Material Safety Data Sheet - Brillux
Material Safety Data Sheet - Brillux
Material Safety Data Sheet - Brillux
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<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente A)<br />
Floortec 2C Epoxy Primer LF 832 (Component A)<br />
Revision : 25.06.2013 Version (Revision) : 8.0.0 (7.0.0)<br />
Print date : 25.06.2013<br />
1. Identification of the substance/mixture and of the company/undertaking<br />
1.1 Product identifier<br />
Floortec 2K-Epoxi-Grund LF 832 (Komponente A)<br />
Floortec 2C Epoxy Primer LF 832 (Component A)<br />
1.2 Relevant identified uses of the substance or mixture and uses advised against<br />
Coating compound / Surface coating / paint.<br />
There are no information about relevant identified uses of the product, which are advised against.<br />
1.3 Details of the supplier of the safety data sheet<br />
Manufacturer/Supplier :<br />
<strong>Brillux</strong> GmbH & Co KG<br />
www.brillux.de<br />
Street/P.O.Box : Weseler Straße 401<br />
Country code/Postal<br />
D - 48163 Münster<br />
code/Town/City :<br />
Telephone : +49 (0)251-7188-0<br />
Telefax : +49 (0)251-7188-280<br />
Contact :<br />
1.4 Emergency telephone number<br />
Outside the business hours:<br />
(Giftnotruf Berlin, consultation in the german and english language)<br />
Telephone: +49 (0)30 30686 790.<br />
2. Hazards identification<br />
E-Mail-Adresse der sachkundigen Person für Sicherheitsdatenblätter:<br />
sdb@brillux.de.<br />
2.1 Classification of the substance or mixture<br />
Directive 67/548/EEC or 1999/45/EC<br />
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · May cause sensitization by skin<br />
contact. · Irritating to eyes and skin.<br />
N ; R 51/53 · R 43 · Xi ; R 36/38<br />
Regulation (EC) No 1272/2008 (GHS)<br />
Causes skin irritation. · May cause an allergic skin reaction. · Causes serious eye irritation. · Toxic to aquatic life with long lasting<br />
effects.<br />
Eye Irrit. 2 ; H319 · Aquatic Chronic 2 ; H411 · Skin Irrit. 2 ; H315 · Skin Sens. 1 ; H317<br />
2.2 Label elements<br />
Directive 67/548/EEC or 1999/45/EC<br />
Danger symbol and danger designation<br />
Xi ; Irritant<br />
N ; Dangerous for the environment<br />
Hazard-determining components of labelling<br />
REACTION PRODUCT: BISPHENOL A-(EPICHLORHYDRIN), EPOXY RESIN (NUMBER AVERAGE MOLECULAR WEIGHT
<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente A)<br />
Floortec 2C Epoxy Primer LF 832 (Component A)<br />
Revision : 25.06.2013 Version (Revision) : 8.0.0 (7.0.0)<br />
Print date : 25.06.2013<br />
C12-C14-ALKYLGLYCIDYLETHER ; CAS-No. : 68609-97-2<br />
R-phrases<br />
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.<br />
43 May cause sensitization by skin contact.<br />
36/38 Irritating to eyes and skin.<br />
S-phrases<br />
28.1 After contact with skin, wash immediately with plenty of water.<br />
61 Avoid release to the environment. Refer to special instructions / safety data sheet.<br />
2 Keep out of the reach of children.<br />
37/39 Wear suitable gloves and eye/face protection.<br />
46 If swallowed, seek medical advice immediately and show this container or label.<br />
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.<br />
23.3 Do not breathe vapour.<br />
24 Avoid contact with skin.<br />
Special designation for certain preparations<br />
92 Contains epoxy constituents. See information supplied by the manufacturer.<br />
Regulation (EC) No 1272/2008 (GHS)<br />
Hazard pictograms<br />
Environment (GHS09) · Exclamation mark (GHS07)<br />
Signal word<br />
Warning<br />
Hazard-determining components of labelling<br />
REACTION PRODUCT: BISPHENOL A-(EPICHLORHYDRIN), EPOXY RESIN (NUMBER AVERAGE MOLECULAR WEIGHT
<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente A)<br />
Floortec 2C Epoxy Primer LF 832 (Component A)<br />
Revision : 25.06.2013 Version (Revision) : 8.0.0 (7.0.0)<br />
Print date : 25.06.2013<br />
3.2 Mixtures<br />
Chemical characterization<br />
Paint based on epoxy resin.<br />
Hazardous components<br />
REACTION PRODUCT: BISPHENOL A-(EPICHLORHYDRIN), EPOXY RESIN (NUMBER AVERAGE MOLECULAR WEIGHT
<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente A)<br />
Floortec 2C Epoxy Primer LF 832 (Component A)<br />
Revision : 25.06.2013 Version (Revision) : 8.0.0 (7.0.0)<br />
Print date : 25.06.2013<br />
Possible symptoms: Irritation of the skin and the eyes. Allergic symptoms.<br />
4.3 Indication of any immediate medical attention and special treatment needed<br />
None.<br />
5. Firefighting measures<br />
5.1 Extinguishing media<br />
Suitable extinguishing media<br />
Adapt extinguishing measures to suit the environment.<br />
5.2 Special hazards arising from the substance or mixture<br />
None.<br />
5.3 Advice for firefighters<br />
No special measures required.<br />
5.4 Additional information<br />
Cool endangered containers with water in case of fire.<br />
