Type TR Cleaner/Degreaser - American Polywater

MATERIAL SAFETY DATA SHEET1. IDENTIFICATION OF SUBSTANCE AND PREPARATIONSupplier/Manufacturer:American Polywater Corporation11222 - 60th Street NorthP.O. Box 53Stillwater, MN 55082 USAPhone: 1-651-430-2270Fax: 1-651-430-3634Polywater Europe BVMauritsplaat 126NL-3012CD RotterdamNetherlandsTel: +31 10 233 0578Product Name: Type TR Cleaner/DegreaserSaturated Wipe or Towel PackageChemical Description: Non-flammable SolventAzeotropeProduct Use: Towelette Saturated with CleaningPreparationEmergency Number: +1-651-430-22702. COMPOSITION / INFORMATION ON INGREDIENTSComponent CAS # EC # Wt1-Bromopropane 106-94-5 203-445-0 < 30 gm/towel (>95%)Stabilizers proprietary -- < 2 gm/towel (

Type TR Cleaner/Degreaser – Saturated Wipe/Towel MSDS, page 24. FIRST AID MEASURESEye Contact:Skin Contact:Inhalation (Breathing):Ingestion (Swallowing):If eye irritation from exposure to vapors develops, move to fresh air.Flush eyes with clean water. If irritation persists, seek medicalattention. For direct eye contact, flush with large quantity of water for15 minutes. Seek medical attention.Remove contaminated clothing; flush skin thoroughly with water. Ifirritation occurs, seek medical attention.If irritation of nose or throat develops, move to fresh air. If irritationpersists, seek medical attention. If breathing is difficult, provideoxygen. If not breathing, give artificial respiration. Seek immediatemedical attention.Less than 30 grams solvent per package. Do not induce vomiting orgive anything by mouth. If victim is drowsy or unconscious, place onthe left side with head down. Do not leave victim unattended. Seekmedical attention.5. FIRE-FIGHTING MEASURESFlash Point (bulk liquid):Flammable Limits (bulk liquid):Autoignition Temperature:Hazardous Decomposition andBy-Products:Extinguishing Media:Special Precautions:Unusual Hazards:None (TCC) for solvent (bulk).Approximately 3-8% in air.Not AvailableInclude hydrogen bromide, bromine, oxides of carbon and oxides ofnitrogen.In case of fire, use extinguishing media suitable for surroundingconditions, possibly water, foam, carbon dioxide, or dry agent.Towelettes will ignite. If burning, smother or isolate from otherflammable materials.Vapors are heavier than air and may travel considerable distances.6. ACCIDENTAL RELEASE MEASURESNo spill hazard with saturated towel package.7. HANDLING AND STORAGEKeep containers and cartons containing saturated wipes tightly closed. Keep containers and cartons cool, dry, andaway from sources of ignition. Use and store this product with adequate ventilation. Avoid inhalation of vapors andpersonal contact with the product. Use good personal hygiene practice. Use of pre-saturated towel limitsexposure. All wipes should be disposed of in an environmentally safe manner and in accordance with governmentalregulations.

Type TR Cleaner/Degreaser – Saturated Wipe/Towel MSDS, page 38. EXPOSURE CONTROLS / PERSONAL PROTECTIONRespiratory Protection:Protective Gloves:Eye Protection:Normal ventilation is adequate. Towelette limits solvent vaporexposure. If exposure exceeds recommended limits, respiratorprotection is recommended. Use a respirator or gas mask withcartridges for organic vapors (NIOSH-approved) or use supplied airequipment.The use of impermeable gloves is recommended to prevent drying andpossible irritation. Use of chemically resistant gloves such as Nitrilefor short-term exposure, or Viton or Silvershield for extendedexposures is suggested.None necessary. Wipe package eliminates splash hazard. Do notallow wipe/towel to directly contact eyes.Other Protective Equipment:It is suggested that a source of clean water be available in work areafor flushing eyes and skin. Impervious clothing should be worn asneeded.Exposure Limits andRecommendations: Chemical Component OSHA PEL ACGIH TLVAn AEL (acceptable exposure limit) of 25 ppm has beenrecommended by the United States EPA. OES/LTEL 100 ppm(525mg/m 3 )9. PHYSICAL AND CHEMICAL PROPERTIES (bulk liquid)Appearance:Odor Threshold:A non-linting towel, lightly saturated with clear, colorless liquid.Very lowVapor Density (Air = 1): 4.3Specific Gravity (H 2 O = 1): 1.33Solubility in Water:Boiling Point:Freezing Point:2.5 grams per liter160°F / 71°C (initial)Not AvailableEvaporation Rate: > 2 (n-butyl acetate = 1)Vapor Pressure: >140 mm Hg @ 20°CCoefficient of Water/Oil Distribution:pH:Not AvailableNot ApplicableVolatiles (Weight %): 100%VOC Content:1330 g/L

