105883-40-7

DENTSPLY PROBOND ADHESIVE 

Chemwatch lndependent Material Safety Data Sheet 

lssue Date: 30-Sep-2009 CHEMWATCH 4613-29 

C9317TC 

Version No:4 

CD 2009/3 Page 1 of 6 

Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFIGATION 

PRODUCT NAME 


PROPER SHIPPING NAME 

ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LlQUlD, N.O.S (contains glutaraldehyde) 

PRODUCT USE 

Two part adhesive, for use in dental restoration 

SUPPLIER 

Company: DENTSPLY (AUSTRALIA) PTY LTD 

Address: 

1 1- 21 Gilby Road 

Mount Waverley 

vtc 3'149 

AUSTRALIA 

Telephone: 1300 55 29 29 

Emergency Tel: 1300 55 29 29 (Hours of operation: 

lvlonday - Friday 9:00 am - 5:00 pm EST; General 

information only) 

Fax: +61 3 9538 8260 

Section 2 - HAZARDS IDENTIFICATION 

STATEMENT OF HAZARDOUS NATURE 

HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code. 

POISONS SCHEDULE 

None 

r Harmful by inhalation and if 

swâllowed 

I lrritating to respiratory system 

and skin 

Risk of serious damage to eyes. 

r May cause SENSITISATION by 

inhalation and skin contact 

r Toxic to aquatic organisms 

SAFETY 

r Do not breathe gas/fumes/vapour/spray 

r Wear suitable protective clothing 

Use only in well ventilated areas 

r Keep container in a well ventilated place 

r To clean the floor and all objects contaminated by th¡s 

material use water and detergent. 

r Keep container tightly closed 

r Keep away from food drink and animal feeding stuffs 

r lf swallowed l|\4MEDIATELY contact Doctor or Poisons 

lnformation Centre (show this contaìner or label) 

r This material and its container must be disposed of as 

hazardous waste 

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS 

NAIVE 

urethane dimethacrylate monomer 

triethylene glycol dimethacrylate 

dipentaerythritol pentaacrylate phosphate 

glutaraldehyde 

CAS RN 

IO 

105883-40-7


Chemwatch lndependent Mater¡al Safety Data Sheet 

lssue Date: 30-Sep-2009 CHEMWATCH 46l3-29 

C9317TC 

Version No:4 

CD 2009/3 Page 2 ofG 

Section 4 - FIRST AID MEASURES 

- Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower 

lids 

SKIN 

r lf skin contact occurs: 

- lmmediately remove all contaminated clothing, ¡ncluding footwear. 

- Flush skin and hair with running water (and soap if available). 

INHALED 

r - lf fumes or combustion products are inhaled remove from contaminated area 

- Lay patient down Keep warm and rested 

NOTES TO PHYSICIAN 

r for poisons (where specific treatment regime is absent): 

BASIC TREATI\4ENT 

- Establish a patent airuvay with suction where necessary. 

- Watch for signs of respiratory insufficiency and assist ventilatíon as necessary 

Treat symptomatically 

Section 5 - FIRE FIGHTING MEASURES 

EXTINGUISHING MEDIA 

r - Foam. 

- Dry chemical powder 

FIRE FIGHTING 

¡ - Alert F¡re Brigade and tell them location and nature of hazard. 

- May be violently or explosively reactive 

FIRE/EXPLOSION HAZARD 

r - Combustible. 

- Slight fire hazard when exposed to heat or flame 

Combustion products include: carbon dioxide (CO2), nitrogen oxides (NOx), other pyrolysis products typical of burning organic material 

lvlay emit poisonous fumes. 

May emit corrosive fumes 

FIRE INCOMPATIBILITY 

I - Avoid contamination with oxidising agents i e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc as ignition may result 

HAZCHEM: ¡32 

Personal Protect¡ve Equ¡pment 

Gas tight chemical resistant suit 

Section 6 - ACCIDENTAL RELEASE MEASURES 

MINOR SPILLS 

r - Remove all ignition sources. 

