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Calcium Chloride Pellets 90% min Technical Grade - Zirax

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SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

Date issued: 10.08.2006<br />

Date revised: 02.04.2014<br />

Revision №: 2<br />

SECTION 1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING<br />

1.1. Product identifier<br />

<strong>Calcium</strong> chloride pellets / powder 94-98%<br />

Trademark: UniPell TM<br />

<strong>Technical</strong> grade<br />

CHEMICAL NAME: calcium chloride, CaCl2<br />

CAS №: 10043-52-4<br />

EC №: 233-140-8<br />

REACH registration number: 01-2119494219-28-0013<br />

Index № CLP Annex VI Regulation (EC) No 1272/2008: 017-013-00-2<br />

1.2. Relevant identified uses of the substance or mixture and uses advised against<br />

Industrial uses: construction, industrial wastewater treatment, dust suppression, drying of industrial gas and air, as<br />

a cooling agent, tire weighing, concrete acceleration, dehumidification, refrigeration.<br />

No uses advised against are identified.<br />

1.3. Details of the supplier of the safety data sheet<br />

MANUFACTURER: <strong>Zirax</strong> LLC<br />

ADDRESS: Microrayon 4, 6 Svetly Yar settlement, 404171 Volgograd region, RUSSIA<br />

Telephone: +7 8442 494999<br />

Fax: +7 8442 499444<br />

e-mail: info@zirax.com<br />

1.4. Emergency telephone number<br />

+7 8442 49-49-99<br />

SECTION 2. HAZARDS IDENTIFICATION<br />

2.1. Classification of the substance or mixture<br />

According to Regulation (EC) No 1272/2008 of the European Parliament:<br />

Hazard statement code: H319: Causes serious eye irritation<br />

Hazard Class and category code: Eye Irritation 2<br />

According to Directive 67/548/EEC:<br />

Xi; R36 Irritating to eyes<br />

2.2. Label elements<br />

According to Regulation (EC) No 1272/2008<br />

EEC HAZARD PICTOGRAM<br />

GHS07: exclamation mark<br />

SIGNAL WORD: Warning<br />

HAZARD STATEMENT: H319: Causes serious eye irritation<br />

PRECAUTIONARY STATEMENTS:<br />

P 264: Wash hands thoroughly after handling.<br />

page 1 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

P 280: Wear protective glasses with splash shields or safety goggles/shield.<br />

P305 + P351 + P338: IF IN EYES Rinse eyes cautiously with water for 15 <strong>min</strong>utes. Remove contact lenses, if<br />

present and easy to do. Continue rinsing.<br />

P337 + P 313 If irritation continued get prompt qualified medical advice / attention.<br />

2.3. Other hazards<br />

<strong>Calcium</strong> chloride can cause <strong>min</strong>or skin irritation.<br />

SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS<br />

3.1. Substances<br />

Component Name<br />

CAS Number EC №<br />

Concentration<br />

w/w<br />

Classification:<br />

Regulation (EC) No 1272/2008<br />

<strong>Calcium</strong> <strong>Chloride</strong> 10043-52-4 233-140-8 94-98%<br />

H319: Causes serious eye irritation<br />

Eye Irritation 2 class<br />

SECTION 4. FIRST AID MEASURES<br />

4.1. Description of first aid measures<br />

EYES: Remove contact lenses, if present and easy to do. Rinse cautiously with water for 15 <strong>min</strong>utes. Seek medical<br />

attention.<br />

SKIN: Remove conta<strong>min</strong>ated clothes; wash off any skin conta<strong>min</strong>ations with soap and water. Launder<br />

conta<strong>min</strong>ated clothes before re-use.<br />

INGESTION: Get prompt qualified medical attention. If conscious, give 1-2 glasses of water with absorbent carbon.<br />

INHALATION: Remove to fresh air. Keep in warm and at rest. Give oxygen or artificial aspiration if needed. If<br />

symptoms persist seek medical attention.<br />

FIRST AID MEASURES: absorbent carbon, saline purge.<br />

4.2. Most important symptoms and effects, both acute and delayed<br />

EYES: Could cause irritant or burn effects to the eyes.<br />

SKIN: Could cause irritant effects to the skin. No delayed symptoms after washing conta<strong>min</strong>ated skin.<br />

INGESTION: May cause nausea. May cause GI tract irritation.<br />

INHALATION: Dust may cause irritation to mucous membranes and respiratory system.<br />

4.3. Indication of any immediate medical attention and special treatment needed<br />

No special antidotes. If case of ingestion wash mouth with water and give plenty water to drink. Get medical<br />

attention if needed.<br />

SECTION 5. FIRE FIGHTING MEASURES<br />

5.1. Extinguishing media<br />

This product is a nonflammable substance. However, hazardous decomposition and combustion products may be<br />

formed in a fire situation. Cool exposed containers with water spray to prevent overheating. Extinguish fire using<br />

agent suitable for type of surrounding fire and/or chemicals. Do not use water directly on material. Heat is<br />

generated when product mixed with water.<br />

5.2. Special hazards arising from the substance or mixture<br />

No special hazards.<br />

5.3. Advice for firefighters<br />

Respiratory and eye protection are required for fire fighting personnel. Avoid breathing corrosive vapors.<br />

page 2 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

SECTION 6. ACCIDENTAL RELEASE MEASURES<br />

6.1. Personal precautions, protective equipment and emergency procedures<br />

Wearing the appropriate personnel protective equipment designated in Section 8, move the container to a<br />

containment area or rotate the container so that the opening is above the liquid level.<br />

6.2. Environmental precautions<br />

WATER SPILL: Use appropriate containment to avoid runoff or release to sewer or waterways.<br />

LAND SPILL: Use appropriate containment to avoid runoff or release to ground.<br />

6.3. Methods and material for containment and cleaning up<br />

Construct temporary dikes of dirt, sand, or any appropriate readily available material to prevent spreading of the<br />

material. Wearing the appropriate personal protective equipment designated in Section 8, close or cap valves<br />

and/or block or plug hole in leaking container and transfer to another container. Remove containers with disposal<br />

from release area.<br />

6.4. Reference to other sections<br />

For addition information see section 13.<br />

SECTION 7. HANDLING AND STORAGE<br />

7.1. Precautions for safe handling<br />

Avoid skin and eye contact and breathing dusts. Use proper protective and respiratory equipment. Not to eat, drink<br />

and smoke in work areas. Wash hands thoroughly after handling. Launder conta<strong>min</strong>ated clothing before re-use.<br />

Ventilate area. Sweep or vacuum; do not create dust; place in a dry container for disposal. Clean spill area with<br />

water.<br />

7.2. Conditions for safe storage, including any incompatibilities<br />

Store in a cool, dry, well-ventilated place. Keep container closed when not in use. Keep away from incompatible<br />

materials. Protect from atmospheric moisture.<br />

7.3. Specific end use(s)<br />

No specific end uses.<br />

SECTION 8. EXPOSURE CONTROLS/ PERSONAL PROTECTION<br />

8.1. Control parameters<br />

National occupational exposure limit values:<br />

maximum allowable concentration in the air of the working zone – 2 mg/m, aerosol (according to Russia standard<br />

“Maximum permissible concentration of harmful substance in the working zone area. Hygienic regulations”).<br />

8.2. Exposure controls<br />

ENGINEERING CONTROLS: Where environmental controls are lacking or in enclosed spaces use a NIOSH/MSHA<br />

approved respirator for dust/fumes. Provide local exhaust ventilation system. Eye wash station and safety shower<br />

should be provided within the immediate work area for emergency use.<br />

EXPOSURE LIMITS: No occupational exposure limits established by OSHA/ACGIH/NIOSH.<br />

PERSONAL PROTECTIVE EQUIPMENT:<br />

EYES: Wear safety glasses with splash shields or safety goggles/shield.<br />

BODY: Wear appropriate protective (impervious) clothing. Leather work boots and/or leather products will<br />

dehydrate with resultant shrinkage and possible destruction.<br />

RESPIRATORY: A respirator is not indicated under normal operating conditions. Use of a NIOSH approved<br />

respirator should be based upon the presence of nuisance dust. When warranted, use a face mask particulate<br />

respirator with particulate respirator with a NIOSH N95 rating.<br />

HANDS AND FEET: Wear appropriate rubber gloves and non-leather protective boots.<br />

page 3 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

WORK HYGIENIC PRACTICES: Use reasonable care in handling this product. Wash hands after use and before<br />

eating.<br />

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES<br />

9.1. Information on basic physical and chemical properties<br />

(a) Appearance: White pellets / powder<br />

(b) Odour: Odourless<br />

(c) Odour threshold: Not applicable<br />

(d) pH: Neutral or slightly alkaline<br />

(e) Melting point/freezing point: 772 o C (1,422 Fº)<br />

(f) Initial boiling point and boiling range; >1627°C<br />

(g) Flash point: Not applicable<br />

(h) Evaporation rate: Not applicable<br />

(i) Flammability (solid, gas): Not Flammable<br />

(j) Upper/lower flammability or explosive limits: Not applicable<br />

(k) Vapour pressure: Not applicable<br />

(l) Vapour density: Not applicable<br />

(m) Relative density: Min 700 kg/m 3 (50 lb/ft³)<br />

(n) Solubility(ies): Soluble in alcohol, acetic acid and acetone<br />

(o) Partition coefficient: n-octanol/water: inorganic substance, not applicable<br />

(p) Auto-ignition temperature: Not applicable<br />

(q) Decomposition temperature: Not applicable<br />

(r) Viscosity: Not applicable for a solid product<br />

(s) Explosive properties: the substance is non-explosive<br />

(t) Oxidising properties: the substance is non-explosive<br />

9.2. Other information<br />

MOLECULAR WEGHT: 111<br />

SECTION 10. STABILITY AND REACTIVITY<br />

10.1. Reactivity<br />

Reacts exothermically with water, acids and alkali.<br />

10.2. Chemical stability<br />

Product is stable under normal / recommended storage and handling conditions.<br />

10.3. Possibility of hazardous reactions<br />

Will not occur.<br />

10.4. Conditions to avoid<br />

To avoid contact of material with incompatible materials.<br />

10.5. Incompatible materials<br />

Incompatible with organic materials, acids, alkali, non- ferrous and ferrous metals.<br />

10.6. Hazardous decomposition products<br />

Does not occur under normal temperatures and pressures.<br />

SECTION 11. TOXICOLOGICAL INFORMATION<br />

11.1. Information on toxicological effects<br />

Acute toxicity of product is low. The value of DL 50 mg/kg study with animals:<br />

1000-4000 oral, rat<br />

page 4 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

1940 oral, mouse<br />

1384 oral, rabbit<br />

LOCAL EFFECTS: Eye, mucous membrane and skin irritant.<br />

HEALTH EFFECTS: Moderately toxic by ingestion, slightly toxic by dermal absorption.<br />

CARCINOGENICITY: Not Listed by NTP. Not listed by IARC. Not listed by OSHA.<br />

