Material Safety Data Sheet - Brillux

Material Safety Data Sheet
according to Regulation (EC) 1907/2006
Product name : Floortec Epoxi-Härter 849
Floortec Epoxy Hardener 849
Revision : 16.06.2014 Version (Revision) : 10.0.0 (9.0.0)
Print date : 16.06.2014
1. Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Floortec Epoxi-Härter 849
Floortec Epoxy Hardener 849
1.2 Relevant identified uses of the substance or mixture and uses advised against
Hardener componente for the Brillux product Floortec 2C-Epoxy Seal 848.
There are no information about relevant identified uses of the product, which are advised against.
1.3 Details of the supplier of the safety data sheet
Manufacturer/Supplier :
Brillux GmbH & Co KG
www.brillux.de
Street/P.O.Box : Weseler Straße 401
Country code/Postal
D - 48163 Münster
code/Town/City :
Telephone : +49 (0)251-7188-0
Telefax : +49 (0)251-7188-280
Contact :
1.4 Emergency telephone number
Outside the business hours:
(Giftnotruf Berlin, consultation in the german and english language)
Telephone: +49 (0)30 30686 790.
2. Hazards identification
E-Mail-Adresse der sachkundigen Person für Sicherheitsdatenblätter:
sdb@brillux.de.
2.1 Classification of the substance or mixture
Directive 67/548/EEC or 1999/45/EC
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · May cause sensitization by skin
contact. · Irritating to eyes and skin.
N ; R 51/53 · R 43 · Xi ; R 36/38
Regulation (EC) No 1272/2008 (GHS)
Causes skin irritation. · May cause an allergic skin reaction. · Causes serious eye irritation. · Toxic to aquatic life with long lasting
effects.
Eye Irrit. 2 ; H319 · Aquatic Chronic 2 ; H411 · Skin Irrit. 2 ; H315 · Skin Sens. 1 ; H317
2.2 Label elements
Directive 67/548/EEC or 1999/45/EC
Danger symbol and danger designation
Xi ; Irritant
N ; Dangerous for the environment
Hazard-determining components of labelling
REACTION PRODUCT: BISPHENOL A-(EPICHLORHYDRIN), EPOXY RESIN (NUMBER AVERAGE MOLECULAR WEIGHT

Material Safety Data Sheet
according to Regulation (EC) 1907/2006
Product name : Floortec Epoxi-Härter 849
Floortec Epoxy Hardener 849
Revision : 16.06.2014 Version (Revision) : 10.0.0 (9.0.0)
Print date : 16.06.2014
R-phrases
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
43 May cause sensitization by skin contact.
36/38 Irritating to eyes and skin.
S-phrases
61 Avoid release to the environment. Refer to special instructions / safety data sheet.
2 Keep out of the reach of children.
51 Use only in well-ventilated areas.
37/39 Wear suitable gloves and eye/face protection.
46 If swallowed, seek medical advice immediately and show this container or label.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
24/25 Avoid contact with skin and eyes.
Special designation for certain preparations
92 Contains epoxy constituents. See information supplied by the manufacturer.
Regulation (EC) No 1272/2008 (GHS)
Hazard pictograms
Environment (GHS09) · Exclamation mark (GHS07)
Signal word
Warning
Hazard-determining components of labelling
REACTION PRODUCT: BISPHENOL A-(EPICHLORHYDRIN), EPOXY RESIN (NUMBER AVERAGE MOLECULAR WEIGHT

Material Safety Data Sheet
according to Regulation (EC) 1907/2006
Product name : Floortec Epoxi-Härter 849
Floortec Epoxy Hardener 849
Revision : 16.06.2014 Version (Revision) : 10.0.0 (9.0.0)
Print date : 16.06.2014
3. Composition/information on ingredients
3.2 Mixtures
Chemical characterization
Hardener based on epoxy resins.
Hazardous components
REACTION PRODUCT: BISPHENOL A-(EPICHLORHYDRIN), EPOXY RESIN(NUMBER AVERAGE MOLECULAR WEIGHT

