air<br />

exchange rate between adjacent monitors ranged from 0 to 56 ACH, and the average difference<br />

was 6.6 ACH.<br />

Observations and measured data support the fact that the air <strong>in</strong> the kitchens was not well mixed,<br />

which <strong>in</strong>dicates that the tracer method is <strong>in</strong>appropriate <strong>for</strong> use <strong>in</strong> homes of this and similar<br />

construction. It may be appropriate, however, to look at these measurements as effective local<br />

decay rates <strong>for</strong> air parcels at that location. This value would <strong>in</strong>clude the sum of diffuse and<br />

advective transport <strong>in</strong>to and out of that air parcel from all adjacent air parcels. Additionally, the<br />

exchange rates calculated by this method did have a tendency to follow the qualitative ventilation<br />

classification of homes, as is shown <strong>in</strong> Table 2. Though the method is <strong>in</strong>appropriate <strong>for</strong> precise<br />

quantification of ventilation <strong>in</strong> these not well-mixed environments, it may be a useful way of<br />

assess<strong>in</strong>g relative importance of ventilation <strong>in</strong> homes of this construction.<br />

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School of Public Health, UC Berkeley<br />

Appendix A: Air exchange rates <strong>for</strong> all experiments and all homes<br />

Casa 29: ACH (hour -1 )<br />

Monitor Height (m)<br />

Experiment 0.5 1 1.5 2<br />

1 26 27 29 32<br />

2 21 16 23 30<br />

3 23 28 41 59<br />

4 13 31 31 31<br />

Casa 37: ACH (hour -1 )<br />

Monitor Height (m)<br />

Experiment 0.5 1 1.5 2<br />

1 20 26 28 27<br />

2 13 22 44 101<br />

3 13 32 22 11<br />

4 27 24 71 64<br />

Casa 90: ACH (hour -1 )<br />

Monitor Height (m)<br />

Experiment 0.5 1 1.5 2<br />

1 29 15 14 13<br />

2 24 13 14 14<br />

3 9 16 17 20<br />

4 10 16 18 22<br />

Casa 237: ACH (hour -1 )<br />

Monitor Ht<br />

Experiment 0.5 1 1.5 2<br />

1 14 14 12<br />

2 9 12 13 13<br />

3 26 20 17 22<br />

4 28 19 18 22<br />

Casa 247: ACH (hour -1 )<br />

Monitor Ht<br />

Experiment 0.5 1 1.5 2<br />

1 16 13 18 9<br />

2 16 12 17 7<br />

3 20 20 18 17<br />

4 19 24 35 46<br />

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School of Public Health, UC Berkeley<br />

Casa 328: ACH (hour -1 )<br />

Monitor Ht<br />

Experiment 0.5 1 1.5 2<br />

1 11 12 16 22<br />

2 17 13 15 18<br />

3 4 12 13 24<br />

4 14 14 14 21<br />

9

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