6. Accidental release measures<br />
6.1 Personal precautions, protective equipment and emergency procedures<br />
Keep no protective persons away, personal should wear protective clothings.<br />
6.2 Environmental precautions<br />
Do not empty into drains. If the product contaminates lakes, rivers or sewages, inform appropriate authorities in accordance with<br />
local regulations.<br />
6.3 Methods and material for containment and cleaning up<br />
Absorb with liquid-binding material (sand, diatomite, acid-binders, universal binders, sawdust). Dispose of contaminated material as<br />
waste according to section 13.<br />
Phrase P391: Collect spillage.<br />
6.4 Reference to other sections<br />
None.<br />
6.5 Additional information<br />
You find information about the safety equipment of persons in the section 8, information about the refuse disposal in section 13.<br />
7. Handling and storage<br />
7.1 Precautions for safe handling<br />
Information for safe handling<br />
Ensure a good ventilation in room and working area. For personal protection see Section 8.<br />
Immediately change the protective clothing which are contaminated or damaged and wash the skin away with water. By mixing<br />
the components slowly, the container have to cover the product container to reduce the splashing danger. Working carefully and<br />
slowly when decanting the mixture in another container.<br />
Phrase P102: Keep out of reach of children.<br />
Phrase P103: Read label before use.<br />
Phrase P262: Do not get in eyes, on skin, or on clothing.<br />
Information about protection against explosions and fires<br />
No special precautionary measure necessary.<br />
7.2 Conditions for safe storage, including any incompatibilities<br />
Requirements to be met by storerooms and containers<br />
No particular measures required.<br />
Phrase P405: Store locked up.<br />
Information about separation of incompatible products<br />
Page : 4 / 9<br />
( EN / D )
<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente A)<br />
Floortec 2C Epoxy Primer LF 832 (Component A)<br />
Revision : 25.06.2013 Version (Revision) : 8.0.0 (7.0.0)<br />
Print date : 25.06.2013<br />
Store away from foodstuffs.<br />
Further information about storage conditions<br />
Store containers tightly closed in a cool well ventilated place. Keep only in the original container.<br />
Storage class : 10<br />
7.3 Specific end use(s)<br />
Coating material as a primer in Floortec PUR Coating System for exterior use and, under Floortec 2C Epoxy Thick Layer LF 834, for<br />
interior use. In combination with Floortec Quartz Sand 1526 also usable as scratch, shrink hole and compensation filler as well as<br />
flow coating. Can also be used for gluing suitable groove profiles or for manual production of grooves.<br />
8. Exposure controls/personal protection<br />
8.1 Control parameters<br />
None.<br />
8.2 Exposure controls<br />
Personal protective equipment<br />
General protective and hygiene measures<br />
Keep away from food, drink and animal feeding stuff. Immediately remove all contaminated clothing. Wash hands before breaks<br />
and after work. Avoid contact with eyes and skin.<br />
Respiratory protection<br />
Use suitable respiratory protective device in case of insufficient ventilation. When workers are facing concentrations above the<br />
exposure limit they must use appropriate certified respirators. Half mask with combination filter, class A1P2 minimum, or<br />
breathing mask with outer air supply.<br />
Do not inhale the vapour.<br />
Hand protection<br />
Use protective gloves based on nitrile-rubber. Following notes of the gloves-manufacturer. The choice of a suitable glove is<br />
dependent on the material and other quality characteristics which are different depending on manufacturer. Because the product<br />
is a preparation of several substances, the resistance of the glove materials have to be checked before use. The exact break<br />
trough time has to be found out by the manufactor of the protective gloves and has to be observed.<br />
Eye protection<br />
Use tightly fitting safety glasses.<br />
Body protection<br />
By working with epoxy resins a fitting protective clothing should be worn. To these clothes an additional protective clothing can<br />
be necessary, e. g. aprons, sleeve schooners, overcoats.<br />
By working with the product uncovered skin places have to be avoided also at warm weather.<br />
Additional information about engineering measures<br />
Observe data available of section 7. Provide adequate ventilation. Where reasonably practicable this shoud be achieved by the use<br />
of local exhaust ventilation and good general extraction.<br />
9. Physical and chemical properties<br />
9.1 Information on basic physical and chemical properties<br />
Image<br />
Form :<br />
Colour :<br />
Odour :<br />
Relevant safety data<br />