Type TR Cleaner/Degreaser – Saturated Wipe/Towel MSDS, page 410. STABILITY AND REACTIVITYStability:StableConditions to Avoid:Materials to Avoid:Hazardous Decomposition Products:Avoid heat, flame or other hot surfaces that could cause thermaldecomposition.Strong alkalis, oxidizers and reactive metals (i.e. potassium, sodium,etc.).Thermal decomposition products include hydrogen bromide, bromineand oxides of carbon as well as oxides of nitrogen.11. TOXICOLOGICAL INFORMATIONToxicity to Animals:Chronic Exposure:Medium Aliphatic PetroleumSolventNot AvailableLD 50 (oral rat) 4,260 mg/kgLC 50 (inhl rat) 253,000 mg/m 3 /0.5 hrCarcinogenic Status:Reproductive Toxicity:Mutagenicity:Teratogencity:Toxicologically SynergisticProducts:This substance contains less than 1% 1,2 butylene oxide listed asIARC 2B, “Possibly carcinogenic to humans”.Product may cause reproductive effects based on animal studies.Target organs include kidneys, CNS, liver, and bone marrow.Not AvailableNot AvailableNot Available12. ECOLOGICAL INFORMATIONMobility:Bioaccumulation:Ecotoxicity:Sinks in water.Low potential.Large volumes may penetrate soil and contaminate groundwater.(Unlikely in towelette package.)Ozone Depletion Potential: 0.013 - 0.018Other:Not readily biodegradable, but low atmospheric lifetime.Aquatic Toxicity: 1-Bromopropane: 96 h LC 50 Fathead Minnow 67,300 µl/l13. DISPOSAL CONSIDERATIONSDispose of product in accordance with National and Local Regulations.

Type TR Cleaner/Degreaser – Saturated Wipe/Towel MSDS, page 514. TRANSPORTATION INFORMATIONUN Number:UN Proper Shipping Name:Class and Subsidiary Risk:Packing Group:TDG:ICAO/IATA-DGR:IMDG:ADR/RID:Not ListedNot ApplicableNot ApplicableNot ApplicableNot RegulatedNot RegulatedNot RegulatedNot Regulated15. REGULATORY INFORMATIONUSA Federal and StateAll components are listed on the TSCA inventory.Hazard Categories for SARASection 311/312 ReportingAcute Chronic Fire Pressure ReactiveYes Yes No No NoCERCLA/SARA Sec 302 SARA Sec. 313Components Hazardous Substance RQ EHS TPQ Toxic Release1,2-Butylene Oxide (CAS# 106-88-7) 100 lbs No 1%Type TR Cleaner/Degreaser Solvent Wipes contain less than 1% 1,2 Butylene Oxide as a stabilizer.Any release of 100 lbs or greater must be reported (over 1 million TR-1 Solvent Wipes).California Proposition 65WARNING: This product contains a chemical known to the State of California to cause birth defects or otherreproductive harm.European UnionProduct is classified as hazardous according to European Directives 88/379/EEC and 67/548/EEC and EURegulation (EC) No 1272/2008.Risk Phrases:Safety Phrases:Symbol:R36/37/38: Irritating to eyes, respiratory system and skinR48/20: Harmful: danger of serious damage to health by prolongedexposure through inhalationR60: May impair fertilityR63: Possible risk of harm to the unborn childR67: Vapors may cause drowsiness and dizzinessS2: Keep out of reach of childrenS53: Avoid exposureS45: In case or accident or if you feel unwell, seek medical adviceimmediately.T: Toxic

Type TR Cleaner/Degreaser – Saturated Wipe/Towel MSDS, page 6Product complies with the communication requirements of REACH Regulation (EC) No. 1907/2006. It does notcontain Substances of Very High Concern (SVHC).CanadaThis product has been classified according to the hazard criteria of the CPR and the MSDS contains all theinformation required by the CPR.WHMIS Classification:Canadian DSL:Class D, Division 2BAll ingredients listed.AustraliaAll components are listed on the AICS.Hazardous according to criteria of NOHSC Australia.Contact Information:ADAPT Australia Pty. Ltd.11 - 19 Global DriveTullamarine Victoria 3043Telephone Number. 03 9330 0666Emergency Telephone Number: 0421 277 88916. OTHER INFORMATIONNFPA Ratings: Health: 2Fire: 0Reactivity: 0National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnelduring spill, fire or similar emergencies. Hazard ratings are based on physical and toxic properties of combustion ordecomposition.Revision Date: May. 13, 13Revision Number: 2Reviewed By:S. H. DahlkeThe information and recommendations contained herein are believed to be reliable. However, the supplier makesno warranties, express or implied, concerning the use of this product. The buyer must determine conditions of safeusage and assumes all risk and liability in handling this product.TRWipe:MSDS