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Régis REAUSciences Chimiques de Rennes - UMR 6226 CNRS-Université de Rennes 1 - 35042 RENNES Cedex(FRANCE). : 33(0)2 23 23 57 84 ; e-mail : regis.reau@univ-rennes1.fr ; http://pmm.univ-rennes1.fr/1988 Ph.D. Thesis Chemistry, Dr I. Tkatchenko, Laboratoire de Chimie de Coordiantion, Toulouse.1989 Post-doctoral research assistant, Prof. W. Keim, Aachen (Germany)Alexander von Humboldt Foundation Fellowship1990 - 97 Chargé de Recherche CNRS., Dr G. Bertrand, Laboratoire de Chimie de Coordination, Toulouse1996 Habilitation, University of Toulouse1997 Full Professor, Université de Rennes 12001 Junior member of the Institut Universitaire de France2002-05 Member of the Scientific Council of the Université de Rennes 12007 Guest Professor at the University of Durham, UK (2 months), RSC Journals Grant Award2007 Scientific Advisor at the « Agency of the Valuation of Research and Higher Education -AERES»2008 Member of the Steering Committee of the International Conference on Phosphorus Chemistry2008 Member of the Management Committee of the Cost Action PhosNet98 Publications, 10 Patents, 4 Book Chapters13 J. Am. Chem. Soc.11 Angew. Chem. Int. Ed.8 Organometallics7 Chem. Commun.6 Chem. Eur. J.6 Phosphorus, Sulfur, Silicon4 J. Organomet. Chem.4 World PAtents3 J. Catal.4 C.R. Acad. Sci. Paris2 J. Org. Chem.2 New J. Chem.2 Tet. Lett.2 J. Mol. Catal.2 Heteroatom. Chem.2 Enveloppes Soleau2 Pure and Applied Chem.2 Inorg. Chem.1 Adv. Mat.1 Chem. Rev.1 Coord. Chem. Rev.1 Dalton Transactions1 Chem. Med. Chem.1 European Patent1 French Patent1 Org. Biomol. Chem.1 Org. Lett.1 J. Biol. Chem.1 J. Chem. Soc. Perkin Trans.1 Synthetic Metals1 Eur. J. Inorg. Chem.1 Bull. Soc. Chim. Belg.1 Bull. Soc. Chim. Fr.1 Flavins and Flavoproteins1 Polymer Bull.1 Herrmann-Brauer1 Conference Proceedings1 J. Mex. Chem. Soc.1 Sciences ChimiquesBook Chapters- Methoden der organischen Chemie. Houben-Weyl. 1996- Topics in Current Chemistry "New Aspects in Phosphorus Chemistry". Springer. 2005- Functional π-Systems - Syntheses and Strategies, "Design of π-Conjugated Systems Using Organophosphorus BuildingBlocks", Wiley-VCH. 2006- Comprehensive Heterocyclic Chemistry. 3rd Edition, Phospholes, Elsevier, 200824 Invited Lectures at Conferences and Workshops (21 international)3 Plenary Lectures; 44 University Seminars (30 abroad); 6 Talks in schools

Publications[1][2][3][4][5][6][7][8][9][10]Nouveau procédé d'hydroformylation del'hexène-1.F. Mathey, D. Neibecker, R. RéauEnveloppe Soleau 73 174, SNPE, 1986.Evidence for the lability of a bridgingphosphido ligand under hydrogen atmosphere;reaction of the cluster complex Ru 3 (µ-P(C 6 H 5 )(C 5 H 4 N)(µ-P(C 6 H 5 ) 2 )(CO) 8 .N. Lugan, G. Lavigne, J. J. Bonnet, R. Réau,D. Neibecker, I. TkatchenkoJ. Am. Chem. Soc., 1988, 10, 5369.Nouveau procédé d'hydroformylation del'hexène-1.F. Mathey, D. Neibecker, R. RéauEnveloppe Soleau 93 162, SNPE, 1988.Unexpected non-influence of the phosphinerhodiumratio on the activity and selectivity ofrhodium-phosphine hydroformylationcatalysts.C. Bergounhou, D. Neibecker, R. RéauJ. Chem. Soc., Chem. Commun., 