Liquid.<br />
According to product identification.<br />
characteristic<br />
Boiling temperature/boiling<br />
range:<br />
( 1013 hPa ) 200 °C<br />
Flash point: > 100 °C<br />
Ignition temperature: 184 °C<br />
Lower explosion limit: 1,3 Vol-%<br />
Page : 5 / 9<br />
( EN / D )
<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente A)<br />
Floortec 2C Epoxy Primer LF 832 (Component A)<br />
Revision : 25.06.2013 Version (Revision) : 8.0.0 (7.0.0)<br />
Print date : 25.06.2013<br />
Upper explosion limit: 13 Vol-%<br />
Vapour pressure: ( 20 °C ) 0,1 hPa<br />
Density: ( 20 °C ) ca. 1,14 g/cm 3<br />
Water solubility: ( 20 °C ) Not or littly mixable.<br />
VOC value :<br />
max.<br />
200 g/l<br />
9.2 Other information<br />
The mentioned VOC value refers to the mixture of the product, incl. harder, ready for use.<br />
10. Stability and reactivity<br />
10.1 Reactivity<br />
No dangerous reaction known. Particularly larger quantities of the 2C-Mixture material could get hot by the progressive polyaddition,<br />
if the mixture would not using. Carbon monoxide, carbon dioxide and nitric oxides could arise.<br />
10.2 Chemical stability<br />
Stable under recommended storage and handling conditions (see section 7).<br />
10.3 Possibility of hazardous reactions<br />
No dangerous reactions are known if stored and handled the product correctly.<br />
10.4 Conditions to avoid<br />
Keep away from frost, heat and direct sunlight.<br />
10.5 Incompatible materials<br />
No dangerous reaction known.<br />
10.6 Hazardous decomposition products<br />
No dangerous decomposition product are known if stored and handled correctly.<br />
11. Toxicological information<br />
11.1 Information on toxicological effects<br />
Acute toxicity:<br />
- Acute oral toxicity: No data available;<br />
- Acute dermal toxicity: No data available;<br />
- Acute inhalation toxicity: No data available.<br />
Primary irritant effect<br />
Reizwirkung:<br />
- Bei Hautkontakt: Reizt die Haut.<br />
- Bei Augenkontakt: Reizt dien Augen.<br />
Sensitization<br />
The product contains sensitizing substances, which may produce an allergic reaction (see section 2 and 3).<br />
Cancerogenic and mutagenic effects, risks to reproduction<br />
The product is not classified as human germ cell mutagenic, carcinogenic or human reproductive toxic (CMR effects).<br />
11.2 Experience on practice<br />
This product is unlikely to harm health, given normal and proper handling and hygenic precautions.<br />
11.3 Additional toxicological information<br />
The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for the<br />
Preparations as issued in the latest version: Irritant.<br />
12. Ecological information<br />
12.1 Toxicity<br />
Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.<br />
Other information<br />
Page : 6 / 9<br />
( EN / D )
<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente A)<br />
Floortec 2C Epoxy Primer LF 832 (Component A)<br />
Revision : 25.06.2013 Version (Revision) : 8.0.0 (7.0.0)<br />
Print date : 25.06.2013<br />
Remark: Toxic for fishes.<br />
12.2 Persistence and degradability<br />
These are not data availably about the potential of the product concerning his persistency and degradability.<br />
12.3 Bioaccumulative potential<br />
These are not data availably about the bio accumulation potential of the product. No information about the individual components is<br />
available either.<br />
12.4 Mobility in soil<br />
These are not datas availably about the potential of the product concerning his mobility in the ground.<br />
Due to the low water solubility of the product a bioavailability is not probable.<br />
A penetrating into soil, waters and sewage system should be prevented.<br />
12.5 Results of PBT and vPvB assessment<br />
This product does not contain any relevant substances which were classified as a PBT or vPvB-substance.<br />
12.6 Other adverse effects<br />
There are no data available on the product itself.<br />
12.7 Additional information<br />
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water. Avoid exposing into ground, waterways and<br />
drainage.<br />
Danger of drinking water if even small quantities leak into soil. Harmful to aquatic organismen.<br />
13. Disposal considerations<br />
13.1 Waste treatment methods<br />
Recommendation<br />
Can be taken to a suitable incineration centre in oberservance of local regulations. Do not dispose together with household<br />
garbage. Do not allow product to reach sewage system.<br />
Waste key<br />
Disposal-definition No. (AVV-Code): 08 01 11* Paint and varnish waste which contains organic solvents or other dangerous<br />
substances.<br />
Contaminated packaging<br />
Recommendation<br />
Contaminated packaging must be emptied of all residues and, following appropriate cleaning, may be sent to a recycling plant.<br />
