Calcium Chloride Pellets 90% min Technical Grade - Zirax
Calcium Chloride Pellets 90% min Technical Grade - Zirax
Calcium Chloride Pellets 90% min Technical Grade - Zirax
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SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
Date issued: 10.08.2006<br />
Date revised: 02.04.2014<br />
Revision №: 2<br />
SECTION 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING<br />
1.1. Product identifier<br />
<strong>Calcium</strong> chloride pellets / powder 94-98%<br />
Trademark: UniPell TM<br />
<strong>Technical</strong> grade<br />
CHEMICAL NAME: calcium chloride, CaCl2<br />
CAS №: 10043-52-4<br />
EC №: 233-140-8<br />
REACH registration number: 01-2119494219-28-0013<br />
Index № CLP Annex VI Regulation (EC) No 1272/2008: 017-013-00-2<br />
1.2. Relevant identified uses of the substance or mixture and uses advised against<br />
Industrial uses: construction, industrial wastewater treatment, dust suppression, drying of industrial gas and air, as<br />
a cooling agent, tire weighing, concrete acceleration, dehumidification, refrigeration.<br />
No uses advised against are identified.<br />
1.3. Details of the supplier of the safety data sheet<br />
MANUFACTURER: <strong>Zirax</strong> LLC<br />
ADDRESS: Microrayon 4, 6 Svetly Yar settlement, 404171 Volgograd region, RUSSIA<br />
Telephone: +7 8442 494999<br />
Fax: +7 8442 499444<br />
e-mail: info@zirax.com<br />
1.4. Emergency telephone number<br />
+7 8442 49-49-99<br />
SECTION 2. HAZARDS IDENTIFICATION<br />
2.1. Classification of the substance or mixture<br />
According to Regulation (EC) No 1272/2008 of the European Parliament:<br />
Hazard statement code: H319: Causes serious eye irritation<br />
Hazard Class and category code: Eye Irritation 2<br />
According to Directive 67/548/EEC:<br />
Xi; R36 Irritating to eyes<br />
2.2. Label elements<br />
According to Regulation (EC) No 1272/2008<br />
EEC HAZARD PICTOGRAM<br />
GHS07: exclamation mark<br />
SIGNAL WORD: Warning<br />
HAZARD STATEMENT: H319: Causes serious eye irritation<br />
PRECAUTIONARY STATEMENTS:<br />
P 264: Wash hands thoroughly after handling.<br />
page 1 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
P 280: Wear protective glasses with splash shields or safety goggles/shield.<br />
P305 + P351 + P338: IF IN EYES Rinse eyes cautiously with water for 15 <strong>min</strong>utes. Remove contact lenses, if<br />
present and easy to do. Continue rinsing.<br />
P337 + P 313 If irritation continued get prompt qualified medical advice / attention.<br />
2.3. Other hazards<br />
<strong>Calcium</strong> chloride can cause <strong>min</strong>or skin irritation.<br />
SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS<br />
3.1. Substances<br />
Component Name<br />
CAS Number EC №<br />
Concentration<br />
w/w<br />
Classification:<br />
Regulation (EC) No 1272/2008<br />
<strong>Calcium</strong> <strong>Chloride</strong> 10043-52-4 233-140-8 94-98%<br />
H319: Causes serious eye irritation<br />
Eye Irritation 2 class<br />
SECTION 4. FIRST AID MEASURES<br />
4.1. Description of first aid measures<br />
EYES: Remove contact lenses, if present and easy to do. Rinse cautiously with water for 15 <strong>min</strong>utes. Seek medical<br />
attention.<br />
SKIN: Remove conta<strong>min</strong>ated clothes; wash off any skin conta<strong>min</strong>ations with soap and water. Launder<br />
conta<strong>min</strong>ated clothes before re-use.<br />
INGESTION: Get prompt qualified medical attention. If conscious, give 1-2 glasses of water with absorbent carbon.<br />
INHALATION: Remove to fresh air. Keep in warm and at rest. Give oxygen or artificial aspiration if needed. If<br />
symptoms persist seek medical attention.<br />
FIRST AID MEASURES: absorbent carbon, saline purge.<br />
4.2. Most important symptoms and effects, both acute and delayed<br />
EYES: Could cause irritant or burn effects to the eyes.<br />
SKIN: Could cause irritant effects to the skin. No delayed symptoms after washing conta<strong>min</strong>ated skin.<br />
INGESTION: May cause nausea. May cause GI tract irritation.<br />
INHALATION: Dust may cause irritation to mucous membranes and respiratory system.<br />
4.3. Indication of any immediate medical attention and special treatment needed<br />
No special antidotes. If case of ingestion wash mouth with water and give plenty water to drink. Get medical<br />
attention if needed.<br />
SECTION 5. FIRE FIGHTING MEASURES<br />
5.1. Extinguishing media<br />
This product is a nonflammable substance. However, hazardous decomposition and combustion products may be<br />
formed in a fire situation. Cool exposed containers with water spray to prevent overheating. Extinguish fire using<br />
agent suitable for type of surrounding fire and/or chemicals. Do not use water directly on material. Heat is<br />
generated when product mixed with water.<br />
5.2. Special hazards arising from the substance or mixture<br />
No special hazards.<br />
5.3. Advice for firefighters<br />
Respiratory and eye protection are required for fire fighting personnel. Avoid breathing corrosive vapors.<br />
page 2 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
SECTION 6. ACCIDENTAL RELEASE MEASURES<br />
6.1. Personal precautions, protective equipment and emergency procedures<br />
Wearing the appropriate personnel protective equipment designated in Section 8, move the container to a<br />
containment area or rotate the container so that the opening is above the liquid level.<br />
6.2. Environmental precautions<br />
WATER SPILL: Use appropriate containment to avoid runoff or release to sewer or waterways.<br />
LAND SPILL: Use appropriate containment to avoid runoff or release to ground.<br />
6.3. Methods and material for containment and cleaning up<br />
Construct temporary dikes of dirt, sand, or any appropriate readily available material to prevent spreading of the<br />
material. Wearing the appropriate personal protective equipment designated in Section 8, close or cap valves<br />
and/or block or plug hole in leaking container and transfer to another container. Remove containers with disposal<br />
from release area.<br />
6.4. Reference to other sections<br />
For addition information see section 13.<br />
SECTION 7. HANDLING AND STORAGE<br />
7.1. Precautions for safe handling<br />
Avoid skin and eye contact and breathing dusts. Use proper protective and respiratory equipment. Not to eat, drink<br />
and smoke in work areas. Wash hands thoroughly after handling. Launder conta<strong>min</strong>ated clothing before re-use.<br />
Ventilate area. Sweep or vacuum; do not create dust; place in a dry container for disposal. Clean spill area with<br />
water.<br />
7.2. Conditions for safe storage, including any incompatibilities<br />
Store in a cool, dry, well-ventilated place. Keep container closed when not in use. Keep away from incompatible<br />
materials. Protect from atmospheric moisture.<br />
7.3. Specific end use(s)<br />
No specific end uses.<br />
SECTION 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION<br />
8.1. Control parameters<br />
National occupational exposure limit values:<br />
maximum allowable concentration in the air of the working zone – 2 mg/m, aerosol (according to Russia standard<br />
“Maximum permissible concentration of harmful substance in the working zone area. Hygienic regulations”).<br />
8.2. Exposure controls<br />
ENGINEERING CONTROLS: Where environmental controls are lacking or in enclosed spaces use a NIOSH/MSHA<br />
approved respirator for dust/fumes. Provide local exhaust ventilation system. Eye wash station and safety shower<br />
should be provided within the immediate work area for emergency use.<br />
EXPOSURE LIMITS: No occupational exposure limits established by OSHA/ACGIH/NIOSH.<br />
PERSONAL PROTECTIVE EQUIPMENT:<br />
EYES: Wear safety glasses with splash shields or safety goggles/shield.<br />
BODY: Wear appropriate protective (impervious) clothing. Leather work boots and/or leather products will<br />
dehydrate with resultant shrinkage and possible destruction.<br />
RESPIRATORY: A respirator is not indicated under normal operating conditions. Use of a NIOSH approved<br />
respirator should be based upon the presence of nuisance dust. When warranted, use a face mask particulate<br />
respirator with particulate respirator with a NIOSH N95 rating.<br />
HANDS AND FEET: Wear appropriate rubber gloves and non-leather protective boots.<br />
page 3 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
WORK HYGIENIC PRACTICES: Use reasonable care in handling this product. Wash hands after use and before<br />
eating.<br />
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES<br />
9.1. Information on basic physical and chemical properties<br />
(a) Appearance: White pellets / powder<br />
(b) Odour: Odourless<br />
(c) Odour threshold: Not applicable<br />
(d) pH: Neutral or slightly alkaline<br />
(e) Melting point/freezing point: 772 o C (1,422 Fº)<br />
(f) Initial boiling point and boiling range; >1627°C<br />
(g) Flash point: Not applicable<br />
(h) Evaporation rate: Not applicable<br />
(i) Flammability (solid, gas): Not Flammable<br />
(j) Upper/lower flammability or explosive limits: Not applicable<br />
(k) Vapour pressure: Not applicable<br />
(l) Vapour density: Not applicable<br />
(m) Relative density: Min 700 kg/m 3 (50 lb/ft³)<br />
(n) Solubility(ies): Soluble in alcohol, acetic acid and acetone<br />
(o) Partition coefficient: n-octanol/water: inorganic substance, not applicable<br />
(p) Auto-ignition temperature: Not applicable<br />
(q) Decomposition temperature: Not applicable<br />
(r) Viscosity: Not applicable for a solid product<br />
(s) Explosive properties: the substance is non-explosive<br />
(t) Oxidising properties: the substance is non-explosive<br />
9.2. Other information<br />
MOLECULAR WEGHT: 111<br />
SECTION 10. STABILITY AND REACTIVITY<br />
10.1. Reactivity<br />
Reacts exothermically with water, acids and alkali.<br />
10.2. Chemical stability<br />
Product is stable under normal / recommended storage and handling conditions.<br />
10.3. Possibility of hazardous reactions<br />
Will not occur.<br />
10.4. Conditions to avoid<br />
To avoid contact of material with incompatible materials.<br />
10.5. Incompatible materials<br />
Incompatible with organic materials, acids, alkali, non- ferrous and ferrous metals.<br />
10.6. Hazardous decomposition products<br />
Does not occur under normal temperatures and pressures.<br />
SECTION 11. TOXICOLOGICAL INFORMATION<br />
11.1. Information on toxicological effects<br />
Acute toxicity of product is low. The value of DL 50 mg/kg study with animals:<br />
1000-4000 oral, rat<br />
page 4 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
1940 oral, mouse<br />
1384 oral, rabbit<br />
LOCAL EFFECTS: Eye, mucous membrane and skin irritant.<br />
HEALTH EFFECTS: Moderately toxic by ingestion, slightly toxic by dermal absorption.<br />
CARCINOGENICITY: Not Listed by NTP. Not listed by IARC. Not listed by OSHA.<br />
