Material Safety Data Sheet According to 91/155 EEC

Reviewed on 12.02.07 01/08/2007Material Safety Data SheetAccording to 91/155 EEC1. Identification of the substance/preparation and of the company/undertaking• Trade Name:• Other names• Intended use of chemical• Manufacturer/SupplierUltimate Algicide ConcentrateCopper Sulphate MixtureThe prevention and cure of algaeComplete Pool Controls Ltd, Unit 2, The Park, StokeOrchard, Bishops Cleeve, Gloucestershire, GL52 7RS.Tel: +44 (0) 8712 229081Fax: +44 (0) 8712 2290832. Composition/information on ingredients• Chemical characterization:Mixture of substances listed below with no hazardousadditions.• CAS No. Description 7758-987 Copper Sulphate

Reviewed on 12.02.07 01/08/2007Trade Name:Ultimate Algicide Concentrate4. First Aid measures• After inhalation:• After skin contact:• After eye contact:If inhaled, remove individual to fresh air. If breathing is difficult havea trained person administer oxygen. Seek medical professionalattention immediately.If contact with skin occurs, wash off excess chemical with soap andflush with cool water for at least 15 minutes. If skin irritationpersists, seek professional medical attention immediatelyIf contact with eyes occurs, immediately flush contaminated eye(s)with cool, gently flowing water for at least 20 minutes, holdingeyelid(s) open. Take car not to splash contaminated water into thenon-affected eye. Seek professional medical attention immediately.• After Ingestion:If swallowed, drink large amounts of water or milk. DO NOTINDUCE VOMITING. Avoid alcohol. NEVER GIVE ANYTHING BYMOUTH TO AN UNCONSCIOUS PERSON. Seek professionalmedical attention immediately.5. Fire fighting measures• Special extinguishing media:• Special exposure hazards:• Special protective equipment:Use media that is suitable for surrounding fire, i.e. water,dry powder, carbon dioxideOxides of sulphur, copper fumesFire fighters should wear full protective clothing and selfcontainedbreathing apparatus (SCBA).6. Accidental release Measures• Personal Protection Wear suitable chemical resistant clothing as detailed in section 8.• Environmental ProtectionDo not allow to penetrate the ground/soil. Do not allow to entersewers/surface or ground water.• Methods for cleaning:Contain and absorb the spillage with inert material such as sand.Sweep up the spill and place in clean, dry plastic containersincluding any contaminated soil. Dispose of product in accordancewith relevant local and national waste disposal legislation.7. Handling and storage• Personal Protection• StorageDO NOT MIX WITH OTHER CHEMICALS. Incompatible with strongbases, magnesium. Mix only with water.Keep this product in original, closed container when not in use.Store in a cool, dry, well-ventilated area

Reviewed on 12.02.07 01/08/2007Trade Name:Ultimate Algicide Concentrate8. Exposure control/personal protection• Exposure control limits and source:8hr TWA15min STELppm mg/m3 ppm mg/m3Copper (Dusts and mists) - 1 - 2 EH40Copper (Fume) - 0.2 - - EH40Potassium Hydroxide - - - 2 EH40• Respiratory Protection• Hand Protection• Eye Protection• Skin ProtectionWhere mist emissions are possible, suitable respiratory protectionshould be usedWear suitable chemical resistant glovesWear appropriate safety gogglesWear appropriate safety clothing9. Physical and chemical properties• Appearance at 20oC• OdourClear blue/green liquidFaintly acidic• Density at 20oC 1.18 gml -1• pH 2.4• Viscosity15 cps @15 OC• Flash PointN/A• Solubility in waterFully miscible.10. Stability and reactivity• Conditions to avoidHigh temperature. Poor ventilation. Contamination.• Materials to avoidOther swimming pool/spa chemicals in theirconcentrated forms. Bases and strong oxidising agents.• Hazardous decomposition products Copper oxide and sulphur above 40 O C.

Reviewed on 12.02.07 01/08/2007Trade Name:Ultimate Algicide Concentrate11. Toxilogical Information• Inhalation• IngestionMists can cause ulceration of nasal systems.May cause systemic copper poisoning.• Skin• EyesIrritation and redness.Irritation of eye with possible clouding of the cornea, ulceration,conjunctivitis.• ToxicityAcute Dermal LD50:Oral LD50:-1>50000 mgkg (rabbit)-1>3501 mgkg (rat)12. Ecological Information• EtoxicityThis product may be toxic to fish and aquatic organisms. Do not flush to sewerwithout prior consent from the relevant water authority. Keep product from enteringwaterways and watersheds.13. Disposal Considerations• Substance• ContainerDO NOT put product, spilled product or filled or partially filled containers into thewaste. Disposal of unused, uncontaminated product is regulated according to localand national disposal regulations.DO NOT re-use container. Rinse thoroughly before discarding.14. Transport Information• U N No• Proper shipping nameUN1760Corrosive Liquid, N.O.S. (copper sulphate/potassium hydroxide)• Class/division 8• Packing groupIII• Hazard I D No 80• EAC• Pollutant2XMay be considered a marine pollutant

Reviewed on 12.02.07 01/08/2007Trade Name:Ultimate Algicide Concentrate15. Regulatory information• Product Name• SymbolUltimate Algaecide ConcentrateXi, N• Indications of dangerIrritant; Dangerous for the Environment• Risk phrasesR36/37/38R51/53Irritating to eyes, respiratory system and skin.Toxic to aquatic organisms may cause long-term adverse effects inthe aquatic environment.• Safety phrasesS1/2 Keep locked up and out of the reach of children.S24/25 Avoid contact with skin and eyes.S26S29/56S45S36/37/39In case of contact with eyes, rinse immediately with plenty of waterand seek medical advice.Do not empty into drains, dispose of this material and its containerat hazardous waste collection point.In case of accident or if you feel unwell, seek medical adviceimmediately (show label where possible)Wear suitable protective clothing, gloves and eye/face protection16. Other informationThis information is based on our present knowledge. However, this shall not constitute a guarantee for anyspecific product features and shall not establish a legally valid contractual relationship.