Amercoat 78HB Cure - MSDS - AltaPaints and Coatings

Material Safety Data SheetDate of issue 17 February 2009Version 2.011 .Product and company identificationProduct nameCodeSupplierEmergency telephonenumberTechnical Phone Number2 .Hazards identificationEmergency overviewPotential acute health effectsInhalationIngestionSkinEyes: AMERCOAT 78HB CURE: AT78HB-B~F2:::::::PPG Industries, Inc.One PPG PlacePittsburgh, PA 15272(412) 434-4515 (U.S.)(514) 645-1320 (Canada)01-800-00-21-400 (Mexico): (412) 492-5200 (ALLISON PARK, PA) 8:00 a.m. - 5:00 p.m. ESTDANGER!Harmful or fatal if swallowed. Corrosive to the digestive tract. Causes burns.Over-exposure signs/symptomsInhalation: Adverse symptoms may include the following:respiratory tract irritationcoughingwheezing and breathing difficultiesasthmaIngestionSkinCOMBUSTIBLE LIQUID AND VAPOR. HARMFUL OR FATAL IF SWALLOWED.CAUSES RESPIRATORY TRACT, DIGESTIVE TRACT, EYE AND SKIN BURNS.HARMFUL IF INHALED OR ABSORBED THROUGH SKIN. MAY CAUSE ALLERGICRESPIRATORY AND SKIN REACTION. PROLONGED OR REPEATED CONTACTMAY DRY SKIN AND CAUSE IRRITATION. CONTAINS MATERIAL THAT CANCAUSE TARGET ORGAN DAMAGE.Keep away from heat, sparks and flame. Do not breathe vapor or mist. Do not swallow.Do not ingest. Do not get in eyes or on skin or clothing. Use only with adequateventilation. Keep container tightly closed and sealed until ready for use. Washthoroughly after handling.Harmful if inhaled. Corrosive to the respiratory system. May cause sensitization byinhalation. Exposure to decomposition products may cause a health hazard. Seriouseffects may be delayed following exposure.Corrosive to the skin. Causes burns. Toxic in contact with skin. May cause an allergicskin reaction.Corrosive to eyes. Causes burns.: Adverse symptoms may include the following:stomach pains: Adverse symptoms may include the following:pain or irritationrednessdrynesscrackingblistering may occurUnited States - Canada - MexicoPage: 1/9

Product code AT78HB-B~F2 Date of issue 17 February 2009 VersionProduct name AMERCOAT 78HB CURE2.012 .EyesHazards identificationMedical conditionsaggravated by overexposureSee toxicological information (section 11): Adverse symptoms may include the following:painwateringrednessRepeated exposure to high vapor concentrations may cause irritation of the respiratory system and permanent brain andnervous system damage. Inhalation of vapor/aerosol concentrations above the recommended exposure limits causesheadaches, drowsiness and nausea and may lead to unconsciousness or death. There is some evidence that repeatedexposure to organic solvent vapors in combination with constant loud noise can cause greater hearing loss than expectedfrom exposure to noise alone.:Pre-existing respiratory and skin disorders and disorders involving any other targetorgans mentioned in this MSDS as being at risk may be aggravated by over-exposure tothis product.This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200).This product has been classified in accordance with the hazard criteria of the Controlled Products Regulationsand the MSDS contains all the information required by the Controlled Products Regulations.3 .Composition/information on ingredientsName CAS number %3,6,9-triazaundecamethylenediamine 112-57-2 10 - 30diethylenetriamine 111-40-0 10 - 30benzyl alcohol 100-51-6 5 - 101-methoxy-2-propanol 107-98-2 3 - 71,2-cyclohexanediamine 694-83-7 3 - 7hexamethylenediamine 124-09-4 3 - 7phenol 108-95-2 1 - 5solvent naphtha (petroleum), light arom. 64742-95-6 1 - 52,4,6-tris(dimethylaminomethyl)phenol 90-72-2 1 - 51,2,4-trimethylbenzene 95-63-6 1 - 5mesitylene 108-67-8 0.1 - 1There are no additional ingredients present which, within the current knowledge of the supplier and in theconcentrations applicable, are classified as hazardous to health or the environment and hence require reporting inthis section.4 .First aid measuresIf ingestion, irritation, any type of overexposure or symptoms of overexposure occur during or persists after use of thisproduct, contact a POISON CONTROL CENTER, EMERGENCY