Uncleaned packaging must be disposed of in the same manner as the medium.<br />
14. Transport information<br />
14.1 UN number<br />
3082<br />
14.2 UN proper shipping name<br />
ADR/RID<br />
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( EPOXIDE RESIN )<br />
IMDG-Code<br />
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( EPOXIDE RESIN )<br />
ICAO-TI / IATA-DGR<br />
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( EPOXIDE RESIN )<br />
14.3 Transport hazard class(es)<br />
ADR/RID<br />
Class : 9<br />
Classification-Code :<br />
M6<br />
Kemlercode : 90<br />
Tunnel restriction code :<br />
E<br />
Special provisions : LQ 7<br />
Label :<br />
9 / N<br />
Page : 7 / 9<br />
( EN / D )
<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente A)<br />
Floortec 2C Epoxy Primer LF 832 (Component A)<br />
Revision : 25.06.2013 Version (Revision) : 8.0.0 (7.0.0)<br />
Print date : 25.06.2013<br />
IMDG-Code<br />
Class : 9<br />
EmS number :<br />
F-A / S-F<br />
Label :<br />
9 / N<br />
ICAO-TI / IATA-DGR<br />
Class : 9<br />
Label :<br />
9 / N<br />
14.4 Packing group<br />
III<br />
14.5 Environmental hazards<br />
ADR/RID : N<br />
IMDG-Code : P<br />
ICAO-TI / IATA-DGR : N<br />
14.6 Special precautions for user<br />
None.<br />
15. Regulatory information<br />
<strong>Safety</strong>, health and environmental regulations/legislation specific for the substance or<br />
15.1<br />
mixture<br />
National regulatory information<br />
Regulation on safety management (BetrSichV)<br />
No flammable liquid according to BetrSichV. VbF-class (till 31.12.2002): The product is not subject to the ordinance.<br />
Water pollution classification<br />
Class : 2 according Self classification<br />
Other regulations<br />
The product is not classified as a solid substance according to the criteria of the Penetrometer test (ADR, part 2, section 2.3.4)<br />
and also fulfils not the criteria for solid substances according to the TRwS 779 number 2.1.1.<br />
International regulatory information<br />
In accordance to the EU guideline 2004/42/EC :<br />
Product sub-category and VOC limiting values in accordance with appendix II, letter A of the guideline:<br />
Category j, type Lb;<br />
VOC limiting value of the category for 2010: 500 g/l.<br />
This product contains max. 200 g/l VOC (preparation ready for use).<br />
15.2 Chemical safety assessment<br />
A chemical safety assessments was not carried out.<br />
16. Other information<br />
Further information<br />
Product code in accordance with GISBAU (hazardous materials information system of the German professional associations of the<br />
building and construction industry) for epoxy resin coating cloths (GISCODE): RE 1.<br />
R-Phrases of components<br />
20/22 Harmful by inhalation and if swallowed.<br />
21 Harmful in contact with skin.<br />
36/38 Irritating to eyes and skin.<br />
38 Irritating to skin.<br />
43 May cause sensitization by skin contact.<br />
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.<br />
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.<br />
GHS Hazard statements of components<br />
H302<br />
Harmful if swallowed.<br />
Page : 8 / 9<br />
( EN / D )
<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente A)<br />
Floortec 2C Epoxy Primer LF 832 (Component A)<br />
Revision : 25.06.2013 Version (Revision) : 8.0.0 (7.0.0)<br />
Print date : 25.06.2013<br />
H312<br />
H315<br />
H317<br />
H319<br />
H332<br />
H411<br />
H412<br />
Harmful in contact with skin.<br />
Causes skin irritation.<br />
May cause an allergic skin reaction.<br />
Causes serious eye irritation.<br />
Harmful if inhaled.<br />
Toxic to aquatic life with long lasting effects.<br />
Harmful to aquatic life with long lasting effects.<br />
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall<br />
not establish a legally valid contractual relationship.<br />
Page : 9 / 9<br />
( EN / D )
<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente B)<br />
Floortec 2C Epoxy Primer LF 832 (Component B)<br />
Revision : 01.07.2013 Version (Revision) : 10.0.0 (9.0.0)<br />
Print date : 01.07.2013<br />
1. Identification of the substance/mixture and of the company/undertaking<br />
1.1 Product identifier<br />
Floortec 2K-Epoxi-Grund LF 832 (Komponente B)<br />
Floortec 2C Epoxy Primer LF 832 (Component B)<br />
1.2 Relevant identified uses of the substance or mixture and uses advised against<br />
Coating compound / Surface coating / paint.<br />
There are no information about relevant identified uses of the product, which are advised against.<br />
1.3 Details of the supplier of the safety data sheet<br />
Manufacturer/Supplier :<br />
<strong>Brillux</strong> GmbH & Co KG<br />
www.brillux.de<br />
Street/P.O.Box : Weseler Straße 401<br />
Country code/Postal<br />
D - 48163 Münster<br />
code/Town/City :<br />
Telephone : +49 (0)251-7188-0<br />
Telefax : +49 (0)251-7188-280<br />
Contact :<br />
