MSDS 54KB - Baker Hughes

Region USABaker HughesMaterial Safety Data SheetSection 1. Chemical Product and Company IdentificationProduct NameSupplierMaterial Uses24 HourEmergencyNumbersMAGNACIDE® 575 MICROBIOCIDEBaker Hughes Petrolite12645 W. Airport Blvd. (77478)P.O. Box 5050Sugar Land, TX 77487-5050For Product Information/MSDSs Call: 800-231-3606(8:00 a.m. - 5:00 p.m. cst, Monday - Friday) 281-276-5400Microbiocide.CHEMTREC 800-424-9300 (U.S. 24 hour)Baker Hughes Petrolite 800-231-3606(001)281-276-5400CANUTEC 613-996-6666 (Canada 24 hours)CHEMTREC Int'l 01-703-527-3887 (International 24 hour)CodeXC575Version 4.0Effective Date 4/11/2006Print Date 4/11/2006® a trademark of Baker Hughes, Inc.National Fire ProtectionAssociation (U.S.A.)Health02 1FlammabilityInstabilitySpecific HazardSection 2. Hazards IdentificationPhysical State andAppearanceCERCLA ReportableQuantityHazard SummaryRoutes of ExposureMedical Conditionsaggravated byExposureState: Clear. Liquid., Color: Colorless., Odor:Not applicable.Skin (Contact), Eyes, Inhalation.Pungent.WARNING. May cause chronic effects. May be irritating to eyes, skin and respiratory tract. Maycause skin sensitization (allergic reaction).Potential acute healtheffectsEyes May be severely irritating to the eyes. Prolonged contact may cause burns.Skin May be irritating to skin. Skin sensitizer. May cause allergic skin reactions with repeatedexposure.Inhalation May be irritating to lungs.Ingestion Not considered a likely route of exposure, however, may be toxic if swallowed.See Toxicological Information (section 11)Additional HazardIdentification RemarksExposure to this product may aggravate medical conditions involving the following: liver,gastrointestinal tract, respiratory tract, skin/epithelium, eyes.Not available.Continued on Next Page

MAGNACIDE® 575 MICROBIOCIDE Page: 2/6Section 3. Composition and Information on IngredientsName CAS # % by WeightTetrakis(hydroxymethyl)phosphonium sulfate 55566-30-8 60 - 100See Section 8 for information on permissible exposure limits and threshold limit values.Section 4. First Aid MeasuresEye ContactSkin ContactInhalationIngestionNotes to PhysicianAdditional First AidRemarksImmediately flush the eye(s) continuously with lukewarm, gently flowing water for at least 20-60minutes while holding the eyelid(s) open. Get medical attention immediately.Remove and launder or clean contaminated clothing and shoes. Wash with soap and water forat least 15 minutes or until no evidence of material remains. Get medical attention if irritationoccurs.Remove to fresh air. Oxygen may be administered if breathing is difficult. If not breathing,administer artificial respiration and seek medical attention. Get medical attention if symptomsappear.Get medical attention immediately. If swallowed, do not induce vomiting unless directed to do soby medical personnel. Wash out mouth with water if person is conscious. Never induce vomitingor give anything by mouth to a victim who is unconscious or having convulsions.Not available.Not available.Section 5. Fire Fighting MeasuresFlammability of theProductOSHA FlammabilityClassProducts ofCombustionFire Hazards inPresence of VariousSubstancesFire Fighting Mediaand InstructionsProtective Clothing(Fire)Special Remarks onFire HazardsNot regulated as flammable or combustible.IIIBThese products are carbon oxides (CO, CO2) sulfur oxides (SO2, SO3 etc.) Oxides ofphosphorous. Phosphine.Open Flames/Sparks/Static. Heat.In case of fire, use foam, dry chemicals, or CO2 fire extinguishers. Evacuate area and fight firefrom a safe distance. Water spray may be used to keep fire-exposed containers cool. Keepwater run off out of sewers and public waterways.Do not enter fire area without proper personal protective equipment, including NIOSH approvedself-contained breathing apparatus.Containers may explode (due to the build-up of pressure) when exposed to extreme heat.Section 6. Accidental Release MeasuresSpillPut on appropriate personal protective equipment. Keep personnel removed and upwind of spill.Shut off all ignition sources; no flares, smoking, or flames in hazard area. Approach releasefrom upwind. Shut off leak if it can be done safely. Contain spilled material. Keep out ofwaterways. Dike large spills and use a non-sparking or explosion proof means to transfermaterial to an appropriate container for disposal. For small spills add absorbent (soil may beused in absence of other suitable materials scoop up material and place in a sealed, liquid-proofcontainer. Waste must be disposed of in accordance with federal, state and local environmentalcontrol regulations.Continued on Next Page

