EU MSDS - McGean

SAFETY DATA SHEETC-46Page: 1Sent to:McGEAN INC WEBSITECompilation date: 07/2008Revision No: 3Section 1: Identification of the substance/mixture and of the company/undertaking1.1. Product identifierProduct name: C-46Product code: 750581.2. Relevant identified uses of the substance or mixture and uses advised againstUse of substance / mixture:Cleaner1.3. Details of the supplier of the safety data sheetCompany name: McGean Rohco (UK) LtdQualcast RoadLower Horseley FieldsWolverhamptonWest MidlandsWV1 2QPUKTel: +44 (0) 1902 456563Fax: +44 (0) 1902 457443Email:sales@mcgean-rohco.co.uk1.4. Emergency telephone numberEmergency tel: +44 (0) 1902 456563(office hours only)Section 2: Hazards identification2.1. Classification of the substance or mixtureClassification under CHIP:Most important adverse effects:C: R35Causes severe burns.2.2. Label elementsLabel elements under CHIP:Hazard symbols:Corrosive.Risk phrases:Safety phrases:R35: Causes severe burns.S22: Do not breathe dust.S26: In case of contact with eyes, rinse immediately with plenty of water and seek medicaladvice.[cont...]

SAFETY DATA SHEETC-46Page: 2S36/37/39: Wear suitable protective clothing, gloves and eye / face protection.S45: In case of accident or if you feel unwell, seek medical advice immediately (show thelabel where possible).2.3. Other hazardsPBT:This substance is not identified as a PBT substance.Section 3: Composition/information on ingredients3.2. MixturesHazardous ingredients:SODIUM HYDROXIDEEINECS CAS CHIP Classification CLP Classification Percent215-185-5 1310-73-2 C: R35 - 70-90%SODIUM METASILICATE ANHYDROUS 100%229-912-9 6834-92-0 C: R34; Xi: R37 - 1-10%Section 4: First aid measures4.1. Description of first aid measuresSkin contact:Eye contact:Ingestion:Inhalation:Remove all contaminated clothes and footwear immediately unless stuck to skin. Drench theaffected skin with running water for 10 minutes or longer if substance is still on skin. Transferto hospital if there are burns or symptoms of poisoning.Bathe the eye with running water for 15 minutes. Transfer to hospital for specialistexamination.Do not induce vomiting. If unconscious, check for breathing and apply artificial respiration ifnecessary. If unconscious and breathing is OK, place in the recovery position. Transfer tohospital as soon as possible.Remove casualty from exposure ensuring one's own safety whilst doing so. If unconscious,check for breathing and apply artificial respiration if necessary. If unconscious and breathingis OK, place in the recovery position. If conscious, ensure the casualty sits or lies down. Ifbreathing becomes bubbly, have the casualty sit and provide oxygen if available. Transfer tohospital as soon as possible.4.2. Most important symptoms and effects, both acute and delayedSkin contact:Eye contact:Ingestion:Inhalation:Severe burns may occur.There may be severe pain. Corneal burns may occur. May cause permanent damage.There may be difficulty swallowing. Corrosive burns may appear around the lips. Nausea andstomach pain may occur.There may be irritation of the throat with a feeling of tightness in the chest. Exposure maycause coughing or wheezing.[cont...]

SAFETY DATA SHEETC-46Page: 34.3. Indication of any immediate medical attention and special treatment neededSection 5: Fire-fighting measures5.1. Extinguishing mediaExtinguishing media:Water spray. Alcohol or polymer foam. Dry chemical powder.5.2. Special hazards arising from the substance or mixtureExposure hazards:Corrosive. In combustion emits toxic fumes.5.3. Advice for fire-fightersAdvice for fire-fighters:Wear self-contained breathing apparatus. Wear protective clothing to prevent contact withskin and eyes.Section 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency proceduresPersonal precautions:Mark out the contaminated area with signs and prevent access to unauthorised personnel.6.2. Environmental precautionsEnvironmental precautions:Do not discharge into drains or rivers.6.3. Methods and material for containment and cleaning upClean-up procedures:Transfer to a closable, labelled salvage container for disposal by an appropriate method.6.4. Reference to other sectionsSection 7: Handling and storage7.1. Precautions for safe handlingHandling requirements:Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area.7.2. Conditions for safe storage, including any incompatibilitiesStorage conditions:Store in cool, well ventilated area. Keep container tightly closed.7.3. Specific end use(s)Section 8: Exposure controls/personal protection8.1. Control parametersHazardous ingredients:SODIUM HYDROXIDEWorkplace exposure limits:Respirable dustState 8 hour TWA: 15 min. STEL: 8 hour TWA: 15 min. STEL:[cont...]

