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unit (7) organic compounds

unit (7) organic compounds

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IUPAC Rules for Naming Branched-Chain AlkanesI) An Alkane With Only One Branch1. Determine the name of the parent chain, the longest continues carbon chain in thealkane.2. The parent chain is numbered from the end nearest to the alkyl group. Give thealkyl group (the branch) a name and a number. Use a hyphen to connect thenumber to the name.3. Write the name as single word.Worked Example 7-3Name the following alkane:SolutionCH 3CH 3 - CH 2 - CH - CH 2 -CH 2 -CH 2 -CH 31. The longest continuous chain contains seven carbon atoms (heptane).2. There is one methyl group on the chain on carbon 3. “3-methyl” (Thenumbering must be from the left to give the lowest number to the branch).3. The correct name is 3-methylheptane.II) An Alkane With More Than One BranchWhere Branches Are Identical1. Determine the name of the parent chain, the longest continuous carbon chain in thealkane.2. The parent chain is numbered from the end nearer the first alkyl group. Give eachalkyl group a name and a number. Use hyphens to separate the numbers from thedifferent prefixes and commas to separate numbers. If two or more identical alkylsare present, use one of the prefixes di-, tri-, tetra-, and so forth, to the name of thealkyl.3. Write the name as single word.7-7

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