C - Hanford Site

00J29S)2
JU -10 GINEERING DATA TRANSMITTAL Page 1 of 1
a_
2. To:
_ _ _ _ _
(Receiving Organization)
_ _ _
3. From:
_.__EDT___
(Originating Organization)
_-136130 1__
4. Related EDT No.:
Distribution Site Remediation Management N/A
7. Purchase Order No.:
5. Proj./Prog./Dept.IDiv.: nvrmetl
R staration Engneen a
S. Originator Remarks:
Document for release/approval,
6. Cog. Engr.:
C. A. Rowley
N/A
9. Equip./Component No.:
N/A
10. System/Bldg./Facility:
N/A
12. Major Aesm. Dwg. No.:
11. Receiver Remarks: N/A
13. Permit/Permit Application No.:
N/A
14. Required Response Date:
______________________________________________________ N/A
15. DATA TRANSMITTED (F) (G) (H) (I)
(A) Reason Origi- Receiv-
Item (B) Documnent/Drawing No. (C) Sheet (D) Rev. (E) Title or Description of Data Transmitted Impact for nator er
No. No. No. Level Trans- Dispo- Dispo-
____ Mittal stion sition
1 WHC-SD-EN-TI -136 0 100-N Area Underground Storag~e 4 11/2 1
____________ ____Tank Closures 4;41a
16. KEY
Impact Level (F) Reason for Transmittal (G) Disposition (H) & (1)
1, 2, 3, or 4 (see 1. Approval 4. Review 1. Approved 4. Reviewed no/comment
MRP 5.43) 2. Release 5. Post-Review 2 . DApovdwcom 5. Reviewed w/comment
3. Information 6. Dist. (Receipt Acknow. Required) 3.Dsprvdw/comment 6. Receipt acknowledged
H IG 7 (See Impact Level for required signatures) G (H
Re-Disp. QJ) Name (K Signature (L) Date (M) MSIN QJ) Name (K) Signature IL Date (M) MSIN Re-Disp.
son A, son
1 1 Cog. Eng. C. A. Rowley 6-02 EDMC (2) c )H4;-H' 3
1 1 Cog-.Mgr- R. C. R005.-- fc{' Information Release Admin. (z) H4-17 3
QA Central Files (2) L8-04 3
Safety ERC H6-07 3
-- Env.
1 1 G. S. HunacekA fT-4A,
1 1 D. J. Watsorrr__ __ _ __ __ __ __ _
1.19. U20. 21. DOE APPROVAL (if required)
Ltr No. _ _ _ _ _ _ _
p773 7/-1.7_ Approved
Sint of EDT Date Authorized Representative Date Cognizsr Vanager Date l Approved w/comments
Orgno for Receiving Organization l Disapproved w/comments
BD-7400-172 (07/91)

BLOCK TITLE
INSTRUCTIONS FOR COMPLETION OF THE ENGINEERING DATA TRANSMITTAL,: !
(USE BLACK INK OR TYPE)
(1) EDT 0 Pre-assigned EDT number.
(2) To: (Receiving Organization) 0 Enter the individual's name, title of the organization, or entity (e.g., Distribution) that the EDT is
being transmitted to.
(3) From: (Originating Organization) 0 Enter the title of the organization originating and transmitting the EDT.
(4) Related EDT No. 0, Enter EDT numbers which relate to the data being transmitted.
(5) * Proj./Prog./Dept./Div. 0 Enter the Project/Program/Departrent/ivision tidle or Project/Program acronym or Project
Number, Work Order Number or Organization Code.
(6) * Cognizant Engineer * Enter the name of the individual identified as being responsible for coordinating disposition of
the EDT.
(7) Purchase Order No. * Enter related Purchase Order (P.O.) Number, if available.
(8) * Originator Remarks * Enter special or additional comments concerning transmittal, or "Key" retrieval words may be
entered.
(9) Equipment/Component No. 0 Enter equipment/component number of affected item, if appropriate.
(10) S ystem/Bldg. /Facility 0 Enter appropriate system, building or facility number, if appropriate.
(11) Receiver Remarks 0 Enter special or additional comments concerning transmittal.
(12) Major Assm. Dwg. No. 0 Enter applicable drawing number of major assembly, if appropriate.
(13) Permit/Permit Application No. 0 Enter applicable permit or permit application number, if appropriate.
(14) Required Response Data 0 Enter the date a response is required from individuals identified in Block 17
(1 5) Data Transmitted
(Signature/Distribution).
(A) Item Number * Enter sequential number, beginning with 1, of the information listed on EDT.
(B)* Document/Drawing No. 0 Enter the unique identification number assigned to the document or drawing being transmitted.
(C)* Sheet No. 0 Enter the sheet number of the information being transmitted. If no sheet number. leave blank.
(D)* Rev. No. 0 Enter the revision number of the information being transmitted. If no revision number, leave
blank.
(E) Title or Description of 0 Enter the title of the document or drawing or a brief description of the subject if no title is
Data Transmitted identified.
(F)* Impact Level * Enter the appropriate Impact Level (Block 15). Also, indicate the appropriate approvals for each
item listed, i.e., SQ, ESQ, etc. Use NA for non-engineering documents.
(G) Reason for Transmittal 0 Enter the appropriate code to identify the purpose of the data transmittal (see Block 16).
(H) Originator Disposition * Enter the appropriate disposition code (see Block 16).
(1) Receiver Disposition 0 Enter the appropriate disposition code (see Block 16).
(16) Key 0 Number codes used in completion of Blocks 15 (G), (H), and (1), and 17 (G), (H)
(Signature/Distribution).
(17) Signature/Distribution
(G) Reason 0 Enter the code of the reason for transmittal (Block 16).
(H) Disposition S Enter the code for the disposition (Block 16).
QJ) Name 0 Enter the signature of the individual completing the Disposition 17 (H) and the Transmittal.
(K) Signature 0 Obtain appropriate signature(s).
WL* Date S Enter date signature is obtained.
(M)* MSIN 0 Enter MSIN. Note: If Distribution Sheet is used, show entire distribution (including that
indicated on Page 1 of the EDT) on the Distribution Sheet.
(18) Signature of EDT Originator S Enter the signature and date of the individual originating the EDT (entered prior to transmittal
to Receiving Organization). If the EDT originator is the cognizant engineer, sign both
Blocks 17 and 18.
(19) Authorized Representative * Enter the signature and date of the individual identified by the Receiving Organization as
for Receiving Organization authorized to approve disposition of the EDT and acceptance of the data transmitted, as
applicable.
(20)" Cognizant Manager 0 Enter the signature and date of the cognizant manager. (This signature is authorization for
release.)
(21)" DOE Approval S Enter DOE approval (if required) by letter number and indicate DOE action.
*Asterisk denote the required minimum items check by Configuration Documentation prior to release; these are the minimum release requirements.
BD-7400-1 72R (07/91)

SUPPORTING DOCUMENT 1. Total Pages 350
2. Title 3. Number 4. Rev No.
100-N Area Underground Storage Tank Closures WHC-SD- EN-TI -136. _ 0
5. Key Words 6. Author
182-N-1-DT, 182-N-2-DT, 182-N-3-DT, 105-N-LFT M: .A. Rowley
100-N-SS-27, 100-N-SS-28, soil excavation,N
sample collection APRO EDF0
PUB3LIC RE EASEjY organizati vCharge Code 1f/NA
7. Abstract This report describesthe em~ovadlcharacterization actions concerning
underground storage tanks at the 100-N Area,
8. PUN D S OF DOCUMIENT -Thi as prepar use 10. RELEASE STAMP
wihn S epartment of Ei its ractor is to
be used to perform , or in t under
U.S. Depart of Eneg s. This doc t approved
PATENT STATUS .
o a
ument coy since
edac , is madevil
tr
confi
tted in
piety
U.S. D of Energ . is documen t to be publish r
-its c otherwise diss ed or for purposes other thanRE
aabove before patent Val such release or use has
of ured, upon request, from Patent Counsel, U.S. Department
ofEnergy Field Office, Richland, WA.
DISCLAIMER - This report was prepared as an account of work
sponsored byan agency of the United States Government. Neither the
United States Government nor any agency thereof, nor any of their
employees, nor any of their contractors, subcontractors or their
employees, makes any warranty, express or implied, or asauimes any
legal liability or responsibility for the accuracy, completeness, or
any third party's use or the results of such use of any information,
apparatus, product, or process disclosed, or represents that its use
would not infringe privately owned rights. Reference herein to any
specific commercial product, process, or service by trade nowe,
trademark, mansuf acturer, or otherwise, does not necessarily
constitute or imply its endorsement, recommendation, or favoring by
the United States Government or any agency thereof or its
contractors or subcontractors. The views and opinions of authors
expressed herein do not necessarily state or reflect those of the
United States Governiment or any agency thereof.
AS
OFFICIALRE AS
BY WHC@
DATE JUL 2 1 -1993
9. Impact Level 4
A-6400-073 (11/91) (EF) WEF124

a.
'K
U:
- .-.-
4 U

Dae Reced INFORMATION RELEASE REQUEST Wef-re-ce4
Complete for all Types of Release
El Speech or
Presentation
Purpose
(Check 43
Rp eference
jrechnlcal Report
ID Number (include revision, volume, etc.)
WHC-SD-EN-TI-136, Rev. 0
C3 FuLl Paper only 0 E Thesis or List attachmments.
El
0
Summary
Abstract
suffix) Dissertation
a ManuamEDl363
a] Brochure/FLier ET163
Cl
C]
0] Visual Aid
Speakers Bureau
Poster Session
C]
C]
El
Software/Database
Control led Document
Other
DaaRlseeqid
DaeRlse euid
Jn ,19
11 Videotaoe _____________ _______________________
Tit nde e 1 0 g -r TitelO..NAra
A und r a Sto ag Ta k l os re Unclassified Category7I p c
ndrgoud SorgeTak lours tC- 630 ILevel 4
New or novel (patentable) subject matter? [ NO [H Information received from others in confidence, such as
Yes proprietary data, trade secrets, and/or inventions?
If NYesH, has disclosure been submitted by WNC or other No [7] Yes (identify)
company?
[1No [HYes__DisclosureNo(s). ___________________________
Copyrights? [A No 1]Yes Trademarks?
If NYes", has written permission been granted? No [] Yes (identify)
[]No [] Yes (Attach Permission)
Complete for Speech or Presentation
Title of Conference or Meeting Group or Society Sponsoring
Date(s) of Conference or Meeting City/Stsa Witt proceedings be [] Yes [J No
published? YsN
Witt material be handed [ e ] N
out?
Title of Journal
CHECKLIST FOR SIGNATORIES
Review Reaiui red per WHC-CM-3-4 Yes No Reviewer - Signature Indicates Approval
Classification/Unclassified
Controlled Nuclear Information
Patent - General Counsel
Legal -General Counsel
[
M
1
[H
[1
!Nme(prnted)
_______________________________
S. W. Berglin
S. W. Berglin
'
Sionature Date
Y 3
Applied Technology/Export
Controlled Information or
International Program_________________________________
WHC Program/Project
Commuications
RL Program/Project
Publication Services
Other Program/Project
[1
[
(]
0]. Vatson
A,:7
M. R. Knightf-
Information conforms to all applicable requirements. The above information is certified to be correct.
References Available to intended
Audience
Transmit to DOE-NO/Office of
Yes No
[]
INFOR1MATION RELEASE ADMINISTRATION APPROVAL STAMP
Stemp is required before release. Release is contingent upon
resolution of mandatory comments.
Scientific and Technical
Information5d
Author/Requestor (Print /Signatur
U
Date
F0,
Co A. Rnwlpy ;7
Intende Audience VA
H]Internet [H sponsor [ xera
Responsible Manager (Printec/Signature).5/27/te
R. C.Ros
BD-7600-062 (04a"-V6074 Part 1

a
* S

WHC-SD-EN-TI-136, Rev. 0
CONTENTS
1.0 INTRODUCTION .. .. ........ ....... ........ ... 1
2.0 HISTORY .. ...... ....... ....... ........ .. 1
3.0 182-N-1-DT, 182-N-2-DT, AND 182-N-3-DT. .. ..... ....... .. 1
4.0 105-N-LFT .. ..... ........ ........ .... ...... 3
5.0 100-N-SS-27 AND 100-N-SS-28. .. ........ ....... .... 8
6.0 CLOSURE RECOMMENDATIONS: TANK 100-N-SS-28. .. ..... ....... 15
1.0 SUMMARY .. ...... ....... ........ ....... .. 15
8.0 REFERENCES. .. ..... ........ ....... ........ 15
APPENDIXES:
A MEMO DATED 5-18-93 .. ...... ....... ........ .... A-i
B CORRESPONDENCE. ... ....... ........ ....... ... B-i
C UNUSUAL OCCURRENCE REPORTS. ... ....... ........ .... C-i
D VALIDATED SAMPLE DATA. .. ..... ....... ........ ... D-i
FIGURES:
1. Locations of Underground Storage Tanks at the 100-N Area. ... .... 2
2. Sampling Locations at 182-N-1-DT, 182-N-2-DT, and 182-N-3-DT. .. ... 4
3. Sampling Locations at 105-N-LFT Tank .. ..... ........ ... 7
4. Soil Excavation and Sample Collection at Tank 100-N-SS-27
(3.7 m [12 ft] Below Grade Surface). .. ..... ........ .. 9
5. Soil Excavation and Sample Collection at Tank 100-N-SS-28
(0.46 m and 0.9 m [1.5 ft and 3 ft] Below Grade Surface) .. ..... 10
6. Soil Excavation and Sample Collection at Tank 100-N-SS-28
(3 m [10 ft] Below Grade Surface) .. ... ....... ....... 12
7. Soil Excavation and Sample Collection at Tank 100-N-SS-28
(10.9 cm [36 ft] Below Grade Surface. ... ....... ...... 13
8. Soil Excavation and Sample Collection at Tank 100-N-SS-28
(-12.2, -14.3, and -16.7 m [-40, -47, and -55 ft]) . ..........14
TABLES:
1. Tank Identification. .. ..... ........ ....... .... 3
2. Sample Analyses Results. .. ..... ........ ..........5
iii

WHC-SD-EN-TI-136, Rev. 0
iv

WHC-SD-EN-TI-136, Rev. 0
1.0 INTRODUCTION
This report describes the removal/characterization actions concerning
underground storage tanks (UST) at the 100-N Area (Figure 1). Included are
105-N-LFT, 182-N-1-DT, 182-N-2-DT, 182-N-3-DT, 100-N-SS-27, and 100-N-SS-28.
The text of this report gives a summary of remedial activities. In addition,
correspondence relating to UST closures can be found in Appendix B. Appendix
C contains copies of Unusual Occurrence Reports, and validated sampling data
results comprise Appendix D.
2.0 HISTORY
Tanks 105-N-LFT, 182-N-1-DT, 182-N-2-DT, 182-N-3-DT, and 100-N-SS-27 are
located in the 100-N Area and were temporarily taken out of service in August
1990. Tank 100-N-SS-28 was removed on July 17, 1991. The single-shell tanks
were constructed of carbon steel and varied in size from 11,356 to 56,781 L
(3,000 to 15,000 gal). All tanks contained diesel fuel with the exception of
Tank 100-N-SS-27, which contained unleaded gasoline. The tanks varied in age
from 11 to 30 years at time of removal (Table 1).
Advance notification for closure of UST 105-N-LFT, 182-N-1-DT,
182-N-2-DT, 182-N-3-DT, and 100-N-SS-27 was given in accordance with Chapter
40 Code of Federal Regulations (CFR) 280/281. This 30-day advance
notification was given to the State of Washington Department of Ecology
(Ecology) on September 20, 1990 (Correspondence No. 9004172). Advance
notification for Tank 100-N-SS-28 was given to Ecology on June 13, 1991
(Correspondence No. 9102476) in accordance with Washington Administrative Code
(WAC) 173-360-385.
Notice of Permanent Closure for UST 105-N-LFT, 182-N-1-DT, 182-N-2-DT,
182-N-3-DT, and 100-N-SS-27 was given to Ecology on July 16, 1991
(Correspondence No. 9103422), and Notice of Permanent Closure for
UST 100-N-SS-28 was given on June 13, 1991 (Correspondence No. 9102476) (See
Appendix B).
3.0 182-N-1-DT, 182-N-2-DT, AND 182-N-3-DT
Tanks 182-N-1-DT, 182-N-2-DT, and 182-N-3-DT were removed on November
30, 1990. It was noted in the field log book (WHC 1992a) that these tanks
were in excellent condition with no significant rust or dents. A slight
diesel odor, however, was noticed in the tank excavation area. Further
investigation by the site safety officer (SSO) and the field team leader (FTL)
revealed no levels of organic vapor above background detected with HNU meter
(a tradename of HNU Systems, Inc.). It was suggested that the odor was
probably coming from the valve caissons still in place. Samples were
collected for each respective tank and sent offsite for laboratory analysis
(Figure 2). The results of these samples were below detection levels.
1

WHC-SD-EN-TI-136, Rev. 0
Figure 1. Locations of Underground Storage Tanks at the 100-N Area.
C LL-
00029M 0.9 0
.E 0 0
0 C 0 0
00069M
00
)
-oN
0
z
U)
1o
C14
CF
lp-
:30
0 0
L-00
0
0
00
090
0
00
0 0
z O z z-
02
+
0)
to
0)

WHC-SD-EN-TI-136, Rev. 0
Table 1. Tank Identification. ________
Tank Location Contents Size* Date Removed
182-N-1-DT 100-N Diesel Fuel 15,000 Nov. 30, 1990
182-N-2-DT 100-N Diesel Fuel 15,000 Nov. 30, 1990
182-N-3-DT 100-N Diesel Fuel 15,000 Nov. 30, 1990
105-N-LFT 100-N Diesel Fuel 5,000 Dec. 7, 1990
100-N-SS-27 100-N Unleaded 3,000 Dec. 18, 1990
gasoline
100-N-SS-28 100-N Diesel Fuel 2,000 July 17, 1990*
*Denotes volume in gallons.
**This tank last held unleaded gasoline for approximately 1 year prior to
closure.
After the valve caissons had been removed, further site characterization
continued on March 5, 1991. The soil was noted as looking dark and stained
below the valves. Samples were collected from the discolored soils in all
three caisson locations. Analysis of these samples revealed elevated levels
of petroleum hydrocarbons. On September 14, 1991, further remediation of
contaminated soil under valve caissons was attempted. It was determined that
the contamination extended below and beyond several asbestos-wrapped pipes
that prevented access with the backhoe. Work was delayed until the pipes
could be removed for complete excavation.
On March 26, 1992, the asbestos-wrapped pipes had been removed and
sampling activities were continued. Soil was excavated to a depth of 51 to
63 cm (20 to 25 in.) in each caisson location, and samples were taken. The
FTL noted in the field log book (WHC 1991) that all three sample points were
screened with an OVM meter (a pending tradename of Olympus Corporation) and
were less than detectable at the point of collection. Results from sample
analysis were below action levels. For sample summary, refer to Table 2.
4.0 105-N-LFT
Tank 105-N-LFT was removed on December 7, 1990. The tank was surveyed
and determined to be radiologically contaminated. The outer surface of the
tank measured up to 20,000 counts per minute (cpm) on a Geiger-Mueller meter
(GM). Underground piping and cables prevented proper sloping of the
excavation to allow personnel to enter. Therefore, samples were collected
from the bucket of the backhoe. Four locations were sampled, within the
excavation. Radiological contamination levels of the samples measured between
20,000 to 50,000 cpm. Radiological contamination of samples prevented
laboratory analysis before holding times expired.
On March 30, 1992, resampling activities were implemented (Figure 3).
The tank site was excavated to 3.9 m (13 ft) below ground surface. At this
point, plastic markers used to identify the final depth of original sampling
3

WHC-SD-EN-TI-136, Rev. 0
Figure 2. Sampling Locations at 182-N-1-DT, 182-N-2-DT and 182-N-3-DT
182-N-DT-1 182-N-DT-2 182-N-DT-3
X N-108 X N-116
XN-107
X N-105 N-i 115
XN-1 14
X N-104
X X N-112
X N-103 N-106 XN-113
N-102X XN-101 N-11OX XXN19
XN- 123
XN-124
X N-122
XN-120 N-1210(
L N109ANKN-ill XN-1 18 g -1
47VL777
x x x
L - LA L\
MK-103 (04/05/91) MK-102 (04/05/91) MK-101, MK-105 (04/05/92)
B0iGM3 (04/26/92) B0iGMi, B01GM2 (04/26/92) B01GMO (04/26/92)
xSample Location
Sample Depth - Tanks -11 ft Below Grade Surface
Caissons -25 in. Below Grade Surface
4
-
RCR\031 293-A

F-U
I
z
ZL
0
WHC-SD-EN-TI-136, Rev. 0
Table 2. Sample Analyses Results. (Sheet 1 of 2)
CM CD 0m cm 0DC) cm m
E: E E E EE EE E
a- r r0 00 ~ 04 a 0
wJzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzzz
III
II
Z
Z
W
-
00
z
z
ww
CM CV C') 0
z z z z z
FZZZZZZzZZZZd.rZZZZZZZZZZZZZZZZZZZZZZZZZ

WHC-SD-EN-TI-136, Rev. 0
Table 2. Sample Analyses Results. (Sheet 2 of 2)
0)D))0)M 0) < < <

WHC-SD-EN-TI-136, Rev. 0
Figure 3. Sampling Locations at 105-N-LFI Tank.
BO1GM9 - Clean Blank
105-LFT Tank
X B01GM8
X B01GM6
BO1GM7
X BO1GM4
X Sample Location
(Sample Depth -13 ft
Below Grade Surface)
7
RCR\031 293-B

WHC-SD-EN-TI-136, Rev. 0
excavation were located. Samples were again taken from the bucket of the
backhoe. No indication of tank leakage or petroleum contamination were found
by the FTL at the time of tank removal. Analytical results from samples were
below action levels (See Table 2).
5.0 100-N-SS-27 AND 100-N-SS-28
Tank 100-N-SS-27 was taken out of service on June 22, 1990 because of a
failed tightness test conducted the day before. Twenty- four-hour notification
was made to the Department of Energy (DOE) Richland Operations Office (RL) and
Ecology per 40 CFR 280.61, and an Event Fact Sheet (#D&D/10O-10-90) was
prepared as well. Tank excavation was initiated on December 13, 1990, in
accordance with 40 CFR 280.71. Immediately following tank removal on December-
18, 1990, soil sampling was implemented. Field screening procedures consi sted
of collecting approximately 1/2 cup of soil, placing the soil in a plastic
bag, and sealing by twisting the top, including as much air as possible. The
plastic bag was then shaken for approximately 10 seconds and the OVM probe was
inserted in the bag for a reading. This procedure will be referred to as the
OVM bag technique. Field screening using the OVM bag technique revealed
organic vapor concentrations greater than 200 ppm in the south end of the tank
impression. Additional field screening between 100-N-SS-27 and the sister
tank (100-N-SS-28), which were about 2.7 m (9 ft) apart, showed vapor
concentrations up to 350 ppm. Tank 100-N-SS-27 was noted to be in very good
condition with no observable holes; however, the discovery of petroleum
product in the excavation initiated an Unusual Occurrence Report
(RL-WHC-WHC600EM-1990-0337). It was believed at that time that the
contamination was from occasional overfilling of the tanks and a reported
release of 337 L (89 gal) of gasoline on January 18, 1988 (Unusual Occurrence
WHC-00-88-004-R,D&EO-1). The gravel and porous backfill surrounding the tan ks
may have created a natural pathway for surface spills. Samples were collected
for offsite laboratory analysis (Figure 4). Analytical results from soil
sampling indicate that the contaminated soil from the tank excavation site i s
well above cleanup levels set by the WAC 173-340-745 codes. Therefore,
continued cleanup action was determined to be necessary.
On January 11, 1990, excavation of contaminated soil resumed. An
additional 0.6 m (2 ft) of soil was removed, making the total depth about
4.3 m (14 ft), before reaching the excavation limit of the backhoe. Field
screening using the OVM bag technique revealed elevated levels of volatile
organic vapors ranging from 200 ppm to 350 ppm. There was no indication that
the lower limit of contamination had been reached. The contamination was
believed to extend south under the neighboring tank, 100-N-SS-28. No sample s
were collected at this time for laboratory analysis. It was noted in the 45day
report (Correspondence No. 910299) dated January 31, 1992, that complete
cleanup would require excavation/removal of Tank 100-N-SS-28. The report al sC3
stated that Tank 100-N-SS-28 would be removed within the next three years, at
which time this entire project would be cleaned up or would be included in the
100-NM-i Operable Unit remediation plan.
On July 16, 1991, removal and remediation activities of UST 100-N-SS-28
were implemented under WAC 173-360. Soil was excavated from around the tank
and background samples were taken (Figure 5). The tank was removed the
8

WHC-SD-EN-TI-136, Rev. 0
Figure 4. Soil Excavation and Sample Collection at Tank 100-N-SS-27
(3.7 m (12 ft] Below Grade Surface).
C -C
I 0
I~0 0
0A~
I I X
(NN
V)
I
04
1I0
X
a))
)
I
T) 0
>t U)
04
.0 0 1( U)-
I 0
I 00
0 0
I 00
L - ----
I (D
I IO
I 0I
I I I
(N
I 0I
L -- - - J
I (I)9
CI 0
0

U1)
WHC-SD-EN-TI-136, Rev. 0
Figure 5. Soil Excavation and Sample Collection at Tank 100-N-SS-28
(0.46 m and 0.9 m [1.5 ft and 3 ft] Below Grade Surface).
0
041
S04 (D
r z 00
(N
I I C
00-
X
C,
0.
7-a-
1 0)
L - ---- V
_I z
010
41) 0
01
0

WHC-SD-EN-TI-136, Rev. 0
following day. Visual inspection revealed the tank to be in very good
condition with no holes or damage that would compromise the integrity of the
tank. However, the bottom half of the tank was somewhat dirty, indicating
that it was in contact with liquid. The excavated area also looked wet in the
centerline of the pit. Additional investigation showed a loose pipe
connection on the delivery line leading from the tank to the pump island. An
eroded area of soil directly underneath the loose connection was observed. A
clay layer of saturated soil 15 to 30 cm (6 to 12 in.) deep at the bottom of
the efcavation appeared saturated with petroleum product. Approximately
2.7 m (3 yd 3 ) of this soil was removed and packaged into barrels for
disposal. Samples were collected at this time (IFigure 6). Another Unusual
Occurrence Report was completed on July 17, 1991, (RL--WHC-NREACTOR-1991-
1030). Analytical results verified the soil to be contaminated with petroleum
product. Maximum levels of toluene were 100 mg/kg and xylene 1800 mg/kg (See
Table 2 for sample analyses results and Appendix C for Unusual Occurrence
Reports).
Excavation of 100-N-SS-28 tank site resumed on September 14, 1991, to
remove the contaminated soil. Backhoe limitations prevented excavating deeper
than 7.6 m (25 ft) below grade surface (BGS). Using the bag technique, OVM
readings were approximately 312 ppm. There was no indication that the extent
of the contamination plume had been determined. Work was abandoned at this
time pending further evaluation. Excavation was continued on April 29, 1992.
A bench for the backhoe was excavated 1.5 m (5 ft) BGS in an attempt to remove
the remaining contaminated soil. At 10 m (33 ft) BGS, the OVM bag technique
was utilized. Readings of 440 ppm were detected in the head space of the bag.
Backhoe limitations were once again encountered at 10.0 m (36 ft) BGS, at
which point OVM bag readings were 760 ppm. Samples were collected for offsite
laboratory analysis (Figure 7). These sample results confirmed petroleum
product in the soil. Maximum Levels were toluene, 4.7 mg/kg; diesel, 1000
mg/kg; and kerosene, 3085 mg/kg (See Table 2).
On September 9, 1992, borehole sampling was implemented. The borehole
was positioned over the previous excavation area and soil borings were
collected to assess remaining contamination in the soil. The borehole started
at ground level, drilling through the backfill, and was to extend 1.5 m (5 ft)
below the lowest point of contamination detected by field instruments, or a
maximum of 16.8 m (55 ft) BGS. Sample collection began near contact between
clean fill and native soil, which was approximately 11 m (36 ft) BGS. Samples
were collected from the borehole cuttings at approximately 12.2, 14.3, and
16.8 m (-40, 47, and 55 ft) and sent offsite for analysis (Figure 8).
Analytical results from these samples were less than detectable (See Table 2).
As the borehole was abandoned, three vapor probes were installed at
approximately 6.1, 10.1, and 12.5 m (-20, 33, and 41 ft) depths. Field
screening analysis of vapors through these probes have been below detection
levels.
During the most recent excavation of this tank site (April 29, 1992),
petroleum product was present in the soil. The lack of contamination found
during soil boring activity could be a result of volatilization and
biodegradation of the petroleum contaminants. It is also possible that the
borehole did not intersect the remaining contamination.
Groundwater in the vicinity of the excavation is at approximately 18.2 m
(60 ft). Four groundwater wells are located near the old 100-N fuel station
(Tanks 100-N-SS-27/100-N-SS-28). These wells are 199-N-54, 199-N-55, 199-N-
11

WHC-SD-EN-TI-136, Rev. 0
Figure 6. Soil Excavation and Sample Collection at Tank 100-N-SS-28
(3 m [10 ft] Below Grade Surface).
V
N
0.Lf
1 0-
M I)
U)0
LL
I -C
mU))
------ 12
C4
A
LO o
U) ~
I 4-. L-0
X .
___________________________

WHC-SD-EN-TI-136, Rev. 0
Figure 7. Soil Excavation and Sample Collection at Tank 100-N-SS-28
(10.9 cm [36 ft] Below Grade Surface).
0)1
r
I-
04 E
1 0x
I IJL(:
010
0I
-5
V
IU
I0
IC
0
CI
I)
N
>
I (0
r) -- -- -- CN
U,) Wi
0
2
a 0:
II It
1 0
I0
rr~~( ('D
I I 0
I0 It0
13
4 0 0
3: 0)

WHC-SD-EN-TI-136, Rev. 0
Figure 8. Soil Excavation and Sample Collection at Tank 100-N-SS-28
(-12.2, -14.3, and -16.7 m [-40, -47, and -55 ft]).
39.2 ft-
Approximate
Borehole
Location Side View
48.3 t -
Original Grade_______
100 N-SS --- -- -- --
-. . , I100-N-SS-27
Sample Date 9/11/92
807604, 8076C5
Sample Dote 9/11/92
807606
ISample Location
536f- Sample Date 9/14/92 0 5 Feet
B076DO
0 1 2 Meters
14
RCR\031 293E1

WHC-SD-EN-TI-136, Rev. 0
56, and 199-N-57 (See Figure 1). They have been monitored for total petroleum
hydrocarbons (TPH) and for benzene, toluene, M+P-xylene, and 0-xylene (BTEX)
from 1988 to present. Records back to 1988 indicate that no organic carbons
(other than chloroform) have been detected in any of these wells.
6.0 CLOSURE RECOMMENDATIONS: TANK 100-N-SS-28
The WAC 173-340 "Model Toxic Control Act--Cleanup" and WAC 173-360
"Underground Storage Tank Regulations" are the established guidelines. These
guidelines specify the means and degree for any corrective/cleanup action. If
contaminated soil is found in contact with the groundwater or if soil
contamination appears to extend below the lowest soil sampling depth, testing
shall include the installation of groundwater monitoring wells to test for the
presence of possible groundwater contamination. The minimum testing will be
for BTEX and TPH constituents. Based upon these guidelines, recommendations
of Site Remediation Management (SRM) are as follows:
Option 1: Excavate the area in question using an excavator capable of
reaching depths of at least 12 m (40 ft).
(a) If contamination is not present after excavating to 40 ft BGS, SRM will
consider the site to be clean from petroleum product.
(b) If contamination is determined to be present, excavation will continue
until contaminated soils are removed, or Option 2 will be used.
Option 2: Install monitoring wells as required by the regulations. Because
there are some wells already in close proximity, a compromise could possibly
be reached with the State of Washington concerning the number of wells needed.
7.0 SUMMARY
This document was created in an effort to summarize the
remediation/characterization activities concerning USTs at 100-N Area and to
compile supporting documentation. The 182-N-1-DT, 182-N-2-DT, 182-N-3-DT, and
105-N-LFT UST's are considered clean closed (Appendix A). The 100-N-SS-27 and
100-N-SS-28 UST site are pending a preferred alternative decision for clean
closure. Tables have been created summarizing analytical results. Maps and
figures of removal sites and sample locations are included. Copies of all
official correspondence letters are contained in Appendix B. Unusual
Occurrence Reports can be found in Appendix C, and validated sample
documentation from the offslte laboratories is included in Appendix D.
15

WHC-SD-EN-TI-136, Rev. 0
8.0 REFERENCES
40 CFR 280, 1992, "Technical Standards and Corrective Action Requirements for
Owners and Operators of Underground Storage Tanks (UST)," Code of
Federal Regulations, as amended.
40 CFR 281, 1992, 'Approval of State Underground Storage Tank Programs," Code
of Federal Regulations, as amended.
WAC 173-340, 1990, "The Model Toxics Control Act Cleanup Regulations," Code of
Federal Regulations, as amended.
WAC 173-360, 1990, "Underground Storage Tank Regulations," Washington
Administrative Code, as amended.
WHC, 1991, Field Log Book, "Underground Storage Tank Investigation," EFL-1009,.
Westinghouse Hanford Company, Richland, Washington.
WHC, 1992a, Field Log Book, "Underground Storage Characterization and
Remediation," WHC-N-349, Westinghouse Hanford Company, Richland,
Washington.
WHC, 1992b, Field Log Book, "100-N Gas Station Leaking Underground Storage
Tank Investigation," EFL-1044, Westinghouse Hanford Company, Richland,
Washington.
16

WHC-SD-EN-TI-136, Rev. 0
APPENDIX A
MEMO DATED KAY 18, 1993
A-i

WHC-SD-EN-TI-136, Rev. 0
A-li

WHC-SD-EN-TIL4 36 , Rev. 0
Westinghouse Itra
KHanford Company Mnemna
From: Site Remediation Management Section 81353-93-027
Phone: 6-9218 H6-04~
Date: May 18, 1993
Subject: UST 182-N AND 105-N
To: G. S. Hunacek XO-41
cc: C. A. Rowley H6-04
D. J. Watson XO-41
RCR File/LB
Regarding Underground Storage Tanks 182-N-1-DT, 182-N-2-DT,
182-N-3-DT, AND 105-N-LFT. I was present during removal of
these UST's and performed the original site assessment. I
have reviewed the sample data from the removal and sampling
activities.
Tank 105-N-LFT was not contaminated with petroleum
product and is considered clean.
Tanks 182-N-1,2,3-DT were not contaminated with
petroleum products. There was some incidental
contamination from the valves and piping which has been
removed and is considered clean.
R. C. Roc s
Manager
car
54-7600-081 (2/91) (EF) GEF074 A-1
Internet. Letterhead (Short)

WHC-SD-EN-TI-136, Rev. 0
A-2

WHC-SD-EN-TI-1 36 , Rev 0
APPENDIX B
CORRESPONDENCE
B-i

WHO-SD-EN-TI-i 36 , Rev. 0
B-il

WHC-SD-EN-TI-136, Rev. 0
CONTENTS
Advance Notification for Closure of Underground
Storage Tanks at the Hanford Site (9004172) .. .. . .... ........ B-1
Information and Notifications for Underground
Storage Tanks at the Hanford Site (9103422) .. .. ..... ........ B-5
Forty-Five Day Report for Underground Storage
Tank 100-N-SS-27 (9100299) .. .... ...... . .... .........- 9
Underground Storage Tank 100N-SS-28
Closure (9155942D) .. .... ...... . .... ...... . .....- 17
Permanent Closure of Underground Storage
Tank 10ON-SS-28 (9102476) .. .. .... . ...... .... . ......- 27
B-iii

WHC-SD-EN-TI-136, Rev 0
B-i v

WHC-SD-EN-TI-136, Rev. 0
CORRESPONDENCE DISTRIBUTION COVERSHEET
Author Addressee Correspondence No.
R. D. Izatt Timothy L. Nord 9004172
Subject: ADVANCE NOTIFICATION FOR CLOSURE OF UNDERGROUND STORAGE TANKS AT
THE HANFORD SITE
INTERNAL DISTRIBUTION
Approval. Date Name Location w/att
Correspondence Control A3-01.* X
M. R. Adams H4-55* X
R. J. Bliss 83-04 X
L. C. Brown H4-51 X
G. 0. Carpenter H4-15* X
R. A. Evanhoff GR-10* X
K. A. Gano XO-21* X
C. J. Geier H4-57 X
E- M. Greager .L6-60* X
R. P. Henckel H4-55* X
K. L. Hoewing 83-06 X
M. C. Hughes RI-15 X
G. S. Hunacek XO-4i* X
K. N.; Jordan B2-15* X
R. E. Lerch (assignee) 82-35 x
M. A. tMihalic R1-15* X
M. R. Morton R2-77* X
R. J. Pyzel XO-42* X
R. L. Shuck S4-67* X
D. E. Simpson 83-51 X
0. R. Speer R2-77* X
G. E. Van Sickle RI-15 X
B. L. Vedder 82-19* X
D. J. Watson XO-4i* X
R. D. Wojtasek 82-15 X
*ADDITIONAL DISTRIBUTION EM 42
54-6000-i17(EF) WEF008
Correspondence Distribution Coversheet
B-i

I!". Richland
WHC-SD-EN-TI-136, Rev. 0
Department of Energy
Operations Office
90-ERS-117 E2 i0
Mr. Timothy L. Nord
Hanford Project Manager
State of Washington
Department of Ecology
Mail Stop PV-11
Olympia, Washington 98504-8711
Dear Mr. Nord:
Richiand, Washington 99352 Icmn 047
GuY -
ADVANCE NOTIFICATION FOR CLOSURE OF UNDERGROUND STORAGE TANKS AT THE HANFORD
SITE
Enclosed is a listing of the underground storage tanks (UST) that are being
planned for removal (closure) at the Hanford Site. This notification is
given in accordance with 40 CFR 280/281 to provide a 30-day advance
notification prior to their removal.
Tanks 105-N LFT, 182-N-1-DT, 182-N-2-OT, 182-N-3-DT, and 100-N-SS-27 are
located at the 100-N Area (N Reactor) and were temporarily taken out of
service in August 1990. They are single wall tanks constructed of carbon
steel and vary in size from 3,000 to 15,000 gallons. They vary in age from
11 to 30 years. All the tanks contained diesel fuel except 100-N-SS-27
which contained unleaded gasoline. Due to the complexity of the site, the
piping associated with these tanks (approximately 1,200 linear feet of 2-inch
and 4-inch diameter) will be pressure tested, capped, and left in place to
be remediated when the entire site is decommissioned/remediated. The actual
removal of these tanks is currently scheduled to begin in mid-October.
Tanks 3000-1, 3000-2, 3000-3, and 3000-4 are located in the 3000 area and
were temporarily taken out of service in February of 1990. They are also
single wall tanks constructed of carbon steel and are each approximately
12,000 gallons in size. They are all approximately 40 years old and contained
either gasoline (both leaded and unleaded) or diesel fuel. The removal of
these tanks is scheduled to begin in December and be completed prior to
February.. Their actual removal dates may vary dependent upon winter weather
conditions. Concurrent with the removal of these tanks, tank 325 'will also
be removed. This tank was discovered on site in 1989. Advance notification
for closure of tank 325 was given in Mr. Leo Little's letter to
Mr. Tom Lufkin of June 25, 1990, "Information and notifications for
underground storage tanks at the Hanford Site.' Tank 325 was previously
used to store emergency diesel generator fuel. Although considered exempt
from current regulations, it will be removed under guidance of 40 C-FR 280/281.
The tank is approximately 550 gallons in size and is located in the Hanford
300 Area.
B-2
..-

WHC-SD-EN-TI-136, Rev. 0
Incoming 9004172
Mr. Timothy L. Nord -2- SE
Site assessments and sampling of the tanks will be performed as pa rt of each
tank closure. The Washington State Department of Ecology will be notified
of any unusual circumstances in accordance with the regulations. Additional
USTs are planned for removal in early 1991, but have not yet been scheduled.
Additional notification will be made prior to their removal. When the
closures are complete, revised notification forms will be forwarded to you.
If you have any questions or require additional information, please call
Mr. P. M. Pak at (509) 376-4798.
Sincerely,
ttDirector
ERD: PMP Environm ntal Restoration Division
Enclosure
cc w/encl:
W. H. Bodily, KEH
P. T. Day, EPA
1-R. E. Lerch, WHC
T. B. Veneziano, WHC
B-3

WIIC-SD-EN-TI-136, Rev. 0
UNDERGROUND STORAGE TANKS
PLANNED FOR REMOVAL/CLOSURE DURING FY 1991
Incoming 9004172
ENCLOSURE
Size Date Removed
Tank # Location Contents (Gallons) From Service Scheduled Removal
105-N-LFT 100-N Diesel Fuel 5,000 Aug. 1990 mid-October 1990
182-N-1-DT 100-N Diesel Fuel *15,000 Aug. 1990 mid-October 1990
182-N-2-OT 100-N Diesel Fuel 15,000 Aug. 1990 mid-October 1990
182-N-3-DT 100-N Diesel Fuel 15,000 Aug. 1990 mid-October 1990
100-N-SS-27 100-N Unleaded 3,000 Aug. 1990 mid-October 1990
Gasoline
3000-1 3000 Either Leaded 12,000 Feb. 19.90 December* 1990
Area or Unleaded
Gasoline or
Diesel Fuel
3000-2 3000 12,000 Feb. 1990 December* 1990
Are a
3000-3 3000 12,000 Feb. 1990 December* 1990
Are a
3000-4 3000 "12,000 Feb. 1990 December* 1990
Are a
325 300 Diesel Fuel 550 Unknown December* 1990
Area
*Actual removal dates may vary dependent upon winter weather conditions.
B-4

WHC-SD-EN-TI-136, Rev. 0
CORRESPONDENCE DISTRIBUTION COVERSHEET
Author Addressee Correspondence No.
Leo E. Little Mike C Osweiler Incoming 9103422
RL Ecology XRF: 91543690
subject: INFORMATION AND NOTIFICATIONS FOR UNDERGROUND STORAGE TANKS AT THE
HANFORD SITE
INTERNAL DISTRIBUTION
Approval Date Name Location I'/att
Correspondence Control A3-01
M. R. Adams H4-55
R. J. Bliss, Level 1 83-04
L. C. Brown H4-51
G. D. Carpenter B2-16
M. L. Douglas R2-77
R. A. Evanoff G4-10
K. A. Gano XO-21
C. J. Geier H4-57
R. P. Henckel H-4-55
K. L. Hoewing B3-06
M. C. Hughes (2) L4-88
G. S. Hunacek XO-42
R. E. Lerch, Assignee B2-35
M. A. Mihalic L4-88
A. D. Poor G4-11
R. L. Shuck S4-67
E. H. Smith 132-19
0. J. Watson XO-41
R. D. Wojtasek L4-92
EDMC H4-51
B-5

Department of Energy/
Richland Operations Office
0
91-ERB-129
P.O. Box 550
Richland, Washington
JUL 16 1991
99352
e.--,-
Incoming: 9103422
Mr. Mike C. Osweiler
Nuclear and Mixed Waste,
Hanford Project
State of Washington
Department of Ecology
7601 W. Clearwater, Suite 102
Kennewick, Washington 99336
!:
Dear Mr. Osweiler:
INFORMATION AND NOTIFICATIONS FOR UNDERGROUND STORAGE TANKS (USTs) AT THE
HANFORD SITE
The following notifications and information on the Hanford USTs is attached to
comply with the requirements of the State of Washington Department of
Ecology's (Ecology) UST Regulations as described in WAC 173-360.
Washington State UIST Notification Forms
The Notification forms provided in Attachment 1, have been updated to delete
those tanks removed during Calendar Year (CY) 1990 and CY 1991 (to date), and
to include 12 active emergency generator tanks that were previously
interpreted as being exempt from the Federal UIST Regulations. In addition,
21 abandoned LISTs, all of which were taken out of service prior to
December 22, 1988, have been included. The notification forms do not include
the deferred heating oil tanks that do not require operating permits.
Notice o-f Permanent Closure of STs 105-N-LFT. 182-N--Dr. 182-N-2-DT.
182-N-3-DT. and 100-N-SS-27
Since the tanks (105-N-LFT, 182-N-I-Or, 182-N-2-DT, 182-N-3-DT, and
100-N-SS-27) were removed prior to the time of Ecology's UIST Regulations'
becoming effective, the old Notice of Permanent Closure of UST forms have been
used and included in Attachment 2. The LISTs removed after December 29, 1990,
(3000-1/-2/'-3/'-4) will have the required forms submitted in accordance with
173-360-630 (12) after the site is closed or when final remediation is
complete. (This was a release site.)
Closure of STs at the Hanford Site
A total of nine (9) LISTs have been permanently closed (removed) in
CY 1990/1991 to date. Five LISrs (105-N-LFT, 182-N-I-Or, 182-N-2-DT, 182-11-3-
OT, and 100-N-SS-27) required by CFR 280/281 to be closed by December 22;
1990, were closed (removed) prior to that date. Those USTs (3000-1/-Z/-3/-4)
that were permanently taken out of service in February 1990, were removed in
January 1991. Attachment 3 lists these LISTs, their locations, contents, date
removed from service, and their actual removal dates.
B-6

WHC-SD-EN-TI-136, Rev. 0
Mr. Mike C. Osweiler -2- SII-141~
The advance notification for removal of these USTs (Letter 90-ERB-117,
Mr. R. D. Izatt, DOE-RL, to Mr. Timothy L. Nord, Ecology, 'Advance
Notification for Closure of Underground Storage Tanks at the Hanford Site,w
dated September 20, 1990) stated that approximately 1,200 linear feet of
2-inch and 4-inch diameter piping associated with the USTs to be removed at
the N Reactor site would be pressure tested, capped, and left in place until
final remediation of the N Reactor site. Since pressure testing is not a
requirement of 40 CFR 280.71, nor of WAC 173-360-385, the lines were capped,
but not pressure tested. There was no history of any leakage associated with
these tanks/piping, and therefore, no reason to suspect any leakage. However,
a recent site inspection resulted in notification to Ecology of a site
leak/spill associated with the piping system.
The advance notification also stated that a non-regulated, abandoned UST
(tank 325) located in the 3000 Area would be removed along with tanks
3000-1/-2/-3/'-4. Because of funding considerations, this tank was not removed
at that time. Its removal will be rescheduled as funding becomes available
and advance notification will be provided as required by the regulations.
The sites of LISTs 100-N-SS-27 and 3000-1/-2/-3/-4 (one site) were discovered
to be release sites after the tanks were removed. These sites were
contaminated with gasoline and diesel fuel which, apparently, were the result
of spills/tank overfills and, in the 3000 Area, the result of leaking
pressurized piping associated with the LISTs. Notifications were made to
Ecology as required by the regulations, and the sites have been inspected by
Ecology personnel. A remediation plan is being prepared for the 3000 Area
site and will be made available to Ecology for review and comments prior to
being finalized. (The initial draft is expected to be completed by June 25.)
The sister tank to the 100-N-SS-27 tank (UIST 100-N-22-28) is planned to be
removed in mid-July to facilitate the characterization/remediation of this
site. 30-day advance notification has been provided to Ecology for the
removal effort.
All the LISTs that have been removed as indicated above (with the exception of
the 105-LFT tank) are currently stored at the 100-C Area on the Hanford Site
and are scheduled to be disposed of at off site as scrap. A subcontract for
this action is currently being prepared and is expected to be completed by
August 1991. After its removal, the 105-LFT tank was discovered to be
radioactively contaminated on its exterior surface and is undergoing
decontamination at N Area prior to its being cut up and disposed of at the low
level waste burial ground on the Hanford Site.
The site of LISTs 3000-5/46 (which were removed in September 1989) was also
discovered to have been a release site (see the 45-day report dated
November 1, 1989) and was resampled and then backfilled in January 1991.
Based on the initial sampling results, no additional remedlatlon was required.
Confirmation soil samples were taken and the results of the analysis, along
with the applicable forms as required by WAC 173-360, will be submitted to
Ecology for concurrence on closing the site.
B-7

WHC-SD-EN-TI-136, Rev. 0
Mr. Mike C. Osweiler -3- 91-ERB-129
At is M
Hanford UST Tightness Testing and Piping Pressure Testing for CY 1991
Attachment 4 provides the results of the tightness testing required by 40 CFR
280. Tightness testing was completed by December 22, 1990, for all the USTs
as required by the regulations. The results were acceptable with the
exceptions of UST 200E-HSF17 (helicopter refueling pad) and UST 100-N-SS-27.
UST 2OOE-HSF17 was found to have a leak around each of its manhole covers
during its initial testing in August 1990. In addition, testing on
its suction piping was not completed due to an internal pump leak. The tank
was temporarily taken out of service, repaired, and was successfully retested
on December 28, 1990. UST 100-N-SS-27 was determined to have a leak near the
top of the tank. This tank was removed from service in June and closed
(removed) in December 1990.
If there are any questions concerning this matter, please contact
Mr. Paul M. Pak of my staff at (509) 376-4798.
Sincerely,
Peo!E.itteAssistant Manager
ERD:PMP Xor Environmental Management
Attachments:
1. Washington State UST Notification Form
2. Notice of Permanent Closure of liSTs
3. Hanford liSTs Closures During CY 1990/1991
4. Hanford UiST Tank Tightness Testing
and Piping Pressure Testing for CY 1990
cc w/att:
P. T. Day, EPA
T. Lufkin, Ecology
T. 1. Nord, Ecology
T. B. Veneziano, WHC
cc w/o att:
W. H. Bodily, KEH
T. D. Chikalla, PNL
R. E. Lerch, WfIC
M. C. Hughes, WHC
B-8

WHC-SD-EN-TI-136, Rev. 0
CORRESPONDENCE DISTRIBUTION COVERSHEET
Author Addressee Correspondence wo.
N. M. Highland Dave Nylander Incoming 9100299
U.S. Dept. of Energy Ecology XRF: 91506830
Subject: FORTY-FIVE DAY REPORT FOR UNDERGROUND STORAGE TANK IOON-SS-27
INTERNAL DISTRIBUTION
ApprovaL Date Name Location Wlat t
Correspondence Control A3-01 X
M. Rt. Adams H4-55 X
R. J. Bliss B3-04 X
L. C. Brown H4-51 X
G. D. Carpenter B2-16 X
M. L. Douglas R2-77 X
R. A. Evanoff G4-10 X
K. A. Gano XO-21 X
C. J. Geier H4-57 X
R. P. Henckel H4-55 X
K. L. Hoewing B3-06 X
M. C. Hughes (2) L4-88 X
G. S. Hunacek X
1. D. Jacques ~ t6-60 X
K. Rt. Jordan B3-51 X
Rt. E. Lerch (assignee) B2-35 X
M. A. Mihalic L4-88 X
A. D. Poor G4-11 X
R. J. Pyzel XO-42 X
-ft. L. Shuck S4-67 X
E. H. Smith B2-19 X
D. R. Speer R2-77 X
G. E. Van Sickle R2-81 X
D. J. Watson XO-41 X
R. 0. Wojtasek L4-92 X
EDMC H4-51
B-9

Mr. Dave Nylander
State of Washington
Department of Ecology
7601 W. Clearwater, Suite 102
Kennewick, WA 99336
Dear Mr. Nylander:
WHC-SD-EN-TI-136, Rev. 0
Department of Energy
P-0 Bu- 550
JAN~ 3 Incoming
9100299
FORTY-FIVE DAY REPORT FOR UNDERGROUND STORAGE TANK (UST) 100N-22-27
Attached are the Twenty and Forty Five Day Reports on UST 100N-SS-27, that was
discovered to be leaking after its removal on December 18, 1990. This report
is the required follow-up of the verbal notification given to the Washington
State Department of Ecology by the U.S. Department of Energy Richland
Operations Office (DOE-RL) on December 19, 1990. A Twenty/Forty Five Day
report was previously submitted (July 1990) for this same UST when it was
discovered to have a minor leak during tightness testing.
Should you have any questions or require additional information, please
contact Mr. N. G. Thomas of my staff on (509) 376-9624 or Mr. M. C. Hughes of
Westinghouse Hanford Company on (509) 373-3262.
Sincerely,
Nadine M. Highland, Director
SID:NGT Site Infrastructure Division
Endlosure
cc w/encl:
P. T. Day, EPA
R . E. Lerch, WHC tggZ.3
R. F. Stanley, Ecology
T. L. Nord, Ecology
R. A. Holten, DOE-RL
G. M. Bell, DOE-RL
R. D. Izatt, DOE-RL
B- 10

INTRODUCTION
WC-SD-EN-TI-136, Rev. 0
FORTY-FIVE DAY REPORT
FOR UNDERGROUND STORAGE TANK IOON-SS-27
This report describes the site investigation and remediation plan for
the 100N-SS-27 fuel tank removal, located in the 100 N Reactor Area on the
Hanford site at the Fuel Station (Figure 1). The tank, approximately 23 years
old, has a 3,000 gallon capacity and was last used to store unleaded gasoline.
The tank was taken out of service on June 22, 1990, because of a failed
tightness test conducted the previous day. Twenty-four hour notification was
made to DOE-RL and Ecology per 40CFR280.61, and an Event Fact Sheet (#D&D/100-
10-90) was prepared as well.
TANK EXCAVATION
Tank excavation and tank removal were completed on December 18, 1990.
Approximately 25 feet of associated piping was removed from the ground along
with the tank. An inspection of the tank did not reveal any holes or cracks
and the overall condition of the tank was very good. The tank was taken to
the 190-C storage pad and will be cleaned and sold as scrap.
Immediately following the lifting of the tank, soil sampling was
conducted to test for the presence of contaminated soil . Samples were
collected for laboratory analyses of volatile and semi-volatile compounds to
assess potential petroleum hydrocarbon contamination. An organic vapor
monitor (OVM; HNU model PL 101) was used for the field investigation. The
field procedure consisted of collecting approximately 1/2 cup of soil, placing
it in a plastic bag, and sealing by twisting the top while including as much
air as possible. The plastic bag was then shaken for approximately 10 seconds
and the OVM probe was inserted in the bag for a reading. Photographs were
taken during and after tank excavation to document the condition of the tank
and surrounding soil.
INITIAL FIELD INVESTIGATION
The field sampling in the north 8 feet of the excavation (see Figure 2)
did not indicate a presence volatile organics. Samples taken at the south end
of the tank impression had readings in excess of 200 ppm. Additional field
samples were taken on the south end of the excavation between the IOON-SS-27
and -28 tank, approximately 9 feet apart, which showed vapor concentrations of
up to 350 ppm. Field sampling along the piping trench did not reveal the
presence of any volatile organics.
In addition to the field screening, additional samples were collected in
the same approximate locations, for laboratory analyses (Figure 2). These
were taken with new stainless steel spoons and deposited directly into clean
QA I-Chem bottles. The samples were packed in ice and sent to the K-25
Laboratory in Oak Ridge Tennessee for analysis. Chain of custody records will
be maintained.
B-11

INITIAL CLEAN UP
WHC-SD-EN-TI-136, Rev. 0
The initial site remediation plan was to excavate while taking field
samples until clean soil was encountered. Because the tank was in good
condition, the contamination was believed to be from a confirmed and reported
83- to 95-gallon spill that occurred on January 18, 1988, and from occasional
overfills and spills that may have gone unreported over the tank's 20 plus
years of service.
On January 11, 1990, another 2 feet of soil was removed from the south
end of the excavation with every 5th bucket being sampled with the OVM bag
technique. The last 4 buckets showed sequentially greater concentrations of
volatile organic vapors, ranging from 200 ppm to 350 ppm. There was no
indication that the lower limit of contamination had been reached. The
contamination is believed to extend south, under the neighboring tank, 100N-
SS-28 (Figure 3).
INTERIM PLAN
The l00-N-SS-28 tank will be removed within the next three years.
Because complete clean up would require excavation back under this tank, it is
planned to remediate the entire site at a later date. The cleanup may take
place at the time of removal of the 100-N-SS-28 tank or as part of the 100-NM-
1 Operable Unit. The 100-N-SS-28 was tightness tested on October 18, 1990 and
was determined to be tight per 40CFR280.43(c). Furthermore, filling
procedures have been implemented that prevent any tank overfills.
There are four ground water monitoring wells positioned down stream of
the fuel station. These wells have been monitored since June 1989 for a
limited constituent list. The majority of the organic constituents were below
detectable limits. Any elevated quantities of aliphatic hydrocarbons
(indicating diesel fuel) would have shown up in the volatile organic analysis.
None were found in any of the groundwater samples collected from these wells.
In consideration of the above information, it is believed that the
source of the existing contamination has been eliminated.
We are continuing to investigate the cause of the contaminated soil
found under tank 100-N-SS-27. Other measures are being taken to determine the
extent of the contaminated soil and whether cleanup should be deferred until
100-N-SS-28 tank is removed in three years.
B-12

"O143.4
Xf 0
M1~.
CONM
0 ~ ~C
,U
rgug-e I
WHC-SD-EN-TI-1.36, Rev. 0
B-IN 13
AREACTRAE
CAL INFC5
0

C/C)
WHC-SD-EN-TI-136, Rev. 0
z.
I. <
cu _r,
cuc
00J
LLA-
LiL
-- JL
0 l
Iz 9
B- 14
z

mL
WHC-SD-EN-TI-136, Rev. 0
- J
-~< <
zz
ccu
w <
B-i15
z-
z
IL-
=<
z
zI-m
0o
c -

WHC-SD-EN-TI-136, Rev. 0
TWENTY-DAY REPORT
FOR UNDERGROUND STORAGE TANK 100N-SS-27
9150027D
ATTACHMENT
This report describes the site investigation and intended remediation
activities for the 100N-SS-27 underground storage tank. This 3000 gallon tank
site is located at the 100 N Area Service Station on the Hanford Site and is
approximately 23 years old. It was last used to store unleaded gasoline. The
tank was taken out of service on June 22, 1990, because of a failed tightness
test conducted the day before. The leak was determined to be in the top of
the tank where the fill tube is attached. This portion of the tank does not
normally contain product, but was used for the tightness test. This was
previously reported to Ecology in July 1990 via a 20/45 Day Report.
Tank excavation and removal were initiated on December 13, 1990, per 40 CFR
280.71. Immediately following the tank removal on December 18, soil sampling
was conducted to test for the presence of contaminated soil. Samples were
collected for laboratory analyses of volatile and semi-volatile compounds to
assess potential petroleum hydrocarbon contamination. An organic vapor
monitor was used for the field investigation. The field procedure consisted
of collecting approximately 1/2 cup of soil, placing it in a plastic bag, and
sealing by twisting the top while including as much air as possible. The
plastic bag was then shaken for approximately 10 seconds and the OVM probe was
inserted in the bag for a reading.
The field sampling indicated organic vapor concentrations greater than 200 ppm
were present in the south end of the tank impression. Additional samples
taken on the south end between the 100N-SS-27 and -28 tank, approximately nine
feet apart, showed vapor concentrations of up to 350 ppm.
The tank was in very good condition with no observable holes. It is believed
that the contamination was from occasional overfilling of the tanks and from
an 83 to 95 gallon spill that occurred on January 18, 1988, (and reported to
Ecology). The gravel and porous backfill surrounding the tanks may have
created a natural pathway for surface spills.
Current plans are to remove the contaminated soil from the tank impression,
sample for organic vapors, and backfill once the excavation is determined to
be clean. The contaminated soil will be taken to an area where it can be
stored on plastic for proposed solid phase remediation at a later date. The
tank has been taken to a storage pad and will be cleaned/flushed and disposed
of as clean salvage.
B- 16

WHC-SD-EN-TI-136, Rev. 0
CORRESPONDENCE DISTRIBUTION COVERSHEET
Author Addressee Correspondence go.
M. A. Mihalic, 6-0967 E. A. Bracken, RL 91559420
sub~ject: UNDERGROUND STORAGE TANK 100N-SS-28 CLOSURE
INTERNAL DISTRIBUTION
ApprovaL Date Name Location W/att
Correspondence Control A3-01 X
President's Office 83-01
R. J. Bliss 133-04 X
G. D. Carpenter B2-16 X
M. L. Douglas R2-77 X
C. 3. Geier H4-57 X
x R. P. Henckel 1-4-55 X
IAIAK. L. Hoewing B3-06 X
&I /,M. C. Hughes (2) L4-88 X
Xf~- G. S. Hunacek XO-41 X
R. E. Lerch B2-35 X
xM. A. Mihalic 1-4-88 X
R. G. Shuck S4-67 X
* E. H. Smith B2-19 X
X D . J. Watson XO-41 X
R. D. Wojtasek L4-92 X
EDMC 114-22 X
B- 17

Westinghouse WHC-SD-EN-TI-136, Rev. 0
~JHanford Company
P.0. Box 1970 Richland, WA 99352
August 14, 1991 91559420
Ms. E. A. Bracken, Director J.
Environmental Restoration Division .
U.S. Department of Energy
Field Office, Richland
Richland, Washington 99352
Dear Ms. Bracken:
UNDERGROUND STORAGE TANK IOON-SS-28 CLOSURE
Attachment I to this letter is the completed Permanent Closure/Change-In-
Service Checklist, and Attachment 2 (two copies) is the Site Check/Site
Assessment Checklist for underground storage tank 100N-SS-28, which was
permanently closed (removed) on July 17, 1991. These checklists are required
to be submitted to Ecology in accordance with the requirements of Washington
Administrative Code 173-360-630 (12).
The U.S. Department of Energy Field Office, Richland, is requested to submit
these checklists to the Washington State Department of Ecology (Ecology) no
later than August 19, 1991. Attachment 3 is a draft transmittal letter to
Ecology.
If you have questions regarding this information, please call me on 376-7000,
or Mr. M. C. Hughes at 376-0787.
Very truly yours,
R. D. Wojtasek, Manager
Environmental Restoration Program
Environmental Division
mag
Attachments 3
RL - J. K. Erickson
E. D. Goller
R. 0. Puthoff (w/o attachments)
R. P. Saget
B-18
Hanicid OQefations and Engineering Contractor for the US Oepantment of Energy

WHC-SD-EN-TI-136, Rev. 0
8-19
91 55942D
ATTACHMENT 1
2 Pages

WHC-SD-EN-TI-136, Rev. 0
UNDERGROUND STORAGE TANK
Site Check/Site Assessment Checklist
Tbc pur pose oft this form is to certify the proper invesligatiufl of atn USTstc for thc prcscncc of a release. These acu iviics
shall he conducted in aceordatncc with Chzuptcr 1 73.3(A) WAC. A description of thc various sit uzt ions requiring a site
check or sitc assessment is provided in the guidance document for LIST site checks and site assessments.
This Site Check/Sitc Assessment Chcckli.-t shall he completed and signed by a person rcgistcrcd with the Department of
Ecology to perform sitc asescssmcnts.
Two copies of the results of the site check or site assc.ssmcnt should bc included with this checklist according to the reporting
requirements in the guidance document for LIST site checks and site assessments.
For further information about comipleting this form, plcase contact thc Department of Ecology LIST Program.
The completed checklist should he mailcd to thfe following iddrcss:
1. LIST SYSTEM OWNER AND LOCATION
Underground Storage Tank Section
Department of Ecology
Mail Stop PV- I I
Olym~pia. WA 98504-8711
UST Owner/Operato: IJ~f l3rt.Mggt nf Pgrgy Richlandl nopra-tinnc
Owners Address: 825 Jadwinf
SOWt
Richland
cey
WA
550
P 0. 50-t
99352
zIP CO"
.Telephone: (509 ) 3767387
Site 10 Number (an invoice or available from Ecology if tank is registered):
01 2763
She/Business Name: U.S. Department of Energy - Richland Operations
Sao Address: 825 Jadwin P.O. Box 550
skem
Benton
co.-v~
Richland WA 99352
Ciy om ZIP Cod*
2. SITE CHECKISITE ASSESSMENT CONDUCTED BY:
Registered Person: Ronald M - Mi tchell1
Address: Westinghouse Hanford Company P. 0. Box 1970
Telephone: (509 ) 3765122
Richland WA 99352 -
.11 "A1-4 11AM
B-20
Pag

WHC-SDI-EN-TI-136, Rev. 0
This page must be completed separately for each tank permanently closed (decommissioned) or change-
In-service at the site. For additional tanks you may photocopy this form prior to completing.
3. TANK CLOSURE/CH-ANGE.IN-SERVICE INFORMATION
1. Tank ID Number (as registered with Ecology): 10ON-SS-28 2. Year installed: 1 976
3. Tank capacity in gallons: 2000______________ 4. Date of last use: 12/90__________
5. Last substance stored: Ulae Gsoie6. Date of clostue/change-in-seivice: 7/1 7/91
7. Type of closure: Closure with lank Rlemoval [I In-place Clostite Change-in-Seivice L
8. It in-place closure is used, the tank has been filled with the following substance: N/A
9. If change-in-service, Indicate new substance stored in tank: N/A
10. Local per mit (s) (it any) obtained from: N/A
Always contact local authorities regarding permit requirements.
11. Has a site assessment been completed? Yes Eli No
Unless an external release detection system is operating at the time o1 closure or change in service, and a report is provided as specified in WAC
173-360-390, a site assessment must be conducted. This site assessmenit must be cotiducted by a person registered with the Department of
Ecology to perform site assessmeonts. Remilts of tits site ass essapent must be included will) tite Site Assessment Checklist (ECY01O-158).
4. CHECKLIST
Each item of thc following checklist shall he initialed by the licensed stipervisnir whose signature appears below.
___________________ ___ __________________ Yes No NA*
1. Has all liquid been removed from product lities?
2. Has all product piping been capped or removed?
3. Have all non-product lines been capped or removed?
4. Have all liquid and accumulated sludges been removed from the tank?
S. Has the tank been properly purged or inefted?
6. Have the drop tube, fill pipe, gauge pipe, pumps and other tank fixures been removed?
7. Have all tank openings been plugged or capped? NOTE: One plug should have 1/8 inch vent hole.
8. Have all sludges removed from the tank been designated and disposed of in accordance with the stale
of Washington's dangerous waste regulations (Chapter 173-303 WAC)?____ ___
9. If removed, was tank properly labeled and disposed of in accordance with all applicable local, state
and federal regulations? LABELED AND AWAITING FINAL DISPOSAL ________
Iftemn not applicable
I hereby certify that I hravne been I/ne licensed sitpen'isor preset opt site dttring tire arbove listen pernianent closure activities and to
tihe best of rmy knowledge threy have beenl conldrilcen in colliplhurnCC Ivitirtill applicable stale rrndfcderal lirs, regulations and
procedures pertaining to rtndergrortinnl trrage tanik.
Personrs surinitting false inrformratin tire srtbject i peptalriesurnder Cjter 173.360 111/1 C.
5. ADDITIONAL REQUIRED SIGNATURES
ECYOIe-,ea 111 B-21 Ipage 2

WfIC-SD-EN-TI-136, Rev. 0
B-22
91559420
ATTACHMENT 2
2 Pages
(2 copies)

t C 0L 14
WHC-S-EN-TI-136, Rev. 0
UNDERGROUND STORAGE TANK
Permanent Closure/Change-In-Service Checklist
The purpose of this form is to certify thc proper closure/change-in-servicC of unrderground storage tank (UST) systems.
These activities must bc condticted in accordane with Chapter 173.300) WAC. Washington State UIST rules require the
tank owner or operator to notify Ecology in writing 30) days prior to closure or change-in-servie of tanks. This must he
donc by completing the 30 Day Notice formt (ECY 010- 155).
This Permnanent Closure Checklist shall be completed and signed by a Liceeised D~ecommnissioning Supervisor. Thc supervisor
shall be on site when all tank p~ermanen~t ctosure/change-in-servicc activities are being conducted. The firm which
cemploys the licensed supervisor shall also be licensed by the \Vashtnglon Slate Department of Ecology as a Service Provider.
If any of the activitics listed below have been supervised by a different licensed supervisor, a separate checklist
must be filled out and signed by the licensed supervisor p~erformuing those activities.
For further information about completing this form, pleatse contact the Department oif Ecology LIST Program.
A separate checklist must be comnpleted for each LIST system (tank and associated piping), except that UST systems at
one site may bc reported together by completing page 2 of* this foi in separately for cacth system. The completed checklist
should be mailed to the following address within 30) days of the completion of the closure or chiange-in-service.
Undeground Storage Tank Section
Department of Ecology
Mail Slop PV- I I
Olympia, WA 98504 -871 1
1. UST SYSTEM OWNER AND LOCATION
Site Owner/Operator: U.S. Department of Energy Field Office, Richland
Owners Address: 825 Jadwin 550
Sheet
P'C Sax
Richland WA 99352
-C Sim*. ZICode
Telephone. 509 )376-7387
Shte 10 Number (on invoice of available from Ecology if tank is registered): 012763
Site/Business Name: U.S. Department of Energy Field Office, Richland
Site Address: 825 Jadwin, P.O. Box 550 Benton
Subet
cow*f
Richland WA 99352
dyq slaV ZIP Co
2. TANK PERMANENT CLOSURE/CHANGE-IN.SERVICE PERFORMED BY:
Firm: Westinghouse Hanford Company LicenseNumber: S001592
Address:
R...icland WA 99352
cioy Shate ZIP co".
Telephone: (509 ) 376-7411
D. A. Riley Decommissioning t14000778
Licensed Supervisor: _________ ______________ License Number: __________
B-23
EcYoo, 0t& 12 (12 page
1970