- Clean up all spills immediately 

MAJOR SPILLS 

r l\4oderate hazard 

- Clear area of personnel and move upwind. 

- Alert Fire Brigade and tell them location and nature of hazard. 

Personal Protective Equipment advice is contained in Section I of the MSDS. 

Section 7 - HANDLING AND STORAGE 

PROCEDURE FOR HANDLING 

¡ - Most acrylic monomers have low viscositytherefore pouring, material transferand processing of these materials do not necessitate heating. 

- Viscous monomers may require heating to facilitate handling To fac¡litate product transfer from original containers, product must be heated to no 

more than 60 deg. C. (140 F.), for not more than 24 hours. 

- DO NOT allow clothing wet with material to stay in contact with skin 

- Avoid all personal contact, including inhalation 

- Wear protective clothing when risk of exposure occurs 

SUITABLE CONTAINER 

r - Metal can or drum 

cont¡nued...


Ghemwatch lndependent Material Safety Data Sheet 

lssue Date:30-Sep-2009 CHEMWATCH 4613-29 

C9317TC 

- Packaging as recommended by manufacturer. 

STORAGE INCOMPATIBILITY 

r for multifunctional acrylates: 

- Avoid exposure to free radical initiators (peroxides, persulfates) , iron, rust, oxidisers, and strong acids and strong bases 

- Avo¡d heat, flame, sunlight, X-rays or ultra-violet radiation., halogens 

Avoid mixing with alkali metals such as sodium, potassium and lithium 

Avoid reaction with 

STORAGE REQUIREMENTS 

r - Store in original containers 

- Keep containers securely sealed 

Version No:4 

CD 2009/3 Page 3 of 6 


Section I - EXPOSURE CONTROLS / PERSONAL PROTECTION 

EXPOSURE CONTROLS 

Source 

l\ilateriaì 

Peak ppm Peak mg/m' Notes 

Australia Exposure 

Standards 


(Glutaraldehyde) 

01 041 

Sen 

The following materials had no OELs on our records 

. urethane dimethacrylate monomer: 

. triethylene glycol dimethacrylate: 

CAS:105883- 40- 7 

CAS:'109- 16- 0 

PERSONAL PROTECTION 

RESPIRATOR 

Type ANO Filter of sufficient capacity 

EYE 

r - Safety glasses w¡th side shields 

- Chemical goggles. 

HANDS/FEET 

r - Wear chemical protective gloves, eg. PVC 

- Wear safety footwear or safety gumboots, eg. Rubber 

NOTE: 

- The material may produce skin sensitisation in predisposed individuals Care must be taken, when removing gloves and other protective equipment, to 

avoid all possible skin contact. 

- Contaminated leather items, such as shoes, belts and watch-bands should be removed and destroyed 

Suitability and durability of glove type is dependent on usage. Factors such as: 

- frequency and duration of contact, 

- chemical resistance of glove material, 

OTHER 

r - Overalls. 

- P.V C apron 

ENGINEERING CONTROLS 

r Local exhaust ventilation usually required lf risk of overexposure exists, wear approved respirator 

Section I - PHYSICAL AND CHEMICAL PROPERTIES 

APPEARANCE 

Light yellow liquid with a characteristic odour; does not mix with water 

PHYSICAL PROPERTIES 

Liquid 

Does not mix with water. 

Sinks in water. 

lvlolecular Weight: Not Applicable 

lvlelt¡ng Range (C): Not Available 

Solubility in water (g/L): lmmiscible 

pH (1% solution): Noi Applicable 

Volatile Component (%vol): Not Available 

Relative Vapour Density (air=1): Not Available 

Lower Explosive Limit (%): Not Available 

Autoignltion Temp (C): Not Available 

State: Liquid 

Boiling Range (C): Not Available 

Specific Gravity (water=1): 1.1 approx 

pH (as supplied): Not Available 

Vapour Pressure (kPa): Not Available 

Evaporat¡on Rate: Not Available 

Flash Point (C): Not Available 

Upper Explosive Limit (%): Not Available 

Decomposition Temp (C): Not Available 

Viscosity: Not Available 

cont¡nued...