MAGNACIDE® 575 MICROBIOCIDE Page: 3/6Other Statements If RQ (Reportable Quantity) is exceeded, report to National Spill Response Office at 1-800-424-8802.Additional AccidentalRelease MeasuresRemarksNot available.Section 7. Handling and StorageHandling and StorageAdditional Handlingand Storage RemarksPut on appropriate personal protective equipment. Avoid contact with eyes, skin and clothing.Avoid breathing vapors or spray mists. Use only with adequate ventilation. Protect from ignition.Store in a dry, cool and well ventilated area. Keep away from incompatibles. Keep containertightly closed and dry.Not available.Section 8. Exposure Controls/Personal ProtectionExposure LimitsTetrakis(hydroxymethyl)phosphonium sulfateACGIH TLV (United States). SkinsensitizerTWA: 2 mg/m 3 8 hour/hours.Additional Informationon Exposure LimitsEngineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations ofvapors or particles below their respective threshold limit value. Ensure that eyewash stations andsafety showers are proximal to the work-station location.Personal ProtectionPersonal Protective Equipment recommendations are based on anticipated known manufacturing and use conditions.These conditions are expected to result in only incidental exposure. A thorough review of the job tasks and conditions by asafety professional is recommended, however, to determine the level of personal protective equipment appropriate for thesejob tasks and conditions.Eyes Chemical safety goggles.Body Wear long sleeves to prevent repeated or prolonged skin contact.Respiratory Respirator use is not expected to be necessary under normal conditions of use. In poorlyventilated areas, emergency situations or if exposure levels are exceeded, use NIOSH approvedfull face respirator.Hands Chemical resistant gloves. Nitrile or Neoprene gloves.Feet Chemical resistant boots or overshoes.Other information Not available.Additional ExposureControl RemarksNot available.Not available.Section 9. Physical and Chemical PropertiesPhysical State andAppearancepHSpecific gravityDensityFlash PointsFlammable LimitsAutoignitionTemperatureContinued on Next PageClear. Liquid.3.1 - 3.3 (Neat - without dilution.)1.363 - 1.375 @ 20°C (68°F)11.35 - 11.45 lbs/gal @ 20°C (68°F)Closed cup: >93.4°C (200°F). (CLOSED CUP)L.E.L. Not available. U.E.L. Not available.Not available.OdorColorPungent.Colorless.

MAGNACIDE® 575 MICROBIOCIDE Page: 4/6Initial Boiling Point Not available.Boiling Point 108°C (226°F)Vapor Density >1 (Air = 1)Vapor PressureEvaporation RateVOCViscosityPour PointSolubility (Water)Physical ChemicalComments16.7 - mm Hg @ 21°C (70°F) Calculated Value for all Components.Not Available or Not Applicable for Solids.Not available.42 - 46 cP @ 25°C (77°F)-43ºC (-45.4ºF) Freezing PointSolubleNot available.Section 10. Stability and ReactivityStability and ReactivityConditions ofInstabilityIncompatibility withVarious SubstancesHazardousDecompositionProductsHazardousPolymerizationSpecial Stability &Reactivity RemarksThe product is stable.Not available.Oxidizing material. Reducing materials. Acid. Alkali.Not applicable.Hazardous polymerization is not expected to occur.Avoid temperatures above 320ºF (160ºC).Section 11. Toxicological informationComponent Toxicological InformationAcute Animal ToxicityTetrakis(hydroxymethyl)phosphonium sulfateORAL (LD50): Acute: 248 mg/kg [Rat].Chronic Toxicity Data1) Tetrakis(hydroxymethyl)phosphonium sulfateTetrakis(hydroxymethyl) phosphonium sulfate ( THPS) is a component of this product. THPS contains a material which hascaused liver damage in rats. An oral dose of 650 mg/kg/13 weeks intermittent produced changes in the liver of rats.THPS caused cell type mutations in mice lymphocytes at a dose of 6 mg/L, and cell type mutations in hamster lung cells at adose of 5000 ppm. THPS caused morphological transformations in mouse embryo cells at 5000 ppm, and in hamsterkidney cells at 5000 ppm.Product Toxicological InformationAcute Animal Toxicity ORAL (LD50): Acute: 575 mg/kg [Rat]. DERMAL (LD50): Acute: >2000 mg/kg [Rabbit].VAPOR (LC50): Acute: 0.59 mg/l 4 hour/hours [Rat].Target Organsliver, gastrointestinal tract, respiratory tract, skin/epithelium, eyes.Other Adverse EffectsNot available.Continued on Next Page