3. TANK INFORMATION WHC-S-ENT-136, Rev. 0
1. Tank 10 Nucnbef (as registeted wun Ecology): 10OWN-SS-28 2. Yeal' installed: 1 976
3. Tank capacity in gallons; 2000 4. Last su0Stance sloted: UMIL EAflED r;ot pit
4.'REASONi FORCONDUCfTING SITE CHECK/SIE ASSESSMENT -. . .;' *t.-'-,
Cnaeck one:
____investigate
investigate Suspected feleasea due t0 on-site envitonmfental coniaThnadof
suspected lease due to cd-site envitonmental contamrinlationl
Extend iempotary ctosuie of UST system to( mote than 12 months
UST system undelgOing cnange-ifl-sevice
UST system pamanenty ciosad-it-ptace
X UST system petmanently Closed withi lank removed
5. CHECKLIST
Requit ed by Ecofogy ot delegated agenc.y to( UST system closed oetoce Decemoaer 22. 1988
Otner (desctibe):
________________________________________
E.ach itatm of thet fullciwirig checiit Shull bz illitiailu by tlic persn registcred with ihi: Depaftment of Ecology whosat
inaict appcafs bclow.
1. H-as Ine site cfecktisite assessmet oeen conducted according to applicaote Frocadutes specilied in the UST ~
sute cneck/site asssaet guidlance issued oy mea Depanmeni or Ecology?V
2. H-"a a telease Iram Ute UST system oten confitmned?
NOTE; Owvaetsiop4awOs fhjust topofl ad cismei~d ieleaSdS 1o Use Oepataiefl ol Ecology ot daiegatl digwncy widtUf 24
3I Asore mreult of the site cnecK/site assessment enclosed with mis checklist?
NOTE. Two copies oi ine sitei claoclc/uitsi asswesiti fdstlis must1 Od smoaitte' to we. Oupeflmnflt Lf Ecology accoting Wo the
espoakfl t~quudifleflt speciaie in ine uS r .t eksitO 6f aSSOSeADIffl guida"CV-
I hereby crtify thuf I laaave bces in repjusible c/u argr uf perforin ic site Jick/sita iisxssmnt described above.
Persons subosaitingJ'alX' ittlaioniauar ~e surbjct io pcuaalii tinder Chapter 173360 1 VAC
O~~.
6. OWNER'S SIGNATURE
siqjika. Cod uenw PA..na" -0 1140"y
/' 54aade.. as I ew A.WA. b~sm
B-24
Yes No

WHC-SD-EN-TI-136, Rev. 0
B- 25
9155942D
ATTACHMENT 3
1 Page

Mr. Mike C. Osweiler
Nuclear and Mixed Waste,
Hanford Project
State of Washington
Department of Ecology
7601 W. Clearwater, Suite 102
Kennewick, Washington 99336
Dear Mr. Osweiler:
WHC-SD-EN-TI-136, Rev. 0
Department of Energy
Richilanid Operatjions Office
P.O. Box 550
R ichlanid, Washiligton 99352
UNDERGROUND STORAGE TANK IOON-SS-28 CLOSURE
Enclosed are the completed Permanent Closure/Change-In-Service Checklist and
the Site Check/Site Assessment Checklist (two copies) for underground storage
tank 100N-SS-28, which was permanently closed (removed) on July 17, 1991.
These checklists are submitted in accordance with the requirements of
WAC 173-360-630 (12).
The tank which was previously emptied and rinsed has been transported to the
100-B Area where it is awaiting final disposal (salvage). The remaining
system piping (two lines approximately ten feet long) and pumps are being
scheduled for removal. As far as can be determined, no product remains in
these lines.
If you have any questions or require additional information, please call
Mr. Eric Goller at (509) 376-7326.
Enclosures 2
cc: w/o endls.:
P. T. Day, EPA
R. E. Lerch, WHC
T. Lufkin, Ecology
B-26
Sincerely,
E. A. Bracken, Director
Environmental Restoration Division

WHC-SD-EN-TI-136, Rev. 0
CORRESPONDENCE DISTRIBUTION COVERSHEET
Author Addressee Correspondence No.
E. A. Bracken Mike C. Osweiler Incoming 9102476
U.S. Dept. of Energy Ecology XRF: 91541450
subject: PERMANENT CLOSURE OF UNDERGROUND STORAGE TANK 100N-SS-28
INTERNAL DISTRIBUTION
Approval Date Nam Location w/att
Correspondence Control A3-01 X
M. R. Adams H-4-55
R. J. Bliss B3-04
L. C. Brown H4-51
G. D. Carpenter 82-16
M. L. Douglas R2-77
R. A. Evanoff G4-10
K. A. Gano, XO-21
C. J. Geier H4-57
R. P. Henckel H4-55
K. L. Hoewing B3-06
M. C. Hughes (2) L4-88 X
G. S. Hunacek XO-42
R. E. Lerch (assignee) B2-35
M. A. Mihalic L4-88 X
RECEIVED A. 0. Poor G4-11
R. L. Shuck S4-67
JUN 2 0 E. H. Smith B2-19
0. J. Watson XO-41
D. J. WATSON R. D. Wojtasek L4-92
EDMC H4-51 x
B- 27

U '. Richland
WHC-SD-EN-TI-136, Rev. 0
Department of Eblergy-
Operations Office
0Richland, Washington 99352 Incoming: 9102476
91-ERB-116
Mr. Mike C. Osweiler
Nuclear and Mixed Waste,
Hanford Project
State of Washington
Department of Ecology
7601 W. Cleatrwater, Suite 102
Kennewick, Washington 99336
Dear Mr. Osweiler:
.i U . 1991
PERMANENT CLOSURE OF UNDERGROUND STORAGE TANK (UST) 100N-SS--28
The purpose of this letter, as required by WAC 173-360-385, is to provide the
Washington State Department of Ecology (Ecology) with at least 30 days advance
notification prior to beginning permanent closure (removal) of UST 100N-SS-28.
This tank is located at the lOON Area of the Hanford Site, has a capacity of
2,000 gallons, and is constructed of 3/16" wall carbon steel with an asphalt
coating. Originally, the 100N-SS-28 tank contained diesel fuel. Unleaded
fuel was transferred from the UST IOON-SS-27 into UST IOON-SS-28 following
closure of the 100N-SS-27 UST in June of 1990. The 100N-SS-28 tank was
tightness tested in October of 1990 and found to be tight per 40 CFR 280/281.
This tank is no longer needed and is being removed to facilitate the site
assessment of the 10ON fuel station site. These two tanks were both part of a
self-service gas station and were located approximately nine feet apart. Tank
100N-SS-27 was removed in December 1990 after it had failed tightness testing
and the decision made, because of its age, to close the tank rather than
upgrade it to new tank standards. Contaminated soil was discovered at the
site after the tank was removed. (See Enclosure 1, Twenty-Day Report; and
Enclosure 2, Forty-Five Day Report.)
Since this site has already been confirmed as a release site and the required
24-hour notification given after the removal of the 100N-SS-27 UST, an
additional 24-hour notification pursuant to WAC 173-360-372 will not be given
unless there is other evidence of a release emanating from tank JOON-SS-28.
However, all other reporting requirements as given in WAC 173-340-450 will be
met. A plan for the remediation of the site will be prepared following the
IOON-SS-28 removal and site characterization activities, which are expected to
be completed by August 15, 1991. Also, additional site characterization is
being conducted to determine the extent of the contamination. Ecology will be
provided with a draft of the remediation plan for review prior to initiating
remedial activities.
B-28

WHC-SD-EN-TI-136, Rev. 0
JUN 319
M,,. Mike C. Osweiler -2- 91-ERB-116
If you have any questions or require additional information regarding this
letter, please call Mr. Paul Pak of my staff on 376-4798.
Sincerely,
E. A. Bracken, Director
ERD:PMP Environmental Restoration Division
Enclosures: As stated
cc w/encls:
P. T. Day, EPA
R. E. Lerch, WHC
M. C. Hughes, WHC
T. F. Veneziano, WHC
T. L. Nord, Ecology
D. Nylander, Ecology
R. F. Stanley, Ecology
B-29

WHC-SD-EN-TI-136, Rev. 0
B-30

WHC-SD-EN-TI-136, Rev. 0
APPENDIX C
UNUSUAL OCCURRENCE REPORTS
C-i

WHC-SD-EN-TI-136, Rev. 0
C-il

WHC-SD-EN-TI-136, Rev. 0
CONTENITS
Gasoline Spill to Ground (WHC-UO-88-004-R,D&EO-1) .. .. . .. .. . .. C-1
Leaking Underground Storage Tank (RL--WHC-WHC600EM-1990-033) . .. ..... C-5
Characterization of Spill Site (RL--WHC-NREACTOR-1991-1030) .. .. . ... C-11
Leaking UST (D&IJ/iOO-Oi-90). .. .. . .. ... . .. .. . .. ......C-i7
C-iii

WHC-SD-EN-TI-136, Rev. 0
C-iv

P.O. Box 1970 Rfichland. WA 99352
WHC-SD-EN-TI-136, Rev. 0
March 11, 1988 8851734
Mr. J. L. Rhoades, Assistant Manager
Safety, Safeguards and Quality Assurance
U. S. Department of Energy
Richland Operations Office
Richland, Washington 99352
Dear Mr. Rhoades:
UNUSUAL OCCURRENCE WHC-OO-88-004-R,D&EO-l, GASOLINE SPILL TO GROUND, 89
GALLONS
Reference: Letter, M. W. Waicher to 3. L. Rhoades, "Unusual Occurrence
WHC-OO-88-004-R,D&EO-1, GASOLINE SPILL TO GROUND, 89 GALLONS',
8850715, February 1, 1988
The attached final Unusual Occurrence Report for the subject gas'oline spill
is provided for your information. It has undergone a controlled nuclear
information review and has been determined to be unclassified and
satisfactory for public release.
Very truly yours, -
M. W. Walcher, Manager
Operations Support Services
PC k
At tachment
DOE-RL -A. W. Kellogg, AMO Operations Office
*6 MGMHangid opetabofis ama Engnewtng canitaum w rInc US Depanmnal Energy

WHC-SD-EN-TI-136, Rev. 0
Westinghouse Hanford Company Report Number: WHC-UO-88-004-R,D&EO-1
Date of Event/Occurrence: January 18, 1988
Status and Date:_____ Initial 1/28/88 Time of Event/Occurrence: 2:10 p.m.
1. Department or Project
Operations Support Services
2. Facility, System, and/Equipment
100-N Fuel Station, 1716 NA Building
Vehicle: 68C 4365
Nozzle: OPW11A 15/16 and OPW11-AKH 13/16
3. Subject of Event/Occurrence
Gasoline Spill to Ground, 89 gallons
4. Apparent Cause: Design _Material X Personnel P ProcedureOther___
Personnel: Inattention to fueling activities and failure to report the
second spill. -
Material: Failure of the fueling nozzle automatic shut off function.
5. Description of Event/Occurrence:
Employee was dispensing fuel from tank truck, 68C 4365, (equipped with three
separate storage tanks and dispensing systems) into underground fuel tanks at the
100-N fueling station. He placed the fuel dispensing nozzle into the 4" fill
spout of the service station tank, set the automatic shut-off and returned to his
truck to complete related paperwork while waiting for the tank to fill. The
nozzle did not shut off and the tank overflowed. The employee did not observe
the spillage until a passerby walked up to the truck to inform him of the
overflowing condition. The fuel truck driver immediately turned the nozzle off
manually. The passerby noted the fuel truck driver was in the truck attending
paperwork and .wearing radio headphones which may have'contributed to his
inattention to fueling activities. The spill was reported to N-Reactor
Operations Management and the Supervisor, Special Delivery Services. Initial
assessment of the spill area was done by N-Reactor Operations Management
personnel. Environmental Assurance was advised.
The employee then proceeded to manually fill the second underground tank with the
remaining fuel in the first tank of the truck. When that truck tank was drained,
he stored the hose and nozzle and proceeded to continue filling the second
service station tank from the second truck tank with a different nozzle. He set
the new nozzle on automatic and stepped back to remain clear of the fumes.
C-2

WHC-SD-EN-TI-136, Rev. 0
This nozzle also failed to shut off causing an overflow of the second tank. The
employee alertly stopped the flow of fuel as quickly as possible. The employee
did not report the second spill thinking it was an insignificant amount based on
earlier conversations with N-Reactor Operations Management personnel at the
first spill.
6. Operating Conditions of Facility at Time of Event/Occurrence:
The service station was available for refueling. Three utility carts were parked
adjacent to the station in the area where the fuel truck normally parks. This
made it necessary to position the fuel truck 40 td 50 feet further away from the
service station tanks than usual.
7. Iuumediate Evaluation:
The spill area was roped off. The immediate assessment at the time of the first
spill was that the amount was not significant enough to require reporting as an
Unusual Occurrence. The Environmental Protection Representative, later in the
day, calculated the spill area and determine that the amount of fuel spilled
exceeded the unusual occurrence reporting requirements of 220 pounds (35
gallons). Subsequent review of fueling and inventory records determined that a
total of 89 gallons was spilled.
8. Immediate Action Taken and Results:
Action Taken:
o Required report was made to DOE-RL..,.
o Clean up and stabilization of the spill area was completed on January 20,
1988. The contaminated soil was loaded in 55 gallon drums for storage at
the 1100 Area 90 day Storage Facility pending disposal.
o Disciplinary action was taken against the employee for carelessness in
performance of his work and failure to report in accordance with established
procedures.
o All employees in the Road, Delivery and Equipment Operation Section have
been instructed that the use of personal radios with headphones is
inappropriate in the work place and shall not be permitted.
o The defective nozzles were replaced on January 20, 1988, and tested
to determine the cause of failure. Evaluation of the cause of the nozzle
failures was completed by February 12, 1988. The results of the evaluation
were inconclusive lending even more credence to the need for personnel
attentiveness.
C-3

15. Signatures
WHC-SD-EN-TI-136, Rev. 0
Originator _________________ _____Da t /Ce
3. F. N6ods, Manager-Road, Delivery and Equipment Op rations
-Approved by 4

WHC-SD-EN-TI-136, Rev. 0
RL--WHC-WHC600EM-1990-0337 10 Day Update
UNOFFICIAL COPY (Incomplete
OCCURRENCE REPORT
600 Area/Env. Restoration-Waste Mgmt
HANFORD SITE
(Name of Facility)
(Facility Function Involved)
(Name of Laboratory, Site or Organization)
Name: Evanoff, Richard
Title: Fleet Maintenance Manager
Telephone No.: (509)376-6680 (FTS)444-6680
(Facility Manager/Designee)
Name: Mihalic, M.
Title: Hanford Surplus Facility Program
Telephone No.: (509)376-0967 (FTS)444-0967
(Originator)
1. OCCURRENCE REPORT NUMBER: RL--WIIC-WHC600EM-1990-0337
2. REPORT TYPE AND DATE: Date Time
[INotification Report 12/19/90
[]10 Day Report 01/07/91
[X] 10 Day Update (latest)
[ ] Final Report
3. OCCURRENCE CATEGORY
[ ] Emergency
[X] Unusual
[IOff-Normal
4. DIVISION OR PROJECT
5. DOE PROGRAM OFFICE
EM - Environmental Restoration
1992/02/27 C-5 page

WHC-SD-EN-TI-136, Rev. 0
RL--WHC-WHC600EM-1990-0337 10 Day Update
UNOFFICIAL COPY (Incomplete
OCCURRENCE REPORT
6. SYSTEM, BLDG., OR EQUIPMENT 7. UCNI? 8. PLANT AREA
Gas Station Tank No 100 N
9. DATE AND TIME DISCOVERED 10. DATE AND TIME CATEGORIZED
12/18/90 1300 12/18/90 1400
11. DOE NOTIFICATION:
12/18/90 1500
12. OTHER NOTIFICATIONS
12/18/90 Ganeo, Ken
13. SUBJECT OR TITLE OF OCCURRENCE
Leaking Underground Storage Tank
14. NATURE OF OCCURRENCE
15. DESCRIPTION OF OCCURRENCE
During routine Underground Storage Tank (UST) removal as
described in WHC-SP-0472, Implementation Plan for Title 40
CFR Regulations, Part 280 and 281, tank 100N-SS-27, located
at LOON area was found to have contaminated soil adjacent to
the tank. This UST had been utilized to store unleaded
gasoline. Visual inspection of the tank did not indicate
the tank integrity had been breached. Contaminated soil was
found on the lower one third of the tank on the opposite end
of the fill connection. It appears that an unknown quantity
of unleaded gasoline had been spilled over the years,
possibly from the adjacent tank, whose fill connection is
within five feet of where the contamination was found.
16. OPERATING CONDITIONS OF FACILITY AT TIME OF OCCURRENCE
Tank 10ON-SS-27 had been taken out of service after routine
tightness testing determined the tank had a leak.
1992/02/27 C6page 2

WHC-SD-EN-TI-136, Rev. 0
RL--WHC-WHC600EM- 1990-0337 10 Day Update
UNOFFICIAL COPY (Incomplete)
OCCURRENCE REPORT
17. ACTIVITY CATEGORY
18. IMMEDIATE ACTIONS TAKEN AND RESULTS
Sampling was completed, then additional sampling was
conducted to determine how deep the contamination
penetrated, this sampling revealed that the contamination
had not penetrated below four inches from the bottom of the
tank. Hanford Surplus Facility Program Office (Mike
Mihalic) was notified of the leak at 1400 hours December 18,
1990. The Programs Office notified Environmental
Protection. As this project is being performed under
approved decommissioning work procedures, and it had been
anticipated that the soil contamination could/would be
found, this Occurrence Report is submitted for notification
purposes. A complete detailed report will be prepared and
submitted upon completion of the sample analysis. By copy
of the unusual occurrence report, Environmental Engineering
is requested to perform the necussary evaluation,
notification, and remedial action as required by 40 CFR
280/281.
19. DIRECT CAUSE
20. CONTRIBUTING CAUSE(S)
21. ROOT CAUSE:
22. DESCRIPTION OF CAUSE
From reconstructing the most likely cause of the
contaminated soil found during the removal of tank IOON-27,
it was observed that the tank condition did not indicate the
tank to be a leaker. There has been one reportable spill at
this location in 1988. It is assumed there have been other
unreported spills at this tank fill location. The gravel
and porous backfill surrounding the tanks creates a natural
pathway for surface spills, to the location where the
contaminated soil was found.
1992/02/27 page 3
C-7

WHC-SD-EN-TI-136, Rev. 0
RL--WHC-WHC600EM-1990-0337 10 Day Update
UNOFFICIAL COPY (Incomplete )
OCCURRENCE REPORT
23. EVALUATI'ON : (By Facility Manager/Designee)
Current plan is to remove the layer of contaminated soil
from the tank impression, sample for organic vapors and
backfill once the excavation is clean.
24. IS FURTHER EVALUATION REQUIRED? :Yes [I No [X]
IF YES - BEFORE FURTHER OPERATION? Yes [] No [X]
BY WHOM?:
BY WHEN? :----
25. CORRECTIVE ACTIONS
(* Date added/revised since final report was signed off)
1) On 1991/01/04, the contaminated soil was removed from the
tank impression and the site cleared. Resampling of the
site is being scheduled prior to backfilling.
TARGET COMPLETION DATE: --- /-COMPLETION DATE: -/--
26. IMPACT ON ENVIRONMENT, SAFETY AND HEALTH:
No worker was exposed to gasoline vapors during the
excavation of the tank. The total quantity of the spills is
unknown except for the reported spill January 18, 1988.
Impact to the environment was minimal. Approximately 3
cubic yards of soil was contaminated.
Impact Oversight Group: Environmental Assurance
27. PROGRAMMATIC IMPACT
None at this time.
28. IMPACT UPON CODES AND STANDARDS
The excavation of the tank was in accordance with the
requirements of 40 CFR 280.71. No changes are required to
existing procedures.
1992/02/27 C-8 page 4

WHC-SD-EN-TI-136, Rev. 0
RL--WHC-WHC600EM-1990-0337 10 Day Update
UNOFFICIAL COPY (Incomplete)
OCCURRENCE REPORT
29. FINAL EVALUATION AND LESSONS LEARNED:
The purpose of removing underground storage tanks having
contained petroleum products in accordance with 40 CFR
280.11 is to remove inactive and/or leaking tanks from
service and from the ground. The regulations also require
the clean up of spills associated with the tanks. This is
the fourth of twenty-seven tanks removed to date where soil
contamination has been found.
30. SIMILAR OCCURRENCE REPORT NUMBERS
Fact sheet DD/3000-5-OO1-89
DD/703-1-01-89
00/100-01-89
31. DOE FACILITY REPRESENTATIVE INPUT
Entered by: Date: -/--
1992/02/27 C9page 5

Leaking underground storage tank.
25. CORRECTIVE ACTIONS:
WHC-SD-EN-TI-136, Rev. 0
OCCURRENCE REPORT NUMBER
RL-WHC-WHC600EM- 1990-337
This update describes the site investigation and remediation at the 1OON
Services Station. At this service station, two underground storage tanks were
removed: IOON-SS-27 was removed in December 1990 and 100N-SS-28 was removed
in July 1991.
Tank 100N-SS-27
The excavation and removal of tank IOON-SS-27 was completed on December 18,
1990. Approximately 25 feet of associated piping was removed from the ground
along with the tank. An inspection of the tank did not reveal any holes or
cracks. Field sampling conducted following the removal of the tank indicated
the presence of volatile organics between it and the adjacent tank, 100N-SS-
28. On January 11, 1991 additional soil was removed from between the tanks and
found to be contaminated.
Tank 100N-SS-28
To further characterize and facilitate closure of the IOON-SS-27 site, tank
100N-SS-28 was removed in July 1991. At the time of removal of 100N-SS-28,
saturated soil was observed in the tank depression. There had been no
petroleum in the IOON-SS-28 tank as of December 1990 for safety reasons due to
the removal of 100N-SS-27. The saturated soil was approximately 12 feet below
land surface. The soil was removed and placed in four 55 gallon hazardous
waste drums and disposed as a hazardous waste. In July and August 1991
groundwater samples were collected and tested for volatile organics. The
analytical results indicated that no hydrocarbon contamination is present in
the groundwater.
In September 1991, the UST site was excavated from 14 feet to 27 feet below
land surface. At that depth, contaminated soil was found. This soil was
removed and placed on plastic sheeting , bermed, and barricaded.
In order to determine the extent of petroleum contamination, it is planed to
drill two wells since the site may not be able to be clean closed. These
wells are to be placed at the plum location and down gradient of the service
station. This additional work is planed during May-August time frame 1992.
c-10

RL--Wbh:-NREACTOR-1991-1o30 WHC-SD-EN-TI-136, Rev. 0 Final Report
UNOFFICIAL COPY (Incomplete)
OCCURRENCE REPORT
N-Reactor and 10OK Fuel Storages
Category "A" Reactors
HANFORD SITE
(Name of Facility)
(Facility Function Involved)
(Name of Laboratory, Site or Organization)
Name: Davis, Kenneth W.
Title: Senior Plant Engineer
Telephone No.: (509)373-3143 (FTS)440-3143
(Facility Manager/Designee)
Name: G. S. Hunacek Jr.
Title: Environmental Engineer
Telephone No.: (509)373-1673 (FTS)440-1673
(Originator)
1. OCCURRENCE REPORT NUMBER: RL--WHC-NREACTOR-1991-1030
2. REPORT TYPE AND DATE: Date Time
[]Notification Report 07/18/91 1106 (MTZ)
[]10 Day Report 07/18/91
(]10 Day Update (latest)
(X] Final Report
3. OCCURRENCE CATEGORY:
[ ] Emergency
[X] Unusual
[ ] Off-Normal
4. DIVISION OR PROJECT:
lOON Operations
5. DOE PROGRAM OFFICE
DP - Defense Programs
1993/02/02 page
C-l1

RL--WFC-NREACTOR-1991-1030 WH-DE-I16 e.0 Final Report
UNOFFICIAL COPY (Incomplete)
OCCURRENCE REPORT
6. SYSTEM, BLDG., OR EQUIPMENT 7. UCNI? 8. PLANT AREA
Tank 100N-SS-28 No 10ON
9. DATE AND TIME DISCOVERED 10. DATE AND TIME CATEGORIZED
07/17/91 1200 07/17/91 1230
11. DOE NOTIFICATION:
07/18/91 1530 UNKNOWN DOE/HQ
12. OTHER NOTIFICATIONS
07/17/91 1230 P. M. Pack DOE-RL
07/17/91 1700 L. A. Huffman DOE-RL
07/17/91 1230 M. C. Osweiler WOE
07/18/91 0945 G. D. Trump ONG
13. SUBJECT OR TITLE OF OCCURRENCE
Characterization of spill site
14. NATURE OF OCCURRENCE
2) Environmental
B. Hazardous Substances/Regulated Pollutants/Oil Releases
15. DESCRIPTION OF OCCURRENCE:
It was reported on 12/18/92, under Occurrence Report number:
RL--WHC-WHC60OEM-1990-0337, that one service station tank
(100-SS-27) had leaked. To further characterize that leak,
tank IOON-SS-28 was removed on 7/17/91. At the time of
removal of tank 100N-SS-28, petroleum product was observed
in the excavation area. Tank 100N-SS-28 was tightness
tested 10/90 and passed. There has been no petroleum in
100N-SS-28 since it was emptied in December 1990. The
excavation was approximately 12 feet below grade. Area that
was found to contain product material was ten feet by ten
feet.
1993/02/02 page 2
C-12

RL--WH-C-NREACTOR-1991-103O WHC-SD-EN-TI-136, Rev. 0 Final Report
UNOFFICIAL COPY (Incomplete)
OCCURRENCE REPORT
16. OPERATING CONDITIONS OF FACILITY AT TIME OF OCCURRENCE
N-Reactor is in "Transition to Shutdown". The re-fueling station
has been deactivated and its storage tanks removed.
17. ACTIVITY CATEGORY
Shutdown
18. IMMEDIATE ACTIONS TAKEN AND RESULTS
Sampled the affected soil to determine what petroleum
product was present.
Removed petroleum saturated soil and placed in four 55
gallon hazardous waste drums, and placed said drums on the
163N less than 90-day storage pad.
19. DIRECT CAUSE:
3) Personnel Error
B. Inattention to Detail
20. CONTRIBUTING CAUSE(S)
21. ROOT CAUSE:
6) Management Problem
A. Inadequate Administrative Control
22. DESCRIPTION OF CAUSE:
From reconstructing the most likely cause of the
contaminated soil found during the removal of tank lOON-
SS-27, it was observed that the tank condition did not
indicate it to be a leaker.
There has been one reportable above ground spill at this
location in 1988. It is assumed there have also been other,
unreported, above ground spills at this re-fueling station.
The gravel and porous backfill surrounding the tanks creates
a natural pathway for surface spills, to the location where
the contaminated soil was found.
1993/02/02 page 3
C-13

RL--WHC-NREACTOR- 1991-1030 WHC-SD-EN-TI-136, Rev. 0 Final Report
UNOFFICIAL COPY (Incomplete)
OCCURRENCE REPORT
Therefore, the cause is determined to be the result of
inadequate administrative control of the servicing
activities at this station in the past, resulting in
spillage and consequent soil contamination.
23. EVALUATION :(By Facility Manager/Designee)
See item #29
24. IS FURTHER EVALUATION REQUIRED? Yes (] No [X]
IF YES - BEFORE FURTHER OPERATION? Yes [] No [X]
BY WHOM?:
BY WHEN? :----
25. CORRECTIVE ACTIONS
(* Date added/revised since final report was signed off)
1) Complete site drilling, soil sampling and field analysis of
samples.
ACTIONEE: D.J. Watson (11120)
TARGET COMPLETION DATE: 08/01/92 COMPLETION DATE: 08/15/92
2) Scope remaining site remedial actions.
ACTIONEE: D.J. Watson (11120)
TARGET COMPLETION DATE: 01/31/93 COMPLETION DATE: 01/27/93
3) Complete soil sample laboratory analysis, review analysis,
validate data and schedule any additional corrective actions
that may be determined to be necessary at that time.
ACTIONEE: D.J. Watson (11120)
TARGET COMPLETION DATE: 12/01/92 COMPLETION DATE: 12/01/92
4) Implement remedial action schedule.
ACTIONEE: D.J. Watson (11120)
TARGET COMPLETION DATE: 03/31/93 COMPLETION DATE: -/--
1993/02/02 page 4
C-14

RL--WIIC-NREACTOR-1991-1030 WfC-SD-EN-TI-136, Rev. 0 Final Report
UNOFFICIAL COPY (Incomplete)
OCCURRENCE REPORT
5) Conclude document closure and notify Washington State
Ecology department of closure.
ACTIONEE: D.J. Watson (11120)
TARGET COMPLETION DATE: 12/12/93 COMPLETION DATE: -I--
26. IMPACT ON ENVIRONMENT, SAFETY AND HEALTH
Potential for environmental degradation.
27. PROGRAMMATIC IMPACT
None.
28. IMPACT UPON CODES AND STANDARDS
None.
29. FINAL EVALUATION AND LESSONS LEARNED
The purpose of removing underground storage tanks having
contained petroleum products in accordance with 40 CFR
280.71 is to remove inactive and/or leaking tanks from
service and from the ground. The regulations also require
the clean up of spills associated with the tanks. This is
the fourth of twenty-seven tanks removed to date where soil
contamination has been found.
TANK IOON-SS-27
The excavation and removal of tank 100N-SS-27 was completed
on Dec. 18, 1990. Approximately 25 feet of associated piping
was removed from the ground along with the tank. An
inspection of the tank did not reveal any holes or cracks.
Field sampling conducted following the removal of the tank
indicated the presence of organics between it and the
adjacent tank, 100N-SS-28. On January 11, 1991 additional
soil was removed from between the tanks and found to be
contaminated.
TANK 100N-SS-28
To further characterize and facilitate closure of the lOON-
1993/02/02 page 5
C- 15

RL--WHC-NREACTOR-1991-10Oo WHC-SD-EN-TI-136, Rev. 0 Final Report
UNOFFICIAL COPY (Incomplete)
OCCURRENCE REPORT
SS-27 site, tank 100N-SS-28 was removed in July 1991. At the
time of the removal of IOON-SS-28, saturated soil was
observed in the tank depression. There had been no petroleum
in the 100N-SS-28 tank. The saturated soil was approximately
12 feet below land surface. The soil was removed and placed
in four 55 gallon hazardous waste drums and disposed of as a
hazardous waste. In July and August of 1991 groundwater
samples were collected and tested for volatile organics. The
analytical results indicated that no hydrocarbon
contamination is present in the groundwater.
In September 1991 the UST site was excavated from 14 feet to
27 feet below the land surface. At that depth, contaminated
soil was found. This soil was removed and placed in plastic
sheeting, bermed, and barricaded.
In order to determine the extent of the petroleum
contamination, it is planned to drill two wells, since the
site may not be able to be clean closed. These wells are to
be placed at the plume location and down gradient of the
service station. This additional work is planned to be
completed by mid-December 1993.
The corrective actions associated with this incident are
also being tracked on occurrence report RL--WHC-WHC600EM-
1990-0337.
30. SIMILAR OCCURRENCE REPORT NUMBERS:
RL--WHC-WHC600EM-19go-0337
31. DOE FACILITY REPRESENTATIVE INPUT:
This report has been reviewed and revised several times to
clarify and correct mistakes. It has been reviewed and found
to be acceptable at this time. The reviews have been done by
both Charlie Loftis, DOE-RL site representative as well as by
D.W. Templeton, Chief, Facility Surveillance Branch.
Entered by: Templeton, Dave W. Date: 05/29/92
1993/02/02 page 6
C- 16

WHC-SD-EN-TI-136, Rev. 06 '..
EVENT FACT SHEET AND CRITIOUT.
DISTRIBUTION LIST
WES7INGHOUSE HANFORD COMPANY
JR BELL R3-60
ML BELL TB-50
TD BLANKENSHIP RI-62
RJ BLISS B3-04
NC BOYTER RZ-52
WR BROOKSHER L4-01.
GO CARPENTER H4-15
HF DAUGHERTY R2-53
GT DUKELOW RZ-i7
ML GRY GI EL S6-65
JW HAGAN G6-ZB
KR JORDAN R2-56
JR KN IGHT 84-52
E i KOSIANCIC R2-67
RE LERCH 62-35
DA LUCOFF N2-34
MA PAYNE SS-66
Rj PYZEL-- XDO-42
WG RU FF R2-50
WJ SCHLAUDER G4-02
RG SLOCUM R2-34
EF VOTAW GlI-3 5
WP WHITING 33-30
%'#C WIBORG (2) R3-09
COrjRRES CONTROL RI-03
QSDM NI-13
US DEPARTMENT OF rNERGY
RE GERTON, DIRECTOR, WASTE
MANAGEMENT DIVISION A6-86
RA HOLTEN, DIRECTOR, ENVTRONMENT&
SAFETY DIVISION AB-5
RD IZATT, DIRECTOR, ENVIRONMENTAL
RESTORATION DIVISION Ac:-39
KiH JACKSON, DIRECTOR, SAFEGUARDS&
SECURITY DIVISION A6-33-
JE MECCA, ACT ING DIRECTOR, OPERITONS
DIVISION A6-Z35
LC WILLIAMS, DI.RECTOR, ?RC :ET
MANAGEMENT DIVISION AE-.3
WE MCCLUNG A4-35
AG KRASDPOULOS AS -55
ADDITIONAL DTSR1BUTION
RA E va nof-f1 G4-10
MC Hughes RI-15
MA Mihalic R2.-i5
JU 299
JU 'NRG 2190
MR Morton
KS Pedersen
AD Poor
Shuck
R2-77
S4-67
G4-11.
54-67
"Entire Dist." 3'-1266 DE Stocker G4-11
DR Speer
GE Van Sickle
D3 Watson
VR Weil
R2-77
RI-15
XO-41
G-1-04
IFTEEARE ANY CHANGES OR DELET-IO1NS TO THIS LIST, *PLEA.!SE CALL VICXK
L:ST UPDATED ON 6-3-90.
ZN 3-256.
C-17

CONTRACTOR : WHC
WHC-SD-EN-TI-136, Rev. 0 Page 1 of 2
EV ENT FACT SHEET
1. Title: Leaking UST
2. Reporting Organization: Decomissioning Engineering
3. Division/Department/Project: Environmental/Hanford Restorati on Oper.
4. Number: D&D/100-O1-90 5. Rev.: 0
6. Date of Event/Time: 6/21/90, 2:00pm Date Discovered: 6/21/90
7. Event Identification:
A) Location of Event: 100-N Service Station (Tank 100-N-SS-27)
B) Plant/Faci'lity Status: Station was out-of-service for testing
---- --------- t---------------------------------------t----- ---
1. Alarm: Facility Type 5. Radiological - Personnel
(False Fire, CAM, CAS, etc.) Contamination, Internal
Z. Regulatory Requirement Deposition, Over Exposure, etc.
(CERCLA, RCRA, WDOE, DOE-RL, 6. Industrial Safety, Personnel
DOE-HQ, etc.) Injury, First Aid, etc.
3. Operating Requirements (OSR, 7. Process Misrouting
CPS, Tech Spec., Procedure 8. Utility System - Electrical,
Administrative, etc.) Steam, Air, Water
4. Release/Spread'- Radioactive 9. Hoisting/Lifting
Contamination/Hazardous 10. Other
Material
C) Event Type: 2 (4OCFR28O.43 [C])
OSR/TS: Nonconformance f)Violation f
CPS: Infraction [3 Violation [
8. Apparent Cause(s) of Event:
Design [3Administrative Control []
Personnel Error [3Procedure [
Material t)Other: [X] Tank age
9. Descriiotion of Event:
While preparing for routine UST Tightness Testing, the 100-N-SS-27 tank
was determined to have a leak. The leak is in the top 10% of the t 'ank
volume (probably at the fill pipe to tank connection) as evidenced by
satisfactory inventory control data for this tank (less than 1%
discrepancy on the last 6 to 12 months). The total release of unleaded
gasoline is estimated at less t han 5 gallons occurring between 6/20/90
(tank fill for testing) and 6/21/90 (discovery of leak).
10. Consequences of Event:
Small release of unleaded gasoline (less than 5 gallons)
A-7400-329 (3/90) (EF) WEFOO5
Event Fact Sheet
C- 18

11. Actions Taken (A) or -Planned (B8):
1,. 24 hour WDOE notification (A)
2. Remove tank contents (B - 6/22/90)
3. Followup notification to WDOE (B - 7/12/90)
4. Permanent tank closure (B - 6/21/91)
WHC-SD-EN-TI-136, Rev. 0 Page 2 of 2 -
12. Tentative Disposition:
Event meets criteria for a Unusual Occurrence Report (UOR) ~
Event meets criteria for a Critique
Undetermined: Revised EPS will be issued in 3 working days [
Above criteria not met: no further report[I
1. Si-gnatures:
Originator/-Date
Approved/Date
! -Z- 4.-"z -1
ADV/UCNI Review Oficial Review date
A-7400-329 (3/90) (EF) WEFOOS
Event Fact Sheet
C1

WHC-SD-EN-TI- 36 9 Rev. 0
C -20

WHC-SD-EN-TI-136, Rev. 0
APPENDIX D
VALIDATED SAMPLE DATA
D- i

WHC-SD-EN-TI-136, Rev. 0
D-ii

WIIC-SD-EN-TI-136, Rev. 0
CONTENTS
Table. .. ... ...... . ... . ...... . ... .........D-iv
182 Tanks (Sample Date 11/30/90). .. .... . .. .... .........- 1
182 Caissons (Sample Date 4/5/91). .. .. ....... . ... .....-125
182 Caissons (Sample Date 4/26/92) .. .... . ... . ...... ...- 135
105 LFT (Sample Date 4/30/92) .. .. . .... .... . .. .... ...- 157
100-N-SS-27 (Sample Date 12/18/90) .. .... . .... ...... .. D-185
100-N-SS-28 (Sample Dates 7/16/91 and 7/17/91. .. .. ....... ...- 225
100-N-SS-28 (Sample Date 4/29/92). .. ... ...... . ... . ... D-245
100-N Gas Station "Lust' (Sample Date 9/9/92). .. .. ....... ...- 259
D- iii

WHC-SD-EN-TI-136, Rev. 0
Table D-1. Validated Sample Information Sequence.
LOCATION DATE SAMPLES
Tank 182-N-1-DT 11/30/90 N-101 thru N-108
Tank 182-N-2-DT 11/30/90 N-109 thru N-116
Tank 182-N- 3-DT 11/30/90 N-ill thru N-126, N-127*
Caisson 182-N-1-DT 03/05/91 MK-103
Caisson 182-N-2-DT 03/05/91 MK-102
Caisson 182-N-3-DT 03/05/91 JMK-101, MK-105, MK-1O4*
Caisson 182-N-1-DT 03/26/92 BO1GM3
Caisson 182-N-2-DT 03/26/92 BOIGMi, BO1GM2
Caisson 182-N-3-DT 03/26/92 JB01GMO
Tank 105-N-LFT 320/92 NO1GM8 thru NO1338 (LOT)9
Tank 105-N-LFT 03/30/92.J N-1284 thru N-1338 (LOST) *
Tank 100-N-SS-27 12/18/90 27-101*, 27-102 thru 27-106
Tank 100-N-SS-28 07/16/91 BOOZN6, BOOZN7, BOOZN8*, BOOZN9*
Tank 100-N-SS-28 07/17/91 BOOZPO thru BOOZP4, BOOZP5*,
___________BOOZP6*
Tank 100-N-SS-28 04/29/92 B06D35*, B06D36, B06D37
Tank 100-N-SS-28 09/09/92 B076C4 thru B076C6, B07600,
BOREHOLE ________B076C7*, B076C8*, B076C9*
*Denotes trip/equipment blanks
This table correlates sample numbers associated with each sample activity.
All validated sample information in Appendix C follows the sequence of this
table.
D- iv

WHC-SD-EN-TI-136, Rev. 0
182 TANKS
Sample Date November 30, 1990
D-1

WHC-SD-EN-TI-136, Rev. 0
D-2

WestInghous WHC-SD-EN-TI-136, Rev. 0 Internal
Hanford Cofinfy Memo
From: Office of Sample Management 28600-91-032
Phone: 3-3415 MO-346/200W T6-08
Date: April 8, 1991
Subect: TRANSMITTAL OF VALIDATED DATA FOR THE UNDERGROUND
STORAGE TANK REMOVAL PROJECT (TRANS #1)
TO: R. C. Roos H4-55
cc: R. P. Henckel HI4-55*
J. H. Kessner~y T6-08*
E. J. Kosiancic S0-61*
K. S. Pedersen S4-67*
R. G. Shuck S4-67*
JAL File/LB
*wj/o enclosures
Validated sample data from the Underground Storage Tank Removal
Project is being transmitted by the Office of Sample Management (OSM)
for the Delivery Group N-101. The delivery group contains results for
33 soil samples which were analyzed by the Martin Marietta Energy
Systems, Incorporated, K-25 Laboratory for volatile and semi-volatile
organics.
The Office of Sample Management data validation procedure is a review
of laboratory performance and implementation of applicable protocols.
Subsequent technical data evaluation by project lead personnel should
include a determination of the appropriateness of results from a
standpoint of past history and present knowledge of the sample site.
If you have any questions, please contact me at the number listed
above.
q~.Lerch
Scientist
ti n
Enclosure
D-3
Hanford Operations and Engineering Contractor for the US Depertrrent of Energy

WHC-SD-EN-TI-136, Rev. 0
Table 2. Sample Identification in Project 90-027
OSM Sample ID Lab Sample ID Lab File ID Matrix Comments
N-10l 901206-019 NA Soil Sample
901213-028 Water ENA Blank
901211-004 Water VOA Blank
N-102 901206-020 NA soil Sample
901210-025 Water VOA Blank
N-103 901206-021 NAk soil Sample
N-104 901206-022 NA soil Sample
N-l05 901206-023 NA Soil Sample
N-106 901206-024 NA Soil Sample
N-107 901206-025 NA soil Sample
N-107-MS 901206-026 NA Soil Matrix Spike
N-107-MSD 901206-027 NA Soil Matrix Spike
Duplicate
N-108 901206-028 NA soil Sample
N-109 901206-029 NA soil Sample
N-110 901206-030 NA Soil Sample
N-ill 901206-031 NA Soil Sample
N-112 901206-032 NA soil Sample
N-113 901206-033 NA soil Sample
N-114 901206-034 NA soil Sample
N-115 901206-035 NA soil Sample
N-116 901206-036 NA Soil Sample
901214-083 Water BNA Blank
N-117 901206-037 NA soil Sample
N-118 901206-038 NA soil Sample
N-118-MS 901206-039 NA soil Matrix Spike
N-118-MSD 901206-040 NA soil matrix Spike
Duplicate
N-119 901206-041 NA soil Sample
N-120 901206-042 NA Soil Sample
N-121 901206-043 NA soil Sample
N-122 901206-044 NA soil Sample
N-123 901206-045 NA soil Sample
N-124 901206-046 NA soil Sample
N-125 901206-047 NA soil Sample
N-125D 901206-048 NA soil Duplicate Sample
N-126 901206-049 NA soil Sample
N-127 901206-050 NA soil Sample
242-101 901209-018 NA soil Sample
901218-067 P17 t NA Blank
242-102 901209-019 NA -*i 1 Sampl-
242-102-MS 901209-020 NA soil Sample
242-103 901209-021 NA soil Sample
242-104 901209-022 NA soil Sample
242-105 901209-023 NA Soil Sample
242-105-D 901209-024 NA Soil Sample
242-106 901209-025 NA soil Sample
D-4

:,l ~ouse WHC-SD-EN-TI-136, Rev. 0
Hanford Company
OSM RCRA LEVEL C DATA ASSESSMENT
DATE 1+ /4-Y H SAMPLES/MATRIX seL- _____o~w1
REV IEWED BY Lo~~..c-. ro
-.1I
L A B O R A T O R Y --
CASE # -____
SOG # g-I (ssy. bvCZM)
DATA ASSESSMENT SUMMARY
QUALITY CONTROL CHECK ANALYS IS VOA -________VO
2. M:1A5 .r D
3. 4 ~~~
0Xpc~
4. .3Aerpc5) #e- Ra=y ra X_
6. A^i~.. Vs ;- ')e,__ ___
7.__ _ __ _ _
8. _ _ _ _ _ _ _ _ _ _ _ _
9. __ _ _ _ _ _ _ _ _ _ __ _ _
10. __ _ _ _ _ _ _ _ _ _ ___ _ __ _ _
C
s ot_
_ _ _ _ _
0 = data had no problems
X - data qualified due to minor problems
M = data qualified due to major problems/some data may be unusable
OVERALL ASSESSSMENT: r%0 m. 6 r - ?re)b to wc - a- I rar LA -r
NOTES: A0ok1,-
o Refer to the corresponding attachments for explanation of any problems.
D-5

W -104 NZ
J-107 N-IZ~o
iH-)2-'7
11lL+ 244Z-105-
WHC-SD-EN-TI-136, Rev. 0
D-6

WHC-SD-EN-TI-136, Rev. 0
RCRA LEVEL C OC
Name 07 Lo-. Date 04_10_C_0_6_
COMMENTS: Vo.4 - oiWolIcdie ; 4; pt.e cr' 4 c*-ic '-'e
ACTION: O'o PIQ-
/0 ~ JA-rc~+('r cr 4 4 er - i-s 7,co l)
waoe,c r-i**.--rcig k4-0 ctpoo:Lrc
sampole # constituent val ue/gual sample constituent val-ue/oual
IOf G~
D-7

WHC-SD-EN-TI-136, Rev. 0
RCRA LEVEL C OC
Name Z',JTA ccVr Date o_____o_(o
QC Check: ________ _______ _______
COMMENTS: -Sea-. L4rl).)fi r- (a- Sc. w.
%IA- o.II rexcoyer'es -a- R1ts L4li-% 1fr*dAs
IRPD w--x4s~ar of' hwA4.ri Y1 i~.4 oi d;r-cr F cr -A~.
samgle # constituent value/gual samole # constituent val ue/gual
VOA sp; kp-s
S- 107 ^AS W ~- 0 MS D
5e.. VO A spt-
N -10? MS, ,jj-f0O7AASDL
t4-11,# ,45 J1A&S
0 of (40
D-8

WHC-SD-EN-TI-136, Rev. 0
RCRA LEVEL C OC
Name U-A &&..ctb. " Date ____JOG ____1
QC Check: Vpu.%k I/i
COMMENTS: 1L~; c-te- .. 4i-rpi#~ir~)~ ,rfc M~-S'
ACTION: Yo-L.
sample # constituent value/gual sample # constituent value/gual
D-9

WHC-SD-EN-TI-136, Rev. 0
RCRA LEVEL-C OC
Name ZTJ- LaQrcC-Z D a t e4 b/o b
QC Check: S rco,, CA e_ kLcoLvery
COMMENTS: S-e -2VOA- 2s LA rr o oA-ez o.a Lx 4 4ri I
f-,,- N-12G I oiA-, 4(at i J-121,; c41 c
Yt~-c4lrecveies e fo-c
ACTION: o4 C r- es LA 14-res ~ e-c
samnle # constituent value/aual sample # constituent value/gual
D-10

WHC-SD-EN-TI-136, Rev. 0
k~. RCRA LEVEL C OC
Name A3* Lo-cL Date o Li/eco /Ii
QC Check: ______________
COMMENTS: V A - Yr'wC1 cc-e 4 oiotn. c,, seerod 7C A e4ed
obseJ sev-Lo-r c-r dLI'eehc ;*b#-dL
ACTION: eCe-h.Q- reL1 1 SM
sample # constituent value/gual sample # constituent value/gual
VoA flid--
+VL oA ~ ~-e -Pat-A
OkaVc OA Tickv- Vo
~of~
D11

WHC-SD-EN-TI-136, Rev. 0
RCRA LEVEL-C OC
Name 7EA Lrr .k Date ________C_
QC Check: 0 4 ~J
COMMENTS: t o y-g-~
ACTION: A %Q
sample # constituent value/aual sample # constituent value/gual
6of~
D-12

Ms. Joan Kessner
Westinghouse Hanford Company
office of Sample Management
2355 Stevens Drive
Richland, Washington 99352
Dear MS Kessner:
WHC-SD-EN-TI-136, Rev. 0
January 29, 1991
Analytical Results Package on Projects 90-027, Tank Farm Samples
Attached are the analytical results on sample from Project 90-027, Tank Farm
Samples, received into the Analytical Chemistry Department (ACD) Laboratories
on December 5, 6, 7, and 9, 1990. in accordance with agreements between the OSM
and K-25 ACD, the protocol shown in Table 1 was utilized in performing these
analyses. The sample identification for this project is shown in Table 2.
The results are reported on ACD's ANALIS report format, per letter dated
December 20, 1990. All data quality objectives were satisfied on the project.
Semi-Volatiles (BNAs)
Samples received on the dates listed above were extracted and analyzed within
the prescribed holding times. All surrogate standards criteria were within
percent recovery acceptance limits. All DF TPP tune criteria were within
acceptance criteria. All "CCC" and "SPCC" components met acceptance criteria for
both the initial and continuing calibration check samples. All internal
standard areas met water matrix acceptance criteria. All matrix spikes and
matrix spike duplicates were within the acceptance requirements.
Volatiles (NOWs
All surrogate standards criteria were within percent recovery acceptance
limits. All BFB tune criteria were within acceptance criteria. All CCC and SPCC
components met acceptance criteria for both the initial and continuing
calibration check sample. All internal sta'ndard ~er- w''s w'ithin ~~tn
criteria for a water matrix. All matrix spilies -1 nr mattrix:i'k i'Ii-'.r
within the acceptance requi rement~g.
D-13
G~L SL LN,'

WHC-SD-EN-TI-136, Rev. 0
Analytical Results Package on Projects 90-027, Tank Farm Samples- Continued
I certify that this data package is in compliance with the terms and conditions
of the OSM's revised Statement of work and letter dated December 20, 1990, both
technically and for completeness, for other than conditions detailed above.
Release of the data contained in this hardcopy data package has been authorized
by the Laboratory Manager or his designee, as verified by the following
signature.
Roy W. Morrow
Department Man ger
Analytical Chemistry Department (K-25)
D-14
Sincerely,
/*?/ C
-4 , y
Clarence R. Kirkpatrick
Program Manager
Waste Management Analysis

Analysis
A. Semi-Volatiles
B. Volatiles
WHC-SD-EN-TI-136, Rev. 0
Table 1. Analytical Protocol used for Project 90-027
D-15
Protocol
BNA (CLP) protocol
VOA (CLP) protocol

WIIC-S-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 2
AnaLIS ID: 901206-019 Customer Sample 10: N-101
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite ID: 10646 Saimpte Matrix: SOIL
Instrument ID: 597093 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
BRA -*ase/Neutrat/Acid Compounds (TCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 13-DEC-1990
Preparation Procedure Nuber: Analysis Procedure Nuber: BRA (CLP) MOP
Percent Moisture: 5.7 Dilution Factor: 1.0
Percent moisture (decanted): Analyst: C MEEHAN
Associated Blank: 901213-028 OA File Mumber: NA
El: Result has been Corrected for Spike
CAS uglKg CAS Ug/Kg
108-95-2 Phenol 980tJ 106-47-8 4-Chloroanitine 98OU
111-44-4 bis(2-Chloroethyl)ether 980U 87-68-3 Hexachlorobutadiene, 980U
95-57-8 2-Chtorophenol 980U 59-50-7 4-Chloro-3-methyLpheno. 980U
541-73-1 1,3-Dichtorobenzene 980U 91-57-6 2-MethyinaphthaLene 984.
106-46-7 l.4-Dichlorobenzene 980U 77-4.7-4 HexachlorocycLopentadiene 980U
100-51-6 UenzyL Alcohol 980U 88-06-2 2,I..6-Trichtorophenot 980U
95-50-1 1,2-Dichlorobenzene 98OU 95-95-4 2.4,5-Trichtorophenot 4700u
95-48-7 2-MethylphenoL 980U 91-58-7 2-Chtoronaphthalene 980u
108-60-1 bis(2-ChLoroisopropyt)ether 980U 88-74-4 2-Mitroanitine 4700U
106-44-5 4-MethyLphenot 980U 131-11-3 Dimethytphthalate 980U
621-64-7 M-Mitroso-di-n-propyanine 980U 208-96-8 Acenaphthylene 980U
67-72-1 Hexachtoroethane 980U 99-09-2 3-Mitroaniline 470OU
98-95-3 Nitrobenzene 980U 83-32-9 Acenaphthene 980U
78-59-1 Isophorone 980U 51-28-5 2,4-Dinitrophenol 470OU
88-75-5 2-NitrophenoL 980U 100-02-7 is-Mitrophenot 4700U
105-67-9 2,4-Dimethytphenol 980U 132-64-9 Dibenzofuran 980U
65-85-0 Benz *oic Acid 4700U 121-14-2 2.I.-Dinitrotoluene 980U
111-91-1 bisC2-Chloroethoxy)methane 980U 606-20-2 2,6-DinitrotoLuene 980U
120-83-2 2,4-Dichlorophenol 980U 84-66-2 Diethylphthalate 180 4iQ do (A
120-82-1 1,2,4-TrichLorobenzene 980U 7005-72-3 4-ChLorophenyL-phenylether 980u
91-20-3 Naphthalene 980U 86-73-7 Fluorene 980U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
i - indicates an estimated value.
ND - Not detected./
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D- 16

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLIS ID: 901206-019 Customer Sample ID: N-101
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNERIR. SHUCK
Fite ID: 10646 Samp~le Matrix: SOIL
instrument ID: 597093 Requisition Number:
Authorized By: D. C. Canada Date Samrple Received: 6-DEC-1990
UNA - Base/Neutral/Acid Comrpou~nds (TCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 13-DEC-1990
Preparation Procedure Number: Analysis Procedure Number: SNA (CLP) NDP
Percent Moisture: 5.7 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEEHAN
Associated Blank: 901213-028 CA File Number: NA
El : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
100-01-6 4-Nitroaniline 470OU 53-70-3 Dibenz(ah)anthracene 98OU
534-52-1 4,6-Dinitro-2-methytphenol 4700U 191-24-2 Benzo(ghi)perytene 980U
86-30-6 N-itrosodiphenylamine 9S0U
101-55-3 4-Bromopheny-phenylether 98OU
118-74-1 Nexachlorobenzene 980U
87-86-5 Pentachtorophenot 4700U
85-01-8 Phenanthrene 980U
120-12-7 Anthracene 980Ui
84-74-2 Di -n-butylphthalate 42006 IA
206-44-0 Fluoranthene 980t
129-00-0 Pyrene 98WU
85-68-7 Butylbenzylphthalate 98OU
91-94-1 3,3'-Dichlorobenzidine 1900U
56-55-3 Benzo~a)anthracene 980U
117-81-7 bis(2-Ethythexyl)phthalate *00 9 80 L-.
218-01-9 Chrysene 98OW
117-84-0 DI-ui-octylphthalate 98WU
205-99-2 Benzo(b)fluoranthene 98WU
207-08-9 Benzo~k)fluorenthene 98WU
50-32-8 Benzo(a)pyren. 98WU
193-39-5 Indeno(1,2,3-cd)pyrene 98WU
Data Reporting Qualifiers:
U - Comrpound was analyzed for but not detected. The numb~er is the attainable detection limit for the samrple.
* - Analyte was found in the reagent blank as well as the samrple.
J - indicates an estimated value.
ND - Not detected.
A -Aldol condensation product.
o - Secondary dilution.
E - Exceeds Initial calibration range.
D-17

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
INA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS ID: 901206-019 Custmer Samrple 1D: N-101
Laboratory: Organic MassSpectroscopy Laboratory Customer: J1. KESSNER/R. SNUCK
Sample Matrix: SOIL File ID: 10646
Level: (tow/med): LOW Date Received: 6-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 13-DEC-1990
% Moisture: not dec. 5.7 dec. _____Date Extracted: 12-DEC-1990
Extraction: CSepF/Cont/Sonc) SoxH PH*:
GPC Cleanup: CT/N) N
Concentration units
Number TICs found: 15 (ug/L or ug/Kg): uqK
I CAS NUMBER C01MPOUND NAME I RT EST. CONC. a
I1. 123-42-21 2-Pentenone, 4-hydroxy-4-mothy 5 .9i i aCI"I
2. 872-50-41 2-Pyrrotidinone. 1-methyl- 9 .81! -44 -B
I3. 1 Unknown 1 12.50! goo1
I4- 25013-16-51 Phenot.(1.1-dimethylethyl)-4-m
I5. Unknown
4 6.L 4;
mee1 -----
6. IUnknown
I7._17851-53-51 1.2-genzenedicarboxylic acidb j.3
Wes0 IWag
--oul t
~
I 8. I Unknown (Hydrocarbon) .2~i.6 - -4-4 -- I
I9.
10.
I11.
IUnknown
IUnknown (Hydrocarbon)
IUnknown
I
I
21.96 J420
23.74 J590
24.11 J570
1 1
I 1
1
12.______ Unknown (sat'd Hydrocarbon)
13. Unknown (sat'd Hydrocarbon)
I14. jUnknown (Hydrocarbon)
I15. fUnknown (sat'd Hydrocarbon)
116.
I
I
A .6i-
149t
27.78 I2100
i-O.3
-tmI JB
inn 1 4_1
1~
-9
___ I
17. ___I
is8. ____IL___I
1'9._____III__ _
120.--II __
121. ___________________ 1 __ I
22.II I
123.I I
124.--- I
125. ___________________1II
126. I
127. I I
128.II I
129.--I
130.I I
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B Analyte was foun~d in the reagent blank as well as the sample.
J1 - indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds Initial calibration range.
P - Probable Identification. D- 18

WfIC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 1
AnaLIS ID: 901206-019 Customer Sample 10: N-101
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: 07606 Sample Matrix: SOIL
Instrument 10: 597012 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
VOA -Volatile Organic Compounds CTCI)
Date Extracted/Prepared: Date Analyzed: 11-DEC-1990
Preparation Procedure Number: PURGE & TRAP Analysis Procedure Number: VOkA (CP) MOP
Percent Moisture: 6 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: GL HL3DLESTOM
Associated Slank: 901211-004 CA File Number: MA
0l : Result has been Corrected for Spike
CAS uglKg CAS ug/Kg
74-87-3 Chloromethane 11U 79-00-5 1.1,2-Trichtoroethane 5U
74-83-9 Uromomethane 1Ut 71-43-2 Benzene 5u
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1,3-Dichtoropropene 5U
75-00-3 Chloroethane 11t) 75-25-2 Bromoform 5u
75-09-2 MethyLene Chloride 5U 108-10-1 4-Nethyt-2-pentanone 11U
67-64-1 Acetone 11U 591-78-6 2-Hexanone 11U
75-15-0 Carbon Disuifide 5U 127-18-4 Tetrachtoroethene 5u
75-35-4 1*1-Dfchtoroethene SU 79-34-5 .1.1,2.Z-TetrachLoroethane 5U
75-34-3 1 1 1-Dichtoroethane 5U 108-88-3 Toluene 5U
540-59-0 1,2-Dichioroethene (total) SU 108-90-7 Chlorobenzene 5U
67-66-3 Chloroform .5U 100-41-4 Ethylbenzene 5U
107-06-2 1,2-Oichioroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1,1*1-Trichtoroethane 5U
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate 11U
75-27-4 Bromodichtoromethane 5U
78-87-5 1,2-Dichioropropane 5U
10061-01-5 cis-1,3-Dichloropropene 5U
79-01-6 Trichtoroethene 5U
124-48-1 Dibronwchtoromethane sU
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The nwiber is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J -Indicates an estimated value.
NO - Not detected.
A - Aldot condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D- 19

WHC-SD-EN-TI-136, Rev, 0
ANALYSIS DATA REPORT Page 1 of 2
AnaLIS 10: 901206-020 Customer Sample 10: N-102
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSUER/R. SHUCK
File 10: 10647 .Sample Matrix: SOIL
Instrument 10: 597003 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
BRA - Base/NeutraL/Acid Compounds (TCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 13-DEC-1990
Preparation Procedure Numb~er: Analysis Procedure Number: BNA (CLP) HOP
Percent Moisture: 7.7 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEEHAN
Associated Blank: 901213-028 aA Fite Number: UA
[U : Result has been Corrected f or Spike
CAS ug/Kg CAS ug/Kg
...... ..................... .......... ........... .............................. ..........
108-95-2 Phenol 99OU 106-47-8 4-Chtoroanitine 990U
111-44-4 bis(2-ChLoroethyl)ether 990U 87-68-3 HexachLorobuitadiene 990u
95-57-8 2-ChlorophenoL 99OU 59-50-7 4-ChLoro-3-methyiphenot 990u
541-73-1 1,3-DichLorobenzene 99OU 91-57-6 2-MethylnaphthaLene 990u
106-46-7 1,4-Dichiorobenzene 99OU 77-47-4 HexachLorocyclopentadiene 990U
100-51-6 *enzyl Alcohol 990U 88-06-2 2,4,6-TrichLorophenoL 990U
95-SO-1 1,2-OlchLorobenzene 99OU 95-95-4 2,S,-Trichlarophenot 4800u
95-48-7 2-Methyiphenot 99OU 91-58-7 2-Chtoronaplithatene 990u
108-60-1 bis(2-ChLoroisopropyt)ether 990U 88-74-4 2-IditroaniLine 480OU
106-44-5 4-Nethytphenot 990U 131-11-3 DimethyLpinhatate 990u
621-64-7 N-Nitroso-di-n-propylamine 990U 208-96-8 Acenaplithylene 990U
67-72-1 Hexachtoroethane 990U 99-09-2 3-NitroaniLine 480OU
98-95-3 Nitrobenzene 9901U 83-32-9 Acenaphthene 990U
78-59-1 Isophorone 990U 51-28-S 2,4-Dinitrophenot 480OU
88-75-S 2-Nitrophenot 990U 100-02-7 4-Witrophenol. 480OU
105-67-9 2,4-DimethyLphenol 99OU 132-64-9 Dibenzofuran 990U
65-85-0 *enzoic Acid 11'Q 489-do-. LA 121-1U-2 2,4-Dinitrotoluene 990U
111-91-1 bisC2-Chloroethoxy)methane 990U 606-20-2 2, 6 -Oinitrototuene 990U
120-83-2 2,4-Dichlorophenol 990U 84-66-2 Diethylphthalate 9)90 2~0-. 6 A
120-82-1 1,2,4-Trichtorobenzene 990U 7005-72-3 4 -Chtorophenyt-phenyLether 990U
91-20-3 Naphthalene 99OU 86-73-7 I'Luorene 990U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number Is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J1 - Indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D- 20

WIIC-S-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaL!! ID: 901206-020 Customer Samle ID: N-102
Laboratory: organic Mass Spectroscopy Laboratory Customer: J. KESSWER/R. SHUCK
Fite ID: 1064.7 Sample Matrix: SOIL
Instrument ID: 5970#3 Requisition Number:
Authorized By: D. C. Canada Date Samuple Received: 6-DEC-1990
DNA -*ase/Neut ratl/Acid copounads (TCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 13-DEC-1990
Preparation Procedure Number: Analysis Procedure Number: BNA (CLP) MOP
Percent Moisture: 7.7 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C 1MEEMAN
Associated Blank: 901213-028 QA File Number: NA
[I : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
...... .................. .......... ........... .............................. ..........
100-01-6 4-Nitroaniline 4800Uj 53-70-3 Dibenz(a~h)anthracene 990U
534.-52-1 4,6-Dinitro-2-methylphenol 4800U 191-24-2 Uenzo(g,h,i)perylene 990U
86-30-6 N-Nltrosodiphenylamine 99OU
101-55-3 4-Uromopheny-phenylether 990Ui
118-74-1 HexachLorobenzene 990U
87-86-5 PentachLorophenol 4800ui
85-01-8 Phenanthrene 990Ui
120-12-7 Anthracene 990Ui
84-74-2 Di-n-butylpdhthaLat* 32001k, Lk.
206-44-0 Fluoranthene 990U
129-00-0 Pyrene 9901J
85-68-7 Dutytbenzylphthatate 990U
91-94-1 3,3'-Olchlorobenzidine 2000Ui
56-55-3 Bonzo~a)anthracene 990U
117-81-7 bis(2-Ethythexyl)phthaLate 420 jo- 990 )
218-01 -9 Chrysene 990U
117-84-0 Di-n-octylphthalate 990U
205-99-2 Uenzo(b)f luorantherve 990U
207-08-9 Benzo(k)fluoranthene 990U
50-32-8 Senzo(a)pyrene 990U
193-39-5 indeno(l,2,3-cd)pyrene 990U
Data Reporting Qualifiers:
U - Compounid was analyzed for but not detected. The number is the attainable detection Limit for the samrple.
6 - Analyte was foun~d In the reagent blank as well as the samrple.
J - Indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
o - Secondary dilution.
E - Exceeds initial calibration range.
D-21

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
BRA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED C0MI)WNDS
AnaLIS ID: 901206-020 Customer Sample ID: N-102
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J1. KESSNER/R. SHUCK
Sample Matrix: SOIL Fite ID: 10647
Level: (tow/med): LOWJ Date Received: -6-0EC-1990
Dilution Factor: 1.0 Date Analyzed: 13-0EC-1990
% Moisture: not dec. 7.7 dec. On____Dte Extracted: 12-DEC-1990
Extraction: (SepF/Cont/Sonc) SoxH PH:_____
GPC Cleanup: (YIN) N
Concentration Units
Numb~er TICs found: 14 (ug/L or uglKg): y~_K
CAS NUMBER j COMPOUND NAME RT EST. CONC. Q
1.
I2.
123-42-21 2-Pentenone._4-hydroxy-4-methY
872-50-41 2-Pyrrotidinone._1-methyl-
I 9-"I~
9.03 I 30
3. 25013-16-51 Phenot.(1.1-dimethytethyt)-4-m i14;7 I 54"
4. 1 Unknown I 10.08 ia 1303 d
I5. 17851-53-51_1.2-Benzenedicarboxytic acld.b
6. IUnknown (sat'd Hydrocarbon)
I7. Iunknown
8. IUnknown (sat'd Hydrocarbon)
I
I
j
2.31
--2S.6~1 I
26.001
60- I a
60I .s
4601.
6
I
9. IUnknown J 27.70 I2100 I.
10. IUnknown (Atkyl Hydrocarbon) 26A1 3- 620 IJ
11. IUnknown (Alkyt- Hydrocarbon) P82.91 I "2L J-JB-
12. IUnknown (sat'd Hydrocarbon) I 30.55 I410 1 3
13. IUnknown (sat'd Hydrocarbon) I 32.61 I400 1 .
114. Iunknown I 33.75 4201.
I
15.III
116. __ _ _ _ _ _ _ _ _ _.._ _ _ _1_ _ _ _1_ _ I
17.L__ _ _ _ _ _ _ _ _ _I_ _ _ _I_ _ _ _I_ _ _
118. 1_ _ _ _ _ _ _ _ _ _ _ _ _ _ _
19._ _ _ _ _ _ __ _ 1_ _ _ _1 _ _ _ _ _
120.1__ _ _ _ _ _ _ _ _ _ __ _ _ _I_ _ _ _ I__ _ I
I21. _ _ _ _1_ _ _ _ _ _ _ _ _ _ _ _ _ 1 _ _ _ _ 1 _ _ _ _ _1_ _ _
122. _ _ _ _ _1_ _ _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _ _ _ _ _ _ _I_ _ _
123. _ _ _ _ _1_ _ _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _ _ _ _ _ _ _I_ _ _
124. J_ _ _ _ _ _ _ _ _ _ _ _ _ _ _]_ _ _ _ _ _
125. _ _ _ _ _1_ _ _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _ _ _ _ _ _ _1_ _ _
126. _ _ _ _ _1_ _ _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _ _ _ _ _ _ _I_ _ _
127.1__ _ _ _ _ _ _ _ _ _ 1__ _ _ _1_ _ _ _ 1__ _
128. _ _ _ _ _1_ _ _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _ _ _ _ _ _ _1_ _ _
129.1 __ _ _ _i_ _ _ _ __ _
130. i_ _ _ _ _ _ _ _ _ _ _ _ _ _I_ _ _ _ _ _ _ _ _ _I_ _ _
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the samp~te.
B-Analyte was found in the reagent blank as well as the sample.
J3 - Indicates an estimated value.
NO - Not detected.
A -Aldol condensation product.
D - secondary dilution.
E - Exceeds initial calibration range.
P - Probable Identification.
D- 22