MUTAGENICITY: Not Available<br />

REPRODUCTIVE TOXICITY<br />

REPRODUCTIVE EFFECTS: testing does not appear necessary as calcium chloride will not reach the foetus or the<br />

male and female reproductive organs when exposed orally, dermally orby inhalation, as it does not become<br />

available systemically.<br />

TERATOGENIC EFFECTS: Not Available<br />

SENSITIZATION:<br />

Not Available<br />

SECTION 12. ECOLOGICAL INFORMATION<br />

12.1. Toxicity<br />

<strong>Calcium</strong> chloride is not classified as hazardous for the environment. <strong>Calcium</strong> and chloride are normally occurring<br />

ions that don’t have long term negative effect.<br />

Overview of short-term effects on fish<br />

Method Results Remarks Reference<br />

Pimephales promelas<br />

freshwater<br />

static<br />

Method: other: EPA/600/4-<br />

90/027, EPA/600/6-91/003<br />

Lepomis macrochirus<br />

freshwater<br />

static<br />

Method: other: Doudroff et al.,<br />

(1951)<br />

Lepomis macrochirus<br />

freshwater<br />

static<br />

Method: other<br />

Gambusia affinis<br />

freshwater<br />

static<br />

Method: other: not mentioned<br />

LC50 (96 h): 4630 mg/L<br />

LC50 (48 h): > 6560 mg/L<br />

LC50 (24 h): > 6660 mg/L<br />

2 (reliable with restrictions)<br />

key study<br />

experimental result<br />

Test material (EC name):<br />

calcium chloride<br />

(96 h): 9500 — 11300 mg/L 2 (reliable with restrictions)<br />

supporting study<br />

experimental result<br />

Test material (EC name):<br />

calcium chloride<br />

LC50 (96 h): 10650 mg/L<br />

LC50 (96 h): 13400 mg/L<br />

Overview of short-term effects on aquatic invertebrates<br />

2 (reliable with restrictions)<br />

supporting study<br />

Test material (EC name):<br />

calcium chloride<br />

2 (reliable with restrictions)<br />

supporting study<br />

experimental result<br />

Test material (EC name):<br />

calcium chloride<br />

Mount, D.R., Gulley,<br />

D.D., Hockett, J.R.,<br />

Garrison, T.D. and<br />

Evans, J.M. (1997a)<br />

Cairns, J., Jr. and<br />

Scheier, A. (1959)<br />

Trama, F.B. (1954)<br />

Method Results Remarks Reference<br />

Daphnia magna<br />

freshwater<br />

static<br />

OECD Guideline 202 (Daphnia<br />

sp. Acute Immobilisation Test)<br />

Ceriodaphnia dubia<br />

freshwater<br />

static<br />

LC50 (48 h): 2400 mg/L<br />

based on: mobility<br />

LC50 (48 h): 1830 mg/L<br />

based on: mobility<br />

1 (reliable without<br />

restriction)<br />

key study<br />

experimental result<br />

Test material (EC name):<br />

calcium chloride<br />

2 (reliable with restrictions)<br />

supporting study<br />

experimental result<br />

Wallen, I.E., Greer,<br />

W.C. and Lasater, R.<br />

(1957)<br />

de Groot, W.A. and<br />

Groeneveld, A.H.C.<br />

(1998)<br />

Mount, D.R., Gulley,<br />

D.D., Hockett, J.R.,<br />

Garrison, T.D. and<br />

page 5 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

Method: other: EPA/600/4-<br />

90/027, EPA/600/6-91/003<br />

other aquatic worm: Tubifex<br />

tubifex<br />

freshwater<br />

semi-static<br />

Method: other<br />

EC50 (96 h): 780 mg/L<br />

based on: mobility<br />

EC50 (48 h): 1830 mg/L<br />

based on: mobility<br />

EC50 (24 h): 2260 mg/L<br />

based on: mobility<br />

other aquatic crustacea: Cyclops LC50 (48 h): 19400 mg/L<br />

abyssorum prealpinus<br />

based on: mortality<br />

freshwater<br />

static<br />

Method: other: not mentioned<br />

other aquatic crustacea:<br />

Eudiaptomus padanus padanus<br />

freshwater<br />

static<br />

Method: other: not mentioned<br />

other aquatic crustacea:<br />

Daphnia hyalina<br />

freshwater<br />

static<br />

Method: other: not mentioned<br />

Caenorhabditis elegans<br />

freshwater<br />

static<br />

Method: other<br />

other aquatic crustacea: Nitocra<br />

spinipes<br />

freshwater<br />

static<br />

Method: other: not mentioned<br />

Daphnia magna<br />

freshwater<br />

static<br />

Method: other: not mentioned<br />

Daphnia magna<br />

static<br />

Method: other: EPA/600/4-<br />

90/027, EPA/600/6-91/003<br />

Daphnia magna<br />

static<br />

Method: other<br />

LC50 (48 h): 11100 mg/L<br />

based on: mortality<br />

LC50 (48 h): 8300 mg/L<br />

based on: mortality<br />

LC50 (24 h): 44400 mg/L<br />

based on: mortality<br />

LC50 (96 h): 1600 mg/L<br />

based on: mortality<br />

LC50 (48 h): 1285 mg/L<br />

based on: mortality<br />

LC50 (48 h): 2770 mg/L<br />

based on: mobility<br />

(48 h): 1062 mg/L based<br />

on: mobility<br />

Test material (EC name):<br />

calcium chloride<br />

2 (reliable with restrictions)<br />

supporting study<br />

experimental result<br />

Test material (EC name):<br />

calcium chloride<br />

2 (reliable with restrictions)<br />

supporting study<br />

experimental result<br />

Test material (EC name):<br />

calcium chloride<br />

2 (reliable with restrictions)<br />

supporting study<br />

experimental result<br />

Test material (EC name):<br />

calcium chloride<br />

2 (reliable with restrictions)<br />

supporting study<br />

experimental result<br />

Test material (EC name):<br />

calcium chloride<br />

2 (reliable with restrictions)<br />

supporting study<br />

experimental result<br />

Test material (EC name):<br />

calcium chloride<br />

2 (reliable with restrictions)<br />

supporting study<br />

experimental result<br />

Test material (EC name):<br />

calcium chloride<br />

2 (reliable with restrictions)<br />

supporting study<br />

experimental result<br />

Test material (EC name):<br />

calcium chloride<br />

2 (reliable with restrictions)<br />

supporting study<br />

experimental result<br />

Test material (EC name):<br />

calcium chloride<br />

2 (reliable with restrictions)<br />

supporting study<br />

experimental result<br />

Test material (EC name):<br />

calcium chloride<br />

Evans, J.M. (1997b)<br />

Khangarot, B.S.<br />

(1991)<br />

Baudouin, M.F. and<br />

Scoppa, P. (1974a)<br />

Baudouin, M.F. and<br />

Scoppa, P. (1974b)<br />

Baudouin, M.F. and<br />

Scoppa, P. (1974a)<br />

Tatara, C.P.,<br />

Newman, M.C.,<br />

McCloskey, J.T. and<br />

Williams, P.L. (1997)<br />

Bengtsson, B.-E.<br />

(1978)<br />

Biesinger, K.E. and<br />

Christensen, G.M.<br />

(1972)<br />

Mount, D.R., Gulley,<br />

D.D., Hockett, J.R.,<br />

Garrison, T.D. and<br />

Evans, J.M.<br />

Khangarot, B.S. and<br />

Ray, P.K. (1989)<br />

Overview of long-term effects on aquatic invertebrates<br />

Method Results Remarks Reference<br />

Daphnia magna EC50 (21 d): 610 mg/L 2 (reliable with restrictions) Biesinger, K.E. and<br />

page 6 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

Method: other: not mentioned<br />

based on: reproductive<br />

impairment<br />

EC16 (21 d): 320 mg/L<br />

based on: reproductive<br />

impairment<br />

LC50 (21 d): 920 mg/L<br />

based on: mortality<br />

key study<br />

experimental result<br />

Test material (EC name):<br />

calcium chloride<br />

Christensen, G.M.<br />

(1972)<br />

Overview of effects on algae and aquatic plants<br />

Method Results Remarks Reference<br />

Selenastrum capricornutum EC50 (72 h): 2900 mg/L<br />

(new name: Pseudokirchneriella based on: biomass<br />

subcapitata) (algae)<br />

EC50 (72 h): > 4000 mg/L<br />

OECD Guideline 201 (Alga, based on: growth rate<br />

Growth Inhibition Test) EC50 (72 h): 27000 mg/L<br />

based on: growth rate<br />

EC20 (72 h): 1000 mg/L<br />

based on: biomass<br />

1 (reliable without<br />

restriction)<br />

key study<br />

experimental result<br />

Test material (EC name):<br />

calcium chloride<br />

de Groot, W.A.<br />

(1998)<br />

12.2. Persistence and degradability<br />

Test not available as product is inorganic.<br />

12.3. Bioaccumulative potential<br />

Product is not biodegrade or accumulate.<br />

12.4. Mobility in soil<br />

In accordance with REACH Annex XI, the study does not need to be conducted as in water; calcium chloride is<br />

dissociated into calcium and chloride ions and chloride ions will not adsorb on particulate matter. The calcium ion<br />

may bind to particulate matter or may form stable inorganic salts with sulphate and carbonate ions, but calcium is<br />

naturally present in soil. Therefore, exposure of the soil compartment is unlikely.<br />

12.5. Results of PBT and vPvB assessment<br />

According to Annex XIII of the REACH Regulation 1907/2006/EC inorganic substances do not need to be subjected<br />

to a PBT assessment.<br />

12.6. Other adverse effects<br />

None identified.<br />

SECTION 13. DISPOSAL CONSIDERATIONS<br />

13.1. Waste treatment methods<br />

Observe federal, state, and local regulations when disposing of this substance.<br />

DISPOSAL METHOD: Dispose of waste at an appropriate waste disposal facility according to current applicable<br />

laws and regulations.<br />

FOR LARGE SPILLS: Contain material according to section 6.<br />

PRODUCT DISPOSAL: Dispose of at a supervised incineration facility or an appropriate waste disposal facility<br />

according to current applicable laws and regulations and product characteristics at time of disposal.<br />

EMPTY CONTAINER: Rinse drums with a suitable solvent and steam to remove vapors before disposal or reuse in<br />

accordance with applicable regulations<br />

SECTION 14. TRANSPORT INFORMATION<br />

14.1. UN number Not applicable<br />

page 7 of 34


14.2. UN proper shipping name Not regulated<br />

14.3. Transport hazard class(es) Not applicable<br />

14.4. Packing group Not applicable<br />

14.5. Environmental hazards Not applicable<br />

14.6. Special precautions for user Not applicable<br />

SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable<br />

SECTION 15. REGULATORY INFORMATION<br />

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture<br />

General principles of protection EH 44<br />

15.2. Chemical safety assessment<br />

A chemical safety assessment has been performed for calcium chloride according to REACH.<br />

SECTION 16. OTHER INFORMATION<br />

To the best of our knowledge, this Safety Data Sheet conforms to the requirements of:<br />

- Regulation (EC) №1907/2006 of the European Parliament and of the Council of 18 December 2006<br />

- Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008<br />

- Commission Regulation (RU) №453/2010 of 20.05.2010<br />

List of relevant R phrases, hazard statement, safety phrases and precautionary statement:<br />

According to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008:<br />

HAZARD STATEMENT: H319: Causes serious eye irritation<br />

PRECAUTIONARY STATEMENTS:<br />

P 264: Wash hands thoroughly after handling.<br />

P 280: Wear protective glasses with splash shields or safety goggles/shield.<br />

P305 + P351 + P338: IF IN EYES Rinse eyes cautiously with water for 15 <strong>min</strong>utes. Remove contact lenses, if<br />

present and easy to do. Continue rinsing.<br />

P337 + P 313 If irritation continued get prompt qualified medical advice / attention.<br />

