CO-NH2 CO-NH2 â€žâ€žCO-NH2 CO-NH2

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R 7.1 CO-NH2 7.12 „ CO-NH2 7.13 CO-NH2 „ 7.14 „ CO-NH2 7.15 CO-NH2 ? 7.16 CO-NH2 747 •>•> CO-NH2 7.19 7.18 CO-NH2 CO-NH2 7.21 7.20 „ CO~NH2 CO-NH2 7.2 CO-NH2 7.23 CO-NH2 7.24 „ CO-NH2 TABLE IV—continued a P NAA' Formula H „„ H NC5H10 „, „ (b) C21H26N2O CH3 H„„H HNC4H8O , (d) „ C21H26N2O2 CH3 „„ NC4H8O (d) C21H26N2O2 „ H „ NC2HBz-CsH7 C21H28N2O „ H N(C2H5)2 C21N28N2O , „ H CH3N(C2H5)2 C21H2SN2O „HHH„„ H „ NC4H6-(CH3)2(o) C2H28N2O HH„„HHHH„ NC4H6(CH3)2 (p) NC5H9-CH3 (f) C2H28N2O n C,2H28N2O H „ „ NC5H9-CH3 HH (q) „ NC5H9-CH3 (r) NC6H12 (g) C2H.28N2O C2H28N2O CH3 NC5H10 H „ (b) C2H28N2O C2H28N2O CH3NC5H10 (b) C2H28N2O Base Salts Ref. m — 178-9 CH3Br 216; — -> O 167-5-8-5 dl\ m m 176-7 HC1 206-7-5 480 340 * d\ m 78-82 143-4 dec. ——— m 140-2 31,32 31, 32 * 15 C2H5Br m 135-7 89-91 159-62; /-C3H7Br 234, 235 —_—— 62 m 134-7-5 O5 161-5-3 628* i m 164-5 153-8 i H2SO4 m 129-31 -> O 173-4; 146-5-8 CH3Br 231-3; m 165-6-5 HC1 222-4; CH3Br 231-5 46 340 C7H7SO3-CH3 — 164-6 CH3C125-8; CH3130 170-6 3408 ml29 HC1 208-10; CH3Br 209-10 234, m!80 — 340 235 m 140-1 CH3I 228-32 m 155-7 CH3I 213-5-5 234, 234, 235 * 235 m 158-5-60 153-3-5 62 m 156-7 — * — 35Og 62,88
7.26 7.27 7.28 7.29 7.30 7.31 7.32 7.33 7.34 7.35 7.36 7.37 8.1 8.2 8.3 8.4 CO-NH_ CO-NH2 CO-NH2 CO-NH2 CO-NH2 CO-NH2 » CO-NH2 CO-NH2 CO-NH2 CO-NH2 CO-NH2 CO-NH2 CO-NH2 COOH „ COO-Ag COO-Ag COOH » H H H H H H » H CH3 H H H H H H „ CH3 H CH3 » H H H J9 H H H » H H CH3 H H H H H „ H CH3 H » NQHbO\CH3J, (s) N(«-C3H7)2 N(/-C8H7)a NCHs-CeHi! NC4H5(CH3)3 (v) NC5H8(CH3)2 (h) » NC7H14 NC4H6(CH3)2 (o) NC4H6(CH3)2 (o) N(/i-C4H9)2 N(z-C4H9)2 NC9H16 (x) N2CnH15 (y) N(CH3)2 5 ,, N(CH3)2 N(CH3)2 N(CH3)2 C-2H:5N2O, C22H30N2O C22H30N2O C23H30N2O C23H30N2O C23H30N2O » C23H30N2O C23H30N2O C23H30N2O C24H34N2O C24H34N9O C25H32N2O C27H31N3O C18H21NO2 5 „ C19H22AgNO2 Q9H22AgNO2 C19H23NO2 m l~5-6 — m 102-3 m84-6 — ml27 m 124-6 m 129-32 m 119-22 m91-5 — — — m 93-5-5 m 169-5-72 m71-2 m 197-8 dec. m 201-2 — — m 176-8 — CH3I ZOZ-A C2H2O4 120 — CH3Br 237; CH3C1 238; CH3I 198-201; (CH3)2 SO4, 170; C2H5Br 89-91 ;/-C3H7Br 95-105 H2SO4 178-80 — HCl 221-3; CH3Br 225-6 HCl 222-4; CH3Br 231-5 CH3I 235-6 CH3I 168-78 dec. — — CH3I± 220 dec; li C2H2O4 133-5 CH3I 163-5 HCl 212-5-4-5; CH3Br 200-2 — HBr 237-9 dec. — — — — HCl 205-8 H2SO4 137-43 234, 235 234, 235 340 234, 235 340 340 466 466 * 340 49 126 166 166 166 3 Z w 02
Page 1 and 2: S Y N T H E T I C A N A L G E S I C
Page 3: C o n t e n t s Page Preface . . .
