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COSHH Liquid Weld - Polypipe

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Safety Data Sheet<strong>Liquid</strong> <strong>Weld</strong> Cement Issue 25.11.101. Identification of the Substance/Preparation and the Company UndertakingProduct NameSupplier<strong>Polypipe</strong> Terrain <strong>Liquid</strong> <strong>Weld</strong><strong>Polypipe</strong> TerrainCollege RoadNew Hythe Business ParkAylesfordKentME20 7PJTel: 01622 795200Emergency Telephone Tel. 01622 795200ApplicationAdhesive2. Hazard IdentificationHazard DescriptionIrritantHighly FlammableInformation concerning particular hazards to man and environmentRepeated exposure may cause skin dryness or crackingVapours may cause drowsiness and dizzinessIrritating to eyesVapours are heavier than air and can travel long distances to a source of ignitionClassification SystemR11 Highly FlammableR36 Irritating to eyesR66 Repeated exposure may cause skin dryness or crackingR67 Vapours may cause drowsiness and dizziness3. Composition/Information on IngredientsNameEINECS CAS-No. Content Classification Risk Phrase(s)No.Butanone 201-159-0 78-93-3 60-100% Xi, F R11, R36, R66, R67Tetrahydrofuran 203-726-8 109-99-9 5-10% Xi, F R11, R19, R36/37Cyclohexanone 203-631-1 108-94-1 1-5% Xn R10, R20Bisphenol A-Epichlorohydrin EpoxyResin (Number AV MW


Safety Data Sheet<strong>Liquid</strong> <strong>Weld</strong> Cement Issue 25.11.104. First Aid MeasuresIn the event of exposure by inhalationRemove victim from source of exposureMove the exposed person to fresh air at onceGet medical attentionIn the event of splashes or contact with eyesRinse the eye with water immediatelyContinue to rinse for 15 minutes and get medical attentionIn the event of splashes or contact with skinPromptly flush contaminated skin with waterPromptly remove clothing if soaked through and flush skin with waterWash skin with soap and waterGet medical attention if irritation persists after washingIn the event of swallowingDO NOT induce vomitingGet medical attention immediately5. Fire Fighting MeasuresExtinguishing MediaExtinguish with Powder or FoamUnusual Fire and Explosion HazardsGenerates massive smoke during fireVapours are heavier than air and may spread near ground to source of ignitionHIGHLY FLAMMABLERisk of explosion in closed containers if pressure rises rapidlySolvent vapours may form explosive mixtures with airSpecific HazardsToxic gases/vapours/fumes of Caron dioxide (CO2), Carbon monoxide (CO)Special Protective Equipment for Fire FightersSelf contained breathing apparatus and full protective clothing must be worn in case of fire6. Accidental Release MeasuresPersonal PrecautionsAvoid contact with skin and eyesProvide adequate ventilationWear protective clothing as described in section 8 of this safety sheetEnvironmental PrecautionsPrevent entry to drainsAvoid discharge into water courses or onto the groundMSDS 450.2 Page 2 of 8


Safety Data Sheet<strong>Liquid</strong> <strong>Weld</strong> Cement Issue 25.11.106. Accidental Release Measures (continued)Methods for Cleaning upExtinguish all ignition sourcesAvoid sparks, flames, heat and smokingVentilateRunoff or release to sewer, waterway or ground is forbiddenAbsorb with sand or other inert absorbentCollect with absorbent, non-combustible material into suitable containersContainers with collected spillage must be properly labelled with correct contents and hazardsymbols7. Handling and StorageUsage PrecautionsKeep away from heat, sparks and open flameAvoid spilling, skin and eye contactVentilate well, avoid breathing vapoursUse approved respirator if air contamination is above accepted levelStorage PrecautionsFlammable/combustible – Keep away from oxidisers, heat and flamesGround containers and transfer equipment to eliminate static electric sparksStore at a moderate temperature in dry, well ventilated areaStorage ClassFlammable liquid storage8. Exposure Control/Personal ProtectionExposure Limit ValuesName Std TWA – 8 hrs STEL – 15 minButanone WEL 200 ppm(Sk) 600 mg/m³(Sk) 300 ppm(Sk) 899 mg/m³(Sk)Tetrahydrofuran WEL 50 ppm(Sk) 100 ppm(Sk)Cyclohexanone WEL 10 ppm(Sk) 20 ppm(Sk)WEL = Workplace Exposure LimitProtective Equipment`Engineering EquipmentExplosion-proof general and local exhaust ventilationMSDS 450.2 Page 3 of 8