According to Directive 67/548/EEC:<br />

Xi Irritant<br />

R36 Irritating to eyes<br />

S-phrases:<br />

(S2) - keep out of the reach of children<br />

S22 - do not breathe dust<br />

S24 - avoid contact with skin<br />

Individuals handling this product should be informed of the recommended safety precautions and should have<br />

access to this information. It is the users' responsibility to satisfy themselves as to the suitability and completeness<br />

of such information for their own particular use. We do not accept liability for any loss or damage that may occur<br />

from the use of this information nor do we offer warranty against patent infringement.<br />

ZIRAX LLC reserves the right to refuse shipment of this product to any customer who fails to demonstrate the<br />

ability to consistently handle and use it safely and in compliance with all applicable laws, rules and regulations.<br />

Such demonstration may require on-site inspection of any or all storage, processing, packaging and other handling<br />

systems that come in contact with it.<br />

page 8 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

ANNEX 1<br />

The overview of exposure scenarios of <strong>Calcium</strong> <strong>Chloride</strong><br />

Life Cycle Stage(s) covered by the<br />

IU<br />

Short description of<br />

Identified Use<br />

Product<br />

Category<br />

(PC)<br />

Manufacture<br />

Formulation<br />

End Use<br />

Industrial<br />

Professional<br />

Consumer<br />

Service Life (for<br />

article)<br />

Sector of use<br />

(SU)<br />

Process Category<br />

(Proc)<br />

Article<br />

Category<br />

(AC)<br />

Environmental<br />

Release<br />

Category<br />

(ERC)<br />

ES1: Production of<br />

calcium chloride<br />

Not applicable X SU8 (SU3) PROC1, PROC2, PROC3,<br />

PROC4, PROC6, PROC8a,<br />

PROC8b, PROC9,<br />

PROC15, PROC26<br />

Not<br />

applicable<br />

ERC1<br />

ES2: Use of calcium<br />

chloride as chemical<br />

intermediate<br />

Not applicable X SU8, SU9, SU14<br />

(SU1, SU3, SU4,<br />

SU5, SU6b)<br />

PROC1, PROC2, PROC3,<br />

PROC4, PROC6, PROC8a,<br />

PROC8b, PROC9,<br />

PROC15, PROC22a,<br />

PROC22b, PROC22c,<br />

PROC23a, PROC23b,<br />

PROC23c, PROC26 1 ,<br />

PROC27a 2 , PROC27b 3<br />

Not<br />

applicable<br />

ERC6a<br />

1<br />

No specific assessment has been performed with ECTOC TRA for this PROC, but activities for PROC 26 (handling of solid inorganic substances at abient temperature) are covered within this<br />

scenario.<br />

2<br />

No specific assessment has been performed with ECTOC TRA for this PROC, but activities for PROC27a (Production of metal powders (hot processes)) are covered within this scenario by<br />

PROC22 and PROC23.<br />

3<br />

No specific assessment has been performed with ECTOC TRA for this PROC, but activities for PROC 27b (Production of metal powders (wet processes)) are covered within this scenario.<br />

page 9 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

Life Cycle Stage(s) covered by the<br />

IU<br />

Short description of<br />

Identified Use<br />

Product<br />

Category<br />

(PC)<br />

Manufacture<br />

Formulation<br />

End Use<br />

Industrial<br />

Professional<br />

Consumer<br />

Service Life (for<br />

article)<br />

Sector of use<br />

(SU)<br />

Process Category<br />

(Proc)<br />

Article<br />

Category<br />

(AC)<br />

Environmental<br />

Release<br />

Category<br />

(ERC)<br />

ES3: Formulation and/or<br />

distribution of <strong>Calcium</strong><br />

<strong>Chloride</strong><br />

Not applicable X SU19 (SU1,<br />

SU2a,<br />

SU2b,SU3, SU4,<br />

SU5, SU6b, SU8,<br />

SU11, SU12,<br />

SU13, SU14,<br />

SU15, SU19,<br />

SU20, SU0-<br />

C23.5/ C23.6)<br />

PROC1, PROC2, PROC3,<br />

PROC5,<br />

PROC6, PROC8a,<br />

PROC8b, PROC9,<br />

PROC14, PROC15<br />

PROC26 1 , PROC27a 2 ,<br />

PROC27b 3<br />

Not<br />

applicable<br />

ERC2<br />

ES4: Use of calcium<br />

chloride as processing aid<br />

Not applicable X SU3 (SU1, SU2a,<br />

SU2b, SU4, SU5,<br />

SU6b, SU8, SU9,<br />

SU10, SU11,<br />

SU12, SU13,<br />

SU14, SU15,<br />

SU16, SU17)<br />

PROC1, PROC2, PROC3,<br />

PROC4, PROC6, PROC7,<br />

PROC8a, PROC8b,<br />

PROC9, PROC10,<br />

PROC13, PROC15,<br />

PROC22a, PROC22b,<br />

PROC22c, PROC23a,<br />

PROC23b, PROC23c,<br />

PROC26 1 , PROC27a 2 ,<br />

PROC27b 3<br />

Not<br />

applicable<br />

ERC4<br />

ES5: Industrial outdoor<br />

use of calcium chlorideend<br />

use<br />

Not applicable X SU3(SU1, SU2a,<br />

SU2b)<br />

PROC1, PROC2, PROC5,<br />

PROC7, PROC8a,<br />

PROC8b,<br />

Not<br />

applicable<br />

ERC4<br />

page 10 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

Life Cycle Stage(s) covered by the<br />

IU<br />

Short description of<br />

Identified Use<br />

Product<br />

Category<br />

(PC)<br />

Manufacture<br />

Formulation<br />

End Use<br />

Industrial<br />

Professional<br />

Consumer<br />

Service Life (for<br />

article)<br />

Sector of use<br />

(SU)<br />

Process Category<br />

(Proc)<br />

Article<br />

Category<br />

(AC)<br />

Environmental<br />

Release<br />

Category<br />

(ERC)<br />

PROC9, PROC13,<br />

PROC19,<br />

PROC26 1 ,<br />

ES6: Professional indoor<br />

use of calcium chloride<br />

Not applicable X SU22 (SU1,<br />

SU10, SU19,<br />

SU20, SU0-<br />

C23.5/ C23.6)<br />

PROC1, PROC2, PROC3,<br />

PROC4, PROC5, PROC8a,<br />

PROC8b, PROC9<br />

PROC10, PROC11,<br />

PROC15, PROC19,<br />

PROC20, PROC26 1 ,<br />

Not<br />

applicable<br />

ERC8a,<br />

ERC8d<br />

ES7: Professional outdoor<br />

use of calcium chloride<br />

Not applicable X SU22 (SU1, SU5,<br />

SU10, SU13,<br />

SU19, SU20,<br />

SU0- C23.5/<br />

C23.6)<br />

PROC1, PROC2, PROC5,<br />

PROC8a, PROC8b,<br />

PROC9, PROC10<br />

PROC11, PROC13,<br />

PROC19, PROC20<br />

PROC26 1<br />

Not<br />

applicable<br />

ERC8d<br />

ES8: Handling of<br />

(aqueous) calcium<br />

chloride<br />

X X SU3,SU22 (SU1,<br />

SU2a,SU4,SU5,S<br />

U6b,SU8,SU9,<br />

SU10,<br />

SU11,SU12,SU1<br />

3, SU14,SU15<br />

SU19, SU20,<br />

PROC1, PROC2, PROC3,<br />

PROC4, PROC5, PROC6,<br />

PROC7, PROC8a,<br />

PROC8b, PROC9,<br />

PROC10, PROC11,<br />

PROC13, PROC14,<br />

PROC15<br />

Not<br />

applicable<br />

ERC1, ERC6a,<br />

ERC2, ERC4,<br />

ERC8a, ERC8d<br />

page 11 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

Life Cycle Stage(s) covered by the<br />

IU<br />

Short description of<br />

Identified Use<br />

Product<br />

Category<br />

(PC)<br />

Manufacture<br />

Formulation<br />

End Use<br />

Industrial<br />

Professional<br />

Consumer<br />

Service Life (for<br />

article)<br />

Sector of use<br />

(SU)<br />

Process Category<br />

(Proc)<br />

Article<br />

Category<br />

(AC)<br />

Environmental<br />

Release<br />

Category<br />

(ERC)<br />

SU0- C23.5/<br />

C23.6)<br />

ES9: Handling of calcium<br />

chloride with low<br />

dustiness<br />

X X SU3,SU22 (SU1,<br />

SU2a,SU4,SU5,S<br />

U6b,SU8,SU9,<br />

SU10,<br />

SU11,SU12,SU1<br />

3, SU14,SU15<br />

SU19, SU20,<br />

SU0- C23.5/<br />

C23.6)<br />

PROC1, PROC2, PROC3,<br />

PROC4, PROC5, PROC6,<br />

PROC7, PROC8a,<br />

PROC8b, PROC9,<br />

PROC10, PROC11,<br />

PROC13, PROC14,<br />

PROC15, PROC22a,<br />

PROC22b, PROC22c,<br />

PROC23a, PROC23b,<br />

PROC23c<br />

Not<br />

applicable<br />

ERC1, ERC6a,<br />

ERC2, ERC4,<br />

ERC8a, ERC8d<br />

ES10: Use of calcium<br />

chloride by consumers<br />

PC2, PC5,<br />

PC35, PC37,<br />

PC4, PC12, PC<br />

27,PC16, PC0-<br />

UCN code<br />

K35100<br />

X SU21 Not applicable Not<br />

applicable<br />

ERC8a,<br />

ERC8d<br />

page 12 of 34


9.1. Production of calcium chloride<br />

9.1.1. Exposure scenario – Production (ES1)<br />

SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

Section 1<br />

Exposure Scenario Title<br />

Title Production of calcium chloride; CAS: 10043-52-4<br />

Use Descriptor<br />

Processes, tasks,<br />

activities covered<br />

Section 2<br />

Field for additional<br />

statements to<br />

explain scenario if<br />

required.<br />

Section 2.1<br />

Product<br />

characteristics<br />

Physical form of<br />

product<br />

Concentration of<br />

substance in<br />

product<br />

Amounts used<br />

Frequency and<br />

duration of use<br />

Human factors not<br />

influenced by risk<br />

management<br />

Other Operational<br />

Conditions affecting<br />

worker exposure<br />

Contributing<br />

Scenarios<br />

Sector of Use: Industrial SU8, (SU3)<br />

Process Categories: PROC1, PROC2, PROC3, PROC4, PROC6,<br />

PROC8a, PROC8b, PROC9, PROC15,PROC26<br />

Environmental Release Categories: ERC1<br />

Manufacturing of <strong>Calcium</strong> <strong>Chloride</strong>, includes recycling/ recovery,<br />

material transfers, storage, maintenance and loading (including marine<br />

vessel/barge, road/rail car and bulk container), sampling and<br />

associated laboratory activities.<br />

Operational conditions and risk management measures<br />

Control of worker exposure<br />

Solid, medium dustiness [OC2]<br />

Covers percentage substance in the product up to 100 % (unless<br />

stated differently) [G13].<br />

Not applicable<br />

Covers daily exposures up to 8 hours (unless stated differently) [G2]<br />

Not applicable<br />

Assumes use at not more than 20°C above ambient temperature,<br />

unless stated differently [G15].;<br />

Assumes a good basic standard of occupational hygiene is<br />

implemented [G1].<br />

Risk Management Measures<br />

Note: list RMM standard phrases according to the control hierarchy<br />

indicated in the ECHA template: 1. <strong>Technical</strong> measures to prevent<br />

release, 2. <strong>Technical</strong> measures to prevent dispersion, 3. Organisational<br />

measures, 4. Personal protection.<br />

Justification<br />

General measures<br />

(irritants) [G19].<br />

General exposures<br />

[CS1]. With sample<br />

collection [CS56].<br />

General exposures<br />

[CS1]. Continuous<br />

process [CS54]. ;<br />

Avoid all skin contact with product, clean up conta<strong>min</strong>ation/spills as<br />

soon as they occur. Wear gloves (tested to EN374) if hand<br />

conta<strong>min</strong>ation likely, wash off any skin conta<strong>min</strong>ation immediately.<br />