ROOM OR PHYSICIAN immediately; have MaterialSafety Data Sheet information available. Never give anything by mouth to an unconscious or convulsing person.Eye contactSkin contactInhalationIngestionNotes to physician:::::Check for and remove any contact lenses. Immediately flush eyes with running waterfor at least 15 minutes, keeping eyelids open.Remove contaminated clothing and shoes. Wash skin thoroughly with soap andwater or use recognized skin cleanser. Do not use solvents or thinners.Remove to fresh air. Keep person warm and at rest. If not breathing, if breathing isirregular or if respiratory arrest occurs, provide artificial respiration or oxygen bytrained personnel.If swallowed, seek medical advice immediately and show this container or label.Keep person warm and at rest. Do not induce vomiting.In case of inhalation of decomposition products in a fire, symptoms may be delayed.The exposed person may need to be kept under medical surveillance for 48 hours.United States - Canada - MexicoPage: 2/9

Product code AT78HB-B~F2 Date of issue 17 February 2009 VersionProduct name AMERCOAT 78HB CURE2.015 .Fire-fighting measuresFlammability of the product :Extinguishing mediaSuitable :Not suitable :Special exposure hazards :Hazardous combustionproductsSpecial protectiveequipment for fire-fighters:Combustible liquid. In a fire or if heated, a pressure increase will occur and thecontainer may burst, with the risk of a subsequent explosion.Use dry chemical, CO2, water spray (fog) or foam.Do not use water jet.Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining. Move containers from fire area if this can be done without risk. Use waterspray to keep fire-exposed containers cool.: Decomposition products may include the following materials:carbon oxidesnitrogen oxidesFire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.6 .Accidental release measuresEnvironmental precautionsLarge spill :: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Use spark-proof tools and explosion-proof equipment. Prevent entry intosewers, water courses, basements or confined areas. Wash spillages into an effluenttreatment plant or proceed as follows. Contain and collect spillage with noncombustible,absorbent material e.g. sand, earth, vermiculite or diatomaceous earth andplace in container for disposal according to local regulations (see section 13). Disposeof via a licensed waste disposal contractor. Contaminated absorbent material may posethe same hazard as the spilled product. Note: see section 1 for emergency contactinformation and section 13 for waste disposal.Small spill :Stop leak if without risk. Move containers from spill area. Use spark-proof tools andexplosion-proof equipment. Dilute with water and mop up if water-soluble or absorb withan inert dry material and place in an appropriate waste disposal container. Dispose ofvia a licensed waste disposal contractor.7 .Handling and storageHandling :Put on appropriate personal protective equipment (see section 8). Eating, drinking andsmoking should be prohibited in areas where this material is handled, stored andprocessed. Persons with a history of skin sensitization problems or asthma, allergies orchronic or recurrent respiratory disease should not be employed in any process in whichthis product is used. Do not breathe vapor or mist. Do not swallow. Do not get in eyesor on skin or clothing. Use only with adequate ventilation. Wear appropriate respiratorwhen ventilation is inadequate. Do not enter storage areas and confined spaces unlessadequately ventilated. Keep in the original container or an approved alternative madefrom a compatible material, kept tightly closed when not in use. Store and use awayfrom heat, sparks, open flame or any other ignition source. Use explosion-proofelectrical (ventilating, lighting and material handling) equipment. Use non-sparking tools.Take precautionary measures against electrostatic discharges. To avoid fire orexplosion, dissipate static electricity during transfer by grounding and bonding containersand equipment before transferring material. Empty containers retain product residueand can be hazardous. Do not reuse container.United States - Canada - MexicoPage: 3/9