C9317TC 

Version No:4 

CD 2009/3 Page 4 of6 

Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION 

CONDITIONS CONTRIBUTING TO INSTABILITY 

r - Presence of incompatible materials 

- Product is considered stable. 

- Presence of elevated temperatures. 

For incompatible mater¡als - refer to Sect¡on 7 - Handling and Storage 

Section l1 - TOXICOLOGICAL INFORMATION 

POTENTIAL HEALTH EFFECTS 

ACUTE HEALTH EFFECTS 

r Risk of serious damage to eyes 

r Harmful by inhalation and if swallowed 

r lrritating to respiratory system and 

skin 

CHRONIC HEALTH EFFECTS 

r May cause SENSITISATION by inhalation and skin 

contact 

TOXICITY AND IRRITATION 

r Not available. Refer to individual constituents. 

URETHANE DII\4ETHACRYLATE MONOMER: 

r No significant acute toxicological data identified in literature search. 

TRIETHYLENE GLYCOL DIMETHACRYLATE: 

r unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. 

TOXICITY 

IRRITATION 

Oral (rat) LD50: 10837 mg/kg 

Nil Reported 

Oral (mouse) LD50: 10750 mg/kg 

r Contact allergies quickly manifest themselves as contact eczema, more rarely as urt¡caria or Quincke's oedema. The pathogenesis of contact eczema 

involves a cell-mediated (T lymphocytes) immune reaction of the delayed type. 

Asthma-like symptoms may continue for months or even years after exposure to the material ceases This may be due to a non-allergenic condit¡on known 

as reactive airways dysfunction syndrome (RADS) which can occurfoliowing exposure to high levels of highly irritating compound. 

GLUTARALDEHYDE: 

r unless otherwise specifìed data extracted from RTECS - Registerof Toxic Effects of Chemical Substances. 

TOXICITY 

Oral (rat) LD50: '134 mg/kg 

lnhalation (rat) LC50: 480 mg/m'/4h 

Dermal (rabbit) LD50: 403 mg/kg 

IRRITATION 

Skin (human): 6 mg/3d- int- SEVERE 

Skin (rabbit): 13 mg open- N4ild 

Skin (rabbit): 2 mgl24h- SEVERE 

Eye (rabbit): 1 mg- SEVERE 

Eye (rabbit): O 25mgl24h- SEVERE 

r Asthma-like symptoms may continue for months or even years after exposure to the material ceases This may be due to a non-allergenic condition 

known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating compound 

The material may produce severe skin irritation after prolonged or repeated exposure, and may produce a contact dermatitis (nonallergic) Th¡s form 

of dermatitis is often characterised by skin redness (erythema) thickening of the epidermis 

Animal studies indicate that the oral LD50 of glutaraldehyde in rats, mice and guinea pigs, is approximately 50-250 mg/kg, and that the acute dermal 

toxicity in rabbits, rats and mice is approximately 1000-4500 mg/kg, with skin absorption at high concentrat¡ons Glutaraldehyde has a high acute 

inhalational toxicity in rats and mice and lung damage has been reported 

SENSITISER 

triethylene glycol 

dimethacrylate 

Australia Final Report on Hazard 

Classification of Common Skin Sensitisers 

Recommended for 

Hazard Classification 

(R43) 

No 

Section l2 - ECOLOGICAL INFORMATION 

Toxic to aquatic organisms 

This material and its container must be disposed of as hazardous waste 

Ecotoxicity 

lngredient 

Dentsply Probond Adhesive 

urethane dimethacrylate monomer 



Persistence: Persistence: Bioaccumulat Mobility 

Water/Soil Air ion 

No data 

No data 

No data 

No data 

continued...




