BASF Trimix NCA MSDS - Brock White

Safety Data SheetTRIMIX NCARevision date : 2011/12/06 Page: 1/6Version: 1.0(30368797/SDS_GEN_US/EN)1. Product and Company IdentificationCompanyBASF CORPORATION100 Campus DriveFlorham Park, NJ 07932, USA24 Hour Emergency Response InformationCHEMTREC: 1-800-424-9300BASF HOTLINE: 1-800-832-HELP2. Hazards IdentificationEmergency overviewWARNING:MAY CAUSE EYE IRRITATION.MAY CAUSE SKIN IRRITATION.Ingestion may cause irritation to mucous membranes.Avoid contact with the skin, eyes and clothing.Wash thoroughly after handling.Keep container tightly closed.State of matter: liquidColour: product specificOdour: slight odourPotential health effectsPrimary routes of exposure:Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry forgases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases.Irritation / corrosion:Irritating to eyes and skin.The product has not been tested. The statement has been derived from the properties of the individualcomponents.Potential environmental effectsAquatic toxicity:There is a high probability that the product is not acutely harmful to aquatic organisms.3. Composition / Information on IngredientsCAS Number Content (W/W) Chemical name13477-34-4 >= 15.0 -

Safety Data SheetTRIMIX NCARevision date : 2011/12/06 Page: 2/6Version: 1.0(30368797/SDS_GEN_US/EN)4. First-Aid MeasuresGeneral advice:First aid personnel should pay attention to their own safety. Remove contaminated clothing.If inhaled:If difficulties occur after vapour/aerosol has been inhaled, remove to fresh air and seek medical attention.If on skin:After contact with skin, wash immediately with plenty of water and soap. Under no circumstances should organicsolvent be used. If irritation develops, seek medical attention.If in eyes:Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eyespecialist.If swallowed:Rinse mouth immediately with water. Seek medical attention if necessary. Do not induce vomiting unless told toby a poison control center or doctor.5. Fire-Fighting MeasuresFlash point: > 212 °F The product has not been tested.Suitable extinguishing media:carbon dioxide, water sprayHazards during fire-fighting:carbon monoxide, carbon dioxide, harmful vapours, nitrogen oxides, fumes/smoke, carbon blackProtective equipment for fire-fighting:Wear a self-contained breathing apparatus.Further information:The degree of risk is governed by the burning substance and the fire conditions. Contaminated extinguishingwater must be disposed of in accordance with official regulations.6. Accidental release measuresPersonal precautions:Use personal protective clothing. Do not breathe vapour/aerosol/spray mists. Handle in accordance with goodbuilding materials hygiene and safety practice.Environmental precautions:Contain contaminated water/firefighting water. Do not discharge into drains/surface waters/groundwater.Cleanup:For small amounts: Pick up with inert absorbent material (e.g. sand, earth etc.). Dispose of contaminatedmaterial as prescribed.For large amounts: Pump off product.

Safety Data SheetTRIMIX NCARevision date : 2011/12/06 Page: 3/6Version: 1.0(30368797/SDS_GEN_US/EN)7. Handling and StorageHandlingGeneral advice:Avoid aerosol formation. Avoid inhalation of mists/vapours. Avoid skin contact. No special measures necessaryprovided product is used correctly.Protection against fire and explosion:The product does not contribute to the spreading of flames, nor is it self combustible, not explosive.StorageGeneral advice:Keep only in the original container in a cool, well-ventilated place. Protect from direct sunlight. Store protectedagainst freezing.Temperature toleranceProtect from temperatures below: 0 °CPROTECT FROM FREEZING DURING THE COLD-SEASON (BELOW 40°F / 5°C ).Protect from temperatures below: 32 °F8. Exposure Controls and Personal ProtectionPersonal protective equipmentRespiratory protection:When workers are facing concentrations above the occupational exposure limits they must use appropriatecertified respirators.Hand protection:Wear chemical resistant protective gloves.Eye protection:Safety glasses with side-shields.Body protection:depending upon conditions of use., Cover as much of the exposed skin as possible to prevent all skin contact.,light protective clothingGeneral safety and hygiene measures:Avoid contact with the skin, eyes and clothing. In order to prevent contamination while handling, closed workingclothes and working gloves should be used. Handle in accordance with good building materials hygiene andsafety practice. When using, do not eat, drink or smoke. Hands and/or face should be washed before breaksand at the end of the shift. At the end of the shift the skin should be cleaned and skin-care agents applied.Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks).9. Physical and Chemical PropertiesForm:liquidOdour:slight odourColour:product specificpH value:neutral to slightly alkalineDensity: 1.20 g/cm3 ( 20 °C)10.0 lb/USg ( 20 °C)Relative density: 1.20Vapour density:Heavier than air.Solubility in water:partly soluble