Page 7 and 8: I n t r o d u c t i o n THE main pu
Page 9 and 10: 15. 16. 17. 18. 19. 20. 21. CONH2 C
Page 11 and 12: CHAPTER I A n a l g e s i c " Activ
Page 13 and 14: CHAPTER II T h e " A n a l g e s i
Page 15 and 16: METHADONE, MORPHINE, PETHIDINE AND
Page 17 and 18: Symbol ED50 ED50 ED50 ED50 ED50 ED5
Page 19 and 20: CHAPTER III 3 : 3 - D i p h e n y l
Page 21 and 22: o .s HI S T oo HJ * 3 :3-DIPHENYLPR
Page 23 and 24: 2.1 2.2 2.3 2.4 2.5 2.6 OH „ OH O
Page 25 and 26: 2.15 2.16 2.17 2.18 2.19 2.20 2.21
Page 27 and 28: 3.15 4.1 4.2 4.3 4.4 4.5 4.6 4-7 5.
Page 29 and 30: 5.4 5.5 „ 55 » „ CN CN „ „
Page 31 and 32: 5.14 5.15 5.16 5.17 5.18 5.19 5.20
Page 33 and 34: 5.35 5.36 5.37 5.38 5.39 5.40 5.41
Page 35 and 36: 6.9 6.10 6.11 6.12 6.13 6.14 6.15 6
Page 37 and 38: 6.46 6.47 6.48 6.49 6.50 6.51 6.52
Page 39: 7.4 7.5 7.6 7.7 7.8 7.9 7.10 7.11 C
Page 43 and 44: 8,15 8.16 8.17 9.1 9.2 9.3 9.4 9.5
Page 45 and 46: 10.4 1 _ CONi,CH3j, 2 H" HH N CK- N
Page 47 and 48: 10.47 10.48 10.49 10.50 10.51 10.52
Page 49 and 50: 11.15 COOC-H5 11.14 COOCHg 11.15 11
Page 51 and 52: 13.9 13.10 13.11 CH-C.H5OOC- CH3
Page 53 and 54: 13.13 13.24 13.25 13.26 13.27 13.28
Page 55 and 56: 1-*»1Z c c.:-:f XH 14.13 14.14 14.
Page 57 and 58: 14.56 14.37 14.38 14.39 COCH; COCH3
Page 59 and 60: •> 5 5? 5 5 55 M » I n 5 w 5? )?
Page 61 and 62: 14.49 14.50 14.51 14.52 14.53 14.54
Page 63 and 64: 14.66 14.67 14.68 14.69 14.70 14.71
Page 65 and 66: 14.9" CO-C£H£ 14.98 14.99 14.100
Page 67 and 68: 16.13 16.14 17.1 17.2 17.3 17.4 17.
Page 69 and 70: ti 1.1 1.2 1.3 1.4 1.5 1.6 1.7 1.8
Page 71 and 72: 2.4 2.5 2.6 2.7 2.8 2.9 2.13 2.14 2
Page 73 and 74: 3.5 3.7 4.1 4.3 4.4 4.5 4.7 5.1 5.2
Page 75 and 76: 5.53 5.59 6.1 6.4 6.8 6.9 6.14 6.18
Page 77 and 78: 3:3-DIPHENYLPROPYLAMINES 71 flo****
Page 79 and 80: 9.19 9.20 9.21 9.22 9.23 9.26 9.27
Page 81 and 82: 10.22 10.23 10.24 10.25 10.26 10.30
Page 83 and 84: 10.42 10.43 10.59 10.60 10.61 10.62
Page 85 and 86: 11.7 11.8 11.9 11.10 11.11 11.12 11
Page 87 and 88: „ — R- 13.10 — CF RT R- CF CF
Page 89 and 90: 13.24 13.25 13.27 13.31 13.33 13,35
Page 91 and 92:
14.36 14.37 14.38 14.39 „ RT RT R
Page 93 and 94:
CF RT CF RT ET RB •>•> PRT ET R
Page 95 and 96:
14.41 14.42 14.43 14.44 RB — CF ,
Page 97 and 98:
14.54 14.55 14.56 14.57 14.58 14.59
Page 99 and 100:
14.76 14.77 14.78 14.82 14.83 14.84
Page 101 and 102:
If o ^ 1.1 1.4 1.5 1.6 1.8 1.9 1.10
Page 103 and 104:
3.3 3.4 5.1 5.2 5.3 — — — —
Page 105 and 106:
5.6 5.9 5.12 5.13 5.17 5.27 5.32 5.