MUTAGENICITY: Not Available<br />
REPRODUCTIVE TOXICITY<br />
REPRODUCTIVE EFFECTS: testing does not appear necessary as calcium chloride will not reach the foetus or the<br />
male and female reproductive organs when exposed orally, dermally orby inhalation, as it does not become<br />
available systemically.<br />
TERATOGENIC EFFECTS: Not Available<br />
SENSITIZATION:<br />
Not Available<br />
SECTION 12. ECOLOGICAL INFORMATION<br />
12.1. Toxicity<br />
<strong>Calcium</strong> chloride is not classified as hazardous for the environment. <strong>Calcium</strong> and chloride are normally occurring<br />
ions that don’t have long term negative effect.<br />
Overview of short-term effects on fish<br />
Method Results Remarks Reference<br />
Pimephales promelas<br />
freshwater<br />
static<br />
Method: other: EPA/600/4-<br />
90/027, EPA/600/6-91/003<br />
Lepomis macrochirus<br />
freshwater<br />
static<br />
Method: other: Doudroff et al.,<br />
(1951)<br />
Lepomis macrochirus<br />
freshwater<br />
static<br />
Method: other<br />
Gambusia affinis<br />
freshwater<br />
static<br />
Method: other: not mentioned<br />
LC50 (96 h): 4630 mg/L<br />
LC50 (48 h): > 6560 mg/L<br />
LC50 (24 h): > 6660 mg/L<br />
2 (reliable with restrictions)<br />
key study<br />
experimental result<br />
Test material (EC name):<br />
calcium chloride<br />
(96 h): 9500 — 11300 mg/L 2 (reliable with restrictions)<br />
supporting study<br />
experimental result<br />
Test material (EC name):<br />
calcium chloride<br />
LC50 (96 h): 10650 mg/L<br />
LC50 (96 h): 13400 mg/L<br />
Overview of short-term effects on aquatic invertebrates<br />
2 (reliable with restrictions)<br />
supporting study<br />
Test material (EC name):<br />
calcium chloride<br />
2 (reliable with restrictions)<br />
supporting study<br />
experimental result<br />
Test material (EC name):<br />
calcium chloride<br />
Mount, D.R., Gulley,<br />
D.D., Hockett, J.R.,<br />
Garrison, T.D. and<br />
Evans, J.M. (1997a)<br />
Cairns, J., Jr. and<br />
Scheier, A. (1959)<br />
Trama, F.B. (1954)<br />
Method Results Remarks Reference<br />
Daphnia magna<br />
freshwater<br />
static<br />
OECD Guideline 202 (Daphnia<br />
sp. Acute Immobilisation Test)<br />
Ceriodaphnia dubia<br />
freshwater<br />
static<br />
LC50 (48 h): 2400 mg/L<br />
based on: mobility<br />
LC50 (48 h): 1830 mg/L<br />
based on: mobility<br />
1 (reliable without<br />
restriction)<br />
key study<br />
experimental result<br />
Test material (EC name):<br />
calcium chloride<br />
2 (reliable with restrictions)<br />
supporting study<br />
experimental result<br />
Wallen, I.E., Greer,<br />
W.C. and Lasater, R.<br />
(1957)<br />
de Groot, W.A. and<br />
Groeneveld, A.H.C.<br />
(1998)<br />
Mount, D.R., Gulley,<br />
D.D., Hockett, J.R.,<br />
Garrison, T.D. and<br />
page 5 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
Method: other: EPA/600/4-<br />
90/027, EPA/600/6-91/003<br />
other aquatic worm: Tubifex<br />
tubifex<br />
freshwater<br />
semi-static<br />
Method: other<br />
EC50 (96 h): 780 mg/L<br />
based on: mobility<br />
EC50 (48 h): 1830 mg/L<br />
based on: mobility<br />
EC50 (24 h): 2260 mg/L<br />
based on: mobility<br />
other aquatic crustacea: Cyclops LC50 (48 h): 19400 mg/L<br />
abyssorum prealpinus<br />
based on: mortality<br />
freshwater<br />
static<br />
Method: other: not mentioned<br />
other aquatic crustacea:<br />
Eudiaptomus padanus padanus<br />
freshwater<br />
static<br />
Method: other: not mentioned<br />
other aquatic crustacea:<br />
Daphnia hyalina<br />
freshwater<br />
static<br />
Method: other: not mentioned<br />
Caenorhabditis elegans<br />
freshwater<br />
static<br />
Method: other<br />
other aquatic crustacea: Nitocra<br />
spinipes<br />
freshwater<br />
static<br />
Method: other: not mentioned<br />
Daphnia magna<br />
freshwater<br />
static<br />
Method: other: not mentioned<br />
Daphnia magna<br />
static<br />
Method: other: EPA/600/4-<br />
90/027, EPA/600/6-91/003<br />
Daphnia magna<br />
static<br />
Method: other<br />
LC50 (48 h): 11100 mg/L<br />
based on: mortality<br />
LC50 (48 h): 8300 mg/L<br />
based on: mortality<br />
LC50 (24 h): 44400 mg/L<br />
based on: mortality<br />
LC50 (96 h): 1600 mg/L<br />
based on: mortality<br />
LC50 (48 h): 1285 mg/L<br />
based on: mortality<br />
LC50 (48 h): 2770 mg/L<br />
based on: mobility<br />
(48 h): 1062 mg/L based<br />
on: mobility<br />
Test material (EC name):<br />
calcium chloride<br />
2 (reliable with restrictions)<br />
supporting study<br />
experimental result<br />
Test material (EC name):<br />
calcium chloride<br />
2 (reliable with restrictions)<br />
supporting study<br />
experimental result<br />
Test material (EC name):<br />
calcium chloride<br />
2 (reliable with restrictions)<br />
supporting study<br />
experimental result<br />
Test material (EC name):<br />
calcium chloride<br />
2 (reliable with restrictions)<br />
supporting study<br />
experimental result<br />
Test material (EC name):<br />
calcium chloride<br />
2 (reliable with restrictions)<br />
supporting study<br />
experimental result<br />
Test material (EC name):<br />
calcium chloride<br />
2 (reliable with restrictions)<br />
supporting study<br />
experimental result<br />
Test material (EC name):<br />
calcium chloride<br />
2 (reliable with restrictions)<br />
supporting study<br />
experimental result<br />
Test material (EC name):<br />
calcium chloride<br />
2 (reliable with restrictions)<br />
supporting study<br />
experimental result<br />
Test material (EC name):<br />
calcium chloride<br />
2 (reliable with restrictions)<br />
supporting study<br />
experimental result<br />
Test material (EC name):<br />
calcium chloride<br />
Evans, J.M. (1997b)<br />
Khangarot, B.S.<br />
(1991)<br />
Baudouin, M.F. and<br />
Scoppa, P. (1974a)<br />
Baudouin, M.F. and<br />
Scoppa, P. (1974b)<br />
Baudouin, M.F. and<br />
Scoppa, P. (1974a)<br />
Tatara, C.P.,<br />
Newman, M.C.,<br />
McCloskey, J.T. and<br />
Williams, P.L. (1997)<br />
Bengtsson, B.-E.<br />
(1978)<br />
Biesinger, K.E. and<br />
Christensen, G.M.<br />
(1972)<br />
Mount, D.R., Gulley,<br />
D.D., Hockett, J.R.,<br />
Garrison, T.D. and<br />
Evans, J.M.<br />
Khangarot, B.S. and<br />
Ray, P.K. (1989)<br />
Overview of long-term effects on aquatic invertebrates<br />
Method Results Remarks Reference<br />
Daphnia magna EC50 (21 d): 610 mg/L 2 (reliable with restrictions) Biesinger, K.E. and<br />
page 6 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
Method: other: not mentioned<br />
based on: reproductive<br />
impairment<br />
EC16 (21 d): 320 mg/L<br />
based on: reproductive<br />
impairment<br />
LC50 (21 d): 920 mg/L<br />
based on: mortality<br />
key study<br />
experimental result<br />
Test material (EC name):<br />
calcium chloride<br />
Christensen, G.M.<br />
(1972)<br />
Overview of effects on algae and aquatic plants<br />
Method Results Remarks Reference<br />
Selenastrum capricornutum EC50 (72 h): 2900 mg/L<br />
(new name: Pseudokirchneriella based on: biomass<br />
subcapitata) (algae)<br />
EC50 (72 h): > 4000 mg/L<br />
OECD Guideline 201 (Alga, based on: growth rate<br />
Growth Inhibition Test) EC50 (72 h): 27000 mg/L<br />
based on: growth rate<br />
EC20 (72 h): 1000 mg/L<br />
based on: biomass<br />
1 (reliable without<br />
restriction)<br />
key study<br />
experimental result<br />
Test material (EC name):<br />
calcium chloride<br />
de Groot, W.A.<br />
(1998)<br />
12.2. Persistence and degradability<br />
Test not available as product is inorganic.<br />
12.3. Bioaccumulative potential<br />
Product is not biodegrade or accumulate.<br />
12.4. Mobility in soil<br />
In accordance with REACH Annex XI, the study does not need to be conducted as in water; calcium chloride is<br />
dissociated into calcium and chloride ions and chloride ions will not adsorb on particulate matter. The calcium ion<br />
may bind to particulate matter or may form stable inorganic salts with sulphate and carbonate ions, but calcium is<br />
naturally present in soil. Therefore, exposure of the soil compartment is unlikely.<br />
12.5. Results of PBT and vPvB assessment<br />
According to Annex XIII of the REACH Regulation 1907/2006/EC inorganic substances do not need to be subjected<br />
to a PBT assessment.<br />
12.6. Other adverse effects<br />
None identified.<br />
SECTION 13. DISPOSAL CONSIDERATIONS<br />
13.1. Waste treatment methods<br />
Observe federal, state, and local regulations when disposing of this substance.<br />
DISPOSAL METHOD: Dispose of waste at an appropriate waste disposal facility according to current applicable<br />
laws and regulations.<br />
FOR LARGE SPILLS: Contain material according to section 6.<br />
PRODUCT DISPOSAL: Dispose of at a supervised incineration facility or an appropriate waste disposal facility<br />
according to current applicable laws and regulations and product characteristics at time of disposal.<br />
EMPTY CONTAINER: Rinse drums with a suitable solvent and steam to remove vapors before disposal or reuse in<br />
accordance with applicable regulations<br />
SECTION 14. TRANSPORT INFORMATION<br />
14.1. UN number Not applicable<br />
page 7 of 34
14.2. UN proper shipping name Not regulated<br />
14.3. Transport hazard class(es) Not applicable<br />
14.4. Packing group Not applicable<br />
14.5. Environmental hazards Not applicable<br />
14.6. Special precautions for user Not applicable<br />
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable<br />
SECTION 15. REGULATORY INFORMATION<br />
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture<br />
General principles of protection EH 44<br />
15.2. Chemical safety assessment<br />
A chemical safety assessment has been performed for calcium chloride according to REACH.<br />
SECTION 16. OTHER INFORMATION<br />
To the best of our knowledge, this Safety Data Sheet conforms to the requirements of:<br />
- Regulation (EC) №1907/2006 of the European Parliament and of the Council of 18 December 2006<br />
- Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008<br />
- Commission Regulation (RU) №453/2010 of 20.05.2010<br />
List of relevant R phrases, hazard statement, safety phrases and precautionary statement:<br />
According to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008:<br />
HAZARD STATEMENT: H319: Causes serious eye irritation<br />
PRECAUTIONARY STATEMENTS:<br />
P 264: Wash hands thoroughly after handling.<br />
P 280: Wear protective glasses with splash shields or safety goggles/shield.<br />
P305 + P351 + P338: IF IN EYES Rinse eyes cautiously with water for 15 <strong>min</strong>utes. Remove contact lenses, if<br />
present and easy to do. Continue rinsing.<br />
P337 + P 313 If irritation continued get prompt qualified medical advice / attention.<br />
According to Directive 67/548/EEC:<br />
Xi Irritant<br />
R36 Irritating to eyes<br />
S-phrases:<br />
(S2) - keep out of the reach of children<br />
S22 - do not breathe dust<br />
S24 - avoid contact with skin<br />