Safety Data SheetTRIMIX NCARevision date : 2011/12/06 Page: 4/6Version: 1.0(30368797/SDS_GEN_US/EN)10. Stability and ReactivityConditions to avoid:Avoid extreme temperatures.Substances to avoid:oxidizing agentsHazardous reactions:The product is stable if stored and handled as prescribed/indicated.Decomposition products:Hazardous decomposition products: carbon oxidesThermal decomposition:No decomposition if stored and handled as prescribed/indicated.11. Toxicological informationAcute toxicityInformation on: Calcium nitrate tetrahydrateAssessment of acute toxicity:Virtually nontoxic after a single skin contact. There is a risk of damage to the blood (methemoglobinemia) after asingle uptake of large quantities. The product has not been tested. The statement has been derived fromproducts of a similar structure or composition.----------------------------------Repeated dose toxicityInformation on: Calcium nitrate tetrahydrateAssessment of repeated dose toxicity:The substance may cause the formation of methemoglobin after repeated uptake of high doses. The producthas not been tested. The statement has been derived from products of a similar structure or composition.----------------------------------12. Ecological InformationDegradability / PersistenceBiological / Abiological DegradationTest method: Directive 88/302/EEC, part C, p. 99Evaluation:Not readily biodegradable (by OECD criteria).BioaccumulationSignificant accumulation in organisms is not to be expected.13. Disposal considerationsWaste disposal of substance:Recommendations: Use excess product in an alternate beneficial application. Do not discharge intodrains/surface waters/groundwater. Dispose of in accordance with local authority regulations.Container disposal:Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling afterbeing thoroughly cleaned.

Safety Data SheetTRIMIX NCARevision date : 2011/12/06 Page: 5/6Version: 1.0(30368797/SDS_GEN_US/EN)14. Transport InformationLand transportUSDOTNot classified as a dangerous good under transport regulationsSea transportIMDGNot classified as a dangerous good under transport regulationsAir transportIATA/ICAONot classified as a dangerous good under transport regulations15. Regulatory InformationFederal RegulationsRegistration status:Chemical TSCA, US released / listedEPCRA 311/312 (Hazard categories):Not hazardous;EPCRA 313:CAS Number Chemical name13477-34-4 Calcium nitrate tetrahydrateCERCLA RQ CAS Number Chemical name5000 LBS 91-22-5 quinoline100 LBS 50-00-0; 91-20-3 Formaldehyde; naphthaleneState regulationsState RTK CAS Number Chemical nameNJ 13477-34-4 Calcium nitrate tetrahydrateCA Prop. 65:THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSECANCER.16. Other InformationHMIS III ratingHealth: 1 Flammability: 1 Physical hazard: 0NFPA and HMIS use a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of zero means that thesubstance possesses essentially no hazard; a rating of four indicates extreme danger. Although similar, the two ratingsystems are intended for different purposes, and use different criteria. The NFPA system was developed to provide an

Safety Data SheetTRIMIX NCARevision date : 2011/12/06 Page: 6/6Version: 1.0(30368797/SDS_GEN_US/EN)on-the-spot alert to the hazards of a material, and their severity, to emergency responders. The HMIS system was designedto communicate workplace hazard information to employees who handle hazardous chemicals.We support worldwide Responsible Care® initiatives. We value the health and safety of our employees,customers, suppliers and neighbors, and the protection of the environment. Our commitment to ResponsibleCare is integral to conducting our business and operating our facilities in a safe and environmentally responsiblefashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of ourproducts, and minimizing the impact of our operations on society and the environment during production,storage, transport, use and disposal of our products.MSDS Prepared by:BASF NA Product Regulationsmsds@basf.comMSDS Prepared on: 2011/12/06IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREINARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE , IT IS PROVIDED FOR YOURGUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WERECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOURPARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED ORIMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULARPURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATIONSET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUTINFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THEDESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OURTERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THATTHE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANYHEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THEDESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEINGGIVEN AND ACCEPTED AT YOUR RISK.END OF DATA SHEET