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According to REACH Regulation (EC) No 1907/2006

According to REACH Regulation (EC) No 1907/2006

According to REACH Regulation (EC) No 1907/2006

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SAFETY DATA SHEET<strong>According</strong> <strong>to</strong> <strong>REACH</strong> <strong>Regulation</strong> (<strong>EC</strong>) <strong>No</strong> <strong>1907</strong>/<strong>2006</strong>1. Identification of the substance/preparation and of the company/undertaking• Trade Name:• Intended use of chemical• Manufacturer/SupplierTop Tablet (White)Cleaning AgentComplete Pool Controls LtdUnit 2, The ParkS<strong>to</strong>ke OrchardBishops CleeveGloucestershireGL52 7RSTel: +44 (0) 01242 662700 Fax: +44 (0) 01242 677978• Contact E-mail for advice E-mail: sales@cpc-chemicals.co.uk• Emergency Telephone Tel: +44 (0) 01242 662700 (office hours)2. Hazard IdentificationXn HarmfulN Dangerous for the environment• Hazard Information concerning particular hazards for humans and the environmentThe product has <strong>to</strong> be labelled according <strong>to</strong> the calculation procedure of the General Classification guideline forpreparations of the EU in the latest valid version.R22 Harmful if swallowedR31 Contact with acids liberates <strong>to</strong>xic gasesR36/37 Irritating <strong>to</strong> eyes and respira<strong>to</strong>ry systemR50/53 Very <strong>to</strong>xic <strong>to</strong> aquatic organisms, may cause long term adverse effects in the aquatic environmentWARNING Do not use <strong>to</strong>gether with other products. May release dangerous gases (chlorine)Use Biocides safely. Always read the label and product information before use.3. Composition/information on ingredients• Chemical characterization:Description Cas <strong>No</strong> <strong>EC</strong> <strong>No</strong>. Index <strong>No</strong>. Hazard %Trichloroisocyanuric acid 87-90-1 201-782-8 50 - 100 Xn; Xi; O; N 75 - 100%Copper Sulphate 7758-98-7 231-847-6 Xn; Xi; N 0.5 - 1%Boric Acid 10043-35-3 10043-35-3 0.5 - 1%4. First Aid measuresSymp<strong>to</strong>ms of poisoning may occur even after several hours; therefore medical observation for at least 48 hours after theaccident.Immediately remove any clothing soiled by the product. Show this safety data sheet <strong>to</strong> the doc<strong>to</strong>r• General Advice:in attendance. Remove from exposure, lie down.Move <strong>to</strong> fresh air. Allow patient <strong>to</strong> assume the most comfortable position and keep warm. Keep• After inhalation:at rest until fully recovered. Consult doc<strong>to</strong>r if symp<strong>to</strong>ms persist.• After skin contact:• After eye contact:• After Ingestion:Immediately wash with plenty of water. Remove contaminated clothing and wash before re-use.Seek medical advice. Launder clothes before re-use.Check for and remove any contact lenses. Rinse opened eye for at least 15 minutes underrunning water. Keep eye wide open while rinsing. Urgently seek medical attention.Rinse mouth thoroughly and have patient drink plenty of water. Call for a doc<strong>to</strong>r immediately.


Trade Name:Top Tablet (white)5. Fire fighting measures• Special extinguishing media:• Unsuitable extinguishing media:• Special Hazards:case of fire the following can be released• Special protective equipment:InCO2 powder or carbon dioxide.FoamNitrogen oxides (<strong>No</strong>x),Hydrogen Chloride (HCI)Wear positive pressure self contained breathing apparatus (SCBA).Wear fully protective suit.6. Accidental release Measures• Personal Protection~ Avoid formulation of dust~ Ensure adequate ventilation.~ Mount respira<strong>to</strong>ry protective device.~ Keep unprotected persons away.• Environmental Protection~ Keep contaminated washing water and dispose of appropriately.~ Do not allow <strong>to</strong> enter sewers/ surface or ground water.~ Inform respective authorities in case of seepage in<strong>to</strong> water course/system..• Methods for cleaning:~ Dispose of contaminated material as waste according <strong>to</strong> item 13.~ Ensure adequate ventilation7. Handling and s<strong>to</strong>rage• HandlingInformation for safe handling:~ S<strong>to</strong>re in a c ool dry place in tightly closed receptacles~ Provide suc tion extrac<strong>to</strong>rs if dust is formed~ Restrict the quantity s<strong>to</strong>red at the workplace~ Do not refill residue in<strong>to</strong> s<strong>to</strong>rage receptaclesInformation about fire and explosion protection:• S<strong>to</strong>rageRequirements <strong>to</strong> be met by s<strong>to</strong>rerooms:~ <strong>No</strong> special measures required~ S<strong>to</strong>re only in original receptaclesInformation about s<strong>to</strong>rage in common facility: ~ Do not s<strong>to</strong>re <strong>to</strong>gether with acidsFurther information~ Protect from humidity and water~ Keep container tightly sealed~ S<strong>to</strong>re in cool dry conditions in well sealed receptacles,8. Exposure control/personal protection• Additional information about design of technical facilities: <strong>No</strong> further data see item 7• Ingredients with limit values that require moni<strong>to</strong>ring in the workplace:The product does not contain any relevant quantities of materials with critical values that have <strong>to</strong> be moni<strong>to</strong>red in theworkplace.Personal Protective EquipmentSelect PPE appropriate for the operations taking place taking in<strong>to</strong> account the product properties:


