Arizona - Makhteshim-Agan

PCS No. 04555MAPP 15318A suspension concentrate formulation containing 500 g/l folpet. Contains Folpet andhexamethylene tetramine: may produce an allergic reaction.For protection against Leaf blotch (Septoria tritici/Mycosphaerella gramincola) on wheat and Leaf blotch(Rhynchosporium secalis) on barley.RISK AND SAFETY INFORMATIONLimited evidence of a carcinogenic effect.Very toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.Keep out of reach of children.Keep away from food, drink and animal feeding stuffs.When using do not eat, drink or smoke.Avoid contact with skin and eyes.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.If swallowed, seek medical advice immediately and show this container or label.This material and its container must be disposed of in a safe way.Use appropriate containment to avoid environmental contamination.Do not allow direct spray from ground crop sprayers to fall within 5m of the top of the bank of a staticor flowing waterbody or within 1m of the top of a ditch which is dry at the time of application.Direct spray away from water.SpecimenHARMFULDANGEROUS FORTHE ENVIRONMENTTo avoid risks to man and the environment, comply with the instructions for use PCS No. 04555MAPP 15318MAKHTESHIM-AGAN (UK) LIMITED Unit 16, Thatcham Business Village, Colthrop Way, Thatcham, Berkshire RG19 4LW UKTel: + 44 (0)1635 860555 Technical Helpline: + 44 (0)1635 876622 www.mauk.co.ukARIZONA® is a registered trademark of Makhteshim Agan (UK) LtdPROTECT FROM FROST Batch No. See packaging10 LitresShake well before useFor advice on medical emergencies, fires or major spills telephone the UK National Chemical Emergency Centreon 00 44 (0) 1865 407333UK only: This label is compliant with the CPA Voluntary Initiative Guidance97050735D/201203 MAR 12

This leaflet/booklet is part of the approved product labelARIZONA (PCS No. 04555) MAPP 15318A suspension concentrate formulation containing 500 g/l folpet. Contains Folpet and hexamethylene tetramine:may produce an allergic reaction.For protection against Leaf blotch (Septoria tritici/Mycosphaerella gramincola) on wheat and Leaf blotch (Rhynchosporiumsecalis) on barley.Very toxic to aquaticorganisms, may cause long-termadverse effects in the aquaticenvironment.HARMFULDANGEROUS FORKeep out of reach of children.THE ENVIRONMENTKeep away from food, drink and animal feeding stuffs.When using do not eat, drink or smoke.Avoid contact with skin and eyes.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing and gloves.If swallowed, seek medical advice immediately and show this container or label.This material and its container must be disposed of in a safe way.Use appropriate containment to avoid environmental contamination.Do not allow direct spray from ground crop sprayers to fall within 5m of the top of the bank of a static orflowing waterbody or within 1m of the top of a ditch which is dry at the time of application.Direct spray away from water.PCS No. 04555To avoid risks to man and the environment, comply with the instructions for use. MAPP 15318CropWinter wheat,spring wheat,winter barley,spring barleyRISK AND SAFETY INFORMATIONLimited evidenceof a carcinogenic effect.IMPORTANT INFORMATIONFOR USE ONLY AS A PROFESSIONAL AGRICULTURAL FUNGICIDEMaximum IndividualDose (litres ofproduct/ha)SpecimenMaximum TotalDose (litres ofproduct/ha/crop)Latest Time ofApplication1.5 3 Before end of heading/inflorescence fullyemerged (GS 59)READ THE LABEL BEFORE USE. USING THIS PRODUCT IN A MANNER THAT IS INCONSISTENT WITH THELABEL MAY BE AN OFFENCE. FOLLOW THE CODE OF PRACTICE FOR USING PLANT PROTECTION PRODUCTS.

SAFETY PRECAUTIONSUK only: The Control of Substances Hazardous to Health Regulations may apply to the use of this product at workOperator ProtectionEngineering control of operator exposure must be used where reasonably practicable in addition to the followingpersonal protective equipment.WEAR SUITABLE PROTECTIVE GLOVES when handling the concentrate or handling contaminated surfacesUK only: However, engineering controls may replace personal protective equipment if a COSHH assessment showsthey provide an equal or higher standard of protection.WASH CONCENTRATE from skin or eyes immediately.WASH HANDS AND EXPOSED SKIN before eating or drinking and after work.IF YOU FEEL UNWELL, seek medical advice immediately (show the label where possible).Environmental ProtectionDo not contaminate water with the product or its container. Do not clean application equipment near surface water.Avoid contamination via drains from farmyards and roads.UK only: To protect aquatic organisms respect an unsprayed buffer zone distance to surface water bodies in line withLERAP requirements.UK only: DO NOT ALLOW DIRECT SPRAY from horizontal boom sprayers to fall within 5m of the top of the bank of astatic or flowing water body unless a Local Environmental Risk Assessment for Pesticides (LERAP) permits a narrowerbuffer zone, or within 1m of the top of a ditch which is dry at the time of application. Aim spray away from water.UK only: This product qualifies for inclusion within the Local Environmental Risk Assessment for Pesticides (LERAP)scheme. Before each spraying operation from a horizontal boom sprayer, either a LERAP must be carried out inaccordance with CRD's published guidance or the statutory buffer zone must be maintained. The results of the LERAPmust be recorded and kept available for three years.SpecimenIreland only: Do not allow direct spray from ground crop sprayers to fall within 5m of the top of the bank of a static orflowing waterbody or within 1m of the top of a ditch which is dry at the time of application.Direct spray away from water.Storage and DisposalKEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place.DO NOT RE-USE CONTAINER FOR ANY PURPOSE.