1.4 Emergency telephone number<br />
Outside the business hours:<br />
(Giftnotruf Berlin, consultation in the german and english language)<br />
Telephone: +49 (0)30 30686 790.<br />
2. Hazards identification<br />
E-Mail-Adresse der sachkundigen Person für Sicherheitsdatenblätter:<br />
sdb@brillux.de.<br />
2.1 Classification of the substance or mixture<br />
Directive 67/548/EEC or 1999/45/EC<br />
Causes burns. · May cause sensitization by skin contact. · Harmful to aquatic organisms, may cause long-term adverse effects in<br />
the aquatic environment. · Harmful by inhalation, in contact with skin and if swallowed.<br />
C ; R 34 · R 43 · R 52/53 · Xn ; R 20/21/22<br />
Regulation (EC) No 1272/2008 (GHS)<br />
Causes severe skin burns and eye damage. · Harmful if swallowed. · May cause an allergic skin reaction. · Harmful to aquatic life<br />
with long lasting effects.<br />
Aquatic Chronic 3 ; H412 · Acute Tox. 4 ; H302 · Skin Corr. 1B ; H314 · Skin Sens. 1 ; H317<br />
2.2 Label elements<br />
Directive 67/548/EEC or 1999/45/EC<br />
Danger symbol and danger designation<br />
C ; Corrosive<br />
Hazard-determining components of labelling<br />
BENZYL ALCOHOL ; CAS-No. : 100-51-6<br />
3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE ; CAS-No. : 2855-13-2<br />
R-phrases<br />
34 Causes burns.<br />
43 May cause sensitization by skin contact.<br />
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.<br />
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.<br />
S-phrases<br />
61 Avoid release to the environment. Refer to special instructions / safety data sheet.<br />
Page : 1 / 8<br />
( EN / D )
<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente B)<br />
Floortec 2C Epoxy Primer LF 832 (Component B)<br />
Revision : 01.07.2013 Version (Revision) : 10.0.0 (9.0.0)<br />
Print date : 01.07.2013<br />
1/2 Keep locked up and out of the reach of children.<br />
20 When using do not eat or drink.<br />
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.<br />
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where<br />
possible).<br />
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.<br />
9 Keep container in a well-ventilated place.<br />
Regulation (EC) No 1272/2008 (GHS)<br />
Hazard pictograms<br />
Corrosion (GHS05) · Exclamation mark (GHS07)<br />
Signal word<br />
Danger<br />
Hazard-determining components of labelling<br />
BENZYL ALCOHOL ; CAS-No. : 100-51-6<br />
3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE ; CAS-No. : 2855-13-2<br />
Hazard statements<br />
H314<br />
Causes severe skin burns and eye damage.<br />
H302<br />
Harmful if swallowed.<br />
H317<br />
May cause an allergic skin reaction.<br />
H412<br />
Harmful to aquatic life with long lasting effects.<br />
Precautionary statements<br />
P273<br />
Avoid release to the environment.<br />
P280<br />
Wear protective gloves/protective clothing/eye protection/face protection.<br />
P301/312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.<br />
P305/351/338<br />
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy<br />
to do. Continue rinsing.<br />
P304/340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.<br />
P303/361/353<br />
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with<br />
water/shower.<br />
P501.1 Dispose of contents/container to approved disposal company or local collection.<br />
2.3 Other hazards<br />
None.<br />
3. Composition/information on ingredients<br />
3.2 Mixtures<br />
Chemical characterization<br />
Mixture based on components, which are called following, and other components.<br />
Hazardous components<br />
BENZYL ALCOHOL ; EC-No. : 202-859-9; CAS-No. : 100-51-6<br />
Percentage : 25 - 50 %<br />
Classification 67/548/EEC : Xn ; R20/22<br />
Classification 1272/2008 (CLP) : Acute Tox. 4 ; H302 Acute Tox. 4 ; H332<br />
3-AMINOMETHYL-3,5,5-TRIMETHYLCYCLOHEXYLAMINE ; EC-No. : 220-666-8; CAS-No. : 2855-13-2<br />
Percentage : 25 - 50 %<br />
Classification 67/548/EEC : C ; R34 R43 R52/53 Xn ; R21/22<br />
Classification 1272/2008 (CLP) : Skin Corr. 1B ; H314 Acute Tox. 4 ; H302 Acute Tox. 4 ; H312 Skin Sens. 1 ; H317<br />
Aquatic Chronic 3 ; H412<br />
Page : 2 / 8<br />
( EN / D )
<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente B)<br />
Floortec 2C Epoxy Primer LF 832 (Component B)<br />
Revision : 01.07.2013 Version (Revision) : 10.0.0 (9.0.0)<br />
Print date : 01.07.2013<br />
POLYAMINE-ADDUKT<br />
Percentage : 25 - 50 %<br />
Classification 67/548/EEC :<br />
Xi ; R41 Xi ; R38<br />
Classification 1272/2008 (CLP) : Eye Dam. 1 ; H318 Skin Irrit. 2 ; H315<br />
For the wording of the listed risk phrases refer to section 16.<br />
4. First aid measures<br />
4.1 Description of first aid measures<br />
General<br />
In all cases of doubt, or when symptoms persist, seek medical attention. Instantly remove any clothing soiled by the product.<br />