Safety Data Sheet<strong>Liquid</strong> <strong>Weld</strong> Cement Issue 25.11.108. Exposure Control/Personal Protection (continued)Respiratory EquipmentRespiratory equipment must be used if air contamination exceeds acceptable levelWear mask supplied with: Gas cartridge suitable for organic substancesHand ProtectionProtective gloves must be worn if there is a risk of direct contact or splash.Use protective gloves made of: Nitrile.Use thin cotton gloves inside rubber gloves if allergy riskEye ProtectionWear splash-proof goggles to prevent any possibility of eye contactOther ProtectionWear appropriate clothing to prevent repeated or prolonged skin contactHygiene MeasuresDO NOT SMOKE IN THE WORK AREA!Wash promptly if skin becomes contaminatedWash at the end of each work shift and before eating, smoking and using the toiletUse appropriate skin cream to prevent drying of skin9. Physical and Chemical PropertiesAppearanceColourOdourBoling Point (ºC)Flash Point (ºC)Thixotropic <strong>Liquid</strong>ColourlessOrganic Solvent65ºC 760 mm Hgminus 14ºC CC (Closed Cup)Relative Density 0.9 @ 20ºC10. Stability and ReactivityStabilityAvoid: Heat, sparks, flamesMaterials to avoidStrong oxidising substancesHazardous decomposition productsFire or high temperatures create: Carbon Dioxide (CO2), Carbon Monoxide (CO)MSDS 450.2 Page 4 of 8


Safety Data Sheet<strong>Liquid</strong> <strong>Weld</strong> Cement Issue 25.11.1011. Toxicological InformationInhalationDrowsiness, dizziness, disorientation, vertigoGas or vapour may irritate respiratory systemIngestionPneumonia may be the result if vomited material containing solvents reaches the lungsSkin ContactProlonged contact may cause dryness of the skinMay cause skin irritation/eczemaEye ContactIrritating to eyes. Irritation, burning, lachrymation, blurred vision after liquid splashHeath WarningDefats the skin. Prolonged or repeated exposure may cause severe irritationMedical ConsiderationsSkin disorders and allergies12. Ecological InformationEcotoxicityNot regarded as dangerous for the environment. However, contamination of the aquaticor terrestrial environments should be avoided13. Disposal ConsiderationsGeneral InformationWaste is classified as hazardous wasteDisposal to licensed waste disposal site in accordance with local Waste DisposalAuthorityDisposal MethodsDispose of waste and residues in accordance with local authority requirements.Do not allow runoff to sewer, waterway or groundRecover and reclaim or recycle, if practicalWaste ClassClassified as Special Waste. Not permitted for landfill in liquid stateMSDS 450.2 Page 5 of 8


Safety Data Sheet<strong>Liquid</strong> <strong>Weld</strong> Cement Issue 25.11.1014. Transport Information.UK Road Class 3Proper Shipping NameADHESIVEUN No. Road 1133 UK Road Pack GR. IIIADR Class No 3 ADR Class Class 3 FlammableliquidsADR Pack Group III Tunnel RestrictionCode(D/E)Hazard No. (ADR) 30 ADR Label No. 3HAZCHEM Code 3YE CEFIC Tec(R) No. 30GF1-III, 30GF1-spRID Class No. 3 RID Pack Group IIIUN No. Sea 1133 IMDG Class 3IMDG Pack Gr. III EMS F-E, S-DMFAG See Guide UN No. Air 1133Air Class 3 Air Pack Gr. III15. Regulatory InformationLabellingIrritantHighly FlammableMSDS 450.2 Page 6 of 8


Safety Data Sheet<strong>Liquid</strong> <strong>Weld</strong> Cement Issue 25.11.1015. Regulatory Information (continued)Risk PhrasesR11R36R66R67Highly FlammableIrritating to eyesRepeated exposure may cause skin dryness or crackingVapours may cause drowsiness and dizzinessSafety PhrasesS16S26S36/37/39S46S51S56P5P14Keep away from sources of ignitionIn case of contact with eyes, rinse immediately with plenty ofwater and seek medical adviceWear suitable protective clothing, gloves and eye/face protectionIf swallowed, seek medical advice immediately and show thiscontainer or labelUse only in well-ventilated areasDispose of this material and its container to hazardous or specialwaste collection pointContains epoxy constituents. See information supplied bymanufacturerContains BISPHENOL A –EPICHLOROHYDRIN EPOXY RESIN(number AV MW


Safety Data Sheet<strong>Liquid</strong> <strong>Weld</strong> Cement Issue 25.11.1016. Other InformationSince the users working conditions are not known by us, the information supplied on this safetysheet is based on our current level of knowledge and on National and community regulations.The product must not be used for any purpose other than those specified under heading 1 withoutfirst obtaining written handling instructions.It is at all times the responsibility of the user to take all necessary measures to comply with legalrequirements and local regulations.The information given on this safety data sheet must be regarded as a description of the safetyrequirements relating to our product and not a guarantee of its properties.MSDS 450.2 Page 8 of 8

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