Material Safety Data Sheet
according to Regulation (EC) 1907/2006
Product name : Floortec Epoxi-Härter 849
Floortec Epoxy Hardener 849
Revision : 16.06.2014 Version (Revision) : 10.0.0 (9.0.0)
Print date : 16.06.2014
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Unsuitable extinguishing media
A full water jet.
5.2 Special hazards arising from the substance or mixture
Fire will produce dense black smoke. Exposure to decomposition products may cause a health hazard.
5.3 Advice for firefighters
Appropriate breathing apparatus may be required.
5.4 Additional information
Cool endangered containers with water in case of fire. Do not allow the quenching water into the sewage system.
6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures
Refer to protective measures listed in sections 7 and 8. Keep no protective persons away, personal should wear protective clothings.
6.2 Environmental precautions
Do not empty into drains. If the product contaminates lakes, rivers or sewages, inform appropriate authorities in accordance with
local regulations. Holding polluted washing water back and disposing of duly.
6.3 Methods and material for containment and cleaning up
Absorb with liquid-binding material (sand, diatomite, acid-binders, universal binders, sawdust). Dispose of contaminated material as
waste according to section 13.
6.4 Reference to other sections
None.
7. Handling and storage
7.1 Precautions for safe handling
Information for safe handling
For personal protection see Section 8.
Avoid contact with skin and eyes Bei Gefahr des Verspritzens geeignete Schutzkleidung und Gesichtsschutz tragen. Ensure a good
ventilation in room and working area. Smoking, eating and drinking in working area forbidden. Wash hands and face before
breaks and after work and take a shower if necessary.
Phrase P103: Read label before use.
Information about protection against explosions and fires
No special precautionary measure necessary. Cool endangered containers with water.
7.2 Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and containers
Keep container tightly in a dry, cool and good ventilated place. Do not store the product in lounge room. Keep only in the original
container. Protect from frost. Keep out of the reach of children.
Information about separation of incompatible products
Store away from foodstuffs.
Further information about storage conditions
Storage class : 10
7.3 Specific end use(s)
Hardener componente for the Brillux product Floortec 2C-Epoxy Seal 848.
8. Exposure controls/personal protection
8.1 Control parameters
None.
Page : 4 / 8
( EN / D )

Material Safety Data Sheet
according to Regulation (EC) 1907/2006
Product name : Floortec Epoxi-Härter 849
Floortec Epoxy Hardener 849
Revision : 16.06.2014 Version (Revision) : 10.0.0 (9.0.0)
Print date : 16.06.2014
8.2 Exposure controls
Personal protective equipment
General protective and hygiene measures
Avoid contact with eyes and skin. Immediately remove all contaminated clothing. Do not eat or drink during work - no smoking.
Wash hands before breaks and after work.
Respiratory protection
Breathing protection equipment is not required at brush or roll application.
Hand protection
At use as agreed a protective gloves from nitrile rubber with a material thickness 0,4 mm has to be used. Notes of the
manufacturer have to be taken into account. Penetration time of the glove material: > = 8 h.
Penetration time of the gloves material: >= 8h. By longer or repeated contact the penetration times can be considerably shorter.
The protective gloves should replaced after the first wear out or a damage of the gloves. Gloves of cotton should be used under
the gloves of polychloropren or nitrile rubber. After washing hands replace lost skin fat by fat containing skin creams.
Eye protection
Use tightly fitting safety glasses.
Body protection
Using protective clothing.
Additional information about engineering measures
Provide adequate ventilation. Where reasonably practicable this shoud be achieved by the use of local exhaust ventilation and
good general extraction.
Observe data available of section 7.
9. Physical and chemical properties
9.1 Information on basic physical and chemical properties
Image
Form :
Colour :
Odour :
Relevant safety data
Liquid.
According to product identification.
Poor, characteristic.
Boiling temperature/boiling
range:
( 1013 hPa ) > 200 °C
Flash point: 135 °C
Ignition temperature: > 290 °C
Vapour pressure: ( 50 °C ) not determined
Vapour pressure: ( 20 °C ) 2,3 hPa
Density: ( 20 °C ) ca. 1,13 g/cm 3
Solvent separation test: ( 20 °C ) not applicable
Water solubility: ( 20 °C ) insoluble
Flow time: ( 20 °C ) not applicable DIN-cup 4 mm
Viscosity: ( 20 °C ) 1450 - 1900 mPa.s
VOC value :
max.
9 g/l
9.2 Other information
The mentioned VOC value refers to the mixture of the product ready for use of tribe varnish and harder.
10. Stability and reactivity
10.1 Reactivity
No dangers connected by a possible reactivity of the product are known to proper handling and storage.
10.2 Chemical stability
Page : 5 / 8
( EN / D )