Product code AT78HB-B~F2 Date of issue 17 February 2009 VersionProduct name AMERCOAT 78HB CURE7 .Handling and storageStorage :8 .Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilatedarea, away from incompatible materials (see section 10) and food and drink. Eliminateall ignition sources. Separate from oxidizing materials. Keep container tightly closedand sealed until ready for use. Containers that have been opened must be carefullyresealed and kept upright to prevent leakage. Do not store in unlabeled containers. Useappropriate containment to avoid environmental contamination.Exposure controls/personal protectionName Result ACGIH OSHA Ontario Mexico PPGdiethylenetriamine TWA 1 ppm Notestablished1 ppm 1 ppm Notestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________benzyl alcohol TWA Not NotNot Not 10 ppmestablished established established established____________________________ ___________ ___________ ___________ ___________ ___________ ___________1-methoxy-2-propanol TWA 100 ppm Notestablished100 ppm NotestablishedNotestablishedSTEL 150 ppm Notestablished150 ppm NotestablishedNotestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________hexamethylenediamine TWA 0.5 ppm Notestablished0.5 ppm NotestablishedNotestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________phenol TWA 5 ppm 5 ppm 5 ppm 5 ppm NotestablishedSTEL NotestablishedNotestablishedNotestablished10 ppm Notestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________1,2,4-trimethylbenzene TWA 25 ppm Notestablished25 ppm 25 ppm NotestablishedSTEL NotestablishedNotestablishedNotestablished35 ppm Notestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________mesitylene TWA 25 ppm Notestablished25 ppm 25 ppm NotestablishedSTEL NotestablishedNotestablishedNotestablished35 ppm Notestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________Key to abbreviationsA = Acceptable Maximum PeakS = Potential skin absorptionACGIH = American Conference of Governmental Industrial Hygienists. SR = Respiratory sensitizationC = Ceiling LimitSS = Skin sensitizationF = FumeTD = Total dustIPEL = Internal Permissible Exposure LimitTLV = Threshold Limit ValueOSHA = Occupational Safety and Health Administration.TWA = Time Weighted AverageR = Respirable Z = OSHA 29CFR 1910.1200 Subpart Z - Toxic and HazardousSubstancesConsult local authorities for acceptable exposure limits.Recommended monitoringprocedures: If this product contains ingredients with exposure limits, personal, workplace atmosphereor biological monitoring may be required to determine the effectiveness of the ventilationor other control measures and/or the necessity to use respiratory protective equipment.2.01United States - Canada - MexicoPage: 4/9

Product code AT78HB-B~F2 Date of issue 17 February 2009 VersionProduct name AMERCOAT 78HB CURE10 .StabilityStability and reactivityConditions to avoidMaterials to avoidHazardous decompositionproductsHazardous polymerization11 .Toxicological informationConclusion/SummaryDefatting irritant?CarcinogenicityConclusion/SummaryCarcinogenicity:::::The product may not be stable under certain conditions of storage or use.2.01Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition.Reactive or incompatible with the following materials:,oxidizing materials,strongacids,strong alkalisUnder normal conditions of storage and use, hazardous decomposition products shouldnot be produced.Under normal conditions of storage and use, hazardous polymerization will not occur.Acute toxicityProduct/ingredient name Result Species Dose Exposure3,6,9-triazaundecamethylenediamine LD50 Oral Rat 0.205 g/kg -LD50 Dermal Rabbit 0.66 g/kg -diethylenetriamine LD50 Oral Rat 1080 mg/kg -LD50 Dermal Rabbit 1090 mg/kg -benzyl alcohol LD50 Oral Rat 1230 mg/kg -LD50 Dermal Rabbit 2000 mg/kg -1-methoxy-2-propanol LD50 Oral Rat 5.2 g/kg -LD50 Dermal Rabbit 13 g/kg -1,2-cyclohexanediamine LD50 