Lecture 28: Heteronuclear Diatomic Molecules The material ... - Cobalt
Lecture 28: Heteronuclear Diatomic Molecules The material ... - Cobalt
Lecture 28: Heteronuclear Diatomic Molecules The material ... - Cobalt
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<strong>Heteronuclear</strong> diatomic molecules Linear variation theoryE =*∫ ψ Hψdvψψ*∫ dvψ*∫ H ψ = C2α + C2α + 2 C C βA A B B A B∫ ψψ* = C2+ C2+ 2C C SA B A BEnergy of electron in orbital ψ A : Always negativeKinetic energy + attraction energy stabilizingfrom both nuclei + repulsion fromall other electronsEnergy of electron in orbital ψ B :Kinetic energy + attraction energyfrom both nuclei+ repulsion fromall other electronsAlways negativestabilizing
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