3rd International Workshop Advances in Cleaner Production

3 rd International Workshop Advances in Cleaner ProductionArCinzasVaporGasesCinzastermelétricaEvaporadorCarvãoCarvãoCinzasdepositadasLodo

3 rd International Workshop Advances in Cleaner ProductionDepósito de cinzas de carvão ao redor de usina de Figueira –PRFonte: Izidoro, J.; Fungaro, D.; Andrade, A. 2007

69. Amendments to the ConstitutionConsideration was given to an amendment to Part 3 of the CouncilsConstitution in relation to the determination of the Council Tax Base andEstimated Business Rate collection.RESOLVED That approval be given to the inclusion of a delegation to the Director ofResources in Part 3. A. 1 (Council Functions) of the Scheme of Delegation asfollows:g. Director of ResourcesTo determine prior to the start of each financial year, in consultation with theExecutive Member for Resources and Performance Management:1. The Council Tax Base2. The estimated business rates to be collected as set out in the NNDR1return70. Appointments to CommitteesConsideration was given to a revised Membership of the Community ServicesScrutiny Committee for the remainder of the 2012/13 Municipal Year.RESOLVED That Councillor Jonathan Barker be replaced on Community ServicesScrutiny Committee by Councillor Tony Harrison.71. Strategic Plan Progress Reports and Minutes of CommitteesRESOLVED That the Strategic Plan Progress Reports of Executive Members togetherwith the Minutes of the meetings of the following Committees held on thedates shown be received and the decisions contained within them be noted.CommitteesDateThe Executive 16 th October 2012The Executive 20 th November 2012Development Control 18 th October 2012Development Control 29 th November 2012Licensing 22 nd November 2012Community Services 27 th November 2012Resources 4 th December 2012Economic Regeneration 5 th December 2012Standards 7 th November 201272. Waiving of Council Procedure RulesRESOLVED That approval be given to the waiving of Council Procedure Rule 8.1 to allowthe meeting to continue beyond 10pm in order to complete the remainingitems of business.Full Council 20 th December 2012 Page 6 of 7

On motion of Haywood, seconded by Frye, the Board voted unanimously to approve the request ofJames Murray as determined consistent with the standards and policies contained within the GrowthManagement Plan outlined in the recommendations provided by the County Planning Board.Approval of Consent AgendaOn motion of Frye, seconded by Lanier, the Board voted unanimously to approve the ConsentAgenda, as presented, and as follows:• approve minutes of regular meeting & closed session of 11/5/12;• approve surety bonds for elected and appointed officials: Finance Officer Will Massie($500,000); Deputy Finance Officer Suzanne Dale ($500,000); Tax Collector Debra Hill($300,000); Deputy Tax Collectors: Sallie Cheek ($200,000), Revonda Cox ($200,000);Deputy Finance Officers for Jail Commissary: Phyllis Calloway ($10,000), Judy Brown($50,000), JoAnn Sapp ($10,000); Sheriff Maynard Reid ($25,000), Register of Deeds KristaLowe ($50,000);• designate Board of Commissioners Chair (Chief Elected Official) to the Regional PartnershipLocal Workforce Development Area Consortium Chief Elected Official Board;• approve Budget Amendment #13 for DSS ($78,562 Carryover of Adoption Enhancement &Adoption Fees), as follows:2012-2013 Budget OrdinanceGeneral Fund—Budget Amendment #13Revenues Increase DecreaseAppropriated Fund Balance $78,562Appropriations Increase DecreaseSocial Services $78,562• appoint Anne Hockett to the Workforce Development Board to fill the unexpired term ofRobert Leslie, who is no longer eligible to serve;• approve Budget Amendment #14 for Health Dept. ($11,218 Women’s Health, TANF Grant;$4,000 Additional Funding from Div. of Public Health/Environmental Health; $2,208Women’s & Children’s Health/Nutrition Grant: total $17,426), as follows:2012-2013 Budget OrdinanceGeneral Fund—Budget Amendment #14Revenues Increase DecreaseRestricted Intergovernmental $17,426Appropriations Increase DecreasePublic Health $17,426• approve Resolution Supporting Randolph County “Welcome To” Sign On US Highway 220 I-73/74 Northbound, as follows:RESOLUTION SUPPORTING RANDOLPH COUNTY “WELCOME TO” SIGN ON USHIGHWAY 220 I-73/74 NBWHEREAS, the North Carolina Department of Transportation (NCDOT) has investigated a requestfrom Randolph County to erect a welcome sign on the right of way of US 220 I-73/74 NB at or near theRandolph/Montgomery county line; and