C9317TC 

Version No:4 

CD 2009/3 Page 5 of6 

Section 13 - DISPOSAL CONSIDERATIONS 

r - Containers may still present a chemical hazatdl danget when empt 

- Return to supplier for reuse/ recycling if poss¡ble 

Legislation addressing waste disposal requirements may differ by country, state and/ or territory Each user must refer to laws operating in their 

area. 

- DO NOT allow wash water from cleaning or process equipment to enter drains. 

- lt may be necessary to collect allwash water for treatment before disposal 

- Recycle wherever possible or consult manufacturer for recycling options 

- Consult State Land Waste Authority for disposal 

Section l4 - TRANSPORTATION INFORMATION 

t Environmentally Hazardous Substances meeting the descriptions of UN 3077 or UN 3082 

are not subject to this Code when transpoñed by road or rail ín; 

(a) packagings; 

(b) lBCs; or 

(c) any other receptacle not exceeding 500 kg(L). 

- Australian Special Provisions (SP AU01) - ADG Code 7th Ed 

Labels Required: MISCELLANEOUS 

HMCHEM: o32 (ADG7) 

ADGT: 

Class or division: 

UN No.: 

Special provisions: 

Notes: 

Portable tanks and bulk 

-14 

conta¡ners - 

lnstructions: 

Packagings and lBCs - 

Pack¡ng instruction: 

P001, lBC03, LP01 

provtstons: 

Shipping Name:ENVIRONI\4ENTALLY HAZARDOUS SUBSTANCE, L|QUlD, N O S 

(conta¡ns glutaraldehyde) 

Land Transport UNDG: 

Class or div¡sion: 9 

Subsidiary risk: 

UN No: 3082 

UN packing group: 

Shipping Name:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LlQUlD, N O S 

(contains glutaraldehyde) 

Maritime Transport IMDG: 

IMDG Class: 

UN Number: 

EMS Number: 

a 

3082 

179,274,331,33s 

None 

o 

3082 

F-A, S- F 

5 L 



Packing lnstructions: 

Limited quantities: 


containers - Special 

provrsrons: 


Special packing 

A¡r Transport IATA: 

ICAO/IATA Class: 9 ICAO/IATA Subrisk 

UN/ID Number: 3082 Packing Group: 

Special provisions: 497 

Sh¡pping Name: ENVIRONMENTALLY HMARDOUS SUBSTANCE, LlQUlD, 

N O S. -(CONTAINS GLUTARALDEHYDE) 

Limited Quantities: 

Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LlQUlD, 

N.O S (contains glutaraldehyde) 

IMDG Subrisk: 

Packing Group: 


l\4arine Pollutant: 

None 

ilt 

None 

5L 

TP1, TP29 

PP1 

None 

ilt 

None 

ilt 

None 

ilt 

274 909 944 

Not Determined 

Section l5 - REGULATORY INFORMATION 

POISONS SCHEDULE: None 

REGULATIONS 

Regulations for ingredients 

triethylene glycol d¡methacrylate (CAS: 109-16-0) is found on the following regulatory l¡sts; 

Production Volume List","OECD Representative List of High Production Volume (HPV) Chemicals" 

cont¡nued...



lssue Date: 30-Sep-2009 

c931 7TC 

CHEMWATCH 46'13-29 

Version No:4 

CD 2009/3 Page 6 of 6 

Section 15 - REGULATORY INFORMATION 

glutaraldehyde (CAS: 111-30-8) ¡s found on the following regulatory lists; 

and Poisons (SUSDP) - Schedule 6","lMO IBC Code Chapter 17: Summar of minimum requirements",'lMO MARPOL 73178 (Annex ll) - List of Noxious Liquid Substances Carried in Bul 

L¡st of High Production Volume (HPV) Chemicals" 

No data for Dentsply Probond Adhesive (CW: 4613-29) 

No data for urethane d¡methacrylate monomer (CAS: , 105883-40-7) 

Section 16 - OTHER INFORMATION 

Denmark Advisory list for selfclassification of dangerous substances 

Substance 

CAS Suggested codes 


109- 16- 0 R43 N; R51/53 

r Class¡fication of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by 

the Chemwatch Classification committee using available l¡terature references. 