1988, 1370.Phosphanorbornadienes as ligands in thetransition metal-catalyzed synthesis of finechemicals.D. Neibecker, R. RéauAngew. Chem. Int. Ed. Engl., 1989, 28, 500.Phospholes as ligands for rhodium systems inhomogeneously-catalysed hydroformylationreactions. Part 1. Stereoelectronic propertiesof the ligands and the hydroformylation of 1-hexene.D. Neibecker, R. RéauJ. Mol. Catal., 1989, 53, 219.Synthesis of 2-arylpropionaldehydes throughhydroformylation.D. Neibecker, R. RéauJ. Org. Chem., 1989, 54, 5208.Phospholes as ligands for rhodium systems inhomogeneously-catalysed hydroformylationreactions. Part 2. Optimisation of the reactionparameters and comparison of the differentcatalytic systems.D. Neibecker, R. RéauJ. Mol. Catal., 1989, 57, 153.Regioselectiverhodium-catalysedhydroformylation of olefines: efficientsynthesis of ethyl 2-formylpropanoate fromethyl acrylate.D. Neibecker, R. RéauNew J. Chem., 1991, 15, 279.Synthesis of (R,R)- and (S,S)-DIOP analogscontaining the 2-5,diphenylphosphol-1-ylmoiety: (2R,3R)- and (2S,3S)-2,3-O-isopropylidene-2,3-dihydroxy-1,4-bis(2,5-diphenyl-phosphol-1-yl)butane, (R,R)- and(S,S)-DIPPOP.H. Hajouji, D. Neibecker, R. Réau[11][12][13][14][15][16][17][18][19][20]C. R. Acad. Sci, Paris, 1991, 312, 229.The first nitrogen NMR spectroscopic study ofnitrile imides (nitrilimines).K. Horchler von Locquenghien, R. Réau, G.BertrandJ. Chem. Soc., Chem. Commun., 1991, 1192.A straightforward synthesis of nitrilimines: X-ray crystal structure of a nitrilimine stabilizedby non-heteroatom substituent.R. Réau, G. Veneziani, F. Dahan, G. BertrandAngew. Chem. Int. Ed. Engl., 1992, 4, 439.Formation of nitrilimines and diazocompounds from lithiated and stannyl diazoderivatives: scope and mechanism.R. Réau, G. Veneziani, G. BertrandJ. Am. Chem. Soc., 1992, 114, 6059.DBU and DBN are strong nucleophiles! X-raycrystal structures of onio- and dioniosubtitutedphosphanes. R. Reed, R. Réau, F.Dahan, G. BertrandAngew. Chem. Int. Ed. Engl., 1993, 32, 399.Transition-metal complexes featuring a diazogroup on a ligand: X-ray crystal structure of[exo-(Me 3 SiCN 2 )-η 5 -C 6 H 6 ]Mn(CO) 3 .R. Réau, R. W. Reed, F. Dahan, G. BertrandOrganometallics, 1993, 12, 1501.Phosphanylcarbenes: from unstableintermediates to X-ray characterizedcompounds.M. Soleilhavoup, G. Alcaraz, R. Réau, A.Baceiredo, G. BertrandPhosphorus, Sulfur and Silicon, 1993, 76, 49.Synthesis and molecular structure of a 1,2-λ 5 -azaphosphete: a cyclic 4-π-electron ylide.J. Tejeda, R. Réau, F. Dahan, G. BertrandJ. Am. Chem. Soc., 1993, 115, 7880.Thermal and metal-catalyzed rearrangementsof bis(stannyl)diazo derivatives intocarbodiimides; carbodiimide-transferreactions.G. Veneziani, R. Réau, G. BertrandOrganometallics, 1993, 12, 4289.Preparation of mono- andbis(germyl)nitrilimines from germanediylsand stannyl diazo derivatives.C. Leue, R. Réau, B. Neumann, H. G.Stammler, P. Jutzi, G. BertrandOrganometallics, 1994, 13, 436.Synthesis and reactivity of cyclic 6-membered6-π and 4-membered 4-π electron ylides.K. Bieger, J. Tejeda, R. Reau, F. Dahan, G.Bertrand J. Am. Chem. Soc., 1994, 116, 8087.