Material Safety Data Sheet
according to Regulation (EC) 1907/2006
Product name : Floortec Epoxi-Härter 849
Floortec Epoxy Hardener 849
Revision : 16.06.2014 Version (Revision) : 10.0.0 (9.0.0)
Print date : 16.06.2014
Stable under recommended storage and handling conditions (see section 7).
10.3 Possibility of hazardous reactions
Exothermic polymerization.
Heavy reactions with bases and other organic substances like alcohols and amines.
10.4 Conditions to avoid
Keep away from frost, heat and direct sunlight. Decomposition starts at 200-250 C°
10.5 Incompatible materials
As of room temperature polymerisiert the product under warmth development with amines, Mercaptanen and Lewis acids.
10.6 Hazardous decomposition products
No dangerous decomposition product are known if stored and handled correctly. When exposed to high temperatures or in case of
fire hazardous decomposition products such as carbon dioxide, carbon monoxide, smoke, nitric oxides or thick, black smoke may
produced.
11. Toxicological information
11.1 Information on toxicological effects
Acute toxicity:
- Acute oral toxicity: No data available;
- Acute dermal toxicity: No data available;
- Acute inhalation toxicity: No data available.
Primary irritant effect
Reizwirkung:
- Bei Hautkontakt: Reizt die Haut.
- Bei Augenkontakt: Reizt dien Augen.
Sensitization
Das Produkt ist als sensibilisierend gekennzeichnet.
Cancerogenic and mutagenic effects, risks to reproduction
The product is not classified as human germ cell mutagenic, carcinogenic or human reproductive toxic (CMR effects).
11.3 Additional toxicological information
The product was classified in toxicological terms on the basis of the results of the calculation procedure outlined within General
Directive on Preparations (1999/45/EC), listed in sections 3 and 15.
At proper dealing and use as agreed the product does not cause any effects bad for health after our experiences and the
information submitted to us.
12. Ecological information
12.1 Toxicity
Toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
12.2 Persistence and degradability
These are not data availably about the potential of the product concerning his persistency and degradability.
12.3 Bioaccumulative potential
These are not data availably about the bio accumulation potential of the product. No information about the individual components is
available either.
12.4 Mobility in soil
These are not datas availably about the potential of the product concerning his mobility in the ground.
Due to the low water solubility of the product a bioavailability is not probable.
A penetrating into soil, waters and sewage system should be prevented.
12.5 Results of PBT and vPvB assessment
This product does not contain any relevant substances which were classified as a PBT or vPvB-substance.
12.6 Other adverse effects
There are no data available on the product itself.
12.7 Additional information
Page : 6 / 8
( EN / D )