Page 107 and 108:
8.8 10.2 10.41 10.43 11.4 11.6 11.9
Page 109 and 110:
14.40 8-99 10-12 d-nci /-base /-bas
Page 111 and 112:
X 14.57 14.64 14.65 14.66 14.69 14.
Page 113 and 114:
Continued from p. 13 3 :3-DIPHENYLP
Page 115 and 116:
3:3-DIPHENYLPROPYLAMINES 109 antisp
Page 117 and 118:
TERTIARY ALCOHOLS 111 halide with a
Page 119 and 120:
TERTIARY ALCOHOLS 113 Tertiary alco
Page 121 and 122:
CHAPTER V S e c o n d a r y A l c o
Page 123 and 124:
5-3 SECONDARY ALCOHOLS 117 C2H5 r n
Page 125 and 126:
SECONDARY ALCOHOLS 119 In the wo-se
Page 127 and 128:
PRIMARY ALCOHOLS reduced (PtO-CH3OH
Page 129 and 130:
NITRILES 123 Basic propyl- and wopr
Page 131 and 132:
NITRILES 125 The following elegant
Page 133 and 134:
NITRILES 127 Nitriles of type [7.1]
Page 135 and 136:
CHAPTER VIII D i a m i n e s a n d
Page 137 and 138:
DIAMINES AND DERIVATIVES 131 Only o
Page 139 and 140:
PRIMARY AMIDES ^ ^NH—CH—CH—N'
Page 141 and 142:
PRIMARY AMIDES 135 Quaternization b
Page 143 and 144:
ACIDS AND ACID CHLORIDES 137 When h
Page 145 and 146:
CHAPTER XI S e c o n d a r y A m i
Page 147 and 148:
CHAPTER XII R 8 7 5 a n d R e l a t
Page 149 and 150:
TERTIARY AMIDES 143 The relation be
Page 151 and 152:
TERTIARY AMIDES 145 (1) In man R 87
Page 153 and 154:
ESTERS DERIVED FROM AMINO ACIDS 147
Page 155 and 156:
ESTERS DERIVED FROM AMINO ACIDS 149
Page 157 and 158:
CHAPTER XV Esters derived f r o m S
Page 159 and 160:
Nomenclature of derived isomers Mel
Page 161 and 162:
CHAPTER XVI K e t i m i n e s , A c
Page 163 and 164:
NAA'* N(CH3)2 „ 55 ?? ?5 *s 5 N(C
Page 165 and 166:
KETIMINES, ACYL KETIMINES AND KETON
Page 167 and 168:
CHAPTER XVIII S u l p h o n e s (I:
Page 169 and 170:
SULPHONES 163 According to KLENK et
Page 171 and 172:
OTHER COMPOUNDS OF STRUCTURE (I) 16
Page 173 and 174:
DISSOCIATION CONSTANTS Steric facto
Page 175 and 176:
R CONFIGURATIONAL STUDIES TABLE XVI
Page 177 and 178:
REFERENCES 1 ADAMI E. and MARAZZI E
Page 179 and 180:
REFERENCES 173 89 CHEN K. K. (1948)
Page 181 and 182:
REFERENCES 175 163 FRIEBEL H. and R
Page 183 and 184:
REFERENCES 177 249 KEATS A. S. and
Page 185 and 186:
REFERENCES 179 339 MOFFETT R. B. (1
Page 187 and 188:
REFERENCES 181 411 SCHULTZ E. M., R
Page 189:
REFERENCES 183 499 WHEATLEY W. B.,
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CO-NH2 CO-NH2 â€žâ€žCO-NH2 CO-NH2

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