Oral Rat 4556 mg/kg -hexamethylenediamine LD50 Oral Rat 750 mg/kg -LD50 Dermal Rabbit 1.11 g/kg -phenol LD50 Oral Rat 0.317 g/kg -LD50 Dermal Rabbit 630 mg/kg -LC50 Inhalation Rat 316 mg/m3 4 hourssolvent naphtha (petroleum), light arom. LD50 Oral Rat 8400 mg/kg -LD50 Dermal Rabbit 3.48 g/kg -2,4,6-tris(dimethylaminomethyl)phenol LD50 Oral Rat 1200 mg/kg -LD50 Dermal Rabbit 1.28 g/kg -1,2,4-trimethylbenzene LD50 Oral Rat 5 gm/kg -LC50 Inhalation Rat 18000 mg/m3 4 hoursmesitylene LD50 Oral Rat 5000 mg/kg -LC50 Inhalation Rat 24000 mg/m3 4 hoursConclusion/Summary : Not available.Chronic toxicityTarget organs: Not available.: Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/ordermatitis.: Contains material which causes damage to the following organs: blood, kidneys, liver,heart, brain, upper respiratory tract, skin, central nervous system (CNS), eye, lens orcornea.Contains material which may cause damage to the following organs: lungs, mucousmembranes, spleen, gastrointestinal tract, pancreas.: Not available.: No known significant effects or critical hazards.ClassificationProduct/ingredient name ACGIH IARC EPA NIOSH NTP OSHAphenol A4 3 - - - -United States - Canada - MexicoPage: 6/9

Product code AT78HB-B~F2 Date of issue 17 February 2009 VersionProduct name AMERCOAT 78HB CURE11 .Toxicological informationMutagenicityConclusion/SummaryMutagenicityTeratogenicityConclusion/SummaryTeratogenicityReproductive toxicityConclusion/SummaryDevelopmental effectsFertility effects12 .: Not available.: No known significant effects or critical hazards.: Not available.: No known significant effects or critical hazards.: Not available.Ecological informationEnvironmental effectsAquatic ecotoxicity: No known significant effects or critical hazards.: No known significant effects or critical hazards.: No known significant effects or critical hazards.Product/ingredientnameResultSpeciesExposurediethylenetriamine Acute LC50 1014000 ug/L Fresh water Fish - Guppy - Poecilia reticulata 96 hours_________________________________ ________________________________ __________Acute LC50 53500 ug/L Fresh water Daphnia - Water flea - Daphnia 48 hoursmagna______________________ _________________________________ ________________________________ __________benzyl alcohol Acute LC50 10000 ug/L Fresh water Fish - Bluegill - Lepomis macrochirus 96 hours______________________ _________________________________ ________________________________ __________phenol Acute LC50 1.75 ug/L Fresh water Fish - Cyprinus carpio 96 hours_________________________________ ________________________________ __________Acute EC50 4200 ug/L Fresh water Daphnia - Water flea - Daphnia 48 hoursmagna______________________ _________________________________ ________________________________ __________1,2,4-trimethylbenzene Acute LC50 7720 to 8280 ug/L Fresh Fish - Fathead minnow - Pimephales 96 hourswaterpromelas______________________ _________________________________ ________________________________ __________13 .Disposal considerationsWaste disposal:2.01The generation of waste should be avoided or minimized wherever possible. Emptycontainers or liners may retain some product residues. This material and its containermust be disposed of in a safe way. Dispose of surplus and non-recyclable products viaa licensed waste disposal contractor. Disposal of this product, solutions and any byproductsshould at all times comply with the requirements of environmental protectionand waste disposal legislation and any regional local authority requirements. Avoiddispersal of spilled material and runoff and contact with soil, waterways, drains andsewers.Empty containers or liners may retain some product residues. This material and itscontainer must be disposed of in a safe way.Disposal should be in accordance with applicable regional, national and local laws and regulations.Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONfor additional handling information and protection of employees. Section 6. Accidental release measuresUnited States - Canada - MexicoPage: 7/9

