Safety Data Sheet

MATKO BOŻA TRĄBKOWSKA PRZYCZYŃ SIĘ ZA NAMIPISMO PARAFII SANKTUARIUM MARYJNEGO W TRĄBKACH WIELKICHCzerwiec 2008 Nr 6 (138)Procesja Bożego Ciała A.D. 2008 (patrz s. 8–9)

Precautionary statement(s)PreventionP210P233P240P241P242P243P261P264P271P280ResponseP303 + P361 + P353P304 + P340P305 + P351 + P338P312P321P332 + P313P337 + P313P362P370 + P378StorageP403 + P233P403 + P235P405DisposalP5012.3 Other hazards - noneKeep away from heat/sparks/open flames/hot surfaces. - No smoking.Keep container tightly closed.Ground/bond container and receiving equipment.Use explosion-proof electrical/ ventilating/ lighting/ equipment.Use only non-sparking tools.Take precautionary measures against static discharge.Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray.Wash skin thoroughly after handling.Use only outdoors or in a well-ventilated area.Wear protective gloves/ protective clothing/ eye protection/ faceprotection.IF ON SKIN (or hair): Remove/ Take off immediately all contaminatedclothing. Rinse skin with water/ shower.IF INHALED: Remove victim to fresh air and keep at rest in a positioncomfortable for breathing.IF IN EYES: Rinse cautiously with water for several minutes. Removecontact lenses, if present and easy to do. Continue rinsing.Call a POISON CENTER or doctor/ physician if you feel unwell.Specific treatment (see supplemental first aid instructions on this label).If skin irritation occurs: Get medical advice/ attention.If eye irritation persists: Get medical advice/ attention.Take off contaminated clothing and wash before reuse.In case of fire: Use dry sand, dry chemical or alcohol-resistant foam forextinction.Store in a well-ventilated place. Keep container tightly closed.Store in a well-ventilated place. Keep cool.Store locked up.Dispose of contents/ container to an approved waste disposal plant.3. COMPOSITION/INFORMATION ON INGREDIENTS3.2 MixturesSynonyms : TYZOR® TBT organic titanateTetrabutyl orthotitanateTetrabutyl titanateOrthotitanic acid tetrabutylesterTNBTFormula : C 16 H 36 O 4 TiMolecular Weight : 340.32 g/molComponent Classification Concentrationtitanium tetrabutanolateCAS-No.EC-No.5593-70-4227-006-8Titanium tetraisopropanolateCAS-No.546-68-9EC-No.208-909-6Flam. Liq. 3; Skin Irrit. 2; EyeIrrit. 2; STOT SE 3; H226,H315, H319, H335Flam. Liq. 3; Acute Tox. 3; EyeIrrit. 2; H226, H319, H331-0.1 - 10 %Fluka - 86910 Page 2 of 8

n-ButanolCAS-No.EC-No.Index-No.71-36-3200-751-6603-004-00-6Flam. Liq. 3; Acute Tox. 4;Skin Irrit. 2; Eye Irrit. 2; STOTSE 3; H226, H302, H315,H319, H335, H336For the full text of the H-Statements and R-Phrases mentioned in this Section, see Section 164. FIRST AID MEASURES4.1 Description of first aid measuresGeneral adviceConsult a physician. Show this safety data sheet to the doctor in attendance.0.1 - 10 %If inhaledIf breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.In case of skin contactWash off with soap and plenty of water. Consult a physician.In case of eye contactRinse thoroughly with plenty of water for at least 15 minutes and consult a physician.If swallowedDo NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water.Consult a physician.4.2 Most important symptoms and effects, both acute and delayed4.3 Indication of any immediate medical attention and special treatment neededno data available5. FIREFIGHTING MEASURES5.1 Extinguishing mediaSuitable extinguishing mediaUse water spray, alcohol-resistant foam, dry chemical or carbon dioxide.5.2 Special hazards arising from the substance or mixtureCarbon oxides, Titanium/titanium oxides5.3 Advice for firefightersWear self contained breathing apparatus for fire fighting if necessary.5.4 Further informationUse water spray to cool unopened containers.6. ACCIDENTAL RELEASE MEASURES6.1 Personal precautions, protective equipment and emergency proceduresUse personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to formexplosive concentrations. Vapours can accumulate in low areas.6.2 Environmental precautionsPrevent further leakage or spillage if safe to do so. Do not let product enter drains.6.3 Methods and materials for containment and cleaning upContain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing andplace in container for disposal according to local regulations (see section 13).6.4 Reference to other sectionsFor disposal see section 13.Fluka - 86910 Page 3 of 8

