3 Irreducible tensor operator techniques <strong>in</strong> atomic spectroscopy 42which is equivalent for several schemes with [λ] = [2 3 ], κ = 1, 2 and [λ] = [2 2 1 2 ], κ = 1, 2, 3.ThenT [22 1 2 ] τ 6 12 T [22 1 2 ]≡∑ɛ46 Ôβ α ([2 2 1 2 ]12), Υ\Υ 6 = {12},α η∈Υ\Υ6T [22 1 2 ]4p ′ 23(̂π 23 T ) [22 1 2 ]4≡ ∑ α 12ϖ 23 ɛ 6 Ô α β ([2 2 1 2 ]12),(̂π 23 T ) [22 1 2 ]4(̂π 23 T ) [22 1 2 ]12(̂π 23 T ) [λ]κ(̂π 234 T ) [λ]κτ −16(̂π 23 T ) [22 1 2 ]12τ ξp ′ 24τ −1ξ≡ ∑ α 12 (̂π 23 T ) κ [λ] ≡ ∑(̂π 234 T ) [λ]κ ≡ ∑(̂π 234 T ) [22 1 2 ]12∑α η∈bπ23 (Υ 6 \Υ)∑α 12 α 23 α η∈bπ23 (Υ\Υ ξ )∑α 12 α 23 α η∈bπ23 (Υ\Υ ξ )≡∑α 12 α 23∑ϖ 23 ɛ 6 ɛ (23)(6) Ô α β ([2 2 1 2 ]12), Υ 6 \Υ = {23},ϖ 23 ɛ 6 ɛ (23)(6) ɛ (23)(ξ) Ô α β ([2 2 1 2 ]12),ϖ 23 ϖ 24 ɛ 6 ɛ (23)(6) ɛ (23)(ξ) Ô α β ([2 2 1 2 ]12),α η∈Aξϖ 23 ϖ 24 ɛ 6 ɛ (23)(6) ɛ (23)(ξ) ɛ (234)(ξ) Ô α β ([2 2 1 2 ]12),(̂π 234 T ) [22 1 2 ]12τ 6 (̂π 234 T ) [22 1 2 ]4≡= ( (̂π 23 (Υ\Υ ξ )) ⋃ (̂π 234 (Υ ξ \Υ)) ) ,∑ ∑ ∑ϖ 23 ϖ 24 ɛ 6 ɛ (23)(6) ɛ (23)(ξ) ɛ (234)(ξ)A ξdefα 12 α 23 α η∈Aξ α η ′ ∈bπ234 (Υ\Υ 6 )(̂π 234 T ) [22 1 2 ]4(̂π 24 T ) [22 1 2 ]4p ′ 34(̂π 24 T ) [22 1 2 ]4τ −16(̂π 24 T ) [22 1 2 ]12≡× ɛ (234)(6) Ô α β ([2 2 1 2 ]12),∑α 12 α 23 α 13∑α η∈Aξϖ 23 ϖ 24 ϖ 34 ɛ 6 ɛ (23)(6) ɛ (23)(ξ) ɛ (234)(ξ)× ɛ (234)(6) Ôβ α ([2 2 1 2 ]12),≡∑ ∑ ∑α 12 α 23 α 13 α η∈Aξ α η ′ ∈bπ24 (Υ 6 \Υ)ϖ 23 ϖ 24 ϖ 34 ɛ 6 ɛ (23)(6) ɛ (23)(ξ)Thus× ɛ (234)(ξ) ɛ (234)(6) ɛ (24)(6) Ôβ α ([2 2 1 2 ]12).ε 24 =∑ ∑f 24 ɛ 6 ɛ (23)(6) ɛ (23)(ξ) ɛ (234)(ξ) ɛ (234)(6) ɛ (24)(6) , (3.35)α 13 α 23 α 34 α η∈Aξ \Υwhere the multiplier f ij denotes the follow<strong>in</strong>g productdeff ij =j−i∏k=1j−i−1∏l=1ϖ i i+k ϖ i+l j . (3.36)Other coefficients ε i i+2 are found from the commutative diagrams with ν s = ν 2 = 5 so thatp ′ tu ◦ τ −1ξ◦ p ′ i i+2 ◦ τ ξ ◦ p ′ rs = p i i+2 . A composition is realised for the numbers r, s, t, u such that̂π i i+2 = ̂π tûπ i i+2̂π rs . It is to be whether (rs) = (i i + 1), (tu) = (i + 1 i + 2) or (tu) = (i i + 1),(rs) = (i + 1 i + 2). Then
3 Irreducible tensor operator techniques <strong>in</strong> atomic spectroscopy 43ε i i+2 =∑α η∈Bξ \Υf i i+2 ɛ (i i+1)(ξ) ɛ (i i+1 i+2)(ξ) , i = 1, 4, (3.37)B ξdef= (̂π i i+1 (Υ\Υ ξ ) ) ⋃(̂πi i+1 i+2 (Υ ξ \Υ) ) . (3.38)ε 35 =∑f 35 ɛ (45)(ξ) ɛ (354)(ξ) , (3.39)α η∈B ′ξ\ΥB ξ′ def= (̂π i+1 i+2 (Υ\Υ ξ ) ) ⋃(̂πi i+2 i+1 (Υ ξ \Υ) ) , i = 3. (3.40)For i = 1, ξ = 6; for i = 3, ξ ∈ {1, 2, . . . , 5}; for i = 4, ξ = 19.The coefficients ε i i+3 are characterised by the commutative diagrams