Product code AT78HB-B~F2 Date of issue 17 February 2009 VersionProduct name AMERCOAT 78HB CURE14 .Transport information2.01Regulation UN number Proper shipping name Classes PG*UN 3082 Paint 9 IIIIMDG 3082 Paint 9 III -DOTReportable quantity RQ :15 .3082 Paint9Regulatory informationUnited States inventory (TSCA 8b) :Australia inventory (AICS) :Canada inventory :China inventory (IECSC) :Europe inventory :Japan inventory (ENCS) :Korea inventory (KECI) :New Zealand :Philippines inventory (PICCS) :United StatesU.S. Federal regulationsSARA 313Form R - ReportingrequirementsCanadaCERCLA: Hazardous substances.: phenol: 1000 lbs. (454 kg);:All components are listed or exempted.All components are listed or exempted.All components are listed or exempted.At least one component is not listed.All components are listed or exempted.All components are listed or exempted.All components are listed or exempted.Not determined.All components are listed or exempted.TSCA 12(b) annual export notification: No products were found.IIIAdditional information-RemarksUSA Only: Bulk Shipments (Greater than 450 Liters) areregulated by DOT for transportas Combustible Liquids.TSCA 12(b) one-time export: No products were found.SARA 302/304/311/312 extremely hazardous substances: phenolSARA 302/304 emergency planning and notification: phenolSARA 302/304/311/312 hazardous chemicals: benzyl alcohol; phenol;hexamethylenediamine; 3,6,9-triazaundecamethylenediamine; diethylenetriamine; 1-methoxy-2-propanol; 1,2,4-trimethylbenzeneSARA 311/312 MSDS distribution - chemical inventory - hazard identification:benzyl alcohol: Immediate (acute) health hazard, Delayed (chronic) health hazard;phenol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) health hazard;hexamethylenediamine: Fire hazard, Immediate (acute) health hazard, Delayed (chronic)health hazard; 3,6,9-triazaundecamethylenediamine: Immediate (acute) health hazard,Delayed (chronic) health hazard; diethylenetriamine: Immediate (acute) health hazard; 1-methoxy-2-propanol: Fire hazard, Immediate (acute) health hazard, Delayed (chronic)health hazard; 1,2,4-trimethylbenzene: Fire hazard, Delayed (chronic) health hazardCERCLA: Hazardous substances.: phenol: 1000 lbs. (454 kg);Product name CAS number Concentration: phenol 108-95-2 1 - 51,2,4-trimethylbenzene 95-63-6 1 - 5WHMIS (Canada):Class E: Corrosive liquid. Class B-3: Combustible liquid with a flash point between37.8°C (100°F) and 93.3°C (200°F). Class D-1A: Material causing immediate andserious toxic effects (Very toxic). Class D-1B: Material causing immediate and serioustoxic effects (Toxic). Class D-2A: Material causing other toxic effects (Very toxic). ClassD-2B: Material causing other toxic effects (Toxic).United States - Canada - MexicoPage: 8/9

Product code AT78HB-B~F2 Date of issue 17 February 2009 VersionProduct name AMERCOAT 78HB CURE15 .MexicoRegulatory informationClassificationFlammability16 .: 2 Health : 3 Reactivity : 1Other information2.01Hazardous Material Information System (U.S.A.)Health : 3 * Flammability : 2 Physical hazards :Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implementedHMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®materials may be purchased exclusively from J. J. Keller (800) 327-6868.The customer is responsible for determining the PPE code for this material.National Fire Protection Association (U.S.A.)HealthDisclaimer: 3 Flammability : 2 Instability :Date of previous issueOrganization that preparedthe MSDS:No previous validation.: EHSIndicates information that has changed from previously issued version.The information contained in this data sheet is based on present scientific and technical knowledge. The purpose of thisinformation is to draw attention to the health and safety aspects concerning the products supplied by PPG, and torecommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given inrespect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measuresdescribed in this data sheet or for any misuse of the products.11United States - Canada - MexicoPage: 9/9