Individuals handling this product should be informed of the recommended safety precautions and should have<br />
access to this information. It is the users' responsibility to satisfy themselves as to the suitability and completeness<br />
of such information for their own particular use. We do not accept liability for any loss or damage that may occur<br />
from the use of this information nor do we offer warranty against patent infringement.<br />
ZIRAX LLC reserves the right to refuse shipment of this product to any customer who fails to demonstrate the<br />
ability to consistently handle and use it safely and in compliance with all applicable laws, rules and regulations.<br />
Such demonstration may require on-site inspection of any or all storage, processing, packaging and other handling<br />
systems that come in contact with it.<br />
page 8 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
ANNEX 1<br />
The overview of exposure scenarios of <strong>Calcium</strong> <strong>Chloride</strong><br />
Life Cycle Stage(s) covered by the<br />
IU<br />
Short description of<br />
Identified Use<br />
Product<br />
Category<br />
(PC)<br />
Manufacture<br />
Formulation<br />
End Use<br />
Industrial<br />
Professional<br />
Consumer<br />
Service Life (for<br />
article)<br />
Sector of use<br />
(SU)<br />
Process Category<br />
(Proc)<br />
Article<br />
Category<br />
(AC)<br />
Environmental<br />
Release<br />
Category<br />
(ERC)<br />
ES1: Production of<br />
calcium chloride<br />
Not applicable X SU8 (SU3) PROC1, PROC2, PROC3,<br />
PROC4, PROC6, PROC8a,<br />
PROC8b, PROC9,<br />
PROC15, PROC26<br />
Not<br />
applicable<br />
ERC1<br />
ES2: Use of calcium<br />
chloride as chemical<br />
intermediate<br />
Not applicable X SU8, SU9, SU14<br />
(SU1, SU3, SU4,<br />
SU5, SU6b)<br />
PROC1, PROC2, PROC3,<br />
PROC4, PROC6, PROC8a,<br />
PROC8b, PROC9,<br />
PROC15, PROC22a,<br />
PROC22b, PROC22c,<br />
PROC23a, PROC23b,<br />
PROC23c, PROC26 1 ,<br />
PROC27a 2 , PROC27b 3<br />
Not<br />
applicable<br />
ERC6a<br />
1<br />
No specific assessment has been performed with ECTOC TRA for this PROC, but activities for PROC 26 (handling of solid inorganic substances at abient temperature) are covered within this<br />
scenario.<br />
2<br />
No specific assessment has been performed with ECTOC TRA for this PROC, but activities for PROC27a (Production of metal powders (hot processes)) are covered within this scenario by<br />
PROC22 and PROC23.<br />
3<br />
No specific assessment has been performed with ECTOC TRA for this PROC, but activities for PROC 27b (Production of metal powders (wet processes)) are covered within this scenario.<br />
page 9 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
Life Cycle Stage(s) covered by the<br />
IU<br />
Short description of<br />
Identified Use<br />
Product<br />
Category<br />
(PC)<br />
Manufacture<br />
Formulation<br />
End Use<br />
Industrial<br />
Professional<br />
Consumer<br />
Service Life (for<br />
article)<br />
Sector of use<br />
(SU)<br />
Process Category<br />
(Proc)<br />
Article<br />
Category<br />
(AC)<br />
Environmental<br />
Release<br />
Category<br />
(ERC)<br />
ES3: Formulation and/or<br />
distribution of <strong>Calcium</strong><br />
<strong>Chloride</strong><br />
Not applicable X SU19 (SU1,<br />
SU2a,<br />
SU2b,SU3, SU4,<br />
SU5, SU6b, SU8,<br />
SU11, SU12,<br />
SU13, SU14,<br />
SU15, SU19,<br />
SU20, SU0-<br />
C23.5/ C23.6)<br />
PROC1, PROC2, PROC3,<br />
PROC5,<br />
PROC6, PROC8a,<br />
PROC8b, PROC9,<br />
PROC14, PROC15<br />
PROC26 1 , PROC27a 2 ,<br />
PROC27b 3<br />
Not<br />
applicable<br />
ERC2<br />
ES4: Use of calcium<br />
chloride as processing aid<br />
Not applicable X SU3 (SU1, SU2a,<br />
SU2b, SU4, SU5,<br />
SU6b, SU8, SU9,<br />
SU10, SU11,<br />
SU12, SU13,<br />
SU14, SU15,<br />
SU16, SU17)<br />
PROC1, PROC2, PROC3,<br />
PROC4, PROC6, PROC7,<br />
PROC8a, PROC8b,<br />
PROC9, PROC10,<br />
PROC13, PROC15,<br />
PROC22a, PROC22b,<br />
PROC22c, PROC23a,<br />
PROC23b, PROC23c,<br />
PROC26 1 , PROC27a 2 ,<br />
PROC27b 3<br />
Not<br />
applicable<br />
ERC4<br />
ES5: Industrial outdoor<br />
use of calcium chlorideend<br />
use<br />
Not applicable X SU3(SU1, SU2a,<br />
SU2b)<br />
PROC1, PROC2, PROC5,<br />
PROC7, PROC8a,<br />
PROC8b,<br />
Not<br />
applicable<br />
ERC4<br />
page 10 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
Life Cycle Stage(s) covered by the<br />
IU<br />
Short description of<br />
Identified Use<br />
Product<br />
Category<br />
(PC)<br />
Manufacture<br />
Formulation<br />
End Use<br />
Industrial<br />
Professional<br />
Consumer<br />
Service Life (for<br />
article)<br />
Sector of use<br />
(SU)<br />
Process Category<br />
(Proc)<br />
Article<br />
Category<br />
(AC)<br />
Environmental<br />
Release<br />
Category<br />
(ERC)<br />
PROC9, PROC13,<br />
PROC19,<br />
PROC26 1 ,<br />
ES6: Professional indoor<br />
use of calcium chloride<br />
Not applicable X SU22 (SU1,<br />
SU10, SU19,<br />
SU20, SU0-<br />
C23.5/ C23.6)<br />
PROC1, PROC2, PROC3,<br />
PROC4, PROC5, PROC8a,<br />
PROC8b, PROC9<br />
PROC10, PROC11,<br />
PROC15, PROC19,<br />
PROC20, PROC26 1 ,<br />
Not<br />
applicable<br />
ERC8a,<br />
ERC8d<br />
ES7: Professional outdoor<br />
use of calcium chloride<br />
Not applicable X SU22 (SU1, SU5,<br />
SU10, SU13,<br />
SU19, SU20,<br />
SU0- C23.5/<br />
C23.6)<br />
PROC1, PROC2, PROC5,<br />
PROC8a, PROC8b,<br />
PROC9, PROC10<br />
PROC11, PROC13,<br />
PROC19, PROC20<br />
PROC26 1<br />
Not<br />
applicable<br />
ERC8d<br />
ES8: Handling of<br />
(aqueous) calcium<br />
chloride<br />
X X SU3,SU22 (SU1,<br />
SU2a,SU4,SU5,S<br />
U6b,SU8,SU9,<br />
SU10,<br />
SU11,SU12,SU1<br />
3, SU14,SU15<br />
SU19, SU20,<br />
PROC1, PROC2, PROC3,<br />
PROC4, PROC5, PROC6,<br />
PROC7, PROC8a,<br />
PROC8b, PROC9,<br />
PROC10, PROC11,<br />
PROC13, PROC14,<br />
PROC15<br />
Not<br />
applicable<br />
ERC1, ERC6a,<br />
ERC2, ERC4,<br />
ERC8a, ERC8d<br />
page 11 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
Life Cycle Stage(s) covered by the<br />
IU<br />
Short description of<br />
Identified Use<br />
Product<br />
Category<br />
(PC)<br />
Manufacture<br />
Formulation<br />
End Use<br />
Industrial<br />
Professional<br />
Consumer<br />
Service Life (for<br />
article)<br />
Sector of use<br />
(SU)<br />
Process Category<br />
(Proc)<br />
Article<br />
Category<br />
(AC)<br />
Environmental<br />
Release<br />
Category<br />
(ERC)<br />
SU0- C23.5/<br />
C23.6)<br />
ES9: Handling of calcium<br />
chloride with low<br />
dustiness<br />
X X SU3,SU22 (SU1,<br />
SU2a,SU4,SU5,S<br />
U6b,SU8,SU9,<br />
SU10,<br />
SU11,SU12,SU1<br />
3, SU14,SU15<br />
SU19, SU20,<br />
SU0- C23.5/<br />
C23.6)<br />
PROC1, PROC2, PROC3,<br />
PROC4, PROC5, PROC6,<br />
PROC7, PROC8a,<br />
PROC8b, PROC9,<br />
PROC10, PROC11,<br />
PROC13, PROC14,<br />
PROC15, PROC22a,<br />
PROC22b, PROC22c,<br />
PROC23a, PROC23b,<br />
PROC23c<br />
Not<br />
applicable<br />
ERC1, ERC6a,<br />
ERC2, ERC4,<br />
ERC8a, ERC8d<br />
ES10: Use of calcium<br />
chloride by consumers<br />
PC2, PC5,<br />
PC35, PC37,<br />
PC4, PC12, PC<br />
27,PC16, PC0-<br />
UCN code<br />
K35100<br />
X SU21 Not applicable Not<br />
applicable<br />
ERC8a,<br />
ERC8d<br />
page 12 of 34
9.1. Production of calcium chloride<br />
9.1.1. Exposure scenario – Production (ES1)<br />
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
Section 1<br />
Exposure Scenario Title<br />
Title Production of calcium chloride; CAS: 10043-52-4<br />
Use Descriptor<br />
Processes, tasks,<br />
activities covered<br />
Section 2<br />
Field for additional<br />
statements to<br />
explain scenario if<br />
required.<br />
Section 2.1<br />
Product<br />
characteristics<br />
Physical form of<br />
product<br />
Concentration of<br />
substance in<br />
product<br />
Amounts used<br />
Frequency and<br />
duration of use<br />
Human factors not<br />
influenced by risk<br />
management<br />
Other Operational<br />
Conditions affecting<br />
worker exposure<br />
Contributing<br />
Scenarios<br />
Sector of Use: Industrial SU8, (SU3)<br />
Process Categories: PROC1, PROC2, PROC3, PROC4, PROC6,<br />
PROC8a, PROC8b, PROC9, PROC15,PROC26<br />
Environmental Release Categories: ERC1<br />
Manufacturing of <strong>Calcium</strong> <strong>Chloride</strong>, includes recycling/ recovery,<br />
material transfers, storage, maintenance and loading (including marine<br />
vessel/barge, road/rail car and bulk container), sampling and<br />
associated laboratory activities.<br />
Operational conditions and risk management measures<br />
Control of worker exposure<br />
Solid, medium dustiness [OC2]<br />
Covers percentage substance in the product up to 100 % (unless<br />
stated differently) [G13].<br />
Not applicable<br />
Covers daily exposures up to 8 hours (unless stated differently) [G2]<br />
Not applicable<br />
Assumes use at not more than 20°C above ambient temperature,<br />
unless stated differently [G15].;<br />
Assumes a good basic standard of occupational hygiene is<br />
implemented [G1].<br />
Risk Management Measures<br />
Note: list RMM standard phrases according to the control hierarchy<br />
indicated in the ECHA template: 1. <strong>Technical</strong> measures to prevent<br />
release, 2. <strong>Technical</strong> measures to prevent dispersion, 3. Organisational<br />
measures, 4. Personal protection.<br />
Justification<br />
General measures<br />
(irritants) [G19].<br />
General exposures<br />
[CS1]. With sample<br />
collection [CS56].<br />
General exposures<br />
[CS1]. Continuous<br />
process [CS54]. ;<br />
Avoid all skin contact with product, clean up conta<strong>min</strong>ation/spills as<br />
soon as they occur. Wear gloves (tested to EN374) if hand<br />
conta<strong>min</strong>ation likely, wash off any skin conta<strong>min</strong>ation immediately.<br />
Provide basic employee training to prevent / <strong>min</strong>imise exposures and<br />
to report any skin problems that may develop [E3].Use suitable eye<br />
protection [PPE26].<br />
Provide a good standard of general ventilation. Natural ventilation is<br />
from doors, windows etc. Controlled ventilation means air is supplied<br />
or removed by a powered fan. [E1].<br />
Provide a good standard of general ventilation. Natural ventilation is<br />
from doors, windows etc. Controlled ventilation means air is supplied<br />
or removed by a powered fan. [E1].<br />
measured<br />
data, see 9.1.2<br />
(PROC1)<br />
measured<br />
data, see 9.1.2<br />
(PROC2)<br />
page 13 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
With sample<br />
collection [CS56].<br />
General exposures<br />
[CS1]. Use in<br />
contained batch<br />
processes [CS37].<br />
General exposures<br />
(open systems)<br />
[CS16].<br />
Batch process<br />
[CS55]. With<br />
sample collection<br />
[CS56]. ;<br />
Filling / preparation<br />
of equipment from<br />
drums<br />
or<br />
containers. [CS45].<br />
Calendering<br />