[21][22][23][24][25][26][27][28][29][30][31]Phosphorus substituted “CN 2 " groups: buildingblocks in heterocyclic chemistry.Baceiredo, R. Réau, G. BertrandBull. Soc. Chim. Belg., 1994, 103, 531.Bis(phosphino)carbodiimide: a bis(1,3)-dipole.G. Veneziani, R. Réau, F. Dahan, G. BertrandJ. Org. Chem., 1994, 59, 5927.N-cyano P-hydrogeno iminophosphoranestrimethylchlorostannane adducts [R 2 P(H)=N-C≡N, Me 3 SnCl] and related species: buildingblocks for bis(carbodiimides) of phosphorus.G. Veneziani, P. Dyer, R. Réau, G. Bertrand ,Inorg. Chem., 1994, 33, 5639.Synthesis and reactivity of cyclic 4-π electronylides: non-antiaromatic inorganic ringsystems.R. Réau, A. Baceiredo, G. BertrandPhosphorus, Sulfur, and Silicon, 1995, 93, 1.The surprising unstability of(phosphino)(stannyl)carbenes!N. Emig, J. Tejeda, R. Réau, G. BertrandTetrahedron Letters, 1995, 36, 4231.Synthesis of onio-, diono-, and trioniosubstitutedphosphines; the nucleophilicbehavior of DBN and DBU toward maingroup electrophiles.G. Bouhadir, R. A. Reed, R. Réau,G. BertrandHeteroatom Chemistry, 1995, 6, 371.Simple kinetics of the rhodium-phosphanecomplex-catalyzed hydroformylation ofolefins: the rhodium-1,2,5-triphenylphospholesystem-catalyzed hydroformylation of styrene.Kinetically-deduced involvement of a 14-electron bis(1,2,5-triphenylphosphole)rhodiumintermediate.C. Bergounhou, D. Neibecker, R. RéauBull. Soc. Chim. Fr., 1995, 132, 815.Synthesis of a stable 1λ 5 , 2λ 3 -diphosphete:the first codimer of a λ 3 -phosphaalkyne with aλ 5 -phosphaalkyne.R. Armbrust, M. Sanchez, R. Réau, U.Bergstrasser, M. Regitz, G. BertrandJ. Am. Chem. Soc., 1995, 117, 10785.λ 5 -Phosphetes, benzo-λ 5 -phosphetes,naphtho-λ 5 -phosphetes: four-π-, eigth-π-, andtwelve-π electron systems.U. Heim, H. Pritzkow, U. Fleischer, H.Grützmacher, M. Sanchez, R. Réau, G.Bertrand Chem.Eur. J. Chem., 1996, 1, 68.Comment jouer avec un vieux concept tel quel'antiaromaticité ?G. Bertrand, R. Réau, A. BaceiredoSciences Chimiques, Lettres des DépartementsScientifiques du CNRS, 1995-96, 55, 20.The ligand behavior of a (Z)-phosphazide (a1,2,3,4λ 5 -triazaphosphinine) and of the[32][33][34][35][36][37][38][39][40]corresponding phosphazene (a 1,2λ 5 -azaphosphete).K. Bieger, G. Bouhadir, R. Réau, F. Dahan, G.BertrandJ. Am. Chem. Soc., 1996,118, 1038.Aluminum trichloride-promoted aminolysis ofcyclic imides and oxazolidinones.E. Bon, R. Réau, G. Bertrand, D.C.H. BiggTetrahedron Letters, 1996, 8, 1217.Bis(trimethylstannyl)diazomethane and(triisopropylsilyl)(trimethylstannyl)diazomethane Me 3 Sn-C(N 2 )-SnMe 3 , i-Pr 3 Si-C(N 2 )-SnMe 3 .R. Réau, G. Bertrand, Herrmann-Brauer:Synthetic Methods of Organometallic andInorganic Chemistry, Vol. 2, Georg ThiemeVerlag, Stuttgart New York, 1996, 2, 286.Bis(stannyl)diazo derivatives and theirstructural isomers: powerful CN 22- transferagents.R. Réau, G. BertrandReviews on Heteroatom Chemistry, 1996, 14,137.Synthesis and structure of the first chiraltetracoordinated aluminum cation.N. Emig, R. Réau, H. Krautscheid, D. Fenske,G. BertrandJ. Am. Chem. Soc., 1996, 118, 5822.4-π-electron 4-membered phosphorusheterocycles.R. Réau, A. Baceiredo, G. BertrandPhosphorus, Sulfur and Silicon, 1996, 109-110, 429.Diphosphirenium salt: a new versatile ligandY. Canac, G. Bouhadir, R. Réau, A.Baceiredo, G. BertrandPhosphorus, Sulfur and Silicon, 1996, 111, 53.From 1σ 4 -2σ 2 to 1σ 4 -2σ n -Diphosphetes(n=3-6): The surprising persistence of the P-Pbond.M. Sanchez, R. Réau, F. Dahan, M. Regitz, G.BertrandAngew. Chem. Int. Ed. Engl., 1996, 35, 2228.Phosphorus and other group 15 substitutedcarbenes or equivalents.R. Réau, G. BertrandMethoden der Organische Chemie. Houben-Weyl., 1996, E17a, 794.Nouveaux composés possédant un élément dugroupe 13 lié à un ligand tridentatedianionique, leur procédé de préparation etleur application comme catalyseurs depolymérisation.N. Emig, R. Réau, J. B. Cazaux, G. BertrandBrevet WO9742197, 1997

