Amercoat 78HB Black Resin - MSDS - AltaPaints and Coatings

Product code UC87162 Date of issue 18 April 2009 VersionProduct name AMERCOAT 78HB BLACK RESIN8 .Exposure controls/personal protection6Name Result ACGIH OSHA Ontario Mexico PPGtalc , not containing asbestiformfibresKey to abbreviationsA = Acceptable Maximum PeakS = Potential skin absorptionACGIH = American Conference of Governmental Industrial Hygienists. SR = Respiratory sensitizationC = Ceiling LimitSS = Skin sensitizationF = FumeTD = Total dustIPEL = Internal Permissible Exposure LimitTLV = Threshold Limit ValueOSHA = Occupational Safety and Health Administration.TWA = Time Weighted AverageR = Respirable Z = OSHA 29CFR 1910.1200 Subpart Z - Toxic and HazardousSubstancesConsult local authorities for acceptable exposure limits.Recommended monitoringproceduresEngineering measuresTWA 2 mg/m³ R 20 mppcf Z 2 f/cc2 mg/m³ RTDSTEL Not 1 f/cc Z Notestablishedestablished2 mg/m³ NotestablishedNotestablishedNotestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________pitch, coal tar, high-temp. TWA 0.2 mg/m³(as benzenesolubles)0.02 mg/m³ Notestablished0.2 mg/m³ 0.2 mg/m³(totalbenzenesolublecompounds)STEL NotestablishedNotestablishedNotestablished0.015 ppm Notestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________1,2,4-trimethylbenzene TWA 25 ppm Notestablished25 ppm 25 ppm NotestablishedSTEL NotestablishedNotestablishedNotestablished35 ppm Notestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________mesitylene TWA 25 ppm Notestablished25 ppm 25 ppm NotestablishedSTEL NotestablishedNotestablishedNotestablished35 ppm Notestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________ethanol TWA 1000 ppm 1000 ppm 1000 ppm 1000 ppm Notestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________xylene (mixture of o-, m-, p-isomers)TWA 100 ppm 100 ppm 100 ppm 100 ppm NotestablishedSTEL 150 ppm Notestablished150 ppm 150 ppm Notestablished____________________________ ___________ ___________ ___________ ___________ ___________ ___________: If this product contains ingredients with exposure limits, personal, workplace atmosphereor biological monitoring may be required to determine the effectiveness of the ventilationor other control measures and/or the necessity to use respiratory protective equipment.: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits. The engineering controls also need to keep gas, vaporor dust concentrations below any lower explosive limits. Use explosion-proof ventilationequipment.United States - Canada - MexicoPage: 4/9

Product code UC87162 Date of issue 18 April 2009 VersionProduct name AMERCOAT 78HB BLACK RESIN8 .Exposure controls/personal protectionHygiene measuresPersonal protectionEyesHandsGloves :RespiratorySkinEnvironmental exposurecontrols: Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.:::Safety glasses with side shields.: Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary.butyl rubberIf workers are exposed to concentrations above the exposure limit, they must useappropriate, certified respirators. Use a properly fitted, air-purifying or air-fed respiratorcomplying with an approved standard if a risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels, thehazards of the product and the safe working limits of the selected respirator.Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.: Emissions from ventilation or work process equipment should be checked to ensure theycomply with the requirements of environmental protection legislation. In some cases,fume scrubbers, filters or engineering modifications to the process equipment will benecessary to reduce emissions to acceptable levels.69 .Physical and chemical propertiesPhysical stateColorOdorpHBoiling/condensation pointMelting/freezing pointSpecific gravityVapor pressureVapor densityVolatilityOdor thresholdEvaporation rateOctanol/water partitioncoefficient:::::::::::Liquid.Flash point: Closed cup: 52.78°C (127°F)Explosion limits : Lower: 1.2%Density ( lbs / gal ) : 12.52% Solid. (w/w) : 83.94Not available.Not available.Not available.>37.78°C (>100°F)Not available.1.50.89 kPa (6.7 mm Hg)Not available.28% (v/v), 16.06% (w/w)Not available.: 37 (Butyl acetate. = 1): Not available.United States - Canada - MexicoPage: 5/9

Product code UC87162 Date of issue 18 April 2009 VersionProduct name AMERCOAT 78HB BLACK RESIN610 .StabilityStability and reactivityConditions to avoidMaterials to avoidHazardous decompositionproductsHazardous polymerization:::::Stable under recommended storage and handling conditions (see section 7).Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,braze, solder, drill, grind or expose containers to heat or sources of ignition.Reactive or incompatible with the following materials:,acids,oxidizing materials,strongalkalisUnder normal conditions of storage and use, hazardous decomposition products shouldnot be produced.Under normal conditions of storage and use, hazardous polymerization will not occur.11 .Toxicological informationAcute toxicityProduct/ingredient name Result Species Dose Exposurepitch, coal tar, high-temp. LD50 Oral Rat 3300 mg/kg -LD50 Dermal Rabbit >5000 mg/kg -reaction product: bisphenol-A-LD50 Oral Rat >2 g/kg -(epichlorhydrin) and epoxy resin (numberaverage molecular weight 2 g/kg -solvent naphtha (petroleum), light arom. LD50 Oral Rat 8400 mg/kg -LD50 Dermal Rabbit 3.48 g/kg -1,2,4-trimethylbenzene LD50 Oral Rat 5 gm/kg -LC50 Inhalation Rat 18000 mg/m3 4 hoursmesitylene LD50 Oral Rat 5000 mg/kg -LC50 Inhalation Rat 24000 mg/m3 4 hoursethanol LD50 Oral Rat 7 gm/kg -xylene (mixture of o-, m-, p-isomers) LD50 Oral Rat 4.3 g/kg -LD50 Dermal Rabbit >1.7 g/kg -LC50 InhalationVaporRat 5000 ppm 4 hoursConclusion/SummaryChronic toxicityConclusion/SummaryDefatting irritant?Target organsCarcinogenicityConclusion/SummaryCarcinogenicityClassification: Not available.: Not available.: Not available.Product/ingredient name ACGIH IARC EPA NIOSH NTP OSHAtalc , not containing asbestiform fibres A4 3 - - - -pitch, coal tar, high-temp. A1 1 - + - -MutagenicityConclusion/SummaryMutagenicityTeratogenicity: Prolonged or repeated contact can defat the skin and lead to irritation, cracking and/ordermatitis.: Contains material which causes damage to the following organs: lungs, brain, upperrespiratory tract, skin, central nervous system (CNS), eye, lens or cornea.Contains material which may cause damage to the following organs: blood, kidneys,bladder, cardiovascular system.: Contains material which can cause cancer. Risk of cancer depends on duration andlevel of exposure.: Not available.: No known significant effects or critical hazards.United States - Canada - MexicoPage: 6/9