SAFETY DATA SHEETC-46Page: 4UK - 2mgm3 - -8.2. Exposure controlsEngineering measures:Hand protection:Eye protection:Skin protection:Ensure there is sufficient ventilation of the area.Protective gloves.Safety goggles. Ensure eye bath is to hand.Protective clothing with elasticated cuffs and closed neck. Boots made of PVC. Ensuresafety shower is to hand.Section 9: Physical and chemical properties9.1. Information on basic physical and chemical propertiesState:Colour:Odour:Oxidising:Solubility in water:pH:PowderGold-brownOdourlessNon-oxidising (by EC criteria)Highly solubleStrongly alkaline.9.2. Other informationSection 10: Stability and reactivity10.1. Reactivity10.2. Chemical stabilityChemical stability:Stable under normal conditions.10.3. Possibility of hazardous reactions10.4. Conditions to avoidConditions to avoid:Heat.10.5. Incompatible materialsMaterials to avoid:Aluminium. Zinc.10.6. Hazardous decomposition productsHaz. decomp. products:In combustion emits toxic fumes of carbon dioxide / carbon monoxide.Section 11: Toxicological information11.1. Information on toxicological effectsRelevant effects for mixture:[cont...]

SAFETY DATA SHEETC-46Page: 5Effect Route BasisCorrosivity OPT INH DRM Hazardous: calculatedSymptoms / routes of exposureSkin contact:Eye contact:Ingestion:Inhalation:Severe burns may occur.There may be severe pain. Corneal burns may occur. May cause permanent damage.There may be difficulty swallowing. Corrosive burns may appear around the lips. Nausea andstomach pain may occur.There may be irritation of the throat with a feeling of tightness in the chest. Exposure maycause coughing or wheezing.Section 12: Ecological information12.1. Toxicity12.2. Persistence and degradability12.3. Bioaccumulative potential12.4. Mobility in soil12.5. Results of PBT and vPvB assessmentPBT identification:This substance is not identified as a PBT substance.12.6. Other adverse effectsSection 13: Disposal considerations13.1. Waste treatment methodsDisposal of packaging:NB:Arrange for collection by specialised disposal company.The user's attention is drawn to the possible existence of regional or national regulationsregarding disposal.Section 14: Transport information14.1. UN numberUN number:UN175914.2. UN proper shipping nameShipping name:CORROSIVE SOLID, N.O.S.(SODIUM HYDROXIDE; SODIUM METASILICATE ANHYDROUS MIXTURE)14.3. Transport hazard class(es)Transport class: 8[cont...]

SAFETY DATA SHEETC-46Page: 614.4. Packing groupPacking group:II14.5. Environmental hazardsEnvironmentally hazardous: No Marine pollutant: No14.6. Special precautions for userSection 15: Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture15.2. Chemical Safety AssessmentChemical safety assessment:A chemical safety assessment has not been carried out for the substance or the mixture bythe supplier.Section 16: Other informationOther informationOther information:Phrases used in s.2 and 3:Legal disclaimer:This safety data sheet is prepared in accordance with Commission Regulation (EU) No453/2010.* indicates text in the SDS which has changed since the last revision.R34: Causes burns.R35: Causes severe burns.R37: Irritating to respiratory system.The above information is believed to be correct but does not purport to be all inclusive andshall be used only as a guide. This company shall not be held liable for any damage resultingfrom handling or from contact with the above product.[final page]