A list of reference resources used to assist the committee may be found at: 

www chemwatch.neUreferences. 

r The (lVl)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment Many factors determine whether the reported Hazards 

are Risks in the workplace or other sett¡ngs. 

This document is copyright. Apañ from any fair dealing for the purposes of private study, research, review or 

criticism, as permitted under the Copyright Act, no pan may be reproduced by any process without written 

permission from CHEMWATCH. TEL (+61 3) 9572 4700 

lssue Date: 30-Sep-2009 

Print Date: 30-Sep-2009 

Th¡s is lhe end of the MSDS

DENTSPLY PROBOND PRIMER 

Ghemwatch lndependent Material Safety Data Sheet 

lssue Date: 8-Oct-2009 CHEMWATCH 4613-30 

C93I7TC 

Version No:5 

CD 2009/3 Page 1 of6 

Section I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION 

PRODUCT NAME 

DENTSPLY PROBOND PRII\¡ER 

PROPERSHIPPING NAME 

FLAMMABLE L|QUlD, N O S (contains acetone and ethanol) 

PRODUCT USE 

Two part adhesive, for use in dental restorations 

SUPPLIER 

Company: DENTSPLY (AUSTRALIA) PTY LTD 

Address: 

1 1- 21 Gilby Road 

Mount Waverley 

vtc 3149 

AUSTRALIA 

Telephone: '1300 55 29 29 

Emergency Tel: 1300 55 29 29 (Hours of operation: 

Monday - Friday 9:00 am - 5:00 pm EST; General 

information only) 

Fax: +61 3 9538 8260 

Section 2 - HAZARDS IDENTIFICATION 

STATEMENT OF HAZARDOUS NATURE 

HAZARDOUS SUBSTANCE. DANGEROUS GOODS. According to the Criteria of NOHSC, and the ADG Code. 

POISONS SCHEDULE 

None 

RSK 

Highly flammable 

lrritat¡ng to eyes. 

r HARMFUL- May cause lung damage if 

swallowed. 

I Repeated exposure may cause skin 

dryness and cracking 

r Vapours may cause drowsiness and 

dizziness. 

SAFETY 

I Keep away from sources of ignition No smoking. 

r Do not breathe gas/fumes/vapour/spray. 

r Avoid contact with eyes 

I Wear suitable protective clothing 

r Use only in well ventilated areas 

r Keep container in a well ventilated place 

r Do not empty into drains 

r To clean the floor and all objects contaminated by this 

material use water. 

r Keep container tightly closed. 

r Keep away from food drink and animal feeding stuffs 

r ln case of contact with eyes rinse with plenty of water 

and contact Doctor or Poisons lnformation Centre. 

¡ lf swallowed IMMEDIATELY contact Doctor or Poisons 

lnformation Centre (show this container or label). 

r This material and its container must be disposed of as 

hazardous waste 

Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS 

NAME 

acetone 

ethanol 

dipentaerythritol pentaacrylate phosphate 

CAS RN 

67-64-1 

64-17 -5 

% 



lssue Date:8-Ocþ2009 CHEMWATCH 4613-30 

C9317TC 

Version No:5 

CD 2009/3 Page 2 of 6 

Section 4 - FIRST AID MEASURES 

EYE 

r lf this product comes in contact with the eyes: 

- lmmediately hold eyelids apart and flush the eye continuously w¡th running water. 

- Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occas¡onally lifting the upper and lower 

lids 

SKIN 

I lf skin or hair contact occurs: 

- Flush skin and hair with running water (and soap if available) 

- Seek medical attention in event of irritation. 

INHALED 

r - lf fumes or combustion products are inhaled remove from contaminated area 

- Lay patient down Keep warm and rested. 

NOTES TO PHYSICIAN 

r Any material aspirated during vómiting may produce lung injury. Therefore emesis should not be induced mechanically or pharmacologically. 

For acute or short term repeated exposures to acetone: 

- Symptoms of acetone exposure approximate ethanol intoxication. 

- About 20% is expired by the lungs and the rest is metabolised. Alveolar air half-life is about 4 hours following two hour inhalation at levels near 

the Exposure Standard; in overdose, saturable metabolism and limited clearance, prolong the elimination half-life to 25-30 hours 

For acute or short term repeated exposures to ethanol: 

- Acute ingestion in non-tolerant patients usually responds to supportive care with special attention to prevent¡on of aspiration, replacement of 

fluid and correction of nutritional deficiencies (magnesium, thiamine pyridoxine, Vitamins C and K). 

- Give 50% dextrose (50-100 ml) ¡V to obtunded patients following blood draw for glucose determination 

Section 5 - FIRE FIGHTING MEASURES 

EXTINGUISHING MEDIA 

r - Alcohol stable foam 

- Dry chemical powder. 

FIRE FIGHTING 

r - Alert Fire Brigade and tell them location and nature of hazard. 

- May be violently or explosively reactive 

FIRE/EXPLOSION HAZARD 

r - Liquid and vapour are highly flammable 

- Severe fire haza¡d when exposed to heat, flame and/or oxidisers. 

Combustion products include: carbon dioxide (C02), carbon monoxide (CO), other pyrolysis products typical of burning organic material. 

lVay emit poìsonous fumes. 

FIRE INCOMPATIBILITY 

r - Avoid contamination with oxidising agents ie nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignit¡on may result 

HAZCHEM: e3YE 


Glasses: 

Full face- shield. 

Gloves: 

PVC chemical res¡stant type 

Respirator: 

Type AXNO Filter of sufficient capac¡ty 

Section 6 - AGGIDENTAL RELEASE MEASURES 

MINOR SPILLS 

r - Remove all ignition sources 

- Clean up all spills immediately. 

MAJOR SPILLS 

r - Clear area of personnel and move upwind. 

- Alert Fire Brigade and tell them location and nature of hazard. 

Personal Protective Equipment advice is contained in Section I of the MSDS. 

cont¡nued...



lssue Date: 8-Oct-2009 

c931 7TC 

CHEMWATCH 4613-30 

Version No:5 

CD 2009/3 Page 3 of 6 


PROCEDURE FOR HANDLING 

r - Avoid all personal contact, including inhalation. 

- Wear protective clothing when risk of exposure occurs. 

- DO NOT allow clothing wet with material to stay ¡n contact with skin. 

SUITABLE CONTAINER 

r - Packing as supplied by manufacturer. 

- Plastic containers may only be used if approved for flammable liquid 

- For low viscosity materials (i) : Drums and jerry cans must be of the non-removable head type. (ii) : Where a can is to be used as an inner package, 

the can must have a screwed enclosure. 

- For materials with a viscosity of at least 2680 cSt (23 deg. C). 

STORAGE INCOMPATIBILITY 

I - Avoid reaction with oxidising agents. 

STORAGE REQUIREMENTS 

r - Store in original containers in approved flame-proof area 

- No smoking, naked lights, heat or ignition sources 

- Store below 38 deg. C. 

Section I - EXPOSURE CONTROLS / PERSONAL PROTECTION 

EXPOSURE CONTROLS 

Source 

Material 

TWA ppm 

TWA mg/m' 

STEL ppm 

STEL mg/m3 


Standards 


Standards 

acetone (Acetone) 

ethanol (Ethyl alcohol) 

500 

1 000 

1185 

1 880 

1 000 

2375 


RESPIRATOR 

Type AXNO Filter of sufficient capacity 

EYE 

r - Chemical goggles. 