Phrase P101: If medical advice is needed, have product container or label at hand.<br />
After inhalation<br />
Fresh air supply, go to doctor at complaints.<br />
After skin contact<br />
Wash away with soap and water and rinse.<br />
After eye contact<br />
Remove contact lenses, keep eyelids open. Rinse open eye immediately with plenty of running water. Seek medical adivce if<br />
complaint continues.<br />
After ingestion<br />
Rinse mouth with plenty of water. When swallowed immediately consult and show packing or label to physician.<br />
4.2 Most important symptoms and effects, both acute and delayed<br />
Possible symptoms: Irritation of the skin and the eyes. Allergic symptoms.<br />
4.3 Indication of any immediate medical attention and special treatment needed<br />
After ingestion there is a corrosive effect in the mouth room and throat as well as danger of the perforation of the gullet and the<br />
stomach.<br />
5. Firefighting measures<br />
5.1 Extinguishing media<br />
Suitable extinguishing media<br />
Adapt extinguishing measures to suit the environment.<br />
5.2 Special hazards arising from the substance or mixture<br />
None.<br />
5.3 Advice for firefighters<br />
When extinguishing fires, use breathing apparatus with an independent source of air.<br />
6. Accidental release measures<br />
6.1 Personal precautions, protective equipment and emergency procedures<br />
Keep no protective persons away, personal should wear protective clothings.<br />
6.2 Environmental precautions<br />
Do not empty into drains. If the product contaminates lakes, rivers or sewages, inform appropriate authorities in accordance with<br />
local regulations.<br />
6.3 Methods and material for containment and cleaning up<br />
Absorb with liquid-binding material (sand, diatomite, acid-binders, universal binders, sawdust). Dispose of contaminated material as<br />
waste according to section 13. Disposing of contaminated material as waste after section 13. Ensure adequate ventilation.<br />
6.4 Reference to other sections<br />
None.<br />
Page : 3 / 8<br />
( EN / D )
<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente B)<br />
Floortec 2C Epoxy Primer LF 832 (Component B)<br />
Revision : 01.07.2013 Version (Revision) : 10.0.0 (9.0.0)<br />
Print date : 01.07.2013<br />
6.5 Additional information<br />
See section 8 for the personal protection and section 13 for information about the waste disposal.<br />
7. Handling and storage<br />
7.1 Precautions for safe handling<br />
Information for safe handling<br />
Ensure a good ventilation in room and working area. For personal protection see Section 8.<br />
Immediately change the protective clothing which are contaminated or damaged and wash the skin away with water. By mixing<br />
the components slowly, the container have to cover the product container to reduce the splashing danger. Working carefully and<br />
slowly when decanting the mixture in another container.<br />
Phrase P102: Keep out of reach of children.<br />
Phrase P103: Read label before use.<br />
Phrase P262: Do not get in eyes, on skin, or on clothing.<br />
Information about protection against explosions and fires<br />
No special precautionary measure necessary.<br />
7.2 Conditions for safe storage, including any incompatibilities<br />
Requirements to be met by storerooms and containers<br />
No particular measures required.<br />
Phrase P405: Store locked up.<br />
Information about separation of incompatible products<br />
Store away from foodstuffs.<br />
Further information about storage conditions<br />
Store containers tightly closed in a cool well ventilated place. Keep only in the original container or in containers recommended by<br />
the manufacturer.<br />
Storage class : 8<br />
7.3 Specific end use(s)<br />
Hardenercomponent of the product Floortec 2C Epoxy Primer LF 832.<br />
8. Exposure controls/personal protection<br />
8.1 Control parameters<br />
None.<br />
8.2 Exposure controls<br />
Personal protective equipment<br />
General protective and hygiene measures<br />
Keep away from food, drink and animal feeding stuff. Immediately remove all contaminated clothing. Wash hands before breaks<br />
and after work. Avoid contact with eyes and skin.<br />
Respiratory protection<br />
Use suitable respiratory protective device in case of insufficient ventilation. When workers are facing concentrations above the<br />
exposure limit they must use appropriate certified respirators. Half mask with combination filter, class A1P2 minimum, or<br />
breathing mask with outer air supply.<br />
Do not inhale the vapour.<br />
Hand protection<br />
Use protective gloves based on nitrile-rubber. Following notes of the gloves-manufacturer. The choice of a suitable glove is<br />
dependent on the material and other quality characteristics which are different depending on manufacturer. Because the product<br />