MAGNACIDE® 575 MICROBIOCIDE Page: 5/6Section 12. Ecological InformationEcotoxicityMAGNACIDE® 575MICROBIOCIDEDaphnia magna (LC50)Bluegill sunfish (LC50)Brown shrimp. (LC50)Rainbow trout (LC50)48 hour/hours96 hour/hours96 hour/hours96 hour/hours19.4 mg/l93 mg/l340 mg/l119 mg/lBOD5 and CODNot available.Biodegradable/OECDNot available.Toxicity of the Productsof BiodegradationNot available.Special RemarksAn EcoTox Report, and/or the material's environmental fate is available upon request at thefollowing number: 1-800-235-4249, then press 4.Section 13. Disposal ConsiderationsResponsibility for proper waste disposal rests with the generator of the waste. Dispose of any waste material in accordancewith all applicable federal, state and local regulations. Note that these regulations may also apply to empty containers, linersand rinsate. Processing, use, dilution or contamination of this product may cause its physical and chemical properties tochange.Additional WasteRemarksNot available.Section 14. Transport InformationDOT ClassificationTOXIC LIQUID, ORGANIC, N. O. S. (Contains: Tetrakis(hydroxymethyl)phosphonium sulfate), 6.1, UN2810, IIIPOISON6DOT ReportableQuantityMarine PollutantAdditional DOTInformationEmergency ResponseGuide Page NumberNot applicable.Not applicable.When MAGNACIDE 575 MICROBIOCIDE is shipped in boxes (Code XC575-40), it ships underthe DOT Limited Quantity Exemption.153Section 15. Regulatory InformationHCS ClassificationU.S. FederalRegulationsEnvironmentalRegulationsTarget organ effects. Irritant. Sensitizer. Toxic.Extremely Hazardous Substances: Not applicable to any components in this product.SARA 313 Toxic Chemical Notification and Release Reporting: Not applicable to any componentsin this product.SARA 302/304 Emergency Planning and Notification substances: Not applicable to anycomponents in this product.Hazardous Substances (CERCLA 302): Not applicable to any components in this product.SARA 311/312 MSDS distribution - chemical inventory - hazard identification: immediate healthhazard;Continued on Next Page

MAGNACIDE® 575 MICROBIOCIDE Page: 6/6ThresholdPlanningQuantity (TPQ)TSCA InventoryStatusClean Water Act (CWA) 307 Priority Pollutants: Not applicable to any components in this product.Clean Water Act (CWA) 311 Hazardous Substances: Not applicable to any components in thisproduct.Clean Air Act (CAA) 112(r) Accidental Release Prevention Substances: Not applicable to anycomponents in this product.Not applicable.All components are included or are exempted from listing on the US Toxic Substances ControlAct Inventory.This product does not contain any components that are subject to the reporting requirements ofTSCA Section 12(b) if exported from the United States.State RegulationsInternationalRegulationsCanadaWHMIS (Canada) D-1B, D-2BState specific information is available upon request from Baker Petrolite.All components are compliant with or are exempted from listing on the Canadian DomesticSubstance List.European UnionOther RegulatoryInformationAll components are included or are exempted from listing on the European Inventory of ExistingCommercial Chemical Substances or the European List of Notified Chemical Substances.International inventory status information is available upon request from Baker Petrolite for thefollowing countries: Australia, China, Korea (TCCL), Philippines (RA6969), or Japan.This product is subject to regulation under the US Federal Insecticide, Fungicide and RodenticideACT (FIFRA) and is therefore exempt from US Toxic Substance Control Act (TSCA) Inventorylisting requirements. EPA Registration No. 33677-7-10707.Section 16. Other InformationOther SpecialConsiderationsFile 142810/14/03 - Changes to Sections 1, 3, 5, 8, 9, 11, 12 and 15.06/21/05 - Changes to Sections 2, 3, 5, 8, 9 and 15.04/11/06 - Changes to Sections 2, 5, 9, 10, 11, 12, 14, and 15In April, 2005, a number of format changes were made. The most notable of these were switching Sections 2and 3, moving the exposure limits to Section 8, and moving the flash point from Section 5 to Section 9.Baker Hughes DisclaimerNOTE: The information on this MSDS is based on data which is considered to be accurate. Baker Petrolite, however,makes no guarantees or warranty, either expressed or implied of the accuracy or completeness of this information.The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may bebeyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability forloss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of thisproduct.This MSDS was prepared and is to be used for this product. If the product is used as a component in another product,this MSDS information may not be applicable.