- Full face shield may be requ¡red for supplementary but never for primary protection of eyes 

HANDS/FEET 

I - Wear chemical protective gloves, eg PVC 

- Wear safety footwear or safety gumboots, eg Rubber. 

OTHER 

r - Overalls. 

- PVC Apron 

¡ None under normal operating conditions 

ENGINEERING CONTROLS 

I Local exhaust ventilation usually required, lf risk of overexposure exists, wear approved respirator 

Section I - PHYSICAL AND GHEMICAL PROPERTIES 

APPEARANCE 

Water white, highly flammable liquid w¡th a characteristic odour; does not mix with 

water 

PHYSICAL PROPERTIES 

Liquid 

Mixes with water 

Molecular Weight: Not Applicable 

Melting Range (C): Not Available 

Solubility in water (g/L): Miscible 

pH (1% solution): Not Available 

Volat¡le Component (%vol): Not Available 

Relative Vapour Density (air='1): Not Available 

Boiling Range (C): 56 

Specific Gravity (water=1): 0.8 approx 

pH (as supplied): Not Available 

Vapour Pressure (kPa): Not Available 

Evaporation Rate: Not Available 

Flash Point (C):



lssue Date: 8-Oct-2009 CHEMWATCH 4613-30 

C9317TC 

Lower Explosive Limit (%): 2.5 Upper Explosive Limit (%): 13 

Autoignition Temp (C): Not Available 

State: Liquid 

Version No:S 

CD 2009/3 Page 4 of 6 

Section 9 - PHYSICAL AND CHEMICAL PROPERTIES 

Decomposition Temp (C): Not Available 

Viscosity: Not Available 

Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION 

CONDITIONS CONTRIBUTING TO INSTABILITY 

r - Presence of incompatible materials. 

- Product is considered stable. 

For incompatible materials - refer to Section 7 - Handling and Storage 

Section 11 - TOXICOLOGICAL INFORMATION 

POTENTIAL HEALTH EFFECTS 

ACUTE HEALTH EFFECTS 

I lrritating to eyes. 

r HARMFUL- l\rlay cause lung damage if 

swallowed. 

r Vapours may cause dizziness or 

suffocation. 

r Vapours may cause drowsiness and 

diziness. 

CHRONIC HEALTH EFFECTS 

I Repeated exposure may cause sk¡n dryness and 

cracking 

TOXICITY AND IRRITATION 

I Not available Refer to individual constituents 

ACETONE: 

r unless otherwise specified data exiracted from RTECS - Register of Toxic Effects of Chemical Substances 

TOXICITY 

IRRITATION 

Oral (man) TDLo: 2857 mg/kg 

Eye (human): 500 ppm - lrritant 


Eye (rabbit): 3 95 mg - SEVERE 

lnhalation (human) TCLo: 500 ppm 

Eye (rabbit): 2omgl24hr - Moderate 

lnhalation (man)TCLo: 12000 ppm/4 hr 

Skin (rabbit):395m9 (open) - Mild 

lnhalation (man) TCLo: 10 mg/m3/6 hr 

Skin (rabbit): 500 mg/24hr - M¡ld 

lnhalation (rat) LC50: 50100 mg/m'/8 hr 

Dermal (rabbit) LD50: 20000 mg/kg 

I The materìal may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic) This form of 

dermatitis is often characterised by skin redness (erythema) and swelling epidermis 

for acetone: 

The acute toxicity of acetone is low Acetone is not a skin irritant or sensitiser but is a defatting agent to the skin 

ETHANOL: 

I unless otherwise specifìed data extracted from RTECS - Registerof Toxic Effects of Chemical Substances 