[41][42][43][44][45][46][47][48][49]The versatile behavior of a 1,2λ 5 -azaphosphete towards protic nucleophiles.G. Bouhadir, K. Bieger, P. Livotto, R. Réau,H. Gornitzka, F . Dahan, G. BertrandJ. Organomet. Chem., 1997, 529, 79.Nitrilimines: Evidence for the AllenicStructure in Solution, Experimental and AbInitio Studies of the Barrier to Racemization,and First Diastereoselective [3+2]-Cycloaddition.J-L. Fauré, R. Réau, M. W. Wong, R. Koch,C. Wentrup, G. BertrandJ. Am. Chem. Soc., 1997, 119, 2819.1σ 4 ,2σ x -Diphosphetes (x = 2-6) : On thePersistence of P-P Bond.M. Sanchez, R. Réau, H. Gornitzka, F. Dahan,M. Regitz, G. BertrandJ. Am. Chem. Soc., 1997, 119, 9720.New chiral bidentate nitrogen donor ligands :synthesis of 1,2-diiminophosphoranes andtheir palladium complexes.O. Tardif, B. Donnadieu, R. RéauC. R. Acad. Sci Paris, Série II c, 1998, 661.The azide-nitrilimine analogy in aluminiumchemistry.N. Emig, F.P. Gabbaï, H. Kraustscheid, R.Réau, G. BertrandAngew. Chem. Int. Ed. Engl., 1998, 37, 989.Neutral and Cationic TetracoordinatedAluminum Complexes Featuring TridentateNitrogen Donors: Synthesis, Structure andCatalytic Activity for the Ring-OpeningPolymerization of Propylene Oxide and (D,L)-Lactide.N. Emig, H. Nguyen, H. Krautscheid, R.Réau, G. BertrandOrganometallics, 1998, 17, 3599.Nouveaux composés possédant un élément dugroupe 11,12 ou 14 et un ligand tridentate,leur procédé de préparation et leur applicationnotamment comme catalyseurs depolymérisation.J-L. Fauré, H. Hahn, R. Réau, J. B. Cazaux, G.Bertrand.Brevet EP890575., 1999.From 2-Phosphino-2H-Phosphirene to 1-Phosphino-1H-Phosphirene, 1λ 5 ,2λ 3 -Diphosphete,and 1,2-Dihydro-1λ 3 ,2λ 3 -Diphosphete: an Experimental and Theoretical Study.M. Sanchez, R. Réau, C. J. Marsden, M.Regitz, G. BertrandChem. Eur. J., 1999, 5, 274.2,5-Di(2-pyridyl)phospholes: modelcompounds for the engineering of π-conjugated donor-acceptor co-oligomers witha chemically tunable HOMO-LUMO gapC. Hay, D. Le Vilain, V. Deborde, L. Toupet,R. RéauChem. Commun., 1999, 345.[50][51][52][53][54][55][56][57][58][59]The dramatic Influence of DianidoamineLigands on the Structure and Reactivity ofLow-Valent Tin and Bismuth DerivativesJ.-L. Fauré, H. Gornitzka, R. Réau, D. Stalke,G. Bertrand.Eur. J. Inorg. Chem. 1999, 2295.Diphosphetes-substituent stabilized ringsystems.G. Bertrand, W. Eisfeld, L. Nyulaszi, R. Réau,M. Regitz, D. SzieberthJ. Chem. Soc., Perkin Trans. 2, 2000, 2324.Electropolymerisation of π-ConjugatedOligomers Containing Phosphole Cores andTerminal Thienyl Moieties: Optical andElectronic Properties.C. Hay, C. Fischmeister, M. Hissler, L.Toupet, R. RéauAngew. Chem. Int. Ed., 2000, 39, 1812.Palladium(II) Complexes of Chiral 1,2-Diiminophosphoranes : Synthesis, StructuralCharacterization and Catalytic Activity for theAllylic AlkylationM. Sauthier, J. Forniés-Cámer, L. Toupet, R.RéauOrganometallics, 2000, 19, 553A Rare Phosphine Coordination Mode: ASymmetrically µ 2 -Bridging Phosphole in aBinuclear Palladium(I) Complex.M. Sauthier, B. Le Guennic, V. Deborde, L.Toupet, J.-F. Halet, R. RéauAngew. Chem. Int. Ed., 2001, 40, 228.Phosphole-Containing π-Conjugated Systems:from Model Molecules to Polymer Films onElectrodes.C. Hay, M. Hissler, C. Fischmeister, J. Rault-Berthelot, L. Toupet, L. Nyulaszi, R. RéauChem. Eur. J., 2001, 7, 4222.A bridging ligand featuring terminal 2-pyridylphosphole moieties: Synthesis, opticalproperties and Ru(II)-complex.C. Hay, M. Sauthier, V. Deborde, M. Hissler,L. Toupet, R. RéauJ. Organomet. Chem., 2002, 643-644, 494.New conjugated π-systems incorporatingphosphole ringsC. Hay, M. Sauthier, M. Hissler, L. Nyulaszi,R. RéauPhosphorus, Sulfur and Silicon and relatedelements, 2002, 177, 1423.NiCl 2 (α-diiminophosphorane) complexes : anew family of readily accessible and tunablecatalyst for oligomerisation of ethyleneM. Sauthier, F. Leca, R. F. de Souza, K.Bernardo-Gusmao, L. F. Trevisan Queiroz, L.Toupet, R. RéauNew J. Chem., 2002, 26, 630.Palladium complexes of a Novel Family ofP,N-chelates, the 2-(2-Pyridyl)phospholes:

[60][61[62]Synthesis, Structural Characterization andCatalytic Activity for Olefins/COCopolymerizationM. Sauthier, F. Leca, L. Toupet, R. RéauOrganometallics, 2002, 21, 1591.Ligand trans-effect: using an old concept as anovel approach to bis(dipolar) NLO-phoresC. Fave, M. Hissler, K. Sénéchal, I. Ledoux, J.Zyss, R. RéauChem. Commun, 2002, 1674.A study of the coordination ability of 2,5-di(2-pyridyl)phospholes on Ru centres.A. Caballero, F. Jalón, B. Manzano, M.Sauthier, L. Toupet, R. RéauJ. Organomet. Chem., 2002, 663(1-2), 118.Disulfide Reductases Current DevelopmentsA. Irmler, A. Bechthold, E. Davioud-Charvet,V. Hofmann, R. Réau, S. Gromer, R. H.Schirmer, K. BeckerFlavins and Flavoproteins, 2002, 803.[69][70][71]Connecting π-Chromophores by σ-P-P bond:New Type of Assemblies Exhibiting σ-πConjugationC. Fave, M. Hissler, T. Kárpáti, J. Rault-Berthelot, V. Deborde, L. Toupet, L. Nyulászi,R. RéauJ. Am. Chem. Soc., 2004, 126, 6058.Ethylene dimerization into 1-butene using 2-pyridylphosphole nickel catalystsR. F. de Souza, K. Bernardo-Gusmão, G. A.Cunha, C. Loup, F. Leca, R. RéauJ. Catal., 2004, 226(1), 235.Combined Raman, electrochemical andDFT/TD-DFT studies on a series of α,α'-thiophene-phosphole oligomers and theircorresponding polymersJ. Casado, V. Hernandez, J. T. LopezNavarrete, R. RéauInternational Conference on SyntheticMaterials Proceedings, 2004, ISBN1741280613.[63][64]Biphasic oligomerization of ethylene withnickel-1,2-diiminophosphorane complexesimmobilized in 1-n-butyl-3-methylimidazolium organochloroaluminate.K. Bernardo-Gusmão, L. F. Trevisan Queiroz,R. F. de Souza, F. Leca, C. Loup, R RéauJ. Catal., 2003, 219, 59.Linear organic π-conjugated systems featuringthe heavy group 14 and 15 elementsM. Hissler, P. W. Dyer, R. Réau,Coord. Chem. Rev., 2003, 244, 1.[72][73]Dérivés phospholes complexés à des métauxet leurs utilisations pharmaceutiquesE. Davioud-Charvet, V. Deborde, R. Réau, R.H. Schirmer, K. BeckerBrevet Français, 2004, FR 04/08427. BrevetMondial ; WO 2006/024770A new family of P,N-chelates : Stereoselectivesynthesis of 2-pyridyl-phospholenes in Pd(II)-complexes coordination sphereF. Leca, C. Lescop, R. RéauOrganometallics, 2004, 23, 6191.[65][66][67][68]Chemistry of Bridging Phosphanes: Pd I -Dimers Bearing 2,5-DipyridylphospholeLigandsF. Leca, M. Sauthier, V. Deborde, L. Toupet,R. RéauChem. Eur. J., 2003, 9(19), 3785.Stereospecific isomerisation of P-heterocyclestriggered by coordination: Synthesis of thefirst P,N-chelates featuring a 2-phospholenemoiety.F. Leca, M. Sauthier, B. le Guennic, C.Lescop, L. Toupet, J.-F. Halet, R. RéauChem. Commun, 2003, 1774.The First Examples of Organophosphorus-Containing Materials for Light-EmittingDiodesC. Fave, T-Y. Cho, M. Hissler, C-W. Chen, T-Y. Luh, C.-C. Wu, R. RéauJ. Am. Chem. Soc., 2003, 125, 9254Synthesis and electronic properties ofalternating α,α'-thiophene-phospholeoligomersC. Hay, C. Fave, M. Hissler, J. Rault-Berthelot, R. RéauOrg. Lett., 2003, 19, 3467.[74][75][76][77][78]Procédé de sécurisation de documents devaleurH. Le Bozec, R. Réau, O. Lohio, O. Maury, F.Demaimay, X. BordeBrevet Français, 2004, FR 04 11152. BrevetMondial ; WO 2006/042967π-Conjugated systems: can phosphole offersmore than pyrrole ?M. Hissler, C. Lescop, R. RéauPure and Applied Chem., 2005, 77, 2099.The rise of organophosphorus derivatives in π-conjugated material chemistryM. Hissler, P. W. Dyer, R. RéauTopics in Current Chemistry New Aspects inPhosphorus Chemistry V, Springer, 2005.Organophosphorus π-conjugated materials:The rise of a new fieldM. Hissler, C. Lescop, R. RéauJ. Organomet. Chem., 2005, 690, 2482Conjugated derivatives containing phospholerings: synthesis, properties and coordinationchemistryM. Hissler, C. Lescop, R. RéauC. R. Acad. Sci Paris, Série II c, 2005, 250,127.

