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Top 5 (High Impact Factor)<br />

Mercury-ion optical sensors<br />

Trends in analytical chemistry,vol.38,2012<br />

Sherif A. El-Safty, 2, M.A. Shenashen1<br />

The toxicity of mercury (Hg) to humans,<br />

including damage to the nervous system, is well<br />

known. Hg cannot be degraded into non-toxic<br />

compounds or other elements. It is released<br />

mainly through mining, industries, and fossil fuel<br />

combustion. Anthropogenic and natural<br />

activities, such as volcanoes, transform<br />

elemental Hg (Hg0) into its ionic form [Hg(II)],<br />

which bioaccumulates in biota and is<br />

biomagnified in the food chain, notably in<br />

aquatic environments.<br />

With regard to proximal sensing, we consider<br />

controlled assessment processes that involve<br />

the evaluation of intrinsic properties (e.g., signal<br />

change, long-term stability, adsorption<br />

efficiency, extraordinary sensitivity, selectivity,<br />

and reusability).<br />

This study provides evidence that miniaturized<br />

mesosensor strips can revolutionize consumer<br />

and industrial markets with the introduction of<br />

ion-sensor strips.<br />

This critical report aims to control Hg(II)-ion<br />

toxicity through risk assessment, recognition,<br />

and removal via high-level waste management.<br />

We first discuss successful and up-to-date<br />

developments in different techniques, designs<br />

and studies that are potentially useful in<br />

enhancing the effectiveness of control of Hg(II)-<br />

ion toxicity.<br />

The key to design optical nanosensors is to<br />

construct chromophore and fluorophore<br />

receptors as nanoscale platform scavengers<br />

with different functional characteristics (e.g.,<br />

density, accessibility, and intrinsic mobility),<br />

which allow for easy, reliable signaling in<br />

continuous monitoring modes.<br />

We highlight a Technique that depends on the<br />

use of engineering mesocage materials that<br />

have multidirectional cavities and microsized,<br />

particle-like monoliths to control the<br />

adsorption/detection of toxic metal ions,<br />

especially Hg(II) ions.<br />

EPRI Annual Report 2012 63

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