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 1
AnaLIS ID: 901206-020 Customer Sample ID: N-102
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSMER/R. SHUCK
File ID: 07598 Samle Matrix: SOIL
instrument ID: 597012 Re~iisition Nmbe~r:
Authorized By: 0. C. Canada Date Sample Received: 5-OEC-1990
VOA - Volatile, Organic Compounds (TCL)
Date Extracted/Prepared: Date Analyzed: 10-DEC-1990
Preparation Procedure Number: PURGE & TRAP Analysis Procedure Number: VGA (CLP) MOP
Percent Moisture: 8 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: SL STAFFORD
Associated Blank: 901210-025 GA Fite Number: MA
U:Result has been Corrected for Spike
CAS ug/Kq CAS ug/Kg
......................... .......... ........... .............................. ..........
74-87-3 ChLoromethane 1IU 79-00-5 1,1.2-Trichtoroethane 5U
74-113-9 Bromomethane 11U 71-43-2 Benzene 5u
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1.3-Dichloropropene 5U
75-00-3 Chtoroethane 111U 75-25-2 Bromoform 5U
75-09-2 Methytene Chloride 5 -Q--ft LA 108-10-1 4-Methyt-2-pentenone llu
67-64-1 Acetone 30-1. Ik 591-78-6 2-Nexanone 11U
75-15-0 Carbon DisuLfide 5U 127-18-4 Tetrachloroethene 5U
75-35-4 1.1-Dichloroethene 5U 79-34-5 1.1.,2-TetrachLoroethane 5U
75-34-3 1*1-Dichtoroethane 5U 108-88-3 Toluene 5U
540-59-0 1,2-DichLoroethene (total) 5U 108-90-7 Chlorobenzene su
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5U
107-06-2 1,2-Dichloroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1lelelTrichioroethane 5U
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate 11U
75-27-4 Bromodichtoromethane 5U
78-87-5 1,2-Dichtoropropane 5U
10061-01-5 cis-1,3-Dichloropropene
5UA
79-01-6 Trichloroethene 5U 1 /43,
124-48-1 Dibromochtoroinethane 5U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
8B Analyte was founad In the reagent blank as well as the sample.
J1 - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D- 23

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 2
AnaLS I: 90206021Customer Sample ID: N-103
Laboratory: Organic Kass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: 10648 Sample Matrix: SOIL
Instruaent 10: 597003 Requisition Numb~er:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
BRA - Base/Neutral/Acid Compounds CTCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 13-DEC-1990
Preparation Procedure Number: Analysis Procedure Numbier: BNA (CIP) NOP
Percent Moisture: 5.5 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEEHAN
Associated Blank: 901213-028 GA File Numbrder: NA
El : Result has been Corrected for spike
CAS Ug/Kg CAS ug/Kg
108-95-2 Phenol 1000U 106-47-8 4-ChtoroaniLine 1000U
111-44-4 bis(2-Chtoroethyt)ether 1000U 87-68-3 Hexachtorobutadiene l0Ou
95-57-8 2-Chlorophenot 1 000U 59-50-7 4-Chloro-3-methytphenot 1000U
541-73-1 1,3-Dichtorobenzene I 000U 91-57-6 2-Methytnaphthatene 100OU
106-46-7 1,4-DichLorobenzene 1OOOU 77-47-4 Nexachtorocyclopentadiene I 000u
100-51-6 Benzyt Alcohol, 1000U 88-06-2 2,4,6-TrichtorophenoL l0OUt
95-50-1 1,2-Dichlorobenzene I 000U 95-95-4 2,4,5-TrichloropheroL 5100u
95-48-7 2-MethyiphenoL 100OU 91-58-7 2-ChLoronaphthatene 1000U
108-60-1 bisC2-Chloroisopropyt)ether 100OU 88-74-4 2-Nltroanitine 510Wu
106-44-5 4-Methylphenot IOO0OU 131-11-3 Dimethylphthalate 1000U
621-64-7 N-Nitroso-di-n-propytamine I 000U 208-96-8 Acenaphthylene 1000U
67-72-1 Hexachtoroethane 1000U 99-09-2 3-NitroaniLine 51OU
98-95-3 Nitrobenzene 1 00WU 83-32-9 Acenaphthene 1000W
78-59-1 Isophorone I100WU 51-28-5 2.4-Dinitrophenol Sl00U
88-75-5 2-Nitrophenol 100WU 100-02-7 4-Mitrophenot 5Ou
105-67-9 2,4-Dimethytphenot IOOOU 132-64-9 Dibenzofuran 1000U
65-85-0 Benzoic Acid 510WU 121-14-2 2,4-DinitrotoLuene 1000u
111-91-1 bis(2-Chloroethoxy)methane 100OW 606-20-2 2,6-Dinitrotoluene 1000U
120-83-2 2,4-Dichlorophenol 100WU 84-66-2 Diethytphthalate 1000 doQ-G (
120-82-1 1,2,4-Trichtorobenzene 1000U 7005-72-3 4-ChLorophenyl-phenylether 100OW
91-20-3 Naphthalene 100WU 86-73-7 Fluorene l0OU
Data Reporting Qualifiers:
U - Conpound was analyzed for but not detected. The numaber is the attainable detection limit for the samrple.
8 - Analyte w~as found in the reagent blank as well as the samrple.
J - Indicates an estimated value.
NO - Not detected.
A-Aldol condensation product.
O - Secondary dilution.
E - Exceeds initial calibration range.
D-24

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLIS 10: 901206-021 Customer Sample ID: N-103
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: 10648 Sample Matrix: SOIL
instrument ID: 597003 Requisition Numbr:
Authorized By: 0. C. Canada Date Sample Received: 6-DEC-1990
BNA - Base/Neutral/Acid Compounds CTCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 13-DEC-1990
Preparation Procedure Nuber: Analysis Procedure Number: DNA (CLP) HOP
Percent Moisture: 5.5 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C KEENAN
Associated Blank: 901213-028 QA File Numb~er: NA
EU : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
......................... ...... .......... ........... .............................. ..........
100-01-6 4-Nitroaniline 510OU 53-70-3 Dibenz~a,h)anthracene IOOOU
534-52-1 4,6-Dinitro-2-methytphenoL 5100U 191-24-2 Benzo(g,h~i)perylene 1000U
86-30-6 *N-Nitrosodiphenylamine 1000U
101-55-3 4-Iromophenyl-phenylether 1000U
118-74-1 Hexachlorobenzene 100OU
87-86-5 PentachiorophenoL 5100U
85-01-8 Phenanthrene 1000U
120-12-7 Anthracene 100OU
84-74-2 Di-n-buitylphthaLate 2900 S, LA
206-44-0 Fluoranthene 100OU
129-00-0 Pyrene 1000U
85-68-7 Iutytbenzytplhthatate 1000U
91-94-1 3,3'-Dichlorobenzidine 2100U
56-55-3 *enzo~a)anthracene 1000U
117-81-7 bis(2-Ethylhexyl)phthatate 5ie d- too~o LA
218-01-9 Chrysene 1000u
117-84-0 Di-n-octylphthaLate 1000U
205-99-2 *enzo(b)ftuoranthene I 000U
207-08-9 Senzo(k)ftuoranthene 100OU
50-32-8 Benzo(a)pyrene 1000U
193-39-5 Indeno(1,2,3-cd)pyrene IOOOU
Data Reporting Qualifiers:
U - Compoun~d was analyzed for but not detected. The number is the attainable detection limit for the sample.
8 - Anatyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range. q& q
D-25

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
BHA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS ID: 901206-021. Customer Sample ID: M-103
Laboratory: Organic Mass Spectroscopy Laboratoy Customer: J3. KESSWER/R. SHUCK
Sample Matrix: SOIL File ID: 10648
Level: Clow/med): LOW Date Received: 6-D EC-1990
Dilution Factor: 1.0 Date Analyzed: 13-DEC-1990
% Moisture: not dec. 5.5 dec. _____Date Extracted: 12-DEC-1990
Extraction: CSepFIContISonc) SoxH pH: ____
CPC Cleanup: (YIN) N
Concentration Units
Number TICs found: -8 (ugIL or ug/Kg): usLXa
CAS NUMBER ICOMPOUND NAME R T IEST. CONC. 0
:zzzzzzuz228 32=ZZ333Z332335323BZ532: u 5zzz:2323zz.zzc
s zszz 1 zXzz~ us:253zs z2z~jzz~z3
1.- 123-42-21 2-Pentanone. 4-hydroxy.I.-methy 5_______b !7~ ii, 96
12. 1 Unknown
3. 17851-53-51 1.2-Senzenedicarboxylic acidb
I4. IUnknown (Atkyt Hydrocarbon)
I5. IUnknown (Atkyt Hydrocarbon)
1 12.50O1
_________
!5________?*
j -e.16i-
700 1
ape ~
I IM4
6.
I7.
IUnknown (sat'd Hydrocarbon)
IUnknown I
-q4e49
27.72
174 I 20
2300 I
Unknown (sat'd Hydrocarbon) -V
110. I
I
11.I I
1'3. I
114. I
115._______________________1_____1__ _
116. II_____I___
117. II___
118. II___
119. IIII___
120. ____I
121. I _____ ___
122. ______I___I
123. II____ __
124. ______I___I
I25.I _____I_ __
I26.I ______I___I
j27. _______ I
128._III
129. III_______
130. I_________I
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The numb~er is the attainable detection Limit for the sample.
6 - Analyte was found in the reagent blank as well as the sample.
J3 - Indicates an estimated value.
ND -Not detected.
A - Aldol condensation product.
Do Secondary dilution.
E - Exceeds initial calibration range.
P - Probable Identification.
D -26

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of I
AnaLIS ID: 901206-021 Customer Sample 1D: N-103
Laboratory: organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite 10: 0,7599 Sampte Matrix: SOIL
Instrument 10: 597012 Requisition Nuumber:
Authorized By: D. C. Canada Date Sample Received: 5-DEC-1990
VDA Volatile Organic Compounds (TCL)
Date Extracted/Prepared: Date Analyzed: 10-DEC- 1990
Preaparation Procedure Number: PURGE & TRAP Analysis Procedure Number: VOA (CLP) NOP
Percent Moisture: 6 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: SL. STAFFORD
Associated Blank: 901210-025 QA File Number: WA
D) : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
.............................. .......... ........... .............................. ..........
74-87-3 Chloromethane 11t) 79-00-5 1,1.2-Trichioroethane 5U
74-83-9 Brbmomethane 11U 71-43-2 Benzene 5U
75-01-4 Vinyl Chloride 11t; 10061-02-6 trans-1.3-Dlchtoropropene 5U
75-00-3 ChLoroethane 11U 75-25-2 Bromoforu 5U
75-09-2 Methylene Chloride .5 2-
-g- L 108-10-1 4-Methyl-2-pentanone 11U
67-64-1 Acetone 28 S. LJA 591-78-6 2-Hexanone 11U
75-15-0 Carbon Disulfide 5t; 127-18-4 Tetrachtoroethene 5U9
75-35-4 1,1-Dichloroethene 5U 79-34-5 1,1,2,2-Tetrachloroethane 5U
75-34-3 1,1-Dichtoroethane 5U9 108-88-3 Toluene 519
540-59-0 1,2-Dichloroethene (total) 5U 108-90-7 ChLorobenzene 519
67-66-3 Chloroform 5U 100-41-4 EthyLbenzene 5U
107-06-2 1,2-DichLoroethane 5U 10-25Styrene 5U
78-93-3 2-Butanone 1U 1330-20-7 XyLene (total) 5U
71-55-6 1.1,1-Trichtorotthane 5U
56-23-5 Carbon Tetrachloride 519
108-05-4 Vinyl Acetate 11U
75-27-4 Bromodichtoromethane 5U
78-87-5 1,2-Dichloropropane 519
10061-01-5 cis-1,3-Dichloropropene 519
79-01-6 Trichloroethene 5S9
124-48-1 Dibromochloromethane 519
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - AnaLyte was founxd in the reagent blank as well as the sample.
.3 - Indicates an estimated value.
RD - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-27

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 2
AnaLIS ID: 901206-022 Customer Sample to: N-104
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: 10649 Sample Matrix: SOIL
Instrument ID: 597013 Reqisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
RNA -Base/Neutral/Acid compounds CTCL)
Date Extracted/Prepared: 12-DEC- 1990 Date Analyzed: 13-DEC-1990
Preparation Procedure Nu~mber: Analysis Procedure Number: DNA (CLP) NDP
Percent Moisture: 5.2 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C KEENAN
Associated Dlank: 901213-028 DA File Number: NA
Cl:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
108-95-2 Phenol IOOOU 106-47-8 4-Chtoroanitine 100OU
111-44-4 bisc2-Chtoroethyt)ether 1000U 87-68-3 Nexachlorobijtadiene 100OU
95-57-8 2-Chlorophenol 1000u 59-50-7 4-Ch Loro-3-methyLphenot 1000u
541-73-1 1,3-Dichlorobenzene 100OU 91-57-6 2-Methylnaphthalene 1000U
106-46-7 1*I-Dichtorobenzene WOW0 77-47-4 NexachLorocyctopentadiene 1000U
100-51-6 DenzyL Alcohol I DOW 88-06-2 2.,6-Trichlorophenol 100OU
95-50-1 1.2-Dichlorobenzene I1000U 95-95-4 2,4,5-TrichtorophenoL 4900U
95-48-7 2-MethytphenoL 100OU 91-58-7 2-Chloronaphthatene 1000U
108-60-1 bisC2-Chioroisopropyl)ether 1000U) 88-74-4 2-Nitroaniline 4900U
106-44-5 4-Methyiphenol 1000U 131-11-3 Dimethytphthalate 100OU
621-64-7 N-Nitroso-di-n-propyanine 100OU 208-96-8 Acenaphthytene 1000U
67-72-1 Hexachloroethane NOWO 99-09-2 3-Nitroanilina 4900U
98-95-3 Nitrobenzene 1000U 83-32-9 Acenaphthenve 1000U
78-59-1 isophorone 1000U 51-28-5 2.4-Dinitrophenol 4900U
88-75-5 2-Nitrophenol 1000U 100-02-7 4-Nitrophenol 4900U
105-67-9 2,4-Dimethytphentol 100OU 132-64-9 Dibenzofuran l0Ou
65-85-0 Denzoic Acid /600 WO do Lot 121-14-2 2,4-Dinitrotoluene 1000U
111-91-1 bis(2-ChLoroethoxy)methane 1000U 606-20-2 2,6-DinitrotoLuene 1000U
120-83-2 2,4-Dichlorophenol 100WU 84-66-2 DiethylphthaLate 1660 ego'-G do .
120-82-1 1,2,4-Trichtorobenzene 100OW 7005-72-3 4-Chtorophenyt-phenyLether 1000U
91-20-3 Naphthalene 100WU 86-73-7 FLuorene 1000U
Data Reporting Qualifiers:
U - Compound was analyzed for but niot detected. The numbi*er is the attainable detection limit for the samople.
B - Analyte was founid in the reagent blank as well as the sample.
J1 - Indicates an estimated value.
ND - Not detected. /
A-AldoL condensation product.
D - Secondary dilution.
E-Exceeds initial calibration range.
D -28

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLIS ID: 901206-022 Customer Sample 10: N-104
Laboratory: Organic Has$ Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite ID: 10649 Sample Matrix: SOIL
instrument ID: 597013 Requisition Number:
Authorized By: 0. C. Canada Date Sample Received: 6-DEC-1990
BNA - *ase/NeutratlAcid Compounds (TCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 13-OEC-1990
Preparation Procedure Number: Analysis Procedure Nmb~er: OKA (CLP) HOP
Percent Moisture: 5.2 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C KEENAN
Associated Blank: 901213-028 aA File Number: NA
[1 : Result has been Corrected for Spike
CAS uglK9 CAS ug/Kg
...... ................... .......... ........... .............................. ..........
100-01-6 4-Nitroanitine 490OU S3-70-3 Dibenz~ah)anthracene 1000U
S34-52-1 4.6-Dinitro-2-methylphenaL 4900U 191-24-2 *enzo(g,i)perytene I 000U
86-30-6 N-Nitrosodiphenytamine lOOOU
101-55-3 4-IroniophenyL-phenytether IOOOU
118-74-1 Hexachlorobenzene 100OU
87-86-5 PentachlorophenoL 4900W
85-01-5 Phenanthrene I100WU
120-12-7 Anthracene I1000t
84-74-2 Di-n-butyLphthaLate 260O'D.. L&
206-44-0 Ftuoranthene I100WU
129-00-0 Pyrene 100WU
85-68-7 Uutytbenzylphthalate 100WU
91-94-1 3,31-Dichlorobenzidine 200WU
56-55-3 Benzo(a)anthracene
117-81-7 bis(2-Ethythexyt)phthatate
I100WU
&MdO m; O10b LA
215-01-9 Chrysene 100Wt
117-84-0 Di-n-octylphthalate 100WU
205-99-2 Benzo(b)ftuoranthene 100OW
207-08-9 *enzo~kfluoranthene 1000W
50-32-8 Senzo(a)pyrene 100WU
193-39-5 Indeno(1,2,3-cd)pyrene 100WU
Data Reporting Qualifiers: % l I
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the samrple.
8 Anatyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
NO - Not detected.
A -Atdol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D -29

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
SNA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOULND S
AnaLIS ID: 901206-022 Customer Sample ID: N-104
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SNUCK
Sample Matrix: SOIL Fite ID: 10649
Level: (low/mnd): LOW Date Received: 6-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 13-DEC-1990
% Moisture: not dec. 5.2 dec. Date Extracted: 12-DEC-1990
Extraction: (SepF/Cont/Sonc) SOXH PH:
GPC Cleanup: (Y/N) N
Concentration Units
Number TICs found: 16 (uglL or uglKg): _uL~
CAS NUMIER COMPOUND NAME R T jEST. CONC. a
I1. 123-42-21 2-Pentanone, 4-hydroxy-4-methy I4 1(000 1 j
2.- 872-50-41 2-Pyrrotidinone, 1-methyl- I 9.82 ! 4ZO I
13. 1 Unknown 1 12.50! 7401.
4._25013-16-51 Phenot.(1.1-dimethytethyl)-4-m j .d.;I J
5- 1 Unknown (Atkyt Hydrocarbon) 1 19.44 I560 . 1
6. 17851-53-51 1.2-Benzenedicarboxytic acid.b
7. jUnknown (sat'd Hydrocarbon)
8. jUnknown
I .______ Unknown (Alkyl Hydrocarbon)
10. IUnknown (Atkyt Hydrocarbon)
I11- Unknown
12. IUnknown (sat'd Hydrocarbon)
2i1.38 -63 49-
2i6 4-9 1
I21.94 j630 I.
12 M .3- ~
.?*. ----- -! 0--O
I24.11 J.440 I .9
I5 Al I1-dyOI
13.Unknown
14. IUnknown (sat'd Hyrocarbon)
15. IUnknown
I16. IUnknown (sat'd Hydrocarbon)
117.
18. III___
I
I27.74
25.99j
2&4 I
I2400
31IZ
I___
450 1
... 4 j l
1.1
j-
120. IIIj___
121. II___
122. .___I
123. II___
124. III___
125.- 1.___
126.I .___I
127. III___
128. II___
129.I I
130.I II
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection Limit for the sample.
8S Analyte was found in the reagent blank as well as the sample.
J-Indicates an estimated value.
ND - Not detected.
A -Aldo( condensation product.
D Secondary dilution.
E - Exceeds initial calibration range.
P -Probable Identification.
D-30

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 1
AnaLIS ID: 901206-022 Customer Sample ID: M-104
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: 07600 Sample Matrix: SOIL
Instrument ID: 597002 Requisition Number:
Authorized Dy: D. C. Canada Date Sample Received: 5-DEC-1990
VGA - volatile Organic Compounmds CTCL)
Date Extracted/Prepared: Date Analyzed: 10-DEC- 1990
Preparation Procedure Nuber: PURGE & TRAP Analysis Procedure Number: VOA CCLP) MOP
Percent Moisture: 5 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: SL STAFFORD
Associated Blank: 901210-025 GA File Number: NA
D : Result has been Corrected for Spike
CAS ug/Kg CAS uglKg
74-87-3 ChLoromethane 1U1 79-00-5 1,1,2-TrichLoroethane SU
74-83-9 Bromomethane IllU 71-43-2 Benzene 5U
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1,3-Dichloropropene 5U
75-00-3 Chtoroethane litu 75-25-2 Bromoform 5U
75-09-2 Nethylene Chloride 5 dB~e LA 108-10-1 4-Methyl-2-pentanone 11U
67-64-1 Acetone 27 1. LA 591-78-6 2-Hexanone 11u
75-15-0 Carbon Disulfide 5U 127-18-4 Tetrachtoroethene 5U
75-35-4 1,1-Dichtoroethene 51) 79-34-5 1,1,2,2-Tetrachioroethane 5U
75-34-3 1,1-Dichloroethane 5U 108-88-3 Toluene 5U
540-59-0 1,2-Dichtoroethene (total) 5U 108-90-7 Chlorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5U
107-06-2 1,2-DichLoroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Butanone llU 1330-20-7 XyLene (total) 5U
71-55-6 1,1,1-TrichLoroethene 5U
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate 11t;
75-27-4 Drombdichloromethane 5U
78-87-5 1,2-DichLoropropane SU
10061-01-5 cis-1,3-Dichloropropene 5U
79-01-6 Trichloroethene 5U
124-48-1 Dibromochloromethane 5U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection Limit for the sample.
* - Analyte was foun~d in the reagent blank as well as the sample.
J1 - Indicates an estimated value.
NO - Not detected.
A - AldoL condensation product.
O - Secondary dilution.
E - Exceeds initial calibration range.
D-31

WC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 2
AnaLIS ID: 901206-023 Customer Sample ID: W-105
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite ID: 10652 Sample Matrix: SOIL
Instrument ID: 5970513 Requfsition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
BRA - lase/NeutraL/Acid Compounmds (TCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 14-DEC-1990
Preparation Procedure Number: Analysis Procedure Numb~er: RNA (CIP) NOP
Percent Moisture: 5.0 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEEHAN
Associated Blank: 901213-028 GA File Number: MA
11:Result has been Corrected f or Spike
CAS ug/Kg CAS ug/Kg
.................................. .......... ........... .............................. ..........
108-95-2 Phenol 980U 106-47-8 4-Chtoroanitine 980U
111-44-4 bisc2-ChLoroethyl)ether 980U 87-68-3 Hexachlorobutadiene 980U
95-57-8 2-Chlorophenot 980U 59-50-7 4-Chloro-3-methyiphenot 980U
541-73-1 1,3-DlchLorobenzene 9B0U 91-57-6 2-1MethylnaphthaLene 980u
106-46-7 1,4-Dlchiorobenzene 980U 77-47-4 Nexachtorocyctopentadiene 98OU
100-51-6 *enzyl Alcohol 980U 88-06-2 2,4,6-TrichlorophenoL 980u
95-50-1 1,2-Dichlorobenzene 981. 95-95-4 2,4.5-Trichlorophenol 4700u
95-48-7 2-MethyiphenoL 980U 91-58-7 2-ChLoronaphthalene 98Ou
108-60-1 bis(2-ChloroisopropyL)ether 980U 88-74-4 2-NitroaniLine 4700U
106-44-5 4-MethylphenoL 980U 131-11-3 DimethyiphthaLate 980U
621-64-7 N-Nitroso-di-n-propylamine 980U 208-96-8 Acenaphthylene 980U
67-72-1 Hexachioroethane 981. 99-09-2 3-Nitroaniline 4700u
98-95-3 Hitrobenzene 9B0U 83-32-9 Acenaphthene 981.
78-59-1 Isophorone 9B0U 51-28-5 2,4-Dinitrophenol 4700U
88-75-5 2-Nltrophenot 981. 100-02-7 4-NitrophenoL 4700u
105-67-9 2,4-DimethylphenoL 981. 132-64-9 Dlbenzofuran 980U
65-85-0 Benzoic Acid 4780 -~.~rLA 121-14-2 2,4-Dinitrotoluene 980U
111-91-1 bis(2-Chtoroethoxy)methane 9801) 606-20-2 2,6-Dinitrototuene 980U
120-83-2 2,4-DichLorophenoL 98OU 84-66-2 Diethylphthalate i20 46e~e LA
120-82-1 1,2,4-Trichlorobenzene 9801. 7005-72-3 4 -Chi orophenyL -phenyl ether 980U
91-20-3 Naphthatene 981. 86-73-7 FLuorene 980U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J1 - Indicates an estimated value.
NO Not detected.
A - ALdol condensation product.
D - Secondary dilution.
7
E - Exceeds initial calibration range.
D-32

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLIS 1D: 901206-023 Customer Sample tD: N-105
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File to: 10652 Sample Matrix: SOIL
Instrument t0: 597093 Requisition Number:
Authorized Bly: D. C. Canada Date Sample Received: 6-DEC- 1990
BRA - *ase/Meutral/Acid Compounds CTCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 14-DEC-1990
Preparation Procedure Numb~er: Analysis Procedure Number: BRA CCLP) HOP
Percent Moisture: 5.0 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEEHAN
Associated Stank: 901213-028 QA File Numb~er: NA
11 : Result has been Corrected f or Spike
CAS ug/Kg CAS ug/Kg
100-01-6 4-Nftroanitlne 4700t) 53-70-3 Dibenz(a~h)anthracene 98OW
534-52-1 4.6-Dinitro-2-methytphenot 4701U 191-24-2 *enzo(g.h.l)perylene 9S0U
86-30-6 -Ntrosodlphenytmlne 980U
101-55-3 4-Bromophenyl-phenylether 9BOU
118-74-1 Hexachlorobenzene 980U
87-86-5 Pentachtorophenot, 470OU
85-01-8 Phenanthrene 98OU
120-12-7 Anthracene 980U
84-74-2 Di-n-butylphthalate 3600s,.. LA.
206-44-0 Fluoranthene 98WU
129-00-0 Pyrene 98Wu
85-68-7 UutylbenzyLphthalate 98WU
91-94-1 3,3'-DichLorobenzidine 200WU
56-55-3 genzo(a)anthracene 98WU
117-81-7 bis(2-Ethythexyt)phthaLate "ede 5 ,50 (A.
218-01-9 Chrysene 98WU
117-84-0 Di-n-octylphthatate 98WU
205-99-2 *enzo(b)fluoranthene 98WU
207-08-9 Benzo~kfLuoranthene 98W ' (
50-32-8 Senzo(a)pyrene 98WU
193-39-5 lndenoCl,2,3-cd)pyrene 98WU
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The numb~er is the attainable detection limit for the sample.
B - Analyte was foun~d in the reagent blank as well as the sample.
J - Indicates an estimated value.
NO - Not detected.
A - AldoL condensation product.
O - Secondary dilution.
E - Exceeds initial calibration range.
D-33

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical chemistry Department
BHA CTCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COIPOIJNOS
AnaLIS ID: 901206-023
Customer Sample ID: N-105
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Sample Matrix: SOIL
File I0: 10652
Level: (low/med): LOU Date Received: 6-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 14-DEC-1990
% Moisture: not dec. .0 dec. Date Extracted: 12-DEC- 199
Extraction: (SepF/Cont/Sonc) SoxH
PH: ____
GPC Cleanup: (Y/N) N
Niber Tics founrd: 13
Concentration Units
(ugIL or ug/Kg): uM~
CASNULMBER ICOMPOUND NAKE RY EST. CONC. 0
1. 123-42-21 2-Pentanone, 4-hydroxy-4-methy I 57" i 1Zees~
2. 1 Unknown 12.561 4701
I3. 25013-16-51 Pheno.C.-dimethylethyt)4-m I 4.''I 10I
4. 1751-53-51 1.2-Renzenedicarboxylic acid.b I Z129 4- Ia4
I5. IUnknown (sat'd Hydrocarbon) ..7.., i-- -~ I5 J
6. IUnknown (AtkytHydrocarbon) I :23A71 4 420 1.j
7. IUnknown I 24..10 500 -,
g . IUnknown (Atkyt Hydrocarbon) J 6 48 4iI is0[-o
110. Iunknown j 27.711 2400j
I11. IUnknown (set'd Hydrocarbon) 3 0.Q 610 -.
I12. Unknown (sat'd Hydrocarbon) 28 9e.; 4i~ot-
I13. unknown 3 33.88 j570 ...... I
114. __ _ _ _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _ 1__ _ I
115. ____
116.__ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ ._ _ _
17. _ _
118. ____
__
__ _ _ _.1_ _ _
_____I___
19. _ _I_ _ _ _ _ _ __ _ _ _ _ _ _ _ _ __I_ _ _ _ _I_ _ _
120. j_ _ _ _ _ _ _ _ _ _ _ _ _ _ _I_ _ _ _ _ _
121. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _I_ _ _ _ _I_ _ _ _ _I_ _ _
122. j__ _ _ _3I
123. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ JI
124. IJ_ _ _ _ _ _ _ _ _ _ _ _ _ _
125. _____I
126._____I
127.__ _ _ _ ._ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ I
2Z8. _ _ _ _ _I_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
129. _ _ _ _ _1_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
~30.
Data Reporting Qualifiers:
U -Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J -Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
0 -Secondary dilution.
E -Exceeds initial calibration range.
P -Probable Identification. D-34
I

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 1
AnaLIS ID: 901206-023 Customer Sample ID: N-105
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: 07607 Sample Matrix: SOIL
Instrumaent ID: 597092 Requisition Numbzer:
Authorized By: D. C. Canada Date Sample, Received: 6-DEC-1990
VGA -Volatile Organic Compounds (TCL)
Date Extracted/Prepared: Date Analyzed: 11-DEC-1990
Preparation Procedure Nuber: PURGE & TRAP Analysis Procedure Number: VOA CCLP) NOP
Percent Moisture: S Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: GL NWDDLESTON
Associated Stank: 901211-004 aA File Nu~mber: NA
El : Result has been Corrected for Spike
CAS tag/Kg CAS ug/Kg
74-87-3 Chloromethane 1IU 79-00-5 1.1,2-Trichloroethane 5U
71.-83-9 Bromomethane 11U 71.143-2 Benzene 5U
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1,3-Dichlorapropene 5U
75-00-3 Chloroethane 11U 75-25-2 Iromoform 5U
75-09-2 Methylene Chloride *--*t LA 108-10-1 4-Methyl-2-pentanone 11U
67-64-1 Acetone 11U 591-78-6 2-Hexanone 11U
75-15-0 Carbon Disulfide SU 127-18-4 Tetrachloroethene 5U
75.35-4 1,1-Dichioroethene 5U 79-34-5 1,1,2,2-Tetrachtoroethane 5U
75-34-3 I 1-Dichtoroethane 5U 108-88-3 Toluene 5U
540-59-0 1,2-Dichloroethene (total) 5U 108-90-7 Chlorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5U
107-06-2 1,2-Dichloroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Dutanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1,1,1-Trichloroethane 5U
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate 11U
75-27-4 Dromodichtoromethane 5U
78-87-5 1,2-Dichloropropene 5U
10061-01-5 cis-1,3-Dichloropropene 5U
79-01-6 Trichloroethene 5U
124-48-1 Dibromochloromethane 5U
Data Reporting Qualifiers:
U -Conpound was analyzed for but not detected. The number Is the attainable detection limit for the sample.
8 - Analyte was found In the reagent blank as well as the sample.
J - Indicates an estimated value.
RD - Hot detected.
A - Atlol condensation product.
D - Secondary dilution.
E - Exceeds Initial calibration range.
D-35

WIIC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 2
AnaLIS ID: 901206-024 Customer Sample ID: N-106
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite ID: 10653 Sample Matrix: SOIL
Instrument ID: 597013 Requisition Numb~er:
Authorized By: 0. C. Canada Date Sample Received: 6-OEC-1990
BRA -Base/Neutral/Acid Compounds CTCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 14-DEC-1990
Preparation Procedure Numiber: Analysis Procedure Number: BRA (CLP) MOP
Percent Moisture: 3.3 Dilution Factor: 2.0
Percent Moisture (decanted): Analyst: C M4EEHAN
Associated Blank: 901213-028 GA File Number: NA
I]:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
108-95-2 Phenol 2000U) 106-47-8 4-ChtoroaniLine 20001U
111-44-4 bis(2-Chtoroethyt)ether 2000t) 87-68-3 Nexachtorobutadiene 200OU
95-57-8 2-ChlorophenoL 200OU 59-50-7 4-Chlora-3-methylphenoL 200OU
541-73-1 1,3-Dichlorobenzene 200013 91-57-6 2-Methyinaphthalene 2000u
106-46-7 1,4-Dichlorobenzene 20001U 77-47-4 HexachLorocyclopentadiene 2000t3
100-51-6 Benzyl Alcohol. 20001U 88-06-2 2,4.,6-Trichlorophenot 20001U
95-50-1 1,2-DichLorobenzene 20003 95-95-4 2.4,5-Trichtorophenol 9501U
95-48-7 2-MethytphenoL 2000t3 91-58-7 2-ChloronaplithaLene 2000u
108-60-1 bisC2-Chloroisopropyl)ether 20001U 881-74-4 2-Nitroaniline 9500U3
106-"4-5 4-MethyLphenol 2000t3 131-11-3 DimehylphthoLate 2000t)
621-64-7 -Nitroso-di-n-propylamine 20001U 208-96-8 Acenaphthylene 200013
67-72-1 Hexachloroethane 2000U 99-09-2 3-Nitroaniline 950013
98-95-3 Nitrobeniene 200013 83-32-9 Acenaphthene 20001U
78-59-1 Isophorone 200013 51-25-5 2,4-DinitrophenoL 950013
88-75-5 2-Nitrophenol 2000t3 100-02-7 4-Nitrophenol 950013
105-67-9 2,4-DimethytphenoL 20001U 132-64-9 Dibenzofuran 20001U
65-85-0 Benjoic Acid 950OU 121-14-2 2,4-Dinitrotoluene 20001U
111-91-1 bis(2-Chloroethoxy)methane 20001U 606-20-2 2,6-Dinitrotoluenve 2000u3
120-83-2 2,4-Dichlorophenol 20001U 84-66-2 Diethytphthalate 2oaa 25e~O do ..
120-a2-1 1,Z,4-Trichlorobenzene 200013 7005-72-3 4-ChtorophenyL-phenylether 20001U
91-20-3 Naphthalene 20001U 86-73-7 Fluorene 2000u3
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
8 - AnaLyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
NO - Not detected.
A - Aldol. condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-36

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLiS ID: 901206-024 Customer Sample ID: N-106
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File 10: 10653 Sample Matrix: SOIL
Instrument ID: 597003 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
BNA -Base/NeutraL/Acid Compounlds (TCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 14-DEC-1990
Preparation Procedure Numb*er: Analysis Procedure Number: DNA CCLP) MOP
Percent Moisture: 3.3 Dilution Factor: 2.0
Percent Moisture (decanted): Analyst: C MEENAN
Associated Blank: 901213-028 CA File Number: NA
0 : Result has been Corrected f or Spike
CAS ug/Kg CAS ug/K9
100-01-6 4-Nitroanitine 950OU 53-70-3 Dibenz(a~h)anthracene 200OU
534-52-1 4,6-Dlnitro-2-mthytphenoL 950OU 191-24-2 Benzo(g,h~i)peryLene 2000U
86-30-6 N-itrosodiphenylamine 200OL!
101-55-3 4-Dromopheny-phenylether 200OU
118-74-1 Hexachtorobenzene 2000U
87-86-5 PentachtorophenoL 9500U
85-01-8 Phenanthrene 2000U
120-12-7 Anthracene 2000U
84-74-2 Di -n-butytphthalate 2000'S.. LA
206-44-0 Fluoranthene 200DU
129-00-0 Pyrene 200WU
85-68-7 Dutylbenzylphthalate 200OU
91-94-1 3,3'-Dichiorobenzidine 390WU
56-55-3 Denzo(a)anthracene 200WU
117-81-7 bis(2-Ethythexyt)phthatate 2500 S, LA
218-01-9 Chrysene 2000t
117-84-0 Di-n -octytphthatate 110 J ,4
205-99-2 Benzo~b)ftuoranthene 200WU
207-08-9 Denzo(k)fLuoranthene 2000W
50-32-a Denzo(a)pyrene 280 .1
193-39-5 Indeno(1,2,3-cd)pyrene 320 J
Data Reporting Qualifiers:
U - Comrpound was analyzed for but not detected. The number is the attainable detection limit for the samrple.
B - Analyte was found in the reagent blank as well as the sample.
J1 - Indicates an estimated value.
NO - Mot detected.
A - AldoL condensation product.
0 - Secondary dilution.
E - Exceeds initial calibration range.
D-37

WtIC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
BHA CTCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS ID: 901206-024
Customer Sample ID: N-106
Laboratory: Organic Mass Spectroscopy Laboratoy Customer: J9. KESSNER/R. SHUCK
Sample Matrix: SOIL
File ID: 10653
Level: (low/med): LOW Date Received: 6-DEC-1990
Dilution Factor: 2.0 Date Analyzed: 14-DEC-1990
% Moisture: not dec. 3.3 dec. _____Date Extracted: 12-DEC-1990
Extraction: CSepFICont/Sonc) SoxH PH:
GPC Cleanup: (YIN) N
Number TiCs found: 9
Concentration Units
CugIL or ug/Kg): uqLK.
CAS NUM'BER COMPOUND NAME RT EST. CONC. 0
1. 123-42-21 2-Pentanone, 4-hydroxy-4-methy j I : -4v j i ~
2. 1 Unknown (Atkyt Hydrocarbon) j 19.48 I990 1 1
I3.
I4.
I5.
IUnknown
IUnknown (Alkyl Hydrocarbon)
849-99-01 mexanedioic acid, dicyctohexyt
22.031
25.6i
26.39 1
12001.J
1190 4a,
8100
I
6.
I7.
a .
I9.
110. _________________
IUnknown (Hydrocarbon)
IUnknown (Hydrocarbon)
IUnknown (Hydrocarbon)
1 Unknown 1
!6.49
27.76 1
29.59 1
33.96 1
I 'U
2600 J .
1400 I 9
1300 1. 1
1_____1________
I 11. 1__ _ _ _ 1II
112. __ _ I
113. 1 ____ _________I
14.__ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _I_ _ _ _ _I_ _ _ _ _ _ _ _ I
I 15. I II
116. ___________________I______________
~17.
I 18.
119.
II
I
I
120.
I21. _
122.
_ _ _
I
_1_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
I
123.j__________________________
124.
125.
126.j
127.1
128.1
129.1
130.1II
I
I
I
I
I
I
I
Data Reporting Qualifiers:
U - Coffownd was analyzed for but not detected. The number Is the attainable detection limit for the sample.
83 Analyte was founad in the reagent blank as well as the sample.
J.- Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
P - Probable Identification. D- 38

WF!C-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 1
AnaLIS ID: 901206-024 Customer Sampte ID: N-106
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite ID: 07608 Sample Matrix: SOIL
Instrument ID: 597082 Requisition Niuber:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
VOA - Volatile Organic Compounds (TCL)
Date Extracted/Prepared: Date Analyzed: 11-DEC-1990
Preparation Procedure Number: PURGE & TRAP Analysis Procedure Number: VGA CCLP) NOP
Percent Moisture: 3 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: GL IIJODLESTON
Associated Blank: 901211-004 OA File Number: NA
El : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
.................................. .......... ........... .............................. ..........
74-87-3 Chloromethane IOU 79-00-5 1,1,2-Trichloroethane 5U
74-83-9 Bromomethane lOU 7 1-43-2 Benzene 5U
75-01-4 Vinyl Chloride I OU 10061-02-6 trans-1,3-Dichtoropropene SU
75-00-3 Chloroethane IOU 75-25-2 Bromform 5U
75-09-2 MethyLene Chloride 5 2*- (A 108-10-1 4-MethyL-2-pentanone IOU
67-64-1 Acetone I1W 591-78-6 2-Hexanone IOU
75-15-0 Carbon Disuifide 5U 127-18-4 TetrachLoroethene 5U
75-35-4 1*1-Dichtoroethene 5U 79-34-5 1*1 92.2-Tetrachloroethane 5U
75-34-3 1,1-Dichloroethane 5U 108-88-3 Toluene 5U
540-59-0 1,2-Oichtoroethene (total) 5U 108-90-7 Chlorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5U
107-06-2 1,2-Dichtoroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Butanone I1W 1330-20-7 Xylene (total) 5U
71-55-6 1,1,1-TrichLoroethane 5U
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate IOU
75-27-4 Bromodichloromethene 5U
78-87-5 1,2-Dichloropropane SU
10061-01-5 cis-1,3-Dichioropropene 5U L
79-01-6 TrichLoroethene 5U
124-48-1 Dibromochtoromethane 5U
Data Reporting Qualifiers:
U - Compound was analyzed for but niot detected. The number is the attainable detection limit for the sample.
8 - AnaLyte was found in the reagent blank as well as the sample.
J- Indicates an estimated value.
RD - Not detected.
A - Aldol condensation product.
0 - Secondary dilution.
E - Exceeds initial calibration range.
D-39

WIIC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 2
AnaLIS 10: 901206-025 Customer Sample ID: N-107
Laboratory: organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File 1D: 10654 Sample Matrix: SOIL
Instrument ID: 597003 Requisition Neuber:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
BNA - Ease/Neutral/Acid Compounds (TCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 14-DEC-1990
Preparation Procedure Numb~er: Analysis Procedure Number: BNA CCLP) MOP
Percent Moisture: 5.0 Dilution factor: 1.0
Percent Moisture (decanted): Analyst: C MEENAN
Associated Btank: 901213-028 GA Fite Number: NA
El Result has been Corrected f or Spike
CAS ug/Kg
............................ ..........
CAS ug/Kg
........... .............................. ..........
108-95-2 Phenol 100OU 106-47-8 4-ChLoroaniLine 100OU
111-44-4 bisC2-Chloroethyt)ether 100OU 87-68-3 Nexachlorobuatadiene 10O0u
95-57-8 2-Chlorophenol 1000U 59-50-7 4-Chtoro-3-methyLphenot 1000U
541-73-1 1,3-Dichlorobenzene 1000U 91-57-6 2-NethylnaphthaLene I 000U
106-46-7 1,4-Dichtorobenzene 1000U 77-47-4 Hexachiorocyclopentadiene 1000U
100-51-6 BenzyL Alcohol 100OU 88-06-2 2,4,6-Trichlorophenol 1000U
95-50-1 1,2-Dichlorobenzene 100OU 95-95-4 2.I..5-TrichtorophenoL 490OU
95-48-7 2-Methyiphenol 100OU 91-58-7 Z-Chloronaphthatene 1000U
108-60-1 bisC2-ChtoroisopropyL)ether 1 00OU 88-74-4 2-Nitroanline 4900U
106-44-5 4-Methyiphenol I 00OU 131-11-3 Dimethylphthalate 1000U
621-64-7 N-N itroso-di-n-propyLamine I 00OU 208-96-8 Acenaphthylene 100Ou
67-72-1 Hexachtoroethane 100OU 99-09-2 3-Nitroaniline 490OU
98-95-3 Nitrobenzene 1000U 83-32-9 Acenaphthene 1000U
78-59-1 Isophorone 1000U 51-28-5 2,4-DinitrophenoL 4900U
88-75-5 2-Nitrophenol IOOOU 100-02-7 4- N it rophenolI 490OU
105-67-9 2,4-Dimethytphenot 1000U 132-64-9 Dibenzofuran l0OUt
65-85-0 Uenzoic Acid /066 43096 Ue( 121-14-2 2,4-Dinitrotoluene 1000u
111-91-1 bisc2-Chloroethoxy)methane 1000U 606-20-2 2,6-Dinitrotoluene 1000u
120-83-2 2,4-DichlorophenoL 1000U 84-66-2 DiethylphthaLate fo00 238-~- do
120-82-1 1,2,4-Trichlorobenzene 1 000U 7005-72-3 4-Chlorophenyt-ph eny tether 1000U
91-20-3 Naphthalene 1000U 86-73-7 Fluorene 1000U
Data Reporting Qualifiers:
4
U - Compound was analyzed for but not detected. The numb~er Is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J1 - Indicates an estimated value.
NO - Not detected.
AlAdol condensation product.
D - Secondary dilution. e
E-Exceeds initial calibration range.
D-40

WNC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLlS 10: 901206-025 Customer Sampte ID: N-10?
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite 10: 10654 Sample Matrix: SOIL
Instrument 10: 597013 Requisition Number:
Authorized By: 0. C. Canada Date Sample Received: 6-DEC-1990
BNA -Base/Neutral/Acid Compounds CTCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 14-DEC-1990
Preparation Procedure Numb~er: Analysis Procedure Number: DNA (CLP) HOP
Percent Moisture: 5.0 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEEHAN
Associated Blank: 901213-028 OA File Numb~er: NA
U] : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
100-01-6 4-Nitroanitine 4900U 53-70-3 Dibenz(a~h)anthracene IOOOU
534-52-1 4,6-Dinitro-Z-methytphenot 4900U 191-24-2 Senzo(g~hJi)perytene 100OU
86-30-6 N-Nitrosodlphenylaamine 1000U
101-55-3 4-Bromophenyl-phenytether IOOOU
118-74-1 Hexachtorobenzene 1000U
87-56-5 Pentachlorophenol 4900U
85-01-8 Phenanthrene 100OU
120-12-7 Anthracene 1000U
84-74-2 Di-n-butyLphthalate 3300-S. LA'
206-44-0 Fluoranthene 1000U
129-00-0 Pyrene 91 .1
85-68-7 Butytbenzylphthatate 1000U
91-94-1 3,3'-Dichlorobenzldine 200OU
56-55-3 Benzo~aanthracene 100OU
117-81-7 bis(2-Ethythexyt)phthaiste 439 ds /000 Lk
218-01-9 Chrysene 1000U
117-84-0 Di-n-octytphthatate 100OU
205-99-2 Benzo(b) f uoranthene i000U
207-08-9 Denzo(k)fluoranthene
50-32-8 Uenzo(a)pyrene
193-39-5 lndeno(1,2,3-cd)pyrene
Data Reporting Qualifiers:
1000U
i000U
1000u /
U -Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
8 - Analyte was found in the reagent blank as welt as the sample.
i Indicates an estimated value.
NO - Not detected.
A -Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-41

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
SNA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COM4POUNDS
AnaLIS ID: 901206-025 Customer Saumple 10: N-107
Laboratory: Organic Mass Spectroscopy Laborator Customer: J1. KESSNER/R. SHUCK
Samrple Matrix: SOIL File ID: 10654
Level: (tow/med): LOW Date Received: 6-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 14-OEC-1990
% Moisture: not dec. 5.0 dec. _____Date Extracted: 12-DEC-1990
Extraction: CSepF/ContlSonc) SoxH PH: ____
GPC Cleanup: (Y/N) N
Numb~er TICs founid: 15
Concentration Units
(ugIL or uglKg): _u2L1
CAS NUMBER COMPOUND MAKE iT I EST. CONC. 0
S**SSWSSUUUU I.usawasssu ISU3SSSswunsan I3.sasawea
_K
~
1. 141-79-71 3-Penten-2-one, 1.-methyl- 4.94 1 450 1 JIA
2. 123-42-21 2-Pentanone, 4-hydroxy-4-methy I .00 6 34880 I
4. 1 Unknown (sat'dHydrocarbon) 19.44 I6903 15l-65_hnl11dmtvehl-~
J
6. 17851-53-SI12Bneeiabxlcai~
7 51 -I1.2-genzenedicarboxytic ~5 acid~b
I7.I Unknown (Alkyl Hydrocarbon)
a. IUnknown (sat'd Hydrocarbon)
I
I
1.ql
2[... I
MalI
~
~
;; 1
1
do
-
I9. jUnknown 25.901 1000 [
10. jUnknown (Alkyt Hydrocarbon) 'j81 -ife-jd
Ill.____ Unknown 27.68 j800
12.
13.
Unknown (sat'd Hydrocarbon)
jUnknown (Hydrocarbon) 1
-26H;------4Q ?Bi
is.O
30.53 1430 J
14. Unknown (Hydrocarbon) 32.59 j450 .i
15. jUnknown (Hydrocarbon) j 33.43 j1500 _____
116._____j_____________j__________I__ _
117. j______________ _ _ _ __
118. ____ 1II___
120.I I
21.III
122.I II
123. I
124.II
125.III
126.III
27.I
128.III
129.I
130. II
Data Reporting Qualifiers:
U -Comrpound was analyzed for but not detected. The numb~er is the attainable detection limit for the sample.
8-AnaLyte was found in the reagent blank as well as the sample.
J-Indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
o - Secondary dilution.
E - Exceeds initial calibration range. D4
P - Probable Identification. D4

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 1
AnaLIS ID: 901206-025 Customer Sample ID: U-107
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSHER/R. SHUCK
Fit* 10: 07609 Sample Matrix: SOIL
Instrument ID: 5970#2 Requisition Number:
Authorized By: 0. C. Canada Date Sample Received: 6-DEC-1990
VOA - Volatile Organic Comp~ounds (TCL)
Date Extracted/Prepared: Date Analyzed: 11-DEC-1990
Preparation Procedure Number: PURGE L TRAP Analysis Procedure Number: VOA (CLP) NOP
Percent Moisture: 5 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: GL HIDOLESTON
Associated Blank: 901211-004 CA File Number: NA
[D : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
.................................. .......... ........... .............................. ..........
74-87-3 Chtoromethane 11U 79-00-5 1,1,2-Trichloroethane SU
74-83-9 Bromomethane 11U 71-43-2 Benzene 5U
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1,3-Dichloropropene 5U
75-00-3 Chloroethane 11t) 75-25-2 Bromoform 5U
75-09-2 Methylene Chloride £ -3-+.1, 108-10-1 4-Methyl-2-pentanone 11t)
67-64-1 Acetone 11U 591-78-6 2-Hexanone 11U
75-15-0 Carbon DisuLfide 5U 127-18-4 TetrachLoroethene 5U
75-35-4 1,1-Dichloroethene 5U 79-34-5 1,1,2,2-Tetrachloroethane 5U
75-34-3 1,1-Dichioroethane 5U 108-88-3 Toluene 5U
540-59-0 1,2-Dichloroethene (total) 5U 108-90-7 Chtorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 EthyLbenzene 5U
107-06-2 1,2-Dichioroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1,1,1-TrichLoroethane 5U
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate I1U
75-27-4 Iromodichloromethane 5U
78-87-5 1,2-Dichloropropane 5U
10061-01-5 cis-1,3-Dichloropropene SU
79-01-6 Trichloroethene 5U
124-48-1 Dibromochloromethane 5U 71
Data Reporting Qualifiers:
U -Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B Analyte was found In the reagent blank as well as the sample.
J Indicates an estimated value.
NO Not detected.
A -ALdol condensation product.
D Secondary dilution.
E -Exceeds initial calibration range.
D-43

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 1
AnaLIS ID: 901206-028 Customer Sample ID: N-108
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. LESSNER/R. SHUCK
File ID: 07612 Sample Matrix: SOIL
InstrumIent ID: 597012 Reqisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
VGA - Volatile Organic Compounds (CL)
Date Extracted/Prepared: Date Analyzed: 11-DEC-1990
Preparation Procedure Nmbier: PURGE & TRAP Analysis Procedure Number: VOA (CLP) NDP
Percent Moisture: 5 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: CL HUDDLES70N
Associated Blank: 901211-004 QA File Number: NA
[I : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
.................................. .......... ........... .............................. ..........
74-87-3 Chloromethane 11U 79-DO-5 1,1.2-Trlchtoroethane Su
74-83-9 Bromomethane 11U 71-43-2 Benzene SU
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1.3-Dichtoropropene SU
75-00-3 Chtoroethane 11U 75-25-2 Bromoform 5U
75-09-2 MethyLene Chloride % --d L4 108-10-1 4-gethyt-2-pentanone 11U
67-64-1 Acetone 14 LA 591-78-6 2-Hexanone 11U
75-15-0 Carbon Disutfide SU 127-18-4 Tetrachtoroethene, 5U
75-35-4 1,1-Dichloroethene 5U 79-34-5 1,1,2,2-Tetrachtoroethane 5U
75-34-3 1,1-Dichtoroethane SU 108-88-3 Toluene 5U
540-59-0 1,2-Dfchtoroethent (total) 5U 108-90-7 ChLorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5U
107-06-2 1.2-Dichtoroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Butanone 11U 1330-20-7 Xytene (total) 5U
71-55-6 1,1,1-Trichtoroethane 5U
56-23-S Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate 11U
75-27-4 Bromodichioromethane 5U
78-87-5 1,2-Dichtoropropane 5U
10061-01-5 cis-1,3-Dichloropropene 5U
79-01-6 TrichLoroethene 5U
124-48-1 Dibromochtoromethane 5U
Data Reporting Qualifiers:
U - Com~pound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
O - Secondary dilution.
E - Exceeds initial calibration range.
D-44

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 2
AnaLIS 10: 901206-029 Customer Sample ID: M-109
Laboratory: organic Mass Spectroscopy Laboratory Customer: J9. KESSNER/R. SHUCK
Fite I0: 10658 Samrple Matrix: SOIL
Instrument ID: 597013 Requisition Number:
Authorized Bly: D. C. Canada Date Sample Received: 6-DEC-1990
INA -Base/Neutral/Acid Compoun~ds (TCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 14-DEC-1990
Preparation Procedure Number: Analysis Procedure Number: BNA CCLP) NOP
Percent Moisture: 8.0 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEENAN
Associated Stank: 901213-028 CA File Number: NA
C]:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
108-95-2 Phenol 980U 106-47-8 4-ChLorosnitine 980U
111-44-4 bis(2-Chloroethyl)ether 980U 87-68-3 HexachLorobutadiene 98OU
95-57-8 2-Chlorophenol 980U 59-50-7 4-Chloro-3-methytphenot 9BOU
541-73-1 1,3-Dichtorobenzene 98OU 91-57-6 2-Methytnaphthalene 980U
106-46-7 1.4-Dichtorobenzene 980U 77-47-4 Hexachlorocyclopentadiene 980U
100-51-6 *enzyl Alcohol 98OU 88-06-2 2.4.6-Trichiorophenot 980U
95-50-1 1,2-Dichlorobeniene 9B0U 95-95-4 2.,5-TrichtorophenoL 4700u
95-48-7 2-MethyLphenol 98OU 91-58-7 2-ChLoronaphthalene 980U
108-60-1 bisC2-Chtoroisopropyl)ether 980U 88-74-4 2-Nitroanitlne 470OU
106-44-5 4-Methylphenol 980U 131-11-3 Diuicthylphthalate 980U
621-64-7 N-Nitroso-di-n-propylamine 9B0U 208-96-8 Acenaphthylene 980U
67-72-1 Hexachloroethane 9BOU 99-09-2 3-Nitroanillne 470OU
98-95-3 Nitrobenzene 980tU 83-32-9 Acenaphthene 980Ui
78-59-1 Isophorone 98OU 51-28-5 2,4-Dinitrophenol 4700u
88-75-5 2-Nitrophenol 9B0U 100-02-7 4-Nitrophenot 470OU
105-67-9 2,4-Dimethylphenot 980U 132-64-9 Dibenzofuran 98%.
65-85-0 Benzoic Acid 4)80 .2 d8 LA 121-14-2 2,I.-Dinitrotoluene 98OU
111-91-1 bis(2-Chloroethoxy)methane 980U 606-20-2 2,6-Dinitrotoluene 980U
120-83-2 2,I-DichlorophenoL 980U 84-66-2 Diethytplithalate 4q8 W9-* IA
120-82-1 1,2.4-Trichiorobenzene 980U 7005-72-3 4-Chtorophenyl-phenylether 980U.
91-20-3 Naphthalene 98OU 86-73-7 Fluorene 980U
Data Reporting Qualifiers:
4
U - Compound was analyzed for but not detected. The numrber is the attainable detection limit for the samrple.
B - Analyte was found in the reagent blank as well as the smple.
J9 - Indicates an estimated value.
NO - Not detected.
A l-Adol condensation product.
O - Secondary dilution./
E-Exceeds initial calibration range.
Z 1
D-45
4

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLIS ID: 901206-029 Customer Sample I0: 3-109
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File 10: 10658 Sample Matrix: SOIL
Instrument 10: 59703 Requisition Number:
Authorized By: 0. C. Canada Date Sample Received: 6-DEC-1990
BNA -Base/Neutral/Acid Compounds CTCL)
Date Extracted/Pr epa red: 12-DEC-IM9 Date Analyzed: 14-DEC-1990
Preparation Procedure Numb~er: Analysis Procedure Number: INA (CLP) NOP
Percent Moisture: 8.0 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEENH
Associated Blank: 901213-028 CA Fite Number: NA
(I : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
...... ............................ .......... ........... .............................. ..........
100-01-6 4-Nitroaniline 4701. 53-70-3 Dibenz~a,h)anthracene 980U
534-52-1 4,6-Dinitro-2-methytphenot 4700tU 191-24-2 Benzo(g~hi0perylene 98OU
86-30-6 M-Nitrosodiphenylamine 980U
101-55-3 4-Bromophenyl-phenvylether 9B0U
118-74-1 Nexachlorobenzene 9801.
87-86-5 Pentachtorophenol 4700tU
85-01-8 Phenanthrene 980U
120-12-7 Anthracene 981.
84-74-2 Di-n-butylphthalate 1700& %A
206-44-0 Fluoranthene 981.
129-00-0 Pyrene 980U
85-68-7 Butylbenzylplithalate 9BOU
91-94-1 3,3'-Dichtorobenzidinte 200OU
56-55-3 Senzo~a)anthracene 980U
117-81-7 bis(2-EthyLhexyt)phthaLate 380 d- -160 LA
218-01-9 Chrysene 98WU
117-84-0 Di-n-octylphthalate 981.
205-99-2 Uenzo(b)fluoranthene 98OU
207-08-9 Benzo(k)fluoranthene 980U
50-32-8 Benzo(a)pyrene 98OUI
193-39-5 Indeno(l*2,3-cd)pyrene 981.1 l /
Data Reporting Qualifiers:
10%6 /
U - Compounmd was analyzed for but not detected. The number Is the attainable detection limit for the sample.
B - Analyte was founmd in the reagent blank as welt as the samle.
J - indicates an estimated value.
RD - Not detected.
A - Aldol condensation product.
0 - Secondary dilution.
E - Exceeds initial calibration range.
D-46

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
BNA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS 10: 901206-029 Customer Sample 1D: P-109
Laboratory: Organic Mass Spectroscopy Laborator Customer: J. KESSNER/R. SHUCK
Sample Matrix: SOIL Fite ID: 10658
Level: (loa/med): LOW Date Received: 6-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 14-DEC-1990
% Moisture: not dec. 8.0 dec. _____Date Extracted: 12-OEC-1990
Extraction: (SepFIContISonc) SoxH PH: ____
GPC Cleanup: (YIN) N
Numb~er TICs found: 14
Concentration Units
(ug/L or uglKq): _uL~
I CAS NUMBER COM4POUND NAME j RT EST. CONC. a
I1.
I2.
I3.
141-79-71 3-Penten-2-one, 4-methyl-
123-42.21 2-Pentanone. 4-hydroxy-4-methy
1 Unknown (Alkyt Hydrocarbon)
j4.93
j
I1100 .A J
. 9 140300 d O
18.23 I580 IJ
4. jUnknown (Alkyt Hydrocarbon) j 18.78 I600 I 1
5. jUnknown (Atkyt Hydrocarbon) £ 19.43 I1800 1
6. jUnknown (Alkyl Hydrocarbon) 2 1.69-i 1180-4- JO
7. jUnknown (sat'd Hydrocarbon) j 2.?9 6C i5 0l
a .j
9. J
Unknown (sat'd Hydrocarbon)
1 Unknown
_ n I11C -
25.87 j460
404 I
1 .1
10.
Ill.___
12.
Unknown (Alkyt Hydrocarbon)
_ junknown
jUnknown (sat'd Hydrocarbon)
I
I61
2648-
27.69k
7 --- O I-a
5801 J
-- see.- I.' da
13.
14.
115. ____
jUnknown (Atkyt Hydrocarbon)
jUnknown (Hydrocarbon) I
32.59 430 J ~
33.43 11200 J
116. _
17. ____
118. ____
119. ____
_ _
120.1I I
121. ____1II
22?.____
123.1
124.1
125.1I
I
I
126. I
127. II
128. I
129.
130. I
I
I
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The numb~er is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
RD - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
P - Probable Identification. D-47

W:C-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of I
AnaLIS ID: 901206-029 Customer Sample ID: N-109
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: 07613 Sample Matrix: SOIL
Instrument ID: 597002 Requisition Numb~er:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
VOA -Volatile Organic Compounmds CTCL)
Date Extracted/Prepared: Date Analyzed: 11-DEC-1990
Preparation Procedure Numb~er: PURGE & TRAP Analysis Procedure Numb~er: VOA (CLP) MOP
Percent moisture: 8 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: GL NUDDLESTON
Associated Blank: 901211-004 QA File Number: NA
CI:Result has been Corrected for Spike
CAS ug/Kg CAS uglKg
74-87-3 Chioromethane 11U 79-00-5 1,1*2-Trichloroethane 5U
74-83-9 Bromomthane 11U 71-43-2 Benzene 5U
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1,3-Dichtoropropene 5U
75-00-3 ChLoroethane
75-09-2 Methylene Chloride
11U
.5t-*- LA
75-25-2 Bromoform
108-10-1 4-Methyl-2-pentanone
SU
11U
67-64-1 Acetone 15 IA 591-78-6 2-Hexanone I 1U
75-15-0 Carbon Disulfide 5U 127-18-4 Tetrachtoroethene SU
75-35-4 *1-Dichtoroethene SU 79-34-5 1,1,2,2-Tetrachloroethane 5U
75-34-3 ,1-DlchLoroethane 5U 108-88-3 Toluene 5U
540-59-0 1,2-Dichtoroethene (total) 5U 108-90-7 Chlorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5U
107-06-2 1,2-DichLoroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1,11-TrichLoroethane 5U
56-23-5 Carbon Tetrachloride 5U
108-05-4 vinyl Acetate 11U
75-27-4 Iromodichloromethane 5U
78-87-5 1,2-Dichloropropane 5U
10061-01-5 cis-13-OichLoropropene
79-01-6 Trichtoroethene
5U
5U I J69
124-48-1 Dibromochioromethane SU
Data Reporting Qualifiers:
U -Comrpounrd was analyzed for but not detected. The number is the attainable detection limit for the sample.
B Analyte was found in the reagent blank as well as the sample.
J -Indicates an estimated value.
ND -Not detected.
A -Aldol condensation product.
D Secondary dilution.
E -Exceeds initial calibration range.
D-48

WIIC-S-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 2
AnaLIS IN: 901206-030 Customer Samuple ID: N-110
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fit@ ID: 10659 Sample Matrix: SOIL
instrument tD: 597093 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
DNA -Base/Neutral/Acid Compounmds (TCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 14-DEC-1990
Preparation Procedure Numiber: Analysis Procedure Numb~er: DNA CCLP) WOP
Percent Moisture: 7.4 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEEHAN
Associated Btank: 901213-028 QA File Number: NA
[] : Result has been Corrected for Spike
CAS iig/Kg CAS ug/Kg
108-95-2 Phenol 990U 106-47-8 4-Chloroanitine 990U
111-44-4 bis(2-Chloroethyt)ether 99OU a7-68-3 Nexachiorobutadiene 990U
95-57-8 2-Chtorophenol 99OU 59-50-7 4-Chioro-3-methytphenol 990U
541-73-1 1,3-Dichtorobenzene 990U 91-57-6 2-MethytnaphthaLene 990U
106-46-7 1.4-Olchlorobenzene 990U 77-47-4 HexachLorocyclopentadiene 990U
100-51-6 BenzyL Alcohol 990U 88-06-2 2,4,6-TrichlorophenoL 990U
95-50-1 1,2-Dichtorobenzene 990U 95-95-4 2,4,5-TrichtorophenoL 4800U
95-48-7 2-Methytplienol 990U 91-58-7 2-Chtoronsphthalene 990U
108-60-1 bis(2-Chtoroisopropyt)ether 990U 88-74-4 2-Nitroaniline 480OU
106-44-5 4-methyLphenol 990U 131-11-3 Dlmethylphthalate 990U
621-64-7 N-Nitroso-di-n-propytamine 99OU 208-96-8 Acenaphthylene 99OU
67-72-1 Hexachloroethane 99W 99-09-2 3-Nitroaniline 480WU
98-95-3 Nitrobenzene 990U 83-32-9 Acenaphthene 99WU
78-59-1 Isophorone 990U 51-28-S 2,4-Dinitrophenot 480OU
88-75-5 2-Nitrophenol 99WU 100-02-7 4-Nitrophenol 4800U
105-67-9 2.4-DimethylphenoL 99W 132-64-9 Oibenzofuran 990U
65-85-0 Benzoic Acid 4"0 40-d41 L)A 121-14-2 2,4-Dinitrotoluene 990W
111-91-1 bis(2-Chtoroethoxy)methane 99W 606-20-2 2,6-Dinitrotoluene 990U
120-83-2 2,4-Dichlorophenol 99W 84-66-2 .Diethytphthatate q0me# L&.
120-82-1 1,2,4-Trichtorobenzene 99W 7005-72-3 4-Chtorophenyl-phenytother 99W
91-20-3 Naphthalene 99W 86-73-7 Fluorene 990U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The numb~er is the attainable detection limit for the sampLe.
B - Analyte was foun~d in the reagent blank as well as the sample.
J - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution. 11
E - Exceeds Initial calibration range.
D-49

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLiS ID: 901206-030 Customer Sample ID: N-110
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNERIR. SHUCK
Fite 1D: 10659 Sample Matrix: SOIL
Instrumnent ID: 597093 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
BNA -Base/Neutral/Acid Compounzds CTCL)
Date Extracted/Prepared: IZ-DEC-1990 Date Analyzed: 14-DEC-1990
Preparation Procedure Nuber: Analysis Procedure Number: UNA CCLP) MOP
Percent Moisture: 7.4 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEEHAN
Associated Blank: 901213-028 GA File Number: NA
U:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
............................ .......... ........... .............................. ..........
100-01-6 4-Nitroanitine 4800U 53-70-3 Dibenz~a,h)anthracene 991.
534-52-1 4.6-Dinitro-2-methylphenol 4800U 191-24-2 Benzo(g~hJi)perylene 991.
56-30-6 N-Nitrosodiplienylamine 990U
101-55-3 4-Bromopheyl-phenylether 990U.
118-74-1 Hexachlorobenzene 990U
87-86-5 Pentachtorophenol 480OU
85-01-8 Phenantht-ene 990U
120-12-7 Anthracene 991.
84-74-2 Di-n-butylphthaLate 1800'S.. Li.
206-44-0 Fluoranthene 991.
129-00-0 Pyrene 99OU
85-68-7 Butylbenzylphthalate 990U
91-94-1 3,3'-Dichiorobenzidine 2000U
56-55-3 Benzo~aenthracene 990u
117-81-7 bisC2-Ethythexyl)phthaLate 389-" -IC 09 LA,
218-01-9 Chrysene 990k)
117-84-0 Oi-n-octylphthelate 990U
205-99-2 Benzo(b)ftuoranthene 990U
207-08-9 Benzo(k)fluoranthene 990U
50-32-8 Benzo(a)pyrene 990U
193-39-5 Indeno(1,2,3-cd)pyrene 990U
Data Reporting Qualifiers:
U Comipounid was analyzed for but not detected. The number is the attainable detection limit for the sample.
B -Analyte was foun~d in the reagent blank as well as the sample.
J -Indicates an estimated value.
NO -Not detected.
A -Aldol condensation product.
D Secondary dilution.
E -Exceeds initial calibration range.
D- 50

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
BRA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPUNDS
AnaLIS ID: 901206-030 Customer Sample ID: N-110
Laboratory: Organic Mass Spectroscopy Laborotor Customer: J. KESSNER/R. SHUCK
Sample Matrix: SOIL File IDN 10659
Level: Clow/med): LOW Date Received: 6-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 14-DEC-1990
% Moisture: not dec. 7.4 dec. _____Date Extracted: 12-DEC-1990
Extraction: (SepFICont/Sonc) SoxH PH: -
GPC Cleanup: (Y/N) N
Concentration Units
Number TIC& found: 12 CugIL or uglKg): gxLK
CAS NUMBER COMPOUND NAME RT IEST. CONC. I 0
I1.
I2.
141-79-71 3-Penten-2-one, 4-methyl-
123-42-21 2-Pentanone. 4-hydroxy-4-methy
4.92 I49"
-b..O "
1 JIA
I3. 872-50-41 2-Pyrrolidinone. 1-methyt-
I4. IUnknown (sat'd Hydrocarbon)
I5. IUnknown (sat'd Hydrocarbon)
I6. IUnknown (Hydrocarbon)
I7. IUnknown (sat'd Hydrocarbon)j
I8. IUnknown 1
I9. jUnknown (Hydrocarbon)
110. jUnknown (Hydrocarbon) 1
I 1.jUnknown (Hydrocarbon) I
9 .E:I'6 2
19.43 I660 J
256 86 j0-
25.89 I850 IJ
u.I
27.671 1500 1
pe.i[ I .490-+. .n
30.531 410j 1
32.60 1420 J .
/
6
12. JUnknown (Hydrocarbon) I 33.45 I 1300I I
113. _ __ _1III
I14.__ _ _ _ j II
I15.__ _ _ _ j II
116. ____
117. 1___
118. ____
119. ____
120.j II
121.11____1
122. 11____1____1___
123.1____1____1 I
24. 1____1____1___
125. I1____1____I___
126. 1_ _ _ _. _ _ _ 1__ _ I
127. II____I____I___
128. - I____ ____I___
129. _____I____i___I
130. I
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The nu~mber Is the attainable detection limit for the samp~le.
8 - Anolyte was found in the reagent blank as well as the sample.
j - Indicates an estimated value.
RD - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds Initial calibration range.
P - Probable Identification. D-51