Trade Name:Top Tablet ( white)8. Exposure control/personal protection (cont)General protective and hygienic measures~ Keep away from all foodstuffs, beverages and feed.~ Immediately remove all soiled and contaminated clothing.~ Wash hands before break and at the end of work.~ Avoid contact with eyes~ Avoid contact with skin and eyes.• Respira<strong>to</strong>ry ProtectionUse suitable respira<strong>to</strong>ry protective device when high concentrations are present.Short term filter device:~ Filter P2~ Filter P3In case of brief exposure or low pollution use respira<strong>to</strong>ry filter device. In case of intensive or longer exposure use selfcontained respira<strong>to</strong>ry protective device.• Hand ProtectionWear suitable chemical resistant glovesThe glove material has <strong>to</strong> be impermeable and resistant <strong>to</strong> the product.Selection of the glove material on consideration of the penetration times, rates of diffusion and thedegradation.Material of glovesThe selection of the suitable gloves does not only depend on the material but also on further marks and varies frommanufacturer <strong>to</strong> manufacturer. As the product is a preparation of several substances, resistance of the glove materialcannot be calculated in advance and has therefore <strong>to</strong> be checked prior <strong>to</strong> the application.Penetration time of glove materialThe exact breakthrough time has <strong>to</strong> be found by the manufacturer of the protective gloves and has <strong>to</strong> be observed.For permanent contact gloves made of the following materials are suitable:~ Nitrile rubber (NBR) ~ Fluorocarbon rubber (Vi<strong>to</strong>n)~ Butyl rubber (BR) ~ PVC Gloves• Eye Protection• Body ProtectionTightly sealed gogglesImpervious protective clothingBoots and gloves9. Physical and chemical properties• General InformationForm: TabletsColour: WhiteOdour: Like chlorine• Change in conditionMelting Point: UndeterminedBoiling Point: Undetermined• Flash Point• Self igniting• Danger of explosion• Density at 20°CN/AProduct is not self ignitingProduct does not present an explosion hazard<strong>No</strong>t determined• Solubility/Miscibility with in waterFully Miscible


Trade Name:Top Tablet (white)9. Physical and chemical properties (continued)• Solvent contentOrganic Solvents: 0.00%VOC (<strong>EC</strong>): 0.00%• Solids content 100%10. Stability and reactivity• Thermal decomposition:<strong>No</strong> decomposition if used according <strong>to</strong> specifications• Materials <strong>to</strong> avoid:Warning!Do not use with other products. May release dangerous gases (chlorine)• Dangerous reactions:~ Strong exothermic reaction with acids.~ Reacts with flammable substances~ Reacts with acids releasing chlorine~ Reacts with reducing agents• Dangerous decomposition products:~ Nitrogen oxides (<strong>No</strong>x),~ Hydrogen Chloride (HCI)11. Toxilogical Information• Acute ToxicityLD/LC50 values relevant for classification87-90-1 trichloroisocyanuric acidOral LD50 406 mg/kg (rat)7758-98-7 copper sulphateOral LD50 300 mg/kg (rat)• Primary Irritant effect:• On the skin: <strong>No</strong> irritant effect• On the skin: Irritating effect• Sensitization:<strong>No</strong> sensitizing effects known• Additional <strong>to</strong>xilogical information:The product shows the following dangers according <strong>to</strong> the calculation method of the General EU ClassificationGuidelines for Preparations as issued in the latest version:HarmfulIrritant12. Ecological Information• Eco<strong>to</strong>xical effects• RemarkVery <strong>to</strong>xic <strong>to</strong> fish• General <strong>No</strong>tes~ Water hazard class 2 (German regulation) (Self - assessment) : hazardous for water~ Do not allow product <strong>to</strong> reach ground water, water course or sewage system~ Danger <strong>to</strong> drinking water even in small quantities~ Also poisonous for fish and plank<strong>to</strong>n in water bodies~ Very <strong>to</strong>xic for aquatic organisms