(including<br />
Banburys) [CS64]<br />
Process sampling<br />
[CS2]. Dedicated<br />
facility [CS81]<br />
Laboratory activities<br />
[CS36].<br />
Process sampling<br />
[CS2]. Nondedicated<br />
facility<br />
[CS82]<br />
Drum/batch<br />
transfers [CS8].<br />
Transport [CS58].<br />
bulk open loading<br />
and unloading<br />
[CS503]Nondedicated<br />
facility<br />
[CS82]<br />
bulk closed loading<br />
and unloading<br />
[CS501]Dedicated<br />
facility [CS81]<br />
Equipment cleaning<br />
and maintenance<br />
[CS39]. Nondedicated<br />
facility<br />
[CS82]<br />
Storage<br />
[CS67].General<br />
exposures (closed<br />
systems) [CS15].<br />
Storage<br />
[CS67].With sample<br />
collection [CS56].<br />
Provide a good standard of general ventilation. Natural ventilation is<br />
from doors, windows etc. Controlled ventilation means air is supplied<br />
or removed by a powered fan. [E1].<br />
Provide a good standard of general ventilation. Natural ventilation is<br />
from doors, windows etc. Controlled ventilation means air is supplied<br />
or removed by a powered fan. [E1].<br />
Provide a good standard of general ventilation. Natural ventilation is<br />
from doors, windows etc. Controlled ventilation means air is supplied<br />
or removed by a powered fan. [E1].<br />
Provide a good standard of general ventilation. Natural ventilation is<br />
from doors, windows etc. Controlled ventilation means air is supplied<br />
or removed by a powered fan. [E1].<br />
Provide a good standard of general ventilation. Natural ventilation is<br />
from doors, windows etc. Controlled ventilation means air is supplied<br />
or removed by a powered fan. [E1].<br />
Provide a good standard of general ventilation. Natural ventilation is<br />
from doors, windows etc. Controlled ventilation means air is supplied<br />
or removed by a powered fan. [E1].<br />
Provide a good standard of general ventilation. Natural ventilation is<br />
from doors, windows etc. Controlled ventilation means air is supplied<br />
or removed by a powered fan. [E1].<br />
Provide a good standard of general ventilation. Natural ventilation is<br />
from doors, windows etc. Controlled ventilation means air is supplied<br />
or removed by a powered fan. [E1].<br />
Provide a good standard of general ventilation. Natural ventilation is<br />
from doors, windows etc. Controlled ventilation means air is supplied<br />
or removed by a powered fan. [E1].<br />
Provide a good standard of general ventilation. Natural ventilation is<br />
from doors, windows etc. Controlled ventilation means air is supplied<br />
or removed by a powered fan. [E1].<br />
Provide a good standard of general ventilation. Natural ventilation is<br />
from doors, windows etc. Controlled ventilation means air is supplied<br />
or removed by a powered fan. [E1].<br />
Provide a good standard of general ventilation. Natural ventilation is<br />
from doors, windows etc. Controlled ventilation means air is supplied<br />
or removed by a powered fan. [E1].<br />
measured<br />
data, see 9.1.2<br />
(PROC3)<br />
measured<br />
data, see 9.1.2<br />
(PROC4)<br />
measured<br />
data, see<br />
9.1.2.(PROC6)<br />
measured<br />
data, see 9.1.2<br />
(PROC8b)<br />
measured<br />
data, see 9.1.2<br />
(PROC8a)<br />
measured<br />
data, see 9.1.2<br />
(PROC9)<br />
measured<br />
data, see 9.1.2<br />
(PROC15)<br />
measured<br />
data, see 9.1.2<br />
(PROC8a)<br />
measured<br />
data, see 9.1.2<br />
(PROC8b)<br />
measured<br />
data, see 9.1.2<br />
(PROC8a)<br />
measured<br />
data, see 9.1.2<br />
(PROC1)<br />
measured<br />
data, see 9.1.2<br />
(PROC2)<br />
page 14 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
9.2. Use of calcium chloride as chemical intermediate<br />
9.2.1. Exposure scenario – Use as an intermediate (ES2)<br />
Section 1<br />
Title<br />
Use Descriptor<br />
Exposure Scenario Title<br />
Use of <strong>Calcium</strong> <strong>Chloride</strong> as chemical intermediate; CAS:<br />
10043-52-4<br />
Sector of Use: Industrial SU8, SU9, SU14 (SU1, SU3, SU4, SU5,<br />
SU6b)<br />
Processes, tasks, activities covered<br />
Section 2<br />
Field for additional statements to explain<br />
scenario if required.<br />
Section 2.1<br />
Product characteristics<br />
Physical form of product<br />
Concentration of substance in product<br />
Amounts used<br />
Frequency and duration of use<br />
Human factors not influenced by risk<br />
management<br />
Other Operational Conditions affecting<br />
worker exposure<br />
Contributing Scenarios<br />
Process Categories: PROC1, PROC2, PROC3, PROC4, PROC6,<br />
PROC8a, PROC8b, PROC9, PROC15, PROC22a, PROC22b, PROC22c,<br />
PROC23a, PROC23b, PROC23c<br />
Environmental Release Categories: ERC 6a<br />
Use of <strong>Calcium</strong> <strong>Chloride</strong> as chemical intermediate. Use as an<br />
intermediate. Includes recycling/ recovery, material transfers,<br />
storage, maintenance and loading (including marine vessel/barge,<br />
road/rail car and bulk container), sampling and associated<br />
laboratory activities.<br />
Operational conditions and risk management measures<br />
Control of worker exposure<br />
Solid, medium dustiness [OC2]<br />
Covers percentage substance in the product up to 100 % (unless<br />
stated differently) [G13].<br />
Not applicable<br />
Covers daily exposures up to 8 hours (unless stated differently)<br />
[G2]<br />
Not applicable<br />
Assumes use at not more than 20°C above ambient temperature,<br />
unless stated differently [G15].;<br />
Assumes a good basic standard of occupational hygiene is<br />
implemented [G1].<br />
Risk Management Measures<br />
Note: list RMM standard phrases according to the control hierarchy<br />
indicated in the ECHA template: 1. <strong>Technical</strong> measures to prevent<br />
release, 2. <strong>Technical</strong> measures to prevent dispersion, 3.<br />
Organisational measures , 4. Personal protection.<br />
General measures (irritants) [G19].<br />
General exposures [CS1].<br />
With sample collection [CS56].<br />
General exposures [CS1].<br />
Continuous process [CS54].<br />
With sample collection [CS56].<br />
Avoid all skin contact with product, clean up conta<strong>min</strong>ation/spills as<br />
soon as they occur. Wear gloves (tested to EN374) if hand<br />
conta<strong>min</strong>ation likely, wash off any skin conta<strong>min</strong>ation immediately.<br />
Provide basic employee training to prevent / <strong>min</strong>imise exposures<br />
and to report any skin problems that may develop [E3].Use suitable<br />
eye protection [PPE26].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
page 15 of 34
General exposures [CS1].<br />
Use in contained batch processes<br />
[CS37].<br />
General exposures (open systems)<br />
[CS16].<br />
Batch process [CS55].<br />
With sample collection [CS56].<br />
Filling / preparation of equipment from<br />
drums or containers. [CS45].<br />
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
No specific measures identified [EI18].<br />
Provide a good standard of general ventilation (not less than 3 to 5<br />
air changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />
better [PPE29]<br />
Calendering (including Banburys) [CS64] Provide a good standard of general ventilation (not less than 3 to 5<br />
air changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />
better [PPE29]<br />
Process sampling [CS2]. Dedicated Provide a good standard of general ventilation (not less than 3 to 5<br />
facility [CS81]<br />
air changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />
better [PPE29]<br />
Process sampling [CS2].<br />
Non-dedicated facility [CS82].<br />
Avoid carrying out operation for more than 1 hour [OC11]<br />
Drum/batch transfers [CS8].<br />
Transport [CS58].<br />
Laboratory activities [CS36].<br />
Bulk open loading and unloading<br />
[CS503].<br />
Non-dedicated facility [CS82]<br />
bulk closed loading and unloading<br />
[CS501]Dedicated facility [CS81]<br />
Equipment cleaning and maintenance<br />
[CS39].<br />
Non-dedicated facility [CS82].<br />
General exposures (closed systems)<br />
[CS15]. Elevated temperature [CS111].<br />
Process temperature ≤ melting point<br />
<strong>Calcium</strong> <strong>Chloride</strong><br />
General exposures (closed systems)<br />
[CS15]. Elevated temperature [CS111].<br />
Process temperature > melting point<br />
<strong>Calcium</strong> <strong>Chloride</strong><br />
Material transfers [CS3].<br />
(open systems) [CS108].<br />
Batch processes at elevated<br />
temperatures [CS136].<br />
Process temperature ≤ melting point<br />
<strong>Calcium</strong> <strong>Chloride</strong><br />
Material transfers [CS3].<br />
(open systems) [CS108].<br />
Batch processes at elevated<br />
temperatures [CS136].<br />
Process temperature > melting point<br />
<strong>Calcium</strong> <strong>Chloride</strong><br />
Provide a good standard of general ventilation (not less than 3 to 5<br />
air changes per hour) [E11., or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />
better [PPE29]<br />
No specific measures identified [EI18].<br />
Provide a good standard of general ventilation (not less than 3 to 5<br />
air changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />
better [PPE29]<br />
Provide a good standard of general ventilation (not less than 3 to 5<br />
air changes per hour) [E11]., or: Wear a respirator confor<strong>min</strong>g to<br />
EN140 with Type A/P2 filter or better [PPE29]<br />
Drain or remove substance from equipment prior to break-in or<br />
maintenance [E81], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />
better [PPE29]<br />
No specific measures identified [EI18].<br />
Provide extract ventilation to points where emissions occur [E54],<br />
or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />
better [PPE29]<br />
No specific measures identified [EI18].<br />
Provide a good standard of controlled ventilation (10 to 15 air<br />
changes per hour) [E40]., or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />
better [PPE29]<br />
page 16 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
Storage [CS67].<br />
General exposures (closed systems)<br />
[CS15].<br />
Storage [CS67].<br />
With sample collection [CS56].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
9.3. Formulation and/or distribution of calcium chloride<br />
9.3.1. Exposure scenario – Formulation and/or distribution (ES3)<br />
Section 1<br />
Title<br />
Use Descriptor<br />
Processes, tasks, activities covered<br />
Section 2<br />
Field for additional statements to<br />
explain scenario if required.<br />
Section 2.1<br />
Product characteristics<br />
Physical form of product<br />
Concentration of substance in product<br />
Amounts used<br />
Frequency and duration of use<br />
Human factors not influenced by risk<br />
management<br />
Other Operational Conditions affecting<br />
worker exposure<br />
Contributing Scenarios<br />
General measures (irritants) [G19].<br />
Exposure Scenario Title<br />