[79][80][81][82][83][84][85][86]Bridging Phosphanes: Exotic or VersatileBinucleating Ligands?F. Leca, C. Lescop, E. Rodriguez, K. Costuas,J.-F. Halet, R. RéauAngew. Chem. Int. Ed., 2005, 44, 2190.Mechanistic studies of a novel, highly potentgold-phosphole inhibitor of human glutathionereductaseM. Deponte, S. Urig, L. D. Arscott, K. Fritz-Wolf, R. Réau, C. Henrold-Mende, S.Koncaveric, M. Meyer, E. Davioud-Charvet,B. P. Ballou, C. H. Williams, K. BeckerJ. Biol. Chem., 2005, 280, 20628.Utilisation de copolymères organiquesconducteurs de type poly(phospholebithiophène)pour la détection de moléculesorganophosphorées électriquement neutresM. Hissler, C. Odin, J. Rault-Berthelot, P.Bauerle, R. RéauBrevet Français, 2005, FR 05004789A Study of Mono- and 1,1’-Di-Phosphaferrocenes as Building Blocks for π-Conjugated SystemsL. Zhang, M. Hissler, H-B. Bu, P. Bäuerle, C.Lescop, R RéauOrganometallics, 2005, 24, 5369.Combined Raman, electrochemical andDFT/TD-DFT studies on a series of α,α'-thiophene-phosphole oligomers and theircorresponding polymersJ. Casado, V. Hernandez, J. T. LopezNavarrete, R. RéauSynthetic Metals, 2005, 153, 249.Undressing of Phosphine Gold(I) TherapeuticAgents as Irreversible Inhibitors of HumanDisulfide ReductasesS. Urig, K. Fritz-Wolf, R. Réau, C. Herold-Mende, K. Toth, E. Davioud-CHarvet, K.BeckerAngew. Chem. Int. Ed., 2006, 45, 1881.Toward Functional π-ConjugatedOrganophosphorus Materials: Design ofPhosphole-based Oligomers forElectroluminescent DevicesH.-C. Su, O. Fadhel, C.-J. Yang, T.-Y. Cho,C. Fave, M. Hissler, C.-C. Wu, R. RéauJ. Am. Chem. Soc., 2006, 128, 983.2-Pyridyl-2-phospholenes: New P,N ligandsfor the palladium-catalyzed isoprenetelomerizationF. Leca, R. RéauJ. Catal., 2006, 238, 425.[88][89][90][91][92][93][94][95][96]Chem. Eur. J., 2006, 12, 3759.Small change makes a big difference. Anaromatic-antiaromatic switch in P-heteroles.L. Nyulászi, O. Hollóczki, C. Lescop, M.Hissler, R. RéauOrg. Biomol. Chem., 2006, 4, 996.Mimicking [2,2]Paracyclophane Topology :Molecular Clips for the Coordination-DrivenCo-facial Assembly of π-Conjugated SystemsB. Nohra, S. Graule, C. Lescop, R. RéauJ. Am. Chem. Soc., 2006, 128, 3520.Functional phosphorus-based conjugatedsystems: structural diversity without multistepsynthesisR. RéauJ. Mex. Chem. Soc., 2006, 50, 51.Phosphole-modified Poly(thiophenes): UniquePostfunctionalizable Conjugated PolymersThat Sense Elemental ChalcogenidesM. Sebastian, M. Hissler, C. Fave, J. Rault-Berthelot, C. Odin, R. RéauAngew. Chem. Int. Ed., 2006, 45, 6152-6155."Design of π-Conjugated Systems UsingOrganophosphorus Building Blocks"P. Dyer, R. RéauFunctional π-Systems Syntheses andStrategies. Wiley-VCH. 2006Organophosphorus Conjugated MaterialsT. Baumgartner, R. RéauChem. Rev., 2006, 106, 4681.Diodes organiques électroluminescentesblanches à base de molécules dérivées duphospholeM. Hissler, R. Réau, O. Fadhel, N. Lemaître,B. GeffroyBrevet Français, 2006, 06 53146. WO2008/012298.Functional phosphorus-based π-conjugatedsystems: Structural diversity withoutmultistep synthesisM. Hissler, C. Lescop, R. Réau,Pure and Applied Chem., 2007, 79, 153.Coordination polymers with π-stackedmetallocyclophane motifs: unprecedented F-shape mixed-coordination bimetallicconnectoresB. Nohra, Y. Yao, C. Lescop, R. RéauAngew. Chem. Int. Ed., 2007, 46, 8242.