DIRECTIONS FOR USEIMPORTANT: This information is approved as part of the Product Label. All instructions within this section must beread carefully in order to obtain safe and successful use of this product.ResistanceARIZONA contains folpet, a protectant fungicide from the phthalimide chemical group with multi-site contact activity.For resistance management purposes, it's mode of action is classified as M4 under the FRAC* code which indicateslow-risk without any signs of resistance or cross-resistance developing.For current advice on resistance management contact your agronomist or specialist advisor, and visit the FRAG-UKwebsite.Disease Control in Wheat and BarleyFor the reduction of Leaf Spot (Septoria tritici/Mycosphaerella gramincola) in Winter and Spring wheat and Leaf Blotch(Rhynchosporium secalis) in Winter and Spring Barley, ARIZONA may be applied in a programme of 2 suitably timedsprays.Dose Rate1.5 l/ha per applicationSeptoria Leaf Spot (Septoria tritici/Mycosphaerella gramincola) in winter and spring wheatAs ARIZONA is a protectant fungicide with contact activity, it is important to apply the first spray before the diseasebecomes established in the crop (normally GS30-33). A second spray should be timed to protect new growth fromdisease and therefore needs to be applied prior to further infection. This is normally 3 weeks after the first applicationbut may be sooner under conditions of rapid growth and high disease pressure. Where disease infection or re infectionhas occurred prior to application, ARIZONA should be mixed with alternative chemistry, e.g. epoxiconazole, to providecurative activity (see Compatibility section).SpecimenLeaf Blotch (Rhynchosporium secalis) in winter and spring barleyAs ARIZONA is a protectant fungicide with contact activity, it is important to apply the first spray before the diseasebecomes established in the crop (normally GS30-33). A second spray should be timed to protect new growth fromdisease infection. This is normally 3 weeks after the first application but may be sooner under conditions of rapidgrowth and high disease pressure. Where disease infection or re infection has occurred prior to application, ARIZONAshould be mixed with alternative chemistry, e.g. epoxiconazole, to provide curative activity (see Compatibility section).Water VolumeApply ARIZONA in a water volume of 200-400 l/ha. As ARIZONA has contact activity, it is important to achieve a goodcoverage of the crop when spraying.

Mixing and SprayingFor use by tractor mounted/trailed sprayer only.Before spraying it is important to check all hoses, filters and nozzles, and to ensure that the sprayer is clean andcorrectly calibrated to give an accurate application at the correct volume. Half fill sprayer tank with clean water. Add therequired amount of ARIZONA to the water and commence agitation. On emptying the container, RINSE CONTAINERTHOROUGHLY by using an integrated pressure rinsing device or manually rinsing three times. Add washings tosprayer at time of filling and dispose of container safely. Add the remainder of the water whilst continuing to agitate themixture until spraying is complete.Apply ARIZONA as a medium spray (as defined by the BCPC) in cereals.Thoroughly clean the sprayer and measuring equipment after using ARIZONA.CompatibilityUK only: Arizona may be tank mixed with 'Opus' or 'Cortez' which must be applied at the recommended rate of useagainst these diseases.Ireland only: Consult Makhteshim-Agan (UK) Ltd or your distributor for details on the products which may be mixedwith Arizona in Ireland. Maintain agitation during the mixing process and continue until the spraying iscomplete. Do not leave in spray tank for long periods without using.CautionAfter spraying a herbicide, sprayer tanks and equipment should be thoroughly cleaned before using ARIZONA.CONDITIONS OF SUPPLYAll products supplied by us are of high grade and conform to specification at the time of delivery but, as we cannotexercise control over their subsequent storage, handling, mixing or use or the weather conditions before, during andafter application which may affect the performance of the products, all conditions and warranties, statutory orotherwise, as to the quality or fitness for any purpose of our products are excluded and no responsibility or liability willbe accepted by us or our re-sellers for any failure in performance, damage or injury to person or property whatsoeverarising from the storage, handling, application or use of the products. These conditions cannot be varied by our staff oragents whether or not they supervise or assist in the use of such products.Arizona® is a registered trademark of Makhteshim Agan (UK) LtdCortez® is a registered trademark of Makhteshim Agan (UK) LtdOpus® is a registered trademark of BASFSpecimen