Formulation and/or distribution of <strong>Calcium</strong> <strong>Chloride</strong>; CAS:<br />
10043-52-4<br />
Sector of Use: Industrial SU10 (SU1, SU2, SU3, SU4, SU5, SU6b, SU8,<br />
SU11, SU12, SU13, SU14, SU15, SU19, SU20, SU0- C23.5/ C23.6)<br />
Process Categories: PROC1, PROC2, PROC3, PROC5, PROC 6, PROC8a,<br />
PROC8b, PROC9, PROC14, PROC15<br />
Environmental Release Categories: ERC2<br />
Formulation and distribution , packing and re-packing (including drums<br />
and small packs) of the <strong>Calcium</strong> <strong>Chloride</strong> and its mixtures in batch or<br />
continuous operations, including storage, materials transfers, mixing,<br />
large and small scale packing, loading (including marine vessel/barge,<br />
rail/road car and IBC loading), maintenance and associated laboratory<br />
activities. e.g. production of adsorbents, cosmetics, metals, fertilizers,<br />
plant protection, cement, haemodialysis solution and general<br />
distributor activities with <strong>Calcium</strong> <strong>Chloride</strong><br />
Operational conditions and risk management measures<br />
Control of worker exposure<br />
Solid, medium dustiness [OC2]<br />
Covers percentage substance in the product up to 100 % (unless<br />
stated differently) [G13].<br />
Not applicable<br />
Covers daily exposures up to 8 hours (unless stated differently) [G2]<br />
Not applicable<br />
Assumes use at not more than 20°C above ambient temperature,<br />
unless stated differently [G15].<br />
Assumes a good basic standard of occupational hygiene is<br />
implemented [G1].<br />
Risk Management Measures<br />
Note: list RMM standard phrases according to the control hierarchy<br />
indicated in the ECHA template: 1. <strong>Technical</strong> measures to prevent<br />
release, 2. <strong>Technical</strong> measures to prevent dispersion, 3. Organisational<br />
measures , 4. Personal protection.<br />
Avoid all skin contact with product, clean up conta<strong>min</strong>ation/spills as<br />
soon as they occur. Wear gloves (tested to EN374) if hand<br />
conta<strong>min</strong>ation likely, wash off any skin conta<strong>min</strong>ation immediately.<br />
page 17 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
General exposures [CS1].<br />
Continuous process [CS54].<br />
General exposures [CS1].<br />
Continuous process [CS54].<br />
With sample collection [CS56].<br />
General exposures [CS1].<br />
Use in contained batch processes<br />
[CS37].<br />
Mixing operations (open systems)<br />
[CS30].<br />
Calendering (including Banburys)<br />
[CS64]<br />
Bulk open loading and unloading<br />
[CS503].<br />
Non-dedicated facility [CS82]<br />
Bulk closed loading and unloading<br />
[CS501].<br />
Dedicated facility [CS81]<br />
Drum/batch transfers [CS8].<br />
Transport [CS58].<br />
Tabletting, compression, extrusion or<br />
pelletisation [CS506].<br />
Laboratory activities [CS36].<br />
Process sampling [CS2].<br />
Dedicated facility [CS81]<br />
Process sampling [CS2].<br />
Non-dedicated facility [CS82].<br />
Equipment cleaning and maintenance<br />
[CS39].<br />
Non-dedicated facility [CS82].<br />
Storage [CS67].<br />
General exposures (closed systems)<br />
[CS15].<br />
Storage [CS67].<br />
General exposures (closed systems)<br />
[CS15].<br />
With sample collection [CS56].<br />
Provide basic employee training to prevent / <strong>min</strong>imise exposures and<br />
to report any skin problems that may develop [E3].<br />
Use suitable eye protection [PPE26].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11].<br />
or: Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />
better [PPE29]<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Avoid carrying out operation for more than 1 hour [OC11].<br />
Drain or remove substance from equipment prior to break-in or<br />
maintenance [E81], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
page 18 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
9.4. Use of calcium chloride as processing aid<br />
9.4.1. Exposure scenario – Use of calcium chloride as processing aid (ES4)<br />
Section 1<br />
Exposure Scenario Title<br />
Title Use of <strong>Calcium</strong> <strong>Chloride</strong> as processing aid; CAS: 10043-52-4<br />
Use Descriptor<br />
Processes, tasks, activities covered<br />
Section 2<br />
Field for additional statements to<br />
explain scenario if required.<br />
Section 2.1<br />
Product characteristics<br />
Physical form of product<br />
Concentration of substance in product<br />
Amounts used<br />
Frequency and duration of use<br />
Sector of Use: Industrial SU3 (SU1, SU2a, SU2b, SU4, SU5, SU6b, SU8,<br />
SU9, SU10, SU11, SU12, SU13, SU14, SU15, SU16, SU17)<br />
Process Categories: PROC1, PROC2, PROC3, PROC4, PROC6, PROC7,<br />
PROC8a, PROC8b, PROC9, PROC10, PROC13, PROC15, PROC22a,<br />
PROC22b PROC22c, PROC23a, PROC23b, PROC23c<br />
Environmental Release Categories: ERC 4<br />
Use of <strong>Calcium</strong> <strong>Chloride</strong> as processing aid. Use as a process chemical<br />
or extraction agent. Includes recycling/ recovery, material transfers,<br />
storage, maintenance and loading (including marine vessel/barge,<br />
road/rail car and bulk container), sampling and associated laboratory<br />
activities. E.g. functions as adsorbent, coagulant, emulsion breaker,<br />
alginates, extraction agent, completion fluid, heat transfer fluid, water<br />
treatment chemical or use within the paper industry for example as<br />
antistatic<br />
Operational conditions and risk management measures<br />
Control of worker exposure<br />
Solid, medium dustiness [OC2].<br />
Covers percentage substance in the product up to 100 % (unless<br />
stated differently) [G13].<br />
Not applicable<br />
Covers daily exposures up to 8 hours (unless stated differently) [G2]<br />
Human factors not influenced by risk<br />
management<br />
Other Operational Conditions affecting<br />
worker exposure<br />
Contributing Scenarios<br />
General measures (irritants) [G19].<br />
General exposures [CS1].<br />
Continuous process [CS54].<br />
Not applicable<br />
Assumes use at not more than 20°C above ambient temperature,<br />
unless stated differently [G15].;<br />
Assumes a good basic standard of occupational hygiene is<br />
implemented [G1].<br />
Risk Management Measures<br />
Note: list RMM standard phrases according to the control hierarchy<br />
indicated in the ECHA template: 1. <strong>Technical</strong> measures to prevent<br />
release, 2. <strong>Technical</strong> measures to prevent dispersion, 3. Organisational<br />
measures, 4. Personal protection.<br />
Avoid all skin contact with product, clean up conta<strong>min</strong>ation/spills as<br />
soon as they occur. Wear gloves (tested to EN374) if hand<br />
conta<strong>min</strong>ation likely, wash off any skin conta<strong>min</strong>ation immediately.<br />
Provide basic employee training to prevent / <strong>min</strong>imise exposures and<br />
to report any skin problems that may develop [E3]. Use suitable eye<br />
protection [PPE26].<br />
No specific measures identified [EI18].<br />
page 19 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
General exposures [CS1].<br />
Continuous process [CS54].<br />
With sample collection [CS56].<br />
General exposures [CS1].<br />
Use in contained batch processes<br />
[CS37].<br />
General exposures (open systems)<br />
[CS16].<br />
Batch process [CS55].<br />
With sample collection [CS56].<br />
Filling / preparation of equipment from<br />
drums or containers. [CS45].<br />
Calendering (including Banburys)<br />
[CS64]<br />
Spraying [CS10].<br />
Bulk open loading and unloading<br />
[CS503].<br />
Non-dedicated facility [CS82]<br />
Bulk closed loading and unloading<br />
[CS501].<br />
Dedicated facility [CS81]<br />
Drum/batch transfers [CS8].<br />
Transport [CS58].<br />
Rolling, Brushing [CS51].<br />
Dipping, immersion and pouring<br />
[CS4].<br />
Laboratory activities [CS36].<br />
Equipment cleaning and maintenance<br />
[CS39]. Non-dedicated facility [CS82]<br />
Process sampling [CS2].<br />
Dedicated facility [CS81]<br />
Process sampling [CS2].<br />
Non-dedicated facility [CS82]<br />
General exposures (closed systems)<br />
[CS15]. Elevated temperature<br />
[CS111].<br />
Process temperature ≤ melting point<br />
<strong>Calcium</strong> <strong>Chloride</strong><br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Minimise exposure by partial enclosure of the operation or equipment<br />
and provide extract ventilation at openings [E60]. or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
Drain or remove substance from equipment prior to break-in or<br />
maintenance [E81], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Avoid carrying out operation for more than 4 hours [OC12].<br />
No specific measures identified [EI18].<br />
page 20 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
General exposures (closed systems)<br />
[CS15]. Elevated temperature<br />
[CS111].<br />
Process temperature > melting point<br />
<strong>Calcium</strong> <strong>Chloride</strong><br />
Material transfers [CS3].<br />
(open systems) [CS108].<br />
Batch processes at elevated<br />
temperatures [CS136].<br />
Process temperature ≤ melting point<br />
<strong>Calcium</strong> <strong>Chloride</strong><br />
Material transfers [CS3].<br />
(open systems) [CS108].<br />
Batch processes at elevated<br />
temperatures [CS136].<br />
Process temperature > melting point<br />
<strong>Calcium</strong> <strong>Chloride</strong><br />
Storage [CS67].<br />
General exposures (closed systems)<br />
[CS15].<br />
Provide a good standard of controlled ventilation (10 to 15 air changes<br />
per hour) [E40], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
No specific measures identified [EI18].<br />
Provide a good standard of controlled ventilation (10 to 15 air changes<br />
per hour) [E40], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
No specific measures identified [EI18].<br />
9.5. Industrial outdoor use of calcium chloride - end use<br />
9.5.1. Exposure scenario – Industrial outdoor use (ES5)<br />
Section 1<br />
Exposure Scenario Title<br />
Title ES5: Industrial outdoor use of <strong>Calcium</strong> <strong>Chloride</strong>; CAS: 10043-<br />
52-4<br />
Use Descriptor<br />
Sector of Use: Industrial SU3 (SU1, SU2)<br />
Process Categories: PROC1, PROC2, PROC5, PROC7, PROC8a,<br />
PROC8b, PROC9, PROC13, PROC19<br />
Environmental Release Categories: ERC4<br />
Processes, tasks, activities covered<br />
Section 2<br />
Field for additional statements to<br />
explain scenario if required.<br />
Section 2.1<br />
Product characteristics<br />
Physical form of product<br />
Concentration of substance in product<br />
Amounts used<br />
Frequency and duration of use<br />
Human factors not influenced by risk<br />
management<br />
Industrial outdoor use of <strong>Calcium</strong> <strong>Chloride</strong>. Covers the end use of<br />
<strong>Calcium</strong> chloride either pure or in formulation by spreading, spraying<br />