TOXICITY 

IRRITATION 


Skin (rabbit):20 mgl24hr- lvloderate 

Oral (human) LDLo: 1400 mg/kg 

Skin (rabbit):40O mg (open)- Mild 

Oral (man) TDLo: 50 mg/kg 

Eye (rabbit):l00mgl24hr- Moderate 

Oral (man) TDLo: 1.40 mg/kg 

Eye (rabbit): 500 mg SEVERE 

Oral (woman) TDLo: 256 mg/kg/12 wks 

lnhalation (rat) LC50: 20, 000 ppm/10h 

lnhalation (rat) LC50: 64000 ppm/4h 

¡ The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic) This form of 

dermatitis is often characterised by skin redness (erythema) and swelling the epidermis 

CARGINOGEN 

Ethanol in alcoholic 

beverages 

lnternat¡onal Agency for Research on Cancer 

(IARC) Carcinogens 

Group 

Section 12 - ECOLOGICAL INFORMATION 

This material and its conta¡ner must be disposed of as hazardous waste 

Ecotox¡c¡ty 

lngredient Persistence: Persistencei Bioaccumulat Mobility 

Water/Soil Air ion 

Dentsply Probond Primer 

acetone 

No data 

No data 

continued...



lssue Date: 8-Ocf2009 

c931 7TC 

CHEMWATCH 4613.30 

Version No:5 

CD 2009/3 Page 5 of 6 

Section 12 - ECOLOGICAL INFORMATION 

ethanol 

No data 

I - Consult manufacturer for 

- Consult State Land Waste 

Section 13 - DISPOSAL CONSIDERATIONS 

recycling options and recycle where possible 

l\4anagement Author¡ty for disposal 

Section I4 - TRANSPORTATION INFORMATION 

Labels Required: FLAMMABLE LIQUID 

HAZCHEI\tf : o3YE (ADG7) 

ADGT: 


UNNo: 


Notes: 


containers - 

lnstructions: 


Packing instruction: 

Shipping Name:FLAMIVIABLE L¡QUlD, N O.S (contains acetone and ethanol) 

Land Transport UNDG: 


UNNo: 

Shipping Name:FLAI\4MABLE LlQUlD, 

3 

1 993 

274 

None 

T7 

P001, tBC02 

1 993 

N O S (contains acetone and ethanol) 



Packing lnstructions: 

Limited quantities: 


containers - Special 

provrsrons: 


Special packing 

provrsrons: 

Subsid¡ary risk: 


None 

il 

None 

1L 

TP1, TP8, TP28 

None 

None 

il 

A¡r Transport IATA: 

ICAO/IATA Class: 

3 

UN/lD Number: 

1 993 

Spec¡al provisions: 

A3 A1 48 

Shipping Name: FLAMMABLE L|QUlD, N O S, .(CONTAINS ACETONE 

AND ETHANOL) 

Maritime Transport IMDG: 

IMDG Class: 

UN Number: 

EIVIS Number: 

Limited Quantitiesi 

3 

1 993 

F-E,S-E 

1L 

Shipping Name: FLAMMABLE L|QUlD, N O S.(contains acetone 

and ethanol) 

ICAO/IATA Subrisk: 


IMDG Subrisk: 


Special provisions 

Marine Pollutant: 

None 

il 

None 

il 

274 330 944 

Not Determined 


POISONS SCHEDULE: None 

REGULATIONS 

Regulations for ingredients 

acetone (CAS: 67-64-1) is found on the following regulatory lists; 

ethanol (CAS: 64-17-5) is found on the following regulatory lists; 

No data for Dentsply Probond Primer (CW: 4613-30) 

cont¡nued...



lssue Dale: 8-Oct-2009 CHEMWATCH 4613-30 

C93I7TC 

Version Nor5 

CD 2009/3 Page 6of6 


Section 16 - OTHER INFORMATION

105883-40-7

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