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of I
AnaLIS ID: 901206-030 Customer Sample ID: N-110
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSWER/R. SHUCK
File ID: 07614 Sample Matrix: SOIL
Instrumaent I0: 597092 Requisition Number:
Authorized By: 0. C. Canada Date Sample Received: 6-DEC-1990
VGA - Volatile Organic Coupoumds (TCL)
Date Extracted/Prepared:
Date Analyzed: 11-DEC-1990
Preparation Procedure Number: PURGE & TRAP Analysis Procedure Nwumber: VOA (CIP) NDP
Percent Moisture: 7 Dilution Factor: 1.0
Percent Moisture (decanted):
Analyst: GL HUODLESTON
Associated Blank: 901211-004 GA File Number: NA
11 Result has been Corrected for Spike
CAS ug/Kg CAS ug/K9
...... .......................... .......... ........... .............................. ..........
74-87-3 Chloromethane 11U 79-00-5 1.1,2-Trichtoroethane 5u
74-83-9 Broomethane 111U 71-43-2 Benzene 5u
75-01-4 Vinyl Chloride iiU 10061-02-6 trans-1,3.Dichloropropene 5U
75-00-3 Chloroethane 11U 75-25-2 Iromoform 5u
75-09-2 Methylene Chloride 5 31-1- LA 108-10-1 4 -Methyt-2-pentanone 11U
67-64-1 Acetone 111) 591-78-6 2-Nexanone 111)
75-15-0 Carbon Disulfide su 127-18-4 Tetrachloroethene, su
75-35-4 1,1-Dichtoroethene 5U 79-34-5 1,.,2-Tetrachloroethane su
75-34-3 .1-Dichtoroethane 5U 108-88-3 Toluene 5u
540-59-0 1,2-Dichtoroethene (total) SU 108-90-7 Chlorobenzene 5u
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5u
107-06-2 1,2-Dichloroethane 5U 100-42-5 Styrene 5u
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1,1,1-Trichloroethane 5U
56-23-S Carbon Tetrachloride 5U
108-05-4 Vinyl. Acetate 11U
75-27-4 Bromodichloromethane SU
78-87-5 1.2-Dichioropropane Su
10061-01-5 cis-1,3-Oichloropropene 5U
79-01-6 TrichLoroethene 5U1
124-48-1 Dibromochloromethane 5U1
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the samp~le.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
NO - Not detected.
A - ALdol condensation product.
D - Secondary dilution.
E - Exceeds Initial calibration range.
D-52

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
VGA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPUND S
AnaLIS ID: 901206-030 Customer Sample ID: N-11O
Laboratory: Organic Mass Spectroscopy Leboratory Customer: J. KESSNER/R. SNUCK
Sample Matrix: SOIL Fite ID: 07614
Level: (Low/med): LOW Date Received: 6-OEC-1990
Dilution Factor: 1.0 Date Analyzed: 11-DEC-1990
% Moisture: not dec. 7
Concentration Units
Number TICs foun~d: 1 (ug/L or ug/Kg): u K2
ICAS NUMBER ICOMPOUND NAME RT iEST. CONC. Q
I1. 76-13-11 Freon 113 4.2~~j 6 S
j3._ _ _1_ _ _ _ _ _ _ _ 1I
j8._ _ _ I
19.1
110. ____
I
12. _ _ _ _
113. ____1 I
114. ____1I I
I15.__ __ _ II
116. ____1 II
1'9._____
20.__ _ _ _
121.
II
II
I
122.jII
123.j
124.J
125.1____________1
126.
127.
128.
129.
130.
III
II
I
I
II
II
I
I
I
I
I
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the samp1e.
B -Analyte was found In the reagent blank as well as the sample.
J3 - Indicates an estimated value.
ND - Not detected.
A -Aldol condensation product.
D Secondary dilution.
E -Exceeds initial calibration range.
P Probable Identification.
D -53

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 2
AnaLIS ID: M0206-031 Customer Sample ID: N-111
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: 10660 Sample Matrix: SOIL
Instrument ID: 597053 Reuqisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
RNA -Base/Neutral/Acid Compounds (TCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 14-DEC-1990
Preparation Procedure Number: Analysis Procedure Number: BHA CCLP) MOP
Percent Moisture: 6.1 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEEHAN
Associated Blank: 901213-028 GA File Number: NA
UI : Result has been Corrected for Spike
CAS ug/Kg CAS ugfKg
...... ............................ .......... ........... .............................. ..........
108-95-2 Phenol 99WU 106-47-8 4-Chtoroaniline 990U
111-14-4 bis(2-Chloroethyl)ether 990t.3 57-68-3 Hexachtorobutadiene 990U
95-57-8 2-Chlorophenol 991. 59-50-7 4-Chloro-3-methytphenot 990U
541-73-1 1,3-Dichtorobenzene 991. 91-57-6 2-MethytnaplhthaLene 990U
106-4.6-7 1*i-Dichlorobenzene 99OU 77-47-4 Nexachtorocyclopentadiene 990U
100-51-6 *enzyl Alcohol 99OU 58-06-2 2,4,6-TrichLorophenol 990U
95-50-1 1,2-Dichlorobenzene 99WU 95-95-4. 2,4.5-TrichLorophenoL 1.800U
95-1.8-7 2-Methytphenol 99WU 91-58-7 2-ChloronaphthaLene 990U
108-60-1 bis(2-Chlorolsopropyt)ether 99WU 88-74-1. 2-Nitroaniline 480OU
106-4.4-5 4-Methytphenol 990U 131-11-3 Dimethyiplithatate 990UJ
621-64-7 U-Nitroso-di-n-propylamine 99WU 208-96-8 Acenaphthytene 990U.
67-72-1 Hexachloroethane 9901 99-09-2 3-Nitroaniline 4800U
98-95-3 NItrobenzene 99WU 83-32-9 Acenaphthene 990U
78-59-1 Isophorone 99WU 51-25-5 2,I.-Dinitrophenol 4800U
88-75-5 2-Nitrophenol 990W 100-02-7 4-Nitrophenol 1.800U
105-67-9 2.4-Dimethytphenot 990U 132-64-9 Dibenzofuran 990U
65-85-0 Benzoic Acid -9,90 e+-*&fl- LA 121-14-2 2,4-Dinitrotoluene 99GU
111-91-1 bis(2-Chicroethoxy)methane 99WU 606-20-2 2,6-Dinitrotoluene 990U
120-83-2 2,4-Dichlorophenol 99WU 84-66-2 Diethylphthalate C 10 ~E-uie- LA
120-82-1 1,2,4-Trichlorobenzene 990U 7005-72-3 4-Chlorophenyl-phenylether 990U
91-20-3 Naphthalene 990U 86-73-7 Fluorene 990U
Data Reporting Qualifiers:
U -Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B -Analyte was found in the reagent blank as well as the sample.
J -Indicates an estimated value.
RD -Not detected.
A -Aldol condensation product.
D Secondary dilution.
E -Exceeds initial calibration range.
D- 54

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLIS 1D: 901206-031 Customer Sample 10: N-111
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File 1D: 10660 Sample Matrix: SOIL
Instrument ID: 597053 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
UNA - Base/Neutral/Acid Compounds (TCL)
Date Extracted/Prepared: 12-DEC- 1990 Date Analyzed: 14-DEC- 1990
Preparation Procedure Numb~er: Analysis Procedure Nuber: INA CCLP) HOP
Percent Moisture: 6.1 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEEHAN
Associated Blank: 901213-028 CA File Nwvber: NA
El : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
100-01-6 /s-Nitroaniline 4080011 53-70-3 Dibenz(a,h)anthracene 99011
534-52-1 4,6-Dinitro-2-methytphenot 480011 191-24-2 Benzo(g,h~i)peryiene 9901
86-30-6 N-Uitrosodiphenylamine 99011
101-55-3 4-Bromopheny-phenytether 99011
118-74-1 Mexachlorobenzene 99011
87-86-5 Pentachtorophenot 480011
85-01-8 Phenanthrene 9901
120-12-7 Anthracene 99011
84-74-2 Di-n-butylphthalate - ie g- 99io LA
206-44-0 Fluoranthene 99011
129-00-0 Pyrene 99011
85-68-7 Butylbenzylphthalate 9901
91-94-1 3,31-Dichtorobenzidine 20001U
56-55-3 Senzo(a)anthracene 99011
117-81-7 bis(2-Ethythexyt)phthaLate 40-B do Cley0 LA
218-01-9 Chrystne 99011
117-84-0 Di-n-octylphthalate 99011
205-99-2 *enzo(b)fluoranthene 99011
207-08-9 Benzo(k)fluoranthene 99011
50-32-8 Ienzo(a)pyrene 99011
193-39-5 Indeno(1,2,3-cd)pyrene 99011
Data Reporting Qualifiers:
U1 - Compound was analyzed for but not detected. The number Is the attainable detection Limit for the sample.
B - Analyte was found in the reagent blank as well as the samiple.
J - Indicates an estimated value.
ND - Not detected.
A - Aidol condensation product.
0 - Secondary dilution.
E - Exceeds initial, calibration range.
D-55

W1dC-SD-EN-TI-136,-Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
INA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnSLIS ID: 901206-031 Customer Sample ID: N-1ll
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SNUCK
Sample Matrix: SOIL File ID: 10660
Level: (tow/mod): LOW Date Received: 6-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 14-DEC-1990
% Moisture: not dec. 6.1 dec. _____Date Extracted: 12-DEC-1990
Extraction: (SepF/Cont/Sonc) SoxH pH: ____
GPC Cleanup: CT/N) N
Concentration Units
Number TICs found: 15 (ug/L or ug/Kg): u2LKI
ICAS NUMBER COMPOUND NAM4E I RT jEST. CONC. a
1. 123-42-21 2-Pentanone. 4-hydroxy-4-methy j 5.3' ''' I!
I2. 872-50-41 2-Pyrrolidinone. 1-methyl- 9 .ZI[ 44 do~I
I3. 25013-16-51 Phenol.(1.1-dimethylethyl)-4-m i6I -W44-49______
I4. 1 Unknown (sat'd Hydrocarbon) 19.42 I830 1 '
I5. Unknown (Atkyl Hydrocarbon) J 1.69Isee M
I6. Unknown (sat'd Hydrocarbon) j 22.73 _ I410_
__ _6
I7. jUnknown (Hydrocarbon) 43j7 se . do
a .______ Unknown (sat'd Hydrocarbon)
I9. Unknown (Hydrocarbon)
110. Unknown (sat'd Hydrocarbon)
it1. IUnknown I
156
25.89 j850
V6 -
27.53 I660
9.O20#-4 is
J .1
00 J
J .
1 'I
12. IUnknown (Hydrocarbon) MR 65 09-
113. IUnknown I 29.39!
~
470 1 1
14.
I15.
116.
IUnknown (sat'd Hydrocarbon)
IUnknown (Hydrocarbon)
I
I
32.59 I420
33.51 I
IJ
1500 I
I
117. 1 I
118.
119.
II_ _ _ _
__ _ _ _
_
_
_
_
_
_
_
_
_
_
_I_
_I_
_
_
_
_ I
120.
121.
122.
123.
II_
II_____
_ _ _
i__ _ _ _
j__ _ _ _
_ _ _ _ _ _I_ _
_ _ _ _ _ _I_ _
_t_ _ _ _ _I_ _
____ __
_
_
_
I
I
125. II_ _ _ _ _ _I_ _ _ _ _ _ _ _
126. __ _ _ _ _I_ _ _ _ _I_ _ _ I
127. ___________I__ _
128.I __ _ _ _I_ _ _ _ I__ _
129. II_ _ _ _ _I_ _ _ _ _I_ _ _
130. ______I_____
Data Reporting Qualifiers:
U -Compound was analyzed for but not detected. The number Is the attainable detection limit for the sample.
8 - Analyte was found in the reagent blank as well as the sample.
J1 - Indicates an estimated value.
NO H ot detected.
A -Aldol condensation product.
D -Secondary dilution.
E -Exceeds Initial calibration range.
P - Probable Identification. D-56

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT
Page I of I
AnaLIS ID: 901206-031 Custom'er Sample ID: N-111
Laboratory:
File 10:
Organic Mass Spectroscopy Laboratory
07615
Customer:
SUam3lS Matrix:
J1. XESSMER/R.
SOIL
SHUCK
Instrument 10: 5970#2 Requisition Number:
Authorized By: 0. C. Canada Date Sample Received: 6-DEC-1990
VOA - Volatile Organic Compound &CTCL)
Date Extracted/Prepared: Date Analyzed: 11-DEC-1990
Preparation Procedure Numb~er: PURGE & TRAP Analysis Procedure Number: VOA (CLP) MOP
Percent Moisture: 6 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: GL MUDDLESTON
Associated Blank: 901211-004 GA File Nuumber: NA
II:Result has been Corrected for Spike
CAS ug/Kg CAS uglKg
......... .............................. .......... ........... .............................. ..........
74-87-3 Chloromethane 11U 79-00-5 1,1,2-Trichloroethane 5U
74-83-9 Bromomethane liii 71-43-2 Benzene 5U
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1,3-Dichloropropene SU
75-00-3 Chtoroethane 11U 75-25-2 Bromoform 5U
75-09-2 Methylene Chloride £ t--LA 108-10-1 4-Methyl-2-pentanone 11U
67-64-1 Acetone 11U 591-78-6 2-Hexanone 11U
75-15-0 Carbon Disulfide SU 127-18-4 Tetrachtoroethene 5U
75-35-4 1,1-Dichloroethene SU 79-34-5 1,1,2,2-Tetrachloroethane 5U
75-34-3 1,1-Dichloroethane SU 108-88-3 Toluene 5U
540-59-0 1,2-Dichloroethene (total) 511 108-90-7 Chlorobenzene 5U
t67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5U
107-06-2 1,2-Dichloroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1,1,1-Trichloroethane 5U
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate 11U
75-27-4 Bromodichloromethane 5U
78-87-5 1,2-Dichioropropane 5U
10061-01-5 cis-i,3-Dichloropropene SU
79-01-6 Trichloroethene 5U
124-48-1 Dibromochtoramethane SU
Data Reporting Qualifiers:
U -cowpotwi was analyzed for but not detected. The number is the attainable detection limit for the sample.
B Analyte was found in the reagent blank as well as the sample.
.1 Indicates an estimated value.
ND -Not detected.
A -Aldol conidensation product.
O Secondary dilution.
E -Exceeds initial calibration range.
D-57

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPOT Page I of Z
AnaLIS ID: 901206-032 Customer Sample ID: N-1i2
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. XESSHER/R. SHUCK
Fite I0: 10661 Sample Matrix: SOIL
Instrument ID: 597093 Requisition Numb~er:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
INA - Dase/Neutral/Acid Compounmds (TCL)
Date Extracted/Prepared: 12-DEC-990 Date Analyzed: 14-DEC-1990
Preparation Procedure Number: Analysis Procedure Number: BRA CCLP) MOP
Percent Moisture: 4.3 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEEHAN
Associated Blank: 901213-028 QA File Number: NA
D) : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
............................ .......... ........... .............................. ..........
108-95-2 Phenol I 000U 106-47-8 4-Chloroanitine iooou
111-44-4 bisC2-Chloroethyt)ether I 00OU 87-68-3 Hexachlorobutediene iooOU
95-57-8 2-Chlorophenol 100OU 59-50-7 4-Chtoro-3-methylphenol 1000U
54173-1 1.3-Dichlorobenzene 100OU 91-57-6 2-Methyinaphthatene l0OU
106-46-7 1,4-Dichlorobenzene IOO0OU 77-47-4 Hexachlorocyclopentadiene 000U
00-51-6 Benzyl Alcohol I 00OU 88-06-2 2,4,6-Trichtorophenot iCOU
95-50-1 1,2-Dichtorobenzene IOQ0ti 95-95-4 2,4.5-Trichlorophenot S0OUt
95-48-7 2-Methylphenol IOOOU 91-58-7 2-ChLoronaphthalene 1000U
108-60-1 bisC2-Chlorolsopropyl)ether I 00OU 88-74-4 Z-Mitroanitlne SQO0ti
106-44-5 4-Methylphenot I 000U 131-11-3 Dimethylphthatate lOC0tU
621-64-7 N-Nitroso-di-n-propylamine iQOUt 208-96-8 Acenaphthylene iQO0ti
67-72-1 Nexachtoroethane 1000U 99-09-2 3-Nitroaniline 5000U
98-95-3 Nitrobenzene 10001) 83-32-9 Acenaphthene l0OUt
78-59-1 Isophorone 10001) 51-28-5 2,4-Dlnitrophenot 50001)
88-75-5 2-Nitroplhenot 1 0001) 100-02-7 4-Nitrophenot 5000U
105-67-9 2,4-Dimethylphenot 10001) 132-64-9 Dibenzofuran 10O0U
65-85-0 Benzoic Acid. to" .Owt- in A 121-14-2 2.4-Dinltrototuene 1000U
111-91-1 bisC2-Chioroethoxy)methene 1 0001) 606-20-2 2,6-Dinitrotoluene 1000U
120-83-2
120-82-1
2,4-Dichlorophenot
1,2,4-Trichiorobenzene
10001)
10001)
84-66-2 Diethylphthatate
7005-72-3 4-Chlorophenyl-phenytether
/*CPO .ae-m- LA
lOO0U
91-20-3 Naphthalene 1000U 86-73-7 Fluorene 1000u
Data Reporting Qualifiers:
U - Compounid was analyzed for but not detected. The numb~er is the attainable detection limit for the sample.
* - Analyte was found in the reagent blank as welt as the sample.
J - Indicates an estimated value.
ND - Not detected.
A - Aldot condensation product.
D-Secondary dilution.I 4 q
E - Exceeds initial calibration range.el61
D -58

WIIC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLIS ID: 901206-032 Customer Sample ID: N-112
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. CESSHER/R. SHUCK
Fit* I0: 10661 Sample Matrix: SOIL
Instrument ID: 597013 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
INA - Base/Neutral/Acid Compounds (TCL)
Date Extracted/Prepared: 12-DEC-IM9 Date Analyzed: 14-DEC-1990
Preparation Procedure Numbier: Analysis Procedure Number: BHA (CLP) NOP
Percent Moisture: 4.3 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEEHAN
Associated Blank: 901213-028 QA File Number: NA
.1 : Result has been Corrected f or Spike
CAS ug/Kg CAS ug/Kg
100-01-6 4-Nitroanitine 5000t) 53-70-3 DibenzCa,h)anthracene 0003
534.-52-1 4,6-Dinitro-2-methylphenot 50003 191-24-2 BenzoCg,i)perylene 1000ti
86-30-6 N-Nitrosodlphenylamlne 100013
101-55-3 4-Uromophey-phenylether 100013
118-74-1 Nexachtorobenzene 100013
87-86-5 Pentachlorophenol 500013
85-01-8 Phenanthrene 100013
120-12-7 Anthracene 100013
84-74-2 DI-n-butylplithalate 3500 1k LA
206-1.4-0 Fluoranthene 100013
129-00-0 Pyrene 1000IJ
85-68-7 Butylbenzylphthalate 1000t)
91-94-1 3,3'-Dichtorobenzidine 210013
56-55-3 Benzo~aenthracene 10003
117-81-7 bis(2-Ethylhexyi)plhthatate wo je- iocaLk
218-01-9 Chrysene 10003
117-81.-0 Di-n-octylphthalate 99 J
205-99-2 *enzo(b)ftuorenthene 10003
207-08-9 Benzo~k)f luoranthene 10003
50-32-8 Benzo(a)pyrene 1000t3f q
193-39-5 Indeno(l2,3-cd)pyrene 100013
Data Reporting Qualifiers:
U -Comvpound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B Analyte was found in the reagent blank as well as the sample.
J -Indicates an estimated value.
ND -Not detected.
A -Aldol condensation product.
D Secondary dilution.
E -Exceeds initial calibration range.
D-59

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-ZS Site
Analytical Chemistry Department
BNA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED CMPOUJNDS
AnaLIS ID: 901206-032 Customer Sample ID: N-112
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Sample Matrix: SOIL File ID: 10661
Level: (lowlmed): LOW Date Received: 6-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 14-DEC-1990
% Moisture: not dec. 4.3 dec. _____Date Extracted: 12-DEC-1990
Extraction: (SepFlContlSorc) SoxH PH: ____
GPC Cleanup: CYIN) N
Concentration Units
Number TICs found: 16 (ug/L or uglKg): u2K
ICAS NLUER COMPOUND NAME I RT jEST. CONC. 0
1. 141-79-71 3-Penten-2-one, 4-methyl-
I2. 123-42-21 2-Pentanome. 4-hydroxy-4-methy
I3. 572-50-41 2-Pyrrolidinome. 1-methyl-
I4. 25013-16-51 Phenot.(I.1-dimethylethyt)-4-m
I5. 17851-53-51 1.2-genzenedicarboxytic acid~b
I6. Unknown (sat'd Hydrocarbon)
I7. JUnknown (Atkyl Hydrocarbon)
1
1
j
1.92 1
9.9? !
9 8;1 4
14
piE.3 I
Z1.69 I3
229
430 1 JiA
3190 I JM
S60
se i d0 o
7990 I
d~ o-
L0 We 0J
I
8.
I'.__
10.
11.
jUnknown (Alkyt Hydrocarbon)
_ JUnknown
JUnknown (sat'd Hydrocarbon)
JUnknown (Atkyl Hydrocarbon)
j
I
J
:L7" 3;9 I
24.00!1
2569 I
25.91 j970
o
440 1 1J
- iNO ! -
1
q
12.
I13.
123-79-51 Dloctyl Adipate
1 Unknown (Alkyt Hydrocarbon)
j 26.40 j
46 to'I
2500
1
J
J
114.
15.
1 Unknown
1 Unknown (Hydrocarbon)
j
J
27.711
e 1.I4..
1400 1
;40 d o
16. junknown j 33.57j 1000 1
17. 1 _ _ _ _ _ _ _ _ 1 _ _ _
118. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
119.1__ _ _ _ _ _ _ _ _ _ 1__ _ _ 1 _ _ _ __ _
120.1__ _ _ _ _ _ _ _ _ _ 1__ _ _ _1_ _ _ _ __ _ I
121.1__ _ _ _ _ _ _ _ _ 1.1_ _ _ _1_ _
122. 1_ _ _ _ _ _ _ _ _ _ _ _ _ _ _I_ _ _ _
123. 1_ _ _ _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _
124. 1_ _ _ _ _ _ _ _ _ _ _ _ _ _ _I_ _ _ _ _ _
125._II_ _ _ _ __ _ _ _ _
126. __ _ _ _I_ _ _ _ I__ _ I
127.I __ _ _ _I_ _ _ _ __ _ I
128. __ _ _ _I_ _ _ _ I__ _ I
129. __ _ _ _I_ _ _ _ I__ _ I
130.II__ _ _ _I_ _ _ _ I__ _ I
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
8 - Analyte was foun~d in the reagent blank as well as the sample.
J3 - Indicates an estimated value.
NO - Not detected.
A - Atdol condensation product.
O - Secondary dilution.
E - Exceeds Initial calibration range.
P - Probable Identification. D-60

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 1
AnaLIS I0: 901206-032 Customer Samrple ID: N-112
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: 07616 Samrple Matrix: SOIL
Instrument ID: 5970#2 Requisition Number:
Authorized By: 0. C. Canada Date Samrple Received: 6-DEC-1990
VGA -Volatile Organic Compoun~ds CTCL)
Date Extracted/Prepared: Date Analyzed: 11-DEC-1990
Preparation Procedure Number: PURGE & TRAP Analysis Procedure Numbier: VOA (CLP) NOP
Percent Moisture: 6 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: CL HUDDLESTON
Associated Blank: 901211-004 GA File Numer: NA
U:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
...... ................... .......... ........... .............................. ..........
74-87-3 Chtoromethane 11U 79-00-5 1,1.2-TrichLoroethane 5U
74-83-9 Bromomethane 11U 71-43-2 Benzene 5U
75-01-4. Vinyl Chloride 11U 10061-02-6 trans-1,3-Dichloropropene 5U
75-00-3 Chtoroethane 11U 75-25-2 Bromoform 5U
75-09-2 Methylene Chloride su 108-10-1 4-Methyl-2-pentenone 11U
67-64-1 Acetone 28 ILA 591-78-6 2-Hexanone 11u
75-15-0 Carbon Disulfide 5U 127-18-4 Tetrachloroethene 5U
75-35-4 1,1-Dichloroethene 5U 79-34-5 1.1.2,2-Tetrachloroethane 5U
75-36-3 1,1-Dichloroethane SU 108-88-3 Toluene 5U
540-59-0 1,2-Dichtoroethene (total) 5U 108-90-7 Chlorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5U
107-06-2 1,2-Dichloroethane SU '100-42-5 Styrene 5U4
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) 5U4
71-55-6 1.1,1-Trichloroethane 514
56-23-5 Carbon Tetrachloride 5U4
108-05-4 Vinyl Acetate 1114
75-27-4 Bromodichioromethane 514
78-87-5 1,2-Dichtoropropane SU
10061-01-5 cis-1,3-Dichtoropropene 514
79-01-6 Trichloroethene 514
124-48-1 Dibromchtoromethane 514
Data Reporting Oualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Anelyte was found In the reagent blank as well as the sample.
J1 - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-61

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 2
AnaLlS ID: 901206-033 Customer Sample ID: N-113
Laboratory: Organic mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite ID: 10662 Sample Matrixi: SOIL
Instrinent 1D: 597083 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
BRA - Base/Neutral/Acid Compouds CTCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 14.-DEC-1990
Preparation Procedure Number: Analysis Procedure Number: BRA (CIP) NDP
Percent Moisture: 3.8 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEEHAN
Associated Blank: 901213-028 CA Fite Number: NA
U:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
............................ .......... ........... .............................. ..........
108-95-2 Phenol 88013 106-4.7-8 4-Chtoroanitine 88013
111-44-4. bis(2-Chloroethyl)ether 88013 87-68-3 Nexachtorobutadiene 88013
95-57-8 2-Chlorophenot 88013 59-50-7 1.-Chloro-3-methylphenol 88013
54.1-73-1 1,3-Dichtorobenzene 88013 91-57-6 2-Methylnaphthatene 88013
106-4.6-7 1,1-Dichiorobenzene 88013 77-1.7-1. Hexachtorocyctopentadiene 880U3
100-51-6 Benzyl Alcohol 88013 88-06-2 2,4,6-Trichlorophenol 8803
95-50-1
95-4.8-7
108-60-1
106-4.4-5
1.2-Dichlorobenzene
2-MethylphenoL
bis(2-Chtorotsopropyt)ether
1-Methylphenol
88013
88013
880ot)
88013
95-95-. 2,4,5-TrichLorophenoL
91-58-7 2-ChtoronaplithaLene
88-74-4. 2-Nitroaniline
131-11-3 Dimethylphthalate
43001U
88013
4.300U
880U.
621-64-7 N-Nitroso-di-n-propylamine
67-72-1 Hexachloroethane
98-95-3 Nitrobenzene
880t)
88013
88013
208-96-8 Acenphthyln
99-09-2 3-Nitroaniline
83-32-9 Acenaphthene
88013
1.3001U
8803
78-59-1 Isophorone 88013 51-28-5 2,I.-Dinitrophenot 1.3001U
88-75-5 2-NitrophenoL 88013 100-02-7 4-Nitrophenol 1.301U
105-67-9 2,4-Dimethylphenot 88013 132-64-9 Dibenzofuran 880.
65-85-0 Benzoic Acid
111-91-1 bis(2-Chloroethoxy)methane
120-83-2 2,1.-Dichiorophenot
SSG 200 o-l L4
58013
88013
121-14-2 2,1.-Dinitrotoluene
606-20-2 2,6-Dlnitrotoluene
84-66-2 Diethylphthalate
88013
880U3
4-do meo LA
120-82-1 i,2,4-Trichlorobenzene 88013 7005-72-3 1-Chtorophenyl-phenylether 880U
91-20-3 Naphthalene. 88013 86-73-7 Fluorene 88013
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The numiber is the attainable detection limit for the samuple.
B - Analyte was found In the reagent blank as well as the sample.
J9 - Indicates an estimated value.
ND - Not detected.
A - A~dol condensation product.
D - Secondary dilution. / A
E - Exceeds initial, calibration range.
D-62

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT page 2 of 2
AnaLIS ID: 901206-033 Customer Sample ID: N-113
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File 10: 10662 Sample Matrix: SOIL
Instrument ID: 597013 Requisition Number:
Authorized Dy: D. C. Canada Date Sample Received: 6-DEC-199
BMA - Dase/Neutrat/Acid Compounds CTCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 14.-DEC-IM9
Preparation Procedure Nu~mber: Analysis Procedure Number: DNA CCLP) WOP
Percent Moisture: 3.8 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEEHAN
Associated Stank: 901213-028 GA File Numrber: NA
U:Result has been Corrected for spike
CAS ug/Kg CAS ug/Kg
100-01-6 4-Mitroanitine 4300U 53-70-3 Dibenz~a,h)anthracene 88OU
534-52-1 4,6-Dinitro-2-methytphenol 4301U 191-24-2 Senzo(g,hI)perylene 880U
86-30-6 M-Nitrosodiphenylamine 88OU
10f1-55-3 4 -8romopheny -phenyl ether 880U
118-74-1 Hexachlorobenzene $110U
87-86-5 Pentachlorophenot 430WU
85-01-8 Phenanthrene 8BOU
120-12-7 Anthracene 8801.
84-74-2 Di-n-butylphthalate 1600'&. tA
206-44-0 Fluoranthene 880U
129-00-0 Pyrene 881.
85-611-7 Dutylbenzylphthalate SB0U
91-94-1 3,3'-Dichtorobenzidine 180OU
56-55-3 Benzo~aanthracene 8801.
11-81-7 bis(2-Ethythexyt)phthatate 645 do - BS LA
218-01-9 Chrysene S80U
117-84-0 i-n-octyiphthatate 880U
205-99-2 Denzo(b)fluoranthene 880U.
207-08-9 Benzo~kfluoranthene 880U
50-32-8 Senzo~a)pyrene 880U.
193-39-5 IndenoC1,2,3-cd)pyrene 880U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
* - Analyte was found in the reagent blank as well as the sample.
J - indicates an estimated value.
No - Not detected.
A - Aldol condensation product.
o - Secondnry dilution.
E - Exceeds initial calibration range.
D0-63

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
BRA CTCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS ID: 901206-033 Customer Sample ID: N-113
Laboratory: Organic Mass Spectroscoy Laboratory Customer: J. KESSNER/R. SHUCK
Sample Matrix: SOIL Fit* ID: 10662
Level: (low/reed): Low Date Received: 6-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 14-DEC-1990
% Moisture: not dec. . 3.8 dec. Date Extracted: 12-DEC-1990
Extraction: CSepF/Cont/Sonc) SoxH PH:
GPC Cleanup: (YIN) N
Concentration Uits
Number TICs found: 13 Cug/L or uglKg): _LtVg
ICAS NUM4BER COMPOUND NAME I RT IEST. CONC. 0
I1. 123-42-21 2-Pentanone. 4-hydroxy-4-methy
I2.- 25013-16-51 Phenot.(1.1-dimethylethyt)-4-M
I3. 1Unknown (Alkyl Hydrocarbon)
4. 1._____ Unknown (Alkyl Hyrocarbon)
I5. 17851-53-51 1.2-gemzenedicarboxylic acid b
I
5?.0I99-O
i o.45
19.43 I550I
N.60 ~
V.80__
; IJ
Ago0 I-~
0 IJ
6. Unknown (Hydrocarbon) 99
7 .______ Unknown (Hydrocarbon) I 25.90 I800 I .
I .jUnknown (sat'd Hyrocarbon) 264 ;Z JOl do
19. 1Iunknown I 27.681 1600 J
I10. Unknown (sat'd Hydrocarbon) e i3 I Jo
I11. Unknown (Hydrocarbon) I 30.54 I370 1
12. [Unknown (Aikyl Hydrocarbon) I 32.60 J410j
13. [Unknown (Alkyt Hydrocarbon) 1 33.461 1400[
14. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
115. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
116. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
17. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
~18. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
119. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _
j20.____ ___________1____
121. II____
122. II____
123.II_____I______ _
124. II____
125. 1_ _ _ _ 1 I
126. I. ____1_______
127. II____
128. I.
129. I.
130. I.
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number Is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
NO - Not detected.
A -Aldol condensation product.
0 - Secondary dilution.
E -Exceeds Initial calibration range.
P - Probable Identification. D-64

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 1
AnaLIS ID: 901206-033 Customer Sample ID: N-113
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: 07617 Sample Matrix: SOIL
Instrument 10: 597002 Reqiuisition Numb~er:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
VOA -Volatile Organic Compounds CTCL)
Date Extracted/Prepared: Date Analyzed: 11-DEC-1990
Preparation Procedure Numb~er: PURGE & TRAP Analysis Procedure Numb~er: VGA (CIP) HOP
Percent Moisture: 6 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: GL HUDOLESTON
Associated Blank: 901211-004 CA File Number: NA
E) : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
.......................... .......... ........... .............................. ..........
74-87-3 Chtoromethane 11t; 79-00-5 1,1,2-Trichloroethone 5U
74-83-9 Bromomethane 11U 71-43-2 Benzene SU
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1.3-Dichioropropene SU
75-00-3 Chloroethane IVU 75-25-2 Bromoform S1)
75-09-2 Methylene Chloride 5U 108-10-1 4-Methyt-2-pentanone Ilt
67-64-1 Acetone 32 LA 591-78-6 2-Hexanone 11U
75-15-0 Carbon Disulfide 5U 127-18-4 Tetrachtoroethene 5U
75-35-4 1,1-Dichloroethene SU 79-34-5 1.1,2,2-Tetrachtoroethane 5U
75-34-3 1.1-Dichtoroethane 5U 108-88-3 Toluene 5U
540-59-0 1,2-Dichioroethene (total) 5U 108-90-7 Chlorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 Ethylbcnzene 5U
107-06-2 1,2-Dichloroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1,1,1-Trichloroethane 51)
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate 11t;
75-27-4 Bromodichloromethane 5U
78-87-5 1.2-Dichioropropane 5U
10061-01-5 cis-1,3-Dichlaropropenc 5U
79-01-6 Trichloroethene 5U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The nuimber is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J9 - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - secondary dilution.
E - Exceeds initial calibration range.
D-65

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 2
AnaLIS ID: 901206-034. Customer Snmple ID: N-114
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite 10: 10663 Samp~le Matrix: SOIL
instrument 10: 5970#3 Requisition N~.uber:
Authorized By: 0. C. Canada Date Sample Received: 6-DEC-1990
DNA - Dase/Neutral/Acid Compounds (TCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 14.-DEC- 1990
Preparation Procedure Numiber: Analysis Procedure Numb~er: ORA (CLP) MOP
Percent Moisture: 3.3 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEEHAN
Associated Blank: 901213-028 CA File Number: NA
D : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
.................................. .......... ........... ............................... ..........
108-95-2 Phenol 8801. 106-4.7-8 4-Chioroanitine 881.
111-4.4-4. bis(2-Chloroethyl)ether 880U 87-68-3 Hexachtorobutadiene 880U
95-57-8 2-Chlorophenot soot) 59-50-7 4-Chloro-3-methylphenot 881.
54-73-1 1,3-Oichlorobenzene 880U 91-57-6 2-Methyinaphthatenve 880U
106-46-7 1,4-Dichiorobenzene SB0U 77-47-4 Nexachlorocyclopentadiene 880U
100-51-6 Benzyt Alcohol 880U 88-06-2 2,4,6-Trichlorophenot 880U
95-50-1 1,Z-Dichlorobenzene 881. 95-95-4 2.4,5-TrichLorophenot 4201.
95-48-7 2-Methylpienol 880U 91-58-7 2-Chloronsphthalene 880U
108-60-1 bisC2-Chloroisopropyt)ether Book) 88-74-4 2-Nitroaniline 420OU
106-44-5 4-Methylphenol 8801. 131-11-3 Dimethylphthalate 881.
621-64-7 N-Nitroso-di-n-propylemine 880U 208-96-8 Acenaphthylene 880U
67-72-1 Nexachloroethane 880U 99-09-2 3-Nitroaniline 4201.
98-95-3 Nitrobenzene 880U 83-32-9 Acenaphthene 880U
78-59-1 isophorone 8801. 51-28-5 2,4-Dinitrophenol 42001U
58-75-5 2-Nitrophenol 880U 100-02-7 4-Nitrophenol 4201U
105-67-9 2,4-ODimethytpIhenot 880U 132-64-9 Dibenzofuran 880U
65-85-0 Benzoic Acid 6W0 "e-19 LA 121-14-2 2,4-Dinitrotoluene 88OU
111-91-1 bisC2-Chloroethoxy)methane 8U 606-20-2 2.6-Dinitrototuone 88OU
120-83-2 2.4-Dichlorophenot 880U 84-66-2 iethylphthelate Sao-aqe-W~ L4A
120-82-1 1,2,4-Trichiorobenzene 880U 7005-72-3 4-Chlorophenyt-phenylether 881.
91-20-3 Naphthalene 881. 86-73-7 Fluorene 880U.
Data Reporting Oualiffiers:
U -Compound waas analyzed for but not detected. The numb~er is the attainable detection limit for the sample.
B -Analyte was found in the reagent blank as waelt as the sample.
J -Indicates an estimated value.
ND -Not detected.
A -Aldol condensation product.
D -Secondary dilution.
E -Exceeds initial calibration range.
D -66

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLiS ID: 901206-034 Customer Sample ID: N-114
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: 10663 Sample Matrix: SOIL
Instrument ID: 597083 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
BRA - Base/Neutral/Acid Compounds (TEL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 14-DEC-IM9
Preparation Procedure Numbr: Analysis Procedure Number: DNA (CLP) NOP
Percent Moisture: 3.3 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEENAN
Associated Blank: 901213-028 QA File Number: NA
[] : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
100-01-6 I-NitroaniLine 4200U 53-70-3 .Dibenz(a~h)anthracene 88OU
534-52-1 4,6-Dinitro-2-methylphenot 420OU 191-24-2 Denzo~g,h.i)perylene 88OU
86-30-6 N-Nitrosodiphenylamine 880U
101-55-3 4-oramopiheny-phenytether 881.
118-74-1 Nexachlorobenzene 881.
87-86-5 Pentachlorophenol 4200U
85-01-8 Phenanthrene 881.
120-12-7 Anthracene BBOU
84-74-2 0i-n-buitylphthalate 2900-5, l.A
206-44.-0 Fluoranthene 880U
129-00-0 Pyrene 881.
85-68-7 Dutyibenzylphthalate 88OU
91-94-1 3,3'-Dichlorobenzidine 1800U
56-55-3 Benzo(a)anthracene 881.
117-81-7 bis(2-Ethylhexyt)plithalate -250il% 880 LA,
218-01-9 Chrysene 880U
117-84-0 Di-n-octylphthalate 88OU
205-99-2 genzo(b)fluorenthene 880U
207-08-9 Denzo(k)fluoranthene 881.
50-32-8 Renzo(a)pyrene 881.
193-39-5 Indeno(1,2,3-cd)pyrene S80U
Data Reporting Qualifiers:
U -Compound was analyzed for but not detected. The number Is the attainable detection limit for the sampLe.
* Analyte was found in the reagent blank as well as the sample.
J1 Indicates an estimated value.
NDO Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D -67

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
SNA CTCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPUNDS
AnaLIS ID: 901206-034 Customer Smple I0: N-114
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Sape Matrix: SOIL File I0: 10663
Level: (low/med): LO Date Received: 6-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 14-DEC-1990
% Moisture: not dec. 3.3 dec. _____Date Extracted: 12wDECw1990
Extraction: CSepFIContISonc) SoxH PH: ____
PC Cleanup: (YIN) N
Concentration Units
Number TICs foun~d: 14. CugIL or uglKg): _ug/~
ICAS NUMBER ICOMPOUND NAME R T EST. CONC. 0
I1. 123-4.2-21 2-Pentanone, 4-hydroxy-4-methy
I2. 872-50-41 2-Pyrrotidinone, 1-methyt-
I3. 25013-16-51_Phenol.(l.1-dimethylethyt)-4-m
I4. 17851-53-51 1.2-genzenedicarboxylic acid.b
I
I
5 .9i
9.&1-
46r
el.29
AW0 0 09
-O 4" §,
"0. is~Qj
52 0% .
I5.
I6.
IUnknown (sat'd Hydrocarbon)
Lunknown 1
-2-6 I7dOj~
21.931
39
3701 /7
a . jUnknown (Alkyl Hydrocarbon) 1r [3.7 )IJ1
I9. Unknown (sat'd Hydrocarbon) 29.9970I
10. junknown 1 25.96 I620 1 J
I11.
12z.
13.
jUnknown (sat'd Hydrocarbon)
lUnknown
IUnknown (Atkyl Hydrocarbon)
.1
I
3.efI3-
27.68j
. ;;
- IJO&
2800 j
400 j-d
114. Iunknown I 33.741 6101 J
116. II
119. III
120. I_ _ _ _ _ _ _ _ _ _ _
121. I_ _ _ _ _ _ _ _ _ _ _ _ _ _ _I_ _ _ _ _ _
122. __ _ _ _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _ 1 _ _
123. 1_ _ _ _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _ _ _
124. 1_ _ _ _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _ _ _
125.1__ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _ _1_ _ _ _ _1_ _ _ I
126.1__ _ _ _ _ _ _ _ _ _ _ 1 _ _ _ _1_ _ _ _ 1 _ _ I
127. 1_ _ _ _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _ _ _
128. 1- ____I____ __
129. 1_ _ _ _ _ _ _ _ _ _ _ _ _ _ _I_ _ _ _ _ _
130.j I I
Data Reporting Qualifiers:
U Compound waas analyzed for but not detected. The number is the attainable detection limit for the sample.
B -Analyte was founrd In the reagent blank as well as the sample.
J -Indicates an estimated value.
NO -Not detected.
A Aldol condensation product.
D -Secondary dilution.
E Exceeds initial calibration range.
P -Probable Identification. D-68

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 1
AnaLtS ID: 901206-034 Customer Sample ID: M-114.
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: 07618 Sample Matrix: SOIL
Instrumnent ID: 597052 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
VGA -Volatile Organic Compounds (TCL)
Date Extracted/Prepared: Date Analyzed: 11-DEC-1990
Preparation Procedure Numiber: PURGE & TRAP Analysis Procedure Number: VOA CCLP) NOP
Percent Moisture: S Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: GL HUDDLESTON
Associated Blank: 901211-004 QA File Number: NA
El : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
74-87-3 Chloromethane 11U 79-00-S 1,1.Z-Trichtoroethane 5U
74-83-9 Bromomethane 11U 71-43-2 Benzene 5U
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1.3-Dichloropropene SU
75-00-3 Chloroethane 11U 75-25-2 Bromoform SU
75-09-2 Methylene Chloride 5U 108-10-1 4-Methyl-2-pentenone 11U
67-61 Acetone 12 L.A 591-78-6 2-Hexanone 11U
75-15-0 Carbon Disulfide 5U 127-18-4 Tetrachtoroethene 5U
75-35-4 1,1-Dichloroethene 5U 79-34-5 1.1.2,2-Tetrachloroethane 5U
75-34-3 1*1-Dichtoroethane 5U 108-88-3 Toluene 5U
540-59-0 1,2-Dichloroethene (total) 5U 108-90-7 Chlorobenzene SU
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5U
107-06-2 1,2-DichLoroethane 5U 100-42-S Styrene 5U
78-93-3 2-Dutanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1,1,1-Trlchloroethane 5U
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate 11U
75-27-4 Bromodichtoromethane 5U
78-87-5 1,2-Dichioropropane SU
10061-01-5 cis-1,3-Dichloropropene 5U
79-01-6 Trichtoroethene 5U
124-48-1 Dibromochtoromethane 5U
Data Reporting Qualifiers: 1
U -Compound was analyzed for but not detected. The number Is the attainable detection limit for the sample.
* - Analyte was found in the reagent blank as well as the sample.
J5 - Indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D -69

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORtT Page I of 2
AnaLIS ID: 901206-035 Customer Sample ID: N6-115
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File 10: 10664 Sample Matrix: SOIL
Instrum~ent 10: 597003 Requisition Numb~er:
Authorized By: D. C. Canada Date Sample Received: 6-DEC- 1990
BRA - Uase/Neutral/Acid Comrpounds CTCL)
Date Extracted/Prepared: 12-DEC-1990 Date Analyzed: 14-DEC-1990
Preparation Procedure Number: Analysis Procedure Number: BRA (CLP) MOP
Percent Moisture: 4.8 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C HEENAN
Associated Blank: 901213-028 OA File Number: NA
El : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
108-95-2 Phenol 90OU 106-47-8 4-Chloroaniline 9001U
111-44-4 bis(Z-Chloroethyl)ether 900u 87-68-3 Hexachtorobtadiene 900U
95-57-8 2-Chtorophenot 90OU 59-50-7 4-Chloro-3-methylphenol 900U
541-73-1 1,3-Dichlorobenzene 90OU 91-57-6 2-Methylnaphthateme 90OU
106-46-7 1,4-Oichtorobenzene 90OU 77-47-4 Hexachlorocyclopentadiene 900U
100-51-6 Benzyl Alcohol 900yU 88-06-2 2,4,6-Trichlorophenot 90WU
95-50-1 1,2-Dichlorobenzene 90OU 95-95-4 2,4,5-Trichtorophenol 4306U
95-48-7 2-Methylphenot 900(1 91-58-7 .2-Chloronaphthalene 900U
108-60-1 bis(Z-Chtoroisopropyt)ether 900(1 88-74-4 2-Nitroanitine 4300(U
106-44-5 4-Methylphenol 900U1 131-11-3 Dimethylphthoate 900(1
621-64-7 N-Mitroso-di-n-propylamine 900(1 208-96-8 Acenaphthytene 900(1
67-72-1 Nexachtoroethane 900(1 99-09-2 3-Mitroanitine 4300(1
98-95-3 Nitrobenzene 900( 83-32-9 Acenaphthene 9001
78-59-1 Isophorone 900(1 51-28-5 2,4-Dinitrophenol 4300(U
88-75-5 2-Nitrophenol 900(1 100-02-7 4-Nitrophenol 4300(U
105-67-9 2,4-Dimethylphenot 9001 132-64-9 Dibenzofuran 900(1
65-85-0 Genzoic Acid C)60 RjO- G-IV 121-14-2 2,4-Dinitrotoluene 900(1
111-91-1 bisC2-Chkoroethoxy)methane 900(h 606-20-2 2,6-Dinitrototuene 900(1
120-53-2 2,4-Dichtorophenol 900(1 84-66-2 Diethylphthalate qOo T"t-je- LA
120-82-1 1,2,4-TrIchLorobenzene 900(1 7005-72-3 4-Chtorophenyl-phenylether 900U
91-20-3 Naphthalene 9001J 86-73-7 Fluorene 900U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection Limit for the sample.
B - Analyte was found In the reagent blank as well as the sample.
J1 - Indicates an estimated value.
RD - Not detected.
A - Aldol condensation product.
D - Secondary dilution.7
E - Exceeds initial calibration range. 6q
D-70

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLlS 10: 901206-035 Customer Saple ID: N-115
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J1. KESSNER/R. SHUCK
File I0: 10664 Sairple Matrix: SOIL
Instrument ID: 597093 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
DMA -*ase/Neutral/Acid Compoun~ds CTCL)
Date Extracted/Prepared: 1Z-DEC-1990 Date Analyzed: 14-DEC-1990
Preparation Procedure Mumb~er: Analysis Procedure Nuber: DNA CCLP) MOP
Percent Moisture: 4.8 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: C MEEHAN
Associated Slank: 901213-028 QA File Number: MA
El : Result has been Corrected for Spike
CAS ug/Kg CAS uglKg
100-01-6 4-Mitroaniline 430OU 53-70-3 Dibenz(a,h)anthracene 900U
534-52-1 4,6-Oinitro-2-methyiphenot 430OU 191-24-2 Benzo(g~h~i)perylen 90OU
86-30-6 -Mitrosodiphenytamine 90OU
101-55-3 4-Bromopheny-phenylether 90OU
118-74-1 exachLorobenzene 900U
87-86-5 Pentachlorophenol 430OU
85-01-8 Phenanthrene 9001.
120-12-7 Anthracene 900U
84-71.-2 Di-n-butylphthaLate 17001..
206-44-0 FLuoranthene 90OU
129-00-0 Pyrene 9001.
85-68-7 Butylbenzylphthalate 900U
91-94-1 3,31-Dichtorobenzidine 180OU
56-55-3 genzo(a)anthraeene 90OU
117-81-7 bis(2-Ethythexyl)plithatate V69 d- c)00 LA
218-01-9 Chrysene 900U
W1-84-0 Di-n-octylphthalate 90OU
205-99-2 Benzo(b)fluoranthene 901.
207-08-9 Benzo~k)fluoranthene 900U
50-32-8 Benzo(a)pyrene 90OU6 '
193-39-5 indeno(1.2.3-cd)pyrene
Data Reporting Qualifiers:qI
900U 61
u -compound was analyzed for but not detected. The number Is the attainable detection Limit for the sample.
* Analyte was found in the reagent blank as well as the sample.
.3 -Indicates an estimated value.
RD -Not detected.
A -Aldol condensation product.
0 -Secondary dilution.
E -Exceeds initial calibration range.
D-71

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
lilA (CL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS I0: 9"1206-035 Customer Sample 10: N1-115
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Sample Matrix: SOIL Fite 1D: 10664
Level: Clow/med): LOW Date Received: 6-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 14-DEC-1990
% moisture: not dec. - 4.8 dec. _____Date Extracted: 12-DEC-1990
Extraction: (SepF/Cont/Sonc) Soxl pM: ___
GPC Cleanup: (T/N) N
Concentration Units
Number TICs found: 14. (ugIL or ug/Kg): _uU
ICAS NUMBER ICOMPOUND NAME
I 332sg~zzU3Uu j 322:uz~~uuzm
I1. 123-42-21 2-Pentanone, 4-hydroxy-4-methy
I2. 872-50-41 2-Pyrrolidinone, 1-methyl-
3. 1 unknown
I4. 25013-16-51 Phenol,(l.1-dimethytethyl)-.-m
AT EST. CONC. j
I ax2azza2zu22 .zZ: W=j =ZZmZ
I .9; I 270-09 -
9 .00 I tip 1 j
12.521 600 J
q 6-5..It~I~
I5. Unknown (Alkyt Hydrocarbon) j l... I40
6. IUnknown (Alkyl Hydrocarbon) 23 n ~ *4 d!
I zuuum*zu
I7. Iunknown (sat'd Hydrocarbon)
I8.- 17851-53-51 1.2-Benzenedicarboxytic acid.b
I9. 123-79-51 Dioctyl Adipate
10. IUnknown (sat'd Hydrocarbon)
I56
j 25.97 1570
j 26.38 I1600
I 6.'f
I
IJ
78I
-1" / / q I
11.
I12.
13.
IUnknown
IUnknown (Alkyl Hydrocarbon)
IUnknown (sated Hydrocarbon)
j 27.79 I1700I
-20.4E I -7O I JO
32.59 390 4____
114.
115.
IUnknown j
I__ _
33.73j
_ _ i__ _ _
380
_ _I_ _ _
J16.II__
117.I __
_
_
_
_
_
_
__
__
_
_
_ _
_ _
_I_
_I_
_
_
_
_ I
18.
119. II_
_______I_______I___
_ _ _ _ _ _ _ _ _I_ _
_
_
120. II_ _ _ _ _ _ _ _ _ _I_ _ _
21. II_ _ _ _ _ _ _ _ _ _I_ _ _
122. II_____ _____ ___
123.II__ _ _ _ __ _ _ _ _I_ _ _ I
124.IIJI
125.I III
126.I II
127.II I
128. I I
129. I II
130. I II
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection Limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
D -Secondary dilution.
E - Exceeds initial calibration range.
P - Probable identification. D-72

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of I
AnaLIS ID: 901206-035 Customer Sample 10: N-115
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSMER/R. SHUCK
File ID: 07619 Sample Matrix: SOIL
Instrum~ent 10: 59702 Requisition Number:
Authorized By: 0. C. Canada Date Samiple Received: 6-DEC- 1990
VOA -Volatile organic Comp~ounds CTCL)
Date Extracted/Prepared: Date Analyzed: 1-DEC-1990
Preparation Procedure Number: PURGE & TRAP Analysis Procedure Numb'~er: VGA (CLP) MOP
Percent Moisture: 5 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: GL HUDOLESTON
Associated Blank: 901211-004 @A File Nmiaber: MA
11 : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
............................... .......... ........... .............................. ..........
74-87-3 Chloromethane 11U 79-00-5 1,1.2-Trichloroethene 5U
74-83-9 Bromomethane 11U 71-43-2 Benzene 5U
75-01-4 Vinyl Chloride 111U 10061-02-6 trans-1.3-Oichloropropene SU
75-00-3 Chloroethane 11U 75-25-2 Iromoform 5U
75-09-2 Methylene, Chloride 511 108-10-1 4-Methyl-2-pentenone 11U
67-64-1 Acetone 34 LA 591-78-6 2-Hexanone 111)
75-15-0 Carbon Disulfide 5U 127-18-4 Tetrachloroethene 5U
75-35-4 1.1-Dichloroethene SU 79-34-5 1,1,.2-Tetrachioroethane 5U
75-34-3 1,1-Dichloroethane 5U 108-08-3 Toluene 5U
540-59-0 1.2-Dichioroethene (total) 5U 108-90-7 Chlorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 Ethylbenzeie 5U
107-06-2 1,2-Dichtoroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Butanone 1IU 1330-20-7 Xylene (total) SU
71-55-6 1,1,1-Trichtoroethane 5U
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate 11UJ
75-27-4 Uromodichloromethane 5U
78-87-5 1,2-Dichtoropropane 5U
10061-01-S cis-1,3-Dichloropropene 5U
79-01-6 Trichloroethene 5U
124-48-1 Dibromochloromethane 51)( 4
Data Reporting Qualifiers:
U - compound was analyzed for but not detected. The ntumber is the attainable detection limit for the sample.
8* Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-73

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 2
AnaLlS ID: 901206-036 Customer Sample ID: M-116
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSMER/R. SNUCK
File ID: 304465 Sample Matrix: SOIL
Instrument ID: HP-5985 Requisition Numb~der:
Authorized By: D. C. Canada Date Sample Received: 5-DEC-1990
BHA - Base/Neutral/Acid Comp~ounds (TCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 2-JAM-1991
Preparation Procedure Nuber: Analysis Procedure Number: BNA (CLP) MOP
Percent Moisture: 6.3 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Blank: 901214-083 CA File Nu.mber: MA
U:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
108-95-2 Phenol ft 9901) 106-47-8 4-Chloroanitine ft 99011
111-44-4 bis(2-Chloroethyt)ether ft 9901) 87-68-3 Nexachlorobutadiene ft 9901)
95-57-8 2-Chtorophenot ft 9901) 59-50-7 4-Chloro-3-methylphenot ft 9901)
541-73-1 1,3-Dichtorobenzene R 9901) 91-57-6 2-MethylnaphthaLene Rt 9901)
106-46-7 1,4-Dichlorobenzene R 9901) 77-47-4 Hexachlorocyclo pen tadiene R 99011
100-51-6 Benzyl Alcohol ft 9901) 88-06-2 2,4,6-Trichtorophenot R 9901)
95-50-1 i,2-Dichlorobenzene ft 9901) 95-95-4 2,4,5-TrichLorophenol R 48001)
95-48-7 2-Methytphenol R 9901) 91-58-7 2-Chtoronaphthatene R 9901
108-60-1 bis(2-ChLoroisopropyt)ether R 9901) 58-74-4 2-Nitroaniline ft 480011
106-441-5 4-Methylphenot ft 9901) 131-11-3 Dimethylphthalate ft 9901)
621-64-7 N-mitroso-di-n-propyiamine R 9901) 208-96-8 Acenaphthylene ft 9901)
67-72-1 Hexachtoroethane R 9901) 99-09-2 3-Nitroaniline R 48001)
98-95-3 Mitrobenzene R 991. 83-32-9 Acenaphthene, R 991.
78-59-1 Isophorone R 991. 51-28-5 2,4-Dinitrophenol Rt 480011
88-75-S 2-Nitrophenol ft 9901) 100-02-7 4-Nitrophenol ft 4801U
105-67-9 2.4-Di 'methylphenot Rt 9901) 132-64-9 Dibenzofuran Rt 99011
65-85-0 Benzoic Acid ft 48001) 121-14-2 2,4-Dinitrotoluene R 99011
111-91-1 bisC2-Chloroethoxy)methane R 9901) 606-20-2 2,6-Dinitrotoluene ft 9901
120-83-2 2,4-Dichlorophenol ft 9901) 84-66-2 Diethylphthatate ft 9901
120-82-1 1,2,4-Trichtorobenzene R 9901) 7005-72-3 4-Chlorophenyl-phenytether Rt 99011
91-20-3 Naphthalene ft 9901) 86-73-7 Fluorene ft 9901
Data Reporting Qualifiers:
U - Comrpound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the saple.
J3 - Indicates an estimated value.
RD - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D- 74

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLIS ID: 901206-036 Customer Sample ID: N-116
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite ID: 314465 Sample Matrix: SOIL
Instrument ID: RP-5985 Rtequisition Number:
Authorized By: 0. C. Canada Date Sample Received: 5-DEC-1990
DNA - Base/Neutral/Acid Compounds (TCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 2-JAN-1991
Preparation Procedure Nuber: Analysis Procedure Number: 3INA (CLP) NOP
Percent Moisture: 6.3 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Blank: 901214-083 GA Fite Number: NA
11:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
.......................... .......... ........... .............................. ..........
100-01-6 4-Nitroaniline ft 4800U 53-70-3 Dibenz~a,h)anthracene ft 990U
534-52-1 4.6-Dinitro-2-methylphenot ft 480OU 191-24-2 Benzo(g~h,i)perylene R 990U
86-30-6 N-itrosodfphenylamine ft 990U
101-55-3 4-Bromophenyl-phenylether ft 990U
118-74-1 Hexachlorobenzene ft 990U
87-86-5 PentachlorophenoL ft 4800U
85-01-8 Phenanthrene ft 990U
120-12-7 Anthracene Rt 990U
84-74-2 Di-n-butylphthaLate 2900-1, Lk.
206-44-0 Fluoranthene ft 99OU
129-00-0 Pyrene ft 990U
85-68-7 Butylbenzylphthalate Rt 99OU
91-94-1 3,3'-Dichlorobenzidine Rt 2100U
56-55-3 Benzo~aanthracene ft 990U
117-81-7 bisC2-Ethythexyl)phthalate R 990U
218-01-9 Chr-ysene ft 990U
117-84-0 Di-neoctylphthalate ft 990U
205-99-2 Benzo(b)fluoranthene ft 990U
207-08-9 Benzo(k)fLuoranthene ft 990U
50-32-8 Benzo(a)pyrene ft 99U
193-39-5 Indeno(1,2,3-cd)pyrene ft 99OU
Data Reporting Qualifiers:
U -Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
8 Analyte was found in the reagent blank as well as the sample.
.1 -indicates an estimated value.
ND -Not detected.
A -Aldol condensation product.
D Secondary dilution.
E -Exceeds initial calibration range.
D-75

WIIC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
BNA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLlS ID: 901206-036 Customer Sample ID: N-116
Laboratory: organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Sample Matrix: SOIL File ID: )14465
Level: (lowlmed): LOW Date Received: 5-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 2-JAN-1991
% Moisture: not dec. - 6.3 dec. Date Extracted: 13-DEC-1990
Extraction: (SepF/Cont/Sonc) SoxH PH:
GPC Cleanup: (TIN) N
Concentration Units
Numb~er TICs found: 18 (ugIL or uglKg): u K
CAS NUMBER ICOMPOUND NAME RT IEST. CONC. a
~ 222222322222222222222Z222:3222 222222222: j 2222232222223 I322222222
I1. 123-42-21 2-Pentanone. 4-hydroxy-4-methy j.6 "'QQl 3 1 .A:1
2.
I3.
4.
I5.
I6.
I7.
I8.
I9.
I10.
1 UNKNOWN
jUNKNOWN ALCOHOL
jUNKNOWN ALCOHOL
jUNKNOWN
UNKNOWN
j.UNKNOWN HYrDROCARBON
UNKNOWN HYDROCARBON
jUNKNOWN PHTHALATE ESTER
jUNKNOWN
j 6.061
J.36
I 1).00I
1F.48L~
2 O.94
23Mi~uI
R.9
j 1. 0 I
1 24.841
420 1j
6to do~
Ju~
IJ
8900 o
1 IJ
We
01J
8401
.1
I11. UNKNOWN HYDRICARUON s.1ig goo~e
12.
13.
UNKNOWN HYDROCARBON
jUNKNOWN HYDROCARBON j
2 6. 5OI 6
27.5n I 1fpl 10
14 UNKNOWN HYDROCARBON j80 o~Iad~r
15. UNKNOWN HYDROCARBON 298 I me . a50I
16. UNKNOWN HYDROCARBON 401!? 1 ! 220 I
17. jUNKNOWN ALKOXY COMPOUJND j 1 .i
18. UNKNOWN HYDROCARBON 31.3 I (0i .e
119.
120.1__
121.
1_ _ _ _ _ _ _
_ _ _ _ _ _
1_ _ _ _ _ _ _ _
_
_
_
_
_
_
_
_
_
_ _
1__ _
_ _
_ _ _
_ 1__ _
_ _1_ _ _
_
_
_
_
__
_
_
_
_
I
122.
123.1__
124.1__
1_ _
_
_
_
_ _
_ _
_
_
_
_
_
_
_
_ _
_ _
_
_
_
_1_ _
_ 1__ _
_ 1__ _
_ _ _
_ _1_ _ _
_ 1__ _
_1_ _
_ 1__ _
_ 1__ _
I
25.__ _ _ _ _ _ _ _ _ _ 1__ _ _ _1_ _ _ _ 1__ _
126.1__ _ _ _ _ _ _ _ _ _ 1__ _ _ 1__ _ _ 1__ _
127.1 I I
128.I I
129. I
130. I
Data Reporting Qualifiers:
U - Compound wos analyzed for but not detected. The numb~er Is the attainable detection limit for the sample.
B - Analyte wias
found in the reagent blank as well as the sample.
J1 - Indicates an estimated value.
NO -Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
P-Probable identification. D-76

WHIC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 1
nLIS ID: 901206-036 Customer Samle ID: N-116
Laboratory: Organic 1Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: 07586 Sample Matrix: SOIL
Instrument ID: 597002 Requisition Number:
Authorized By: D. C. Canada Date Sampte Received: 5-DEC-IM9
VDA -Volatile organic Compounds (TCI.)
Date Extracted/Prepared: Date Analyzed: 10-DEC- 1990
Preparation Procedure Number: PURGE & TRAP Analysis Procedure Nuumber: VOA (CLP) NOP
Percent Moisture: 6 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: SL STAFFORD
Associated Blank: 901210-025 CA File Number: NA
U:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
74-87-3 Chloromethane 11U 79-00-5 1.2-Trichtoroethane SU
71.-83-9 Bromomethane 11U 71-43-2 Benzene SU
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1,3-Dichloropropene 5U
75-00-3 Chloroethane 11U 75-25-2 Breonoform SU
75-09-2 Methylene Chloride 3 d-9' LA, 108-10-1 4-Methyl-2-pentanone 11U
67-64-1 Acetone 11u 591-75-6 2-Hexanone 11u
75-15-0 Carbon Disulfide 5U 127-18-4 Tetrachloroethene 5U
75-35-4 1,1-Dichloroethene SU 79-34-5 1,1,2,2-Tetrachioroethane 5U
75-34-3 1,1-Dichtoroethane 5U 108-88-3 Toluene 5U
540-59-0 1,2-Dichtoroethene (total) 5U 108-90-7 Chlorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5U
107-06-2 1,2-Dichloroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1,1.1-Trichtoroethane 5U
56-23-S Carbon Tetrachloride 5U
108-05-4 Vinyl. Acetate 11U
75-27-4 Bromodichloromethane SU
78-87-5 1,2-Dichloropropane 5U
10061-01-5 cis-1.3-Dichloropropene 5U
79-01-6 Trichioroethene 5U
124-48-1 Dibromochloromethane 5U
CotmRpoutn Qaualyziedrosu:o eece. Tent~r steatial
Dat Repotng waualies: o dtce.Te ubri heatial detection limit for the sample.
B Analyte was found in the reagent blank as well as the sample.
J -Indicates an estimated value.
RD -Not detected.
A -Aldol condensation product.
D -Secondary dilution.
E -Exceeds initial calibration range.
D-77

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
VGA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS ID: 901206-036 Customer Sample ID: N-116
Laboratory: organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUJCK
Samrple Matrix: SOIL Fite ID: 07556
Level: Clow/med): LOW Date Received: 5-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 10-DEC-1990
% Moisture: not dec. 6
Concentration Units
Number TICs found: I (ug/L or ug/Kg): u K2
ICAS NUMBER I COMPOUND NAME I RT EST. CONC. I a
I1. 76-13-11 Freon 113 5.48 ' 64 Io
12.I II
13. IIJ__
15. IIIj__
16. III__
19. IIII__
112.I L___I
113. IIIL_ _ _
115. IIII_ _ _
116. II_ _ _
17.
118.
III_
III_
_
_
_
_
19. III
120.I
121.IIII
I 22.III
III
123.I III
124.
I 25.III
III
I
126. III
127. III
128.III
129.II
130.IIII
I
Data Reporting Qualifiers:
U -Compound was analyzed for but not detected. The number is the attainable detection limit for the samvple.
8B Analyte was found in the reagent blank as well as the sample.
J-Indicates an estimated value.
NOD Not detected.
A -Aldol condensation product.
D - Secondary dilution.
E - Exceeds Initial calibration range.
P -Probable Identification.
D -78

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 2
AnaLIS ID: 901206-037 Customer Sauple ID: N-117
Laboratory: organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: 3,14466 Sample Matrix: SOIL
Instrument ID: NP-5985 Requisition Number:
Authorized Dy: D. C. Canada Date Sample Received: 5-DEC-1990
DNA D ase/Neutral/Acid Compounds (TCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 2-JAN-1991
Preparation Procedure Number: Analysis Procedure Nurter: DNA (CLP) HOP
Percent Moisture: 6.5 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK NEADRICK
Associated Dlank: 901214-083 GA File Number: NA
12:Result has been Corrected for Spike
CAS ug/Kg CAS uglKg
108-95-2 Phenol ft 990U 106-47-8 4-Chioroaniline ft 990U
111-44-4 bis(2-ChtoroethyL)ether ft 99OU 87-68-3 Nexachlorobuitadiene ft 990U
95-57-8 2-Chtorophenol ft 990U 59-50-7 4-Chloro-3-methylphenol ft 99OU
541-73-1 1,3-Dichlorobenzene ft 990U 91-57-6 2-Methyinaphthaene ft 990U
106-46-7 1.4-Dichlorobenzene ft 99OU 77-47-4 Nexachtorocyclopentadiene ft 99DU
100-51-6 Denzyl Alcohol ft 99DU 88-06-2 2,I.,6-Trichlorophenot ft 990U
95-50-1 1,2-Dichlorobenzene ft 990U 95-95-4 2.,5-Trichlorophenol ft 4800U
95-48-7 2-Methylphenol ft 990U 91-58-7 2-Chtoronaphthatene ft 99OU
108-60-1 bis(2-Chloroisopropyt)ether ft 991. 88-74-4 2-Nitroanillne ft 4800U
106-44-5 4-Methytphenot ft 990U 131-11-3 Dimethylpihthatate ft 99OU
621-64-7 N-Nitroso-di-n-propylemine ft 9901) 208-96-8 Acenaphthylene ft 990U
67-72-1 Hexachloroethane ft 991. 99-09-2 3-Nitroaniline ft 4800U
98-95-3 Nitrobenzene ft 99OU 83-32-9 Acenaphthene ft 99OU
78-59-1 Isophorone ft 990U 51-28-5 2,4-Dinltrophenot ft 4800U
88-75-5 2-Nitrophenol ft 990U 100-02-7 4NMitrophenot ft 4801.
105-67-9 2,4-Oimethylphenot ft 990U 132-64-9 Dibenzofuran ft 990U
65-85-0 Denzoic Acid ft 4800Ui 121-14-2 2,4-Dinitrotoluene ft 990U
111-91-1 bis(2-Chtoroethoxy)methane ft 9901. 606-20-2 2,6-Dinitrotouene R 99DU
120-83-2 2,4-Dichlorophenot ft 990U 84-66-2 Diethylphthalate ft 9901]
120-82-1 1.2,4-Trichtorobenzene ft 991. 7005-72-3 4-Chloroplhenyt-phenytether ft 990U
91-20-3 Naphthalene ft 99OU 86-73-7 Fluorene ft 9901.
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection Limit for the sample.
0 Analyte was foundJ In the reagent blank as well as the sample.
J9 - Indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
D Secondary dilution.
E - Exceeds Initial calibration range.
D-79