and pouring. Including storage, materials transfers, mixing, loading<br />
and maintenance. E.g. the use of dust suppression - and de-icingmixtures.<br />
Operational conditions and risk management measures<br />
Control of worker exposure<br />
Solid, medium dustiness [OC2].<br />
Covers percentage substance in the product up to 100 % (unless<br />
stated differently) [G13].<br />
Not applicable<br />
Covers daily exposures up to 8 hours (unless stated differently) [G2]<br />
Not applicable<br />
page 21 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
Other Operational Conditions affecting<br />
worker exposure<br />
Contributing Scenarios<br />
Assumes use at not more than 20°C above ambient temperature,<br />
unless stated differently [G15].<br />
Assumes a good basic standard of occupational hygiene is<br />
implemented [G1].<br />
Outdoor [OC9].<br />
Risk Management Measures<br />
Note: list RMM standard phrases according to the control hierarchy<br />
indicated in the ECHA template: 1. <strong>Technical</strong> measures to prevent<br />
release, 2. <strong>Technical</strong> measures to prevent dispersion, 3. Organisational<br />
measures, 4. Personal protection.<br />
General measures (irritants) [G19].<br />
Mixing operations (open systems)<br />
[CS30].<br />
Bulk open loading and unloading<br />
[CS503].<br />
Non-dedicated facility [CS82]<br />
Bulk closed loading and unloading<br />
[CS501].<br />
Dedicated facility [CS81]<br />
Drum/batch transfers [CS8].<br />
Transport [CS58].<br />
Spraying [CS10].<br />
Spraying [CS10].<br />
Spreading<br />
Large surfaces [CS46].<br />
Mixing operations (open systems)<br />
[CS30].<br />
Manual [CS34].<br />
Spreading Manual [CS34].<br />
Equipment cleaning and maintenance<br />
[CS39].<br />
Non-dedicated facility [CS82]<br />
Storage [CS67].<br />
General exposures (closed systems)<br />
[CS15].<br />
Storage [CS67].<br />
General exposures (closed systems)<br />
[CS15].<br />
With sample collection [CS56].<br />
Section 2.2<br />
Product characteristics<br />
Avoid all skin contact with product, clean up conta<strong>min</strong>ation/spills as<br />
soon as they occur. Wear gloves (tested to EN374) if hand<br />
conta<strong>min</strong>ation likely, wash off any skin conta<strong>min</strong>ation immediately.<br />
Provide basic employee training to prevent / <strong>min</strong>imise exposures and<br />
to report any skin problems that may develop [E3].<br />
Use suitable eye protection [PPE26].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
Minimise exposure by partial enclosure of the operation or equipment<br />
and provide extract ventilation at openings [E60]. or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Avoid carrying out operation for more than 1 hour [OC11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
Control of environmental exposure<br />
Substance is a unique structure [PrC1].<br />
Inorganic substance.<br />
page 22 of 34
Operational conditions<br />
Contributing scenario<br />
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
Amounts used<br />
Annual tonnage of road salt<br />
1.5 tonnes/km<br />
Fraction of CaCl2 in road salt 0.06<br />
Annual tonnage of CaCl2<br />
0.09 tonnes/km<br />
Frequency and duration of use<br />
Type of release<br />
Dispersive use [FD3].<br />
Emission Days (days/year) [FD4]: 25<br />
Environmental factors not influenced by risk management<br />
Spreading width (m): 10<br />
Other Operational Conditions of Use in open systems.<br />
use affecting environmental<br />
exposure<br />
Release fraction to air from process 0<br />
(initial release prior to RMM) [OOC4]:<br />
Release fraction to wastewater from<br />
process (release after RMMs are<br />
applied):<br />
Release fraction to soil from process<br />
(initial release prior to RMM) [OOC6]:<br />
Conditions and measures related<br />
to municipal sewage treatment<br />
plant<br />
Other environmental control<br />
measures additional to above<br />
Outdoor use [OOC1].<br />
De-icing agent, application as a mixture of 70% NaCl and<br />
30% of a 20% solution of CaCl2<br />
0<br />
1<br />
Not applicable as there is no release to wastewater [STP1].<br />
Avoid spilling salt directly onto plants.<br />
Contributing scenario De-icing agent, application as liquid CaCl2 brine (max. 35%<br />
solution)<br />
Amounts used<br />
Annual tonnage of road salt<br />
0.8 tonnes/km<br />
Fraction of CaCl2 in road salt 0.35<br />
Annual tonnage of CaCl2<br />
0.28 tonnes/km<br />
Frequency and duration of use<br />
Type of release<br />
Dispersive use [FD3].<br />
Emission Days (days/year) [FD4]: 25<br />
Environmental factors not influenced by risk management<br />
Spreading width (m): 10<br />
Other Operational Conditions of Use in open systems.<br />
use affecting environmental<br />
exposure<br />
Release fraction to air from process 0<br />
(initial release prior to RMM) [OOC4]:<br />
Release fraction to wastewater from<br />
process (release after RMMs are<br />
applied):<br />
Release fraction to soil from process<br />
(initial release prior to RMM) [OOC6]:<br />
Conditions and measures related<br />
to municipal sewage treatment<br />
0<br />
1<br />
Not applicable as there is no release to wastewater [STP1].<br />
page 23 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
plant<br />
Other environmental control<br />
measures additional to above<br />
Avoid spilling salt directly onto plants.<br />
Contributing scenario De-icing agent, application as solid CaCl2 (up to 100%)<br />
Amounts used<br />
Annual tonnage of road salt<br />
0.25 tonnes/km<br />
Fraction of CaCl2 in road salt 1<br />
Annual tonnage of CaCl2<br />
0.25 tonnes/km<br />
Frequency and duration of use<br />
Type of release<br />
Dispersive use [FD3].<br />
Emission Days (days/year) [FD4]: 25<br />
Environmental factors not influenced by risk management<br />
Spreading width (m): 10<br />
Other Operational Conditions of Use in open systems.<br />
use affecting environmental<br />
exposure<br />
Release fraction to air from process 0<br />
(initial release prior to RMM) [OOC4]:<br />
Release fraction to wastewater from<br />
process (release after RMMs are<br />
applied):<br />
Release fraction to soil from process<br />
(initial release prior to RMM) [OOC6]:<br />
Conditions and measures related<br />
to municipal sewage treatment<br />
plant<br />
Other environmental control<br />
measures additional to above<br />
0<br />
1<br />
Not applicable as there is no release to wastewater [STP1].<br />
Avoid spilling salt directly onto plants.<br />
Contributing scenario Dust suppressor, application as solid CaCl2 (up to 80%)<br />
Amounts used<br />
Annual tonnage of road salt<br />
3 tonnes/km<br />
Fraction of CaCl2 in road salt 0.8<br />
Annual tonnage of CaCl2<br />
2.4 tonnes/km<br />
Frequency and duration of use<br />
Type of release<br />
Dispersive use [FD3].<br />
Emission Days (days/year) [FD4]: 3<br />
Environmental factors not influenced by risk management<br />
Spreading width (m): 10<br />
Other Operational Conditions of Use in open systems.<br />
use affecting environmental<br />
exposure<br />
Release fraction to air from process 0<br />
(initial release prior to RMM) [OOC4]:<br />
Release fraction to wastewater from<br />
process (release after RMMs are<br />
applied):<br />
Release fraction to soil from process<br />
(initial release prior to RMM) [OOC6]:<br />
0<br />
1<br />
page 24 of 34
Conditions and measures related<br />
to municipal sewage treatment<br />
plant<br />
Other environmental control<br />
measures additional to above<br />
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
Not applicable as there is no release to wastewater [STP1].<br />
Avoid spilling salt directly onto plants.<br />
Contributing scenario Dust suppressor, application as CaCl2 solution (up to 37%)<br />
Amounts used<br />
Annual tonnage of road salt<br />
3 tonnes/km<br />
Fraction of CaCl2 in road salt 0.37<br />
Annual tonnage of CaCl2<br />
1.11 tonnes/km<br />
Frequency and duration of use<br />
Type of release<br />
Dispersive use [FD3].<br />
Emission Days (days/year) [FD4]: 3<br />
Environmental factors not influenced by risk management<br />
Spreading width (m): 10<br />
Other Operational Conditions of Use in open systems.<br />
use affecting environmental<br />
exposure<br />
Release fraction to air from process 0<br />
(initial release prior to RMM) [OOC4]:<br />
Release fraction to wastewater from<br />
process (release after RMMs are<br />
applied):<br />
Release fraction to soil from process<br />
(initial release prior to RMM) [OOC6]:<br />
Conditions and measures related<br />
to municipal sewage treatment<br />
plant<br />
Other environmental control<br />
measures additional to above<br />
0<br />
1<br />
Not applicable as there is no release to wastewater [STP1].<br />
Avoid spilling salt directly onto plants.<br />
9.6. Professional (indoor) use of calcium chloride<br />
9.6.1. Exposure scenario – Professional indoor use (ES6)<br />
Section 1<br />
Exposure Scenario Title<br />
Title ES6: Professional use of <strong>Calcium</strong> <strong>Chloride</strong>; CAS: 10043-52-4<br />
Use Descriptor<br />
Processes, tasks, activities covered<br />
Section 2<br />
Field for additional statements to<br />
explain scenario if required.<br />
Sector of Use: professional SU22 (SU1, SU10, SU19, SU20, SU0- C23.5/<br />
C23.6)<br />
Process Categories: PROC1, PROC2, PROC 3, PROC4, PROC5, PROC8a,<br />
PROC8b, PROC9, PROC10, PROC11, PROC15, PROC19, PROC20<br />
Environmental Release Categories: ERC 8a, 8d<br />
Professional use of CaCl2. Covers the end use of <strong>Calcium</strong> chloride either<br />
pure or in formulation including pouring/unloading from drums or<br />
containers; and exposures during mixing/diluting in the preparatory<br />
phase and by spraying, brushing, dipping, wiping automated and by<br />
hand. E.g. the use of, washing and cleaning products or use as heat<br />
transfer fluid.<br />
Operational conditions and risk management measures<br />
page 25 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
Section 2.1<br />
Product characteristics<br />
Physical form of product<br />
Concentration of substance in product<br />
Amounts used<br />
Frequency and duration of use<br />
Control of worker exposure<br />
Solid, medium dustiness [OC2].<br />
Covers percentage substance in the product up to 100 % (unless stated<br />
differently) [G13].<br />
Not applicable<br />
Covers daily exposures up to 8 hours (unless stated differently) [G2]<br />
Human factors not influenced by risk<br />
management<br />
Other Operational Conditions affecting<br />
worker exposure<br />
Contributing Scenarios<br />
General measures (irritants) [G19].<br />
General exposures (open systems)<br />
[CS16].<br />
Batch process [CS55].<br />
With sample collection [CS56].<br />
Filling / preparation of equipment from<br />
drums or containers [CS45].<br />
Application of cleaning products in<br />
closed systems [CS101] With sample<br />