is a preparation of several substances, the resistance of the glove materials have to be checked before use. The exact break<br />
trough time has to be found out by the manufactor of the protective gloves and has to be observed.<br />
Eye protection<br />
Use tightly fitting safety glasses.<br />
Body protection<br />
Page : 4 / 8<br />
( EN / D )
<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente B)<br />
Floortec 2C Epoxy Primer LF 832 (Component B)<br />
Revision : 01.07.2013 Version (Revision) : 10.0.0 (9.0.0)<br />
Print date : 01.07.2013<br />
By working with epoxy resins a fitting protective clothing should be worn. To these clothes an additional protective clothing can<br />
be necessary, e. g. aprons, sleeve schooners, overcoats.<br />
By working with the product uncovered skin places have to be avoided also at warm weather.<br />
Additional information about engineering measures<br />
Observe data available of section 7. Provide adequate ventilation. Where reasonably practicable this shoud be achieved by the use<br />
of local exhaust ventilation and good general extraction.<br />
9. Physical and chemical properties<br />
9.1 Information on basic physical and chemical properties<br />
Image<br />
Form :<br />
Colour :<br />
Odour :<br />
Relevant safety data<br />
Liquid.<br />
According to product identification.<br />
characteristic<br />
Boiling temperature/boiling<br />
range:<br />
( 1013 hPa ) 205 °C<br />
Flash point: 101 °C<br />
Ignition temperature: 380 °C<br />
Lower explosion limit: 1,3 Vol-%<br />
Upper explosion limit: 13 Vol-%<br />
Vapour pressure: ( 20 °C ) 0,1 hPa<br />
Density: ( 20 °C ) ca. 1 g/cm 3<br />
Water solubility: ( 20 °C ) consolute miscible<br />
VOC value :<br />
max.<br />
200 g/l<br />
9.2 Other information<br />
The mentioned VOC value refers to the mixture of the product, incl. harder, ready for use.<br />
10. Stability and reactivity<br />
10.1 Reactivity<br />
No dangerous reaction known. Particularly larger quantities of the 2C-Mixture material could get hot by the progressive polyaddition,<br />
if the mixture would not using. Carbon monoxide, carbon dioxide and nitric oxides could arise.<br />
10.2 Chemical stability<br />
Stable under recommended storage and handling conditions (see section 7).<br />
10.3 Possibility of hazardous reactions<br />
No dangerous reactions are known if stored and handled the product correctly.<br />
10.4 Conditions to avoid<br />
Keep away from frost, heat and direct sunlight.<br />
10.5 Incompatible materials<br />
No dangerous reaction known.<br />
10.6 Hazardous decomposition products<br />
No dangerous decomposition product are known if stored and handled correctly.<br />
11. Toxicological information<br />
11.1 Information on toxicological effects<br />
Acute toxicity:<br />
- Acute oral toxicity: No data available;<br />
- Acute dermal toxicity: No data available;<br />
Page : 5 / 8<br />
( EN / D )
<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente B)<br />
Floortec 2C Epoxy Primer LF 832 (Component B)<br />
Revision : 01.07.2013 Version (Revision) : 10.0.0 (9.0.0)<br />
Print date : 01.07.2013<br />
- Acute inhalation toxicity: No data available.<br />
Primary irritant effect<br />
Irritation:<br />
Causes severe skin burns and eye damage.<br />
Sensitization<br />
The product contains sensitizing substances, which may produce an allergic reaction (see section 2 and 3).<br />
Cancerogenic and mutagenic effects, risks to reproduction<br />
The product is not classified as human germ cell mutagenic, carcinogenic or human reproductive toxic (CMR effects).<br />
11.3 Additional toxicological information<br />
Swallows strong etching effect of the mouth room and throat as well as danger of the perforation of the gullet and the stomach at.<br />
The product shows the following dangers according to the calculation method of the General EU Classification Guidelines for the<br />
Preparations as issued in the latest version: harmful, corrosive, irritant.<br />
12. Ecological information<br />
12.1 Toxicity<br />
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.<br />
12.2 Persistence and degradability<br />
These are not data availably about the potential of the product concerning his persistency and degradability.<br />
12.3 Bioaccumulative potential<br />
These are not data availably about the bio accumulation potential of the product. No information about the individual components is<br />
available either.<br />
12.4 Mobility in soil<br />
These are not datas availably about the potential of the product concerning his mobility in the ground.<br />
Due to the low water solubility of the product a bioavailability is not probable.<br />
A penetrating into soil, waters and sewage system should be prevented.<br />
12.5 Results of PBT and vPvB assessment<br />
This product does not contain any relevant substances which were classified as a PBT or vPvB-substance.<br />