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page Z of 2
AnaLIS ID: 901206-037 Customer Samrple ID: N-117
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: )-14466 Sample Matrix: SOIL
Instrument ID: HP-5985 Requisition Number:
Authorized By: 0. C. Canada Date Samrple Received: 5-DEC-1990
BRA - lass/Neutral/Acid Compounids (TCL)
Date Extracted/Prepared: 13-DEC- 1990 Date Analyzed: 2-JAN-1991
Preparation Procedure Nuber: Analysis Procedure Number: SNA (CLP) MOP
Percent Moisture: 6.5 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AX KEADRICK
Associated Blank: 901214-083 CA File Number. NA
[3 Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
100-01-6 4-Nltroanitine Rt 4800Ui 53-70-3 Dibenz~a,h)anthracene ft 990U
534-52-1 4,6-Dinitro-2-methylphenot Rt 4800U 191-24-2 Benzo(g~hi)peryLene R 990U
86-30-6 N-itrosodiphenylaenine R 990t.1
101-55-3 4-Bromophenyt-pihenylether ft 99OU
118-74-1 Nexachlorobenzene ft 990U
87-86-5 Pentachlorophenot ft 4800U
85-01-8 Phenanthrene ft 990Ui
120-12-7 Anthracene Rt 990U)
84-74-2 Di-n-butylpihthaLate 1400-S, LA
206-44-0 Fluoranthene R 990U
129-00-0 Pyrene Rt 990U
85-68-7 *utylbenzylphthalate ft 990U
91-94-1 3,3'-Dichtorobenzidine ft 2001U
56-55-3 *enzo(a)anthrcrie R 991.
117-81-7 bisC2-Ethylhexyi)phthalate ft 990U.
218-01-9 Chrysene ft 9901J
117-84-0 Di-n-octylphthalate ft 990U
205-99-2 Benzo(b)fluoranthene Rt 99OU
207-08-9 genzo~k)fluoranthene ft 991.
50-32-8 Benzo(a)pyrene ft 990U
193-39-5 Indeno(1*2,3-cd)pyrene Rt 990U
Data Reporting Qualifiers:
U -Compound was analyzed for but not detected. The numbier is the attainable detection limit for the sample.
0 Analyte was found in the reagent blank as well as the samiple.
J1 - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-80

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
SNA CTCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUND S
AnaLlS 10: 901206-037 Customer Samvple ID: N-117
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Samp~le Matrix: SOIL File ID: ),14466
Level: Clow/med): LOW Date Received: 5-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 2-JAN-1991
% Moisture: not dec. .6.5 dec. _____Date Extracted: 13-DEC-1990
Extraction: (SepF/ContlSonc) SoxH PH:
GPC Cleanup: (YIN) N
Concentration Units
Number TiCs foun~d: 18 Cug/L or ug/Kg): _uLK
CAS NUMBER ICOMPOUND NAME RT EST. CONC. a
I1.
I2.
I3.
123-42-21 2-Pentenone. 4-hydroxy-4-methy
1UNKNOWN
1 UNKNOWN ALCOHOL
j ;0
60
6.i :9
3
iO
Ii90-
4. 1._____ UNKNOWN ALCOHOL ;39 2899 1 d o
I5. 1 UNKNOWN -3
6.
I7.
1 UNKNOWN
1UNKNOWN HYDROCARBON
;99 2OV9
*15)7
500I w
T9 J3
I8. jUNKNOWN HYDROCARBON J 23.92 44 I~ "9
I9.
10.
jUNKNOWN PHTHALATE ESTER
jUNKNOWN HYDROCARBON 1
;4.4
24.a7 I750
/,a I' J"
I 1
I11.
I12.
I13.
I14.
I15.
I16.
jUNKNOWN HYDROCARBON
JUNKNOWN HYDROCARBON
jUNKNOWN HYDROCARBON
JUNKNOWN HYDROCARBONJ
£UNKNOWN HYDROCARBON
£UNKNOWN HYDROCARBON
j
I
j
j
j
6.2 3I!!
2.
0'I
V.83 I
)0.09 I"
FI70 .19-
0
'OIO
o~
I.odO
I
17. jUNKNOWN ALKOXY COMPOUND 5!0 10 4eg 0 -;
la.
119. ____
120.1I
121. ____
jUNKNOWN HYDROCARBON I !1.90 1200 I a
122.1
123.1II
III
I
124. III
125.1I II
126.1I I
128.1- I
129. .
~30. I I
Data Reporting Qualifiers:
U - Comvpound was analyzed for but not detected. The number is the attainable detection limit for the sample.
8 - Anolyte was founid in the reagent blank as well as the saple.
J -Indicates an estimated value.
NOD Not detected.
A - Aldol condensation product.
0 - Secondary dilution.
E -Exceeds initial calibration range.
P - Probable Identification.
D-81

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 1
AaLlS I0: 901206-037 Customer Sample ID: N-117
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite ID: 07587 Samople Matrix: SOIL
Instrument ID: 597052 Requisition Numb~er:
Authorized By: D. C. Canada Date Sample Received: 5-DEC-1990
VGA -Volatile Organic Compounds (TCL)
Date Extracted/Prepared: Date Analyzed: 10-DEC-1990
Preparation Procedure Numb~er: PURGE & TRAP Analysis Procedure Nuiber: VOA (CLP) MOP
Percent Moisture: 7 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: St. STAFFORD
Associated Blank: 90210-O25 QA File Number: NA
C):Result has been Corrected for Spike
CAS ug/Kg - CAS ug/Kg
71.-87-3 Chioromethane 11U 79-00-5 1,1,2-Trichtoroethane 5U
74-83-9 Bromomethane 11U 71-43-2 Benzene 5U
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1.3-Dichtoropropene 5U.
75-00-3 Chloroethane
75-09-2 Methylene Chloride
11U
5 7J9-- Lk'
75-25-2
108-10.1
Bromofori.
4-Methyl-2-pentanone
5U
1lU
67-64-1 Acetone II -4-O L. A 591-78-6 2-Hexanone 11U
75-15-0 Carbon Olsulfide 5U 127-18-4 Tetrachtoroethene 5U
75-35-4 191-Dichtoroethene 5U 79-34-5 1,1,2,2-Tetrachloroethane 5U
75-34-3 1,1-Dichloroethane 5U 108-88-3 Toluene SU
540-59-0 1,2-Dichtoroethene (total) 5U 108-90-7 Chlorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5U
107-06-2 1,2-Dichioroethane 5U 100-42-5 Styrene 5u
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1,1,1-Trichtoroethane 5t;
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl- Acetate 11U
75-27-4 Bromodichloromethane 5U
78-87-5 1,2-Dichloropropane sU
10061-01-5 cis-1,3-Dichloropropene 5U
79-01-6 Trichloroethene 5U
124-48-1 Di biomoch Loromethane 5U
Data Reporting Oualifiers: 4 161
U - Compound was analyzed for but not detected. The number Is the attainable detection limit for the sampte.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
O - Secondary dilution.
E - Exceeds initial calibration range.
D-82

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
VGA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnILIS ID: 901206-037 Customer Sample ID: N-117
Laboratory: Organic mass Spectroscopy Laboratory Customer: J. KESSHER/R. SHUCK
Sample Matrix: SOIL File ID: 07587
Level: Clow/med): LOW Date Received: 5-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 10-DEC-1990
% Moisture: not dec. 7
Concentration Units
Number Tics found: 1 CugIL or ug/Kg): -tmL-j
CAS NUMBER COMPOWUNME 1 RT EST. CONC. o
z.2~uz~2E UUUZ23ZUSU2~~zz2~33z23UU j:=zzzzz2U J ==:Z22S32--zU 322332
I1. 76-13-11 Freon 113 1.4 -+4±------6-if Id
I 2. II_ _ _ _ _ _ I_ _
13. __ _ _.__ _ _1_ _ I
17.1__ _ _ _ _ _ _ j I
. I I
j13.__ _ _ _II I
14'. _ _ _ _
15. _ _ _ _
116.__ _ _ _
117. _ _ _ _ 1II
118.__ _ _ _ 1I
119. __ _ _1
II
II
I
I
I
120. _ _ _ _ j II
21. _ _
22?.__ _
123.__ _
_
_
_
_
_
_ jI
I
I
II
II
I
2'. _ _ _ _
125. _ _ _ _ 1I
126._____
I
I
127. ____1
128.__ _ _ _.III
129. ____
J30.JI I
Data Reporting Qualifiers:
u .compound was analyzed for but not detected. The mmnaier Is the attainable detection limit for the sampte.
B Analyte was found In the reagent blank as well as the sample.
J Indicates an estimated value.
ND .Not detected.
A .Aidol condensation product.
D -Secondary dilution.
E Exceeds Initial calibration range.
P -Probable Identification.
D-83
I

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 2
AnaLlS ID: 901206-038 Customer Sample tD: N-118
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File to: >14467 Smple Matrix: SOIL
Instrument ID: MP-5985 Requisition Number:
Authorized By: 0. C. Canada Date Sample Received: 5-DEC-1990
BHA -Base/Neutral/Acid Compounds CTCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 2-JAN-1991
Preparation Procedure Number: Analysis Procedure Numb~er: BNA CCLP) HOP
Percent Moisture: 7.1 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Slank: 901214-083 CA File Number: NA
(I : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
...... ........................... .......... ........... .............................. ..........
108-95-2 Phenol R I00DOW 106-47-8 4-ChLoroaniline R 1000U
111-44-4 bis(2-Chloroethyt)ether R 1000U 87-68-3 Hexachlorobutadiene R 1000U
95-57-8 2-Chtorophenot R 1000U 59-50-7 4-ChLoro-3-methylphenot R 1000U
541-73-1 1,3-Dichlorobenzene R 1000U 91-57-6 2-MethyLnaphthaLene R 1000U
106-46-7 1.4-Dichiorobenzene R 1000U 77-47-4 HexachLorocycLopentadiene R 1000U
100-51-6 Benzyl Alcohol R IOOOU 88-06-2 2,4,6-TrichlorophenoL R 1000U
95-50-1 1,2-Dichlorobenzene R 1000U 95-95-4 2,4.5-Trichtorophenol R 510OU
95-48-7 2-Methylphenol R 1000U 91-58-7 2-ChtoronaphthaLene R 1000U
108-60-1 bis(2-Chloroisopropyt)ether R IOOOU 88-74-4 2-Nitroanitine R 5100U
106-44-5 4-Methylphenol R 1000U 131-11-3 Dimethylphthalate R 1000U
621-64.-7 N-Nitroso-di-n-propylamine R IOOOU 208-96-8 Acenaphthylene R 1000U
67-f2-1 Nexachtoroethane R 1000U 99-09-2 3-Nitroaniline R 5100U
98-95-3 Nitrobenzene R 1000U 83-32-9 Acenaphthene R 1000U
78-59-1 Isophorone R 1000U 51-28-5 2.4-Dinitrophenol R 510OU
88-75-5 2-Nitrophenol R 1000U 100-02-7 4-NitrophenoL R 5100U
105-67-9 2,4-DimethylphenoL R 1000U 132-64-9 Dibenzofuran R 1000U
65-85-0 Benzoic Acid R 5100U 121-14-2 2,4-Dinitrototuene R 100011
111-91-1 bis(2-Chloroethoxy)methane R 1000U 606-20-2 2,6-Dinitrotoiuene R 100011
120-83-2 2,4-Dichlorophenot R 1000U 84-66-2 Diethylphthalate R lOOOU
120-82-1 1,2,4-Trichlorobenzene R IOOOU 7005-72-3 4-ChlorophenyL-phenylether R 100OU
91-20-3 Naphthalene R 100011 86-73-7 Fluorene R 10OOU
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Anaiyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
ND - Not detected.
A - Aldot condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-84

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLlS ID: 901206-038 Customer Sample 10: N-118
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: >14467 Sample Matrix: SOIL
Instrument ID: HP-5985 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 5-DEC-1990
BNA - Base/Neutral/Acid Compounids (TCL)
Date Extracted/Prepared: 13-DEC- 1990 Date Analyzed: 2-JAN-1991
Preparation Procedure Number: Analysis Procedure Numnber: BNA (CLP) NOP
Percent Moisture: 7.1 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Blank: 901214-083 OA File Numb~er: NA
11 : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
100-01-6 4-Nitroanitlne ft 5 1 0U 53-70-3 Dibenz(a,h)anthracene R 1000U
534-52-1 4,6-Dinitro-2-methylphenol ft 5100U 191-24-2 Benzo(g,h,i0perylene R 1000U
86-30-6 M-Nltrosodiphenylamine ft 10000
101-55-3 4-Bromophenyl-phenylether ft 10000
118-74-1 Nexachlorobenzene R 10000
87-86-5 Pentachlorophenol Rt 51000
85-01-8 Phenanthrene R l0OUl
120-12-7 Anthracene ft 10000
84-74-2 Di-n-butytphthalate 1400-.. ,
206-44-0 Fluoranthene ft 10000
129-00-0 Pyrene Rt 10000
85-68-7 ButylbenzylphthaLate ft 10000
91-94-1 3,3'-Dichlorobenzidine ft 21000
56-55-3 Benzo(a)anthracene ft 10000
117-81-7 bis(2-Ethylhexyt)phthalate R 10000
218-01-9 Chrysene ft 10000
117-84-0 Di-n-octylphthalate ft 10000
205-99-2 Benzo(b)fluoranthene R 10000
207-08-9 Benzo(k)fluoranthene ft 10000
50-32-8 Benzo(a)pyrene ft 10000
193-39-5 Indeno(1,2,3-cd)pyrene ft 10000X
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection Limit for the samp~le.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-85

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
BNA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS ID: 901206-038 Customer Sample ID: N-118
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SNUCK
Sample Matrix: SOIL File ID: ),14467
Level: (low/mad): LOW Date Received: 5-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 2-JAN-1991
% Moisture: not dec. 7.1 dec. _____Date Extracted: 13-DEC-1990
Extraction: (SepF/Cont/Sonc) SoxM PH: ____
GPC Cleanup: (YIN) N
Concentration Units
Number TICs found: 17 CugIL or ug/Kg): uVK2
ICAS NUMBER j COMPOUND NAME RT IEST. CONC. a
I ===i= ........... Z .. =-= ... l
....... ....- I . I...
1. 123-42-21 2-Pentanone._4-hydroxv-4-methy 3 .0v i 1T00I JA
12. 1 UNKNOWN 6.051 500 1
I3. 1 UNKNOWN ALCOHOL 4--.-Z.j.Ja. A ;
I4. IUNKNOWN ALCOHOL I 13.88 3000jJ
I5.
6.
7.
IUNKNOWN
IUNKNOWN
IUNKNOWN HYDROCARBON
I;.2
I
4?6f-.---4ej89______
___
_____________
2I F ______ ____
19.
10.
I11.
12.
8. IUNKNOWN HYDROCARBON
IUNKNOWN
jUNKNOWN HYDROCARBON
UNKNOWN HYDROCARBON
[UNKNOWN HYDROCARBON
~I7
I
24.841
26.7.I~
27 I
49 ____ ps-____
460j. 1
i
~ 'I'
j I
13. [UNKNOWN HYDROCARBON 2~7 & r74- I 9 I-
14"._____ UNKNOWN HYDROCARBON 298 -4004-411.
15.
I16.
UNKNOWN HYDROCARBON
UNKNOWN ALKOXY COMPOUND
1
j
30700
3i.09
99 i do
2089 d.
17.
118.
119.
120.
121.
IUNKNOWN PHTHALATE ESTER
I.._
.I_
j 32.37
_ _ _ _1_
1__ _ _ _
__ _ _ _1_
_ _ _ _1_
1100 I 1
_ _ _ _ _ _
_ _ _ 1__
_ _ _ _1_ _
_
I
_
_ I
122.1__ _ _ _1_ _ _ _ 1__ _
123. I_____I____ __ _
124.II__ _ _ _I_ _ _ _ I__ _ I
125. I __ _ _ _I_ _ _ _ I__ _ I
126. I__ _ _ _I_ _ _ _ I__ _ I
127. I. _ _ _ _1_ _ _ _ _ _
128.II__ _ _ _1_ _ _ _ 1__ _ I
129. ____ I___I
130. j____ I
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sampte.
6-Analyte was found in the reagent blank as well as the sample.
J Indicates an estimated value.
ND Not detected.
A - AldoL condensation product.
D - Secondary dilution.
E -Exceeds initial calibration range.
P - Probable Identification. D-86

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of I
AnaLIS ID: 901206-038 Customuer Sampte ID: N-118
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: 07588 Semple Matrix: SOIL
Instrument ID: 597002 Requjisition Numb~er:
Authorized By: 0. C. Canada Date Sape Received: 5-DEC-1990
VDA - Volatile Organic Compounds CTCL)
Date Extracted/Prepared: Date Analyzed: 10-DEC-1990
Preparation Procedure Number: PURGE & TRAP Analysis Procedure Nuumber: VOA (CLP) NOP
Percent Moisture: 7 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: SL STAFFORD
Associated Blank: 901210-025 CA Fite Numiber: NA
El : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
74-87-3 Chloromethane 11U 79-00-S 1,1,2-Trichloroethane SU
74-83-9 Bromomethane 11U 71-43-2 Benzene 5U
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1,3-Dichloropropene 5U
75-00-3 Chtoroethane 11U 75-25-2 Bromoform 5U
75-09-2 Methylene Chloride 5- 9- (A 108-10-1 4-Methyt-2-pentanone 1lU
67-64-1 Acetone 11U 591-78-6 2-Nexanone 11U
75-15-0 Carbon Disulfide 5U 127-18-4 TetrachLoroethene 5U
75-35-4 1,1-oichtoroethene SU 79-34-5 1,1.2,2-TetrachLoroethane 5U
75-34-3 1,1-Dichioroethane 5U 108-88-3 Toluene 5U
540-59-0 1,2-Dichloroethene (total) 5U 108-90-7 Chlorobenzene SU
67-66-3 Chloroform 5U 100-41-4 EthyLbenzene 51)
107-06-2 1,2-Dichtoroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1,1,1-Trichtoroethane 5U
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate 11U
75-27-4 Bromodichtoromethane 5U
78-87-5 1,2-Dichloropropane 5U
10061-01-5 cis-1,3-Dichtoropropene 5U
79-01-6 Trichloroethene 5U /
124-48-1 Dibromochtoromethane 5U
Data Reporting Qualifiers:
U - Compoun~d was analyzed for but not detected. The nu~mber is the attainable detection limit for the salmpte.
8 - Analyte was found in the reagent blank as well as the sampte.
J - Indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-87

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
VOA CTCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS ID: 901206-038 Customer Sample ID: N-118
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Sample Matrix: SOIL Fite ID: 07585
Level: (tow/med): LOW Date Received: 5-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 10-DEC-1990
% Moisture: not dec. 7
Concentration Units
Number TICs found: 1 (ug/L or ug/Kg): g
ICAS NUMBER COMPOUND NAME RT EST. CONC. a
. UNKNOWN I 18.671 6 JJ
I 2. jI1_ _ _ 1_ _
13. ___
_ _ _I_ _
16. __ _ _ _ _ _1_ _ I
7.1_ _ _ _ _ _ _ _ 1 _ _ _ 1
12.__ _
113.__ _
_
_
_II_
_jIII_
114. _ _ _ _ _1III_
_ _ _ _I_ _ _
_ _ I
115.__ _ 1 _ _ I
116. _ _ _ _1II_
117.__ _ _ _1IIj_
j19. J I
120. J I
121. I
122. _____ I
123. __ _ _ _ I I
124. __ _ _ _ __ _ _ _ _ _ _ _ I
125. 1____
126. Ii_ _ _ _ _
127. II_ _ _ _ _ _ _ _ _ _ _ _ _
128. II_ _ _ _ _
129. II____
J30. IjI
Data Reporting Oualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection Limit for the sample.
8 - Analyte was found in the reagent blank as well as the sample.
J- Indicates an estimated value.
ND Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E -Exceeds initial calibration range.
P - Probable Identification.
D -88
_ _
_ _
_ _

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 2
AnaLIS ID: 901206-041 Customer Sample ID: N1-119
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File 10: ),14470 Sample Matrix: SOIL
Instrument 10: NP-5985 Requisition Numb~er:
Authorized By: 0. C. Canada Date Sample Received: 5-DEC-1990
BNA - Base/Neutral/Acid Compounds (TCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 2-JAN-1991
Preparation Procedure Number: Analysis Procedure Nu~mber: BNA CCLP) NDP
Percent Moisture: 6.5 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Blank: 901214-083 QA File Number: NA
U1 : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
108-95-2 Phenol Rt 1000U 106-47-8 4-Chtoroanitine ft IDOWO
111-44-4 bis(2-Chloroethyt)ether R IOOOU 87-68-3 Hexachlorobuitadiene ft 1000U
95-57-8 2-Chlorophenot ft 1 000U 59-50-7 4-Chtoro-3-methylphenol R 1000U
541-73-1 1,3-Dichlorobenzene R 1 000U 91-57-6 2-Nethyinaphthalene Rt 1000U
106-46-7 1,4-Dichlorobenzene ft 1000U 77-47-4 Hexachlorocyclopentadiene R 1000U
100-51-6 Benzyl Alcohol ft 100OU 88-06-2 2,4,6-Trichlorophenol R 1000U
95-50-1 1,2-Dichtorobenzene ft 100OU 95-95-4 2,4,5-Trichtoropienol ft 510OU
95-48-7 2-Methyiphenol ft 100OU 91-58-7 2-Chtoronaphthatene ft 1000U
108-60-1 bis(2-Chloroisopropyi)ether ft 10DOW 88-74-4 2-Nitroaniline ft S100U
106-44-5 4-Methytphenot ft 1000tJ 131-11-3 Dimethylphthalate ft 1000U
621-64-7 N-Nitroso-di-n-propylamine ft 100OU 208-96-8 Acenaphthylene ft 1000U
67-72-1 Hexachtoroethane ft I 00OJ 99-09-2 3-Nitroaniline ft 5100U
98-95-3 Nitrobenzene ft 1000U 83-32-9 Acenaphthene ft 1000U
78-59-1 Isophorone ft 1000U 51-28-5 2,4-Dinitrophenol ft 5100U
88-75-5 2-Nitrophenol ft 1000U 100-02-7 4-Nitrophenol ft 5100U
105-67-9 2,4-Dimethylphenol ft 1000U 132-6,4-9 Dibenzofuran ft 1000U
65-85-0 Benzoic Acid ft 5100U 121-14-2 2,4-Dinitrotoluene ft 1000U
111-91-1 bis(2-Chtoroethoxy)methane ft 1000U 606-20-2 2,6-Dinitrotoluene ft 1000U
120-83-2 2,4-Dichiorophenol ft 1000U 84-66-2 Diethylphthalate ft 1000U
120-82-1 1,2,4-Trichlorobenzene ft 1000U 7005-72-3 4-Chlorophenyt-phenylether ft 1000u
91-20-3 Naphthalene ft 1000U 86-73-7 Fluorene ft 1000U
Data Reporting Qualifiers:
U - Comopound was analyzed for but not detected. The number is the attainable detection Limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D -89

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLIS ID: 901206-041 Customer Samrple ID: N-119
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite ID: 3,14470 Samrple Matrix: SOIL
Instrument 1D: RP-5985 Requaisition Numer:
Authorized By: D. C. Canada Date Sample Received: 5-DEC-1990
UNA - Base/NeutraL/Acid Compounds (TCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 2-JAM- 1991
Preparation Procedure Nu~dber: Analysis Procedure Mumber: SNA (CLP) MOP
Percent Moisture: 6.5 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Btank: 901214-083 OA File Number: NA
I : Result has been Corrected for Spike
CAS ug/Kg CAS uglKg
..-........-..-........................-........-.----------- ------------------------------ ....
100-01-6 4-NitroaniLine R 1 00U 53-70-3 Dibenz~a~h)anthracene R 1000U
534-52-1 4,6-Dinitro-2-methyLphenoL R 5S10Dot 191-24-2 Senzo~g~h,i)perytene R 1000U
86-30-6 N-Nitrosodiphenyamine ft 1000U)
101-55-3 4-Bromophenyl-phenylether Rt 1000U
118-74-1 Hexachlorobenzene R 1001.
87-86-5 Pentachtorophenol R 510OU
85-01 -8 Phenanthrene Rt 1000U
120-12-7 Anthracene R 1001.
84-74-2 DI-n-butylphthalate 4800-SL
206-44-0 Fluoranthene R 1000U
129-00-0 Pyrene R 1000U
85-68-7 Butylbenzylphthalate R 1001.
91-94-1 3,3'-DichLorobenzidine ft 2100U
56-55-3 Benzo(a)anthracene ft 1000U
117-81-7 bis(2-Ethythexyt)phthalate ft 1001.
218-01-9 Chrysene ft IOOOU
117-84-0 Di-n-octylphthalate ft 1000U
205-99-2 Benzo(b)fluoranthene ft 1000U
207-08-9 Benzo~k)fluoranthene ft 1000U
50-32-8 Ienza(a)pyrene R 100111 /
193-39-5 Indeno(1,2,3-cd)pyrene R 1000U
Data Reporting Qualifiers:
q
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
NO - Not detected.
A - AldoL condensation product.
0 - Secondary dilution.
E - Exceeds initial calibration range.
D-90

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
f BNA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS ID: 901206-041 Customer Sample ID: U-119
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Saumple Matrix: SOIL File ID: >14470
Level. (low/med). Low Date Received: 5-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 2-JAM-1991
% Moisture: not dec. 6.5 dec. _____Date Extracted: 13-DEC-1990
Extraction: CSepF/Cont/Sonc) SoxH pH1: ___
CPC Cleanup: (YIN) N
concentration Units
Number TICs founid: 19 Cug/L or tag/Kg): u2LKIa
CAS NUMB8ER COMPOUND WAME I RT IEST. CONC. a
1.
I2.
13.
I4.
I5.
6.
IUNKNOWN
123-42-21 2-Pentanone. 4-hydroxy-4-methy
1 UNKNOWN
IUNKNOWN
IUNKNOWN ALCOHOL
IUNKNOWN ACID
j
J
J
J
j
j
'.39J
S3301 ?
8.311
10.711
i5.94.
15.581
4901
5801
9101
ieee&:-4-g
4601
7. IUNKNOWN Z8!.95 ieooI~
8.
9.
IUNKNOWN PHTHALATE ESTER
JUNKNOWN j
24~.p! -Q8 4..w.___
_
24.861 94014 I 1
.10. JUNKNOWN HYDROCARBON ! 5!O1!
I11. JUNKNOWN HYDROCARBONj LUI3'II
I12. 3UNKNOWN HYDROCARBON j ~ I ~ :~
13.
14.
I15.
16.
17.
18.
19.
JUNKNOWN HYDROCARBON
3UNKNOWN HYDROCARBON
IUNKNOWN HYDROCARBON
IUNKNOW14
IUNKNOWN HYDROCARBON
IUNKNOWN HYDROCARBON
IUNKNOWN ALKOXY COMPOUND
I
J
I
1
-~Z4- 29
-'' / 'XM J.
2944I 3iI I~ w;
08 2 9mI-6
3q.0? I mO J
~ M .89I 130I
32.88 11100 I 1
37.26 j1200 J
120.
121.
122.I
123.
124. II____
I__ _ _
I
I
_I_ _ _ _
I
_ _ _
I
I
I
125. II____
126. II____
127.II_____I_______I
128. II____ _______
129.
130.
II_____
__ _ _ _
________
_I_ _ _ _ _ _ _ _ _ I
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The numb~er is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J4 Indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
D0 Secondary dilution.
E - Exceeds initial calibration range.
P-Probable Identification. D-91

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 1
AnaLIS ID: 901206-041 Customer Sample ID: N-119
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File 10: 07591 Sample Matrix: SOIL
Instrument ID: 597002 Requisition Number:
Authorized By: 0. C. Canada Date Sample Received: 5-DEC-1990
VOA - Volatile Organic Compounds CTCL)
Date Extracted/Prepared: Date Analyzed: 10-DEC- 1990
Preparation Procedure Numb~er: PURGE & TRAP Analysis Procedure Numb~er: VGA (CLP) NOP
Percent Moisture: 7 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: SL STAFFORD
Associated Blank: 901210-025 QA File Number: NA
Cl:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
.................................. .......... ........... .............................. ..........
74-87-3 ChLoromethane 11U 79-00-5 1,1,2-Trichloroethane 5U
74-83-9 Bromomethane 11U 71-43-2 Benzene 5U
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1,3-DichLoropropene 5U
75-00-3 ChLoroethane 11U 75-25-2 Uromoform 5U
75-09-2 Methylene Chloride 5 -- LA 108-10-1 4-Methyl-2-pentanone 11U
67-64-1 Acetone 11 1& A 591-78-6 2-Nexanone 11U
75-15-0 Carbon Disulfide 5U 127-18-4 TetrachLoroethene 5U
75-35-4 1,1-Dichloroethene 5U 79-34-5 1.1.2,2-TetrachLoroethane 5U
75-34-3 1,1-Dichloroethane 5U 108-88-3 Toluene 5U
540-59-0 1,2-Dichtoroethene (total) 5U 108-90-7 Chlorobenzenve 5U
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5U
107-06-2 i,2-Dichtoroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1.1,1-Trichloroethane SU
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl. Acetate 11U
75-27-4 Bromodichioromethane 5U
78-87-5 1,2-Dichloropropane 5U
10061-01-5 cis-1,3-Dichloropropene 5U
79-01-6 Trichtoroethene 5U
124-48-1 Dibromochtoromethane 5U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-92

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 2
AnaLIS ID: 901206-042 Customer Samrple ID: N-120
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J1. KESSNER/R. SNUCK
Fite ID: ),14471 Sample Matrix: SOIL
Instrument ID:
Authorized By:
HP-5985
D. C. Canada
Requisition Number:
Date Sample Received: 5-DEC-1990
BRA - Base/Neutral/Acid Compounlds (TCL)
Date Extracted/Prepared:
Preparation Procedure Number:
13-DEC-1990 Date Analyzed:
Analysis Procedure Numb~er:
2-JAN-1991
BNA CCLP) MOP
Percent Moisture:
Percent Moisture (decanted):
5.6 Dilution Factor:
Analyst:
1.0
AK HEADRICK
Associated Blank: 901214-083 GA File Number: NA
El : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
................
.............................. .......... ........... .............................. ..........
108-95-2 Phenol R 990U 106-47-8 4-Chioroanitine R 990U
111-44-4 bisC?-Chtoroethyt)ether R 99DU 87-68-3 Hexachtorobutadiene ft 990u
95-57-8 2-Chlorophenol R 99OU 59-50-7 4-Chtoro-3-methylphenot ft 990U
541-73-1 1,3-Dichlorobenzene R 991. 91-57-6 2-Methyinaphthalene ft 99OU
106-46-7 1,4-Dichlorobenzene ft 990U 77-47-4 Hexachlorocyclopentadiene ft 99OU
100-51-6 Benzyl Alcohol R 990U. 88-06-2 2,4,6-Trichlorophenot R 990U
95-50-1 1,2-Dichlorobenzene ft 990U 95-95-4 2,4.5-Trichtorophenol R 4800U
95-48-7 2-Methylphenol ft 9901U 91-58-7 2-Chtoronaphthatene R 99OU
108-60-1 bis(2-Chloroisopropyt)ether ft 990U 88-74-4 2-Nitroaniline R 4800U
106-44-5 4-Methylphenol ft 990U 131-11-3 Dimethylphthalate ft 990U
621-64-7 N-Nitroso-di-n-propylamine ft 990U 208-96-8 Acenaphthylene R 990U
67-72-1 Hexachloroethane ft 990U 99-09-2 3-Nitroaniline ft 48001U
98-95-3 Nitrobenzene ft 990U 83-32-9 Acenaphthene ft 990U
78-59-1 Isophorone ft 991. 51-28-5 2.4-Dinitrophenol ft 4800U
88-75-5 2-Nitrophenol ft 99OU 100-02-7 4-Nitrophenol ft 4800u
105-67-9 2,4-Dimethytphenol ft 99OU 132-64-9 Dibenzofuran ft 990U
65-85-0 Benzoic Acid ft 480OU 121-14-2 2,4-Dinitrotoluene ft 990U
111-91-1 bis(2-Chloroethoxy)methane ft 990U 606-20-2 2,6-Dinitrototuene ft 990.
120-83-2 2,4-Dichtorophenol ft 99OU 84-66-2 Diethytphthalate ft 991.
120-82-1 1,2,47Trichtorobenzene ft 990U 7005-72-3 4-Chtorophenyl-phenvylether ft 990U.
91-20-3 Naphthalene ft 990U 86-73-7 Ftuorene ft 990U
Data Reporting Qualifiers:
U -Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B Analyte was found in the reagent blank as well as the sample.
J1 Indicates an estimated value.
ND -Not detected.
A -Atdol condensation product.
D -Secondary dilution.
E -Exceeds initial calibration range.
D -93

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLIS ID: 901206-04.2 Customer Sample ID: N-120
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: -14471 Sample Matrix: SOIL
Instrument ID: RP-5985 Requisition Number:
Authorized By: D. C. Canada Date Samlple Received: 5-DEC-1990
DNA - Base/Neutral/Acid Comn~o~'ds CTCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 2-JAN-1991
Preparation Procedure Nuber: Analysis Procedure Number: BNA CCLP) HOP
Percent Moisture: 5.6 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Slank: 901214-083 GA File Numer: NA
Cl:Result has been Corrected for Spike
CAS uglKg CAS ug/Kg
.. ....... .............................. .......... -----.............................. ..........
100-01-6 4-Nitroaniline R 480OU 53-70-3 Dibenz~a~h)anthracene R 990U
534-52-1 4,6-Dinitro--methytphenoL ft 480OU 191-24-2 Benzo(g,h,i)perylene R 990U
86-30-6 N-Nitrosodiphenylamine R 990U
101-55-3 4-Bromopheny-phenylether Rt 990U
118-74-1 Nexachtorobenzene ft 990U
87-86-5 Pentachlorophenot ft 4800U
85-01-8 Phenanthrene Rt 990U
120-12-7 Anthracene ft 990U
84-74-2 Di-n-butytphthalate 3000 &.LA
206-44-0 Fluoranthene ft 990U
129-00-0 Pyrene Rt 990U
85-68-7 Butylbenzylphthalate ft 99OU
91-94-1 3,3'-Dichlorobenzidine ft 2000U
56-55-3 Senzo(a)anthracene ft 990U
117-81-7 bis(2-Ethylhexyt)phthalate ft 990U
218-01-9 Chrysone ft 990U
117-84-0 Di-n-octylphthalate ft 990U
205-99-2 Benzo(b)fluoranthene Rt 990U
207-08-9 Benzo(k)fluoranthene Rt 990U
50-32-8 Benzo(a)pyrene ft 990U
193-39-5 Indeno(1,2,3-cd)pyrene ft 990U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The numb~er is the attainable detection limit for the sample.
B - Analyte was founmd in the reagent blank as well as the sample.
J - Indicates an estimated value.
NO - Not detected.
A - ALdol condensation product.
D - Secondary dilution.
E - Exceeds Initial calibration range.
D-94

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 2
AnaLIS 10: 901206-043 Customer Samvple ID: N-121
Laboratory: Organic mass Spectroscopy Laboratory Customer: J1. KESSNER/R. SHUCK
File 10: 314"72 Samvple Matrix: SOIL
Instrument 10: Hp-5985 Requisition Number:
Authorized By: 0. C. Canada Date Sample Received: 5-DEC-1990
SNA - Base/Neutral/Acid Compounds (TCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 2-JAN-1991
Preparation Procedure Number: Analysis Procedure Number: BNA CCLP) NDP
Percent Moisture: 5.5 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Stank: 901211-05 CA File Number: NA
U:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
108-95-2 Phenol ft 980U 106-47-8 4-Chtoroaniline R 98OU
111-44-4 bis(2-Chloroethyt)ether ft 980U a7-68-3 Nexachtorobutadiene R 980U
95-57-8 2-Chlorophenol R 980U 59-50-7 4-Chloro-3-methyiphenot R 98OU
541-73-1 ,3-Dichiorobenzene ft 980U 91-57-6 2-Methyinaphthalene ft 98OU
106-46-7 1,4-Dichlorobenzene ft 980U 77-47-4 Hexachlorocyclopentadiene ft 980U
100-51-6 BenzyL Alcohol R 980U 88-06-2 2,4,6-TrichLorophenot R 980U
95-50-1 1,2-Dichlorobenzene R 980LJ 95-95-4 2,4,5-Trichtorophenol R 4800U
95-48-7 2-Methylphenol R 980U 91-58-7 Z-ChloronaphthaLene ft 980U
108-60-1 bis(2-Chtoroisopropyt)ether ft 980U 88-74-4 2-Nitroaniline ft 480OU
106-44-5 4-Methytphenol ft 980U 131-11-3 Dimethylphthalate ft 980U
621-64-7 N-Nitroso-di-n-propyanine ft 980U 208-96-8 Acenaphthytene ft 980U
67-72-1 Nexachloroethane ft 980U 99-09-2 3-Nitroaniline ft 4800U
98-95-3 Nitrobenzene ft 980U 83-32-9 Acenaphthene ft 980U
78-59-1 Isophorone ft 980U 51-28-5 2,4-Dinitrophenol Rt 4800U
88-75-5 2-NitrophenoL ft 980U 100-02-7 4-NitrophenoL ft 4800U
105-67-9 2,4-Dimethytphenol ft 980U 132-64-9 Dibenzofuran ft 980U
65-85-0 Benzoic Acid ft 4800U 121-14-2 2,I.-Dinitrotoluene ft 980U
111-91-1 bis(2-Chloroethoxy)methane Rt 980U 606-20-2 2,6-Dinitrotoluene ft 980U
120-83-2 2,4-Dichlorophenot ft 980U 84-66-2 Oiethylphthalate ft 980U
120-82-1 1,2,4-Trichlorobenzene ft 98OU 7005-72-3 4-Chtorophenyt-phenytether ft 980U
91-20-3 Naphthalene ft 98OU 86-73-7 F'Luorene ft 980U
Data Reporting Qualifiers:
U - Comnm-d was analyzed for but not detected. The number is the attainable detection Limit for the samp~le.
B - Anatyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
O - Secondary dilution.
E - Exceeds Initial calibration range.
0 -97

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLIS ID: 901206-043 Customer Samrple ID: N-121
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: )14472 Sample Matrix: SOIL
Instrument ID: HP-5985 Requisition Number:
Authorized By: D. C. Canada Date Samrple Received: 5-DEC-1990
BRA - Base/Neutral/Acid Comrpounmds (TCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 2-JAN-1991
Preparation Procedure Number: Analysis Procedure Number: BNA CCLP) MOP
Percent Moisture: 5.5 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICKC
Associated Blank: 901214-083 OA File Numiber: NA
C]:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
...... ........................... .......... ........... .............................. ..........
100-01-6 4-Nitroaniline R 4800U 53-70-3 Dibenz~a~h)anthracene R 980U
534-52-1 4,6-Dinitro-2-methylphenol R 4801U 191-24-2 Benzog,h,I)perylene R 960U
86-30-6 N-Nitrosodiphenylamine R 980U
101-55-3 4-Bromophenyl-phenylether R 980U
118-74-1 Hexachlorobenzene R 980U
87-86-5 Pentachtorophenot R 480OU
85-01-8 Phenanthrene R 98OU
120-12-7 Anthracene R 980U
84-74-2 Di-n-butylphthalate 4300't, U~
206-44-0 Fluoranthene R 980U
129-00-0 Pyrene R 980U
85-68-7 Butylbenzylphthalate R 980U
91-94-1 3,3'-Dichtorobenzidine R 2000U
56-55-3 Benzo~a)anthracene R 980U
117-81-7 bisC2-EthylhexyL)phthatate R 980U
218-01-9 Chrysene R 980U
117-84-0 Di-n-octylphthalate R 980U
205-99-2 Benzo(b)fluoranthene R 980U
207-08-9 Denzo(k)fLuoranthene R 980U lI
50-32-8 Benzo(a)pyrene R 980U
193-39-5 lndeno(l.2,3-cd)pyrene R 980U
Data Reporting Qualifiers:
U - Comrpound was analyzed for but not detected. The numiber is the attainable detection limit for the samrple.
B - Analyte was founmd in the reagent blank as well as the samrple.
J - Indicates an estimated value.
RD - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E -Exceeds initial calibration range.
D -98

WHC-SD-EN-TI-136, Rev. 0
oak Ridge K-25 site
Analytical Chemistry Department
BNA CTCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS ID: 901206-043 Customer Sample ID: N-121
Laboratory: organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Sample Matrix: SOIL File ID: ),14472
Level: (tow/med): Low Date Received: 5-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 2-JAN-1991
% Moisture: not dec. 5.5 dec. _____Date Extracted: 13-DEC-1990
Extraction: (SepF/Cont/Sonc) SoxH PHt: -
GPC Cleanup: (YiN) N
Concentration Units
Number TICs found: 19 (ugiL or ugiKg): uqLa
CAS NUMBER COMPOUND NAME RT IEST. CONC. 0
I1.
I2.
I3.
4 ._
123-42-21 2-Pentanone. 4-hydroxy-4-methy
1UNKNOWN ALCOHOL
1UNKNOWN
_ _ _ 1 UNKNOW.N 1
5 .;Z 1 109 j-AO.i581
i Z - I.~ -
109 1 e389 --
4;. 17.2!300 1Ja
5.
6.
1 UNKNOWN
1 UNKNOWN
19i.Z9 1
20.9
17000s + d"
-oo--4--de-
7. 1 UNKNOWN PNALATE ESTER j 4.68. So I 48 I
I .IUNKNOWN ALKOXY COMPOUND j 24.84j 980O1
10.
11. ______UNKNOWN
jANTHRACENEDIONE
HYDROCARBON
1 6.05 j
Z0.30 ~
4000-4-49
I
12.
13.
14.
15.
16.
UNKNOWN HYDROCARBON
UNKNOWN HYDROCARBON
UNKNOWN HYDROCARBON
jUNKNOWN HYDROCARBON
UNKNOWN HYDROCARBON
j
I
I
1
I
Z7.Z
28.;q
29.6.3
29.80 I
30.86I
13 I
2888I
120is~ Q9
2300 I 1
100J
17. jUNKNOWN HYDROCARBON 31.0e I 74404-a
18. ______jUNKNOWN HYDROCARBON I 31.06 we 703
19. jUNKNOWN ALKOXY COMPOUND 37.24 2600 1
120.1__ _ _ _ _ _ _ _ _ _ 1__ _ _ 1__ _ _ 1__ _
121. _ _ _ _1_ _ _ _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _ _ _
122.1__ _ _ _ _ _ _ _ _ _ 1 _ _ _ 11__ _ I
123. 1_ _ _ _ _ _ _ _ _ _ _1_ _ _ _1_ _ _ _ _ _
.24. 1_ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _1_ _
125. 1_ _ _ _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _ _ _
126.1__ _ _ _ _ _ _ _ _ _ 1__ _ _ 1__ _ _ 1__ _
127.1__ _ _ _ _ _ _ _ _ _ 1__ _ _ 1__ _ _ 1__ _
128.1__ _ _ _ _ _ _ _ _ _ 1__ _ _ 1__ _ _ 1__ _
129.1 _ _ _ _ _ _ _ _ _ _ 1__ _ _ 1__ _ _ 1__ _
130. I ___ _
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sampl~e.
8 - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
P - Probable Identification. D-99

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 1
AnaLIS ID: 901206-043 Customer Sample ID: N-121
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SNUCK
Fite ID: 07593 Sample Matrix: SOIL
instrument ID: 597012 Requisition Number:
Authorized By: D. C. Canada Date Samp~le Received: 5-DEC-1990
VOA - Volatile organic Compounads (TCL)
Dote Extracted/Prepared: Date Analyzed: 10-DEC-1990
Preparation Procedure Numb~er: PURGE L TRAP Analysis Procedure Numb~er: VOA (CLP) NOP
Percent Moisture: 6 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: SL STAFFORD
Associated Blank: 901210-025 0A File Numnber: NA
El Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
------ ........................... .......... ........... .............................. ..........
74-87-3 Chtoromethane 11U 79-00-5 1.1,2-TrichLoroothane 5U
74-83-9 Bromomethane 11U 71-43-2 Benzene 5
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1,3-Dichloropropene 5U
75-00-3 Chloroethane 11U 75-25-2 Bromoform 5U
75-09-2 Methylene Chloride 5 1&
A 108-10-1 4-MethyL-2-pentanone 11U
67-64-1 Acetone 21$.&I 591-78-6 2-Hexanone 11U
75-15-0 Carbon Disulfide 5U 127-18-4 Tetrachloroethene 5U
75-35-4 1,1-Dichloroethene 5U 79-34-5 1.1.2.2-Tetrachloroethane 5U
75-34-3 1,1-DichLoroethane 5U 108-88-3 Toluene 5U
540-59-0 1.2-Dichtoroethene (total) 5U 108-90-7 ChLorobenzene 5U
67-66-3 Chloroform SU 100-41-4 Ethylbenzene 5U
107-06-2 1,2-Dichloroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1,1,1-Trichloroethane 5U
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate 11U
75-27-4 Bromodichloromethane 5U
78-87-5 1,2-Dichloropropane SU
10061-01-5 cis-1.3-Dichloropropene 5U
79-01-6 Trichloroethene 5U
124-48-1 Dibromochloromethane SU
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J- Indicates an estimated value.
NO - Not detected.
A -Aldol condensation product.
O - Secondary dilution.
E - Exceeds initial calibration range.
D-100

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 2
AnaLIS ID: 901206-044 Customer Sample ID: N-122
Laboratory: organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: -14473 Samp~le Matrix: SOIL
Instrumrnent ID: MP-5985 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 5-DEC-1990
BNA - Base/Neutral/Acid Compounmds (TCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 2-JAN-1991
Preparation Procedure Nuumber: Analysis Procedure Number: 3NA (CLP) HOP
Percent Moisture: 5.9 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Blank: 901214-083 QA File Numbder: NA
[I : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
108-95-2 Phenol R 990U 106-47-8 4-Chloroaniline ft 999.
111-44-4 bis(2-Chloroethyt)ether R 990U 87-68-3 Hexachtorobutadiene R 9901)
95-57-8 2-Chlorophenol R 990U 59-50-7 4-Chtoro-3-methytphenol ft 990U
541-73-1 1,3-Dichlorobenzene R 990U 91-57-6 2-Methylnaphthalene R 990U
106-46-7 1,4-Dichlorobenzene R 990U 77-47-4 Nexachtorocyclopentadiene R 99OU
100-51-6 Benzyl Alcohol R 990U 88-06-2 2,4,6-TrichLorophenot ft 99OU
95-50-1 1,2-Dichlorobenzene ft 990U 95-95-4 2,4,5-TrichtorophenoL R 480OU
95-48-7 2-Methylphenol ft 990U 91-58-7 2-Chloronaphthatene R 990U
108-60-1 bisC2-Chloroisopropyt)ether R 990U. 88-74-4 2-Nitroaniline R 4800U
106-44-5 4-Methylphenol ft 999. 131-11-3 Dimethylphthalate ft 990U
621-64-7 N-Nitroso-di-n-propylanine ft 990U 208-96-8 Acenaphthylene ft 99OU
67-72-1 Hexachloroethane ft 990U 99-09-2 3-NitroaniLine ft 4800U
98-95-3 Nitrobenzene ft 990U 83-32-9 Acenaphthene ft 990U
78-59-1 Isophorone ft 999. 51-28-5 2,4-Dinitrophenol ft 480OU
88-75-5 2-Nltrophenot ft 990U 100-02-7 4-Nitrophenot ft 480OU
105-67-9 2,4-Dimethylphenol ft 990U 132-64-9 Dibenzofuran ft 990U
65-85-0 Benzoic Acid ft 480OU 121-14-2 2,4-Dinitrotoluene ft 999.
111-91-1 bisC2-Chloroethoxy)methane ft 990U 606-20-2 2,6-Dinitrotoluene ft 990U
120-83-2 2,4-Dichtorophenot ft 99OU 84-66-2 Diethylphthalate ft 990U
120-82-1 1,2,4-Trichlorobenzene ft 990U 7005-72-3 4-Chlorophenyl-phenytether ft 990U
91-20-3 Naphthalene ft 990U 86-73-7 Fluorene ft 990U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The numb~er is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-101

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLIS I0: 901206-044 Customer Sample 10: N-122
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite ID: ),14473 Sample Matrix: SOIL
Instrument ID: HP-5985 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 5-DEC-1990
INA - Base/Neutral/Acid Compounids (TCL)
Date Extracted/Prepared: 13-DEC- 1990 Date Analyzed: 2-JAN-1991
Preparation Procedure Numb~er: Analysis Procedure Number: SNA (CIP) HOP
Percent Moisture: 5.9 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Blank: 901214-083 CA File Number: NA
11 : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
.................................. .......... ........... .............................. ..........
100-01-6 4-Nitroaniline R 480OU 53-70-3 Oibenz(a,h)anthracene R 99OU
534-52-1 4,6-Dlnitro-2-methylphenot R 4800U 191-24-2 Benzo(g,h,i)perylene R 990U
86-30-6 N-Nitrosodiphenylamine R 990U
101-55-3 4-Bromophenyl-phenylether R 990U
118-74-1 Hexachlorobenzene R 990U
87-86-5 Pentachlorophenot R 4800U
85-01-8 Phenanthrene R 990U
120-12-7 Anthracene R 990U.
84-74-2 Di-n-butylphthalate 7100S..LA,
206-44-0 FLuoranthene R 990U
129-00-0 Pyrene R 990U
85-68-7 ButylbenzyLphthalate R 990U
91-94-1 3,3'-DichLorobenzidine R 2000U
56-55-3 Benzo(a)anthracene R 990U
117-81-7 bis(2-EthylhexyL)phthatate R 990U
218-01-9 Chrysene R 990U
117-84-0 Di-n-octylphthalate R 990U
205-99-2 Benzo(b)fluoranthene R 990U
207-08-9 genzo(k)ftuoranthene R 990U
50-32-8 Benzo(a)pyrene R 990U7/ .
193-39-5 Indeno(1,2,3-cd)pyrene R 990U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number Is the attainable detection limit for the sample.
B - Analyte was found In the reagent blank as well as the sample.
J - Indicates an estimated value.
ND - Not detected.
A - Atlol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-102

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
DNA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS 1D: 901206-044. Customer Sample ID: N-122
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Sample Matrix: SOIL File ID: >14473
Level: (towlmed): LOW Date Received: 5-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 2-JAN-1991
% Moisture: not dec. 5.9 dec. _____Date Extracted: 13-DEC-1990
Extraction: CSepFlContlSonc) SoxH PH: ____
CPC Cleanup: (YIN) N
Concentration Units
Number TICs found: 20 (ugIL or ug/Kg): _uK
I CAS NUMBER COMPOUND NAME RT jEST. CONC. 0
I1. 123-42-21 2-Pentanone. 4-hydroxy-4-methy J5.r69- ;9000 1 dAe0
I2. _ jUNKNOWN 1
j8.28j 650 1 1
I3. 1 UNKNOWN ALCOHOL 3 -~99m-4- H00-4,1
I4. _____ jUNKNOWN ACID 15.61 I46011
I5. jUNKNOWN -.9 4OI9094 d o
6. ___ jUNKNOWN ZO79
7. _______jUNKNOWN 1T! 20 d o,
8.______ UNKNOWN j 1.90I ~ 00
I9. jUNKNOWN PNTHALATE ESTER 266 iio -I e
I10. UNKNOWN HYDROCARBON J 24.83 I3400 1 1
11. jUNKNOWN HYDROCARBON ~I70IJ
I12. ______jANTHRACENEDIONE oi.I 7QI9
13. jUNKNOWN HYDROCARBON 2J3 9; I~ N;
14.
15.
IUNKNOWN HYDROCARBON
f UNKNOWN HYDROCARBON J
V-1
.? I
2?0
N100
d7o -I.i
i a;
/16. IUNKNOWN ; 9.6; go 00 0
17.
I18.
IUNKNOWN HYDROCARBON
IUNKNOWN HYDROCARBON
29.84
500
-------- ';
2408O J
19.
I20.
jUNKNOWN HYDROCARBON
UNKNOWN HYDROCARBON
31 70
I
------ 4904-s -
1 999 j0
121. ____11 I
122.11 I
123.__ _ _ 11 I
/24. 1 I
/25. ____
126.1 II
127.1 I
128.1I I
129. I
130.j II
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The numb~er is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the saawple.
J - Indicates an estimated value.
RD -Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
P - Probable Identification. D-103
.

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 1
AnaLlS ID: 901206-04.4 Customer Sample ID: N-122
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite ID: 07605 Sample Matrix: SOIL
instrument ID: 597002 Requisition Numb~er:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
VOA - Volatile Organic Compounds (TCL)
Date Extracted/Prepared: Date Analyzed: 11-DEC-1990
Preparation Procedure Number: PURGE 9 TRAP Analysis Procedure Numb~er: VGA (CLP) NOP
Percent Moisture: 6 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: GL HUDDLESTON
Associated Slank: 901211-004 OA File Number: NA
(I:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
...................
.............................. .......... ...........----------------..........
74-87-3 Chtoromethane 11U 79-00-5 1,1,2-Trichtoroethane 5U
74-83-9 Bromomethane 11U 71-43-2 Benzene 5U
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1,3-Oichtoropropene 5U
75-00-3 Chtoroethane 11U 75-25-2 Bromoform 5U
75-09-2 Methylene Chloride 5U 108-10-1 1-Methyl-2-pentanone llU
67-64-1 Acetone 11U 591-78-6 2-Hexanone 11U
75-15-0 Carbon DisuLfIde 5U 127-18-4 TetrachLoroethene 5U
75-35-4. 1,1-Dichtoroethene 5U 79-34-5 1.1,2,Z-Tetrachloroethane 5U
75-34-3 1,1-Dichtoroethane SU 108-88-3 Toluene 5U
540-59-0 1,2-Dichtoroethene (total) 5U 108-90-7 ChLorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 EthyLbenzene 5U
107-06-2 1,2-Dichtoroethane SU 100-42-5 Styrene 5U
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1,1,1-Trichloroethane 5U
56-23-5 Carbon Tetrachloride 5U
108-05-1. Vinyl Acetate 11U
75-27-4 Bromodichtoromethane 5U
78-87-5 1,2-Dichloropropane SU
10061-01-5 cis-1,3-Dichloropropene SU
79-01 -6 Trichloroethene 5U
124-48-1 Dibromochloromethane 5U
Data Reporting Cualifiers:
U - Comrpound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J2 - Indicates an estimated value.
No - not detected.
A - Aldol condensation product.
O - Secondary dilution.
E - Exceeds initial calibration range.
D-104

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 2
AnaLIS 10: 901206-045 Customer Sample ID: N-123
Laboratory: organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite ID: 3141.74 Sample Matrix: SOIL
Instrument ID: HP5985 Requisition Number:
Authorized By: 0. C. Canada Date Sample Received: 5-DEC-1990
BNA - Base/Neutral/Acld Compoun~ds (TCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 2-JAN-1991
Preparation Procedure Nuber: Analysis Procedure Number: SNA (CLP) HOP
Percent Moisture: 8.5 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Blank: 901214-083 OA File Nu~mber: NA
0] : Result has been Corrected for Spike
CAS uglKg CAS ug/Kg
............................... .......... ........... .............................. ..........
108-95-2 Phenol ft IOOOU 106-47-8 4-ChloroaniLine R IOU
111-44-4 bis(2-ChLoroethyt)ether R 1000U 87-68-3 MexachLarobutadiene ft 1 000tU
95-57-8 2-ChlorophenoL R 1000U 59-50-7 4-Chloro-3-methylphenoL ft 1000U
541-73-1 1,3-Dichlorobenzene ft 1 000U 91-57-6 2-MothytnaphthaLene ft 1000U
106-46-7 1.4-Dichtorobenzene ft 000t; 77-47-4 Hexachlorocyclopentadiene Rt 100OU
100-51-6 Benzyt Alcohol ft 100OU 88-06-2 2,4,6-Trichlorophenot ft 100OU
95-50-1 1,2-Dichlorobenzene ft 1 000tU 95-95-4 2,4,5-Trichlorophenol ft 5200t)
95-48-7 2-Methytphenol ft 100OU 91-58-7 2-ChLoronaphthatene ft 1000U
108-60-1 bls(2-Chlorolsopropyl)ether ft 1 000tU 88-74-4 2-Nitroaniline Rt 520OU
106-44-5 4-MethytphenoL ft 1000U 131-11-3 Dimethylphthalate ft 100OU
621-64-7 N-Witroso-di-n-propylamine Rt I000U 208-96-8 Acenaphthylene ft 1000U
67-72-1 Hexachtoroethane ft 1000U 99-09-2 3-Nitroanitine ft 520OU
98-95-3 Nitrobenzene ft 1000U 83-32-9 Acenaphthene ft 1000U
78-59-1 Isophorone ft I000tU 51-28-5 2,4-Dinitrophenol ft 5200U
88-75-5 2-NitrophenoL ft 1000U 100-02-7 4-Nitrophenol ft 5200u
105-67-9 2,4-DimethytphenoL ft IOOOU 132-64-9 Dibenzofuran R I000U
65-85-0 Benzoic Acid ft 5200U 121-14-2 2,4-Dinitrotoluene ft 1000U
111-91-1 bis(2-Chloroethoxy)methane ft 1000U 606-20-2 2,6-Dinitrotoluene Rt 1000U
120-83-2 2,4-Dichlorophenol ft 1000U 84-66-2 Diethylphthalate Rt 1000U
120-82-1 1,2,4-Trichlorobenzene ft 1000U 7005-72-3 4-Chtorophenyt-phenyLether ft 1 000U
91-20-3 Naphthalene ft 1000U 86-73-7 FLuorene Rt IOOOU
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the samrple.
B - Analyte was found in the reagent blank as well as the sample.
J1 - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds Initial calibration range.
D-105

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLIS ID: 901206-045 Customer Sample ID: M-123
Laboratory: Organic mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: ),14474 Sample Matrix: SOIL
Instrument ID: MP-5985 Requisition Numiber:
Authorized By: 0. C. Canada Date Samp~le Received: 5-DEC-1990
SNA - Base/Neutral /Acid Compyounmds (TCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 2-JAN-1991
Preparation Procedure Numiber: Analysis Procedure Number: INA CCLP) NDP
Percent Moisture: 8.5 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Blank: 901214-083 OA File Numiber: NA
C]:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
------. . ............-----.------- .------.*................ ............................. ..........
100-01-6 4-Nitroaniline R 520OU 53-70-3 Dibenz(a,h)anthracene R IODOU
534-52-1 4,6-Dinitro-2-methylphenoL R 5200U 191-24-2 Benzo(g,h,i)perylene R I 00OU
86-30-6 N-Nitrosodiphenytomine R 1000U
115-3 4-Blromophenyl-plienylether R 1000U
118-74-1 Hexachlorobenzene R 100OU
87-86-5 Pentachtorophenol R 520OU
85-01-5 Phenanthrene R 1000U
120,12,7' Anthracene R 1000U
a4-74-2 Di-n-butytphthalate 33001... Lk.
206-44-0 Fluoranthene, R 100OU
129-00-0 Pyrene R 100OU
85-6a-7 Butylbenzylphthalate R 1000U
91-94-1 3,3'-Dichtorobenzidine R 2100U
56-55-3 Uenzo~a)anthracene R 1000U
117-81-7 bis(2-Ethythexyl)phthatate R 1000U
218-01-9 Chrysene, R 1000U
117-84-0 Di-n-octylphthalate R 1000U
205-99-2 Benzo(b)fluoranthene R 100OU
207-08-9 Benzo(k)fluoranthene R 1000U
50-32-8 Benzo(a)pyrene R 1000U
193-39-5 Indeno(1,2,3-cd)pyrene R 1000U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The numaber is the attainable detection limit for the sample.
B - Analyte was founid In the reagent blank as well as the sample.
J - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-106

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
INA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS ID: 901206-045 Customer Sample ID: N-123
Laboratory: Organic Mass Spectroscop~y Laboratory Customer: J. KESSNER/R. SHUCK
Sample Matrix: SOIL File ID: 3,14474
Level: (low/mad): LOW Date Received: 5-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 2-JAN-1991
% Moisture: not dec. 8.5 dec. _____Date Extracted: 13-DEC-1990
Extraction: CSepF/Cont/Sonc) SoxH PH: ____
GPC Cleanup: (YIN) Nj
Concentration Units
Number TICs founid: 20 Cug/L or ug/Kg): _tsgK2
CAS NUMBER COMPOUND NAME RT EST. CONC.
I1. 123-42-21 2-Pentanone. 4-hydroxy-4-methy
2. 1 UNKNOWN
I3.1 UNKNOWN ALCOHOL
I .65- --- iOfl0 -
15.721 95011 J
438 07 --- I d9 -
I~e
4 .___ _ 1 UNKNOWN 10.90I No"I do
I5.
6.
I7.
jUNKNOWN
JUNKNOWN
jUNKNOWN
I 19.0
i9.?e I40
20!.90 I3e
3neOIJ ! d
I~ d9o
I de
a .
9.
jUNKNOWN HYDROCARBON
1UNKNOWN PHTHALATE ESTER
I 3.7 f I
-?*-~ 60 -~
I11. IUNKNOWN HYDROCARBON I, jt- I
1 2.
I13.
14.
IANTHRACECOTONE
IUNKNOWN HYDROCARBON
IUNKNOWN HYDROCARBON
I65
I
I
j I
Q00
9;
d o
i IM)0
I .
I15. IUNKNOWN HYDROCARBON 2e.7 F9 -"GO Ie-
16. IUNKNOWN ALKOXY COMPOUND j -9.159O
17. IUNKNOWN HYDROCARBON 29.81 I2900 .1
18. IUNKNOWN HYDROCARBON I 3
0.85, C o--o
19.
I20.
UNKNOWN HYDROCARBON
IUNKNOWN HYDROCARBON
I 5l.?V ;8700 I "
nan.7I
121. II___
122. II___
123. IIIJ___
124. J__ _
125. III___
126. III___
127. I __ _ I
28.IIJ__ _
129. IIJ___
130.I I
Data Reporting Qualifiers:
U -Compound was analyzed for but not detected. The numb~er is the attainable detection Limit for the sample.
B8 Analyte was found in the reagent blank as well as the sample.
J Indicates an estimated value.
ND -Not detected.
A Aldol condensation product.
D Secondary dilution.
E -Exceeds initial calibration range.
P -Probable Identification. D-107

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of I
AnaLlS ID: 901206-045 Customer Sample 10: N-123
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File 10: 07595 Sample Matrix: SOIL
Instrument ID: 5970#2 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 5-DEC-1990
VOA -Volatie organic Compounds CTCL)
Date Extracted/Prepared: Date Analyzed: 10-DEC- 1990
Preparation Procedure Number: PURGE & TRAP Analysis Procedure Number: VGA CCLP) NDP
Percent Moisture: 9 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: SL STAFFORD
Associated Blank: 901210-025 GA File Nuber: NA
Dl : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
74-87-3 Chtoromethane 11U 79-00-5 1.1,2-Trichloroethane 5U
74-83-9 Broi methane 11U 71-43-2 Benzene 5U
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1.3-Dichtoropropene SU
75-00-3 Chloroethane 11t; 75-25-2 Bromoform 5U
75-09-2 Methytene Chloride -5 2n- LA 108-10-1 1-Methyt-2-pentanone 11U
67-61 Acetone 17- S 1A 591-78-6 2-Ilexanone 1 1U
75-15-0 Carbon Disulfide SU 127-18-4. Tetrachloroethene 5U
75-35-4 1,1-Dichloroethene 5U 79-34-5 1,1.2,2-TetrachLoroethane 5U
75-34-3 1,1-Dichtoroethane 5U 108-88-3 Toluene 5U
540-59-0 1,2-Dichloroethene (total) 5U 108-90-7 Chlorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5U
107-06-2 1,2-Dichloroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Butanone 11U 1330-20-7 Xyleme (total) 5U
71-55-6 1,1,1-Trichtoroethane 5U
56-23-5 Carbon Tetrachloride 5U
108-05-4. Vinyl Acetate 11U
75-27-4 Bromodichioromethane 5U
1006-01-5 c1,3-Dchorropone 5U
7806-87-5 c1,-Dichloroprne 5U
79-01-6 TiichLoroethene 5U
124-48-1 Dibromochtoromethane 5U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Anslyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-108

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORiT Page 1 of 2
AnaLIS ID: 901206-046 Customer Samiple ID: N-124
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: ),14475 Sample Matrix: SOIL
Instrument ID: MP-5985 Requisition Number:
Authorized Dy: 0. C. Canada Date Sample Received: 5-DEC-i990
DNA - lase/Meutral/Acid Compounds (TCL)
Date Extracted/Prepared: 13-DEC- 1990 Date Analyzed: 2-JAN- 1991
Preparation Procedure Nurter: Analysis Procedure Number: DNA (CLP) HOP
Percent Moisture: 7.1 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Stank: 901214-083 CA File Number: NA
U:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
108-95-2 Phenol ft 1000W 106-47-8 4-ChtoroaniLine ft 10003
111-44-4 bisC2-Chloroethyt)ether ft 100013 87-68-3 Hexachtorobutadiene R 10013
95-57-8 2-Chlorophenot ft 100013 59-50-7 4-Chloro-3-methylphevot ft 100013
541-73-1 1,3-Dichtorobenzene ft 100013 91-57-6 Z-Methyinaphthalene ft 10001
106-46-7 1,4-Dichlorobenzene ft 1000U 77-47-4 Hexachtorocyclopentadiene ft 10001
100-51-6 Renzyl Alcohol ft 100013 88-06-2 2,4,6-Trichtorophenot ft 10003
95-50-1 1,2-Dichiorobenzene ft 10003 95-95-4 2,4,5-Trichlorophenot ft 480013
95-48-7 2-MethylphenoL ft 100013 91-58-7 2-Chloronaphthatene ft 100013
108-60-1 bis(2-Chloroisopropyt)ether ft 100013 88-74-4 2-Nitroanitine Rt 680013
106-44-5 4-Methylphenol R 100013 131-11-3 Dimethyiphthatate ft 100013
621-64-7 N-Nitroso-di-n-propylamine ft 10003 208-96-8 Acenaphthylene ft 1000U
67-72-1 Hexachloroethane ft 100013 99-09-2 3-NitroaniLine ft 48001U
98-95-3 Nitrobenzene ft 10003 83-32-9 Acenaphthene ft 100013
78-59-1 Isophorone ft 100013 51-28-5 2,4-Dinltrophenot ft 48001U
88-75-5 2-Nitrophenol ft 10001. 100-02-7 4-Nitrophenol ft 480013
105-67-9 2,4-pimethyiphenol ft 100013 132-64-9 Dibenzofuran ft 100013
65-85-0 Benzoic Acid R 480013 121-14-2 2,4-Dinitrotoluene ft 100013
111-91-1 bis(2-Chtoroethoxy)methane ft 100013 606-20-2 2,6-Dinitrotoluene ft 100013
120-83-2 2,4-Dichtorophenol ft 100013 84-66-2 Diethylphthatate ft 10003
120-82-1 1,2,4-Trichlorobenzene ft 100013 7005-72-3 4-Chlorophenyi-phenytether ft 100013
91-20-3 Naphthalene ft 10003 86-73-7 Fluorene R 100013
Data Rteporting Oualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
NO - Not detected.
A - Aldot condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-109

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
naLIS ID: 901206-046 Customer Sample ID: U-124
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: >14475 Sample Matrix: SOIL
Instrument ID: HP-5985 Requisition Numer:
Authorized Dy: D. C. -Canada Date sample Received: 5-DEC-1990
BNA - Base/Neutral/Acid Compounds CTCL)
Date Extracted/Prepared: 13-DEC- 1990 Date Analyzed: 2-JAN-1991
Preparation Procedure Number: Analysis Procedure Number: DNA (CIP) NDP
Percent Moisture: 7.1 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Dlank: 901214-083 OA File Numrber: NA
U:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
..............................................----------.............................. ..........
100-01-6 4-Nitroaniline R 4800UJ 53-70-3 Oibenz(a~h)anthracene R 1000u
534-52-1 4,6-Dinitro-2-methylphenot R 48D0U 191-24-2 Denzo(gh,I)perytene R 1000U
86-30,6 N-Nltrosodlphenylamine ft 1000U
101-55-3 4-Dromophenyl-phenytether Rt 1000U
118-74-1 Hexachlorobenzene ft IOOOU
87-86-5 PentachlorophenoL ft 4800U
85-01-8 Phenanthrene ft 1000U
120-12-7 Anthracene R 1000U
84-74-2 0l-n-butytphthatate 3700'ts, Lt.
206-44-0 FLuoranthene ft 1000.3
129-00-0 Pyrene ft 1000U
85-68-7 Dutylbenzylphthalate ft 1000tU
91-94-1 3,3'-DichLorobenzidine R 2000U
56-55-3 Denzo~a)anthracene ft 1000U
117-81-7 bis(2-Ethylhexyt)phthaLate ft 1000U
/
218-01-9 Chrysene R 1000U
117-84-0 Di-n-octylphthatate ft 1000U
205-99-2 Benzo(b)fluoranthene ft 1000UI
207-08-9 Denzo(k)fluoranthene ft 1000U
50-32-8 Denzo(a)pyrene ft 1000U
193-39-5 Indeno~l.2,3-cd)pyrene Rt 1000U
Data Reporting Qualifiers:
V /?
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
9 - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-110