Provide basic employee training to prevent / <strong>min</strong>imise exposures and<br />

to report any skin problems that may develop [E3].Use suitable eye<br />

protection [PPE26].<br />

Provide a good standard of general ventilation. Natural ventilation is<br />

from doors, windows etc. Controlled ventilation means air is supplied<br />

or removed by a powered fan. [E1].<br />

Provide a good standard of general ventilation. Natural ventilation is<br />

from doors, windows etc. Controlled ventilation means air is supplied<br />

or removed by a powered fan. [E1].<br />

measured<br />

data, see 9.1.2<br />

(PROC1)<br />

measured<br />

data, see 9.1.2<br />

(PROC2)<br />

page 13 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

With sample<br />

collection [CS56].<br />

General exposures<br />

[CS1]. Use in<br />

contained batch<br />

processes [CS37].<br />

General exposures<br />

(open systems)<br />

[CS16].<br />

Batch process<br />

[CS55]. With<br />

sample collection<br />

[CS56]. ;<br />

Filling / preparation<br />

of equipment from<br />

drums<br />

or<br />

containers. [CS45].<br />

Calendering<br />

(including<br />

Banburys) [CS64]<br />

Process sampling<br />

[CS2]. Dedicated<br />

facility [CS81]<br />

Laboratory activities<br />

[CS36].<br />

Process sampling<br />

[CS2]. Nondedicated<br />

facility<br />

[CS82]<br />

Drum/batch<br />

transfers [CS8].<br />

Transport [CS58].<br />

bulk open loading<br />

and unloading<br />

[CS503]Nondedicated<br />

facility<br />

[CS82]<br />

bulk closed loading<br />

and unloading<br />

[CS501]Dedicated<br />

facility [CS81]<br />

Equipment cleaning<br />

and maintenance<br />

[CS39]. Nondedicated<br />

facility<br />

[CS82]<br />

Storage<br />

[CS67].General<br />

exposures (closed<br />

systems) [CS15].<br />

Storage<br />

[CS67].With sample<br />

collection [CS56].<br />

Provide a good standard of general ventilation. Natural ventilation is<br />

from doors, windows etc. Controlled ventilation means air is supplied<br />

or removed by a powered fan. [E1].<br />

Provide a good standard of general ventilation. Natural ventilation is<br />

from doors, windows etc. Controlled ventilation means air is supplied<br />

or removed by a powered fan. [E1].<br />

Provide a good standard of general ventilation. Natural ventilation is<br />

from doors, windows etc. Controlled ventilation means air is supplied<br />

or removed by a powered fan. [E1].<br />

Provide a good standard of general ventilation. Natural ventilation is<br />

from doors, windows etc. Controlled ventilation means air is supplied<br />

or removed by a powered fan. [E1].<br />

Provide a good standard of general ventilation. Natural ventilation is<br />

from doors, windows etc. Controlled ventilation means air is supplied<br />

or removed by a powered fan. [E1].<br />

Provide a good standard of general ventilation. Natural ventilation is<br />

from doors, windows etc. Controlled ventilation means air is supplied<br />

or removed by a powered fan. [E1].<br />

Provide a good standard of general ventilation. Natural ventilation is<br />

from doors, windows etc. Controlled ventilation means air is supplied<br />

or removed by a powered fan. [E1].<br />

Provide a good standard of general ventilation. Natural ventilation is<br />

from doors, windows etc. Controlled ventilation means air is supplied<br />

or removed by a powered fan. [E1].<br />

Provide a good standard of general ventilation. Natural ventilation is<br />

from doors, windows etc. Controlled ventilation means air is supplied<br />

or removed by a powered fan. [E1].<br />

Provide a good standard of general ventilation. Natural ventilation is<br />

from doors, windows etc. Controlled ventilation means air is supplied<br />

or removed by a powered fan. [E1].<br />

Provide a good standard of general ventilation. Natural ventilation is<br />

from doors, windows etc. Controlled ventilation means air is supplied<br />

or removed by a powered fan. [E1].<br />

Provide a good standard of general ventilation. Natural ventilation is<br />

from doors, windows etc. Controlled ventilation means air is supplied<br />

or removed by a powered fan. [E1].<br />

measured<br />

data, see 9.1.2<br />

(PROC3)<br />

measured<br />

data, see 9.1.2<br />

(PROC4)<br />

measured<br />

data, see<br />

9.1.2.(PROC6)<br />

measured<br />

data, see 9.1.2<br />

(PROC8b)<br />

measured<br />

data, see 9.1.2<br />

(PROC8a)<br />

measured<br />

data, see 9.1.2<br />

(PROC9)<br />

measured<br />

data, see 9.1.2<br />

(PROC15)<br />

measured<br />

data, see 9.1.2<br />

(PROC8a)<br />

measured<br />

data, see 9.1.2<br />

(PROC8b)<br />

measured<br />

data, see 9.1.2<br />

(PROC8a)<br />

measured<br />

data, see 9.1.2<br />

(PROC1)<br />

measured<br />

data, see 9.1.2<br />

(PROC2)<br />

page 14 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

9.2. Use of calcium chloride as chemical intermediate<br />

9.2.1. Exposure scenario – Use as an intermediate (ES2)<br />

Section 1<br />

Title<br />

Use Descriptor<br />

Exposure Scenario Title<br />

Use of <strong>Calcium</strong> <strong>Chloride</strong> as chemical intermediate; CAS:<br />

10043-52-4<br />

Sector of Use: Industrial SU8, SU9, SU14 (SU1, SU3, SU4, SU5,<br />

SU6b)<br />

Processes, tasks, activities covered<br />

Section 2<br />

Field for additional statements to explain<br />

scenario if required.<br />

Section 2.1<br />

Product characteristics<br />

Physical form of product<br />

Concentration of substance in product<br />

Amounts used<br />

Frequency and duration of use<br />

Human factors not influenced by risk<br />

management<br />

Other Operational Conditions affecting<br />

worker exposure<br />

Contributing Scenarios<br />

Process Categories: PROC1, PROC2, PROC3, PROC4, PROC6,<br />

PROC8a, PROC8b, PROC9, PROC15, PROC22a, PROC22b, PROC22c,<br />

PROC23a, PROC23b, PROC23c<br />

Environmental Release Categories: ERC 6a<br />

Use of <strong>Calcium</strong> <strong>Chloride</strong> as chemical intermediate. Use as an<br />

intermediate. Includes recycling/ recovery, material transfers,<br />

storage, maintenance and loading (including marine vessel/barge,<br />

road/rail car and bulk container), sampling and associated<br />

laboratory activities.<br />

Operational conditions and risk management measures<br />

Control of worker exposure<br />

Solid, medium dustiness [OC2]<br />

Covers percentage substance in the product up to 100 % (unless<br />

stated differently) [G13].<br />

Not applicable<br />

Covers daily exposures up to 8 hours (unless stated differently)<br />

[G2]<br />

Not applicable<br />

Assumes use at not more than 20°C above ambient temperature,<br />

unless stated differently [G15].;<br />

Assumes a good basic standard of occupational hygiene is<br />

implemented [G1].<br />

Risk Management Measures<br />

Note: list RMM standard phrases according to the control hierarchy<br />

indicated in the ECHA template: 1. <strong>Technical</strong> measures to prevent<br />

release, 2. <strong>Technical</strong> measures to prevent dispersion, 3.<br />

Organisational measures , 4. Personal protection.<br />

General measures (irritants) [G19].<br />

General exposures [CS1].<br />

With sample collection [CS56].<br />

General exposures [CS1].<br />

Continuous process [CS54].<br />

With sample collection [CS56].<br />

Avoid all skin contact with product, clean up conta<strong>min</strong>ation/spills as<br />

soon as they occur. Wear gloves (tested to EN374) if hand<br />

conta<strong>min</strong>ation likely, wash off any skin conta<strong>min</strong>ation immediately.<br />

Provide basic employee training to prevent / <strong>min</strong>imise exposures<br />

and to report any skin problems that may develop [E3].Use suitable<br />

eye protection [PPE26].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

page 15 of 34


General exposures [CS1].<br />

Use in contained batch processes<br />

[CS37].<br />

General exposures (open systems)<br />

[CS16].<br />

Batch process [CS55].<br />

With sample collection [CS56].<br />

Filling / preparation of equipment from<br />

drums or containers. [CS45].<br />

SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

No specific measures identified [EI18].<br />

Provide a good standard of general ventilation (not less than 3 to 5<br />

air changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />

better [PPE29]<br />

Calendering (including Banburys) [CS64] Provide a good standard of general ventilation (not less than 3 to 5<br />

air changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />

better [PPE29]<br />

Process sampling [CS2]. Dedicated Provide a good standard of general ventilation (not less than 3 to 5<br />

facility [CS81]<br />

air changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />

better [PPE29]<br />

Process sampling [CS2].<br />

Non-dedicated facility [CS82].<br />

Avoid carrying out operation for more than 1 hour [OC11]<br />

Drum/batch transfers [CS8].<br />

Transport [CS58].<br />

Laboratory activities [CS36].<br />

Bulk open loading and unloading<br />

[CS503].<br />

Non-dedicated facility [CS82]<br />

bulk closed loading and unloading<br />

[CS501]Dedicated facility [CS81]<br />

Equipment cleaning and maintenance<br />

[CS39].<br />

Non-dedicated facility [CS82].<br />

General exposures (closed systems)<br />

[CS15]. Elevated temperature [CS111].<br />

Process temperature ≤ melting point<br />

<strong>Calcium</strong> <strong>Chloride</strong><br />

General exposures (closed systems)<br />

[CS15]. Elevated temperature [CS111].<br />

Process temperature > melting point<br />

<strong>Calcium</strong> <strong>Chloride</strong><br />

Material transfers [CS3].<br />

(open systems) [CS108].<br />

Batch processes at elevated<br />

temperatures [CS136].<br />

Process temperature ≤ melting point<br />

<strong>Calcium</strong> <strong>Chloride</strong><br />

Material transfers [CS3].<br />

(open systems) [CS108].<br />

Batch processes at elevated<br />

temperatures [CS136].<br />

Process temperature > melting point<br />

<strong>Calcium</strong> <strong>Chloride</strong><br />

Provide a good standard of general ventilation (not less than 3 to 5<br />

air changes per hour) [E11., or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />

better [PPE29]<br />

No specific measures identified [EI18].<br />

Provide a good standard of general ventilation (not less than 3 to 5<br />

air changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />

better [PPE29]<br />

Provide a good standard of general ventilation (not less than 3 to 5<br />

air changes per hour) [E11]., or: Wear a respirator confor<strong>min</strong>g to<br />