Approval holder and Marketing CompanyMakhteshim-Agan (UK) LtdUnit 16Thatcham Business VillageColthrop WayThatchamBerkshireRG19 4LWTel: + 44 (0)1635 860555Technical Helpline: + 44 (0)1635 876622For UK: www.mauk.co.uk For Ireland: www.maireland.ieEmail: admin@mauk.co.uk© Copyright of Makhteshim-Agan (UK) Ltd.*FRAC: Fungicide Resistance Action CommitteeFor advice on medical emergencies, fires or spills telephone the UK National Chemical Emergency Centreon 00 44 (0) 1865 407333UK only: This label is compliant with the CPA Voluntary Initiative GuidanceMAR 12Specimen

MATERIAL SAFETY DATA SHEETARIZONA (PCS No. 04555) MAPP 15318This Safety Data Sheet does not form part of the label approved under thePlant Protection Product Regulations 1995.1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OFTHE COMPANY/UNDERTAKINGTrade name: ARIZONAProduct code : R-6289-UKType of product : FungicideChemical formula : Folpet : C9H4Cl3NO2SChemical description : N-(Trichloromethylthio)phthalimideCompany identification: Makhteshim Chemical Works Ltd.PO Box 60Beer Sheva 84100 Israel.Fax : +972-8-6296848MSDS@ma-industries.comPhone nr : 972-3-6106666 Subscription no. 36789 (Makhteshim)Emergency telephone : +972-8-85152112. HAZARDS IDENTIFICATIONHuman health hazards : Limited evidence of a carcinogenic effect.Environmental hazard : Very toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.3. COMPOSITION/INFORMATION ON INGREDIENTSComponents : This product is considered to be hazardous and contains hazardous components.SpecimenSubstance name Value(s) CAS No EC No Index No ClassificationFolpet : 500 g/l 133-07-3 205-088-6 613-045-00-1 Carc. Cat. 3; R40Xn; R20Xi; R36R43N; R50 (M fact. = 10)Condensed naphthalenesulfonate : ca 4 % ----- ----- ----- Xi; R36/38

4. FIRST AID MEASURESEffects and symptomsRepeated exposure may cause contact dermatitis.Eye contact: Redness, tears.First aid measuresIngestion: Do not induce vomiting. Never give anything by mouth to an unconscious person.Wash out mouth with plenty of water. Consult a doctor.Skin contact: Remove affected clothing and wash all exposed skin area with soap and water,followed by warm water rinse. Consult a doctor in the event of any complaints.Eye contact: Wash off with plenty of water. If pain persists, consult an eye specialist.Inhalation: Consult a doctor in the event of any complaints.Remove victim to fresh air.Note to physician : No specific antidote known. Treat symptomatically and give supportive therapy.If ingested perform gastric lavage and administer activated charcoal.5. FIRE-FIGHTING MEASURESSuitable extinguishingmedia: For small fire: foam, dry chemical, carbon dioxide.For large fire: foam, water fog, water spray.Specific hazards : Thermal decomposition may generate : carbon dioxide, carbon monoxide, nitrogenoxides, sulfur oxide, hydrogen chloride, CSCl2.Protection against fire : Wear proper protective equipment. Self-contained breathing apparatus.Special procedures : Fight fires from a protected location. Dike fire control water for later disposal.6. ACCIDENTAL RELEASE MEASURESFor emergencyresponders : Use appropriate protection (see section 8).EnvironmentalprecautionsClean up methodsSpecimen: Dispose of this material and its container at hazardous or special waste collectionpoint, If the product has contaminated surface water, inform the appropriate authorities.Contaminated soil layers have to be dug out.: In the event of minor spillage: Absorb in sand or other inert material. Use appropriatecontainer to avoid environmental contamination.In the event of major spillage: Collect and contain as much free liquid as possible. Dikespills using absorbent or impervious materials such as sand or clay for later disposal.7. HANDLING AND STORAGEHandling: Do not breathe fumes. Avoid contact with skin and eyes.Storage: Keep locked up. Keep container tightly closed. Keep only in the original container in acool, well ventilated place.Packing: Multi-layer high density polyethylene extrusion blow containers

