MSDS - CEREC Optispray

MATERIAL SAFETY DATA SHEETacc. to ISO/DIS 11014Date-Issued: 2007/12/24Revision No.: 02Coating-Spray1. PRODUCT AND COMPANY IDENTIFICATIONPRODUCT NAME: CEREC OptisprayPRODUCT DESCRIPTION: powder spray for CAD/CAM restorations.MANUFACTURER’S NAME:Sirona Dental Systems GmbHFabrikstrasse 31D-64625 BensheimGermanywww.sirona.comEMERGENCY TELEPHONE NUMBERS:Advice centre for poisoning university Mainz phone +49(0)6131/19240or poison information: +49(0)700/GIFTINFO2. COMPOSITION/INFORMATION ON INGREDIENTSCHEMICAL C.A.S. NUMBER Weight %1,1,1,2,3,3,3-Heptafluoropropane 431-89-0 85-95Ethanole 64-17-5 1-2n-Pentane 109-66-0 5-8OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200):Exposure Limits 8 Hours TWA (PPM)TWAEthanole>1000ppm1,1,1,2,3,3,3-Heptafluoropropane >1000ppmn-Pentane1000ppm3. HAZARDS IDENTIFICATIONGENERAL HAZARD:Contents under pressure: Do not expose to temperatures greater than 120° F as containers may burst orvent. EXTREMELY FLAMMABLE. DO NOT INCINERATE (BURN) CONTAINER. AVOID HEAT.KEEP CONTAINER BELOW 120° F (50° C). High temperatures may cause bursting. Do not placecontainer on radiator, stove, in direct sunlight or near other heat sources. DO NOT PUNCTURECONTAINER. Contents under pressure will discharge. AVOID OPEN FLAMES, SPARKS, PILOTLIGHTS. DO NOT SMOKE. Vapour may ignite explosively. Spray mist or vapour evaporating from adeposited film is heavier than air and may settle in low places or travel outward to a source of ignition andflashback. In case of fire, use dry chemical, foam or CO2. Water may be ineffective, but should be used tokeep fire-exposed containers cool.INHALATION:Major route of exposure. Vapour is heavier than air and can cause suffocation by reducing the availableoxygen for breathing. Breathing high concentrations for vapour may lead to narcosis.EYES:Vapours can irritate eyes.SKIN:The spray may cause frostbite if liquid contacts the skin.INGESTION:No specific information.2007-12 Sirona Dental Systems GmbH Page 1 of 4Rev.02AM

MATERIAL SAFETY DATA SHEETacc. to ISO/DIS 11014NFPA Rating 1 (Health, Fire, Reactivity): 1, 3, 1This product has not been classified as a carcinogen or a probable carcinogen by NTP, IRAC, orOSHA.4. FIRST AID MEASURESINHALATION:Move to fresh air in case of accidental inhalation of vapours. If victim has stopped breathing, giveartificial respiration. Call for prompt medical attention.EYE CONTACT:Flush eyes with large amounts of water for 15 minutes or until irritation subsides. If irritation persists, getmedical attention.SKIN CONTACT:Remove contaminated clothing (including shoes) and wash before reuse. Flush with large amounts ofwater. Use soap if available. If irritation persists, seek medical attention.INGESTION:Do not induce vomiting unless directed by a physician. Seek medical attention immediately.5. FIRE FIGHTING MEASURESFIRE FIGHTING INSTRUCTIONS:Firefighters should wear self contained, positive-pressure breathing apparatus and avoid skin contact.FIRE FIGHTING EQUIPMENT:Dry chemical, foam or carbon dioxide. Water may be ineffective. Water spray may be used tokeep fire exposed containers cool.HAZARDOUS COMBUSTION PRODUCTS:Toxic hydrogen fluoride or carbonyl fluoride, oxides of carbon.6. ACCIDENTAL RELEASE MEASURESLAND SPILL:Store in cool, well-ventilated place out of direct sunlight and away from open flames and sources ofignition, avoid heat (See STABILITY AND REACTIVITY Section 10.). Follow all MSD Sheet and labelwarnings even after container is emptied.7. HANDLING AND STORAGESTORAGE TEMPERATURE: AmbientSTORAGE PRESSURE: AtmosphericGENERAL:Store in cool, well-ventilated place. Avoid heat (See STABILITY AND REACTIVITY Section 10.).Follow all MSD Sheet and label warnings even after container is emptied.8. EXPOSURE CONTROLS (OSHA Permissible Exposure Limit (PEL)) / PERSONALPROTECTIONGeneral ventilation is acceptable.TWAEthanole>1000ppm1,1,1,2,3,3,3-Heptafluoropropane >1000ppmn-Pentane1000ppm1 Hazard Rating: Least: 0 Slight: 1 Moderate: 2 High: 3 Extreme: 42007-12 Sirona Dental Systems GmbH Page 2 of 4Rev.02AM