3 rd International Workshop Advances in Cleaner ProductionMetodologia – Determinaçãodos Elementos - Percolado 1MENSALMENTE:Determinação porICP-OES e porAAS1

3 rd International Workshop Advances in Cleaner ProductionMetodologia – SoluçãoSimuladora de ChuvaSolução Ácida : Ácido Nítrico + Ácido Sulfúrico – pH = 4,5CinzaBase na média do índice pluviométrico mensal dosúltimos anos da cidade de São PauloAreia

3 rd International Workshop Advances in Cleaner Production‣ Resultados - Fluorescência de Raios-XNa 2 O(%)MgO(%)Al 2 O 3(%)SiO 2(%)P 2 O 5(%)SO 3(%)Cl(%)K 2 O(%)CaO(%)TiO 2(%)V 2 O 5(%)Cr 2 O 3(%)MnO(%)Fe 2 O 3(%)Co 3 O 4(%)1,07 0,87 18,0 54,4 0,23 2,39 0,02 2,63 1,07 1,09 0,06 0,03 0,05 8,08 ndNiO(%)CuO(%)ZnO(%)GeO 2(%)As 2 O 3(%)Rb 2 O(%)SrO(%)Y 2 O 3(%)ZrO 2(%)Nb 2 O 5(%)MoO 3(%)BaO(%)PbO(%)U 3 O 8(%)PF(%)0,01 0,01 0,16 0,01 0,19 0,01 0,05 0,02 0,12 nd 0,01 0,07 0,06 0,03 9,3

3 rd International Workshop Advances in Cleaner ProductionResultados% Elementos na cinza – antes da lixiviação11Massa dos elementos no Percolado% Elementos lixiviados da cinza – após 1 ano

3 rd International Workshop Advances in Cleaner ProductionElementoConcentração dos elementos nopercolado (mg.L -1 )Intervalo – Colunas de CinzaValor deIntervenção em mg L -1CETESB (2005)As 0,390 - 7,540 0,010Cd 0,019 - 0,114 0,005Zn 0,015 - 1,110 5,000Mo 0,069 - 9,21 0,070por 10As, Cd e MoValor de Intervenção- CETESB

Zn (mg/L)3 rd International Workshop Advances in Cleaner Production1,21.21,01.00,80.80,60.6ZnColuna 1Coluna 20,40.40,20.20,00.0Nov Jan Mar Mai Jul SetTempo (Meses)

Mo (mg/L)3 rd International Workshop Advances in Cleaner Production1086Coluna 1Coluna 2Mo420Nov Jan Mar Mai Jul SetTempo (Meses)

Cd (mg/L)Cd (mg/L)3 rd International Workshop Advances in Cleaner Production0,120.120,100.100,080.08CdColuna 1Coluna 20,060.060,040.040,020.020,000.00Nov Jan Mar Mai Jul SetTempo (Meses)

As (mg/L)3 rd International Workshop Advances in Cleaner Production86AsColuna 1Coluna 2420Nov Jan Mar Mai Jul SetTempo (Meses)

Volume adicionadoà coluna (mL)Massa dos elementoslixiviada (mg)3 rd International Workshop Advances in Cleaner Production12001000800600400200Volume adicionadoOut Nov Dez Jan Fev Mar Abr Mai Jun Jul Ago Set43210Out Nov Dez Jan Fev Mar Abr Mai Jun Jul Ago SetTempo (meses)AsCdZnMo

3 rd International Workshop Advances in Cleaner ProductionConclusões:-O chumbo, apesar de presente na cinza de carvão, não foilixiviado nas condições de estudo;-A concentração de As, Cd e Mo no percolado poderepresentar risco de contaminação da água subterrânea,dependendo das características físico-químicas do solo. Ozinco foi lixiviado em quantidade inexpressiva do ponto devista de contaminação da água subterrânea;- Grande parte dos elementos lixiviados da cinza ao longo deum ano foi detectada no período chuvoso, ocorrendo demaneira significativa já no primeiro mês para Zn e Mo e demaneira mais gradual para As e Cd.

3 rd International Workshop Advances in Cleaner ProductionAgradecimentos:Ao Laboratório de Análises Químicas e Ambientais doCQMA.A Dra. Maria Eugênia Gimenez Boscov da EscolaPolitécnica da Universidade de São Paulo.

3 rd International Workshop Advances in Cleaner ProductionCamila Neves Lange - clange@usp.brDra. Iara M. C. de Camargo – icamargo@ipen.brCentro de Química e Meio AmbienteInstituto de Pesquisas Energéticas e Nucleares - IPEN, SPAv. Prof. Lineu Prestes, 2242, 05508-000, São Paulo, SP, Brasil