EN140 with Type A/P2 filter or better [PPE29]<br />

Drain or remove substance from equipment prior to break-in or<br />

maintenance [E81], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />

better [PPE29]<br />

No specific measures identified [EI18].<br />

Provide extract ventilation to points where emissions occur [E54],<br />

or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />

better [PPE29]<br />

No specific measures identified [EI18].<br />

Provide a good standard of controlled ventilation (10 to 15 air<br />

changes per hour) [E40]., or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />

better [PPE29]<br />

page 16 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

Storage [CS67].<br />

General exposures (closed systems)<br />

[CS15].<br />

Storage [CS67].<br />

With sample collection [CS56].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

9.3. Formulation and/or distribution of calcium chloride<br />

9.3.1. Exposure scenario – Formulation and/or distribution (ES3)<br />

Section 1<br />

Title<br />

Use Descriptor<br />

Processes, tasks, activities covered<br />

Section 2<br />

Field for additional statements to<br />

explain scenario if required.<br />

Section 2.1<br />

Product characteristics<br />

Physical form of product<br />

Concentration of substance in product<br />

Amounts used<br />

Frequency and duration of use<br />

Human factors not influenced by risk<br />

management<br />

Other Operational Conditions affecting<br />

worker exposure<br />

Contributing Scenarios<br />

General measures (irritants) [G19].<br />

Exposure Scenario Title<br />

Formulation and/or distribution of <strong>Calcium</strong> <strong>Chloride</strong>; CAS:<br />

10043-52-4<br />

Sector of Use: Industrial SU10 (SU1, SU2, SU3, SU4, SU5, SU6b, SU8,<br />

SU11, SU12, SU13, SU14, SU15, SU19, SU20, SU0- C23.5/ C23.6)<br />

Process Categories: PROC1, PROC2, PROC3, PROC5, PROC 6, PROC8a,<br />

PROC8b, PROC9, PROC14, PROC15<br />

Environmental Release Categories: ERC2<br />

Formulation and distribution , packing and re-packing (including drums<br />

and small packs) of the <strong>Calcium</strong> <strong>Chloride</strong> and its mixtures in batch or<br />

continuous operations, including storage, materials transfers, mixing,<br />

large and small scale packing, loading (including marine vessel/barge,<br />

rail/road car and IBC loading), maintenance and associated laboratory<br />

activities. e.g. production of adsorbents, cosmetics, metals, fertilizers,<br />

plant protection, cement, haemodialysis solution and general<br />

distributor activities with <strong>Calcium</strong> <strong>Chloride</strong><br />

Operational conditions and risk management measures<br />

Control of worker exposure<br />

Solid, medium dustiness [OC2]<br />

Covers percentage substance in the product up to 100 % (unless<br />

stated differently) [G13].<br />

Not applicable<br />

Covers daily exposures up to 8 hours (unless stated differently) [G2]<br />

Not applicable<br />

Assumes use at not more than 20°C above ambient temperature,<br />

unless stated differently [G15].<br />

Assumes a good basic standard of occupational hygiene is<br />

implemented [G1].<br />

Risk Management Measures<br />

Note: list RMM standard phrases according to the control hierarchy<br />

indicated in the ECHA template: 1. <strong>Technical</strong> measures to prevent<br />

release, 2. <strong>Technical</strong> measures to prevent dispersion, 3. Organisational<br />

measures , 4. Personal protection.<br />

Avoid all skin contact with product, clean up conta<strong>min</strong>ation/spills as<br />

soon as they occur. Wear gloves (tested to EN374) if hand<br />

conta<strong>min</strong>ation likely, wash off any skin conta<strong>min</strong>ation immediately.<br />

page 17 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

General exposures [CS1].<br />

Continuous process [CS54].<br />

General exposures [CS1].<br />

Continuous process [CS54].<br />

With sample collection [CS56].<br />

General exposures [CS1].<br />

Use in contained batch processes<br />

[CS37].<br />

Mixing operations (open systems)<br />

[CS30].<br />

Calendering (including Banburys)<br />

[CS64]<br />

Bulk open loading and unloading<br />

[CS503].<br />

Non-dedicated facility [CS82]<br />

Bulk closed loading and unloading<br />

[CS501].<br />

Dedicated facility [CS81]<br />

Drum/batch transfers [CS8].<br />

Transport [CS58].<br />

Tabletting, compression, extrusion or<br />

pelletisation [CS506].<br />

Laboratory activities [CS36].<br />

Process sampling [CS2].<br />

Dedicated facility [CS81]<br />

Process sampling [CS2].<br />

Non-dedicated facility [CS82].<br />

Equipment cleaning and maintenance<br />

[CS39].<br />

Non-dedicated facility [CS82].<br />

Storage [CS67].<br />

General exposures (closed systems)<br />

[CS15].<br />

Storage [CS67].<br />

General exposures (closed systems)<br />

[CS15].<br />

With sample collection [CS56].<br />

Provide basic employee training to prevent / <strong>min</strong>imise exposures and<br />

to report any skin problems that may develop [E3].<br />

Use suitable eye protection [PPE26].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11].<br />

or: Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or<br />

better [PPE29]<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Avoid carrying out operation for more than 1 hour [OC11].<br />

Drain or remove substance from equipment prior to break-in or<br />

maintenance [E81], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

page 18 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

9.4. Use of calcium chloride as processing aid<br />

9.4.1. Exposure scenario – Use of calcium chloride as processing aid (ES4)<br />

Section 1<br />

Exposure Scenario Title<br />

Title Use of <strong>Calcium</strong> <strong>Chloride</strong> as processing aid; CAS: 10043-52-4<br />

Use Descriptor<br />

Processes, tasks, activities covered<br />

Section 2<br />

Field for additional statements to<br />

explain scenario if required.<br />

Section 2.1<br />

Product characteristics<br />

Physical form of product<br />

Concentration of substance in product<br />

Amounts used<br />

Frequency and duration of use<br />

Sector of Use: Industrial SU3 (SU1, SU2a, SU2b, SU4, SU5, SU6b, SU8,<br />

SU9, SU10, SU11, SU12, SU13, SU14, SU15, SU16, SU17)<br />

Process Categories: PROC1, PROC2, PROC3, PROC4, PROC6, PROC7,<br />

PROC8a, PROC8b, PROC9, PROC10, PROC13, PROC15, PROC22a,<br />

PROC22b PROC22c, PROC23a, PROC23b, PROC23c<br />

Environmental Release Categories: ERC 4<br />

Use of <strong>Calcium</strong> <strong>Chloride</strong> as processing aid. Use as a process chemical<br />

or extraction agent. Includes recycling/ recovery, material transfers,<br />

storage, maintenance and loading (including marine vessel/barge,<br />

road/rail car and bulk container), sampling and associated laboratory<br />

activities. E.g. functions as adsorbent, coagulant, emulsion breaker,<br />

alginates, extraction agent, completion fluid, heat transfer fluid, water<br />

treatment chemical or use within the paper industry for example as<br />

antistatic<br />

Operational conditions and risk management measures<br />

Control of worker exposure<br />

Solid, medium dustiness [OC2].<br />

Covers percentage substance in the product up to 100 % (unless<br />

stated differently) [G13].<br />

Not applicable<br />

Covers daily exposures up to 8 hours (unless stated differently) [G2]<br />

Human factors not influenced by risk<br />

management<br />

Other Operational Conditions affecting<br />

worker exposure<br />

Contributing Scenarios<br />

General measures (irritants) [G19].<br />

General exposures [CS1].<br />

Continuous process [CS54].<br />

Not applicable<br />

Assumes use at not more than 20°C above ambient temperature,<br />

unless stated differently [G15].;<br />

Assumes a good basic standard of occupational hygiene is<br />

implemented [G1].<br />

Risk Management Measures<br />

Note: list RMM standard phrases according to the control hierarchy<br />

indicated in the ECHA template: 1. <strong>Technical</strong> measures to prevent<br />

release, 2. <strong>Technical</strong> measures to prevent dispersion, 3. Organisational<br />

measures, 4. Personal protection.<br />

Avoid all skin contact with product, clean up conta<strong>min</strong>ation/spills as<br />

soon as they occur. Wear gloves (tested to EN374) if hand<br />

conta<strong>min</strong>ation likely, wash off any skin conta<strong>min</strong>ation immediately.<br />

Provide basic employee training to prevent / <strong>min</strong>imise exposures and<br />

to report any skin problems that may develop [E3]. Use suitable eye<br />

protection [PPE26].<br />

No specific measures identified [EI18].<br />

page 19 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

General exposures [CS1].<br />

Continuous process [CS54].<br />

With sample collection [CS56].<br />

General exposures [CS1].<br />

Use in contained batch processes<br />

[CS37].<br />

General exposures (open systems)<br />

[CS16].<br />

Batch process [CS55].<br />

With sample collection [CS56].<br />

Filling / preparation of equipment from<br />

drums or containers. [CS45].<br />

Calendering (including Banburys)<br />

[CS64]<br />

Spraying [CS10].<br />

Bulk open loading and unloading<br />

[CS503].<br />

Non-dedicated facility [CS82]<br />

Bulk closed loading and unloading<br />

[CS501].<br />

Dedicated facility [CS81]<br />

Drum/batch transfers [CS8].<br />

Transport [CS58].<br />

Rolling, Brushing [CS51].<br />

Dipping, immersion and pouring<br />

[CS4].<br />

Laboratory activities [CS36].<br />

Equipment cleaning and maintenance<br />

[CS39]. Non-dedicated facility [CS82]<br />

Process sampling [CS2].<br />

Dedicated facility [CS81]<br />

Process sampling [CS2].<br />

Non-dedicated facility [CS82]<br />

General exposures (closed systems)<br />

[CS15]. Elevated temperature<br />

[CS111].<br />

Process temperature ≤ melting point<br />

<strong>Calcium</strong> <strong>Chloride</strong><br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Minimise exposure by partial enclosure of the operation or equipment<br />

and provide extract ventilation at openings [E60]. or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

Drain or remove substance from equipment prior to break-in or<br />

maintenance [E81], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Avoid carrying out operation for more than 4 hours [OC12].<br />

No specific measures identified [EI18].<br />

page 20 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

General exposures (closed systems)<br />

[CS15]. Elevated temperature<br />

[CS111].<br />

Process temperature > melting point<br />

<strong>Calcium</strong> <strong>Chloride</strong><br />

Material transfers [CS3].<br />

(open systems) [CS108].<br />

Batch processes at elevated<br />

temperatures [CS136].<br />

Process temperature ≤ melting point<br />

<strong>Calcium</strong> <strong>Chloride</strong><br />

Material transfers [CS3].<br />

(open systems) [CS108].<br />

Batch processes at elevated<br />

temperatures [CS136].<br />

Process temperature > melting point<br />

<strong>Calcium</strong> <strong>Chloride</strong><br />

Storage [CS67].<br />

General exposures (closed systems)<br />

[CS15].<br />

Provide a good standard of controlled ventilation (10 to 15 air changes<br />

per hour) [E40], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

No specific measures identified [EI18].<br />

Provide a good standard of controlled ventilation (10 to 15 air changes<br />

per hour) [E40], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

No specific measures identified [EI18].<br />

9.5. Industrial outdoor use of calcium chloride - end use<br />

9.5.1. Exposure scenario – Industrial outdoor use (ES5)<br />

Section 1<br />

Exposure Scenario Title<br />

Title ES5: Industrial outdoor use of <strong>Calcium</strong> <strong>Chloride</strong>; CAS: 10043-<br />