with ν s = ν 5 = 11 sothatp 14 =p ′ 24 ◦ τ6 −1 ◦ p ′ 34 ◦ τ 6 ◦ τ −1ξ◦ p ′ 14 ◦ τ ξ ◦ τ6 −1 ◦ p ′ 13 ◦ τ 6 ◦ p ′ 12, ξ ∈ {1, 2, . . . , 5}, (3.41a)p 25 =p ′ 24 ◦ τ6 −1 ◦ p ′ 35 ◦ τ 6 ◦ τ −1ξp 36 =τ19 −1 ◦ p ′ 35 ◦ τ 19 ◦ p ′ 34 ◦ τ −1ξFrom these diagrams it follows thatε 14 =∑ ∑f 14 ɛ (12)(6) ɛ (123)(6) ɛ (123)(ξ) ɛ (1234)(ξ) ɛ (1234)(6) ɛ (124)(6) ,ε 25 =α 13 α 23 α 34 α η∈Cξ \Υ∑∑α 13 α 23 α 35 α η∈C ′ \Υ ξ◦ p ′ 25 ◦ τ ξ ◦ τ −16 ◦ p ′ 23 ◦ τ 6 ◦ p ′ 45, ξ ∈ {1, 2, . . . , 5}, (3.41b)◦ p ′ 36 ◦ τ ξ ◦ p ′ 46 ◦ τ −119 ◦ p ′ 56 ◦ τ 19 , ξ ∈ {1, 2}. (3.41c)f 25 ɛ (45)(6) ɛ (23)(45)(6) ɛ (23)(45)(ξ) ɛ (2354)(ξ) ɛ (2354)(6) ɛ (254)(6) ,(3.42a)(3.42b)ε 36 =∑ ∑f 36 ɛ 19 ɛ (56)(19) ɛ (465)(ξ) ɛ (3654)(ξ) ɛ (365)(19) ɛ (36)(19) ,(3.42c)α 34 α 35 α 56 α η∈C ′′ξ \Υdefwhere C ξ = (̂π 123 (Υ\Υ ξ ) ) ⋃(̂π 1234 (Υ ξ \Υ) ) , C ξ′ def= (̂π 23̂π 45 (Υ\Υ ξ ) ) ⋃(̂π 2354 (Υ ξ \Υ) ) andC ξ′′ def= (̂π 465 (Υ\Υ ξ ) ) ⋃(̂π 3654 (Υ ξ \Υ) ) .The advantage <strong>of</strong> method <strong>of</strong> commutative diagrams as a language <strong>of</strong> comb<strong>in</strong>atorial computationappears to be evident especially <strong>in</strong> the cases j = i + 4, i + 5. The coefficients ε 15 , ε 26 , ε 16can be found from the commutative diagrams with ν s = ν 6 = 13 for j = i+4 and ν s = ν 7 = 15for j = i + 5. That is,p 15 =p ′ 25 ◦ p ′ 14 ◦ τ6 −1 ◦ p ′ 35 ◦ τ 6 ◦ τ −1ξ◦ p ′ 15 ◦ τ ξ ◦ τ6 −1 ◦ p ′ 45 ◦ p ′ 13 ◦ τ 6 ◦ p ′ 12, (3.43a)p 26 =τ −122 ◦ p ′ 25 ◦ p ′ 36 ◦ τ 22 ◦ p ′ 24 ◦ τ −1ξ◦ p ′ 26 ◦ τ ξ ◦ p ′ 46 ◦ τ −122 ◦ p ′ 56 ◦ p ′ 23 ◦ τ 22 , (3.43b)p 16 =p ′ 26 ◦ τ22 −1 ◦ p ′ 15 ◦ p ′ 36 ◦ τ 22 ◦ p ′ 14 ◦ τ −1ξ◦ p ′ 16 ◦ τ ξ ◦ p ′ 46 ◦ τ22 −1 ◦ p ′ 56 ◦ p ′ 13◦ τ 22 ◦ p ′ 12,where ξ ∈ {1, 2, . . . , 5}. The correspond<strong>in</strong>g coefficients areε 15 =∑ ∑f 15 ɛ (12)(6) ɛ (123)(45)(6) ɛ (123)(45)(ξ) ɛ (12354)(ξ) ɛ (12354)(6) ɛ (1254)(6) ,ε 26 =ε 16 =α 13 α 23 α 35 α η∈Dξ \Υ∑∑α 13 α 23 α 24 αα 25 α 36 α η∈D ′ \Υ56 ξ∑∑α 13 α 14 α 15 αα 23 α 36 α η∈Eξ \Υ56f 26 ɛ 22 ɛ (23)(56)(22) ɛ (23)(465)(ξ) ɛ (23654)(ξ) ɛ (2365)(22) ɛ (26)(22) ,f 16 ɛ (12)(22) ɛ (123)(56)(22) ɛ (123)(465)(ξ) ɛ (123654)(ξ) ɛ (12365)(22) ɛ (126)(22)(3.43c)(3.44a)(3.44b)(3.44c)defwith D ξ = (̂π 123̂π 45 (Υ\Υ ξ ) ⋃(̂π 12354 (Υ ξ \Υ) ) , D ξ′ def= (̂π 23̂π 465 (Υ\Υ ξ ) ) ⋃(̂π 23654 (Υ ξ \Υ) )defand E ξ = (̂π 123̂π 465 (Υ\Υ ξ ) ) ⋃(̂π 123654 (Υ ξ \Υ) ) .In [80, Tab. 3], the coefficients ε 26 and ε 16 have been found to be obta<strong>in</strong>ed from the expressions