12.6 Other adverse effects<br />
There are no data available on the product itself.<br />
12.7 Additional information<br />
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water. Avoid exposing into ground, waterways and<br />
drainage.<br />
Danger of drinking water if even small quantities leak into soil. Harmful to aquatic organismen.<br />
13. Disposal considerations<br />
13.1 Waste treatment methods<br />
Recommendation<br />
Can be taken to a suitable incineration centre in oberservance of local regulations. Do not dispose together with household<br />
garbage. Do not allow product to reach sewage system.<br />
Waste key<br />
Disposal-definition No. (AVV-Code): 08 01 11* Paint and varnish waste which contains organic solvents or other dangerous<br />
substances.<br />
Contaminated packaging<br />
Recommendation<br />
Contaminated packaging must be emptied of all residues and, following appropriate cleaning, may be sent to a recycling plant.<br />
Uncleaned packaging must be disposed of in the same manner as the medium.<br />
14. Transport information<br />
14.1 UN number<br />
Page : 6 / 8<br />
( EN / D )
<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente B)<br />
Floortec 2C Epoxy Primer LF 832 (Component B)<br />
Revision : 01.07.2013 Version (Revision) : 10.0.0 (9.0.0)<br />
Print date : 01.07.2013<br />
2289<br />
14.2 UN proper shipping name<br />
ADR/RID<br />
ISOPHORONEDIAMINE<br />
IMDG-Code<br />
ISOPHORONEDIAMINE<br />
ICAO-TI / IATA-DGR<br />
ISOPHORONEDIAMINE<br />
14.3 Transport hazard class(es)<br />
ADR/RID<br />
Class : 8<br />
Classification-Code :<br />
C7<br />
Kemlercode : 80<br />
Tunnel restriction code :<br />
E<br />
Special provisions : LQ 7<br />
Label : 8<br />
IMDG-Code<br />
Class : 8<br />
EmS number :<br />
F-A / S-B<br />
Label : 8<br />
ICAO-TI / IATA-DGR<br />
Class : 8<br />
Label : 8<br />
14.4 Packing group<br />
III<br />
14.5 Environmental hazards<br />
ADR/RID : -<br />
IMDG-Code : -<br />
ICAO-TI / IATA-DGR : -<br />
14.6 Special precautions for user<br />
None.<br />
15. Regulatory information<br />
<strong>Safety</strong>, health and environmental regulations/legislation specific for the substance or<br />
15.1<br />
mixture<br />
National regulatory information<br />
Regulation on safety management (BetrSichV)<br />
No flammable liquid according to BetrSichV. VbF-class (till 31.12.2002): The product is not subject to the ordinance.<br />
Water pollution classification<br />
Class : 2 according Self classification<br />
Other regulations<br />
The product is not classified as a solid substance according to the criteria of the Penetrometer test (ADR, part 2, section 2.3.4)<br />
and also fulfils not the criteria for solid substances according to the TRwS 779 number 2.1.1.<br />
International regulatory information<br />
In accordance to the EU guideline 2004/42/EC :<br />
Product sub-category and VOC limiting values in accordance with appendix II, letter A of the guideline:<br />
Category j, type Lb;<br />
VOC limiting value of the category for 2010: 500 g/l.<br />
This product contains max. 200 g/l VOC (preparation ready for use).<br />
15.2 Chemical safety assessment<br />
A chemical safety assessments was not carried out.<br />
Page : 7 / 8<br />
( EN / D )
<strong>Material</strong> <strong>Safety</strong> <strong>Data</strong> <strong>Sheet</strong><br />
according to Regulation (EC) 1907/2006<br />
Product name : Floortec 2K-Epoxi-Grund LF 832 (Komponente B)<br />
Floortec 2C Epoxy Primer LF 832 (Component B)<br />
Revision : 01.07.2013 Version (Revision) : 10.0.0 (9.0.0)<br />
Print date : 01.07.2013<br />
16. Other information<br />
Further information<br />
Product code in accordance with GISBAU (hazardous materials information system of the German professional associations of the<br />
building and construction industry) for epoxy resin coating cloths (GISCODE): RE 1.<br />
R-Phrases of components<br />
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.<br />
20/22 Harmful by inhalation and if swallowed.<br />
21/22 Harmful in contact with skin and if swallowed.<br />
34 Causes burns.<br />
38 Irritating to skin.<br />
41 Risk of serious damage to eyes.<br />
43 May cause sensitization by skin contact.<br />
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.<br />
GHS Hazard statements of components<br />
H302<br />
H312<br />
H314<br />
H315<br />
H317<br />
H318<br />
H332<br />
H412<br />
Harmful if swallowed.<br />
Harmful in contact with skin.<br />
Causes severe skin burns and eye damage.<br />
Causes skin irritation.<br />
May cause an allergic skin reaction.<br />
Causes serious eye damage.<br />
Harmful if inhaled.<br />
Harmful to aquatic life with long lasting effects.<br />
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall<br />
not establish a legally valid contractual relationship.<br />
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