MATERIAL SAFETY DATA SHEETacc. to ISO/DIS 11014PERSONAL PROTECTION:RESPIRATOR:If concentrations are over the exposure limit and are known, air purifying respirator with Organic VaporCartridges may be acceptable. Refer to cartridges for acceptable levels. If concentrations are overexposure limit and are unknown, use a supplied air respirator.HAND PROTECTION:Gloves are not required.EYE PROTECTION:Safety Glasses9. PHYSICAL AND CHEMICAL PROPERTIESAppearance:compressed, liquified gasColour:colourlessChange in physical state:Boiling point:3F, -17°C (1,1,1,2,3,3,3-Heptafluoropropane)Vapourpressure:4barFlash point:< -15°CDensity: 1,3 (Water = 1)Solubility in water:not soluble in waterpH-Value:not applicable10. STABILITY AND REACTIVITYGENERAL:StableINCOMPATIBLE MATERIALS AND CONDITIONS TO AVOID:Contact with open flame, heat.HAZARDOUS DECOMPOSITION:Toxic hydrogen fluoride or carbonyl fluoride, oxides of carbon.11. TOXICOLOGICAL INFORMATIONRESULTS OF COMPONENT TOXICITY TEST PERFORMED:1,1,1,2,3,3,3-Heptafluoropropane:LC 50 (rat): 800.000ppm/4hEthanol:LD 50 : (rat) oral 7060 mg / kgn-Pentan:LD 50 : (rat) oral >2.000mg/kgLC 50 (rat): 364g/m 3 /4h12. ECOLOGICAL INFORMATIONFURTHER INFORMATION:None Found13. DISPOSAL CONSIDERATIONSDispose of according to local, state/provincial, and federal requirements. Empty container: May containexplosive vapors. Do not cut, puncture or weld on or nearby. Incineration will cause container to burstviolently.2007-12 Sirona Dental Systems GmbH Page 3 of 4Rev.02AM

MATERIAL SAFETY DATA SHEETacc. to ISO/DIS 1101414. TRANSPORATION INFORMATIONU.S. DOT InformationProper Shipping Name: CONSUMER COMMODITY ORM-DHazard Class: NAUN Number: 1950Limitations: NAIATAICAO/IATA-Class: 2.1UN/ID-No: 1950PAX: Y 203/30 kg G, 203/75 kg,CAO: 203/150 kgLabels: Aerosols, flammableIMOProper Shipping Name: AerosolsClass: 2UN Number: UN 1950Packaging Group: NAEMS: F-D, S-UMarine Pollutant: No15. REGULATORY INFORMATIONUNITED STATES FEDERAL REGULATIONS:This material is a "health hazard" and/or a "physical hazard" as determined when reviewed according tothe requirements of the Occupational Safety and Health Administration 29 CFR Part 1910.1200 "HazardCommunication" Standard.SARA Title III: Section 311/312:Sudden release of pressure (explosion) hazard.16. OTHER INFORMATIONLABEL INFORMATION:NFPA HAZARD RATING:NFPA Rating (Health, Fire, Reactivity): 1, 3, 1DISCLAIMERTo the best of our knowledge, the information contained herein is accurate. However, neither SironaDental Systems GmbH or any of its subsidiaries assumes any liability whatsoever for the accuracy orcompleteness of the information contained herein. Final determination of suitability of any material is thesole responsibility of the user. All materials may present unknown hazards and should be used withcaution. Although certain hazards are described herein, we cannot guarantee that these are the onlyhazards, which exist.2007-12 Sirona Dental Systems GmbH Page 4 of 4Rev.02AM