[87]Tuning Delocalisation in Thienyl-Phospholesπ-Conjugated Systems through P-functionalization. A Joint Raman andTheoretical Study.J. Casado, R. Réau, J. T. López Navarrete[97]Organophosphorus π-conjugated systems foroptoelectronic applicationsB. Nohra, C. Lescop, M. Hissler, R. Réau

[98]Phosphorus, Sulfur and Silicon and relatedelements, 2008, 183, 253.Stereoselective Coordination of DitopicPhospholyl-Azahelicenes: A Novel ApproachTowards Structural Diversity in Chiral π-Conjugated AssembliesW. Shen, S. Graule, J. Crassous, C. Lescop, H.Gornitzka, R. RéauChem. Commun., 2008, 850.[107] Tunable Organophosphorus Dopants for BrightWhite Organic Light-emitting Diodes withSimplified StructuresO. Fadhel, M. Gras, N. Lemaitre, V. Deborde,M. Hissler, B. Geffroy, R. RéauAdv. Mat., 2008, in the press.[108]π-Conjugated Phosphole Derivatives:Synthesis, Optoelectronic Functions andCoordination ChemistryJ. Crassous, R. RéauDalton Transactions, 2008, in the press.[99][100]PhospholesR. Réau, P. Dyer,In Comprehensive Heterocyclic ChemistryIII, AR Katritzky , CA Ramsden, EFVScriven and RJK Taylor , Eds.; Elsevier:Oxford , 2008; Vol. 3, pp 1029 - 1148.Chemistry of Bridging Phosphanes: Cu IDimers Bearing 2,5-Bis(2-pyridyl)phospholeLigandsB. Nohra, E. Rodriguez-Sanz, C. Lescop, R.RéauChem. Eur. J., 2008, 14, 3391.[109]Synthesis and SpectroelecytrochemicalCharacterization of an ElectrochromicPhosphole-EDOT Copolymer :poly([1-phenyl-2,5-bis(2-thienyl)thioxophosphole] 0.14 -co-(3,4-ethylendioxythiopene] 0.86P. M. Carrasco, C. Pozo-Gonzalo, H. Grande,J. A. Pomposo, M. Cortazar, V. Deborde, M.Hissler, R. RéauPolymer Bulletin, 2008, in the press.[101]Synthesis, Electronic Properties andElectropolymerisation of EDOT-capped σ 3 -PhospholesV. Lemau de Talancé, M. Hissler, L.-Z.Zhang, T. Kárpáti, L. Nyulászi, D. Caras-Quintero, P. Bäuerle, R. RéauChem. Commun., 2008, 2200.[102]Système antifalsifiaction de documents muniss’un dispositif de radioidentificationB. Ansel, H. Le Bozec, R. Réau, X. BordeBrevet Français, 2008, FR 08 01589.[103]Documents portant une marque de sécurité àperception visuelle variableB. Ansel, H. Le Bozec, R. Réau, X. BordeBrevet Français, 2008, FR 08 01008.[104]Coordination chemistry of phosphole ligands:From supramolecular assemblies to OLEDs”M. Hissler, C. Lescop, R. RéauC. R. Acad. Sci Paris, 2008, 11, 628.[105]A sugar-modified phosphole gold complexwith antiproliferative properties acting as athioredoxin reductase inhibitor in MCF-7 cellsE. Viry, E. Battaglia, V. Deborde, R. Réau, E.Davioud-Charvet, D. BagrelChemMedChem., 2008, in the press.[106] Ag I -Bimetallic Molecular Clips with AdaptiveCoordination Behavior for SupramolecularChemistryS. Welsch, C. Lescop, M. Scheer, R. RéauInorg. Chem., 2008, in the press.