collection [CS56].<br />
Filling / preparation of equipment from<br />
drums or containers. [CS45].<br />
Mixing operations (open systems)<br />
[CS30].<br />
Bulk open loading and unloading<br />
[CS503].<br />
Non-dedicated facility [CS82].<br />
Bulk closed loading and unloading<br />
[CS501].<br />
Dedicated facility [CS81].<br />
Pouring from small containers [CS9].<br />
Transport [CS58].<br />
Not applicable<br />
Assumes use at not more than 20°C above ambient temperature, unless<br />
stated differently [G15].;<br />
Assumes a good basic standard of occupational hygiene is implemented<br />
[G1].<br />
Risk Management Measures<br />
Note: list RMM standard phrases according to the control hierarchy<br />
indicated in the ECHA template: 1. <strong>Technical</strong> measures to prevent<br />
release, 2. <strong>Technical</strong> measures to prevent dispersion, 3. Organisational<br />
measures, 4. Personal protection.<br />
Avoid all skin contact with product, clean up conta<strong>min</strong>ation/spills as soon<br />
as they occur. Wear gloves (tested to EN374) if hand conta<strong>min</strong>ation<br />
likely, wash off any skin conta<strong>min</strong>ation immediately. Provide basic<br />
employee training to prevent / <strong>min</strong>imise exposures and to report any<br />
skin problems that may develop [E3].<br />
Use suitable eye protection [PPE26].<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11]. or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29].<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29].<br />
page 26 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
Rolling, Brushing [CS51].<br />
Spraying [CS10].<br />
Mixing operations (open systems)<br />
[CS30].<br />
Manual [CS34].<br />
Manual spot cleaning (e.g. textiles etc)<br />
[CS52].<br />
Heat and pressure transfer fluids<br />
(closed systems) in dispersive use.<br />
Equipment cleaning and maintenance<br />
[CS39].<br />
Non-dedicated facility [CS82]<br />
Laboratory activities [CS36].<br />
Storage [CS67].<br />
General exposures (closed systems)<br />
[CS15].<br />
Storage [CS67].<br />
General exposures (closed systems)<br />
[CS15].<br />
With sample collection [CS56].<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Minimise exposure by partial enclosure of the operation or equipment<br />
and provide extract ventilation at openings [E60]. or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29].<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
No specific measures identified [EI18].<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29].<br />
Provide a good standard of general ventilation (not less than 3 to 5 air<br />
changes per hour) [E11]. or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
9.7. Professional outdoor use of calcium chloride<br />
9.7.1. Exposure scenario – Professional outdoor use (ES7)<br />
Section 1<br />
Exposure Scenario Title<br />
Title Professional outdoor use of <strong>Calcium</strong> <strong>Chloride</strong>; CAS: 10043-52-4<br />
Use Descriptor<br />
Processes, tasks, activities covered<br />
Section 2<br />
Sector of Use: Professional SU22 (SU1, SU5, SU10, SU13, SU19, SU20,<br />
SU0- C23.5/ C23.6)<br />
Process Categories: PROC1, PROC2, PROC5, PROC8a, PROC8b, PROC9,<br />
PROC10, PROC11, PROC13, PROC19, PROC20<br />
Environmental Release Categories: ERC 8d<br />
Professional outdoor use of CaCl2. Covers the end use of <strong>Calcium</strong><br />
chloride either pure or in formulation including pouring/unloading from<br />
drums or containers; and exposures during mixing/diluting in the<br />
preparatory phase and by spraying, brushing, dipping, spreading<br />
automated and by hand. Including storage, equipment clean-downs and<br />
disposal. E.g. the use of agrochemicals, dust suppression- and de-icingmixtures<br />
and the use of cement.<br />
Operational conditions and risk management measures<br />
page 27 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
Field for additional statements to<br />
explain scenario if required.<br />
Section 2.1<br />
Product characteristics<br />
Physical form of product<br />
Concentration of substance in product<br />
Amounts used<br />
Frequency and duration of use<br />
Human factors not influenced by risk<br />
management<br />
Other Operational Conditions affecting<br />
worker exposure<br />
Contributing Scenarios<br />
Control of worker exposure<br />
Solid, medium dustiness [OC2].<br />
Covers percentage substance in the product up to 100 % (unless stated<br />
differently) [G13].<br />
Not applicable<br />
Covers daily exposures up to 8 hours (unless stated differently) [G2]<br />
Not applicable<br />
Assumes use at not more than 20°C above ambient temperature, unless<br />
stated differently [G15].<br />
Assumes a good basic standard of occupational hygiene is implemented<br />
[G1].<br />
Outdoor [OC9].<br />
Risk Management Measures<br />
Note: list RMM standard phrases according to the control hierarchy<br />
indicated in the ECHA template: 1. <strong>Technical</strong> measures to prevent<br />
release, 2. <strong>Technical</strong> measures to prevent dispersion, 3. Organisational<br />
measure, 4. Personal protection.<br />
General measures (irritants) [G19].<br />
Mixing operations (open systems)<br />
[CS30].<br />
Bulk open loading and unloading<br />
[CS503].<br />
Non-dedicated facility [CS82].<br />
Filling / preparation of equipment from<br />
drums or containers. [CS45].<br />
Non-dedicated facility [CS82].<br />
Bulk closed loading and unloading<br />
[CS501].<br />
Dedicated facility [CS81].<br />
Drum/batch transfers [CS8].<br />
Transport [CS58].<br />
Avoid all skin contact with product, clean up conta<strong>min</strong>ation/spills as soon<br />
as they occur. Wear gloves (tested to EN374) if hand conta<strong>min</strong>ation<br />
likely, wash off any skin conta<strong>min</strong>ation immediately. Provide basic<br />
employee training to prevent / <strong>min</strong>imise exposures and to report any<br />
skin problems that may develop [E3].<br />
Use suitable eye protection [PPE26].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
Pouring from small containers [CS9]. No specific measures identified [EI18].<br />
Rolling, Brushing [CS51].<br />
No specific measures identified [EI18].<br />
Spraying [CS10].<br />
Minimise exposure by partial enclosure of the operation or equipment<br />
and provide extract ventilation at openings [E60]. or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Spraying [CS10].<br />
Avoid carrying out operation for more than 1 hour [OC11], or:<br />
Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />
[PPE29]<br />
Dipping, immersion and pouring No specific measures identified [EI18].<br />
page 28 of 34
[CS4].<br />
Spreading Large surfaces [CS46].<br />
Mixing operations (open systems)<br />
[CS30]. Manual [CS34].<br />
Spreading Manual [CS34].<br />
Equipment cleaning and maintenance<br />
[CS39]. Non-dedicated facility [CS82]<br />
Heat and pressure transfer fluids<br />
(closed systems) in dispersive use<br />
Storage [CS67].<br />
General exposures (closed systems)<br />
[CS15].<br />
Storage [CS67].General exposures<br />
(closed systems) [CS15].<br />
With sample collection [CS56].<br />
Section 2.2<br />
Product characteristics<br />
Operational conditions<br />
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
No specific measures identified [EI18].<br />
Control of environmental exposure<br />
Substance is a unique structure [PrC1].<br />
Inorganic substance.<br />
Outdoor use [OOC1].<br />
Contributing scenario De-icing agent, application as a mixture of 70% NaCl and 30%<br />
of a 20% solution of CaCl2<br />
Amounts used<br />
Annual tonnage of road salt<br />
1.5 tonnes/km<br />
Fraction of CaCl2 in road salt 0.06<br />
Annual tonnage of CaCl2<br />
0.09 tonnes/km<br />
Frequency and duration of use<br />
Type of release<br />
Dispersive use [FD3].<br />
Emission Days (days/year) [FD4]: 25<br />
Environmental factors not influenced by risk management<br />
Spreading width (m): 10<br />
Other Operational Conditions of Use in open systems.<br />
use affecting environmental<br />
exposure<br />
Release fraction to air from process 0<br />
(initial release prior to RMM) [OOC4]:<br />
Release fraction to wastewater from<br />
process (release after RMMs are<br />
applied):<br />
Release fraction to soil from process<br />
(initial release prior to RMM) [OOC6]:<br />
Conditions and measures related<br />
to municipal sewage treatment<br />
plant<br />
Other environmental control<br />
measures additional to above<br />
0<br />
1<br />
Not applicable as there is no release to wastewater [STP1].<br />
Avoid spilling salt directly onto plants.<br />
Contributing scenario De-icing agent, application as liquid CaCl2 brine (max. 35%<br />
solution)<br />
Amounts used<br />
Annual tonnage of road salt<br />
0.8 tonnes/km<br />
Fraction of CaCl2 in road salt 0.35<br />
page 29 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
Annual tonnage of CaCl2<br />
0.28 tonnes/km<br />
Frequency and duration of use<br />
Type of release<br />
Dispersive use [FD3].<br />
Emission Days (days/year) [FD4]: 25<br />
Environmental factors not influenced by risk management<br />
Spreading width (m): 10<br />
Other Operational Conditions of Use in open systems.<br />
use affecting environmental<br />
exposure<br />
Release fraction to air from process 0<br />
(initial release prior to RMM) [OOC4]:<br />
Release fraction to wastewater from<br />
process (release after RMMs are<br />
applied):<br />
Release fraction to soil from process<br />
(initial release prior to RMM) [OOC6]:<br />
Conditions and measures related<br />
to municipal sewage treatment<br />
plant<br />
Other environmental control<br />
measures additional to above<br />
0<br />
1<br />
Not applicable as there is no release to wastewater [STP1].<br />
Avoid spilling salt directly onto plants.<br />
Contributing scenario De-icing agent, application as solid CaCl2 (up to 100%)<br />
Amounts used<br />
Annual tonnage of road salt<br />
0.25 tonnes/km<br />
Fraction of CaCl2 in road salt 1<br />
Annual tonnage of CaCl2<br />
0.25 tonnes/km<br />
Frequency and duration of use<br />
Type of release<br />
Dispersive use [FD3].<br />
Emission Days (days/year) [FD4]: 25<br />
Environmental factors not influenced by risk management<br />
Spreading width (m): 10<br />
Other Operational Conditions of Use in open systems.<br />
use affecting environmental<br />
exposure<br />
Release fraction to air from process 0<br />
(initial release prior to RMM) [OOC4]:<br />
Release fraction to wastewater from<br />
process (release after RMMs are<br />
applied):<br />
Release fraction to soil from process<br />
(initial release prior to RMM) [OOC6]:<br />
Conditions and measures related<br />
to municipal sewage treatment<br />
plant<br />
Other environmental control<br />
measures additional to above<br />
0<br />
1<br />
Not applicable as there is no release to wastewater [STP1].<br />
Avoid spilling salt directly onto plants.<br />