WIlC-SD-EI-TI-136, Rev. ')
Oak Ridge K-25 Site
Anal ytical Chemistry Department
INA CTCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS ID: 901206-046 Customer Sample 10: N-124
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Sample Matrix: SOIL Fite ID: ),14475
Level: (low/med): LOW Date Received: 5-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 2-JAN-1991
% Moisture: not dec. 7.1 dec. _____Date Extracted: 13-DEC-1990
Extraction: (SepF/Cont/Sonc) SoxH pH: ____
GPC Cleanup: (Y/N) N
Concentration Units
Nuber TICs found: 20 Cug/L or uglKg): u2LK2
CAS NUMBER COMPOUND NME RT IEST. CONC. a
~ O ~
1.
I2.
I3.
I4.
123-42-21 2-Pentanone. 4-hydroxy-4-methy
1 UNKNONW ALCOHOL
1 UNKNOWN ALCOHOL
1 UNKNOWN
6.! I
Q18
+6i; 2
"A-u
66 8J
~ 3000 in~ -
Me H3~
I5.
I6.
I7.
8.
1 UNKNOWN
1 UNKNOWN
1 UNKNOWN
1 UNKNOWN HYDROCARBON ~
1?.ee I 10I.I
19,10I 7OOI ~
288 Z500 4-46-~
M .oIS 658oI
9. [UNKNOWN PHTHALATE ESTER N .6?. 1.
I10. IUNKNOWN HYDROCARBON I 24.84 I1500I
11. IUNKNOWN HYDROCARBON 22.090
I12. IANTHRACECOIONE 28e i 1OOis .D
13. [UNKNOWN HYDROCARBON ?63 8 0I.
14. [UNKNOWN HYDROCARBON N9T.66 1 leg d .
15. UNKNOWN HYDROCARBON ?0Z.;c4 XCOG.I '
16. ______jUNKNOWN ALKOXY COMPOUND I cy.se F 0 IJ
I17. jUNKNOWN HYDROCARBON 1 29.80 1 2100 j.
18. UNKNOWN HYDROCARBON i n RA iOj4.
19. UNKNOWN HYDROCARBON 34~.68 6;90o~
20. jUNKNOWN ALKOXY COMPOUND j 37.26 j1200 j 1
121.1__ _ _ _ _ _ _ _ _ _ j__ _ _ __ _ _ I__ _
122.111__ _ _ 1__ _
123.1__ _ _ _ _ _ _ _ _ _ __ _ _ 1__ _ _ 1__ _
124. I
125. II
126. I I
127. II
128. I
129.I I
130. II
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J Indicates an estimated value.
RD -Not detected.
A - AldoL condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
P-Probable identification. D-111

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 1
AnaLiS ID: 901206-046 Customer SuuLe ID: N-124
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite ID: 07596 Samp~le Matrix: SOIL
instrument ID: 597002 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 5-DEC-1990
VOA - Volatile organic Compounds (TCL)
Date Extracted/Prepared: Date Analyzed: 10-DEC- 1990
Preparation Procedure Numb~er: PURGE & TRAP Analysis Procedure Number: VGA (CLP) MOP
Percent Moisture: 7 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: SL STAFFORD
Associated Blank: 901210-025 OA File Number: NA
El: Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
74-87-3 Chtoromethane 11U 79-00-5 1,1,2-Trichloroethane 5U
74-83-9 Uromomethane 11U 71-43-2 Benzene 5U
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1,3-Dichtoropropene SU
75-00-3 Chloroethane 11U 75-25-2 Bromoform 5U
75-09-2 Methylene Chloride £ dt0 LA 108-10-1 4-Methyl-2-pentanone 111)
67-64-1 Acetone 25 -& (A 591-78-6 2-Hexanone 11U
75-15-0 Carbon Disulfide 5U 127-18-4 Tetrachioroethene S1)
75-35-4 1,1-Dichioroethene 5U 79-34-5 1,1,2,2-Tetrachioroethane 5U
75-34-3 1,1-Dichloroethane SU 108-88-3 Toluene 5U
540-59-0 1,2-Dichtoroethene (total) 5U 108-90-7 ChLorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5U
107-06-2 1,2-Dichloroethane 5U 100-42-5 Styrene 5U
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1,1,1-Trichloroethane 5U
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate 11U
75-27-4 BromodichLoromethane 5U
78-87-5 1,2-Dichtoropropane 5U
10061-01-5 cis-1,3-Dichtoropropene 5U
79-01-6 Trichloroethene 5U
124-48-1 Dibromochtoromethane 5U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-112

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of 2
AnaLlS ID: 901206-047 Customer Sample ID: N-125
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: )14476 Sample Matrix: SOIL
Instrum~ent ID: MP-5985 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 5-DEC-1990
SNA -Base/NeutraL/Acid Compounds CTCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 2-JAN-1991
Preparation Procedure Number: Analysis Procedure Numb~er: INA (CLP) NOP
Percent Moisture: 6.5 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Blank: 901214-083 CA Fite Numiber: NA
[I : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
108-95-2 Phenol R 1000U 106-47-8 4-Chloroaniline R 1000U
111-44-4 bis(2-Chtoroethyl)ether R I 000U 87-68-3 Hexachtorobutadiene R 100OU
95-57-8 2-Chtorophenol ft 1000U 59-50-7 4-Chloro-3-methylphenol ft 1000U
541-73-1 1,3-Dichlorobenzene ft I00OU 91-57-6 2-Methylnaphthalene ft IOOOU
106-46-7 1,4-Dichlorobenzene R I1000t) 77-47-4 Hexachlorocyclopentadiene R 1000U
100-51-6 Benzyl Alcohol R 1000U 88-06-2 2.4,6-Trichlorophenol t R OOOU
95-50-1 1,2-Oichlorobenzene R IOOOU 95-95-4 2,4.5-Trichlorophenol ft 5100U
95-48-7 2-Methytphenol R 100OU 91-58-7 2-ChLoronaphthatene R 1000U
108-60-1 bis(2-Chloroisopropyl)ether ft I000U 88-74-4 2-Nitroaniline R 5100U
106-44-5 4-Methytphenol ft 1000U 131-11-3 Dimethylphthalate R 100OU
621-64-7 N-Nitroso-di-n-propylamine R 1000U 208-96-8 Acenaphthylene R 1000U
67-72-1 Nexachloroethane R 1000U 99-09-2 3-Nitroaniline ft 5100U
98-95-3 Nitrobenzene ft 100OU 83-32-9 Acenaphthene R 1000W
78-59-1 Isophorone R 1000U 51-28-5 2,4-Dinitrophenol ft 5100tJ
88-75-5 2-Nitrophenol ft 100WU 100-02-7 4-Nitrophenol ft 5100U
105-67-9 2,4-Dimethytphenol ft IOOOU 132-64-9 Dibenzofuran ft 1000U
65-85-0 Benzoic Acid R 5100U 121-14-2 2,4-Dinitrotoluene ft 1000U
111-91-1 bis(2-Chloroethoxy)methane ft 1000U 606-20-2 2,6-Dinitrotoluene R 1000U
120-83-2 2,4-Dichlorophenol R 100WU 84-66-2 Diethylphthalate R 1000U
120-82-1 1,2,4-Trichlorobenzene R 100OW 7005-72-3 4-Chtorophenyl-phenytether R 1000W
91-20-3 Naphthalene R 100WU 86-73-7 Fluorene ft IOOOU
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The numb~er is the attainable detection limit for the sample.
B - Anulyte was found in the reagent blank as well as the sample.
J- Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D- 113

u;IC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT *Page 2 of 2
AnaLiS ID: 901206-047 Customer Sample ID: N-125
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite ID: )14476 Sample Matrix: SOIL
Instrument ID: HP-5985 Requisition Numb*er:
Authorized By: 0. C. Canada Date Sample Received: 5-DEC-1990
BNA - Base/Neutral/Acid Compounds (TCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 2-JAN- 1991
Preparation Procedure Number: Analysis Procedure Number: SNA (CIP) NDP
Percent Moisture: 6.5 Dilution Factor: 1.0
Percent moisture (decanted): Analyst: AK HEADRICK
Associated Btank: 901214-083 GA File Number: NA
11 : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
.................................. .......... ........... .............................. ..........
100-01-6 4-Nitroaniline Rt 5 100U 53-70-3 Dibenz~a~h)anthracene R 1000u
534-52-1 4,6-Dinitra-2-methytphenot R 5100U 191-24-2 Uenzo(g,h,i)perylene R 1000U
86-30-6 N-Nitrosodiphenylamine R 1000tJ
101-55-3 4-Bromopheny-phenylether R 100OU
118-74-1 Hexachlorobenzene R 1000U
87-86-5 Pentachlorophenol R 5100U
85-01-8 Phenanthrene 2200
120-12-7 Anthracene R 1000U
84-74-2 Di-n-butylphthaLate 5 6 00 11,u
206-44-0 Fluoranthene R IOOOU
129-00-0 Pyrene R IOOOU
85-68-7 ButytbenzylphthaLate R 1001.
91-94-1 3,3'-DichLorobenzidinte R 2101U
56-55-3 Benzo(a)anthracene R 1000U
117-81-7 bis(2-Ethythexyt)phthalate R 1000U
218-01-9 Chrysene R 1001.
117-84-0 Di-n-octylphthalate R 1000U
205-99-2 Uenzo(b)ftuoranthene R 1000U
207-08-9 Denzo(k)fLuoranthene R 1000U
50-32-8 Benzo(a)pyrene R 10011
193-39-5 Indeno(1,2,3-cd)pyrene R 1000U
Data Reporting Qualifiers:
U -Compound was analyzed for but not detected. The numiber is the attainable detection limit for the sample.
B Analyte was found in the reagent blank as well as the sample.
J -Indicates an estimated value.
NDO Not detected.
A -Aldol condensation product.
D -Secondary dilution.
E -Exceeds initial calibration range.
D-1214

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
DNA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS ID: 901206-047 Customer Sam~ple iD: N-125
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J9. KESSNER/R. SHUCK
Sample Matrix: SOIL File ID: ),14476
Level: (Low/med): LOW Date Received: 5-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 2-JAN-1991
% Moisture: not dec. 6.5 dec. _____Date Extracted: 13-DEC-1990
Extraction: (SepFlContlSonc) SoxH pH: ____
GPC Cleanup: (YIN) N
Number TICs fo und: 20
Concentration Units
(ugIL or uglKg): ug/K2
CAS NUMBER COMPOUND NAME FIT EST. CONC. a
1 . 123-42-21 2-Pentanone, 4-hydroxy-4-methy I 5.7 it ftsee
I2. 1 UNKNOWN HYDROCARBON j 14.12 I 12000 I~
I3. .jUNKNOWN HYDROCARBON j 16.03 I 23000 I.
I4. 1UNKNOWN HYDROCARBON J 17.3e Fees .~
I5. jUNKNOWN HYDROCARBON j 17.81 I 22000 J I
I6. jUNKNOWN HYDROCARBON j 18.56 I8500 I.
I7. jUNKNOWN HYDROCARBON j 18.82 12000 J.
I8.
I9.
UNKNOWN HYDROCARBON
[UNKNOWN
j
1
19.46 I
19.741
28000 1 9
22000 1I
10.
I11.
I12.
I13.
jUNKNOWN HYDROCARBON
1UNKNOWN
UNKNOWN HYDROCARBON
UNKNOWN HYDROCARBON
j
j
j
20.41 I8200 . 1
2 0.94 I 1eee" Ido
20.98 j 17000 . 1
21.70 j 25000 1 .
14.
15.
UNKNOWN HYDROCARBON
jUNKNOWN HYDROCARBON
j
J
22.46 j
22.55 l
42000
23000
1 .
1 9
16. IUNKNOWN HYDROCARBON ; 1.s4 4- 34e00 1 do
17.
18.
IUNKNOWN HYDROCARBON
IUNKNOWN HYDROCARBON
I 23.96 1 18000 1 .9
2 - 1 &-4------VT_-t-1j .9
19. IUNKNOWN HYDROCARBON 26.I40 1 2C;0 i.
20. IUNKNOWN HYDROCARBON I" 2768seC3I
121. III.._ _ _
122.II ___I
123. III. _ _
j24. ___I
125.I I__ _
126.I ___I
127. II___I
28. ___I
129.I I ___I
130. II. __
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number Is the attainable detection limit for the samp'le.
B - Analyte was found in the reagent blank as well as the sample.
J.- Indicates an estimated value.
ND - Hot detected.
A - Aldot condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
P - Probable Identification. D-115

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page I of I
AnaLIS ID: 901206-047 Customer Sample ID: 36-125
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. XESSNER/R. SHUCK
File ID: 07620 Sample Matrix: SOIL
Instrument ID: 597002 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
VOA -Volatile Organic Compounds (TCL)
Date Extracted/Prepared: .Date Analyzed: 11-DEC-1990
Preparation Procedure Numb~er: PURGE & TRAP Analysis Procedure Number: VOA (CLP) NDP
Percent Moisture: 7 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: GL MUDOLESTON
Associated Blank: 901211-004 OA File Numb~er: NA
(3:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
74-87-3 Chloromethane 11U 79-00-5 1,1,2-Trichloroethane 5U
74-83-9 Bromomethane 11U 71-43-2 Benzene SU
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1.3-DichLoropropene SU
75-00-3 Chloroethane 11U 75-25-2 Bromoform SU
75-09-2 MethyLene Chloride 5U 108-10-1 4-Methyt-2-peitanone 11U
67-64-1 Acetone 11U 591-78-6 Z-Hexanone 11U
75-15-0 Carbon Disulfide 5U 127-18-4 TetrachLoroethene 5U
75-35-4 1,1-Dichtoroethene 5U 79-36-5 1,1,2,2-Tetrachtoroethane 5U
75-34-3 1*1-Dichtoroethane 5U 108-88-3 Toluene 5U
540-59-0 1,2-Dichloroethene (total) SU 108-90-7 Chlorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5U
107-06-2 1,2-Dichtoroethane SU 100-42-5 Styrene 5U
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) 5U
71-55-6 1,1,1-Trichloroethane su
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate 11U
75-27-4 Bromodichloromethane 5U
78-87-5 1,2-Dichloropropane 5U
10061-01-5 cis-1,3-Dichloropropene 5U
79-01-6 rrichloroethene 5U
124-48-1 Dibromochtoromethane 5U
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
RD - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E -Exceeds initial calibration range.
D-116

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical chemistry Department
VOA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS ID: 901206-047 Customer Sample ID: N-125
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J.-KESSNER/R. SHUCK
Sample Matrix: SOIL File ID: 07620
Level: (Lowlmed): LOW Date Received: 6-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 11-DEC-1990
% Moisture: not dec. 7
Concentration Units
Numiber TICs founbd: I (ug/L or uglKg): ugLKg
CAS NUMBER COMPOUND NAME R T IEST. CONC. 0
1. 76-13-11 Freon 113 4-4 I.Q1-------.41j.
12. _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _1_ _ _ _1_ _
3.-_ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _1_ _ _ _1_ _
4'.__
6.
1 6.
~7.-II
_ _1_
1_
_
_
_
_
_
_
_ _
_
_
_
_
_
_ .II_ _
18.
19. II___
1_ _ _ 1 I
110.II__
I11.II__
112.
113. II_
_ _ _
_ _ _
I _ _ _ I_
_ _ _ _I_ _
_
_ _
II
I
_
_I_ _
_
_
114.__ _ _ _1II_
_ _ _ _I_ _ _
115. _ _ _ _1_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _ _I_ _ _ I
116.1 __ _ _ __ _ I
117.__ _ _ _1II_
118. _ _ _ _1II_
_ _ _ _I_ _ _
_ _ _ _I_ _ _ I
119.1 L__ _ _ __ _ I
120. 1II_ _ _ _ _ _
121. 1I_ _ _ _ _ _
122. __ _ _ _ _ _ _ _ _ _ 1__ _ _ 1__ _ _ 1__ _ I
123.1__ _ _ _ _ _ _ _ _ _ 1__ _ _ _1_ _ _ _ 1__ _ I
126. 1_ _ _ _ _ _ _ _ _ _ _
127. 1_ _ _ _ _ _ _ _ _ _ _
128.1__ _ _ _ _ _ _ _ _ _ 1 I
129.1 _ _ _ _ _ _ _ _ _ _ 1 I
I30. 1_ _ _ _ _ _ _ _ _ _ _
Data Reporting Qualifiers:
U -Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D Secondary dilution.
E -Exceeds initial calibration range.
P -Probable Identification.
D- 117

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 2
AnaLIS 1D: 901206-049 Customer Sample ID: N-126
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File 1D: 3,14511 Sample Matrix: SOIL
Instrument ID: HP-5985 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
BNA - Base/Neutral/Acid Compounjrds CTCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 17JA(19/
Preparation Procedure Numiber: Analysis Procedure Number: SNA C(e,.D
Percent Moisture: 8.3 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Blank: 901214-083 QA File Number: NA
(I : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
...... ........................... .......... ........... .............................. ..........
108-95-2 Phenol 110007 106-47-8 4-Chloroanitine 11000 7
111-44-4 bis(2-Chloroethyl)ether 11000 7 87-68-3 Nexachtorobutadiene 11000U7
95.57-8 2-Chtorophenot 11000.7 59-50-7 4-Chloro-3-methylphenot 1100071
541-73-1 1,3-Dichlorobenzene 11000.7 91-57-6 2-MethyLnophthaLene i0ou J
106-46-7 1,4-Oichlorobenzene 110oo)07 77-47-4 Nexachtorocyclopentadiene 11000 7
100-51-6 Benzyl Alcohol 11000 7 88-06-2 2,4,6-Trichlorophenot 1100U o
95-50-1 1,2-Dichlorobenzene 110007 95-95-4 2,4,5-Trichlorophenot 5200U07
95.45.7 2-MethytphenoL 1100U7T 91-58-7 2-Chloronaphthatene 110007T
108-60-1 bis(2-Chlorolsopropyt)ether 1100UJ3- 88-74-4 2-NitroaniLine 5200.3
106-44-5 4-MethylpienoL
621-64-7 N-Nitroso-di-n-propyanine
110007
11001.13
131-11-3 DimethyLphthaLate
208-96-8 Acenaphthylene
1100o)03
11000 7
67-72-1
98-95-3
Hexachioroethane
Nitrobenzene
11000 7
110007
99-09-2 3-Nitroaniline
83-32-9 Acenaphthene
52000 JT
11000 3'
78-59-1 Isophorone 11000 7 51-25-5 2,4-Dinitrophenol 5200U 7
88-75-5 2-Nitrophenol 1100U7, 100-02-7 4-Nitrophenot 5200U07
105-67-9 2,4-Dimethylphenol 11000,7 132-64-9 Dibenzofuran l11000X
65-55-0 Benzoic Acid 5200U-T 121-14-2 2.4-Dinitrotoluene 1100U.7
111-91-1 bis(2-ChLoroethoxy)methane 110007 606-20-2 2,6-Dinitrotoiuene 11000 T
120-83-2 2,4-Dichlorophenol 10007J 84-66-2 Diethylphthalate 11000 7
120-82-1 1,2,4-Trichlorobenzene 11000 7 7005-72-3 4-Chtorophenyl-phenytether 1100U,7
91-20-3 Naphthalene 110007 : 86-73-7 Fluorene 11000 7
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The Kx. er is the attainable detection Limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-118
%1

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
8NA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS ID: 901206-049 Customer Sample ID: N-126
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Sample Matrix: SOIL File ID: 2-14511
Level: (Low/med): LOW Date Received: 6-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 17-JAN-1990
% Moisture: not dec. 8.3 dec. _____Date Extracted: 13-DEC-1990
Extraction: (SepFlContlSonc) SoxH pH: ____
CPC cleanup: (YIN) N
Concentration Units
Num~ber TICs found: 20 (ugIL or ug/Kg): u2L2
CAS NUMBER COMPOUND NAME RT EST. CONC. 0
an:~~ nu:V~zz=2 n~arsf :n:. n m~ 1 ... .... .Z
I1. 123-42-21 2-Pentanone, 4-hydroxy-4-methy S.P IA- 440 A IlO
2. 1UNKNOWN HYDROCARBON I 14.13 I 7800 1
3. IUNKNOWN HYDROCARBON I 16.02 I 13000 1
4. IUNKNOWN HYDROCARBON 1 469 4 .43" do
6. _ UNKNOWN HYRCRO 17.781 100 J
6 .
I7.
IUNKNOWN HDOABNI
IUNKNOWN HYDROCARBON I
18.54
18.79 I
10001
5800 J
a. IUNKNOWN HYDROCARBON I 19.41 1 6000 J
I9. IUNKNOWN 19I.R0 ROOI.. d
1 1. IUNKNOWN HYDROCARBON I 20.38 1 4200 J
1 11. IUNKNOWN HYDROCARBON I 20.97 I 15000 J
12.
13.
IUNKNOWN HYDROCARBON
IUNKNOWN HYDROCARBON
I
I
21.67 I
22.43 I
8400
16000
1
1
14. UNKNOWN HYDROCARBON I 22.52 I 8400 J
15. UNKNOWN HYDROCARBON HIB We de-I."
16. UNKNOWN HYDROCARBON I 23.93 I 7300 J
17.
18.
19.
UNKNOWN HYDROCARBON
UNKNOWN ARAMATIC KETONE
[UNKNOWN HYDROCARBON
25.4
260 I
26 238
; 0C0 le-O
9"&c I
I3' I
20. jUNKNOWN HYDROCARBON Z7.4 5;
*0 -asoI
121.______ I
122.__ _ _ _ II I
123. _ _ _ _ 1IIII
124. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _I_ _ _ _ _I_ _ _ _ _I_ _ _
25. 1__________________1______ ______1____
126. _ _ _ _ _1_ _ _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _ _ _ _ _ _ _1_ _ _
127. _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _1_ _ _ _ _1_ _ _ _ _1_ _ _
128.1__ _ _ _1_ _ _ _ 1__ _ I
129. __ _ _ _I_ _ _ _ i__ _ I
130.1__ _ _ _1_ _ _ _ 1__ _
Data Reporting Qualifiers:
U - Compoun~d was analyzed for but not detected. The number is the attainable detection limit for the sample.
B -Analyte was found in the reagent blank as well as the sample.
J4 Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D0 Secondary dilution.
E - Exceeds initial calibration range.
P - Probable Identification. D-119
~

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of I
AnaLiS ID: 901206-049 Customer Sample ID: N-126
Laboratory: organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File ID: 07637 Sample Matrix: SOIL
Instrument ID: 597002 Requisition Number:
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
VOA -Volatile Organic Compounds CTCL)
Date Extracted/Prepared: Date Analyzed: 12-DEC-1990
Preparation Procedure Number: PURGE & TRAP Analysis Procedure Numb~er: VOA CCLP) NOP
Percent Moisture: 8 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: GL HUDDLESTON
Associated Blank: 901212-004 QA File Niuber: NA
C] : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
...... ........................... .......... ........... .............................. ..........
74-87-3 Chtoromethane 11U 79-00-5 1,1,Z-Trichioroethane SU
74-83-9 Uronmmthane 11U 71-43-2 Benzene 5U
75-01-4 Vinyl Chloride 11U 10061-02-6 trans-1,3-Dichtoropropene SU
75-00-3 Chloroethane 11U 75-25-2 Bromnoform 5U
75-09-2 Methylene Chloride 109.3. LAk 108-10-1 4-Methyt-2-pentanone 11U
67-64-1 Acetone 54'S. LA 591-78-6 2-Hexanone 11U
75-15-0 Carbon Disulfide 5U 127-18-4 Tetrachtoroethene 5U
75-35-4 1,1-Dichloroethene 5U 79-34-5 1,1.2,2-Tetrachtoroethane 5U
75-34-3 1,1-Dichloroethane 5U 108-88-3 Toluene 5U
540-59-0 1,2-Dichloroethene (total) 5U 108-90-7 Chlorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5U
107-06-2 1,2-DichLoroethane SU 100-42-5 Styrene 5U
78-93-3 2-Butanone 11U 1330-20-7 Xylene (total) SU
71-55-6 1,1,1-Trichtoroethane 5U
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate 11U
75-27-4 Bromodichtoromethane SU
1006-01-5 c1,3-Dichorropone 5U
7806-87-S
79-01-6
124-48-1
c1-Dichloroprne
Trichloroethene
Dibromochioromethane
5U
5U
5U 6 7
q
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
* - Analyte was found in the reagent blank as well as the sample.
J- Indicates an estimated value.
RD - Not detected.
A - Aldol condensation product.
0 - Secondary dilution.
E - Exceeds initial calibration range.
D-120

WHC-S-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of 2
AnaLIS ID: 901206-050 Customer Sample ID: N-127
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fit. ID: r14481 Sample Matrix: SOIL
Instrument 1D: HP-5985 Requisition Numiber:
-Authorized By: 0. C. Canada Date Samp~le Received: 5-DEC-1990
BRA - Base/Neutral/Acid Comp~ounds (TCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 3-JAN-1991
Preparation Procedure Number: Analysis Procedure Number: BHA (CLP) MOP
Percent Moisture: .1 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK HEADRICK
Associated Slank: 901214-083 QA File Number: NA
H : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
............................... .......... ........... .............................. ..........
108-95-2 Phenol 960UJ 106-47-8 4-ChLoroanilne 960U5
111-44-4 bis(2-ChtoroethyL)ether 960U _ 87-68-3 Hexachlorobuztediene 960U 3
95-57-8 2-ChLorophenol 960U .7 59-50-7 4-Chloro-3-methylphenol 960U-1
541-73-1 1,3-Dichlorobenzene 960) 91-57-6 2-Methytnephthalenve 96OU 7
106-46-7 1,4-Dichlorobenzene 960U Y 77-47-4 Hexachlorocyctopentadiene 960UJ'
100-51-6 Benzyl Alcohol 960U 7 88-06-2 2,4,6-TrichLorophenot 960U 7
95-50-1 1,2-Dichlorobenzene 960U j 95-95-4 2,4.5-Trichlorophenol 480DU J
95-48-7 2-Methyiphenoi 960U7j 91-58-7 2-Chtoronaphthalene 960U 7
108-60-1 bisC2-Chloroisopropyt)ether 960U 7 88-74-4 2-Nitroaniline 4800 11
106-44-5 4-Methytphenot 960U 7 131-11-3 Dimethytplithatate 96DU Jr
621-64-7 N-Nitroso-di-n-propylamine 960U T 208-96-8 Acenaphthylene 960U X
67-72-1 Hexachloroethane 960U3- 99-09-2 3-Nitroaniline 4800U j
98-95-3 Nitrobenzene 960U-Y 83-32-9 Acenaphthene 960UT
78-59-1 Isophorone 960U X 51-28-5 2,4-Dinitrophenol 4800U,7
88-75-5 2-Nitrophenol 960U 3 100-02-7 4-Nitrophenol 4800U 7
105-67-9 2,4-Dimethylphenol 960U T 132-64-9 Dibenzofuran 960U Z
65-85-0 Benzoic Acid 4800U T 121-14-2 2,4-Dinitrototuene 960U 7
111-91-1 bis(2-Chloroethoxy)methane 960U 7 606-20-2 2,6-Dinitrotoluene 960U3r
120-83-2 2,4-Dichlorophenol 960UT 84-66-2 Diethytphthatate 960U.17
120-82-1 1,2,4-Trichlorobenzene 960U 7 7005-72-3 4-Chtorophenyl-phenylether 960U 7
91-20-3 Naphthalene 960U J 86-73-7 Fluorene 960U 3
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the samrple.
B - Analyte was found in the reagent blank as well as the sanipte.
J - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-121

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 2 of 2
AnaLIS ID: 901206-050 Customer Sample ID: N-127
Laboratory: organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
File IN: 314481 Samwple Matrix: SOIL
Instrumient ID: NP-5985 Requisition Number:
Authorized By: 0. C. Canada Date Sample Received: 5-DEC-1990
BRA - Base/Neutral/Acid Compounmds (TCL)
Date Extracted/Prepared: 13-DEC-1990 Date Analyzed: 3-JAN-1991
Preparation Procedure Numb~er: Analysis Procedure Number: BNA (CLP) HOP
Percent Moisture: .1 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: AK NEADRICK
Associated Blank: 901214-083 OA File Numb~er: NA
II:Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
..................---------------- .......... ........... .............................. ..........
100-01-6 4-Nitroaniline 480OUZY 53-70-3 Dibenz(a~h)anthracene 960U7
534-52-1 4,6-Dinitro-2-methylpienot 4800U 7 191-24-2 Benzo(g~h,l)perylene 960U j
86-30-6 N-Nitrosodiphenylamine 960U 3
101-55-3 4-Bromophenyt-pIhenytether 960Uj
118-74-1 Nexachlorobenzene 960U:T
87-86-5 Pentachlorophenol 4800U 1
85-01-8 Phenanthrene 960Uj
120-12-7 Anthracene 960U 7
84-74-2 Di-n-butylphthalate 25001L Lk-y
206-44-0 Fluoranthene 96OU J-
129-00-0 Pyrene 960U 7
85-68-7 Butylbenzylphthalate 960U 7
91-94-1 3,3'-Dichlorobenzidine 2000U IT
56-55-3 Benzo(a)anthracene 960U.T
117-81-7 bis(2-Ethythexyl)phthalate 960U 3
218-01-9 Chrysene 960U 7
117-84-0 Di-n-.octylplithalate 960U T
205-99-2 Benzo(b)ftuoranthene 960U 3
207-08-9 Benzo(k)fluoranthene 960UT
50-32-8 Benzo~a)pyrene 960U,17
193-39-5 Indeno(1.2,3-cd)pyrene 960UJ '
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The numiber is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J - indicates an estimated value.
RD - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-122

WHC-S-EN-TI-136, Rev. 0
Oak Ridge K-25 Site
Analytical Chemistry Department
SNA (TCL) SOIL ORGANICS ANALYSIS DATA SHEETS
TENTATIVELY IDENTIFIED COMPOUNDS
AnaLIS ID: 901206-050 Customer Sample ID: 11-127
Laboratory: Organic Mass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Sample Matrix: SOIL Fite ID: >144.81
Level: (Low/med): LOW Date Received: 5-DEC-1990
Dilution Factor: 1.0 Date Analyzed: 3-JAN-1991
% Moisture: not dec. .1 dec. _____Date Extracted: 13-DEC-1990
Extraction: (SepF/Cont/Sonc) SoxH PH: ____
GPC Cleanup: (YIN) N
Concentration Units
Number TICs found: 20 Cug/L or ug/Kg): _uL~
I CAS NUMBER I COMPOUND NAME RT IEST. CONC.
j~zXX 1 = ==~z* ZZS23232.2..Zzu : =: I I..z 12C33221 ==z~
1.
I2.
I3.
I4.
I5.
6.
I7.
I8.
I9.
123-42-21 2-Pentanone. 4-hydroxy-4-methy
1 UNKNOWN ALCOHOL
1 UNKNOWN
1 UNKNOWN
IUNKNOWN
IUNKNOWN
IUNKNOWN HYDROCARBON
UNKNOWN HYDROCARBON
UNKNOWN PHTHALATE ESTER
j
L
j
j
I23.88
U=4-44&.-.
IO
16.9O------0O-...
~
19I.S. i8 j~
20c.88j -48064-n-
2I? 64
1390 J
mte
I
(10.
I11.
jUNKNOWN
jUNKNOWN HYDROCARBON
I 24.86!
23.00 1
5501
66e
12. jUNKNOWN AROMATIC KETONE 26.9i 70 3
13. jUNKNOWN HYDROCARBON Z6.34
14.
15.
116.
jUNKNOWN HYDROCARBON
jUNKNOWN HYDROCARBON
[UNKNOWN
j
j
PA
o.lu
29.701
4.5 500-1 .. o
)0IJ
8801
I
17. IUNKNOWN HYDROCARBON j 2.?9 liI . de-
18.
19.
I20.
(21.1
IUNKNOWN HYDROCARBON
IUNKNOWN ALKOXY COMPOUND
IUNKNOWN PHTHALATE ESTER
I
j
308 I
).&0
32.36 I1400
1 I
44GOI
IJ
I
(22. ___________________
(23.
(24.
125.1III
1_
J
_ _ _ _ _ _ _ _ _ _
(26.
(27.
III
I I
(28.1 I
29.__ _ _ II
130. I
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection Limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J- Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
P - Probable Identification. D-123

WHC-SD-EN-TI-136, Rev. 0
ANALYSIS DATA REPORT Page 1 of I
AnaLIS ID: 901206-050 Customer Sample ID: N1-127
Laboratory: Organic Kass Spectroscopy Laboratory Customer: J. KESSNER/R. SHUCK
Fite ID: 07635 Sample Matrix: SOIL
Instrument ID: 597002 Requisition Number:)
Authorized By: D. C. Canada Date Sample Received: 6-DEC-1990
VOA - Volatile Organic Compounds (TCL)
Date Extracted/Prepared: Date Analyzed: 12-DEC- 1990
Preparation Procedure Number: PURGE L TRAP Analysis Procedure Number: VOA CCLP) MOP
Percent Moisture: 0 Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: GL NUDDLESTON
Associated Stank: 901212-004 OA File Number: NA
H1 : Result has been Corrected for Spike
CAS ug/Kg CAS ug/Kg
74-87-3 Chtoromethane IOU 79-00-5 1.1.2-Trichtoroethane 5U
74-83-9 Bromomethane IOU 71-43-2 Benzene 5U
75-01-4 Vinyl Chloride IOU 10061-02-6 trans-1,3-DichLoropropene SU
75-00-3 Chloroethane lOU 75-25-2 Iromoform 5U
75-09-2 Methylene Chloride 9-0. 4 108-10-1 4-Methyl-2-pentanona IOU
67-64-1 Acetone 71 '1. LA 591-78-6 2-Hexanone IOU
75-15-0 Carbon Disulfide 5U 127-18-4 Tetrachtoroethene 5U
75-35-4 1,1-Dichloroethene SU 79-34-5 1,1,2,2-Tetrachloroethane 5U
75-34-3 1,1-Dichtoroethane 511 108-88-3 Toluene 5U
540-59-0 1,2-Dichtoroethene (total) 5U 108-90-7 Chlorobenzene 5U
67-66-3 Chloroform 5U 100-41-4 Ethylbenzene 5u
107-06-2 1,2-Dichloroethane 5u 100-42-5 Styrene 5U
78-93-3 2-lutanone 1WU 1330-20-7 Xylene (total) 5U
71-55-6 1,1,1-TrichLoroethane 5U
56-23-5 Carbon Tetrachloride 5U
108-05-4 Vinyl Acetate lOU
75-27-4 Bromodichloromethane 5U
78-87-5 1,2-Dichloropropane 5U
10061-01-5 cis-1,3-Dichtoropropene 5U
79-01-6 Trichtoroethene 5U
124-48-1 Dibromochloromethanve SU
Data Reporting Qualifiers:
U - Compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
6 - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
RD - Not detected.
A - Atdol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration range.
D-124

WHC-SD-EN-TI-136, Rev, 0
182 CAISSONS
Sample Date April 5, 1991
D-125

WHC-SD-EN-TI-136, Rev. 0
D-126

WHC-SD-EN-TI-136, Rev. 0 _______________
MARTIN MARIETTA ENERGY SYSTEMS, INC. PS FIE9X2D
Ms. Joan Kessner
Westinghiouse Hanford Company
Office of Sample Management
2355 Stevens Drive
Richland, Washington, 99352
Dear Ms. Kessner:
July 16, 1991
Analyical Results Package on Project 90-02: Underground Storage Tanks Samples
Attached are the analytical results on five (5) Underground Storage Tanks soil samples, Project 90-
028, received into the K-25 Site Analytical Chemistry Department (ACD) laboratories on March 9,
1991. Also attached are copies of the Chain of Custody records for the samples, and a sample
identification table. As previously requested in the letter dated December 20, 1990, the results are
reported in ACD's AnaLis report format. All data quality objectives were satisfied on this project.
Total Petroleum Hydrocarbons
The total petroleum hydrocarbons analysis was performed by ACD's TP- 184203 method, an extraction
method for determination of total petroleum hydrocarbons in solids. TP-184203 is a modification of
EPA 418.1.
D-127

WHC-SD-EN-TI-136, Rev. 0
Ms. Joan Kessner 2 July 16, 1991
I certify that this data package is in compliance with the terms and conditions of the OSM's revised
Statement of Work and letter dated December 20, 1990, both technically and for completeness, for
other than the conditions detailed above. Release of the data contained in this hardcopy data
package has been authorized by the Laboratory Manager or his designee, as verified by the following
signature.
Clarence R. Kirkpatrick
Acting Department Manager
K-25 Site Analytical Chemistry Department
Attachments
cc/attach: D.LAmburgey
S.R.Smith - RC
cc: N.P.Buddin
H.H.Sullivan
D-128
Sincerely,
Deborah L Amburgey
Program Manager
Hanford Support Program
Fred M alo
Program Manager
Waste Management Analysis

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge K-25 site
Analytical Cheistry Department
Results of Analyses
AnSLIS 10: 910311-006 Project: G132 027S customer Smle ID: MK-101
Customer: KiESSNERIROOS Eaojisi tion Number:
Date Sumpted: 5-MAR-1991 Date Sample Received: 9-MAR-1991
Sompted By: Date SaepL* Coipleted: 7-APR-1991
Mterisl Description: SOIL (3 : Resul It has been Corrected for Spike
10
Date Printed:
15-JUL-1991 12:43
QA Date
Act iv.
Number Procedure No. Analysis Result Units Analyst Pile Number Completed
........... ...................... ........................ .......... ............... ............. .........
184203 TP-184203 Petroleum Hydrocarbons 2.366 %JC OSBORNE 91-4 6-APR-1991
D-129
Program Manager: 0. L. Amburgey
Date Approved: 8-APR-1991

WHC-SD-EN-TI-136, Rev. 0 1
Oak Ridge K-25 Site
AnaLyticaL Chemistry Departmnt
Results of Analyses
AnaLIS ID: 910311-007 Project: G132 027S Customer Sample ID: 14K-102
Customer: KESSNER/ROOS Requisi tion Number:
Dote Samled: 5-M-1991 Date Semple Received: 9-PAR-1991
Samled By: Date sampte completed: 7-APR-1991
Material Description: SOIL 13:Result has been corrected for Spike
Date Printed:
15-JUL-1991 12:43
GA Date
Activ.
Number Procedure No. Analysis Result Units Analyst File Number completed
---------------------------------------- ------------------------ ---------- --------------- ------------- ---------
184203 TP-184203 Petroleum Hydrocarbons 2.948 %JC OSSORME 91-4 6-APR-1991
D-130
Program Manager: D. L. Amburgey
Date Approved: 8-APR- 1991

WHC-SD-EN-TI-136, Rev. 0
12
Oak Ridge K-25 Site Date Printed:
Analytical Chemaistry Department
Results of Analyses
15-JUL-1991 12:43
AnaLlS ID: 910311-008 Project: G132 027S Customer Sample 1D: MK-103
Customer: KESSNER/ROOS Requi si tion Number:
Date Sampled: 5-NAR-1991 Date Sample Received: 9-MAR-1991
Sampled Bly: Date Sample Completed: 7-APR-1991
Material Description: SOIL E3 : Result has been Corrected for Spike
Activ. GA Date
Number Procedure No. Analysis Result Units Analyst Fil 1 oNmber Completed
--------------------------------- ------------------------ ---------- --------------- ------------- ---------
184203 TP-184203 Petroleum Hyrocarbons 0.057 %JC OSSORNE 91-4 6-APR-1991
D-131
Program Manager: D. L. AaIburgey
Date Approved: 8-APR-1991

WHC-SD-EN-TI-136, Rev. 0 1
Oak Ridge K-25 site
Analytical Chemistry Department
Results of Analyses
AnaLIS 1D: 910311-009 Project: G132 027'S Customer Sample ID: NK-104
Customer: KESSNER/ROOS Reqii ition Number:
Date Sampled: 5-MAR-1991 Date Sample Received: 9-M4AR-1991
Sampled By: Date Samle Completed: 7-APR-l19
Noarial Description: SOIL E3 : Result has beew Corrected for Spike
Date Printed:
15-JUL-1991 12:43
QA Date
Activ.
Number Procedure No. Analysis Result Units Anatyst File Number Completed
----------- ------------------------------ ------------------------ ---------- --------------- ------------- ---------
184203 TP-184203 Petroleum Hydrocarbons -'0.001 %JC OSBORNE 91-4 6-APR-1991
0-132
Program Manager: D. L. Airburgey
Date Approved: 8-APR-1991

WHC-SD-EN-TI-136, Rev. 0 14
Oak Ridge K-25 Site
Analytical Ciheistr Department
Results of Analyses
AnaLIS 10: 910311-010 Project: G132 027S Customer Sample 10: WK-105
Customer: KESSNER/ROOS; Requisition Nmb~er:
Date Sampled: 5-PAR-1991 Date Semple Received: 9-MAR-1991
Samled By: Date Semple Completed: 7-APR- 1991
Mterial Description: SOIL U:Result has been Corrected for Spike
Date Printed:
15-JUL-1991 12:"4
Activ.
QA Date
N,.,ier Procedure No. Analysis Result Units Analyst File Number Completed
.......... ............................. ........................ .......... ............... ............. .........
184203 TP-184203 Petroleum Hyrocarbons 12.592 %JC OSBORNE 91-4 6-APR 911
D-133
Progra Manager: D. L. Amburgey
Date Approved: 8-APR- 1991

WHC-SD-EN-TI-136, Rev. 0
D-134

WHC-SD-EN-TI-136, Rev. 0
182 CAISSONS
Sample Date April 26, 1992
D-135

WHC-SD-EN-TI-136, Rev. 0
D-136

LABORATORY: TMA/ARLI
WHC-SD-EN-TI-136, Rev. 0
CASE: 03-090
CASE NARRATIVE J
CONTRACT ID: WESTINGHOUSE HANFORD COMPANY
SDG RECEIPT DATE: March 30, 1992
1.0 DESCRIPTION OF CASE:
000005
Three soil samples were analyzed for Total Petroleum
Hydrocarbons and Purgeable Aromatics. Preliminary
results were provided by FAX within 10 days of VTSR.
This package represents the final results.
2.0 SAMPLE LIST:
WESTINGHOUSE ID L&DZU MATRIX MTO
B01GMO A2-03-090-01 SOIL HC,THE,THP,BX
B01GM1 A2-03-090-02 SOIL HC,THE,THP.BX
B01GM3 A2-03-090-03 SOIL HC,THETHP,BX
Method Codes:HC - EPA 418.1, THE = EPA 8015 EXTRACTABLE,
THP = EPA 8015M PURGEABLE, BX = EPA 8020 BTEX
3.0 COMMENTS ON SAMPLE RECEIPT:
The samples were received intact and properly documented.
4.0 COMMENTS ON ANALYSIS:
4.1 EPA 418.1 - TOTAL PETROLEUM BY IR:
All samples were extracted and analyzed within
method holding time.
All QC results were acceptable.
4.*2 EPA 80 15M - EXTRACTABLE HYDROCARBON:
All samples were extracted and analyzed within
method holding time.
D-137

WHC-SD-EN-TI-136, Rev. 0 000006
All QC results were acceptable. There were no
problems encountered during analysis. Solvent peaks
were eliminated using electronic subtraction. Both
the raw and subtracte~l chromatograms have been
included in the package.
4.3 EPA 8015M - PURGEABLE HYDROCARBONS:
All samples were analyzed within method holding
time.
All QC results were acceptable. There were no
problems encountered during analysis.
4.4 EPA 8020 - BTEX:
All samples were analyzed one day past the method
holding time but within 10 days of VTSR.
All QC results were #deevtable. There were no
problems.
All positive hits were confirmed by GCMS.
5.0 DATA PACKAGE COMMENTS:
The Format of the data deliverable was designed: to
meet or exceed the requirements 6"f ther-Westinghouse
Hanford Company Statement of Work. The intenti of
the package design is'to provide sufficient data for
"stand alone" validation. While the format of the
package is "CLP like" Thermo Analytical Inc. makes
no claim that this package duplicates in part or in
total an EPA CLP data package.
d
I certify that this data package is in compliance with
the terms and conditions of the contract, both
technically and for completeness, for other than the
conditions detailed above. Release of the data contained
in this hard copy data package has been authorized by
the Laboratory Manager or his designee, as verified by
the following signature."
Nicole Roth Dni .Wel
CLP Manager clDrto
D-138

Received: 03/30/92
WHC-SD-EN-TI-136, Rev. 0 Vuuuuu
TUA I nc. REPORT Work Order # A2-413-S90
Rtesutts by Smpt*
SAMPLE 10 ROUND
SAMPLE # 21i FRACTIONS: 9-F
I Date A Time Cottected 0312619 Category
I mg/Kg
SAMPLE 1D 5016141
418j.s.....JL 14I
I mg/Kg
SAMPLE 0 9Z FRACTIONS: F
Date A Time CoLtected 0312619
Category
SAMPLE tD 11016113 SAMPLE 0 31 FRACTIONS: A-B.C
I Date & Time CoLtected 03/261-- category
I mg/Kg
SAMPLE tD 3016N3 Dunilcat* SAMPLE # ALj FRACTIONS: I
I Date A Time CoLlected 03126192 CategoryI
SAMPLE ID no1aml Stank Spike SAMPLE # a. FRACTIONS: F__
I Date & Time Collected 03/26192 Category
% RecoveryI
D-139

leceived: 03/30/92
WHC-SD-EN-TI-136, Rev. 0 0 f 1
TWA Inc. 2EPO0RT Work Order * A2-63-090
Results by S;aple
SAMPLE I103016G FRACTION fJU TEST CODE 201511 NAME Volatile Fucts-TPl
Date & Time Collected 0312619
Category
MODIFIED 8015 -VOLATILE FUEL UYDROCAR5ONS
Matrix: Soj.lt.....
Date Analyzed: 04/08/9L2.
Dilution factor: .00.1A9
Concentration Units: .... ual~J.
Sample
Compound Result POL
CS -C12 Gasoline Range No 25.0
ND *Not detected at the specified limits
Form I
D-140

Received: 03/30/92
WHC-SD-EN-TI-136, Rev. 0 000119
TKA I ac. REPORT Work Order * &Z-03-0"
Results by Semple
SAMPLE 10 BOIGKO FRACTION IL TEST CODE 1111... NAME ITEN by EPA 8020
Date & Time Collected 0312619 Category
$TEX by EPA Method 5020
Matrix: i±L...........
Date Analyzed: 04/10LII.92.
Dilution factor: .00L....
Concentration Units: ual....
Sample
CA$ No. Compound Result POL
71-43-21 Senlene ND 2.5
109-893 Toluene No 2.5
100-41-4 Ithylbenzons ND 2.5
1330-20-7 Xylon.. (Total) ND 2.5
% Recovery Surrogate Compound
Bremof luorobeniene 94......h
NDO Not detected at the specified limits
Form I
D- 141

WHC-SD-EN-TI-136, Rev. 0 000048
TNA Inc. REPORT Uerk order 0 A2-03-090
*eceivedt 03/30/92 aeSUtS by sample
SAMPLE 1D BOIGNO FRACTION ML1 TEST CODE 81112 MNE FYRCALE FUELS *TPN
Date & Tim* Collected 03126192 Category ______
MODIFIED 8015 - EXTRACTABLE FUEL HYDROCARBONS
Matrix: SoJ.lt.....
Date Analyzed: 04108212
Dilution factor: t..00..±~l
Concentration units: waul~i.
S&aple
Compound *esult POL
Kerosene Range ND 5.0
CIO - C16 Jet Fuel, Range ND 5.0
C9 -C22 DiesetloRnge ND 10.0
Hlydraulc Range ND 5.0
ND N ot detected at the specified limits
Form I
D- 142

Received: 03/30/92
WHC-SD-EN-TI-136, Rev. 0 dVl.&.D w
TEA Inc. REPORT Uork order # A2-03-090
Ueuta hr Samplea
SAMPLE 10 *0 GNI FRACTION IML TEST CODE 8015WB MNE Volatile Fuets-TPU
Date A Time Collected 2U2&1I92 Category
MODIFIED 5015 -VOLATILE FUEL NTDROCARIONS
Matrix: soft.....
Data Analyzed: 0l4108l2.
Dilution factor: .00L~
Concentration Units: .ULEJ.
Sample
Compound Resut,
CS - C12 Gasoline Range No 25.0
NO Not detected at the specified limits
Form I
D-143

WHC-SD-EN-TI-136, Rev. 0 0 U I 2iL
TINA Sa. REPORT Uerk Order # AZ-03-090
Received: 63130/92 Results by sample
SAMPLE 10 NOICHI FRACTION flU TEST CODE STEW.. NME ITEN by EPA 31026
Dato & Time Collected O32,6192 Category ______
8TEM by EPA Method 8020
matrix: soft........
Date Analyzed: 04.110/92
Dilution factor: - .00
Concentration Units: UGIj
Sample
CAIS No. Compound Result POL
71-43-2 Benzene No 2.5
103-88-3 Toluene 21 2.5
100-41-4 Ethylbentone No 2.5
1330-20-7 Xylenes CTotal) No 2.5
I Recovery Surrogate Compound
Iromofluorobenzens 8....Jl
NO Not detected at the specified limits
form I
D-144

WHC-SD-EN-TI-136, Rev. 0 000052
TRA Inc. REPORT Vork Order 9 A2-03-090
Received: 03/30/92 Results by Sample
SAMPLE 1D 318111 FRACTION 11 TEST CODE 31111 MNE EXRCTABLE FUELS -TPU
Date & Time Collected 03126192 Category
MODIFIED LO1IS EXTRACTABLE FUEL NYDROCARBONS
Matrfx: Soft......
Date Analyzed: 04/08/2
Dilution factor: 1.00fl
Concentration Unite: .......ia
Sample
Compound Result POL
Kerosene Range No 5.0
CIO -C16 Jet Fuel Range VoD 5.0
C9 - C22 Diesel, Range 63.0 10.0
Nydraulc Range ND 5.0
ND Not detected at the specified limits
Form I
D-145

Received: 03130192
WHC-SD-EN-TI-136, Rev. 0 000123
INA Inc. REPORT Uork Order 8 AZ-43-0S0
Results by Sampte
SAMPLE 1D a61513 FRACTION UL TEST CODE II.U.... NME ILTEX by EPA 3020
cate & Time Collected 03126192
Category______
ITEX by EPA Method 5020
Matrix: soft........
Date Analyzed: 04/10192L..
Dilution factor: .00.IJL...
Concentration Units: ..... U.LLL..
CA$ No. Compound Result POL
71-43-2 Benzene ND 2.S
108-88-3 Toluene 16 2.5
'100-4 1-4 Ethytbonzene No2.
1330-20-7 Kylenes (Total), NO2.
2 Recovery Surrogate Compound
BromoftIuorobenzone
76......i
ND *Not detected at the specified limits
form I
D- 146

Received: 03/30/92
WHC-SD-EN-TI-136, Rev. 0 UU UU21L
TKA lInc. REPORT
Results by Saimple
Vork Order 0 AZ-03-090
SANPLE 10 B01CU3 FRACTION iL TEST CODE 8015NVY MANE Volatile Fuets-TPU
Date & Time Collected 03/26192
Category
NODIFIED £015 -VOLATILE FUEL NYDEOCARSONS
Matrix: jgjl....
Date Analyzed: 04108/2
DiLution factor: .00~...A
Concentration Units: uaK
Sapte
Compound Result POL
CS - C12 Gasoline Range ND 25.0
MD *Not detected at the specified limits
Form I
D-147

tocefv~d: 03/30/92
WHC-SD-EN-TI-136, Rev. 0 000056
ThA Inc. REPORT Work Order # AZ-83-090
lesuts by Samples
SAMPLE ID BIICHI FRACTION UlL TEST CODE SO15MS NAME EXTRACTABLE FUELS T PI
Date & Time Collected 0312619Z Category______
MODIFIED BO015 EXTRAC-TAULE FUEL NYDROCARIONS
Matrix: Sll......
Date Analyzed: 04108192
Dilution factor: 1..00....LA
Concentration units: ma~
Sample
Compound Result POL
Kerosene Range No 5.0
CIO -C16 Jet Fuel Range ND S.D
C9 C22 Diesel Range 21.3 10.0
Hydraulic Range No 5.0
NO Not detected at the specified limits
Form I
D- 148

WHC-SD-EN-TI-136~,Rev,. 0 -
ROY P. WESTON, INC.
LionVille Laboratory
CLIENT: WESTINGHOUSE HANFORD SAXPLBS RECEIVED: 03-28-92
RFW #: 9203L84l, GC VOLATILE
1.0. #: 6168-02-01
NARRATIVE
One (1) soil sample was collected on 03-26-92.
The sample and its associated QC samples were analyzed
according to criteria set forth in Method 602 for Selected
Aromatic Organic Volatile target compounds on 04-03,06-92.
The following is a summary of the QC results accompanying the
sample results and a description of any problems encountered
during their analyses:
1. All surrogate recoveries were within
laboratory control limits.
2. One (1) of eight (8) blank spike recoveries
was outside method control limits. There was
no impact on this case because analytes were
not detected in the sample.
Jack R. ftschall, Ph .D. Date
Laboratory Manager
Lionville Analytical Laboratory
D-149

WHC-SD-EN-TI-136, R~v. 0
V 0
KU
x 04llw
< 4O t a K
w w V0 ~14f 00 m ~
x
b
qW ofN
0rt 0
44
U
N
Nw
010
itN0 0
*: a~~ 3
a014 U ft ?-rf a
t 0
"S
0
0o
t
"a 3 0 0
c t
0 I0
£z
01 N 1. S S
40 HO..
ii1 "U
I-- N
1-. 0,p 1
N n I n
It Ar K1e
.4 to N t0a t
0
*t I- I.- ;-
Ut U t-
g
COON in00 0 a 0
p -. W W K 0 DIa, 8 .. 0oZ - 0 &4
a
I ~ .*
C~
a
A?0 Nt 00
a tS *G:3. 0 0 0~ GV'
10F - - e
nI N N
0 to
* 1 rO W 0
at O at. at a- NlC 0 w(a - W
No
~Z K Im ..
NF I 0
a to 0 -
0? NN
K K 0
0O 0
03
O4 w U4 a
000
U Z It
2PVd *P N)-- 0 V 0 0w
1 IS N
0000K *..000
00i0
n
4?L- 1-0-
00 K o
o~IJK
2; -, -4 CD
00
00.0
so a.. 0 W 0 P
N N)
0 pq U -to
No INo 900
t% U 0
3 t
D-150
m

0.4
A ft
I
2WD
ct
C44
WHC-SD-EN-TI1 36 , Rev. 0
00
I
*
r
V to
to 0.. 't
1 P a
W0
-D
A n
0
0
*00
0:
151
I
00
I-* 00
0
V
ft
m
1 2
0N
0
mu

wCVOLTILS SMETWHC-SD-EN-TI-136, Rev 0"II
Lab Name: Ray P. Weston, Inic. Work Order: 6168-02-01-0000IBl
Client: WNSTINGHOUS3 HKNFORD
Matrix: SOLLab Sample ID: 9203L841-001
Sample wt/vol: 5.66 (g/uL) _q Lab File TD: D3242591
Level: (lew/med) I" Date Received: 03/28/92
%Moisture: not dec. 3~ Date Aal-yzed: 04039
Column: (pack/cap) ZN Dilution Factor: 1.0
CONCINTRATIOK UNITS:
CAS NO. COMPbOUND (ug/L or ug/xg) uqLI9.....
I01-000-000 ------G-asoline I 91 IfU I
D-152
12/88 Rev.

WHC-SD-EN-TI-136, Rev. 0 M 7(
~N
9 N
CD CDIA
CL* -5 N
mD K N
NN CD
lC . 1 CDa
m* 4 r r
D
-. N W
4 N1
Nn __
-CD~ N 0 D nf
u%~ ON
=CU . 0
CDCD rCD
9~C L Acm
!I~D 7 XCDcm
C~l CD
CDn N- C
N AC
N to 0m W cm
CD 0l0 N
0 C
0 N £00
4N 0
~ CD 06 -a =D
MC L nn r-N -~ (~
ON (AC 06 K CD
r- N C 0 M A
-0!4- N 0 4A n
(A
CD
-
N
i £0
9 D
A
E% g
MON0
N0 9
N ~- D N
0153
-

PUSTICIDI ORGANICS AjmLysis -u'_____________
WHC-SD-EN-TI-136, Rev. 0
Lab Nam:s Roy 1P. Weston, Inc. Work order: 6168-02-01-0000 II
Client: WZSTINGHOSR KhANRD
matrix: SOIL..... Lab Sample ID: 9203LS41-001
Sample wt/yols 25.0 (9/L) L_ Lab File ID: 04029227.14
Level: (lev/med) LOW Date Received: 03/28/92
%Moisture: not dec. 3..... dec. Data Extracted: 04/01/92
Extraction: (SepF/Cont/Sonc) SOCDate An-lyzed: 04/03/92
OPC Cleanup: (YIN) F pH: .4 Dilution Factor: OW090T 0
"?' CENTitAT!0E UNITS:
CAB NO. COMPOUND (ug/L or ug/Eg) mlkg.....
I000-00-0-----Diesel fuel I 14 I
FORK 1 PEST 12/88 Rev.
D-154

00
WHC-SD-EN-TI-136, Rev. 0
I.--
I- C-1
a
40 U
10
a.
~~rt
ft 1
ret
as
I S E
Ut 0
ftt 0
V 2c
P 0 St an
39'~~ 3 ' '00
s-U .M0 C nd~
I m U1
Cht I us U,"
o P 0am 0%
0
1 0
U0 0
0: N N~* 6 - oo0
* 0
x t
0 in
a
*~~
w
0
W x9
to
0n
t
bE 0
Pt
00
I
0
01 &.
D-155s- I-
'I

WHC-SD-EN-TI-136, Rev. 0
OC VLATIES ~CLIENT SAMPLE NO.
Lab Name: Roy F. Weston, Inc. Work Order: 6168-02-01-0000II
Clients WESTINGROUSI HANFORD
Matrix: SOI Lab Sample ID: 9203LB41-001
Sample wt/vol: 5.5 (g/.L) 2_ Lab ile ID: D3242476
Level: (low/med) Ji Date Received: 03/28/92
%Moistures not dec. 3 Date Analyzed: 04/03/92
Column: (pack/cap) EA Dilution Factor: 1.00
CONCENTRATION UNITS:
CAS NO. COMPOUND (uq/L or ug/Ig) DO/KG
71-43-2 ------ -enzene I 0.94 ID I
l 00-41-4------thylbenzene 0.94 ID
I108-88-3-----Toluene__________ 0.94 lD I
1330-20-7----Xylene (total) I 1.9 ID I
D-156
12/88 Rev.

WHC-SD-EN-TI-136, Rev. 0
105- N -LFT
April 30, 1992
D-157

WHC-SD-EN-TI-136, Rev. 0
D-158

LABORATORY: THA/ARLI
WHC-S-EN-TI-l 36 , Rev.
CASE: 04-016
CASE NARRATIVE
0000
- -- 7
CONTRACT ID: WESTINGHOUSE HANFORD COMPANY --
SDG RECEIPT DATE: APRIL 3, 1992
1.0 DESCRIPTION OF CASE:
Five soil samples were analyzed for Total Petroleum
Hydrocarbons and Purgeable Aromatics. Preliminary
results were provided by FAX within 10 days of VTSR.
This package represents the final results.
2.0 SAMPLE LIST:
WESTINGHOUSE ID LAB I ~ MATIZX MTO
B01GM4 A2-04-016-01 SOIL HC,THE,THP,BX
B01GM5 A2-04-016-02 SOIL HC,THE,THP.BX
BO1GM6 A2-04-016-03 SOIL HC,THE,THP,BX
B01GM8 A2-04-016-04 SOIL HC,THE,THP,BX
B01GM9 A2-04-016-05 SOIL HC,THE,THP,BX
Method Codes:HC - EPA 418.1, THE - EPA 8015 EXTRACTABLE,
THP = EPA 8015H1 PURGEABLE, BX - EPA 8020 BTEX
3.0 COMMENTS ON SAMPLE RECEIPT:
The samples were received intact and properly documented.
4.0 COMMENTS ON ANALYSIS:
4.1 EPA 418.1 - TOTAL PETROLEUM BY IR:
All samples were extracted and analyzed within
method holding time.
The large difference in the duplicate analysis was
attributed to sample irhomogeneity.
4.2 EPA 8015M - EXTRACTABLE HYDROCARBON:
All samples were extracted and analyzed within
method holding time.
D- 159

wVC-s-EN-TI-136, Rev. 0
000003
All QC results were acceptable. There were no
problems encountered during analysis. solvent peaks
were eliminated using electromic.subtroct ion. Both
the raw and subtracted chi'omatograms-have -"'beiif-"'n. ,
included in the package.
4.3 EPA 8015M - PURGEABLE HYDROCARBONS.
All samples were analyzed within method holding
time. ------. * -
All QC results were acceptable. There were no
problems encountered during analysis.
4.4 EPA 8020 - BTEX:
All samples were analyzed within method holding
time.
All QC results were acceptable. There were no
problems.
5.0 DATA PACKAGE COMMENTS:
The Format of the data deliverable was designed to
meet or exceed the requirements of the Westinghouse
Hanford Company Statement of Work. The intent of
the package design is to provide sufficient data for
"stand alone" validation. While the format of the
package is "CLP like" Thermo Analytical Inc. makes
no claim that this package duplicates in part or in
total an EPA CLP data package.
I certify that this data package is in compliance with
the terms and conditions of the contract, both
technically and for completeness, for other than the
conditions detailed above. Release of the data contained
in this hard copy data package has been authorized by
the Laboratory Manager or his designee, as verified by
the following signature."
Nicole Roth
nkDWels-
CLP Manager S clDrco
D-160

Received: 04133192
WHC-SD-EN-TI-136, Rv
000011
IRA Inc. REPORT
Results by Sauple
Vork Order 0 A2-114-616
SAMPLE 1D 1101611 SAMPLE 0 IL FRACTIONS: A-B.CI
IDate & Time Collected 031ZO192 Catego ry
418-js.. .0L
SAMPLE 10 BO1cu5 SAMPLE # YZ3 FRACTIONS: 3-E Ctgr
I ~Date A Time Collected 03130192-Cateor- -
SAMPLE ID UkOIGM6
SAMPLE # 21 FRACTIONS: I _
I Date & Time Collected 03130/92 CategoryI
SAMPLE ID 1101611 SAMPLE 9 fli FRACTIONS: A-0-C
Date A Time Collected 03130192 CategoryI
SAMPLE ID SOIGNS Dupticate SAMPLE 9 PAj FRACTIONS: a
IDate & Time CoLlected 03130192 Category
I415._1S........162
SAMPLE ID 1101411 Stank snike SAMPLE 8 l FRACTIONS:E
I' Date &Time Cotlected 03/30192 Category
% Recovery
D-161

WHC-SD-EN-TI-136, Rev. 0 000012
THA Inc. REPORT Work Order 0 AZ-04-S6
Received: 34163/92 Results by Sample
SANPLE 10 5816149 SANPLE 9 n~ FRACTIONS: .CI
I Dat* & Time Collected 03130192 Catespry
D-162

( eceived: 04/03/92
WHC-SD-EN-TI-13 6 , Rev. 0
000020
TEA Inc. REPORT Veek Order # A2-04-016
Resuts by Sample
SAMPLE 10 5016N4 FRACTION 33 TEST CODE fljIflj NAME EXTRACTABLE FUELS *TPN
Date A Time Collected 03110192 -- Category
MODIFIED B015 - EXTRACTABLE FUEL NVDROCARIONS
Matrix: Si~al.....
Oate Analyzed: 04LR.091
Dilution factor: .00a.
Concentration Units: ...... La
Sample
Compound Result POL
Kerosene Range NO 5.0
CIO , C16 Jet Fuel. Range No 5.0
C9 - C22 Diesel, Range No 10.0
Hydraulic Range No 5.0
NO Not detected at the specifiled timits
form I
D-163

Received: 04/03/92
WHC-SD-EN-TI-136 , Rev. 0 000101
TEA Inc. REPORT Work order IS AZ-0I.-016
Resutse by Smple
SAMPLEID 0 221c FRACTION U& TEST CODE 3E.1111. MNE Votatile Fuets-TPI
Date & Time Cottected 1110192
Category ______
MODIFIED 5015 -VOLATILE FUEL NVOROCAEBONS
Hatrix: Sol.L.....
Date Analzed: 0410922LZ
Dilution factor: ... 00..IJ
Concentration Units: .... MualLL
Sample
Compound Result POL
CS - C12 Baseline Range NO 2S.0
NO a Not detected at the specified Limits
Form I
D-164
t 1

Received: 04/03/92
WHC-SD-EN-TI-136, Rev. 0 000132
TVA Inc. REPORT Work Order 9 A2-04-016
Egeuta by Sample
SAMPLE 10 3016114 FRACTION MAj TEST CODE IT-l. NAME UTFX bY EPA 3020
Date & Time Collected 03110107
category ______
@TEX by EPA Method 5020
Date Analyzed: Uh.LUL.L....
Dilution factor: .00AQ....
Concentration Units: .....u.ELL..
CAI No. Compound Reault POL
71-4321 Benzene NO12.5
108-55-3 Teluene 22 2.5
100-41-4 9thylbenzene ND 2.5
1330-20-7 Kylenes (Total) No 2.5
I Recovery Surrogate Compound
I romoftIuorobenzene 95.....2
NO a Not detected at the specified Limits
Form I
D-165

Received: 04103/92
WHC-SO-EN-TI-136, Rev. 0
000103
TUA 106. REPORT Work Order 8 A2-04-016
lesults by Sample
$AMPLE to 3011.5S FRACTION H& TEST CODE 901519 NAME V a-l -atite Fuets-TP11
Date & Tint Collected 03/30192
Category
MODIFIED 0015 -VOLATILE FUEL NYDROCARUONS
Matrix: soft........
Date AnalyZed: 04/09/92
Dilution factor: ... 00....L~l
Concenltrationl Units: ...yllca
Sample
Compound Result POL
CS- CIZ gasoline Raonge ND 25.0
ND a Not detected at the specified Limits
Form I
D-166

Received: 04/03/92
WHC-SD-EN-TI-136, Rev. 0
THA Inc. REPORT Work Order. 00-022
Results by Sample
SAMPLE 10 §OIGM5 FRACTION 020 TEST CODE SOISNS NAME EXTRACTABLE FUELS - PN
Date A Time Collected 03130192
Category
MODIFIED B0IS - XTRACTABLE FUEL NYDROCARSONS
Matrix: Soil
Date Analyzed: 04109192
Dilution factor: .00.~A
Concentration Units: 091KO~
Sample
Compound Result POL
Kerosene Range ND 5.0
CIO - C16 Jet Fuel Range No 5.0
C9 C22 Diesel Range ND 10.0
Hydraulic Range 24.2 5.0
ND UNot detected at the specified Limits
D-167

WHC-SD-EN-TI-1 36 , Rev. 0
Inc. EPORT000134
TKA Ic. REORT erk Order 0 A2-"4-616
lecelved: 64/03/92 Results by Semple
SAMPLE 1D BIGNCS FRACTION 02A& TEST CODE IIU.... NME *TEX by EPA 1020
Date & Time Collected 03/30192 Category
VTEX by EPA Method 8020
Matrix: soft
Date Analyzed: 04/13/92
Dilution factor: .00..A2....
Concentration Units: ua~
Sample
CAS No. Compound Result PAL
71-43-2 Benzene ND 2.5
108-88-3 Toluene 17.2 2.S
100-41-4 Ethylbenzeno ND 2.5
1330-20-7 Xylenes (Total) No 2.5
% Recovery Surrogate Compound
Bromoftuorobenzene 74.....~
NO Not detected at the specified Limits
Form I
D-168

Received: 04/03/9Z
WHC-SD-EN-TI-136, Rev. 0 *000026
TRA Inc. IkEPORI Voth Order #.A204.-016
nesulta by Sampte
SAMPLE 10 930 6 FRACTION UL3 TEST COOE SCISL NME EXTRACTABLE FUELS -TF1
Dat* A Time Collected 3130192 Category______
NOOIFIED BOIS - EXTRACTABLE FUEL NYDROCARBONS
Matrix: $il......
Dnto Analyzed: 041092.L
Dilution factor: .00j
Concentration Units: M/fj.2
samp I.
Compound Result POL
Keroen* Rang* NO 5.0
CIO -C16 Jet Fuel Range NO 5.0
C9 - CU2 Diesel Range No 10.0
Hydraulic Rang* 63.0 5.0
No a Not detected at the specified limits
Form I
D-169

Recuived: 04/03/92 Resut by Sample
WHC-SD-EN-TI-136, Rev. 0 000136
TNA Ime. REPORT Uerk order 0 AZ 04-016
SAMPLE ID BOIGNKA FRACTION ilk TEST CODE IL.. NAME RI!! by EPA 5020
Date & Time Collected 6313019
category
UTEX by EPA Method 5020
matrix: SltL........
Date Analyzed: 04113192...
Dilution factor: .00LL..
Concentration Units: ......MlLL.
Sample
CA$ No. Compound Result POL
71-43-2 Benzene No 2.S
106-8-3 Toluene 14 2.5
100-41-4 Ithylbenzene ND 2.5
1330-20-7 Kylanes (Total) NDO.
% Recovery Surrogate Compound
*romofluorobenzene
82.....Z
ND a Not detected at the specified Limits
form I
D-170

WHC-SD-EN-TI-136, Rev. 0 000105
TNA lae. REIWORT Veek Order 0 A2-04-016
Received: @4/03/92 Results by Sample
SAMPLE 10 101CM6 FRACTION OL TEST CODE 80lI19 NAME Volatile Fuels-TPU
oate & Time Collected 0313019 Category______
MODIFIED $015S VOLATILE FUEL HYDROCARBONS
matrix: Soft......
Date AnaLYzed: 0410912LZ
Dilution factor: ... 00Q9
Concentration Units: ... ua/Keu
Sample
Compound Result POL
CS -C12 Gasoline Range ND 2S.0
No a Not detected at the specfied limits
Form I
D-171