52-4<br />

Use Descriptor<br />

Sector of Use: Industrial SU3 (SU1, SU2)<br />

Process Categories: PROC1, PROC2, PROC5, PROC7, PROC8a,<br />

PROC8b, PROC9, PROC13, PROC19<br />

Environmental Release Categories: ERC4<br />

Processes, tasks, activities covered<br />

Section 2<br />

Field for additional statements to<br />

explain scenario if required.<br />

Section 2.1<br />

Product characteristics<br />

Physical form of product<br />

Concentration of substance in product<br />

Amounts used<br />

Frequency and duration of use<br />

Human factors not influenced by risk<br />

management<br />

Industrial outdoor use of <strong>Calcium</strong> <strong>Chloride</strong>. Covers the end use of<br />

<strong>Calcium</strong> chloride either pure or in formulation by spreading, spraying<br />

and pouring. Including storage, materials transfers, mixing, loading<br />

and maintenance. E.g. the use of dust suppression - and de-icingmixtures.<br />

Operational conditions and risk management measures<br />

Control of worker exposure<br />

Solid, medium dustiness [OC2].<br />

Covers percentage substance in the product up to 100 % (unless<br />

stated differently) [G13].<br />

Not applicable<br />

Covers daily exposures up to 8 hours (unless stated differently) [G2]<br />

Not applicable<br />

page 21 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

Other Operational Conditions affecting<br />

worker exposure<br />

Contributing Scenarios<br />

Assumes use at not more than 20°C above ambient temperature,<br />

unless stated differently [G15].<br />

Assumes a good basic standard of occupational hygiene is<br />

implemented [G1].<br />

Outdoor [OC9].<br />

Risk Management Measures<br />

Note: list RMM standard phrases according to the control hierarchy<br />

indicated in the ECHA template: 1. <strong>Technical</strong> measures to prevent<br />

release, 2. <strong>Technical</strong> measures to prevent dispersion, 3. Organisational<br />

measures, 4. Personal protection.<br />

General measures (irritants) [G19].<br />

Mixing operations (open systems)<br />

[CS30].<br />

Bulk open loading and unloading<br />

[CS503].<br />

Non-dedicated facility [CS82]<br />

Bulk closed loading and unloading<br />

[CS501].<br />

Dedicated facility [CS81]<br />

Drum/batch transfers [CS8].<br />

Transport [CS58].<br />

Spraying [CS10].<br />

Spraying [CS10].<br />

Spreading<br />

Large surfaces [CS46].<br />

Mixing operations (open systems)<br />

[CS30].<br />

Manual [CS34].<br />

Spreading Manual [CS34].<br />

Equipment cleaning and maintenance<br />

[CS39].<br />

Non-dedicated facility [CS82]<br />

Storage [CS67].<br />

General exposures (closed systems)<br />

[CS15].<br />

Storage [CS67].<br />

General exposures (closed systems)<br />

[CS15].<br />

With sample collection [CS56].<br />

Section 2.2<br />

Product characteristics<br />

Avoid all skin contact with product, clean up conta<strong>min</strong>ation/spills as<br />

soon as they occur. Wear gloves (tested to EN374) if hand<br />

conta<strong>min</strong>ation likely, wash off any skin conta<strong>min</strong>ation immediately.<br />

Provide basic employee training to prevent / <strong>min</strong>imise exposures and<br />

to report any skin problems that may develop [E3].<br />

Use suitable eye protection [PPE26].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

Minimise exposure by partial enclosure of the operation or equipment<br />

and provide extract ventilation at openings [E60]. or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Avoid carrying out operation for more than 1 hour [OC11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

Control of environmental exposure<br />

Substance is a unique structure [PrC1].<br />

Inorganic substance.<br />

page 22 of 34


Operational conditions<br />

Contributing scenario<br />

SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

Amounts used<br />

Annual tonnage of road salt<br />

1.5 tonnes/km<br />

Fraction of CaCl2 in road salt 0.06<br />

Annual tonnage of CaCl2<br />

0.09 tonnes/km<br />

Frequency and duration of use<br />

Type of release<br />

Dispersive use [FD3].<br />

Emission Days (days/year) [FD4]: 25<br />

Environmental factors not influenced by risk management<br />

Spreading width (m): 10<br />

Other Operational Conditions of Use in open systems.<br />

use affecting environmental<br />

exposure<br />

Release fraction to air from process 0<br />

(initial release prior to RMM) [OOC4]:<br />

Release fraction to wastewater from<br />

process (release after RMMs are<br />

applied):<br />

Release fraction to soil from process<br />

(initial release prior to RMM) [OOC6]:<br />

Conditions and measures related<br />

to municipal sewage treatment<br />

plant<br />

Other environmental control<br />

measures additional to above<br />

Outdoor use [OOC1].<br />

De-icing agent, application as a mixture of 70% NaCl and<br />

30% of a 20% solution of CaCl2<br />

0<br />

1<br />

Not applicable as there is no release to wastewater [STP1].<br />

Avoid spilling salt directly onto plants.<br />

Contributing scenario De-icing agent, application as liquid CaCl2 brine (max. 35%<br />

solution)<br />

Amounts used<br />

Annual tonnage of road salt<br />

0.8 tonnes/km<br />

Fraction of CaCl2 in road salt 0.35<br />

Annual tonnage of CaCl2<br />

0.28 tonnes/km<br />

Frequency and duration of use<br />

Type of release<br />

Dispersive use [FD3].<br />

Emission Days (days/year) [FD4]: 25<br />

Environmental factors not influenced by risk management<br />

Spreading width (m): 10<br />

Other Operational Conditions of Use in open systems.<br />

use affecting environmental<br />

exposure<br />

Release fraction to air from process 0<br />

(initial release prior to RMM) [OOC4]:<br />

Release fraction to wastewater from<br />

process (release after RMMs are<br />

applied):<br />

Release fraction to soil from process<br />

(initial release prior to RMM) [OOC6]:<br />

Conditions and measures related<br />

to municipal sewage treatment<br />

0<br />

1<br />

Not applicable as there is no release to wastewater [STP1].<br />

page 23 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

plant<br />

Other environmental control<br />

measures additional to above<br />

Avoid spilling salt directly onto plants.<br />

Contributing scenario De-icing agent, application as solid CaCl2 (up to 100%)<br />

Amounts used<br />

Annual tonnage of road salt<br />

0.25 tonnes/km<br />

Fraction of CaCl2 in road salt 1<br />

Annual tonnage of CaCl2<br />

0.25 tonnes/km<br />

Frequency and duration of use<br />

Type of release<br />

Dispersive use [FD3].<br />

Emission Days (days/year) [FD4]: 25<br />

Environmental factors not influenced by risk management<br />

Spreading width (m): 10<br />

Other Operational Conditions of Use in open systems.<br />

use affecting environmental<br />

exposure<br />

Release fraction to air from process 0<br />

(initial release prior to RMM) [OOC4]:<br />

Release fraction to wastewater from<br />

process (release after RMMs are<br />

applied):<br />

Release fraction to soil from process<br />

(initial release prior to RMM) [OOC6]:<br />

Conditions and measures related<br />

to municipal sewage treatment<br />

plant<br />

Other environmental control<br />

measures additional to above<br />

0<br />

1<br />

Not applicable as there is no release to wastewater [STP1].<br />

Avoid spilling salt directly onto plants.<br />

Contributing scenario Dust suppressor, application as solid CaCl2 (up to 80%)<br />

Amounts used<br />

Annual tonnage of road salt<br />

3 tonnes/km<br />

Fraction of CaCl2 in road salt 0.8<br />

Annual tonnage of CaCl2<br />

2.4 tonnes/km<br />

Frequency and duration of use<br />

Type of release<br />

Dispersive use [FD3].<br />

Emission Days (days/year) [FD4]: 3<br />

Environmental factors not influenced by risk management<br />

Spreading width (m): 10<br />

Other Operational Conditions of Use in open systems.<br />

use affecting environmental<br />

exposure<br />

Release fraction to air from process 0<br />

(initial release prior to RMM) [OOC4]:<br />

Release fraction to wastewater from<br />

process (release after RMMs are<br />

applied):<br />

Release fraction to soil from process<br />

(initial release prior to RMM) [OOC6]:<br />

0<br />

1<br />

page 24 of 34


Conditions and measures related<br />

to municipal sewage treatment<br />

plant<br />

Other environmental control<br />

measures additional to above<br />

SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

Not applicable as there is no release to wastewater [STP1].<br />

Avoid spilling salt directly onto plants.<br />

Contributing scenario Dust suppressor, application as CaCl2 solution (up to 37%)<br />

Amounts used<br />

Annual tonnage of road salt<br />

3 tonnes/km<br />

Fraction of CaCl2 in road salt 0.37<br />

Annual tonnage of CaCl2<br />

1.11 tonnes/km<br />

Frequency and duration of use<br />

Type of release<br />

Dispersive use [FD3].<br />

Emission Days (days/year) [FD4]: 3<br />

Environmental factors not influenced by risk management<br />

Spreading width (m): 10<br />

Other Operational Conditions of Use in open systems.<br />

use affecting environmental<br />

exposure<br />

Release fraction to air from process 0<br />

(initial release prior to RMM) [OOC4]:<br />

Release fraction to wastewater from<br />

process (release after RMMs are<br />

applied):<br />

Release fraction to soil from process<br />

(initial release prior to RMM) [OOC6]:<br />

Conditions and measures related<br />

to municipal sewage treatment<br />

plant<br />

Other environmental control<br />

measures additional to above<br />

0<br />

1<br />

Not applicable as there is no release to wastewater [STP1].<br />

Avoid spilling salt directly onto plants.<br />

9.6. Professional (indoor) use of calcium chloride<br />

9.6.1. Exposure scenario – Professional indoor use (ES6)<br />

Section 1<br />

Exposure Scenario Title<br />

Title ES6: Professional use of <strong>Calcium</strong> <strong>Chloride</strong>; CAS: 10043-52-4<br />