8. EXPOSURE CONTROLS / PERSONAL PROTECTIONIndustrial hygiene: Facilities storing or utilizing this material should be equipped with an eyewash facility andsafety shower. Wash clothing before re-using. Wash hands thoroughly after handling.Personal protection• Respiratory protection: During spraying wear suitable respiratory equipment.• Skin protection : Wear suitable protective clothing and chemical resistant boots.• Hand protection : Wear suitable gloves.• Eye protection : Chemical goggles or face shield.TLV©: Folpet : Not established9. PHYSICAL AND CHEMICAL PROPERTIESPhysical state at 20 °C : Liquid ( water suspension )Colour: Off-whiteOdour : Faint odour ( characteristic )Melting point [°C] : Folpet :179-180 ( Pure )Flash point [°C] : Not flammableVapour pressure [20°C]: Folpet : 2.1 x (10)-5 Pa (25°C, Pure )Specific gravity : 1.25-1.28Solubility in water : DispersibleLog P octanol /water at 20°C : Folpet : 3.017Explosion limits : Not explosiveMolecular weight : Folpet : 296.6Specimen10.STABILITY AND REACTIVITYChemical stability : Stable under normal conditions.Hazardousdecomposition products: Thermal decomposition may generate : carbon dioxide, carbon monoxide,nitrogen oxides, sulfur oxide, hydrogen chloride, CSCl2.Hazardouspolymerization : Will not occur.Materials to avoid : Alkali materials, such as lime and Bordeaux mixture will reduce fungicidal activity.Conditions to avoid : Protect from sunlight, sources of heat, open flame.

11.TOXICOLOGICAL INFORMATION- Rat oral LD50 [mg/kg]: > 5000- LD50 Rabbit dermal[mg/kg] : > 5000- Rat inhalation LC50[mg/l/4h] : > 5.28Dermal irritation(rabbit): Not irritantEyes irritation (rabbit) : Not irritantSensitization : Guinea pig maximization test: Non sensitizerCarcinogenicity : Folpet : A two-year feeding study of Folpan indicated duodenal tumors in mice afterrepeated administration of high dose levels. The NOAEL (No Observed Adverse EffectLevel) was 450 ppm. No evidence of carcinogenicity was observed in long-term studieswith rats. Information on the mechanism of tumor formation establishes a threshold forthe duodenal tumors, and indicates that this tumor type is not relevant for human riskassessment at likely exposure levels.Mutagenicity : Folpet : Not mutagenic ( in-vivo tests )Toxic for reproduction : Fertility : Folpet : Not teratogenic in animal experiments12.ECOLOGICAL INFORMATIONEcological effectsinformation : The data below are for Folpet :Toxic to aquatic organisms ( fish and algae ), in laboratory experiments.Low toxicity in actual use, due to its hydrolytic instability .LD50 Birds [mg/kg] : > 2000Persistence -degradability : The product is readily biodegradable.Mobility: Product does not leach to ground water.Bioaccumulativepotential: Folpet Does not bioaccumulate in aquatic organisms.Specimen13.DISPOSAL CONSIDERATIONSGeneral: Avoid release to the environment.Dispose in a safe manner in accordance with local/national regulations.14.TRANSPORT INFORMATIONUN N° : 3082Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (500 g/l FOLPET)- IMO-IMDG - classor division : 9H.I. nr : 90- IMDG-Marine pollution: Marine pollutant - Polluant marin

15.REGULATORY INFORMATIONEU Classification : This product is provisionally labelled by the supplier in accordance with the suppliersunderstanding of the EU regulations :Symbol(s) : Xn: Harmful. N: Dangerous for the environment.R Phrase(s)S Phrase(s)Other: R40 - Limited evidence of a carcinogenic effect.R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.: S02 - Keep out of the reach of children.S13 - Keep away from food, drink and animal feedingstuffs.S20/21 - When using, do not eat, drink or smoke.S23 - Do not breathe gas/fumes/vapour/spray.S24/25 - Avoid contact with skin and eyes.S35 - This material and its container must be disposed of in a safe way.S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.S61 - Avoid release to the environment. Refer to special instructions/Safety data sheets.: Contains Folpet & Hexamethylene tetramine. May cause allergic reaction(s).16. OTHER INFORMATIONList of relevant R phrases(heading 3): R20 - Harmful by inhalation.R36 - Irritating to eyes.R36/38 - Irritating to eyes and skin.R40 - Limited evidence of a carcinogenic effect.R43 - May cause sensitization by skin contact.R50 - Very toxic to aquatic organisms.Print date : 31/1/2011Recommended usesand restrictions : None.SpecimenDISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable.However, the information is provided without any warranty, express or implied, regarding its correctness. Theconditions or methods of handling, storage, use or disposal of the product are beyond our control and may bebeyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liabilityfor loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal ofthe product. This MSDS was prepared and is to be used only for this product. If the product is used as a componentin another product, this MSDS information may not be applicable.