WHC-SD-EN-TI-136, Rev. 0 000030 ,
TEA Inc. REPOR1T Verk Order * A2-04-016
Received: 04/03/92 Ileautts by Saimple
SAMPLE____10__________ FRACTION L TEST CODE 801111 NME EXTRACTABLE FUELS -TPE
Date & Time Collected 03130192 Category ______
MODIFIED 80153 EXTRACTABLE FUEL MYDROCARBONS
Matrix: Si.......
Date Analyzed: 04109/92
Dilution factor: ... 0......J
Concentration Units: **jg~j
Sample
Compound Result POL
- Kerosene Range ND 5.0
CIO - C16 Jet Fuel, Range 110 S.D
C9 - C22 Diesel Range NO 10.0
Nydraulic Range No 5.0
90 a Not detected at the specified Limits
Form I
D-172
w

leceived: 04/03192
WHC-SD-EN-TI-13 6 , Rev. 0
TWA Inc. IEPOIT Work Order 0 Z00138
neautt by Sample
SAMPLE 1D EOIGN8_ FRACTION M~ TEST CODE BTIL.. NAME IE by EPA 5020
Date & Time Collected 0313019
Category
Ill! by EPA Method 6020
Matrix: So.lt........
Date Analyzed: 0l.13192..
Dilution factor: .00..2...
Concentration Units: .....U.LL...
sample
CA No. Compound Result POL
71-43-2 Benzene No 2.5
108883 Toluene 13 2.5
10041-4 Ethytbeniene No 2.5
1330-20-7 1Xylones CTotal)
% Recovery Surrogate Compound
BromofLuorobenzene .......Z
90 2.5
No a Not detected at the specified Limits
Form I
D-173

WHC-SD-EN-TI-136, Rev 0 000107
TEA Inc. REPORT Work Order 9 A2-64-016
Received: 04/03/92 Results by Sample
SAMPLE ID BOISNS FRACTION MAh TEST CODE 8015mI NAME Voiatile Fuets-Tpg
Data.& Time Collected 03130/92 Category ______
MODIFIED 8015 -VOLATILE FUEL NYDROCARSONS
Matrix: SofLL......
Date Analyzed: 04/09/2
Dilution factor: .00j
Concentration Units: uajjj
Sample
Compound Result PQt.
CS -CIZ Gasoline Range ND 25.0
NO = Not deteted at the specified Limits
Fore I
D-174

WHC-SD-EN-TI-136, Rev 0 000034
'IRA Inc. REPORT Merk Order 9 A2-S4-016
Received: 04/03/9Z Resuts by Sample
SAMPLE 10 12IGN9 FRACTION ULE TEST CODE 80151111 NAME EXTRACTABLE FUELS -TPI
Oat* S, Time Collected 03130/92 - Category______
MODIFIED 8015 -EXTRACTAILE FUEL NYOROCANIONS
matrix: oitn....
Oate Analyzed: 04109/92
Dilution factor: ... 00.
Concentration Units: soK
sample
Compound Result POL
Kerosene Range ND 5.0
CIO - C16 Jet Fuel Range MID 5.0
C9 -C22 Diesel Range ND 10.0
Nydraulic Range ND 5.0
NDo Not detected at the specified limits
Form I
D-175

Received: 04/03/92
WHC-SD-EN-TI-136, Rev 0 000109
TEA Ine. REPORT Vert order # A2-04-46
leautts by Sample
SAMPLE 10 11011011 FRACTION 2Uk TEST CODE 0141511 NME Volatile Fuels-TPN
Date A Time Collected 03/30192
Category
MODIFIED 8015 - VOLATILE FUEL HYDROCARBONS
Matrix: Soft......
Date Analyzed: 04/09/92
Dilution factor: .00.L~
concentration Units: ...M1Lo
I ~~samoplel
Compound Result POL
CS -C12 asoline Range No 25.0
MD a Not detected at the specified Limits
Fore I
D-176
9

'Ji
tn
'CCC
be0
Zn .n &nJ
L,
.9-90
0. 0D
Ci .C CD CDC C
41 0 0 Z
to LI 0 L;L;L
co
In fu* 00 0
CC)
4) 0..J
Enj 4)C OV
EVA
C 0
0 .-
C2
9'- 0) 00 C04
WHC-SD-EN-TI-136, Rev. 0
D917

WHC-SD-EN-TI-136, Rev. 0
Roy F. Weston, Inc. - Lionville Laboratory
602X ANALYTICAL DATA PACKAGE FOR
WESTINGHOUSE HANFORD
DATE RECEIVED: 04/03/92 RFW LOT 0 :9204L881
CLIENT ID RFW f MTX PREP 0 COLLECTION EXTR/PREP ANALYSIS
BO1GM7 001 S 9201VO17 03/30/92 N/A 04/09/92
BO1GM7 001 MS S 9201VO17 03/30/92 N/A 04/09/92
BOIG147 001 MSD S 9201IV017 03/30/92 N/A 04/09/92
LAB QC:
BLK MB1 S 92D1V017 N/A N/A 04/09/92
BLK M81 BS S 92D1V017 N/A N/A 04/09/92
D-180

WHC-SIY-EN-TI-1-36, Rev. 0
ROY F. WESTON, INC. A Ay19
Lionville Laboratory i1i RECEIVED
Client: WESTINGHOUSE HANFORD
RFW I 9204L881 (PETROLEUM HYDROCARBONS)
W.O. #: 6168-02-01-0000 Z6%
U -Indicates that the compound was analyzed for but not
detected. The detection limit for the sample (not the
method detection limit) is reported with U (e.g., l0u).
J Indicates an estimated value. This flag is used in cases
where a target analyte is detected at a level less than
the lower quantification level. If the limit of
quantification is l~mg/L and a concentration of 3mg/L is
calculated, it is reported as 3J.
NA =Not Applicable. NRl = Not Required.
NC -Not calculable, results below detection limit.
The method used for the analysis of petroleum hydrocarbons is EPA
Method 418.1 (USEPA 600/4-79-020). Solid samples are extracted
using Method 9071 (USEPA SW846) then analyzed by EPA Method 418.1.
The following is a summary of the QC results accompanying these
sample results and a description of any problems encountered during
their analysis:
* Blank was free of contamination.
" Blank spike recovery was inside laboratory control
limits.
" Matrix spike recoveries were within laboratory control
limits.
Samples Received :04/03/92
Date of Extraction: 04/06/92
Date of Analysis :04/09/92
2x)2DJ
pi(. ihel Taylor -D-ae
"~Project Director
Lionville Analytical Laboratory
D- 181

WHC-SD-EN-TI-136, Rev. 0
Roy F. Weston, Inc. - Lionville Laboratory
PHC ANALYTICAL DATA PACKAGE FOR
WESTINGHOUSE HANFORD
DATE RECEIVED: 04/03/92 RFW LOT f :9204LB81
CLIENT ID RFW f MTX PREP f COLLECTION EXTR/PREP ANALYSIS-
BO1GM7 001 S 92D0HC080 03/30/92 04/06/92 04/09/92
BO1GM7 001 MS S 92DHC080 03/30/92 04/06/92 04/09/92
BO1GM7 001 MSD S 92DHCO80 03/30/92 04/06/92 04/09/92
LAB QC:
MB1 S 92DHCO80 N/A 04/06/92 04/09/92
MB1 BS S 92DHC080 N/A 04/06/92 04/09/92
D-182

fA
41 CoC
c:0
WHC-SD-EN-TI-136, Rev. 0
-4
go 0 cmb
we CDI
0 00
c- CDU
0 041
S00 he
"- 1C M
1~.
U~ La
= 41
M c
5- 1-=
am~
l
004
u
0
C
.
- W
4n cu t- uw
a- CL W 41
o 30 CCe-
0 01
*~~~f 0~MI4..
"It x In wsen
U C.
0010U
4r0 00 0 b
4b4..
wOC r=
rL S-
0
I 1C4
.5-
I.V c.4
U D1183
*

WHC-SD-EN-TI-136, Rev. 0
Roy 1. Wanton, Inc. - LLonvLlle Laboratory
OCSC ANALYTICAL DATA PACKAGE FOR
WESTINGHOUSE HANFORD
DATE RECEIVED 04/03/92 RrW LOT # :9204LOSI
CLIENT ID RPM # 1(TX PREP # COLLECTION EXTR/PREP ANALYSIS
30101(7 001 5 921.30528 03/30/92 04/06/92 04/11/92
80101(7 001 KS 8 92L.30528 03/30/92 04/06/92 04/11/92
30101(7 001 MSD S 92L.30528 03/30/92 04/06/92 04/11/92
LAB QC:
BLX 1(31 8 921.30528 N/A 04/06/92 04/11/92
ELK 1(31 BS S 92LE0528 N/A 04/06/92 04/11/92
D-184

WHC-SD-EN-TI-136, Rev. 0
TANK 100-N-SS-27
Sample Date December 18, 1990
D-185

WHC-SD-EN-TI-136, Rev. 0
D-186

MARTIN MARIETTA ENERGY SYSTEMS, INC.
Ms. Joan Kessner-
Westinghouse Hanford Company
Office of Sample Management
2344 Stevens Drive
Richland, Washington 99352
Dear Ms. Kessner:
WHC-SD-EN-TI-136,.Rev. 0
T//
POST OFFICE BOX 2003
OAK RIMGE TENNESSEE 37831 .740
March 7, 1991
Analytical Results Package on Project 90-027: Underground Storage Tanks Sample
Analysis
Attache d are'the results on the underground storage Tanks samples, Project
90-027,' received into the Analytical Chemistry Department (AmD) laboratories
on December 20, 1990. Also attached are the Chain of Custody records for the
samples, a list detailing the protocol utilized in performing these analyses
(in accordance with agreements between the 0514 and K-25 ACD) and sample
identification information.
The results are reported on ACD's AnaLis report format per letter dated December
20, 1990. All data quality objectives were satisified on this project.
The lead analysis on sample 27-102145, a matrix sample, is incomplete at this
time. However, in order that the data deliverables package on the project not
be delayed any longer, the remainder of the package is being released.
Resolution of this analysis is pending.
Lead
All the required quality control criteria was applied to the samples in the
SDG. For this analysis all instrumnt calibrations (SPCC and CCC) were
within acceptance criteria. The internal matrix spike percent recoveries for
the TCLP analysis were within acceptance limits. Interference check samples
results were within acceptable limits. Replicate analyses were conducted on
samples in the SDG and all relative percent deviations were within acceptance
limits. All internal controls and check standards run during these analyses
were within the acceptance limits. At present the ACD cannot report the lead
blank results through the AnaLis database, however it is required according to
ACD QA/WC policy that no analysis result be reported for any element which is
found in the prep blank above the data reporting limits. The raw data within
the GA~ batch (SDG) for any particular analysis contains the prep blank data
and is available upon request.
D-187
i

Ms. Joan Kessner 2 March 7, 1991
WHC-SD-EN-TI-136, Rev. 0 -- 2
Semi-Volatiles: BNA
The samples were not extracted within the prescribed holding time, missing the
seven (7) day holding time for extraction by seven (7) days. Once extracted, the
samples were analyzed within the prescribed holding time. All surrogate
standards criteria were within percent recovery acceptance limits. All DFI'PP
tune criteria were within acceptance criteria. All "CCC" and "SPCC" components
met acceptance criteria for both the initial and continuing calibration check
samples. All internal standard areas were within acceptance criteria. All
matrix spikes and matrix spike duplicates were within the acceptance
requirements.
All the samples were analyzed within the prescribed holding times. All surrogate
standards criteria were within percent recovery acceptance limits. All Bra tune
criteria were within acceptance criteria. All CCC and SPCC components net
acceptance criteria for both the initial and continuing calibration check
sample. All internal standard areas were within acceptance criteria. All
matrix spikes and matrix spike duplicates were within the acceptance
requirements.
I certify that this data package is in compliance with the terms and conditions
of the OSM' s revised Statement of work and letter dated December 20, 1990, both
technically and for completeness, for other than the conditions detailed above.
Release of the data contained in this hardcopy data package has been authorized
by the Laboratory Manager or his designee, as verified by the following
signature.
. Morrow
Department manager
Analytical Chemistry Department (K-25)
Attachments
cc/attach: D.*L .Auiburgey
S.R.smith - RC
cc: N.P.Buddin
S .W.Goza
H.H. Sullivan
D-188
Sincerely,
Deborah L. Amburgey
Program manager
Hanford Support Program
Clarence R. Kirkpatrick
Program Manager
Waste Management Analysis

WHC-SD-EN-TI-1 36 , Rev. 0
a" Ridge K-25 Site5
Analytical Chemistry Department-5
Results of Analyses
sauls 10: "0122"-51. pro ject: 01.32 027S customer Seeple ID: 27-1.02
Cutomer: KSinSU M Requisition Nmber:
oate Sampled: 16S-0C=21990 Date Ss~2. Received: 20-DEC-1990
samp.ed By: Date Sseple completed: 27-JAII-1992.
material Descrition: SOIL (3 Result has been Corrected for Spike
Date
Ac0%v
mnber Proceduare go. Analysis Result Daits AnalystPiem r Colte
1.02003 ZPA-3050 lad

WHC-SD-EN-TI-136, Rev. 0
AAL1SZ Mh! BUM0 wage I of 2
AaLIS 10: 9"1226-051 customer Sample ID: 27-IO1
- lboratory:- Orqanlc Msu* Spectroscopy Laboratory Cutomer: MR8U33/00OI
File ID: lO2 0"sample
MttlE: SOIL
mastrment, ID: )5970-3 aquisition Nmber:
jutborized by: D. C. Canada Date Sample Received: 20-000-1990
ma- Base4Sauttal/Acid Compounds ITCL)
vete utracted/ftepared:
preparation Procedure Numer:
Percent moisture:
Perenut Ygoisture (decanted):
Associated Blank:
3-%jM-1991
ZFA-3530
0.0
910103-263
Dat* Aalysed: 14-JAM-1991
Analysis Proceeksre Nmer: SM (v.P) WIP
Dilution Factor: 1.0
Analyst: C HOWM
OP. File Nmbers Ma
B3: asalt haa been Corrected for Spike
10"S9-2 Nuentol 9900 106-47-4 4-Chloroanhline 9900
111"4-4 bi ( 2-Chlorioethyl ather 9900 87-46-3 nexachlorobutadielle 9900
95-57-8 2-Wuorogbaol 990 59-0-W7 4-duL~eo3-etbl,haflI 9900
541-73-1 1, 3-Dichlorobenaene11 9900 91-57-6 Z-Mthylnaphtbalefl 9900
106-46-7 1, 4-Dichloc~oSansaw 9900 77-47-4 nexaclorocyclopefltadiele 9900
100-51-6 Benmayl Alcohol 9900 86406-2 2,4 ,6-Trichlorophfol 9900
95-50-1 1 .3-Oithlorobeass%* 9900 95-95-4 2,4,5-Tricblorophensol 46000
99-48-7 2-Hathylhansol 9900 91-59-7 2-Chloronaghtbalele 9900
10"-0-1 bia( 2-

MauIs ID: 901226-051
WHC-SD-EN-TI-136, Rev. 0
LIUSIS 0M
Castowse ample ID: 27-101
k-Laboratory: organic name SpeacrescoW LaboratouyCutmr2KSxVM0
File rot )40929
sample Hatriz: SOIL
restmmnto: )5970-3
aqmisitiofl Nmber,
Autborised BY': 0. C. Canada, Data sample Rleceived: 20-014-1990
on- Baso/weutral/3iid Compounds (1CLI
Date zltracte4/??epaod: 3-3)3-1991
fteparation Procedure 3umect SP3-3S50
Percent misture: 0.0
Percent misture (detestedl:
MAsciated Uak: 910103-263
tI : lesult bh been Corrected for Spike
Date mlymed:
Analysis Procodave Nmber:
Dilution Factor:
Analyst:
Gh File Unmber:
14-3AN-1991
Ua (CL) 30W
1.0
C mew0
MA
pU age 2 of 27
100-01-4
S34-52-1
86-30-6
4-Uitroenilifle
4 .46Oiatre-3-metbT~pIW b
3*uitroedibnyrlanie
460011
460011
9901
53-70-3
191-24-2
Dibesfa~eb)anlthcace"
Uemue(9.h,i VIpels
99011
99011
101-5S-3 4-SrosopbolU5Pl-Pholllethet 9901
116-74-1 RexchLoobeeae 99011
67-44-5 Pentacblorophemol 4600W
65-- Pbonanthrmne 9901
120-12-7 Pothacfl 990M
84-74-2 Di-ft-butylphthalate 340 33
206-44-0 rFlouotbooe 9901
129-00-0 Pyrese 9901
8"-4-7 BuLTybefsyljihtalate
9901
91-94-1 3 .3'-Dicleobidile 20001
56-55.-3 Seso e~stkecene 99011
117-61-7 bis(I2Ifthylhe"yl)3thalato 1SO i3
21"-1-9 cigysmae
99011
117-44-0 Di-e-ectylphthalete 9901
20"-9-2 UenMo~b)flu0otntefl
99011
207-06- sne(kWflubntbees 99011
50-32-6 gen0oa)p3Tee 99011
195-3"- Indene( 1,2,3-cd)Wrea
99011
Date Reportinh Qualifiers:
11 - Compotmod was analysed for but not detected. ?be min~or is the attainable detection limit for the Sample.
* - Amalyte mee founod in the reagent blank as well "e the sample.
j - Indicates en estimaoted valuet.
NO - loot detected.
A - Aldol, condensation product.
O - Secondary dilution.
E - zxgeeds initial calibration range.
D-191

WHC-SD-EN-TI-1 36 , Rev. 0
oak Ridge K-23 Site
Analyical Chemistry D"pgU~
af (TCL) ROIL O3OANIS A.LISS DA-A5if
AS&TLtS ID% -12 5 Customer Sampi. IV: 27-101
Laboratory: organic mass spectroscopy Laboratory,
Somple Matriz: SOIL
Level - (1.w/sid) -LOW
Dilution Factor: 1.0
misture: net dec. 0.0 dec. -Date
xxtgactiefs (S.,/co-t/m@ SoKE
customer: USMOA
rile IV: )10929
Cato Received: 20-DS-1990
Date Analysed: 14-JAII-1991
gntracted: 3-3315-1991
ps: -
gmber Tics found: 4
CA ONEER
Gpc 5concentation IONW (T/)
Units
raJg:5!
1nJ
IopUDO is IT.~ I 0 I
I1. ONSPW -4.291 480001 J
I2. 123-42-21 2-Peatanose, 4-hYdroxy-4-thY 5.74 1 8100 1 JAB I
I3. lWWUMMO 12.36 1 M813 I
I4. IppopApoic C ID, -.4TK!L.l(l,1- I 17.97 1 720 1
15. I
I
2 0.
213.
214.
2 6.
I 7.
2 9. III
320.
- copon 122 wa anlye foIu o eetd h ubri h ttial eeto ii o h ape
a 23
iniae 124
wa fon Inlt interaetbakaswlIstesw*
an esi aedvle
no 25. dete ted -
- 126 co d ns t o pro uct
- Seod 127 r diluion
- 12E int a ai rai nIn
3 - Prdobatle adnetiiatedonl.
III
Io
Izsd
D-192
II
II
I
I
I

WHC-SD-EN-TI-136, Rev. 0
AinhL1S am UP ag o
?maLIS to: 90122"-51 Cutomar sample to- 27-101
j-Labotatocy: orgainic Maesa pectroscopy Laboratory Customer: 9K3SSU/ROM
rile ID: )0744 sample ilatrix: S0OIL
Instrument to: 70-2 Requisition Number:
Authotisod By* D. C. Canada, Date samplo Received: 20-DIC-iggO
vm - Volatile organic Compounds (VCL)
Data gatracted/ peredl
Preparation Procedure Nmeus
Percent reolaturs:
percent Moisture (decanted),
Asuecia ted Blank: 901227-032
Date Analysed: 27-DEC-1990
analyhis Procedure Wmer VMP fai NDI =
Dilution Factor: 1.0
Analyst: Ut P0'!M
rP ile Muser: NA
II 2 Rlesult has been Corrected for Spike
CAS up/Kg CAN ug/Kg
74-67-3 CdIoromotheme
74-43-9 3rommethane
75-01-4 Vinyl Chloride
7"-0-3 Calegeetbane
75-09-2 Nathylece Chloride
67-64-1 Acetone
75-15-0 Ca.'o Disulfide
75-35-4 1,*1-aichloroetboem
75-34-3 1.1-Dicloroetbane,
540-59-0 1, 2-iabloroethene, (total)
67-66-3 Chlorof orm
107-06-2 1.2-4Acbloroethame
7"-3-3 2-4utaione
Lou
Lou
Lou
Lou
SU
3235
5V
5V
90
50
50
so
16 a
79-00-5 1,l,2-Trichloroethane
71-43-2 Sonseine
10061-02-4 trane-l.3-DiCCOPCOPe0
75-25-2 Uroaoform
108-10-1 4-MIthyl-2-peltaflom
591-7"- I-Kexanane
127-1"- Tetrachloroetbefle
70-34-5 1.1 .2,2-Ttrachlocoothaue
106-8-3 Toluene
108-90-7 Chlorobeansefe
100-41-4 Etbylbensee
100-42-S styrene
1330-20-7 lylne, (total)
5u
sty
su
su
Lou
Lou
50
5U
50
50
w0
50
sD
71-55-6 1,1,l-Yrichloroethane 5U
5423-5 Carbon Tetrachloride
50
106-0-4 Vin1 Acetate
10U
75-27-4 Breodichlorowarthele 50
7"-7-S 1,2-Doichloropeopaae
so
10061-01-5 cia-I ,3-Dichloropropine 50
79-01-6 Tricbloroethme SO
124-46-1 Dibrouoc,1ogeothae SO
Data Reporting Qualifiers:
U - Compound me analysed for but inot detected. The umber in the attainable detection limit for the *&WISe.
a - Anlyte we f ond in the reaent blank a well as the sample.
3 - indicates an estimated value.
so - not detected.
A - Aldol condensation product.
0 - secondary dilution.
Z - Exceeds initial calibration campe.
D- 193

WIIC-SD-EN-TI-136, Rev. 0
Oak Ridge 5'.25 Site
Analytical Cbddtrj DPerSt
Results ot Analyses
anaUlS to: 901226-052 Mtject: 0132 0275 Osato-er Sample 10: 27-102
Custier: KSin/RAMS
Psquiaition U.mbet:
Date sampled: 1-DU=-1990 Date saple Received: 20-DUC-1990
sampled By:
oate Sample completed: 27-JAM-1991
Material Descriptidn: SOIL
(ISResult has bees Corrected tor Spike
,.ctiv.
mufer ftocedure no. Analysis sesult iAita Analyst
VDate
File m~er Completed
102003 EA-3050
ZPA-7421
Lead
12
5.8 aejy P BUCKZT 101238 27-imU4991
132803 CPA-3550 prep (U%- SW44-Sx) C R EIS 1993 4-jwI-991
prep (U%.- 35-64-Sax)
Analyst -Ju WEIS
Date extracted
-3-33,3-1991
Sample Weight extracted 49) -10.30
Percent Solids
-92.5
Calculated Dried Weight (q) -9.53
extraction Method
-Soshlet
Extraction Solvent
y IthylSoe Chlaride/Acetm*l
extraction Cleanup
a Sodium Sulfate
Final vlum at extract (ML) - I
Associated Blank
a 910103-243
Spike Recovery Data
Amount Amut Percent
Analysis Spiked Recovered Recovered
LEAD 20.0 22.4 112.00
D-194
Program Manager: D. L. Aurgey
onte Approved 7-FU-l991

WHC-SD-EN-TI-136, Rev. 0
Oak Rid" R-25 Site 16
Analytical Oehwiatry Depatctm
am (TC.) SO1L ORGANICS AW.LYSZS OMAShf?
YTWLI IDmN~fl3D
AA&US ID: 901226-052
Labwratorys organic mass spectroscopy Laboratory
Sample Matrix: SO1L
tLrvSI (low/ied): LW
Dilution Factor: 1.0
% Moisture: not dec. 7. 5 de. -Date
Extration: (sep/cont/seflc! SOUR
customer Sample ID: 27-102
Customer- KCE!!R/ -.
File ID: )10930
Date xeceived: 20-IXC-1990
Date Analysed: 14-JAP-1991
Extracted: 3-U-1
put
Me Ccleeav: (Y/') N
concetration Units
muner TICs fonds 14 IUejT or uvq4! t s
Ohs Room I ~ jpwo In"al I I SM m.* a
I1.
I2.
13.
123-42-21 2-Pentanone. -4-ydrort-4-thY
$72-50-41 2-Pyrrolidiafe. -ethyl-
1 U0131"
1
5.76 1
9.68 1
12.37 1
- 8300 1 33k
460 1 3
6701 in
I
4 . 1 Ime 1.31 1 40 13 J
I6.
I7.-
I .
19.
la.
11.
112.
113.
114.
17851-53-51 12-Sonssnedicaboxylic acid,b
UW3OSAURAT iNrC?.flN
VIwUw mKMJTIUf
OICINK MlCASA
I Wum SATRAMS hfzw I5I
hal MW 1
1 U09MSMURAMIDNTrCADMU
IWEWSURIATED =00CMUM
LtiNU
1
I
Ir
1
1
21.16 1
21.57!
21.671
23.621
25.49 1
25.631
26.371
2.01 1
33.01!1
940 I 1
7"013 J9
4"011
670 1 JI
1800 I is
95013 1
1600 1
6001 is
77013 J
IS
I
115.
if6.
117.
III
t
I
120.
121.
122.
123.
I
I
II
I
I
I
124. _ I
125.II
126.
127.I
128. I
II
I
I
Data Peporting Qualifiers:
V Compound was analyzed for but not detected. The c~e
is the attainable detection limit for the sample.
3 - Analyte was found in the reagent blank as well as the sample.
3 Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
0 - Secondary dilution.
E - Excoeds initial calibration range.
P - Probable Identification.
D-197

WHC-SD-EN-TI-136, Rev. 0 1
MTSIS am ISOR Pag I of I
MaNLIS ID: 901226-052 Customer Sample ID: 27-102
-Laboratory, Organic Mo@$ Spectroscopy Laboratory Customer: iNUSXM OS
File ID: )07745 sample Matrix: SOIL
Inatument ID: 70-2 Rlequisition Winbr:
Aithrised my: 0. C. Canada Date Sample Received: 20-MU-1990
Vh- volatile Organic compounds (M~)
Date Zgtrc*ted./ft0Pared: Date Analysed: 27-MC-1990
fteparatioa, procedure Nuidn: Analysis Procedure NmIbert VA (CLP) 3
percent moistures Dilution Factor: 1.0
percent ibisture (deczanted): Analyst: 1A IoTIU
Asoociated Plank: "01227-032 Q& file amber: MU
R esult haa beem Corrected for Spike
CKP U9W9 CM uq/Kq
74-67-3 Culoreme0thane 10ou 79-40-5 1,l,24riclooetaie 90
74-43-9 Sremmmethase 10ou 71-43-2 Donsmi 551
75-01-4 Vinyl Clocid. 10OU 10061-02-4 trans-1.3-Oidloopropene 90
75-00-3 Ciloeotbane L011 75-35-2 Droafor. 55
75-09-2 Metbylen Chloride 90 106-10-1 4-Methyl-2-VentanOUe Lou
47-44-1 Acetone 10OU 591-7"- 2-Usanm 10ou
75-15-0 Carbon Dislf ide 5U 12'7-1"- Tetrackloroethene su
75-35-4 1 .l-ftcbleroothene 90 79-34-S 1.1.2, 2-4%tracklI0othan 511
75-34-3 1,1-Dicblecrothane 90 10"$4-3 Toluene 511
540-59-0 1,2-Dicbloroothene (total) s0 109-90-7 Chlorobones 511
67-66-3 Chlorof orm 90 100-41-4 Sthylbenseve 551
107-06-2 1,2-Dichlorotane 511 100-42-5 Styrene 90
7"-3-3 2-batanone 17 a 1330-20-7 xylone (total) 511
71-55-6 1.1.l-frichlootbane 9
56-23-5 Carbon ?etrackloride 90
109-0-4 Vinyl Acetate 10OU
75--27-4 Brnmdichlorosetbane 90
76"7-5 1,2-ODichlorepropane 90
10061-01-5 cia-I .3.-Dicbloroproen 511
79-01-4 Trickloroethene 511
124-49-1 Dibraoecbhlorouethane 90
Date Reporting Qualifiers:
U -Compsod was analysed for but not detected. The nmber is the attainable detection Limit for the sample.
5 Analyte wa found in the reagent blank as vella the SOaP1e.
i -indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
9 - Exceeds initial calibration range.
D-198

WHC-SD-EN-TI-136, Rev. 0
Oak Rid"e Kr-2S Site
Aalytica etStry Department
V" (TM SoIL ORUM~CS ANALTIS =AASI
W!ALTZVZL IVhNIIIED CCRMMU
mauls xD: 901226-052
Custome~r Sapl ID: 27-102
Laboratory: Organic Mass Spectroscopy Laboratory Cutste: KCUdWMAS
Semple "tria: SOIL. pile rD: )07745
Level: (lovj.d): UN
Date Received: 20-OCC-1990
Dilution Factor?
% isitur.: not dec.
1.0 Date Analysed: 27-DSC-1990
concentrationl ailts
Numer T1C6 fouind: I IUg/L or aaq: !!Sd1
I1. 64-19-71 Acetic acid I 15.62 1 5 1 1
12.II
14. II I
I10.I
I12.I
113.III
14.
117.IIII
I20.
I21.I
I22.
I23.
124. _II
125.III
I26.II
I27.II
129.I
130.I
Data aeportiiq Qulifiers:
v - compound was analysed for but not detected. The nmber is the attainable detection lt for the sample.
3- Analyte was found in the reagent blank as well as the sample.
3 - indicates an estimated value.
ND - Not detected.
A - Aldel condensation product.
D - secondary dilution.
C - ExceeA. initial calibration range.
P - Probable Identification.
D- 199
I
IIII
IIII
III
II
II
II
II
II
I
I
I
1

WHC-SD-EN-TI-136, Rev. 0
Oak lid"e R-25 sit.e3
Analytical awaistry Depae t
Results of Analyses
AnaLIS Zi 90122"-55 ftelect: 0132 0271 custmr S"9ple zD: 27-103
azetoart KISE3S'T0S
Cato Sampled: 18-MC-1990
Seled By:
Material Description: SOIL
Requisition Numer:
Date Sample Received: 20-DCC-1990
Date Sample Completed: 27-JN14-1991
(1 Result has been corrected for Spike
Qa& Date
Activ.
mber Procedure No. Analysis Result MitS Analyst Pile wwoer completed
102003 EPA-3050 toa" 8.4 Uq/I 1 I3Q 101233 21-JAII-1991
zUA-7421
132803 EPA-3550 Prep (anh SW-446-Sox) C 33 U3S 1993 4-.IUS-1991
Prop DiMs- SV.446-Sox)
Analyst -u VMURS
Date Extracted
*3-JAN-1991
Semple Weight Extracted (If - 10.15
Percent Salida
a 93.3
Calculated Dried Weight (g) a 9.*47
Extractioni Method
aSoshlot
Extraction solvent
a Nethylene, ailoride/Acetoae
Extraction Cleanup
= Sodium Sulfate
Filial Volume of Extract (aL) a 1
Associated slamk
a 910103-263
D-200
program M~anager: D. L. AmburqQY
Date Approved: 7-FZB-1991

Ma~lS to: 90122"-55
WHC-SD-EN-TI-136, Rev. 0 PgIo
Cumtonst sample xD: 27-103
- Laboatory: organic Mass Spectroscopy Laboratory Customer: KSU/RAOS
rile ZD: )10933
Sample Matrix: SOIL
mstmsn t ID: 5970-3
PAqUiaition Maher:
Authorized Dr* D. C. Canada Date Sample ReceiVed: 20-09C-1990
am- saa.,4buttal/Acid Compounds (TCL)
Date rxtrated/Prepared:
Preparation Procedure number:
Percent misture:
Percent Hoist"r (doented):
Associated Blank:
3-SAM-1991
ZVP-3550
6.7
910103-263
Date Analysed: 14-IMI-1991
Analysis Procedare nmber: IM (C.1) MP
Dilution Factor: 2.0
Analyst: C IUUWI
QA rile amber: MA
I Rsult has been Corrected for SPike
10"-5-2 2bol 21000 106-4 4-Chloroaniliae 21000
111-4-4 bis(2-Wloroethyl ether 2100t3 17-66-3 Nexacklorobut~diwA~ 21000
9S-37-8 2-Chloropbenal 21000 55 -507 4-WChOr.3-methlPbeI11 21000
541-73-1 1 .3-Oichlorobesme 21000 91-57-6 2-Mthyla#thalefle 21000
10"-6-7 1 .4-Oichlorobensense 2100V 77-47-4 NexachoocclOPeft~diw 21000
100-51-6 leeyl Alcohol 21000 88-6-2 2.4 ,6-ftrichlooPhfOwl 21000
95-SO-1 1 .2-Dichlorobeflsene 21000 9S-95-4 2,*4 *5-Trichlopheftol 100000
9"94-7 z-nwbhlpbenol 2100 91-54-7 2-Wloronaphthalowt 21000
10S640-1 bis(2-waoroisOp1l ether 21000 86-74-4 2-MKitroanilile 100000
106-44-5 4-N4btylpbefol 21000 131-11-3 DimtbYlphthalate 21000
621-64-7 M4itroso-di-O-,ropylamine 2100U 206-6- AeenaPhthYle"k 2100U
67-72-1 H.sschloroethane 21000 9"-9-2 3-*Itroaailine 100000
9"-5-3 Ititrobemeiie 21000 83-32-9 Aceataphthefle 21000
76-55-1 Isephorone 2100U 51-26-5 2,*4-Dinitophfol 100000
88-75-S 2-4itropheol 21000 100-02-7 4-ilitropbeflol 100000
10"-9 2,4-DiUthylphb-I 21000 132-64-9 Dibeasofuraf 21000
65-65-0 Uwsoic Acid 100000 121-14-2 2,4-Difitratolufes 21000
111-91-1 bist 2-Oloroethoxy methane 2100 606-20-2 2 .6-Dinitroto1umwn 21000
120-63-2 2.*4-ftchlorophenol 21000 64-66-2 Diethylphthalato 200 B
120-42-1 1.2 ,4-TricLooboeflefe 21000 7005-72-3 4- W orophenYl-Ph W lather 21000
91-20-3 Nahthalene 21000 86-73-7 Fluorene 21000
Data Reporting Qualifiers:
U-compound was analyzed for but not detected. The m er in the attainable detection limit for the Sample.
S-Analyte was found in the reagent blank as well as the sample.
J - indicates an estimated value.
No - not detected.
A - Aldel condensation product.
D - secondary dilution.
C - Excoed initial calibration range.
D- 201

WHC-SD-EN-TI-136, Rev. 0
UPPShS MF Z Page 2 of 2
An&=I ID: 9"1226-055 customr Sample ID: 27-103
- Aborately: Organic Mass Spectroscopy LAbocatory Cuatomer: VZSSNEU.FMS
File ID: 310933
Sample Matrix: SOIL
Instrument IV: 5970-3 Requisition iNmer:
Authorized my: D. C. Canada Date sample Received: 20-MI-1990
IM - Base/neutral/Acid Compounds (ToL)
Date Ztracted/Preparedt
Preperationt Procedure Number:
PercanI Moisture:
Percent Moisture (deanted):
Asociated Blank:
3-3AM-1991
ZPA-3550
4.7
910103-263
Date Analyxed:
Analysis Procedure Nmber:
Dilution Factor:
Analyst:
C~ File Numer:
14-JA2I-1991
BM. (CLIP) MDF
2.0
C MIMW
MA
(3 ahsult, ba been Corrected for Spike
100"1-4
534-S2-1
66-30-6
4-Nitroaflhlifle
4,6-Dinitro-2-Uewthlphooo
N-uitrosodipbeftYlaaine
1000011
1000011
210011
53-70-3
191-24-2
D~bomsaaflnthracefle
Senso(q,h,i)perylwwl
300 1
210011
101-55-3 4-Bromopbenyl-phonfyl~ther 21001U
118-74-1 Hexachioroboene
21001U
$7-66-5 Pentachlorophsflol 1000011
65-01-4 Phemanthruna 210013
120-12-7 Anthracene 210013
84-74-2 Di-a-btylpbthalate 3600 9
206-44-0 Fluoranthae 210011
129-00-0 Firom 210011
65-44-7 outylhesylhthalate 21001U
91-94-1 3,3'-Oicblorobefsidine 42001U
W455-3
117-81-7
Beseas~thracene
bis( 2-tthylbexyl ~itbalate
21001U
490 3S
21"-1-9 Chcysene
220 3
117-84-0 Di-e-octylpbthalate 2100V1
20S-99-2 Sensobfluoranthelle 210011
207-06-9 Bensotkfluoranthene 210 1
50-32-4 Besso(aOpyroes 270 j
193-39-5 Indmf(l.2.3-cd)pyrene 200 3
Data Reporting Qualifiers:
V -
a -
Coqmoud was analysed for but not detected. The nmer is the attainable detection limit for the Sample.
Analyte, was found in the reagent blank as well as the sample.
i - indicates an estimated value.
MD - not detected.
A - Aldol condensation product.
D - Secondary dilution.
9 - Exceeds initial calibration range.
D-202
35

WHC-SD-EN-TI-136, Rev. 0
ak lid". S-25 Site
jonlytical diemiatry Departmenit3
Ma (=). SOIL CRMCS AWLYSS DaSUT
AnaLIS IM 3012226-055
Laboratory: Organic pgass spectroscop
Sample matrix: so IL
Level: (low/bad): LOW
Dilution Factor: 2.0
% ibiature: not de. 6.7 doe.
Utgactiopi (Seet/cait/softcI Sams
Iabotatory
cusomer sample it: 27-103
customer: YS3~K
file IV: M0933
Data Received: 20-OC-1990
Date Analysed: 14-3)3-1991
Date Extracted: 3-JUB-1991
Vol
WPC cleanups (!W)!N
concentrationl Units
Numbe Ties found: 6 tug^I of UgVfqg: %Ij
I asinauM C0160 M' T WT. co. I I
I1. 123-42-21 2-Pentancee. 4-ydraX?-4-thy 5 .72 1 $700 1 33)
I2. 1UISOU 12.36 1 150013 is
I3. IMMin UAM3ATMYIOD W 19.32 1 93013 IS
I4.
UMwW SATURAXZDI HYRCRO ~n
21.56 1 no6I is
I .IWL93MO SMTURATZO HYOCA)ON 25.438 1300 1 is
I 6. j ~S~nWTED UUOCARBO 26.36 I110013 is
~7.
I
110. I II
I
113.
114. I I
116.
117.
119. I I
120. III
I21.II
122.
I23.
I24.I
II
I
I
125.-II
126.
127.
I
I
I
I29.
I 30.
Data Reporting Qualifiers:
U - compound was analysed for but not detected. The wntber is the attainable detection limit for the sample.
3 - Analyte was found in the reagent blank as well as the sample.
3 - Indicates an estimated value.
M- not detected.
A - Aidol condensation prodect.
D - secondary dilution.
E - Exceed- initial calibration range.
P - Probable Identification.
D-203
II
II
I
I

WHC-SD-EN-TI-136, Rev. 0
MxT3S MTA Romt Pae 1of 1 38
AnaLIS3 ID: 90122"-55 customer sample ID: 27-103
-Laboratory: Organic Maa Spectroscopy Laboratory Customer: KSMER/R0oS
file ID: 07746 Sample Matrix: SOIL
instrument to: 70-2
Requisition Nmer:
Autohied By': 0. C. Canada oate sample Received: 20-DIc-1990
DA- volatile organic Compounds ITCL)
Data tatracte4#epaced:
Date Analyzed: 27-OCC-1990
Preparatio Procedure Mmberi
Analysis Procedure Numer: VOP. (CLP) KOW
Percent Noaiture: Dilution Factor: 1.0
Percent Moisture (decanted): Analyst: LK POTTER
Associated Blank:. 901227-032 a File number: Nh
(3:Result has been corrected for Spike
CAB Uq/Kq CM uqJ~q
74-47-3 Culocamethane
74-43-9 9romomethane
75-01-4 vinyl chloride
75-00-3 Clocoethane
7"-9-2 Methylene Chloride
67-44-1 Acetone
75-15-0 carbon Diaulfide
7S-35-4 Il.-Dicbhloroethefle
75-34-3 1 * -Dichloroethafle
540-39-0 1,*2-Dichlocoethene Mtotal)
67-66-3 Chloroform
107-06-2 1,2-Dichlocoethane
7"-3-3 2-Butanone
1IOU
Lou
Lou
Lou
2 3
46 3
5V
SD
SD
S13
SU
SD
1439
79-0-5 1,1, 2-Trichloroethan*
71-43-2 Blenzene
10061-02-4 trana-l *3-Dichlotoopmee
75-2S-2 Scteoetorn
100-10-1 4-Mthyl-2-pentalofl
591-7"- 2-Nexanone
127-18-4 Tettachloroetheie
79-34-5 Il2,2-Tetrachlotoethan*
106-46-3 Toluene
106-90-7 Chlocobensene
100-41-4 Ethylbensene
100-42-5 Styrene
1330-20-7 xylene (total)
511
SU
S11
5U
2 J
1IOU
5U.
SD
SD
SU
SD
SD
5U.
71-55-4 1,1 ,l-Trichlotoothale 5V
56-23-S Ca-*on Tetrachloride SU
10"-0-4 Vinyl Acetate
I=U
75-27-4 Bromodicloromethane, 5D
76-87-5 1, 2-Oiehlaropropane SD
10061-01-S cia-I *3-Dichloropropene SD
79-01-6 Trichlocoethmn SU
124-41-1 Dibromchloromethafle SD
Data Reporting Qualifiers:
V3 - compound wa analysed for but not detected. The nmb~er is the attainable detection limit for the sample.
a - Analyte was found in the reagent blank as well as the sample.
3 - indicates an estimated value.
No - Not detected.
A - Aldol condensation product.
o - Secondary dilution.
E - exceeds initial calibration range.
D-204

-
WHC-SD-EN-TI-136, Rev. 0
Oak lidte R-25 Site
Analytical ceaistty Department
'Q~OA (TCL) SOIL OMABICS ABALSIS DATA HT
E!TVLY IDE!IED @ID
AnaLIS ID: 901226-055
customer Smp1e ID: 27-103
Laboratory: Organic Mesa SpectroscoVY Laboratory customer: KESZIA
sample Matrix: SOIL File ID: )077483 -
Level: (low/med): LC(
Date Received: 20-OSC-1990
Dilution Factor:
% Moisture: not de.
1.0 DateaAnalysed: 27-OCC-1990
concentration Wits
number TICs found: 1 (Ug/L or ag/hg?: U,~
I1. InIU5.331 5 13
12..
13.
5'.
16.
140.
I16.
117.
119.
I
I20.
II
121.
I
I22.
II
I23.
24. I
II
I
126.
127.
I29.
130.
Data Reporting Qualifiers:
v - compound wasn analysed for but not detected. The n~r is the attainable detection limit for the sample.
a - Analyte was found in the reagent blank as well as the sample.
.7 - indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration ranqe.
P - Probable identification.
D-205
III
II
1
I
I
I
I
I
I
4

WHC-SD-EN-TI-136, Rev. 0
Oa~k aid"e K-25 Site41
Analytical Chemistry Department
Results of Analyses
ManSu ID% 901226-056 Project: G132 0275 Customer Sample JD: 27-104
Customer: V5S~In/IOOS Requisitioni Nmber:
cate Sampled. ls-MS-1990 oate Sample Received: 20-DSC-1990
Sampled By* Date Sample Completed: 27-JAM-1991
material Description: SOIL (1:Result haa been Corrected for Spike
0bDt
Activ.
Number Procedure NO. Analysis Result units Analyst rile Number completed
102003 EPA-3050 Lead 4.6 uq/q P BWCKLEY 10123H 27-JAM-1991
SPAR-7421
132803 ZPA-3S10 prep (Buh- SW-446-Sox) C J11 KZIS 1993 4-JAM-1991
prep (USIA- SM-846-5030
Analyst
a JE RZ13l
Date extracted
a 3-JAU-1991
Sample Weight extracted fg( - 10.32
Percent solids
a 92.7
Calculated Dried weight (q) . 9.57
extraction Method
W Soxhlet
extraction Solvent
a Methlylene Ciloride/Acetole
extraction Cleanup
= Sodium Sulfate
Final volume of extract (Wa I
Associated Blank
a 310103-263
D-206
program manager: D. L. Amburgey
Date Approved: 7-rflS-1991
4

WIIC-SD-EN-TI-136, Rev. 0 a". I of 2
L104=1 DhA3P0
Angusto: "22"S6customer Sample tD: 27-104
-Laboratoly: Orysnic Nags Spectroscopy Laboratory customer: KESSXCMM~S
File ID: )10934 Semple Matrix: SOIL
Instrumenit ID: 9970-3 Requisition Nmber,
Aathoixed By: D. C.- Canada Date Sample Received: 20-OCC-1990
MNa - ease/iueutral/Acid Compounds (TCL)
Date gxtracted/Prepared:
Preparation Procedure Number:
Percent Motisture
Percent Flaisture (decanted):
Associated Blank:
3-J)11-1991
EPA-3550
7.3
910103-263
Date Analyzed: 14-3)11-199L
Analysis Procedure Nuer: BMA (C.?) NDP
Dilution Factor: 9.0
Analyst- C MECHAN
Gh Pile Nmber: NA
(I1 Result has been corrected for Spike
10"-9-2 P"Nol 520013 106-47-8 4-Chlocoaflulife S20013
111-44-4 bi ( 2-diloroethyl )Other 920013 s7-6&-3 nexachlorobutadiefle 920013
95-37-4 2-Walropbenol 9200V3 59-S0-7 4-W~oro-3-eethy1pheflo 920013
S41-73-1 1.*3-0ichlorobentsene 920013 91-57-4 2-IHthy1naphthalefte 24000
106-46-7 1 * 4-Dichlorobensefl 52001U 77-47-4 mexachlorocyclOpentadiefle 52001U
100-51-4 Densyl Alcohol 9200U 8"06-2 2,4 ,6-TrichloroPheflol 920OU
95-90-1 1, 2-Oichlorobonsefle 920013 95-9S-4 2,*4. 5-Trichlor*Phefll 260001U
95-48-7 2-+thylphenol 52001U 91-58-7 2--diloronaPhthalefle 52001U
10"-0-1 bis 2- W oroisopropy ether 52001U 68-74-4 2-Nitroaflilile 240001U
106-44-5 4-IMethylpheno I92001U 131-11-3 Diaethylphthalate 920013
621-64-7 N-fttroso-di-"ropy153ifle 52001U 208-96-8 Acenaphthylefle 520013
67-72-1 Nezachloroethazle 52001U 9"-9-2 3-Nitroanilile 260003
98-95-3 Nitrobensene 520013 83-32-9 Acenaphthefte 760 J
78-59-1 Isophorone 92001U 51-28-5 2 ,4-Diflitraphef-o1 260001U
68-75-5 2-Nitrophanol 5200V3 100-02-7 4-Nitrophenbl 260001U
10"-7-9 2,4-Dimethyiphenol 920013 132-64-9 Dibeflsoturan 5200U
65-0 Densoic Acid 2600013 121-14-2 2,4-Dinltrotoluele 520013
111-91-1 bis (2-adoroethoxy methane 520013 606-20-2 2, 6-Dinitrotoluefle 52001U
120-63-2 2. 4-Dichlorophenl 920013 64-66-2 Diethylphthalate 52001U
120-82-1 1,2, 4-Trieblorobenselle 32001U 7005-72-3 4-Chlorophenyl-pheInylether 52001U
91-20-3 Naphthalene 52001U 86-73-7 Pluorene 52001U
Data Reportiiiq qualifiers:
u3 - compound was analysed for but not detected. The number is the attainable detection limit for the sample.
B - Anayte was found in the reagent blank a well as the Sample.
3 - indicates an estimated value.
ND - Not detected.
A - Aldol condensation product-
0 - Secondary dilution.
S- zxceeds initial calibration ranqe.
D -207

WHC-SD-EN-TI-136, Rev. 0 ~2o
M N N MI S D A N AP g e 2 f 2
iADLIs IV: 901226-056 customer Semple IV: 27-104
-Laboratory: organic mass Spectroscopy Laboratory Customer: USSMS/AXOS
File I0: )10934 Semple matrix: SOIL
instrumnt ID, 5970-3 Requisition Mnber:
Authorized By: D. C. Canada Date Bowpls Received: 20-DEC-1990
DIM - ease/Neutra 1/Acid Compounds (TC.)
Date 9xtrocte4/Prepared: 3-3hMI-1991 Date Analysed: 14-3AW-1991
Preparation Procedure Nuer: EPA-3550 Analysim Procedure nmer. DNA (CL?) ND?
Percent moisture: 7.3 Dilution Factor: 5.0
Percent moisture (decanted): Analyst, C PU(AN
Aseeciated Blank: 910103-263 Ch File Nmb~er: NA
(I Result haa been Corrected for Spike
ChB up/Np ChB up/K1
100-01-6
534-52-1
4-Nitroaniline
4,6-finitro-2-sthy1phenlI
2600013
2600013
S3-70-3 Dibens(a~h)anthracene
191-24-2 Bsnxo4p.h.i)perylene
560 3
52001U
86-30-6 N-it rosodiphenylamne S2001U
101-55-3 4-Sromhny1-zheWlether 520013
118-74-1 Hexachlorobensene 520013
87-46-5 Pentachlorog'henol 2600013
6S-01-6
120-12-7
Phemanthrene
Anthracene,
3600 J
520013
84-74-2 Di-n-butylphthalate 3400 J
206-44-0 Fluoranthene
7200
129-00-0 Pyrene 7200
8"84-7 Dutylbeasylphthalate
520013
91-94-1 3,3'-Dieblorobenxidine 1000013
56-55-3 Defho~aanthracens 4100 J
117-61-7 bis(2-zthylhexyl)phthalate 1600 1
21"-1-9 Chryene
6100
117-64-0 Di-n-octylphthalate 520013
20 5-99-2 Denso( b) fluoranthene 6000
207-08-9 Saaao~kfluornthele 52001U
50-32-6 Dec50 (a pyrafe 4000 J
193-39-5 Indeno(l,2,3-cd)pyrene 520013
Data Reporting Qualifiers:
13 - Compound was analysed for but niot detected. The number is the attainable detection limit for the sample.
B - Analyte was found in the reagent blank as well as the sample.
J - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
9 - Exceeds initial calibration range.
D-208

-
AnaLs In: 90122"-56
Laboratory: organic Mass Spectroscopy Laboratory
Sample Matrix: SOIL
Level: (low/mad): LOW
WHC-SD-EN-TI-136, Rev. 0
Oak Rid"e K-25 Sit.
Analytical chemistry Dvpartmant
sue.~a (TCL) SOIL OW.NICS ANALYSIS DATA UI
Customer Sample ID: 27-104
Customer: KESSM/ROOS
File ID! >10934
Date Received: 20-DCC-1990
Dilution Factor: 5.0 Date Analyzed: 14-JA11-1991
% Moisture: net dec. 7.3 dec. Date gxtracted: 3-JAM-1991
Utractiofl: (Sep/Coflt/S3flc) 5011
p:
arc Cleanup: (nwK)!
Concent ration Units
amber TICe found: 21
(neiL or uVq): nm~
I CAS am I COMPOND AM IT ESUT. CONC. I Q I
I1. I (NIW SM JRAMZ 1YROOM 8.19 I 44000 1 J
I2.- 10"-7-81 1,3.5-Trimethylbeflleno 1 8.39 I 46000 1 J
I3.-
80I SE. -ETnVL-M=H 1 8.56 I 17000 I 1 IY
4.IDUZ an= -uzTL-lC TL 9.41 I 43000 1 Y
I5.- INM m3S SM HYDROCARNSO 9.62 1 40000 1 J
6. I S3W3n. -ICT ITL-PSOPYL 9.96 I 95000 J 3
I7. I SEZDI,-EITY1-DIMRTHftL I 10.11 I 61000 I 1
8 .
I9.
to0.
It1.
I12.
I13.
I14.
I 5.I
I 3zNZM -3TTL-DI1NfTUYL
BEN3. -IUIL-DINIUIL
Benen, MtTH!L-IMflTLZTL
Imm wn ARmaIC XY41CAUMN
I I.Um AWW=SC HNYRCMWMN
UWn" ARMATC HYDRCAIRBON
MOW A"MTC WIIDROCARSM
in AW=C inom"'
I
I
I
10.43 I
10.47 I
10.621
10.88
11.47 I6700
11.58 1
11.74 1
11.86 1
33000 JY1
17000 J 3
70001 J
mo 880 i3
1 3
17000 1 J
23000 1 J
11000 1 3
I
-A
I 16QW
17'.is1.
I19.
20.
AnWoTI Na C3O
IT WV AM IC HDOCKABOSK
3911210M.-DUIIS?!W RLEI~T1L
Um"ne
a-u3100IZ,2.3-DUCTWO-D1M1fTL
I
I
11.96 1 12000 1 1
12.11 1 620013J
12.49 I 16000 I 1
13.33
6500 1
13.54 I6600 I 1
I21.
122.I
123.
24.
I25.
III
126.- I
127. _ III
I29.
130.
Data Roportinq Qualifiers:
I&TM tPII I -uL1YML I 14.37 I 11000 1
1
U - Compound was analysed for but not detected. The number is the attainable detection limit for the sample.
III
B1 - Analyte was found in the reagent blank as well as the sample.
3 - Indicates an estimated value.
No - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Exceeds initial calibration ranqe.
P - Probable Identification.
D-209
II
I
I
45

WHC-SD-EN-TI-136, Rev. 0
PA ?MIS DATA MMO Page I of 1
NIUS ID: 90122"65 Customer sample ID: 27-104
-Laboratory: Orgafic Mass SpeOcUOpOY Laboratory Customr: IKsSiN/ROS
File 1D: )07775 Sample Matrix* SOIL
instrument IV: 70-2 Requisition Number:
Authorized Dy: D. C. Canada Date Sample Received: 20-DUC-1990
VGA - Volatile Orqsnic Compounds (TCL)
Date, xxtracted/rroeared: Date Analyzed: 31-09C-1990
Preparation Procedure Nmber: Analysis Procedure Mmber* VOA, (CLP) MW?
Percent moisture: Dilution Factor: 100.0
percent misture Idecanted): Analyst: Ut PDT=U
Associated Dlank: 901231-001 gh File Nmber: M
(3 esult has been Corrected for Spike
CAS U9/K9 CKl uq/Kq
74-47-3 Culoromethane
74-63-9 Bromometbafte
75-01-4 Vinyl Chloride
IS-00-3 Cbloroethane
75-09-2 Methylene Chloride
67-64-1 Acetone
7S-15-0 Carbon Disulfide
7S-35-4 ll-Dicbloroteie
7S-34-3 1, 1-Dickloroethafle
540-5"- 1.*2-Dickloroethefl (total)
67-66-3 Chloroform
107-06-2 1, 2-Dichloroethane,
78-93-3 2-Dutanone
13000
1300U
13000
13000
260 35
1300U
630U
630U
630U
630U
6300
6300
13000
79-- 1,1, 2-Trichloroethane
71-43-2 Denies.
10061-02-6 trans-1, 3-Dickloroproper-
75-25-2 Bromoforn
106-10-1 4--Nethyl-2-pentalone
391-7"- 2-4meanone
127-1"- Tetrachloroethefle
79-34-5 1.1,2,2-Tetrachlaroethate
10"-6-3 Toluene,
106-90-7 Culorobensene
100-41-4 thylbensene
100-2-5 Styrene
1330-20-7 Xylene (total)
630U
6300
6300
6300
13000
5400
630U
630u
630U
160 3
6300,
630U
13000)
71-SS-6 1,1.1 -?ricbhloroethafle 630U
56-23-5 Carbon Tetrachloride 630U
106-05-4 Vinyl Acetate 13000
7S-27-4 Dromodichloromethafle 6300
7"-7-5 1, 2-Dichlocopropafle
6300
10061-01-5 cis-1,*3-Dichloropropene 6300
79-01-6 Trichloroethefle 6300
124-48-1 Dibrosochloromethafle 630U
Data Reportinq Qualifiers:
U - Compound %me analyzed for but not detected. The nmber is the attainable detection limit for the simple.
a - Analyte ws found in the reagent blank as wiell "n the sample.
3 - indicates an estimated value.
ND - Not detected.
A - Aldol condesation product.
O - Secondary dilution.
9 - Exceeds initial calibration ranqe.
D-210

WHC-SD-EN-TI-136, Rev. 0
Oak aid"e F-25 Site
Analytical Chemistry Depa rtment .4 8
.- I!CL) SOIL GRUNICS AMULSIS =AAS~l
AmaLlS ID: 901226-056
Lebnratoty: Organic Has* Spectroscopy LabOratoVY
"saml Mattis: SOIL
Lewell (1ga/mod)l LOW
Dilution Factor: 100.0
Custoer sample ID: 27-104
Customer: KSURM
rule ID: >07775
Date Received: 20-M6-1990
Date Analysed: 31-IXC-1990
% Misiture: not dsc.
concentration units
Nmer TICs found: 9 (ugyL or uq9: !!1
I CmS f j" Cava=~ I9 ST I T. C .I I
II. IU W I 13.761 9301 J
2. I3.-IuTYL FO 14.581 6301 J
I3. IUOUM WTMCR3W 16.001 520, 1
I4. IMMw HNTIMO35M 17.391 1900 1
IMO 5.YMO~NTCAMMU 17.53 1 20 1 I
I .un~HD~8OUI 19.09 1 930 1 I
I7. IwinM NTOMCS33W 1 21.30 1 11000 13 1
I S. Iui MO!C3U I 22.06 1 200013 J
ITr 9.M
BOL~h UM LI lwM
22.45 1 2300013 J
13.
j14.
117.I
120.
21.
122,
123.
124.
125.
126.
127.
129.I
130.
Data Reporting Qualifiers:
V Compound was analyzed for but not detected. The numer is the attainable detection limit for the sample.
3-Analyte ws fod in the reagent blank as well as the sample.
3-Indicates an estimated value.
ND - toot detected.
A - Aldel condensation product.
D - Secondary dilution.
E- REced initial calibration range.
P - Probable identification.
D-211
III
I
I
I
I
I
I
I
I
I
I
I

WHC-SD-EN-TI-136, Rev. 0
Oak Ridge Ir-25 Site 50
Analytical Chemistry Department
Results .t Analyses
AmmS 10, 90122"507 Proe.cti 0132 027S Customer Sample 10: 2710a
Cotmar, inS~o5kk Requisition Nmbe:
Date Sampled: 18-M~-1990 Dte Sample Received: 20-MU-1990
Sampld 3 1 c: Dote Sample Copleted: 27-JAMI-l991
material Description: SOIL (I:Result has beam Corrected for Spike
ACtiv. GA Date
Nmber Procedure no. Analysis Result units Analyst Fie u.mber COWletod
102003 ZPA-3050 Load 4.3 Usyg P SUCZZ 16123R 27-Jam-1991
PAF-7421
132803 SPA-3550 Prep 131%- S*446-Sexy C in ShIS 1"93 4-JAM-1991
Prep (XHA- SW-846-Sou)
Analyst - 33S SRI=
Date Extracted - 3-JAII-1991
Sample IWight gxtracted (q) a 10.60
Percent Solids - 92.5
Calculated Dried Weight 1g) a 9.81
Etraction Method a Sshlet
Extraction solvent - Hathlylen. ailoud/Acetone
Etraction Cleanup a Sodium Sulfate
Final Volume of Extract (maid I
Associated Blank - 910103-263
*** Comments from the Ocganic mass Spectroseopy Laboratory
TZuu SAMPLE wC NOT NUET CLI W Olt LABSAIMR GAP M1!UI FOR SURMOGATE
STANDARD % ROERY FOR ZZIAUBL NAMau. TWO OR IC SUINCOWS
STwAMIRS WZR OUysXD APTwANCE CRIIRA, wuuXT WA TO URX ZmFCT AND
DUmAITm. ZUUSA STAM MODAWS N wnumZ CLP SOW AM LKNOAM GW
D-212
Program Manager: 0. L. Amburgey
Date Approved: 7-rED-1991

WHC-SD-EN-TI-136, Rev. 0
AnLtS DsAOTA US~Pag,
ADaLIS to: 90122"-57 Customer Sample Io: 27-105
-Laboratory: Organic Mans Spectroscopy Laboratory customer: X9S8HiNO00
rile IV: 10935 Sape Matrix: SOIL
Insumnt IV. 5970--3 Requiition nmber:
Authorized by: 0. C. Canada oate Sample Received: 20-MU-1990
SEA - D sefU~tral/Acid Compounds (TC.3
Dats xxtracted/Prepared: 3-JMI-1991 onto Analysed, 14-JAS-1991
Preparation Procedure nmers ZPA-3330 Analysis Procedure Suabt: Ift ( HL) OP
percent Moisture: 7.5 Dilution Factor: 5.0
percent moisture (decanted): Analyst: C IIM
Associated Blank: 910103-263 1%W rile amber: Wh
ti Result bas beom corrected for Spike
1 of 2
ChM mg/Kg CS m/I;
10$-95-2 Phenol SOOOU 106-47-8 4-Welroanilile 500
111-44-4 blat 2-diloroethyl )ether 50001U 67-48-3 llezachlorobutadiene 500OU
95-57-8 2-Chlorepbenol, 500013 59-50-7 4-Chloro-3-mothylphsIol 10001
541-73-1 1, 3-Dichlorobeflsefe 500013 91-S7-6 2-mathyluaghthalefte 35000
10"-6-7 1, 4-Dichloraoenan 500013 77-47-4 Ilexachl orocyclopefltadiefle 50001
10"-1-4 Deesyl, Alcohol 5000u3 86-04-2 2,*4 ,6-fTichorophelldl 500013
95-50-1 1, 2-Dichlorobeuisene 500013 9"-5-4 2,4.3 -frichloraph -,I 2400013
95-40-7 2-Naothylphenol 500013 91-5W7 2- W oronapbthaleno 50001
10"-0-1 biat 2-chloroiapopyl ether 5001 88-74-4 2-ftroaniline 2400013
106-44-5 4-Nothylpbeol 50001 131-11-3 Dimsthylpbthalate 5001
621-44-7 N-Mit roso-di-n-propylamile 500013 208-96-8 Acenahthylene 50001
67-72-1 Hexachloroethane 500013 99-09-2 3-alit roamiline 2400013
98-5-3 Nitrobeasene 500013 83-32-9 Acenaphthete, 2000 .7
7"-9-1 Isoghorone 500013 51-20m-5 2,4-Dinitopheflal 2400013
88-75-5 2-fitrophmW 500013 100-02-7 4-Nitrephenol 240003
105-67-9 2 ,4-Dimethylpbenol 500013 132-4- Diheasofuran 500013
45-85-0 Sensoic Acid 2400013 121-14-2 2,*4-Diaitrotoluene 50001U
111-91-1 bist 2-Chloroethoxy methane 500013 606-20-2 2 .6-Olnitrotoluefl 500013
120-$3-2 2, 4..Dchboropbemol 500013 84-46-2 Diethylphthalate 500013
120-82-1 1,2 ,4-Trichlorobnuefle 50001 7005-72-3 4-Wuoropheay1-ghenwlether 508013
9 1-20-3 naphthalene 500013 86-73-7 Fluorene 940 J7
Data Reporting Qualifiers:
13 - Comouond wasn analyzed for but not detected. The number is the attainable detection limit for the sample.
a - Analyte was found in the reagent blank as well anthe sample.
J7 - Indicates an estimated value.
RD - not detected.
A - Aldol condensation product.
0 - Secondary dilution.
9 - Exceeds initial calibration rang.
D-213

-L~boratoey-
WIIC-SD-EN-TI-136, Rev. 0 2
DAnaIIs ID: 90122"-57 Custoer Sample to: 27-105 5 2
Organc DAmS SPOCtroscoM L"Mat*Y Customer. KZUSMSKISOOI
Mie, ID: 10935 Sampl Ntri,: SOIL
Instrumnt ID: 5970-3 Plequisition nmber:
AUtborised Dy: D. C. Canada Date Saple Received: 20-MC-1990
M - Sase/Yutral/Acid Compounds (TCL)
Date Zutracte4iltpZred: 3-311-1991 Date Analysed: 14-311-1991
Preparation Procedure Number: ZIPA-35SO Analysis Procedare numer: SM(C.LP NDV
Percent moisture: 7.5 Dilution Factor: 5.0
Percent Moisture (decanted): Analyst: C NNUE
Associated Blank: -910103-263
Re Isult bas bees Corrected for Spike
a3. Mie nmber: Rh
CAB ~uV19 g~ CB
100-01-6
534-S2-1
4-41itroanhline
4.6-Dtitr-2-methrlpbflol
2400OU
240001?
53-70-3
191-24-2
Dibenx(a,h)anthracene
Denxo(q,h. ± perylene
1900 j
SCOOP
06-36-6 N-itroedipbelaaine SOOP
101-35-3 4-9co~, -gh -pb9emyletber
SOO
114-74-1 Noxacblorob.sene SOGOU
87-46-5 Pentachlorophenol 2400OU
85-01-4 Pbemanthcene 9400
120-12-7 Anthracene 2300 3
84-74-2 Di-a-butylphtbalate 3000 is
20"-4-0 Fluoranthene
18000
129-00-0 Pyrem 18000
45-68-7 Dtylbsylpthalste 5000U
91-94-1 3,3 '-Dichlorobenuidine 100001.
54W53 Benno aWanthracsne 12000
117-41-7 bin 2-thylbesyl )pbtbalat* SCOOP
21"-1-9 Carysene 15000
117-44-0 Di-e-octylphthalate SCOP
205-99-2 Deno~bfluoranthene 12000
207-0"- Sensolkflucranthen*
4400 3
50-32-8 Sesuolapyrane 10000
193-39-S Indefo 4. 2,3-cd)pyrrele 1200 1
nota Reporting Qualifiers:
U - Compound was analysed for but not detected. Tbe -1er is the attainable detection limit for the sample.
9 - Analyte was found in the rengent blank as well as the sample.
J - Indicates an estimated value.
ND - not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - Zxceeds initial calibration range.
D-214

WHC-SD-EN-TI-136, Rev. 0
ak aid"e 5-25 sit* 54
Analytical Chemistry Departmenit
BM~ ITCL) SOIL OUM~CS AI.1SIS DAMASZ?
TUNAIVLIVOWIFI
AnaLjS ID: 90122"-57
customer sample ID! 27-105
Laboratory: organic pass spectroscopy Laboratory Customr: ! SERR
Sample, Matrix: SOIL
Mie ID: 10935
Level: (lw/and): L0W
Date Receivd: 20-DC-190
Dilution Factor: 5.0 Date Analysed: 14-3MI-1991
% rbisture: not dec. 7.5 doe. Date Nxtracted: 3-JAN-IS"I
Sittraction: (SepF/Cont/sonc) SOREKM
Womer TICs found: 21
COon etration Units
lolA. or ug/4); uji
I h MSUSS IM0 W.3MW I 2 U T. CMC. 0
I1. I CTUW,22,E-TXRIPUIIIY- 8.23 I 73000 1 3
I .
I3.
926-73-41 1. 2. 3-ftuthIwbemaene,
I3~In -gZETL-,TM
6.43 1
0.59 1
74000 1 J
27000 13 J I-
I4.
I . -
I i ATURATCD HYMMOMM
UMM SAT W ~DRVC1NMN
1 8.62 1
9.611
26000 1 3J
61000 1 I
I . tWW UARMIC HYDROU 10.041 140000 1 J
I7. - WO= 10.161 70000 1
I .
I9.
10Ul
Ill.
IUNUSATAM Z
9I -01nE!L
I ~ARMOC
DRXOM
YinCMM~
I
10.33 1
10.471
10.611
10.921
320001 J
52000 1J
13000 1
10000 1
Iy
I
112. tlinU SATURAMM NE!FCA306 11.231 290001 I
113. Iw 11.51 1 Soo0I13
l14. _ I 11.19 1 17000 1 1
isI._____ IWMUA IC ETM U I 11.80 1 27000 13 J
14. j~n ASX*IC HYDR S I 11.90 1 14000 13 I
117. AIM IrWU 12.00 1 1300013 J
1s. j inin EmD1IYL-UTEL'1N 1 12.11 1"00 1 3Y I
I19. MWU AJT~IC NYMODW I 13.09 I7900 1 1
20. Il- ID2,3-DIU V-0IUYL I 13.37 I 10000 1 3?
121. HUMW 14.391 1400013J
122.
I
123. I I
124.III
I
I26.I
127.
126.
129.
130.I
Dat& Reporting Qualifiers:
u - compound wa analyzed for but not detected. The nmer is the attainable detection limit for the sample.
a - Analyte was founid in the reagent blank as wall as the sample.
3 - Indicates an estimated value.
ND - Not detected.
A - Aldol condensation product.
D - Secondary dilution.
E - EZceed initial calibration range.
P - probable Identification.
D-215
II
I
I
I
I