Contributing scenario Dust suppressor, application as solid CaCl2 (up to 80%)<br />
Amounts used<br />
Annual tonnage of road salt<br />
3 tonnes/km<br />
Fraction of CaCl2 in road salt 0.8<br />
page 30 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
Annual tonnage of CaCl2<br />
2.4 tonnes/km<br />
Frequency and duration of use<br />
Type of release<br />
Dispersive use [FD3].<br />
Emission Days (days/year) [FD4]: 3<br />
Environmental factors not influenced by risk management<br />
Spreading width (m): 10<br />
Other Operational Conditions of Use in open systems.<br />
use affecting environmental<br />
exposure<br />
Release fraction to air from process 0<br />
(initial release prior to RMM) [OOC4]:<br />
Release fraction to wastewater from<br />
process (release after RMMs are<br />
applied):<br />
Release fraction to soil from process<br />
(initial release prior to RMM) [OOC6]:<br />
Conditions and measures related<br />
to municipal sewage treatment<br />
plant<br />
Other environmental control<br />
measures additional to above<br />
0<br />
1<br />
Not applicable as there is no release to wastewater [STP1].<br />
Avoid spilling salt directly onto plants.<br />
Contributing scenario Dust suppressor, application as CaCl2 solution (up to 37%)<br />
Amounts used<br />
Annual tonnage of road salt<br />
3 tonnes/km<br />
Fraction of CaCl2 in road salt 0.37<br />
Annual tonnage of CaCl2<br />
1.11 tonnes/km<br />
Frequency and duration of use<br />
Type of release<br />
Dispersive use [FD3].<br />
Emission Days (days/year) [FD4]: 3<br />
Environmental factors not influenced by risk management<br />
Spreading width (m): 10<br />
Other Operational Conditions of Use in open systems.<br />
use affecting environmental<br />
exposure<br />
Release fraction to air from process 0<br />
(initial release prior to RMM) [OOC4]:<br />
Release fraction to wastewater from<br />
process (release after RMMs are<br />
applied):<br />
Release fraction to soil from process<br />
(initial release prior to RMM) [OOC6]:<br />
Conditions and measures related<br />
to municipal sewage treatment<br />
plant<br />
Other environmental control<br />
measures additional to above<br />
0<br />
1<br />
Not applicable as there is no release to wastewater [STP1].<br />
Avoid spilling salt directly onto plants.<br />
page 31 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
9.9. Handling of calcium chloride with low dustiness<br />
9.9.1. Exposure scenario – Handling of calcium chloride with low dustiness (ES9)<br />
Section 1<br />
Exposure Scenario Title<br />
Title Handling of <strong>Calcium</strong> <strong>Chloride</strong> with low dustiness ; CAS: 10043-<br />
52-4<br />
Use Descriptor<br />
Sector of Use: SU3,SU22 (SU1, SU2a,SU4,SU5,SU6b,SU8,SU9, SU10,<br />
SU11,SU12,SU13, SU14,SU15 SU19, SU20, SU0- C23.5/ C23.6)<br />
Processes, tasks, activities covered<br />
Section 2<br />
Field for additional statements to<br />
explain scenario if required.<br />
Section 2.1<br />
Product characteristics<br />
Physical form of product<br />
Concentration of substance in product<br />
Amounts used<br />
Frequency and duration of use<br />
Human factors not influenced by risk<br />
management<br />
Other Operational Conditions affecting<br />
worker exposure<br />
Contributing Scenarios<br />
General measures (irritants) [G19].<br />
General measures applicable to all<br />
activities [CS135].<br />
Process Categories: PROC1, PROC2, PROC3, PROC4, PROC5, PROC6,<br />
PROC7, PROC8a, PROC8b, PROC9, PROC10, PROC11, PROC13,<br />
PROC14, PROC15, PROC22a, PROC22b, PROC22c, PROC23a, PROC23b,<br />
PROC23c<br />
Environmental Release Categories: ERC1, ERC6a, ERC2, ERC4, ERC8a,<br />
ERC8d<br />
Handling of <strong>Calcium</strong> <strong>Chloride</strong> pellets, flakes or other <strong>Calcium</strong> <strong>Chloride</strong><br />
with low dustiness or preparations of these.<br />
Operational conditions and risk management measures<br />
Control of worker exposure<br />
Solid, low dustiness [OC1].<br />
Covers percentage substance in the product up to 100 % (unless stated<br />
differently) [G13].<br />
Not applicable<br />
Covers daily exposures up to 8 hours (unless stated differently) [G2]<br />
Not applicable<br />
Assumes use at not more than 20°C above ambient temperature,<br />
unless stated differently [G15].<br />
Assumes a good basic standard of occupational hygiene is implemented<br />
[G1].<br />
Risk Management Measures<br />
Note: list RMM standard phrases according to the control hierarchy<br />
indicated in the ECHA template: 1. <strong>Technical</strong> measures to prevent<br />
release, 2. <strong>Technical</strong> measures to prevent dispersion, 3. Organisational<br />
measures, 4. Personal protection.<br />
Avoid all skin contact with product, clean up conta<strong>min</strong>ation/spills as<br />
soon as they occur. Wear gloves (tested to EN374) if hand<br />
conta<strong>min</strong>ation likely, wash off any skin conta<strong>min</strong>ation immediately.<br />
Provide basic employee training to prevent / <strong>min</strong>imise exposure.<br />
Use suitable eye protection [PPE26].<br />
No specific measures identified [EI18].<br />
page 32 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
9.10. Use of calcium chloride by consumers<br />
9.10.1. Exposure scenario – Consumers (ES10)<br />
Section 1<br />
Title<br />
Sector of Use<br />
Product Category<br />
Environmental Release<br />
Category<br />
Processes, tasks, activities<br />
covered<br />
Section 2<br />
Exposure Scenario Title<br />
Consumer use of <strong>Calcium</strong> <strong>Chloride</strong> and <strong>Calcium</strong> <strong>Chloride</strong><br />
containing products<br />
SU21<br />
PC2, PC4, PC 5, PC12, PC16, PC 27, PC35, PC37, PC0- UCN<br />
code K35100<br />
ERC8a, ERC8d<br />
Operational conditions (OC) and risk management<br />
measures (RMM)<br />
Field for additional statements to explain scenario if required<br />
Section 2.1<br />
Control of consumer exposure<br />
Physical form of product<br />
Concentration of Covers concentrations up to 100%. [ConsOC1]<br />
substance in product<br />
Additional sub-headers to Standard phrases linked to each sub-header<br />
Product characteristic as<br />
required.<br />
Amounts used<br />
For each use event, covers use amounts up to 50 kg unless<br />
stated differently. [ConsOC2]<br />
Frequency and duration of<br />
use<br />
Covers use up to 365 days/year, unless stated differently<br />
[ConsOC3]; Covers exposure up to 24 hours/event, unless<br />
stated differently [ConsOC14]<br />
Human factors not Inhalation rate up to 32,9 m3/day (Justification; Default<br />
influenced by risk ConsExpo light exercise- 60 kg. Average bw women, is<br />
management<br />
reasonable worst case);<br />
Other Operational Covers use at ambient temperatures. [ConsOC15]; Room<br />
Conditions affecting volume of 1 m 3 ‘Room volume’ is interpreted here as personal<br />
worker exposure<br />
space: a small area of 1 m 3 around the use. Minimum 0,6 Air<br />
Exchange Rate (1/hr) Justification; equals to indoor typical<br />
(ConsExpo General Factsheet (RIVM report 320104002/2006)-<br />
unspecified room). Covers use with a release area up to 125<br />
m2, unless stated differently. “Do not touch eyes when using<br />
this product”.<br />
Chemical Product<br />
Justification<br />
Categories<br />
PC2 (adsorbents) CaCl2 OC No specific operation conditions identified Reasonable<br />
used as domestic<br />
worst-case<br />
dehumidifier.<br />
RMM No specific measures identified<br />
estimate nonspraying<br />
activities<br />
PC4 (antifreeze + deicing)<br />
CaCl2 used for deicing<br />
and antifreeze<br />
OC<br />
RMM<br />
No specific operation conditions identified<br />
No specific measures identified<br />
Reasonable<br />
worst case<br />
estimate nonspraying<br />
activities<br />
PC9b (Fillers, putties, OC No specific operation conditions identified Reasonable<br />
page 33 of 34
SAFETY DATA SHEET<br />
<strong>Calcium</strong> chloride pellets/powder 94-98%<br />
UniPell T M<br />
plasters modelling clay)<br />
<strong>Calcium</strong> <strong>Chloride</strong> used in<br />
modelling clay<br />
PC12 (fertilizers) <strong>Calcium</strong><br />
<strong>Chloride</strong> in domestic<br />
fertilizers<br />
RMM No specific measures identified worst case<br />
estimate nonspraying<br />
activities<br />
OC No specific operation conditions identified Reasonable<br />
worst case<br />
RMM No specific measures identified<br />
estimate nonspraying<br />
activities<br />
OC No specific operation conditions identified Reasonable<br />
worst case<br />
RMM No specific measures identified<br />
estimate nonspraying<br />
activities<br />
OC Non-spraying activities - No specific operation Reasonable<br />
conditions identified<br />
worst case<br />
RMM No specific measures identified<br />
estimate nonspraying<br />
activities<br />
PC16 (Heat transfer<br />
fluids) <strong>Calcium</strong> <strong>Chloride</strong> as<br />
energy source in selfheating-cup.<br />
PC27 (plant protection)<br />
<strong>Calcium</strong> <strong>Chloride</strong> in plant<br />
protection formulations<br />
OC<br />
RMM<br />
Spraying- Covers concentration up to saturation<br />
(45%) [ConsOC1]; Covers spray duration up too<br />
10 <strong>min</strong>utes/event. Covers use in room of 58m3<br />
with room height of 2,5m. Justification; default<br />
Consexpo-Pestcontrol>>surface spraying<br />
Spray away from person<br />
Reasonable<br />
worst case<br />
estimate<br />
spraying.<br />
PC35 (washing and<br />
cleaning products)<br />
<strong>Calcium</strong> <strong>Chloride</strong><br />
containing washing and<br />
cleaning products<br />
OC<br />
RMM<br />
OC<br />
RMM<br />
Non-spraying activities - No specific operation<br />
conditions identified<br />
No specific measures identified<br />
Spraying- Covers concentration up to saturation<br />
(45%) [ConsOC1]; Covers spray duration up too<br />
10 <strong>min</strong>utes/event. Covers use in room of 58m3<br />
with room height of 2,5m. Justification; default<br />
Consexpo-Pestcontrol>>surface spraying<br />
Spray away from person<br />
Reasonable<br />
worst case<br />
estimate nonspraying<br />
activities<br />
Reasonable<br />
worst case<br />
estimate<br />
spraying<br />
PC37 (water treatment<br />
chemicals) <strong>Calcium</strong><br />
<strong>Chloride</strong> used as water<br />
treatment chemical e.g. in<br />
aquaria<br />
PC0- UCN code K35100<br />
(Cement/concrete/mortar)<br />
<strong>Calcium</strong> <strong>Chloride</strong> in<br />
Cement/concrete/mortar<br />
OC<br />
RMM<br />
No specific operation conditions identified<br />
No specific measures identified<br />
Reasonable<br />
worst case<br />
estimate nonspraying<br />
activities<br />
OC No specific operation conditions identified Reasonable<br />
worst case<br />
RMM No specific measures identified<br />
estimate nonspraying<br />
activities<br />
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