Use Descriptor<br />

Processes, tasks, activities covered<br />

Section 2<br />

Field for additional statements to<br />

explain scenario if required.<br />

Sector of Use: professional SU22 (SU1, SU10, SU19, SU20, SU0- C23.5/<br />

C23.6)<br />

Process Categories: PROC1, PROC2, PROC 3, PROC4, PROC5, PROC8a,<br />

PROC8b, PROC9, PROC10, PROC11, PROC15, PROC19, PROC20<br />

Environmental Release Categories: ERC 8a, 8d<br />

Professional use of CaCl2. Covers the end use of <strong>Calcium</strong> chloride either<br />

pure or in formulation including pouring/unloading from drums or<br />

containers; and exposures during mixing/diluting in the preparatory<br />

phase and by spraying, brushing, dipping, wiping automated and by<br />

hand. E.g. the use of, washing and cleaning products or use as heat<br />

transfer fluid.<br />

Operational conditions and risk management measures<br />

page 25 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

Section 2.1<br />

Product characteristics<br />

Physical form of product<br />

Concentration of substance in product<br />

Amounts used<br />

Frequency and duration of use<br />

Control of worker exposure<br />

Solid, medium dustiness [OC2].<br />

Covers percentage substance in the product up to 100 % (unless stated<br />

differently) [G13].<br />

Not applicable<br />

Covers daily exposures up to 8 hours (unless stated differently) [G2]<br />

Human factors not influenced by risk<br />

management<br />

Other Operational Conditions affecting<br />

worker exposure<br />

Contributing Scenarios<br />

General measures (irritants) [G19].<br />

General exposures (open systems)<br />

[CS16].<br />

Batch process [CS55].<br />

With sample collection [CS56].<br />

Filling / preparation of equipment from<br />

drums or containers [CS45].<br />

Application of cleaning products in<br />

closed systems [CS101] With sample<br />

collection [CS56].<br />

Filling / preparation of equipment from<br />

drums or containers. [CS45].<br />

Mixing operations (open systems)<br />

[CS30].<br />

Bulk open loading and unloading<br />

[CS503].<br />

Non-dedicated facility [CS82].<br />

Bulk closed loading and unloading<br />

[CS501].<br />

Dedicated facility [CS81].<br />

Pouring from small containers [CS9].<br />

Transport [CS58].<br />

Not applicable<br />

Assumes use at not more than 20°C above ambient temperature, unless<br />

stated differently [G15].;<br />

Assumes a good basic standard of occupational hygiene is implemented<br />

[G1].<br />

Risk Management Measures<br />

Note: list RMM standard phrases according to the control hierarchy<br />

indicated in the ECHA template: 1. <strong>Technical</strong> measures to prevent<br />

release, 2. <strong>Technical</strong> measures to prevent dispersion, 3. Organisational<br />

measures, 4. Personal protection.<br />

Avoid all skin contact with product, clean up conta<strong>min</strong>ation/spills as soon<br />

as they occur. Wear gloves (tested to EN374) if hand conta<strong>min</strong>ation<br />

likely, wash off any skin conta<strong>min</strong>ation immediately. Provide basic<br />

employee training to prevent / <strong>min</strong>imise exposures and to report any<br />

skin problems that may develop [E3].<br />

Use suitable eye protection [PPE26].<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11]. or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29].<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29].<br />

page 26 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

Rolling, Brushing [CS51].<br />

Spraying [CS10].<br />

Mixing operations (open systems)<br />

[CS30].<br />

Manual [CS34].<br />

Manual spot cleaning (e.g. textiles etc)<br />

[CS52].<br />

Heat and pressure transfer fluids<br />

(closed systems) in dispersive use.<br />

Equipment cleaning and maintenance<br />

[CS39].<br />

Non-dedicated facility [CS82]<br />

Laboratory activities [CS36].<br />

Storage [CS67].<br />

General exposures (closed systems)<br />

[CS15].<br />

Storage [CS67].<br />

General exposures (closed systems)<br />

[CS15].<br />

With sample collection [CS56].<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Minimise exposure by partial enclosure of the operation or equipment<br />

and provide extract ventilation at openings [E60]. or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29].<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

No specific measures identified [EI18].<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29].<br />

Provide a good standard of general ventilation (not less than 3 to 5 air<br />

changes per hour) [E11]. or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

9.7. Professional outdoor use of calcium chloride<br />

9.7.1. Exposure scenario – Professional outdoor use (ES7)<br />

Section 1<br />

Exposure Scenario Title<br />

Title Professional outdoor use of <strong>Calcium</strong> <strong>Chloride</strong>; CAS: 10043-52-4<br />

Use Descriptor<br />

Processes, tasks, activities covered<br />

Section 2<br />

Sector of Use: Professional SU22 (SU1, SU5, SU10, SU13, SU19, SU20,<br />

SU0- C23.5/ C23.6)<br />

Process Categories: PROC1, PROC2, PROC5, PROC8a, PROC8b, PROC9,<br />

PROC10, PROC11, PROC13, PROC19, PROC20<br />

Environmental Release Categories: ERC 8d<br />

Professional outdoor use of CaCl2. Covers the end use of <strong>Calcium</strong><br />

chloride either pure or in formulation including pouring/unloading from<br />

drums or containers; and exposures during mixing/diluting in the<br />

preparatory phase and by spraying, brushing, dipping, spreading<br />

automated and by hand. Including storage, equipment clean-downs and<br />

disposal. E.g. the use of agrochemicals, dust suppression- and de-icingmixtures<br />

and the use of cement.<br />

Operational conditions and risk management measures<br />

page 27 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

Field for additional statements to<br />

explain scenario if required.<br />

Section 2.1<br />

Product characteristics<br />

Physical form of product<br />

Concentration of substance in product<br />

Amounts used<br />

Frequency and duration of use<br />

Human factors not influenced by risk<br />

management<br />

Other Operational Conditions affecting<br />

worker exposure<br />

Contributing Scenarios<br />

Control of worker exposure<br />

Solid, medium dustiness [OC2].<br />

Covers percentage substance in the product up to 100 % (unless stated<br />

differently) [G13].<br />

Not applicable<br />

Covers daily exposures up to 8 hours (unless stated differently) [G2]<br />

Not applicable<br />

Assumes use at not more than 20°C above ambient temperature, unless<br />

stated differently [G15].<br />

Assumes a good basic standard of occupational hygiene is implemented<br />

[G1].<br />

Outdoor [OC9].<br />

Risk Management Measures<br />

Note: list RMM standard phrases according to the control hierarchy<br />

indicated in the ECHA template: 1. <strong>Technical</strong> measures to prevent<br />

release, 2. <strong>Technical</strong> measures to prevent dispersion, 3. Organisational<br />

measure, 4. Personal protection.<br />

General measures (irritants) [G19].<br />

Mixing operations (open systems)<br />

[CS30].<br />

Bulk open loading and unloading<br />

[CS503].<br />

Non-dedicated facility [CS82].<br />

Filling / preparation of equipment from<br />

drums or containers. [CS45].<br />

Non-dedicated facility [CS82].<br />

Bulk closed loading and unloading<br />

[CS501].<br />

Dedicated facility [CS81].<br />

Drum/batch transfers [CS8].<br />

Transport [CS58].<br />

Avoid all skin contact with product, clean up conta<strong>min</strong>ation/spills as soon<br />

as they occur. Wear gloves (tested to EN374) if hand conta<strong>min</strong>ation<br />

likely, wash off any skin conta<strong>min</strong>ation immediately. Provide basic<br />

employee training to prevent / <strong>min</strong>imise exposures and to report any<br />

skin problems that may develop [E3].<br />

Use suitable eye protection [PPE26].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

Pouring from small containers [CS9]. No specific measures identified [EI18].<br />

Rolling, Brushing [CS51].<br />

No specific measures identified [EI18].<br />

Spraying [CS10].<br />

Minimise exposure by partial enclosure of the operation or equipment<br />

and provide extract ventilation at openings [E60]. or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Spraying [CS10].<br />

Avoid carrying out operation for more than 1 hour [OC11], or:<br />

Wear a respirator confor<strong>min</strong>g to EN140 with Type A/P2 filter or better<br />

[PPE29]<br />

Dipping, immersion and pouring No specific measures identified [EI18].<br />

page 28 of 34


[CS4].<br />

Spreading Large surfaces [CS46].<br />

Mixing operations (open systems)<br />

[CS30]. Manual [CS34].<br />

Spreading Manual [CS34].<br />

Equipment cleaning and maintenance<br />

[CS39]. Non-dedicated facility [CS82]<br />

Heat and pressure transfer fluids<br />

(closed systems) in dispersive use<br />

Storage [CS67].<br />

General exposures (closed systems)<br />

[CS15].<br />

Storage [CS67].General exposures<br />

(closed systems) [CS15].<br />

With sample collection [CS56].<br />

Section 2.2<br />

Product characteristics<br />

Operational conditions<br />

SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

No specific measures identified [EI18].<br />

Control of environmental exposure<br />

Substance is a unique structure [PrC1].<br />

Inorganic substance.<br />

Outdoor use [OOC1].<br />

Contributing scenario De-icing agent, application as a mixture of 70% NaCl and 30%<br />

of a 20% solution of CaCl2<br />

Amounts used<br />

Annual tonnage of road salt<br />

1.5 tonnes/km<br />

Fraction of CaCl2 in road salt 0.06<br />

Annual tonnage of CaCl2<br />

0.09 tonnes/km<br />

Frequency and duration of use<br />

Type of release<br />

Dispersive use [FD3].<br />

Emission Days (days/year) [FD4]: 25<br />

Environmental factors not influenced by risk management<br />

Spreading width (m): 10<br />

Other Operational Conditions of Use in open systems.<br />

use affecting environmental<br />

exposure<br />

Release fraction to air from process 0<br />

(initial release prior to RMM) [OOC4]:<br />

Release fraction to wastewater from<br />

process (release after RMMs are<br />

applied):<br />

Release fraction to soil from process<br />

(initial release prior to RMM) [OOC6]:<br />

Conditions and measures related<br />

to municipal sewage treatment<br />

plant<br />

Other environmental control<br />

measures additional to above<br />

0<br />

1<br />

Not applicable as there is no release to wastewater [STP1].<br />

Avoid spilling salt directly onto plants.<br />

Contributing scenario De-icing agent, application as liquid CaCl2 brine (max. 35%<br />

solution)<br />

Amounts used<br />

Annual tonnage of road salt<br />

0.8 tonnes/km<br />

Fraction of CaCl2 in road salt 0.35<br />

page 29 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

Annual tonnage of CaCl2<br />

0.28 tonnes/km<br />

Frequency and duration of use<br />

Type of release<br />

Dispersive use [FD3].<br />

Emission Days (days/year) [FD4]: 25<br />

Environmental factors not influenced by risk management<br />

Spreading width (m): 10<br />

Other Operational Conditions of Use in open systems.<br />

use affecting environmental<br />

exposure<br />

Release fraction to air from process 0<br />

(initial release prior to RMM) [OOC4]:<br />

Release fraction to wastewater from<br />

process (release after RMMs are<br />

applied):<br />

Release fraction to soil from process<br />

(initial release prior to RMM) [OOC6]:<br />

Conditions and measures related<br />

to municipal sewage treatment<br />

plant<br />

Other environmental control<br />

measures additional to above<br />

0<br />

1<br />

Not applicable as there is no release to wastewater [STP1].<br />

Avoid spilling salt directly onto plants.<br />

Contributing scenario De-icing agent, application as solid CaCl2 (up to 100%)<br />

Amounts used<br />

Annual tonnage of road salt<br />

0.25 tonnes/km<br />

Fraction of CaCl2 in road salt 1<br />

Annual tonnage of CaCl2<br />

0.25 tonnes/km<br />

Frequency and duration of use<br />

Type of release<br />

Dispersive use [FD3].<br />

Emission Days (days/year) [FD4]: 25<br />

Environmental factors not influenced by risk management<br />

Spreading width (m): 10<br />

Other Operational Conditions of Use in open systems.<br />

use affecting environmental<br />

exposure<br />

Release fraction to air from process 0<br />

(initial release prior to RMM) [OOC4]:<br />

Release fraction to wastewater from<br />

process (release after RMMs are<br />

applied):<br />

Release fraction to soil from process<br />

(initial release prior to RMM) [OOC6]:<br />

Conditions and measures related<br />

to municipal sewage treatment<br />

plant<br />

Other environmental control<br />

measures additional to above<br />

0<br />

1<br />

Not applicable as there is no release to wastewater [STP1].<br />

Avoid spilling salt directly onto plants.<br />

Contributing scenario Dust suppressor, application as solid CaCl2 (up to 80%)<br />