Trade Name:Top Tablet (white)13. Disposal Considerations• Product• Recommendation~ Must be specially treated adhering <strong>to</strong> official regulations~ Must not be disposed of <strong>to</strong>gether with household garbage~ Do not allow product <strong>to</strong> reach sewage system• European waste catalogueWaste key numbers in accordance with the European Waste catalogue (EWC) are origin referred defined. Since thisproduct is used in several industries no waste key can be provided by the suppler. The waste key number should bedetermined in arrangement with your waste disposal partner or the responsible authority.• Unclean packaging• Recommendation~ Empty contaminated packaging thoroughly. They may be recycled after thorough and proper cleaning.~ Packaging that cannot be cleaned are <strong>to</strong> be disposed of in the same manner as the product.• Recommended cleansing agents:~ Water, if necessary <strong>to</strong>gether with cleansing agents.14. Transport Information• Land Transport ADR/RID (cross border)• ADR/RID class5.1 Oxidising substances• Danger code (Kemler) 50• U N <strong>No</strong> 1479• Packing groupIII• Hazard label 5.1• Special MarkingSymbol (fish and tree)• Proper shipping name 1479 OXIDISING SOLID, N.O.S. (TRICHLOROISOCYANURIC ACID)• Maritime Transport IMDG• IMDG class5.1 Oxidising substances• U N <strong>No</strong> 1479• Packing groupIII• EMS NumberF - A, S - Q• Marine Pollutant<strong>No</strong>• Proper shipping name 1479 OXIDISING SOLID, N.O.S. (TRICHLOROISOCYANURIC ACID)• Air Transport ICAO-TI and IATA-DGR• ICAO/IATA class5.1 Oxidising substances• U N <strong>No</strong> 1479• Hazard label 5.1• Packing groupIII• Proper shipping name 1479 OXIDISING SOLID, N.O.S. (TRICHLOROISOCYANURIC ACID)• UN 'Model <strong>Regulation</strong>'UN1479, OXIDISING SOLID, N.O.S.,5.1 , III


Trade Name:Top Tablet (white)15. Regula<strong>to</strong>ry informationThe product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials• Code letter and hazard designation of productXn HarmfulN Dangerous for the environment• Hazard determining labelling of componentsTrichloroisocyanuric acid• Risk phrasesR22 Harmful if swallowedR31 Contact with acids liberates <strong>to</strong>xic gasesR36/37 Irritating <strong>to</strong> eyes and respira<strong>to</strong>ry systemR50/53 Very <strong>to</strong>xic <strong>to</strong> aquatic organisms, may cause long term adverse effects in the aquatic environment• Safety phrasesS2 Keep out of reach of childrenS7/8 Keep container tightly cS26 In case of contact with eyes, rinse immediately with water and seek medical attention.S29/56 Do not empty in<strong>to</strong> drains, dispose of material and its container at hazardous or special waste pointS46 If swallowed, seek medical advice immediately and show this container or labelS64 If swallowed, rinse mouth with water (only if the person is conscious)WARNING Do not use <strong>to</strong>gether with other products. May release dangerous gases (chlorine)Use Biocides safely. Always read the label and product information before use.16. Other informationThis information is based on our present knowledge. However, this shall not constitute a guarantee for any specificproduct features and shall not establish a legally valid contractual relationship.• Relevant R phrasesR18R22R31R36/37R36/38R50/53R60R61R8In use, may form flammable/explosive vapour-air mixtureHarmful if swallowedContact with acids liberates <strong>to</strong>xic gasesIrritating <strong>to</strong> eyes and respira<strong>to</strong>ry systemIrritating <strong>to</strong> eyes and skinVery <strong>to</strong>xic <strong>to</strong> aquatic organisms, may cause long term adverse effects in the aquatic environmentMay impair fertilityMay cause harm <strong>to</strong> the unborn childContact with combustible material may cause fire.Compiled/Revised onCompiled January 2010ByLinda Brueford

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