Material Safety Data Sheet
according to Regulation (EC) 1907/2006
Product name : Floortec Epoxi-Härter 849
Floortec Epoxy Hardener 849
Revision : 16.06.2014 Version (Revision) : 10.0.0 (9.0.0)
Print date : 16.06.2014
Avoid exposing into ground, waterways and drainage.
The product is evaluated according the method of 1999/45/EC and is not classified as harmful for the enviroment bus contents
components witch are harmful for the enviroment. See sections 2 and 3 for details.
13. Disposal considerations
13.1 Waste treatment methods
Recommendation
Dispose of contents/container to approved disposal company or local collection according to the local regulations. Do not dispose
together with household garbage. Do not allow product to reach sewage system.
Waste key
Disposal-definition No. (AVV-Code): 08 01 11* Paint and varnish waste which contains organic solvents or other dangerous
substances.
Contaminated packaging
Recommendation
Only empty packaging can be transfered to recycling. Packaging with residues have to droped at official collecting sites.
14. Transport information
14.1 UN number
3082
14.2 UN proper shipping name
ADR/RID
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( EPOXY RESIN )
IMDG-Code
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( EPOXY RESIN )
ICAO-TI / IATA-DGR
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( EPOXY RESIN )
14.3 Transport hazard class(es)
ADR/RID
Class : 9
Classification-Code :
M6
Kemlercode : 90
Tunnel restriction code :
E
Special provisions : LQ 7 · E 1
Label :
9 / N
IMDG-Code
Class : 9
EmS number :
F-A / S-F
Special provisions : LQ 5 l · E 1
Label :
9 / N
ICAO-TI / IATA-DGR
Class : 9
Special provisions : E 1
Label :
9 / N
14.4 Packing group
III
14.5 Environmental hazards
ADR/RID : N
IMDG-Code : P
ICAO-TI / IATA-DGR : N
14.6 Special precautions for user
Page : 7 / 8
( EN / D )

Material Safety Data Sheet
according to Regulation (EC) 1907/2006
Product name : Floortec Epoxi-Härter 849
Floortec Epoxy Hardener 849
Revision : 16.06.2014 Version (Revision) : 10.0.0 (9.0.0)
Print date : 16.06.2014
None.
14.8 Remarks
ADR/RID
According to the transport regulations the product is labbeling with the label 9 as also with the symbol "Fish and tree" and in
packages > 5 ltr.
15. Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or
15.1
mixture
National regulatory information
Regulation on safety management (BetrSichV)
No flammable liquid according to BetrSichV. VbF-class (till 31.12.2002): The product is not subject to the ordinance.
Water pollution classification
Class : 2 Classification according to VwVwS
Other regulations
The product is classified as a solid substance according to the criteria of the Penetrometer test (ADR, part 2, section 2.3.4) and
also fulfils the criteria for solid substances according to the TRwS 779 number 2.1.1.
International regulatory information
In accordance with the EU guideline 2004/42/EC :
Product sub-category and VOC limiting values in accordance with appendix II, letter A of the guideline:
Category j, type Wb;
VOC limiting value of the category for 2010: 140 g/l.
This product contains max. 9 g/l VOC.
The mentioned VOC value refers to the mixture of the product ready for use of tribe varnish and harder.
15.2 Chemical safety assessment
A chemical safety assessments was not carried out.
16. Other information
Further information
Product code in accordance with GISBAU (hazardous materials information system of the German professional associations of the
building and construction industry) for epoxy resin coating cloths (GISCODE): RE 1.
Relevant changes
02.2 S-phrases · 02.2 GHS - Hazard pictograms · 02.2 GHS - Signal word · 02.2 GHS - Hazard statements · 02.2 GHS -
Precautionary statements · 02.2 GHS - Supplemental hazard information · 08.1 References to the thresholds · 14. Land transport
ADR/RID and GGVS/GGVE · 14. Classification (ADR) · 14. Substance releasing the danger (ADR) · 14. Maritime transport
IMDG/GGVSea · 14. Classification (IMDG) · 14. Substance releasing the danger (IMDG) · 14. Air transport ICAO-TI and IATA-DGR
· 14. Classification (ICAO) · 14. Substance releasing the danger (ICAO)
R-Phrases of components
36/38 Irritating to eyes and skin.
43 May cause sensitization by skin contact.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
GHS Hazard statements of components
H315
H317
H319
H411
Causes skin irritation.
May cause an allergic skin reaction.
Causes serious eye irritation.
Toxic to aquatic life with long lasting effects.
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features and shall
not establish a legally valid contractual relationship.
Page : 8 / 8
( EN / D )