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unit (7) organic compounds

unit (7) organic compounds

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Worked Example 7-4Name the following alkane:CH 3CH 3CH 3 - CH - C - CH 2 - CH- CH 2 -CH 3CH 3 CH 3Solution1. The longest continuous chain contains seven carbon atoms (heptane).2. There are four methyl groups on the chain. Two methyl groups are on carbon 3,one CH 3 on carbon 2, and one CH 3 on carbon 5.3. The correct name is 2,3,3,5-tetramethylheptane.III) An Alkane With More Than One BranchWhere Branches Are Different1. Determine the name of the parent chain, the longest continues carbon chain in thealkane.2. The parent chain is numbered from the end nearer the first alkyl group. Give eachalkyl group a name and a number. Use hyphens to separate numbers from words; usecommas to separate numbers. If different alkyl groups are present, write them inalphabetical order. If necessary, use one of the prefixes di-, tri-, tetra-, and so forth,but don’t use them for alphabetizing purposes.3. Write the name as single word.Worked Example 7-5Name the following alkane:SolutionCH 2 CH 3CH 3 - CH - CH - CH- CH 2 - CH 2 -CH 3CH 3 CH 31. The longest continuous chain contains seven carbon atoms (heptane).2. There are three branches. Two methyl groups on carbon 2 and 3; one ethylgroup on carbon 4. Write the alkyl groups in alphabetical order (ethyl beforemethyl).3. The correct name is 4-ethyl-2,3-dimethylheptane.7-8

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