Amounts used<br />

Annual tonnage of road salt<br />

3 tonnes/km<br />

Fraction of CaCl2 in road salt 0.8<br />

page 30 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

Annual tonnage of CaCl2<br />

2.4 tonnes/km<br />

Frequency and duration of use<br />

Type of release<br />

Dispersive use [FD3].<br />

Emission Days (days/year) [FD4]: 3<br />

Environmental factors not influenced by risk management<br />

Spreading width (m): 10<br />

Other Operational Conditions of Use in open systems.<br />

use affecting environmental<br />

exposure<br />

Release fraction to air from process 0<br />

(initial release prior to RMM) [OOC4]:<br />

Release fraction to wastewater from<br />

process (release after RMMs are<br />

applied):<br />

Release fraction to soil from process<br />

(initial release prior to RMM) [OOC6]:<br />

Conditions and measures related<br />

to municipal sewage treatment<br />

plant<br />

Other environmental control<br />

measures additional to above<br />

0<br />

1<br />

Not applicable as there is no release to wastewater [STP1].<br />

Avoid spilling salt directly onto plants.<br />

Contributing scenario Dust suppressor, application as CaCl2 solution (up to 37%)<br />

Amounts used<br />

Annual tonnage of road salt<br />

3 tonnes/km<br />

Fraction of CaCl2 in road salt 0.37<br />

Annual tonnage of CaCl2<br />

1.11 tonnes/km<br />

Frequency and duration of use<br />

Type of release<br />

Dispersive use [FD3].<br />

Emission Days (days/year) [FD4]: 3<br />

Environmental factors not influenced by risk management<br />

Spreading width (m): 10<br />

Other Operational Conditions of Use in open systems.<br />

use affecting environmental<br />

exposure<br />

Release fraction to air from process 0<br />

(initial release prior to RMM) [OOC4]:<br />

Release fraction to wastewater from<br />

process (release after RMMs are<br />

applied):<br />

Release fraction to soil from process<br />

(initial release prior to RMM) [OOC6]:<br />

Conditions and measures related<br />

to municipal sewage treatment<br />

plant<br />

Other environmental control<br />

measures additional to above<br />

0<br />

1<br />

Not applicable as there is no release to wastewater [STP1].<br />

Avoid spilling salt directly onto plants.<br />

page 31 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

9.9. Handling of calcium chloride with low dustiness<br />

9.9.1. Exposure scenario – Handling of calcium chloride with low dustiness (ES9)<br />

Section 1<br />

Exposure Scenario Title<br />

Title Handling of <strong>Calcium</strong> <strong>Chloride</strong> with low dustiness ; CAS: 10043-<br />

52-4<br />

Use Descriptor<br />

Sector of Use: SU3,SU22 (SU1, SU2a,SU4,SU5,SU6b,SU8,SU9, SU10,<br />

SU11,SU12,SU13, SU14,SU15 SU19, SU20, SU0- C23.5/ C23.6)<br />

Processes, tasks, activities covered<br />

Section 2<br />

Field for additional statements to<br />

explain scenario if required.<br />

Section 2.1<br />

Product characteristics<br />

Physical form of product<br />

Concentration of substance in product<br />

Amounts used<br />

Frequency and duration of use<br />

Human factors not influenced by risk<br />

management<br />

Other Operational Conditions affecting<br />

worker exposure<br />

Contributing Scenarios<br />

General measures (irritants) [G19].<br />

General measures applicable to all<br />

activities [CS135].<br />

Process Categories: PROC1, PROC2, PROC3, PROC4, PROC5, PROC6,<br />

PROC7, PROC8a, PROC8b, PROC9, PROC10, PROC11, PROC13,<br />

PROC14, PROC15, PROC22a, PROC22b, PROC22c, PROC23a, PROC23b,<br />

PROC23c<br />

Environmental Release Categories: ERC1, ERC6a, ERC2, ERC4, ERC8a,<br />

ERC8d<br />

Handling of <strong>Calcium</strong> <strong>Chloride</strong> pellets, flakes or other <strong>Calcium</strong> <strong>Chloride</strong><br />

with low dustiness or preparations of these.<br />

Operational conditions and risk management measures<br />

Control of worker exposure<br />

Solid, low dustiness [OC1].<br />

Covers percentage substance in the product up to 100 % (unless stated<br />

differently) [G13].<br />

Not applicable<br />

Covers daily exposures up to 8 hours (unless stated differently) [G2]<br />

Not applicable<br />

Assumes use at not more than 20°C above ambient temperature,<br />

unless stated differently [G15].<br />

Assumes a good basic standard of occupational hygiene is implemented<br />

[G1].<br />

Risk Management Measures<br />

Note: list RMM standard phrases according to the control hierarchy<br />

indicated in the ECHA template: 1. <strong>Technical</strong> measures to prevent<br />

release, 2. <strong>Technical</strong> measures to prevent dispersion, 3. Organisational<br />

measures, 4. Personal protection.<br />

Avoid all skin contact with product, clean up conta<strong>min</strong>ation/spills as<br />

soon as they occur. Wear gloves (tested to EN374) if hand<br />

conta<strong>min</strong>ation likely, wash off any skin conta<strong>min</strong>ation immediately.<br />

Provide basic employee training to prevent / <strong>min</strong>imise exposure.<br />

Use suitable eye protection [PPE26].<br />

No specific measures identified [EI18].<br />

page 32 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

9.10. Use of calcium chloride by consumers<br />

9.10.1. Exposure scenario – Consumers (ES10)<br />

Section 1<br />

Title<br />

Sector of Use<br />

Product Category<br />

Environmental Release<br />

Category<br />

Processes, tasks, activities<br />

covered<br />

Section 2<br />

Exposure Scenario Title<br />

Consumer use of <strong>Calcium</strong> <strong>Chloride</strong> and <strong>Calcium</strong> <strong>Chloride</strong><br />

containing products<br />

SU21<br />

PC2, PC4, PC 5, PC12, PC16, PC 27, PC35, PC37, PC0- UCN<br />

code K35100<br />

ERC8a, ERC8d<br />

Operational conditions (OC) and risk management<br />

measures (RMM)<br />

Field for additional statements to explain scenario if required<br />

Section 2.1<br />

Control of consumer exposure<br />

Physical form of product<br />

Concentration of Covers concentrations up to 100%. [ConsOC1]<br />

substance in product<br />

Additional sub-headers to Standard phrases linked to each sub-header<br />

Product characteristic as<br />

required.<br />

Amounts used<br />

For each use event, covers use amounts up to 50 kg unless<br />

stated differently. [ConsOC2]<br />

Frequency and duration of<br />

use<br />

Covers use up to 365 days/year, unless stated differently<br />

[ConsOC3]; Covers exposure up to 24 hours/event, unless<br />

stated differently [ConsOC14]<br />

Human factors not Inhalation rate up to 32,9 m3/day (Justification; Default<br />

influenced by risk ConsExpo light exercise- 60 kg. Average bw women, is<br />

management<br />

reasonable worst case);<br />

Other Operational Covers use at ambient temperatures. [ConsOC15]; Room<br />

Conditions affecting volume of 1 m 3 ‘Room volume’ is interpreted here as personal<br />

worker exposure<br />

space: a small area of 1 m 3 around the use. Minimum 0,6 Air<br />

Exchange Rate (1/hr) Justification; equals to indoor typical<br />

(ConsExpo General Factsheet (RIVM report 320104002/2006)-<br />

unspecified room). Covers use with a release area up to 125<br />

m2, unless stated differently. “Do not touch eyes when using<br />

this product”.<br />

Chemical Product<br />

Justification<br />

Categories<br />

PC2 (adsorbents) CaCl2 OC No specific operation conditions identified Reasonable<br />

used as domestic<br />

worst-case<br />

dehumidifier.<br />

RMM No specific measures identified<br />

estimate nonspraying<br />

activities<br />

PC4 (antifreeze + deicing)<br />

CaCl2 used for deicing<br />

and antifreeze<br />

OC<br />

RMM<br />

No specific operation conditions identified<br />

No specific measures identified<br />

Reasonable<br />

worst case<br />

estimate nonspraying<br />

activities<br />

PC9b (Fillers, putties, OC No specific operation conditions identified Reasonable<br />

page 33 of 34


SAFETY DATA SHEET<br />

<strong>Calcium</strong> chloride pellets/powder 94-98%<br />

UniPell T M<br />

plasters modelling clay)<br />

<strong>Calcium</strong> <strong>Chloride</strong> used in<br />

modelling clay<br />

PC12 (fertilizers) <strong>Calcium</strong><br />

<strong>Chloride</strong> in domestic<br />

fertilizers<br />

RMM No specific measures identified worst case<br />

estimate nonspraying<br />

activities<br />

OC No specific operation conditions identified Reasonable<br />

worst case<br />

RMM No specific measures identified<br />

estimate nonspraying<br />

activities<br />

OC No specific operation conditions identified Reasonable<br />

worst case<br />

RMM No specific measures identified<br />

estimate nonspraying<br />

activities<br />

OC Non-spraying activities - No specific operation Reasonable<br />

conditions identified<br />

worst case<br />

RMM No specific measures identified<br />

estimate nonspraying<br />

activities<br />

PC16 (Heat transfer<br />

fluids) <strong>Calcium</strong> <strong>Chloride</strong> as<br />

energy source in selfheating-cup.<br />

PC27 (plant protection)<br />

<strong>Calcium</strong> <strong>Chloride</strong> in plant<br />

protection formulations<br />

OC<br />

RMM<br />

Spraying- Covers concentration up to saturation<br />

(45%) [ConsOC1]; Covers spray duration up too<br />

10 <strong>min</strong>utes/event. Covers use in room of 58m3<br />

with room height of 2,5m. Justification; default<br />

Consexpo-Pestcontrol>>surface spraying<br />

Spray away from person<br />

Reasonable<br />

worst case<br />

estimate<br />

spraying.<br />

PC35 (washing and<br />

cleaning products)<br />

<strong>Calcium</strong> <strong>Chloride</strong><br />

containing washing and<br />

cleaning products<br />

OC<br />

RMM<br />

OC<br />

RMM<br />

Non-spraying activities - No specific operation<br />

conditions identified<br />

No specific measures identified<br />

Spraying- Covers concentration up to saturation<br />

(45%) [ConsOC1]; Covers spray duration up too<br />

10 <strong>min</strong>utes/event. Covers use in room of 58m3<br />

with room height of 2,5m. Justification; default<br />

Consexpo-Pestcontrol>>surface spraying<br />

Spray away from person<br />

Reasonable<br />

worst case<br />

estimate nonspraying<br />

activities<br />

Reasonable<br />

worst case<br />

estimate<br />

spraying<br />

PC37 (water treatment<br />

chemicals) <strong>Calcium</strong><br />

<strong>Chloride</strong> used as water<br />

treatment chemical e.g. in<br />

aquaria<br />

PC0- UCN code K35100<br />

(Cement/concrete/mortar)<br />

<strong>Calcium</strong> <strong>Chloride</strong> in<br />

Cement/concrete/mortar<br />

OC<br />

RMM<br />

No specific operation conditions identified<br />

No specific measures identified<br />

Reasonable<br />

worst case<br />

estimate nonspraying<br />

activities<br />

OC No specific operation conditions identified Reasonable<br />

worst case<br />

RMM No specific measures identified<br />

estimate nonspraying<br />

activities<br />

page 34 of 34

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