Oral communications in national congress- Société Française de Chimie, Section Midi-Pyrénées. Toulouse, 1988.- GECOM XX. Reims, 1992.- Journées Grand Sud-Ouest, SFC. Montpellier, 1992.- Congrès SFC 94. Lyon, 1994.- Journées Grand Sud-Ouest, SFC. Montpellier, 1995.- Lumières sur les Systèmes Moléculaires Organisés, Marly le Roy, 2000.Oral communication in international congress- 7 th Seminario Brasileirio de Catalise. Gramado (Brésil), 1993.- XIIIth International Conference on Phosphorus Chemistry. Jerusalem (Israël), 1995.- IX Journées Franco-Espagnoles de chimie organique. Aspet (France), 1996.- XXX Symposium on Catalysis, Prague (République Tchèque), 1998.- Congrès Catalyse, Caracas (Venezuela), 2000.- RENACOM, Agadir (Maroc), 2003.- 7 th FIGIPS Meeting in Inorganic Chemistry, Lisbone (Portugal), 2003.- 22 nd International Symposium on the Organic Chemistry of Sulfur, Saitama (Japon), 2006.Invited conferences in congress and workshop- CONCORD-GECOM 98. Ile de Noirmoutier, 1998.- 5 th FIGIPS Meeting in Inorganic Chemistry. Toulouse, 1999.- CERC3, Rostock (Allemagne), 1999.- Premier Colloque Francophone sur les métaux moléculaires, Rabat (Maroc), 2002.- Société Française de Chimie EUROCHEM, Toulouse, 2002.- Journées Franco-Espagnole de chimie organique, Valence (Espagne), 2002.- Chemitry Symposium Erlangen-Rennes, Erlangen (Germany), 2004.- 16 th International Conference on Phosphorus Chemistry, Birmingham (UK), 2004.- 21 st International Conference on Organometallic Chemistry, Vancouver (Canada), 2004.- 7th International Conference on Heteroatom Chemistry (ICHAC-7), Shanghai (Chine), 2004.- 7 th Workshop Graduate School of Chemistry and Biochemistry, Bielefeld (Allemagne), 2005.- 2 nd France-Japon Bilateral Symposium on Functional Material, Kyoto (Japon), 2005.- XIV th International Conference on Chemistry of Phosphorus Compounds, Kazan, (Russie), 2005.- XI èmes Journées Polymères Conducteurs, Batz sur Mer (France), 2005.- DFG-CNRS Workshop, Bonn (Allemagne), 2006.- 3 th Corean-France « Star » Workshop, Paris (France), 2006- 16 th International Conference on Organic Synthesis, Merida (Mexique), 2006.- 2 nd Core to Core Symposium on Heteroatom Chemistry, Tokyo (Japon), 2006.- 1 st International Symposium on the Emerging Materials for Nano Bio Technology, Seoul (Corée du Sud),2006.- 17 th International Conference on Phosphorus Chemistry, Xiamen (Chine), 2007.- 2 nd International Symposium on the Emerging Materials for Nano Bio Technology, Seoul (S Corée duSud), 2007.- 1 ere Rencontres Scientifiques Rennes-Sétif, Rennes (France), 2007.- First Scientific Symposium of the Graduate School BuildMoNa (Leipzig), 2008.- International Krutyn Summer School, Frontiers in Molecular Optoelectronics (Pologne), 2008Plenary lectures- Regitz-Scherer Lecture on Phosphorus Chemistry, Kaiserlautern (Allemagne), 2004.- Journées Grand Sud-Ouest – Société Française de Chimie, Bordeaux, 2007.- 23th International Symposium on the Organic Chemistry of Sulfur, Moscou, 2008.

9Invited conferences in UniversityRWTH. Aachen (Allemagne), décembre 1990.Universidade Estadual-UNICAMP. Campinas (Brésil), septembre 1993.Instituto de Quimica. Porto Alegre (Brésil), septembre 1993.Universidade Estadual Paulista²-UNESP. Araraquara (Brésil), septembre 1993.Facultad de Quimica. Sevilla (Espagne), juin 1995.Facultad de Quimica. Alcala de Henares (Espagne), juin 1995.Facultad de Quimica. Ciudad Real (Espagne), juin 1995.Université de Rennes, décembre 1996.Université de Poitiers, avril 1997.Facultad de Quimica. Barcelone (Espagne), décembre 2000.Facultad de Quimica. Ciudad Real (Espagne), décembre 2000.ENSC de Lille, janvier 2001.Université de Marseille, mai 2001.Université de Erlangen (Allemagne), juillet 2001.Université de Bochum (Allemagne), juillet 2001.Université de Wuerzburg (Allemagne), juillet 2001.Université de Budapest (Hongrie), février 2002.Université d'Amsterdam (Hollande), décembre 2002.Université de Biochimie d'Heidelberg (Allemagne), octobre 2003.Université de Stuttgart (Allemagne), novembre 2003.Université de Chimie d'Heidelberg (Allemagne), novembre 2003.Université de Biochimie d'Ulm (Allemagne), novembre 2003.Université de Bourgogne, décembre 2003.Université d'Orléans, janvier 2004.Institut de Chimie Moléculaire et des Matériaux d'Orsay, mars 2004.Institute of Chemistry Academia Sinica (Taiwan), août 2004.National Taiwan University (Taiwan), août 2004.The University of Hong-Kong (Chine), août 2004.University of Pecs (Hongrie), décembre 2004.University of Budapest (Hongrie), décembre 2004.Université Louis Pasteur (Strasbourg), mars 2005.Seoul National University (Corée du Sud), mai 2005.ENSICAEN, (Caen), novembre 2005.Eindhoven TU (Hollande), avril 2006.Laboratoire de Chimie de Coordination (Toulouse), juin 2006.Université de Leipzig (Allemagne), juillet 2006.Université de la Méditerranée (Marseille), octobre 2006.Université Pierre et Marie Curie, (Paris), novembre 2006.Université de Erlangen (Allemagne), janvier 2007.Université de Regensburg (Allemagne), novembre 2007.Ecole Nationale Supérieure de Lyon, février 2008.Université Bordeaux 1, mai 2008.IVIC (Vénézuéla), juillet 2008