Product code UC87162 Date of issue 18 April 2009 VersionProduct name AMERCOAT 78HB BLACK RESIN11 .Toxicological informationConclusion/SummaryTeratogenicityReproductive toxicityConclusion/SummaryDevelopmental effectsFertility effects12 .: Not available.: No known significant effects or critical hazards.: Not available.Ecological informationEnvironmental effectsAquatic ecotoxicity: No known significant effects or critical hazards.: No known significant effects or critical hazards.: No known significant effects or critical hazards.Product/ingredientnameResultSpeciesExposure1,2,4-trimethylbenzene Acute LC50 7720 to 8280 ug/L Fresh Fish - Fathead minnow - Pimephales 96 hourswaterpromelas______________________ _________________________________ ________________________________ __________ethanol Acute LC50 42000 ug/L Fresh water Fish - Rainbow trout,donaldson trout - 4 daysOncorhynchus mykiss_________________________________ ________________________________ __________Acute EC50 2000 ug/L Fresh water Daphnia - Water flea - Daphnia 48 hoursmagna_________________________________ ________________________________ __________Chronic NOEC

Product code UC87162 Date of issue 18 April 2009 VersionProduct name AMERCOAT 78HB BLACK RESIN14 .DOTTransport information1263 Paint3IIIRemarksUSA Only: Can be reclassifiedas Combustible Liquid. Non-Bulk highway shipments (Lessthan or Equal to 450Liters) canbe shipped as non-regulated.6PG* : Packing groupReportable quantity RQ :15 .Regulatory informationUnited States inventory (TSCA 8b) :Australia inventory (AICS)Canada inventory :China inventory (IECSC) :Europe inventory :Japan inventory (ENCS) :Korea inventory (KECI) :New Zealand :Philippines inventory (PICCS) :United StatesU.S. Federal regulationsSARA 313Form R - ReportingrequirementsCanadaWHMIS (Canada)MexicoClassificationCERCLA: Hazardous substances.: pitch, coal tar, high-temp.;::::All components are listed or exempted.All components are listed or exempted.All components are listed or exempted.All components are listed or exempted.All components are listed or exempted.Not determined.All components are listed or exempted.All components are listed or exempted.All components are listed or exempted.TSCA 12(b) annual export notification: No products were found.TSCA 12(b) one-time export: No products were found.SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: talc , not containing asbestiform fibres;pitch, coal tar, high-temp.; 1,2,4-trimethylbenzeneSARA 311/312 MSDS distribution - chemical inventory - hazard identification: talc ,not containing asbestiform fibres: Immediate (acute) health hazard; pitch, coal tar, hightemp.:Delayed (chronic) health hazard; 1,2,4-trimethylbenzene: Fire hazard, Delayed(chronic) health hazardCERCLA: Hazardous substances.: pitch, coal tar, high-temp.;Product name CAS number Concentrationpitch, coal tar, high-temp. 65996-93-2 10 - 301,2,4-trimethylbenzene 95-63-6 1 - 5Class B-3: Combustible liquid with a flash point between 37.8°C (100°F) and 93.3°C(200°F). Class D-2A: Material causing other toxic effects (Very toxic). Class D-2B:Material causing other toxic effects (Toxic).Flammability: 2 Health : 2 Reactivity : 0United States - Canada - MexicoPage: 8/9

Product code UC87162 Date of issue 18 April 2009 VersionProduct name AMERCOAT 78HB BLACK RESIN616 .Other informationHazardous Material Information System (U.S.A.)Health : 2 * Flammability : 2 Physical hazards :( * ) - ChroniceffectsCaution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4representing significant hazards or risks Although HMIS® ratings are not required on MSDSs under 29 CFR1910.1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implementedHMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS®materials may be purchased exclusively from J. J. Keller (800) 327-6868.The customer is responsible for determining the PPE code for this material.National Fire Protection Association (U.S.A.)Health: 2 Flammability : 2 Instability :Date of previous issueOrganization that preparedthe MSDS:No previous validation.: EHSIndicates information that has changed from previously issued version.DisclaimerThe information contained in this data sheet is based on present scientific and technical knowledge. The purpose of thisinformation is to draw attention to the health and safety aspects concerning the products supplied by PPG, and torecommend precautionary measures for the storage and handling of the products. No warranty or guarantee is given inrespect of the properties of the products. No liability can be accepted for any failure to observe the precautionary measuresdescribed in this data sheet or for any misuse of the products.00United States - Canada - MexicoPage: 9/9