WHC-SD-EN-TI-136, Rev. 0, pag I f
AnLW1c "26-57Cutoe sample in: 27-105 5 5
- Lboratory: O,~suic ""a Spectroscopy Laboratory Customer: KZSSMIW.3OO
File ID: )07776 Saple matrix: SOIL
Inatrumaflt ID: 70-2 lequin ition Nmber:
Atborised By: o. C. Canada Date Sample Received: 20-DUC-1990
Vm- volatile Organic COMPoUDa (TC.)
Date Ixtracte4/ftepered: Data Analysed: 31-MS-1990
Preparation Procedure Nmer: Analysia Procedure Nmber: V0& (C1) OW
Penasat moistures Dilution Factor: 100.0
percent Moisture (doeanted): Analyst: IM Par=
Associated Blank: 901231-001 gh File Number:
tI : Basalt bas been corrected for Spike
74-47-3 cilerainethane
74-03-9 Bromo.ethane
7"-1-4 Vinyl lOdef
7S-00-3 Cilecoethane
7"-9-2 MAthyLsme Chloride
13000
13000
13000
13000
260 in
79-00-5
71-43-2
10041-02-4
75-25-2
106-10-1
1.1 ,2-'1'rchloroethafl
Beaene
trana-,3-ichlorpoPel
DrOMform
4-Ne6thyl-2-pentanonle
430V
6300
630U
6300
1300V
67-64-1
75-15-
75-3S-4
75-34-3
540-59-0
ACtoCAe
Carbon Diaulfida
1.1-Dikloroethene
1,1-ftehlor~ethae
l,2-ftcklorotam (total)
13000
6300
630U
6300
6300
591-76-6 2-Sexanone
127-1"- Tetrachloroethene
79-34-5 1.1,2, 2-'1strachloroothane
10"$1-3 Toluene
10"-7 chLorobens-n
1000
6300
6300
6300
6300
67-6-3 Chloroform
107-06-2 1.2-Dicklocoethane
78-93-3 2-Satame
6300
6300
13000
100-41-4 Sthylbenen
100-.4 2-5 Styrene
1330-20-7 xyleme (total)
6300
6300
17000
71-55-4 l.1.1-Trichler-thane 6300
5423-5 Carbm Tetrac.Loride 6300
10"-0-4 vinyl Acetate
1300V
75-27-4 sromndichLorrnethans, 6300
76-41-5 1. 2-OidiloropceranO, 6300
10061-01-5 cia-l .3-Dichloropropene 6300
79-01-6 Trichloroethasse 630U
124-48-1 Dibrornchloromethan 630
Date R~peoig Qualifiers:
Y0 - compound W" analysed for hut not detected. The nmber is the attainable detection limit for the saPle.
a - MAUcit. wag fouind in the reagent blank as -e1l a the sample.
i - Indicates an estiMated value.
go - not detected.
A - Aldol condensation product.
a - secondary dilution.
Z - Exceede initial calibration range.
D-216

WHC-SD-EN-TI-136, Rev. 0
Oak Rid"e -25 Sits,5
Analytical chemistry Department
VO (TO.) SOIL OBMCS ANALYSIS OMA NST
TWD.TIYELY XDCiIF=U COMOUNS
Ane&= ID* "0122"-57
Customer Sample, ID: 27-105
Laboratory: Organic Mass.SuectroacOwY LdattOrY Customer: CHR/4
Sample Hatrix: SOIL File ID: 07773
Level: flow/bed): LOW
onto Received: 20-CSC-19
Dilution Factor: 100.0 cats Analyzed: 31-CUC-1990
% Moisture: not dec.
Concentration Units
Wimer TICs found: .6
(Uu/L or UoVl4i: Us
1 . I2,4-DIETMh~B 13.14 1 1200 1 J
I2. l2,34 TICTL r 13.75 1 3500 131
I3. L3.4TNTL =PrAnZ 14.57 1 960 1
I4. Ii NTF 2S1 17.57 1 140013J
I5. M , rOCRW21.31 1 12000 13
G . UNNO 16.55 1 36000 1 3
110. ____jI
112._____
113. ____ II
114._____jI
117. J I1
Iis.
I
119. I
120. .
121. 1
122.
123. ____
124. ____
I25._____
I
1
I
I
I
I
I
126. ____1 I
127. _ _ _
128. ___ _ 1 I
129. 1
130. 1
Data Reporting Qualifiers:
Vi - Compound wans analysed toe but not detected. The nusber is the attainable detection limit for the saMPle.
8 - Analyte was found in the reagent blank as well as the sample.
3 - Indicates an estimated value.
No - not detected.
A - AMdol condensation product.
D - Secondary dilution.
9 - Exceeds initial calibration range.
P - Probable Identification.
D-217
I
I
5

WHC-SD-EN-TI-136, Rev. 0
Oak Ridte K-25 Site
Analytical OA01mistgy Doprtlei
Results of Analyses
Ama~S x0: 901226-058 project: 0132 0278 customer Sample ID: 27-1"4
Customer: XZSUXC/RWS Requisition 1-1 r:
Dae sampled: IS-CC-1990 Dae Semple Received: 20-CEC-1990
Sampled By: Dae Sample Copleted: 27-JAZ-1S9i
Material DecriptiOut SOIL II:Result has been corrected fee Spike
aA Dts
ACtiV.
muer Procedure mo. Analysis Result units Analyst rile nmber Completed
102003 CPA-3050 Lad 4.2 Ug/g P B3SIOXT 10123U 27-JAN4-1991
IWA-7421
132603 CPA-3550 Prop (- 53.446-So: I C in XDEIS 1393 4-JAII-1291
Prep tatm- 518-44-Sn)
Analyst
a in JamS
Dae extracted 0 3-JMI-1991
Saple Weight extracted (9) - 10-*90
percent Solids - 91.5
Calculated Dried wight 1q) a 9.97
extraction Method
0 Sos9hlet
extraction solvent
a Nthlylene Cloride/Acetone
extraction Cleanup
a Sodium Sulfate
Final Volume of extract (EL) a I
Associated Blanik
a 910103-263
D-218
Program Manager: 0. L. Abrgey
oat* Approved: 7-flS-1991
5

WHC-SD-EN-TI-136, Rev. 0 pag Io 25
ANUMSIS .a REW
#a&LlS in: "01226-058 Customer Sample ID: 27-106
- wbratory organic Mass Spectroscopy Laboratory Custoer- X9313.R/1=
File ID: )10934 Sample matrix: SOIL
instrument ID: 5970-3 Requisition nmber:
Authorized BY: D. C. Canada Date Semple Received: 20-MU-1990
M- sase/woutral/Acid Compounds (TCL)
Data Utractoprepated: 3-JMi-1991 Date Analysed: 14-3516-1991
prearationt proaedare imbr: ZUA-3550 Analysis procedure number: URi I C*) XDP
Permat moisture: 0.5 Dilution Factor: 1.0
percent Imisture (decanted):3 Analyst: C MM3111
Anseciated Blank: 910103-243 ah File vimbet: sh
Re Usult haa been corrected for Spike
CAS uaVa9 Ch uVh19
10"-5-2 Pamo 98011 10"-7-6 4-dilorosailiue 9801U
111-44-4 bis42-ChlGOrsthyl ether 90011 97-48-3 neaaelorbutadiole 90011
9S-57-4 2-c1.ro-'em1 9801 59-W07 4-Chlore-3-sthYlPh-1 9W0U
541-73-1 1 .3-ftchlobeuefl 98011 91-57-4 2-Neehlnphthalen 90011
10"-6-7 1, 4-Oiehltorbeflnss 98011 77-47-4 nexachlococyclopentadieul. 90011
100-51-4 sapl Alcohol 90015 I0-042 2 *4 ,6-YricftlerePhen1 90011O
95-50-1 1 ,2-.Ocblorbesen 98011 95-95-4 2,4. 5-1richiOrophe0dl 490011
95-40-7 2-Othylpbeftol 90011 91-58-1) 2- W oranaPhthal One 90011
10"-0-1 bis I2-ChloriWW9O~l p ther 90011 88-74-4 2-Mitoeflifl 490011
10"-4-5 4-Nthylhesnol, 98011 131-11-3 Dimthylphth~lat* 9601
621-64-7 M-fitroso-di--ro~lMifl 90011 208-96-8 AcenaphthYl-n 98011
67-72-1 Eexachloro~than 90011 9-09-2 3-Kitroanilile 490011
90-4-3 Kitrbenane 90011 $3-32-9 A~enapbthene 90011
79-59-1 Isophorens 901 51-20-5 2 ,4-Dintit9OPheflbl 49001
90-75-5 2-41itrphemonl 98011 10"-2-7 4-ifitrophefol 490011
10-79 2.4-OasmthVlpbe-ll 98011 132.44-9 Dibensofuran 98011
65-- seaseic Acid 140 3 121-14-2 2,4-.DinittOt1u5BC 98011
111-91-1 bisa2-woretboxv)methane 90011 406-20-2 2 .6-DintotoUIl 901
120-03-2 2.*4-fchdlorogheOl 98011 $4-66-2 DiethylphthalatO 170 3O
120-82-1 1.2, 4-Trichiorobensen 90011 7005-72-3 4-CM0OhOReY1-,hbOYleth5" 901
91-20-3 Naphthalene 901 86-73-7 Fluorene 90011
Data Reporting Qulifiers:
U - Comounmd marnlysed for but not detected. The numer is the attainable detection limit for the sample.
3 - Anlyte wma found in the reagent blank as well as the Samnple.
i - indicates an estimated val-e.
ND - Hot detected.
A - Aldol condensation product.
D - secondary dilution.
E - EXcee4e initial calibration range.
D-219

WHC-SD-EN-TI-136, Rev.. 0
AMMZIS Wa iziOS Page 2 of 2 C
ManLIS to: 901226-05 custoer. Sample to: 27-106
-Ldastotyl Organic ma spectroscopyLaboratory Cstomr: flSO'RF06
file to: )10936 Sample Matrix: SOU.
Instrument 10: 5970-3 acquisition Nmber,
Authrized By: 0. C. Canada Date sample Received: 20-MC-1990
am - sase/Noutral/Acid Compounds (TCL)
Date Utwacte4'tpreods 3-353-1991 Date Analysed- 14-JAIS-199I
preparation procedure Nmer: CPAP-35SO Analysis procedure Hmbert SM (CLP) Hop
Percent Misture: 6.5 Dilution Factor: 1.0
percent Ibisture (decentedl: Analyst: C iUZON
ssociated Blank: 910103-263 h File amber:MA
(I:Rsult has been, corrected toe spike
Chs ug/K9 CAS U9/K9
100-01-6
534-52-1
4-01treaailine
4.6-bMitro-2-.etbylpbenol
49001U
490011
53-70-3
191-24-2
Dibeus a ,h~anthracene
Beso(,b~i)perylefl
96011
96011
66-30-6 U-itzeaodipbasyLamine 96011
101-55-3 4-&romphenl-pbenylether 96011
111-74-1 Noeaacklotobeasme 98011
67-9"- Pentachloro-eW
490011
85-01-4 Pbenanthrene 96011
120-12-7 Athzac~ 96011
84-74-2 Di-n-butylphtbalate 3700 3
206-44-0 Fluorauthane 96011
129-0-0 Pyrene, 96011
65-44-7 Butylbuylkthalte 96011
91-94-1 3,3 '-Oicblorobenxidine 200011
S6-5S-3 Boa a)anthrnenme 960V1
117-41-7 bia 2-Ithylbotcr ktbalatet 410 J8
216-01-9 czyein 96081
117-44-0 Di-n-ectylphbalat* 96011
20S-99-2 Senuo~bfluorantbine 96011
207-06-9 3.0501k fluorauthene 96011
50-32-4 Beao(Opyrme 98011
193-39-5 Indeol1,2, 3-cd~pyrene 96011
Data Reporting Qualifiers:
11 - Compound me analysed toe but not detected. The nmer is the attainable detection limit for the sample.
a - Analyte was found in the reagent blank as well an the sample.
.7 - xndicaes an estimted value.
nD - not detected.
A - Aldol condenaation product.
D - Secondary dilution.
9 - gxeeeA, initial calibration range.
D-220

WHC-SD-EN-TI-136, Rev. 0
Oak aid"s V-25 site
Analytical Chemistry Departmnt
am. ITCL) SOIL Oanamc Mw=XIS DM~ NI
MfaulS W.: 901226-058 Customer "eepo 10: 21-106
taberately: organic Mass Spectroscopy Laboratory Custmer: OM'20
"I*pl matrix: SOIL File zD: )10936
LwI l: (1.ed): LOW Date Received: 20-Dce-1990
Dilution Factor: 1.0 Date Mnalyseds 14-.3h1-1991
% Ibisture: not de. 8.5 dec. Date 2tracted: 3-JAN-1991
Rtraction: ISwp/Cont/sonc) Soan
GVe Clenu: (T9) N
PH:
concetration Units
Muner Tl~s found: 14
(ug4. or awjlKg): t laa
I1.*
I2.
123-42-31 2-Poetanono. 4-hydroxy-4-astIM
IL0UO
1
1
5.79 1
14.84 1
9700 1 3M
11001 3
I
13.
1 4.
1 U
IUINOUSAWSMDtfinCMOD 1
15.17 1
15.35 1
410 1
75011 is
I5 9HJ-rIA)RXZ,-Tn 1 16.311 610 1 I
=62M. 16.961 6901 is
I7. 17851-53-51 1,3-8asonedicarbexylic acid.b 1 21.17 1 730 1 in
S8. ItUIMM 21A411 1200 1
19. M MR- ISWAT WNM YDOX 21.54 1 5903 is
to0. Lung 22.83 1 603 is
I .
I12.
I13.
_ I iTJDMU.2,6,lO,15-TK1RtlUT
OI O s~rMWD frMMaMau
IOCTADCAM3,514-DISUTL-
1 23.61 1
25.48 1
26.36 I
1100
760
700
I 1 is
I 1 is
I 1 is
114. _ IU I 32.77 1 1200 13
117. _ II
120.
I21.
122.
123.II
124.I
125.
127.II
129.I
130.
Data Reporting Qualifiers:
U - Compound was analysed for but met detected. The number is the attainable detection limit for the sample.
11 - Analyte was found in the reaget blank as well as the sample.
3 - indicates an estimated value.
so - Not detected.
A - Aldo1 condesiation product.
0 - Secondary dilution.
Z - Exceeds initial calibration ranqe.
P - Probable Idmntification.
D-221
II
II
II
II
I
I
I
6

WHC-SD-EN-TI-136, Rev. 0
nalS tD: 90122"-59 Customer Sample to: 27-106
-Laboratory: organic Mass Spectroscopy Laboratory Cwtomm MSSiN/W908
rile to: )07779 Sample Ma1trix: SOXI.
Instrumenit to: 70-2
Requisitio Nmer:
Authorised, By: D. C. Caoada Data Sample £eCalVedt 20-DIC-1990
VO - Volatile Organic Caopouds (TCL)
Date Estracted/Frepared:
Preparation Procedure Numer:
perct misture:
Percent Patuture (decanted):
Asociated Blank: 9"1231-001
Date, Analybed:
Analysis Procedue imer:
Dilution factor:
Analyst:
Q& rile number:
31--DS-1990
UO (0.1) W
1.0
IM ar
M~
Re bsult baa been Corrected for Spike
ChM uujq CAN GSA
?ae O 1 63
74-47-3 CbLeonetbame
74-63-4 Bromomasthan
7S-01-4 vinyl Chloride
750-W3 Clroethane
71-09-2 riathylmme ailoride
67-44-1 Acetone
7S-15-0 Carbon Disulfide
75-35-4 1 ,-Dichloroetbeno
75-34-3 1,l-Oiloroethame
540-5"- 1,2-Dichloroethene (total)
67-46-3 Ckloeors
107-06-2 1 .2-ftcbloroethme
7"-3-3 2-10saftne
1311
1211
1211
1311
260 33
1311
6U
EU
6U
EU
6V
EU
1311
7"-0-5 1.1 *2-Tricheoothowl
71-43-2 3enaene
10061-02-4 trams-1,3-0ichlooprope
7S-25-2 Sromoform
106-10-1 4-Hathy1-2-pentalofe
591-7$-f 2-Nezamone
127-16-4 ?etrachloroethele
79-34-5 1.1,2 ,2-'fetrachloroothfle
10"6f-3 Toluene
10"-0-7 Chlorobnuene
100-41-4 uthylbnasene
100-42-S Styrene
1330-20-7 Xylone (total)
6v
6U
6V
6V
1313
1311
6U
6U
EU
EU
U11
60
EU
71-355-f 1.l.1-Trichloothale EU
5423-5 Carbon Tetrachloride EU
106-0-4 Vinyl Acetate
1311
75-27-4 Bromdichloranetbefle 6G1
76-87-3 1 ,2-Oiftloropropefle 6U
10061-01-5 cis-1,3-Dichloroprovefle 601
7n-01-4 Tricklrote EU
124-46-1 Dibromochloramethale EU
Data Reporting Qualifiers:
v - compound was analyzed for but not detected. The number is the attainable detection limit for the sample.
* - Amalyte was found in the reagent blank as well "s the sample.
j - Indicates an estiated value.
No - not detected.
A - Aldol conesation product.
D - Secondary dilution.
I - Exceeds initial calibration range.
D-222

WHC-SD-EN-TI-136 Rev. 0
ask lft. ,23 t-
YOA (=~) soIn aome NPLSIS DMT aur
Vw WIGULT ZDOlflU COKAW6D
MnaLlS ID: 901226-054
Customer Sample ID: 27-106
Laboratory- Orgmnic Mass SoctroScOV Laboratory Customer:MO N
Smple matrix: SOIL
rile 10: )07779
Lievel: (1.vjImed)s Law
Date Received: 20-DC-1990
Dilution Factor: 1.0 Date Analysed: 31-MS-1990
mis~ture: not dec.
Concentration Units
nmber TZes founids 4 tueJL or uVq4 ism
Choam Capo WO IT WT I a
I. tU IO 15.361 1200 1 I
I2. I~ U17.96 1 4700 1 J
I3. amU~U 16.22 1 64000 I3 I
I4. INOI 18.77 I 140000 1
I10.
113.II
114.
115.IIII
- II
117.III
119. I I
120.II
I22.
123.I
24.
25.
126.I
127.IIII
I
II
II
II
II
I
129.II
130.
Data Rep@rtinq Qualifiers:
VI Compound ws analysed for but not detected. The ner is the attainable detection limit fee the esuple.
U - alyte was f ound in the reaenet blank as well as the sample.
3-indicates an estimated value.
NO - Not detected.
A - Aldol condensation product.
o - Secondary dilution.
2 - Exceeds initial calibration range.
P - Probable Identification.
D-223
III
I
I
I

WHC-SD-EN-TI-136, Rev. 0
D-224

WHC-SD-EN-TI-136, Rev. 0
TANK 100-N-SS-28
Sample Dates July 16, 1991 and July 11, 1991
D-225

WHC-SD-EN-TI-136, Rev. 0
D-226

WHC-SD-EN-TI-136, Rev 0
____ANALYTICAL REPORT Form ARF-AL
____Page 1 of 2
DATA -Part I ofI
LUaKR
0 M AMENDED
Date 5________O ____1___3_
Agency Identification Number 4491 -051 -MD
Account No. lrlk
Westinghouse Hanford Company
2355 Stevens Drive
KSIN 114-23 345 Hill Street/300 Area
Richland, VA 99352 A O927.1fi
Attentions Briaiia Colley
TeepoX (S09) 177-7]n
Sampling Colection and Shtipamt
Analysis
Sampling Site 1flA-q-? Date of Collection Till 1 6-l 1921
Date Samples Received at Laboratory July 19. 1991
Method of AnalysisCA flus
Date(s) of Analysis idly 410 1991
Analyvical Results_______
*0022 R 2405 $OIL 0.20 ___
moa3 31 2606 SOIL 1.
300114 31 X 2607 BIL 10. ___
300516 21 2609 SOIL 35____
300316 as Z611 SOIL 0.0s5
ZOXX7 21 2412 SOIL 0.24 ___
0*53K7 *up zz 2613 SOIL 0.16 -___
-4a - I
3?50 as 2114 OL 3 ___
301 3 2415 OL 21---
tSao aou *At an last pas*. a. .. coasent an last Page.
NO P:::::::; not deated. C lamt not z.otwa LOU an4 Log.
A t .a caluta
IterieVSc:
960 West LeVoy D~rive /Salt Lalm City, Utah 84123-2547 / (801) 266-7700
A Sorenson Company
0-227

General got Coentz
WHC-SD-EN-TI-136, Rev 0
____ANALYTICAL REPORT Form ARF-C
DATA. .AMEDEDPage 2 of 2
The control spike had 63 % recovery.
Agency Identification Number 5SQ1-05l11 -enf
960 west IeVGY Drive Salt Lake City, Utah 84123-2547 /(801) 266-7700
A Sorenson Company
D-228

WHC-SD-EN-TI-136, Rev. 0
ANALYTICAL REPORT FOR SAMPLE No.E21
EPA METHOD 8240
TARGET ANALYTE RE SULTS
Field Sample ID BOOZN6 Sponsor WESTINGHOUSE HANFORD CO
File ID KM90E21.1 Date of Analysis 0726/91. Date Received 07/L19/912
DataChem SET ID .S91z.Q5...
RESULTS DETECTION LIMITS
74-87-3 chloromethane .... J...... 1.6*
74-83-9 bromomethane U...L... 1.5*
75-01-4 vinyl chloride .... JL..... 1.7*
75-00-3 chloroethane .... J...... 1.4*
75-09-2 methylene chloride ..L..... 1.6*
67-64-1 acetone .L...... 4.3*
75-15-0 carbon disulfide U...L..... 1.6*
75-69-4 trichlorofluoromethane U2..... 1.5*
75-35-4 1,1-dichloroethene .... J...... 1.2*
75-34-3 '1,1-dichioroethane U..~...... 2.1*
540-59-0 total 1,2-dichloroethene ...L.... 1.2*
76-66-3 chloroform ...L..... 1.8*
107-06-2 1,2-dichioroethane JL..... 2.4*
74-88-4 iodomethane ...... L....... 1.5*
107-02-8 acrolein .2...... 58.*
107-13-1 acrylonitrile U...J....... 43.*
78-93-3 2-butanone ....L..... 3.8*
71-55-6 1,1,1-trichloroethane .U...... 1.6*
56-23-5 carbon tetrachloride .... L...... 1.5*
108-05-4 vinyl acetate ..... J...... 3.5*
75-27-4 bromodichloromethane ....L..... 1.8*
78-87-5 1,2-dichioropropane U......L..... 2.0*
10061-02-5 cis-1,3-dichloropropene ...J...... 3.1*
79-01-6 dtrichioroethene U.....L..... 1.3*
71-43-2 benzene 2LU.... 1.6*
124-48-1 dibromochioromethane UL.. 1.4*
79-00-5 1,1,2-trichloroethane ....L..... 1.1*
10061-02-6 trans-1,3-dichloropropene U.....L...... 2.9*
110-75-8 2-chloroethylvinyl ether ...... L...... 3.3*
75-25-2 bromoform ....L..... 1.2*
74-95-3 dibromomethane U....~...... 2.5*
764-41-0 trans-i, 4-dichloro-2-butene U.....L.... 1.7*
108-10-1 4-methyl-2-pentanone ......U... 3.5*
96-18-4 1,2,3-trichioropropane U...J...... 2.3*
591-78-6 2-hexanone .... J...... 4.1*
79-34-5 1, 1,2,2-tetrachioroethane 2LU... 2.0*
127-18-4 tetrachloroethene UL..... 1.5*
97-63-2 ethyl methacrylate .J.... 1.9*
108-88-3 toluene U...J..... 1.5*
108-90-7 chlorobenzene ...... U....... 1.3*
100-41-4 ethylbenzene JLU.... 1.4*
100-42-5 styrene ...U...... 1.2*
1330-20-7 total xylene JL.... 1.0*
D-229
*current DataChem detection limit

Field Sample ID B0OZN6
WHC-SD-EN-TI-136, Rev. 0
ANLYTI CAL REPORT FOR SAMPLE No. EK2 61 ..
Page 2 of 2
NON-TARGET JUIALYTZ ESULTS
Additional Volatiles
Scan Results
Ca. QQCOPOUND Nume uaK Foonote
------ -- NO UNKNOWNS FOUND ------------- -- --
FOOTNOTES
B The analyte was found in the method blank. The reported
results have been adjusted for the quantity found in
the blank.
E The reported concentration is an estimate only. The response
factor was assumed to be 1.000 relative to an internal standard.
J Indicates an estimated concentration below the Method Detection
Limit.
K The isomer is unknown.
N Analytical standards were not analyzed for this compound.
U Not detected.
W The identification is tentative or closely related to the
compound.
D-230

WHC-SD-EN-TI-136, Rev. 0
ANALYTI CAL REPORT FOR SMPLE No .E21
EPA METHOD 8240
TARGET ANALYTE RESULTS
Field Sample ID BOOzN7 ,Sponsor WESTINGHOUSE HANFORD CO
File ID KM99K261 Date of Analysis 0727/1 Date Received 07/L19/9L1
DataChem SET ID S91Q0i13p
RESULTS DETECTION LIMITS
Cas, No COMPOUNDlucrK (u/LG
74-87-3 chloromethane .JU.... 3.2*
74-83-9 bromomethane ...... L...... 3.0*
75-01-4 vinyl chloride .U..... 3.4*
75-00-3 chloroethane U.~...... 2.8*
75-09-2 methylene chloride U.....I...... 3.2*
67-64-1 acetone .6.... 8.6*
75-15-0 carbon disulfide ..i...... 3.2*
75-69-4 trichiorofluoromethane ......I... 3.0*
75-35-4 l,l-dichloroethene JJ 2.4*
75-34-3 1,1-dichloroethane ..... U...... 4.2*
540-59-0 total 1,2-dichloroethene L.. 2.4*
76-66-3 chloroform ...UL.. 3.8*
107-06-2 1,2-dichloroethane .... L...... 4.8*
74-88-4 iodomethane ....J.. 3.**
107-02-8 acrolein U.L...~. 116.*
107-13-1 acrylonitrile ......UL..... 86.*
78-93-3 2-butanone .J.... 7.6*
71-55-6 1,1,1-trichloroethane U..~ 3.2*
56-23-5 carbon tetrachloride ..L... 3.0*
108-05-4 vinyl acetate ..J...... 7.0*
75-27-4 bromodichloromethane ....U..... 3.6*
78-87-5 l,2-dichloropropane .... L...... 4.0*
10061-02-5 cis-1, 3-dichloropropene .U 6.2*
79-01-6 'trichioroethene JL..... 2.6*
71-43-2 benzene U........ 3.2*
124-48-1 dibromochloromethane ...L..... 2.8*
79-00-5 1,1,2-trichloroethane ..... 2... 2.2*
10061-02-6 trans-1,3-dichloropropene U...L..... 5.8*
110-75-8 2-chloroethylvinyl ether U....I..... 6.6*
75-25-2 bromoform .... L...... 2.4*
74-95-3 dibromomethane U....L.... 5.0*
764-41-0 trans-l, 4-dichloro-2-butene U..~...... 3.4*
108-10-1 4-methyl-2-pentanone .... L...... 7.0*
96-18-4 1,2,3-trichloropropane ..J..... 4.6*
591-78-6 2-hexanone ....J..... 8.2*
79-34-5 1,1,2, 2-tetrachioroethane ...... IL..... 4.0*
127-18-4 tetrachloroethene ..... L.... 3.0*
97-63-2 ethyl methacrylate U...L..... 3.8*
108-88-3 toluene U.....L.......
3.0*
108-90-7 chlorobenzene .... J...... 2.6*
100-41-4 ethylbenzene U..L.. 2.8*
100-42-5 styrene .... J...... 2.4*
1330-20-7 total xylene 1000,J...... 2.0*
D- 231
*current DataChem detection limit

Field Sample ID BOOZN7
WHC-SD-EN-TI-136, Rev. 0
ANALYTICAL REPORT rOR SMPLE No. E21
Page 2 of 2
NON-TARGET ANALYTE RESULTS
Additional Volatiles
Scan Results
Cas.NoCOPON Nmbe u/Gff ZFotote
_______C8 hydrocarbon 466L 110,.... EN1L
trimethyihexane i-somer 480.. 370J.... ENWkK
_______C9 hydrocarbon 4832.. 200Q.a... ENWk
_______C9 hydrocarbon 495 400QL.. EkL.
________C9 cvclic hydrocarbon 497L. 400.QJ... ENL
unknown unsat. hydrocarbon ~ JU 440, EW
_________unknown cyclic hydrocarbon 521,. 380,.I... £E...
_______C9 hydrocarbon .549.. 170,. EkLW
_______C9 hydrocarbon 557L 830,~. EW
unknown branched alkane .566. 280 EWN
FOOTNOTES
B The analyte was found in the method blank. The reported
results have been adjusted for the quantity found in
the blank.
E The reported concentration is an estimate only. The response
factor was assumed to be 1.000 relative to an internal standard.
J Indicates an estimated concentration below the Method Detection
Limit.
K The isomer is unknown.
N Analytical standards were not analyzed for this compound.
U Not detected.
W The identification is tentative or closely related to the
compound.
D-232

WIIC-SD-EN-TI-136, Rev. 0
ANALYTicAL RzPORT FrOR SAMPIZ No.E21
zPAL wmETO 8240
TARGET ANALYTE RESULTS
Field Sample ID B00-ZPO Sponsor WESTINGHOUSE HANFORD CO
File ID KM89EK2614j Date of Analysis 07126/91 Date Received 07/L19/91.
DataChem SET ID S9-51D
RESULTS DETECTION LIMITS
74-87-3 chloromethane ..... L..... 1.6*
74-83-9 bromomethane ......U....... 1.5*
75-01-4 vinyl chloride ...JU.... 1.7*
75-00-3 chloroethane ..... L..... 1.4*
75-09-2 methylene chloride ...2...... 1.6*
67-64-1 acetone U...J...... 4.3*
75-15-0 carbon disulfide .i.... 1.6*
75-69-4 trichlorofluoromethane ...... 1.5*
75-35-4 1,1-dichloroethene L... 1.2*
75-34-3 1,1-dichloroethane ...L...... 2.1*
540-59-0 total 1,2-dichloroethene ...L.... 1.2*
76-66-3 chloroform .JU..... 1.8*
107-06-2 1,2-dichloroethane ....L... 2.4*
74-88-4 iodomethane ...LL.. 1.5*
107-02-8 acrolein ....... L....... 58.*
107-13-1 acrylonitrile U.....~...... 43.*
78-93-3 2-butanone .U
71-55-6
3.8*
1,1,1-trichloroethane UL..... 1.6*
56-23-5 carbon tetrachloride U.L... 1.5'
108-05-4 vinyl acetate .. L...... 3.5*
75-27-4 bromodichioromethane .. U... 1.8*
78-87-5 1,2-dichioropropane ..... SU..... 2.0*
10061-02-5 cis-1,3-dichloropropene U.. 3.1*
79-01-6 It trichloroethene U 1.3*
71-43-2 benzene jU 1.6*
124-48-1 dibromochloromethane U. 1.4*
79-00-5 l,1,2-trichloroethane U.J.... 1.1*
10061-02-6 trans-1,3-dichloropropene .J...... 2.9*
110-75-8 2-chloroethylvinyl ether U.L..... 3.3*
75-25-2 bromoform. U....L...... 1.2*
74-95-3 dibromomethane ....... LL......
764-41-0
2.5*
trans-i, 4-dichloro-2-butene 2L. 1.7*
108-10-1 4-methyl-2-pentanone ....JL.. 3.5*
96-18-4 1, 2 ,3-trichloropropane U....L...... 2.3*
591-78-6 2-hexanone U.....I... 4.1*
79-34-5 l,l, 2 ,2-tetrachloroethane U.J...... 2.0*
127-18-4 tetrachloroethene .. 1.5*
10-8-3 ethyl methacrylate U 1.9*
10-83toluene U.1..... 1.5*
108-90-7 chlorobenzene U 1.3*
100-42-5 ethylbenzene 2LU.... 1.4*
10-25styrene ...L..... 1.2*
1330-20-7 total xylene ....JL... 1.0'
D-233
*current DataChem detection limit

Field Sample ID BOZPO
WHC-SD-EN-TI-136, Rev. 0
ANALYTICAL REPORT FOR SAMPLE No. E21
Page 2 of 2
NON-T1RGZT ANALYTZ RESULTS
Additional Volatiles
Scan Results
Cas No COMPOUNDNmbe ugLKG Foonote
----- NO UNKNOWNS FOUND---------------- ----
FOOTNOTES
B The analyte was found in the method blank. The reported
results have been adjusted for the quantity found in
the blank.
E The reported concentration is an estimate only. The response
factor was assumed to be 1.000 relative to an internal standard.
J Indicates an estimated concentration below the Method Detection
Limit.
K The isomer is unknown.
N Analytical standards were not analyzed for this compound.
U Not detected.
W The identification is tentative or closely related to the
compound.
D-234

WHC-SD-EN-TI-136, Rev. 0
ANALYTICAL RZORT FOR SAMPLE No .E21
EPA HETHOD 8240
TARGET ANALYTE RESULTS
Field Sample ID BOOZP1 Sponsor WESTINGHOUSE HANFORD CO
File ID K1E261Z5J Date of Analysis 0727/91l Date Received 07/J.2199
DataChem SET ID S.jQ-JI.3QQ
RESULTS DETECTION LIMITS
74-87-3 chioromethane JLU.... 4000.*
74-83-9 bromomethane ... L.. 3800.*
75-01-4 vinyl chloride ..... I...... 4300.*
75-00-3 chioroethane U..i...... 3500.*
75-09-2 methylene chloride U~ 4000.*
67-64-1 acetone 42000,~... 11000.*
75-15-0 carbon disulfide U...~... 4000.*
75-69-4 trichiorofluoromethane ..... L...... 3800.*
75-35-4 1,1-dichloroethene U.L...... 3000.*
540-59-0 total 1,2-dichloroethene
76-66-3 chloroform
107-06-2 1,2-dichloroethane
74-88-4 iodomethane
107-02-8 acrolein
107-13-1 acrylonitrile
78-93-3 2-butanone
71-55-6 1,1,1-trichioroethane
56-23-5 carbon tetrachloride
108-05-4 vinyl acetate
75-27-4 bromodichloromethane
78-87-5 1,2-dichloropropane
10061-02-5 cis-l,3-dichloropropene
79-01-6 ~ ,trichioroethene
71-43-2 benzene
124-48-1 dibromochloromethane
79-00-5 1,1,2-trichioroethane
10061-02-6 trans-1,3-dichloropropene
110-75-8 2-chloroethylvinyl ether
75-25-2 bromoform
74-95-3 dibromomethane
764-41-0 trans-l, 4-dichloro-2-butene
108-10-1 4-methyl-2-pentanone
96-18-4 1,2,3-trichloropropane
U...JL..... 3000.*
U......L..... 4500.*
..L..... 6000.*
.L. 3800.*
2LU..... 150000.*
.... S...... ll0000.*
B 9500.*
......UL..... 4000.*
L...... 3800.*
U.~...... 8800.*
U....~...... 4500.*
.U... 5000.*
..... I...... 7800.*
U.L..... 3300.*
20000......... 4000.*
U....L..... 3500.*
U 2800.*
...J...... 7300.*
U 8300.*
IL... 3000.*
...U...... 6300.*
.......... 4300.*
..... L...... 8800.*
.J... 5800.*
591-78-6
79-34-5
127-18-4
2-hexanone
1,1,2,2-tetrachioroethane
tetrachioroethene
L..... 10000.*
.U... 5000.*
U......L..... 3800.*
97-63-2 ethyl methacrylate 1. 4800.*
108-88-3 toluene 350000... 3800.*
108-90-7 chlorobenzene ...L...... 3300.*
100-41-4 ethylbenzene 100000Q...L.. 3500.*
100-42-5 styrene UL...-. 3000.*
1330-20-7 total xylene 1300000-.Q. 2500.*
D -235
*current DataChem detection limit

Field Sample ID BOOZPl
WHC-SD-EN-TI-136, Rev. 0
ANLYTI CAL RZORT FOR SAHWLZ No. E21
Page 2 of 2
NON-TARGZT ANALYTZ RZSULTS
Additional Volatiles
Scan Results
Cas. NoCOMPOUD Numbr ug/K Foonote
56-5- 2.3 dimethylpentane 35 1,7E5 EN...
______C7 hydrocarbon 378L 1,E ENWL
________unknown branched alkane 3992L 4,7E5 ENL
_______C8 hydrocarbon A2.L. IAfE5 EkI±.
_______C8 hydrocarbon 440.. 7,6E4 £EL
________mixed soectra: C8 hydrocarbon &
_______C3 subst. benzene 450Q jEj
______ethylmethylbenzene isomer A5.L,. 1-Q.5 EW
______C8 hydrocarbon 465. 1,E EWN1
______C8 hydrocarbon 474. 2,E EWN~
______C8 hydrocarbon 497.. 1,E ELIL
______unknown bicyclo unsat, hydrocarbon_ 5LD 5-4.E4. E
______C9 hydrocarbon .5.iL 1,E EkL
_______C9 hydrocarbon 567.. L.&ES £E..
FOOTNOTES
B The analyte was found in the method blank. The reported
results have been adjusted for the quantity found in
the blank.
E The reported concentration is an estimate only. The response
factor was assumed to be 1.000 relative to an internal standard.
J Indicates an estimated concentration below the Method Detection
Limit.
K The isomer is unknown.
N Analytical standards were not analyzed for this compound.
U Not detected.
W The identification is tentative or closely related to the
compound.
D-236

WHC-SD-EN-TI-136, Rev. 0
ANALYTICIAL REPORT FOR SA14PLZ No.E20
EPA NUTEOD 8240
TARGET ANALYTE RESULTS
Field Sample ID BOOzP2 Sponsor WESTINGHOUSE HANFORD CQO
File ID KN0K20 Date of Analysis 0727/9L1 Date Received 07/~i19
DataChem SET ID Sj.Q.0J1flQ
RESULTS DETECTION LIMITS
74-87-3 chloromethane .L.. 4000.*
74-83-9 bromomethane .... L...... 3800.'
75-01-4 vinyl chloride U.....L..... 4300.'
75-00-3 chloroethane U..~.... 3500.'
75-09-2 methylene chloride ..... L...... 4000.'
67-64-1 acetone .J....... 11000.'
75-15-0 carbon disulfide .. I..... 4000.'
75-69-4 trichlorofluoromethane U~...... 3800.'
75-34-3 1,1-dichioroethane .. 2...... 5300.'
540-59-0 total 1,2-dichioroethene 2L..... 3000.*
76-66-3 chloroform U.L..... 4500.'
107-06-2 1,2-dichioroethane ...J...... 6000.*
74-88-4 iodomethane U 3800
107-02-8 acrolein ....... L....... 150QOOL'
107-13-1 acrylonitrile .... U...... 110000Y.*
78-93-3 2-butanone B. 9500.'
71-55-6 1,1,1-trichloroethane U...J...... 4000.~
56-23-5 carbon tetrachloride ......UL..... 3800.'
108-05-4 vinyl acetate ..... JL... 8800.':
75-27-4 bromodichloromethane UL.... 4500. *
78-87-5 1,2-dichloropropane ...... L...... 5000.',
10061-02-5 cis-1,3-dichloropropene .. J... 7800.'
79-01-6 d trichloroethene U..L...... 3300.'
71-43-2 benzene 180 4000.'
124-48-1 dibromochloromethane 2L..... 3500.'
79-00-5 1,1,2-trichloroethane JL..... 2800.'
10061-02-6 trans-1,3-dichloropropene ..L...... 7300. *
110-75-8 2-chloroethylvinyl ether .... I...... 8300.*
75-25-2 bromoform ...JU..... 3000.' -
74-95-3 dibromomethane L..... 6300).'
764-41-0 trans-i, 4-dichloro-2-butene L.. 4300.'
108-10-1 4-methyl-2-pentanone JL...... 8800.'
96-18-4 1,2,3-trichloropropane U2..... 5800.'
591-78-6 2-hexanone ..... i...... 10000.*
127-18-4 tetrachloroethene 2L..... 3800.'
97-63-2 ethyl methacrylate ..... i...... 4800.'
108-88-3 toluene 43000Q....... 3800.'
108-90-7 chlorobenzene .. L... 3300.'
100-41-4 ethylbenzene 11000...... 3500.'
100-42-5 styrene U.....L...... 3000.'
1330-20-7 total xylene ~540000.Q.L.. 2500.'
0-237
*current DataChem detection limit

Field Sample ID BOOZP2
WfIC-SD-EN-TI-136, Rev. 0
ANALYTICAL REPORT FOR SAMPLE No. E2605.....
Page 2 of 2
NON-TARGET A21ALYTZ. RESULTS
Additional Volatiles
Scan Results
Ca, No OPUDNme ugG Foonte
________CS cycl~ic hydrocarbon 22,7_ 2,1hE4 EkLH.
_______C6 cyclic hydrocarbon 244. 2,QE4 £kLWL
110-54-3 hex ane 322z~ 2,E EWN~
_______C7 hydrocarbon JU 6,0QE4 EWN~L
________unknown branched alkane 401.. 1,7E5 EWNL
______C8 hvdrcarbon 430 3,E EWN
_______C8 hydrocarbon 467.. 6,3E4 EW.
______C8 hydrocarbon A22-. 5,E EW
FOOTNOTES
B The analyte was found in the method blank. The reported
results have been adjusted for the quantity found in
the blank.
E The reported concentration is an estimate only. The response
factor was assumed to be 1.000 relative to an internal standard.
J Indicates an estimated concentration below the Method Detection
Limit.
K The isomer is unknown.
N Analytical standards were not analyzed for this compound.
U Not detected.
W The identification is tentative or closely related to the
compound.
D-238

WHC-SD-EN-TI-1 36 , Rev. 0.'
AHALYTZ CAL EPORT TOR SAMPLE No.K20
EPA MUTHOD 8240
TARGET ANALYTE RESULTS
Field Sample ID BOOZP3 Sponsor WESTINGHOUSE HANFORD CO
File ID KN3E2606 Date of Analysis 07/227/1.. Date Received 07/i19
DataChem SET ID S9-51D
RESULTS DETECTION LIMITS
74-87-3 chioromethane ... JU..... 4000.*
74-83-9 bromomethane U....L..... 3800.*
75-01-4 vinyl chloride UL..... 4300.*
75-00-3 chloroethane L.. 3500.*
75-09-2 methylene chloride .1... 4000.*
67-64-1 acetone U....J...... ll0O0.*
75-15-0 carbon disulfide UL...... 4000.*
75-69-4 trichlorofluoromethane U~..... 3800.*
75-35-4 1,1-dichioroethene 2L. 3000.*
75-34-3 1,1-dichioroethane .U 5300.*
540-59-0 total 1,2-dichioroethene U 3QQQ.*
76-66-3 chloroform U 45QQ.*
107-06-2 1,2-dichioroethane JL...... 6000.*
74-88-4 iodomethane UL..... 3800.*
107-02-8 acrolein U.L...... 150000.*
107-13-1 acrylonitrile UL...... 110000.*
78-93-3 2-butanone 81000Q,.... 9500.*
71-55-6 1,1,1-trichioroethane ....... L...... 4000.*
56-23-5 carbon tetrachloride ....JL.. 3800.*
108-05-4 vinyl acetate .. 8800.*
75-27-4 bromodichioromethane 2L. 4500.*
78-87-5 1,2-dichloropropane .... L...... 5000.*
10061-02-5 cis-1,3-dichloropropene ...L..... 7800. *
79-01-6 'trichloroethene UL...... 3300.*
71-43-2 benzene 4500.,... 4000.*
124-48-1 dibromochioromethane U...L... 35Q.*
10061-02-6 trans-1,3-dichloropropene ...... I....... 730.*
110-75-8 2-chloroethylvinyl ether UL..... 8300.*
75-25-2 bromoform UL.... 3000.*
74-95-3 dibromomethane ....L.. 6300.*
764-41-0 trans-1,4-dichloro-2-butene U~...... 4300.*
108-10-1 4-methyl-2-pentanone 1L... 8800.*
96-18-4 1,2,3-trichioropropane 2......5800.*
591-78-6 2-hexanone JL.... 10000.*
79-34-5 1,1,2,2-tetrachioroethane U.L... 5000.*
127-18-4 tetrachioroethene U....L..... 3800.*
97-63-2 ethyl methacrylate L.. 4800.*
108-88-3 toluene 100000.D... 3800.*
108-90-7 chlorobenzene ...L..... 3300.*
100-41-4 ethylbenzene 320 0Q.~... 3500.*
100-42-5 styrene U~.. 3000.*
1330-20-7 total xylene 180000.1. 2500.*
D-239
*current DataChem detection limit

Field Sample ID BOOZP3
WHC-SD-EN-TI-136, Rev. 0
ANIALYTICAL REPORT FOR SA14PLE No. E20
Page 2 of 2
NON-TARGET AZIALYTE RESULTS
Additional Volaiiles
Scan Results
________C7 cyclic hydrocarbon 338L 8,6E4A EWN.
565-59- 2.3-dimethyltoentan 35 5,E EWkLN
_______C7 hydrocarbon 379L 8-6E £.WNi
______unknown branched alkane 400 2,E EWN
_______C9 oxv hydrocarbon 42 BLAA.4 £kLI
_______unknown branched alkane 466* 1, 5 5 EW
_______C8 hydrocarbon 475.. 1,0E5~ EW
________unknown 480.. 5,2E4. EWL
_______C8 hydrocarbon 498. 1,.5E5 £E1
________unknown branched alkane .57 1,6E5. £kWL
________unknown branched alkane 568. 2,7E~5. EW
FOOTNOTES
B The analyte was found in the method blank. The reported
results have been adjusted for the quantity found in
the blank.
E The reported concentration is an estimate only. The response
factor was assumed to be 1.000 relative to an internal standard.
J Indicates an estimated concentration below the Method Detection
Limit.
K The isomer is unknown.
N Analytical standards were not analyzed for this compound.
U Not detected.
W The identification is tentative or closely related to the
compound.
D-240

WHC-S-EN-TI-136, Rev. 0
ANAhLYTICAL REPORT TOR SANPIZ No.E20
EPA wwTEO 8240
TARGET ANALYTE RESULTS
Field Sample ID BOOZP4 Sponsor WESTINGHOUSE HANFORD CO
File ID KNISEK2607 Date of Analysis 0727/9-i1 Date Received 07/19/9122
DataChem SET ID S91-0513DD2Q
RESULTS DETECTION LIMITS
Cas. o OMPUN (ua/LG) (ug/LG
74-87-3 chloromethane U..L... 4000.*
74-83-9 bromomethane JL...... 3800.*
75-01-4 vinyl chloride ..... L...... 4300.*
75-00-3 chioroethane ......~......3500.*
75-09-2 methylene chloride ....J......4000.*
67-64-1 acetone ..2.....11000.*
75-15-0 carbon disulfide LL...... 4000.*
75-69-4 trichlorofluoromethane ..L...... 3800.*
75-35-4 1,1-dichloroethene JL......3000.*
75-34-3 1,1-dichloroethane .L......5300.*
540-59-0 total 1,2-dichloroethene ....L......3000.*
76-66-3 chloroform L..... 4500.*
107-06-2 1,2-dichioroethane .......L......6000.*
74-88-4 iodomethane U....L...... 3800.*
107-02-8 acrolein ..L.......150000.*
107-13-1 acrylonitrile U........... 110000.*
78-93-3 2-butanone .f........9500.*
71-55-6 1,1,1-trichloroethane .1L...4000.*
56-23-5 carbon tetrachloride U....L..... 3800.*
108-05-4 vinyl acetate ....L..... 8800.*
75-27-4 bromodichloromethane U.L... 4500.'
78-87-5 1,2-dichloropropane U~....... 5000.'
10061-02-5 cis-1,3-dichloropropene .L.... 7800.'
79-01-6 trichloroethene .2L... 3300'*
71-43-2 benzene Z2700.... 4000.'
124-48-1 dibromochloromethane J....... 3500.'
79-00-5 1,1,2-trichloroethane ....J..... 2800.'
10061-02-6 trans-1,3-dichloropropene jU 73QQ.*
110-75-8 2-chloroethylvinyl ether U.I..... 8300.'
75-25-2 bromoform, AL.. 3000.'
74-95-3 dibromomethane 2L...... 6300.*
764-41-0 trans-1,4-dichloro-2-butene ..... L..... 4300.'
108-10-1 4-methyl-2-pentanone U....~...... 8800.'
96-18-4 1,2,3-trichloropropane .... L..... 5800.'
591-78-6 2-hexanone 2L..... 10000.'
79-34-5 1,1,2,2-tetrachloroethane ..J.... 5000.*
127-18-4 tetrachloroethene 2L..... 3800.'
97-63-2 ethyl methacrylate ...... L.... 4800.'
108-88-3 toluene 94000..... 3800.'
108-90-7 chlorobenzene U.....I..... 3300.*
100-41-4 ethylbenzene 23 00,L.... 3500.'
100-42-5 styrene U..L-...- 3000.'
1330-20-7 total xylene 1600000--. 2500.'
D0-241
*current DataChem detection limit

WHC-SD-EN-TI-136, Rev. 0
ANALYTICAL REORT FOR SAMPLE No. E20
Page 2 of 2
NON-TARGZT AHALYTZ RZSULTS
Additional Volatiles
Field Sample iD gooZP **- -
-Scan Restilts
Cas NoCOMOUD Nmbe. u/k Foonote
_______C7 hydrocarbon 2a24,.. -~a.E EW..
________C8 hydrocarbon 3,5E5~A~.. E W1-
________unknown oxy hydrocarboin- 9, flE4~ £E1L
______C8 hydrocarbon 440Q 7,6E4 EW
_________mixed spectra: C8 hydrcarbon & __
______C3 subst benzne 45 ,E W
_______C8 hydrocarbon 1465.. L..5E.5 £kW
_______C8 hydrocarbon 474 1,35 EkiI
_______C8 hydrocarbon 497.. 1,.1E~5 EWN1
_______C9 hydrocarbon 548.. 6,8E4A EWL
______unknown branched alkane 5Li.. 2,E EW
______C9 hydrocarbon 567. 2,9E5. EW
FOOTNOTES
B The analyte was found in the method blank. The reported
results have been adjusted for the quantity found in
the blank.
E The reported concentration is an estimate only. The response
factor was assumed to be 1.000 relative to an internal standard.
J Indicates an estimated concentration below the Method Detection
Limit.
K The isomer is unknown.
N Analytical standards were not analyzed for this compound.
U Not detected.
W The identification is tentative or closely related to the
compound.
D-242

WHC-SD-EN-TI-136, Rev. 0
AlALyTI CAL RigpORT FrOR sANPIz No .E20
zPA wzTHOD 8240
TARGET ANALYTE RESULTS
Field Sample ID B00ZP5 Sponsor WESTINGHOUSE HANFORD CO
File ID KM88EK260 Date of Analysis 0726/9L1 Date Received 07/l19
DataChem SET ID S91-05 1 3D
RESULTS DETECTION LIMITS
74-87-3 chloromethane 2L..... 1.6*
74-83-9 bromomethane 2LU... 1.5*
75-01-4 vinyl chloride ...... I....... 1.7*
75-00-3 chloroethane ..... i...... 1.4*
75-09-2 methylene chloride ..2.... 1.6*
67-64-1 acetone 5. 4.3*
75-15-0 carbon disulfide ..2...... 1.6*
75-69-4 trichlorofluoromethane UL... 1.5*
75-35-4 ,1-dichloroethene U...L.. 1.2*
75-34-3 1,1-dichloroethane U....I.... 2.1*
540-59-0 total 1,2-dichloroethene U.~...... 1.2*
76-66-3 chloroform ....L... 1.8*
107-06-2 1,2-dichloroethane LL...... 2.4*
74-88-4 iodomethane U.J..... 1.5*
107-02-8 acrolein ......U....... 58.*
107-13-1 acrylonitrile ..L... 43.*
78-93-3 2-butanone U..~...... 3.8*
71-55-6 1,1,1-trichloroethane U. 1.6*
56-23-5 carbon tetrachloride .... L...... 1.5*
108-05-4 vinyl acetate U 3.5*
75-27-4 bromodichloromethane U....L... 1.8*
78-87-5 1,2-dichloropropane .1..... 2.0*
10061-02-5 cis-1,3-dichloropropene U...~... 3.1*
79-01-6 ,trichloroethene U...L..... 1.3*
71-43-2 benzene ....L.....1.6*
124-48-1 dibromochioromethane JL..... 1.4*
79-00-5 1,1,2-trichloroethane U...2..... 1.1*
10061-02-6 trans-1,3-dichloropropene U.~...... 2.9*
110-75-8 2-chioroethylvinyl ether LL... 3.3*
75-25-2 bromoform ..L..... 1.2*
74-95-3 dibromomethane U....L..... 2.5*
764-41-0 trans-l,4-dichloro-2-butene U.....~...... 1.7*
108-10-1 4-methyl-2-pentanone ....L..... 3.5*
96-18-4 1,2, 3-trichloropropane U....L..... 2.3*
591-78-6 2-hexanone .... J..... 4.1*
79-34-5 1,1,2,2-tetrachloroethane ......UL..... 2.0*
127-18-4 tetrachloroethene U..L... 1.5*
97-63-2 ethyl methacrylate U~..... 1.9*
108-88-3 toluene 11 1.5*
108-90-7 chlorobenzene U~...... 1.3*
100-41-4 ethylbenzene U2.... 1.4*
100-42-5 styrene ...L...... 1.2*
1330-20-7 total xylene .L... 1.0*
D-243
*current DataChem detection limit

Field Sample ID B OOZP5
WHC-SD-EN-TI-136, Rev. 0
ANALYTI CAL REPORT FOR SAMPLE No. EK60
Page 2 of 2
NON-TARGET ANALYTZ RESULTS
Additional Volatiles
Scan Results
Cas No OMPOUNDNu~mber ugLG Footnte
----------- NO UNKNOWNS FOUND --------------- -
FOOTNOTES___________________________
B Te ws aalye oun inthemetodblak. he epote
results ~ ~ dutdfr ~ ~ ~ h ~ haebe uniyfudi ~ ..- ~
th blank...
B The anaoyted wacondrain the meodibank l. The rerted
factor was assumed to be 1.000 relative to an internal standard.
J Indicates an estimated concentration below the Method Detection
Limit.
K The isomer is unknown.
N Analytical standards were not analyzed for this compound.
U Not detected.
W The identification is tentative or closely related to the
compound.
D-244

WHC-SD-EN-TI-136, Rev. 0
TANK 100-N-SS-28
Sample Date April 29, 1992
D-245

WHC-SD-EN-TI-136, Rev. 0
D-246

LABORATORY: THA/ARLI
WHC-S-EN-TI-136, Rev. 0
CASE NARRATIVE
CASE: 05-014 h
CONTRACT ID: WESTINGHOUSE HANFORD -COHANY
SDG RECEIPT DATE: MAY 4, 1992
0000C9
1.0 DESCRIPTION OF CASE: JJ
Three 50i1 samples were analyzed for Total Petroleum
Hydrocarbons and Purgeable Aromatics. Preliminary
results were provided by FAX within 10 days of VTSR.
This package represents the final results.
2.0 SAMPLE LIST:
WESTINGHOUSE ID L&_ MTI MTHkI
B06D35 A2-05-014-01 SOIL HC,THE
B06D36 A.2-05-014-02 SOIL HC,THE,THP,BX
B06D37 A.2-05-014-03 SOIL HC,THE,THP,BX
Method Codes: HC -EPA 4 18. 1, THE - EPA 8 015 EXTRACTABLE,
THP -EPA 8015M PURGEABLE,BX - EPA 8020 BTEX
3.*0 COMMENTS ON SAMPLE RECEIPT:
The samples were received intact and properly documented.
4.*0 COMMENTS ON ANALYSIS:
4.1 EPA 418.1 - TOTAL PETROLEUM BY IR:
All samples were extracted and analyzed within
method holding time.
All QC results were acceptable.
D-247

WHC-SD-EN-TI-136, Rev. 0
4.*2 EPA 8015M4 - EXTRACTABLE HYDROCARBON:
All samples were extracted and analyzed within
method holding time.
All QC results were acceptable.
Samples B06D36 and B06D37 contained a hydrocarbon
mixture that has the chromatographic pattern of a
combination of kerosene and diesel products. Each
section of the chromatogramn was quantitated against
the appropriate standard separately.
Because of overlapping of late eluting gasoline
compounds the MS and MSD were calculated by taking
the sum of the area counts of five individual
compounds and comparing this area to the sum of the
area counts of the same peaks from the continuing
calibration.
4.3 EPA 8015M4 - PURGEABLE HYDROCARBONS:
All samples were analyzed within method holding
time. All QC results were acceptable.
Due to the high concentration of Kerosene range
hydrocarbons in the samples, one gram was extracted
with 10 mL of Methanol and 50 uL of Methanol purged.
This resulted in a dilution factor of 1000:1. No
gasoline range compounds were found in the samples.
A Methanol Blank has been included in the package.
4.4 EPA 8020 - STEX:
All samples were analyzed within method holding
time.
All QC results were acceptable.
Due to the high concentration of background
hydrocarbons the samples were extracted with
Methanol (1:10) and 50 uL of Methanol purged. This
resulted in a dilution factor of 1000:1. Results of
a Methanol Blank have been included in the package.
All Toluene hits were confirmed by GCMS.
D-248

5.0 DATA PACKAGE COMENTS:
WC-SD-EN-TI-136, Rev. 0 000011
The Format of the data deliverable was designed to
meet or exceed the requirements of the Westinghouse
Hanford Company Statement of Work. The intent of
the package design is to provide sufficient data for
"stand alone" validation. While the format of the
package is "CLP like" Thermo Analytical Inc. makes
no claim that this package duplicates in part or in
total an EPA CLP data package.
I certify that this data package is in compliance with
the terms and conditions of the contract, both
technically and for completeness, for other -than the
conditions detailed above. Release of the data contained
in this hard copy data package has been authorized by
the Laboratory Manager or his designee, as verified by
the following signature."
Nicole Roth Dennis D. Wells
CLP Manager Technical Director
D-249

Received: I5/04/92
SAMPLE ID 506D36
mg/Kg
SAMPLE tD do6D36 buolicate
I mg/Kg
WHC-SD-EN-TI-136 , Rev. 0 000014
TWA Inc. REPORT Verk Order 8 A2-OS5414
itesults by Sample
SAMPLE 9 21Z FRACTIONS: F
Date & Time Collected 04129192
Category
SAMPLE N 9Z3 FRACTIONS: C --
Date & Time Collected 04129/92 Category
SAMPLE 10 ffaink 301110 SAMPLE 0 flZ FRACTIONS: 9
Date & Time Collected 04129102 CategoryI
SAMPLE ID 1106D37
I 1 -I
6
SAMPLE 0 11j FRACTIONS: EFF_
Date A Time Collected 04129192 Category
D-250
I-

Receivedt 615104192
WHC-SD-EN-TI-136, Rev. 0 000023
TUA Inc. REPORT Verk Order 8 AR2-OS-SIA4
ReauittU by temple
SAMPLE 1D moguls FRACTION Mli TEST CODE 815NS1 NME EPA 801511 EXTA. UlS
Dote & Time Collected 0119192 Category
MODIFIED 8015 -EXTRACTABLE FUEL NYDROCARIONS
Matrix: Sit.....
Date Analyzed: 05111192
Ditution factor: 1.0
Concentration Units: ...... LGK
Sample
Compound Result POL
Kerosene Range No 5
CIO - C16 Jet Fuel. Range NDl 5
C9 C22 Diesel Range ND 10
Hydraulic Range ND S
ND w Not detected at the specified limits
Form I
D-251

Received: OS/04.'92
WHC-SD-EN-TI-136, Rev. 0 00011S
TIA Inc. REPORT Work Order 0 AZ-SS-014
Results by Sample
SANPLE 1D 106136 FRACTION ji. TEST CODE IJJL.. NAME BTE! by EPA 3020 MV196)
Date A Time Collected 04129102
Category______
SYEX by EPA Method 5020
Matrix: $l........
Date Analyzed: S.1/2L....
Dlution factor: 1000.2flQ
Concentration Units:
Sample
CA$ No. Compound Result POL
71-43-2 Benzene No So0
108-88-3 Toluene 4,200 500
100-41-4 Ethylbonzene No 0
1330-20-7 Xytenes CTotal) NDo0
% Recovery Surrogate Compound
Bromofluorobenzene 101.J.J
NDO Not detected at the specified limits
Form I
D-252

Received: @5/04/92
WHC-SD-EN-TI-136, Rev. 0 000087
TRA Inc. REPORT Work order * A2-OS-814
Results by Sample
SAMPLE 1D 306816 FRACTION HLU TEST CODE 815l.L NAME Volatile Fue S-TPNU-
Date & lies Collected J~29107 Category
MODIFIED 8015 VOLATILE FUEL NYOROCARBONS
Matrix: Soft.......
Date Analyzed: 051112.
Dilution factor: 10.00.99
Concentration Units: ...... MKaLB
Sample
Compound Result POL
CS - C12 gasoline Range No 5000
No Not detected at the specified limits
Form I
D-253

WHC-SD-EN-TI-136, Rev. 0 000025
TMA Inc. REPORT Work Order * £2-SS-014
Received: 65/04/92 Results by Sample
SAMPLE ID 906036 FRACTION =~ TEST CODE &DISK NAME EPA G015K EXTRACT. (VWt95)
Data A Time, Collected 04.129101 Category
MODIFIED 8015 - EXTRACTABLE FUEL NYDROCARIONS
Matrix: s.oft.....
Date Analyzed: 05/L12/2
Dilution factor: 2.00.
Concentration Units: moK
Semple
Compound Result POL
Kerosene Range 297S 10
CIO - C16 Jet Fuel Range NO 10
C9 - C22 Diesel Range 435 20
Nydraulc Rangel No 10
No a Not detected at the specified Limits
Form I
D-254

WHC-SD-EN-TI-136, Rev. 0 000122
THA Inc. REPORT work Order 9 AZ-45-914
Received: 05/04/92 lecut. by Sample
SANPLE 10 206W3 FRACTION UL~ TEST CODE @TEX... VANE @TEX by EPA 3020 MV1961_
Date A, Time Collected 04129192 Category ______
STEX by EPA Method 8020
Date Analyzed: 5/8/2.......
Dilution factor: 1000......~fff
Concentration Unite: U01KO
$ample
CAS No. Compound Result POL
71-43-Z lenzane ND 500
108-88-3 Toluene 4,700 500
100-41-4 EthyLbenzoe ND 500
1330-20-7 1 ylenes_(Total) ND 0
Z Recovery Surrogate Compound
Iromofluorobenzene 10k...2
MO *Not detected at the specified limits
Form I
D-255

WHC-SD-EN-TI-136, Rev. 0 000090
TEA Inc. REPORT W*rk Order # AZ-GS-014
Received: 05/04/92 lesaltts by Sample
SAMPLE ID 1106037 FRACTION 111 TEST CODE $01510 NAME Volatlil Fuqts-TPU
Date & Time ColLected 04129/92 Category______
MODIFIED 8015 - VOLATILE FUEL HYDROCARBONS
Matrix: oitLL....
.Date Analyzed: 05/112a.
Dilution factor: 1000.00
Concentration Units: ua/Ken
Sample
Compound ReSult POL
CS - C12 asolin Range ND 5000
NO a Not detected at the specified Limits
Form I
D-256

Received: GS/S4192
WIIC-SD-EN-TI-l 36 9 Rev. 0 U 0 j
TEA Inc. REPORT vork order 0 AZ-IS-014
Results by Sample
SAMPLE 10 206037 FRACTION ULh TEST CODE 8015ft MANE LPA 805 XRCT. fVU1951
Date & Time Collected 01.129122
Category
MODIFIED 8015 ,EXTRACTABLE FUEL NYDROCARSONS
Natrix: SitL......
Date Analyzed: 051.Z29
Dilution factor: 2..00....L~l
Concentration Units: ..... zaA.
Sample
Compound Result POL
Kerosene Range 3085 i0
CjG - C16 Jet Fuet Range ND 10
C9 -C22 DiesetloRnge 100 20
Nydreulic Range ND 10
ND Not detected at the epecifted limits
.1
Form I
D-257

WHC-SD-EN-TI-136, Rev 0
D-258

WHC-SD-EN-TI-136, Rev. 0
100-N GAS STATION "LUST"
September 9, 1992
D-259

WHC-SD-EN-TI-136, Rev. 0
D-260

WHC-S-EN-TI-136, Rev7. 0
SOUND ANALYTICAL SERVICES, INC.
SPECILIZING IN UM4USIRIAL & TOXIC WASTE AALYSIS
4813 PACIFC HIGHWAY I!AST, TACO)JA WASWf;GT.* 0$44 -T P~tlr (2M9)22-2310. FAX p22.sw4
Report TO: Westinghouse Hanford Date: September 22, 1992
Report On: Analysis of Soils & Solids Lab No.: 27160
IDENTIFICATION:-Pae1o7
Samples received on 09-16-92
Project: 100 N Gas Station "LUST"
------------------------------------------------------------
ANALYSIS:
Lab No. 27160-1 Client ID: B076C4 (soil)
WTPH-G with ETEX by Method 8020
Date Extracted: 9-17-92
Date Analyzed: 9-15-92
Gasoline, mg/kg < 1.0
(C?.-CUZ)
Benzene, mg/kg

WHC-SD-EN-TI-136, ROV. 0
SOUND ANALYTICAL SERVICES, INC.
Westinghouse Hanford
Project; 100 N Gas Station "LUST"
Page 2 of 7
Lab No. 27160
September 22, 1992
Lab No. 27160-2 Client ID: B076C5 (soil)
WTPH-G with ETEX by Method 8020
Date Extracted: 9-17-92
Date Analyzed: 9-18-92
Gasoline, mg/kg -C 1.0
P CCa)
Benzene, mg/kg 4 0.05
Toluene, mg/kg < 0.05
Ethyl Benzene, mg/kg

WHC-SD-EN-TI-136, Rev. G
SOUND ANALYTICAL SERVICES, INC.
Westinghouse Hanford
Project: 100 N Gas Station "LUST"
Page 4 of 7
Lab No. 27160
September 22, 1992
Lab No. 27160-4 -Client IDs B076C6 (soil)
WTPH-G with BTEX by Method 8020
Date Extracted: 9-17-92
Date Analyzed: 9-18-92
Gasoline, mg/kg

WHC-S-EN-TI-13 6 , Rev. 0
SouND ANALYTicAL SERVICES, INC.
Westinghouse Hanford
Project: 100 N Gas Station "LUST"
Page 3 of 7
Lab No. 27160
September 22, 1992
Lab No. 27160-3 Client ID: B076C7 (solid)
WTPH-G with BTEX by Method 8020
Date Extracted: 9-17-92
Date Analyzed: 9-18-92
Gasoline, mg/kg < 1.0
Benzene, mg/kg < 0.05
Toluene, mg/kg 0.05
Ethyl Benzene, mg/kg < 0.05
Xylenes, mg/kg < 0.05
SUJRROGATE RECOVERY. %
Trifluorotoluene 68
WTPH-D
Date Extracted: 9-18-92
Date Analyzed: 9-21-92
Diesel, mg/kg < 25
(2- CM - C24)
SURROGATE RECOVERY.,
0-Terphenyl 66
WTPH-418.1 Modified
Date Extracted: 9-18-92
Date Analyzed: 9-21-92
Heavy petroleum oils, mg/kg < 100
(C24+)
ICP Metals Per Method 6010
Date Digested: 9-19-92
Date Analyzed: 9-18-92
Lead, mg/kg < 1.1
D-264
Continued . ....
Aslyadb hivd solely ftr thso at in peuca or compsy to whom K addmmnss h labmoM ampts repaob onij far no dv. potfwa of &*.Iin N=& seora wt

WHC-SD-EN-TI-136, Rev. 0
SOUND ANALYTICAL SERVICES, INC.
westinghouse Hanford
Projecti 100 N Gas Station "LUST"
page 5 of 7
Lab No. 27160
September 22, 1992
Lab No. 27160-5 Client ID: B076C8 (solid)
Gasoline, mg/kg
(C7.C1=)
WTPH-G with BT9X by Method 8020
Date Extracted: 9-17-92
Date Analyzed: 9-19-92

SOUND ANALYTICAL SERVICES, INC.
Westinghouse Hanford
project: 100 N Gas Station "LUST"
Page 6 of 7
Lab No. 27160
September 22, 1992
Lab No. 27160-6 Client IDi B076C9 (solid)
Gasoline, mg/kg
(Wcu)12
Benzenle, mg/kg
Toluene, mg/kg
Ethyl Benzene, mg/kg
Xylenes, mg/kg
SURROGATg RECOVERY.,
Trifluorotoluele
Diesel, mg/kg
(),C11 C4)
SURROGATE RECOVERX.
C -Terphenyl
WTPH-G with ETEX by Method 8020
Date Extracted: 9-17-92
Date Analyzed: 9-19-92

WHC-SD-EN-TI-136, Rev. 0
SOUND ANALYTICAL SERVICES, INC.
Westinghouse Hanford
Project: 100 N Gas station "LUST"
Page 7 of 7
Lab No. 27160
September 22, 1992
Lab No. 27160-7 Client ID: B076D0 (soil)
Gasoline, mg/kg
(CY . CU2)
Benzene, mg/kg
Toluene, mg/kg
Ethyl Benzene, mg/kg
Xylenes, mg/kg
SUREOGATE RECOVERY.
Trifluorotoluene
Diesel, mg/kg
(sW C24 )
SURROGATE RECOVERY.
0-Terphenyl
WTPH-G, with STEX by Method 8020
Date Extracted: 9-17-92
Data Analyzed: 9-19-92
< 1.0