7. HANDLING AND STORAGE7.1 Precautions for safe handlingAvoid contact with skin and eyes. Avoid inhalation of vapour or mist.Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostaticcharge.7.2 Conditions for safe storage, including any incompatibilitiesStore in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which areopened must be carefully resealed and kept upright to prevent leakage.Air and moisture sensitive.7.3 Specific end usesno data available8. EXPOSURE CONTROLS/PERSONAL PROTECTION8.1 Control parametersOccupational Exposure LimitsComponent CAS-No. Value Controln-Butanol 71-36-3 PEL(shortterm)8.2 Exposure controlsparameters50 ppm152 mg/m3Fluka - 86910 Page 4 of 8BasisSingapore. Workplace Safety and HealthAct - First Schedule Permissible ExposureLimits of Toxic SubstancesAppropriate engineering controlsHandle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and atthe end of workday.Personal protective equipmentEye/face protectionFace shield and safety glasses Use equipment for eye protection tested and approved underappropriate government standards such as NIOSH (US) or EN 166(EU).Skin protectionHandle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose ofcontaminated gloves after use in accordance with applicable laws and good laboratory practices.Wash and dry hands.The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and thestandard EN 374 derived from it.Body Protectionimpervious clothing, Flame retardant antistatic protective clothing, The type of protective equipmentmust be selected according to the concentration and amount of the dangerous substance at thespecific workplace.Respiratory protectionWhere risk assessment shows air-purifying respirators are appropriate use a full-face respirator withmulti-purpose combination (US) or type ABEK (EN 14387) respirator cartridges as a backup toengineering controls. If the respirator is the sole means of protection, use a full-face supplied airrespirator. Use respirators and components tested and approved under appropriate governmentstandards such as NIOSH (US) or CEN (EU).9. PHYSICAL AND CHEMICAL PROPERTIES9.1 Information on basic physical and chemical propertiesa) Appearance Form: liquidColour: light yellow

) Odour no data availablec) Odour Threshold no data availabled) pH no data availablee) Melting point/freezingpointf) Initial boiling point andboiling rangeg) Flash point 50 °Cno data available206 °C at 13 hPah) Evaporation rate no data availablei) Flammability (solid, gas) no data availablej) Upper/lowerflammability orexplosive limitsno data availablek) Vapour pressure no data availablel) Vapour density no data availablem) Relative density 1.00 g/mL at 20 °Cn) Water solubility no data availableo) Partition coefficient: n-octanol/waterp) Autoignitiontemperatureq) Decompositiontemperatureno data availableno data availableno data availabler) Viscosity no data available10. STABILITY AND REACTIVITY10.1 Reactivityno data available10.2 Chemical stabilityno data available10.3 Possibility of hazardous reactionsno data available10.4 Conditions to avoidHeat, flames and sparks.10.5 Incompatible materialsStrong acids and oxidizing agents10.6 Hazardous decomposition productsOther decomposition products - no data available11. TOXICOLOGICAL INFORMATION11.1 Information on toxicological effectsAcute toxicityno data availableSkin corrosion/irritationno data availableFluka - 86910 Page 5 of 8

Serious eye damage/eye irritationno data availableRespiratory or skin sensitizationno data availableGerm cell mutagenicityno data availableCarcinogenicityIARC:Reproductive toxicityno data availableNo component of this product present at levels greater than or equal to 0.1% is identified asprobable, possible or confirmed human carcinogen by IARC.Specific target organ toxicity - single exposureno data availableSpecific target organ toxicity - repeated exposureno data availableAspiration hazardno data availablePotential health effectsInhalationIngestionSkinEyesAdditional InformationRTECS: XR158500012. ECOLOGICAL INFORMATION12.1 Toxicityno data available12.2 Persistence and degradabilityno data available12.3 Bioaccumulative potentialno data available12.4 Mobility in soilno data available12.5 Results of PBT and vPvB assessmentno data available12.6 Other adverse effectsno data available13. DISPOSAL CONSIDERATIONS13.1 Waste treatment methodsMay be harmful if inhaled. Causes respiratory tract irritation.May be harmful if swallowed.May be harmful if absorbed through skin. Causes skin irritation.Causes serious eye irritation.ProductBurn in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting asthis material is highly flammable. Offer surplus and non-recyclable solutions to a licensed disposalcompany.Contaminated packagingDispose of as unused product.Fluka - 86910 Page 6 of 8

14. TRANSPORT INFORMATION14.1 UN numberADR/RID: 1993 IMDG: 1993 IATA-DGR: 199314.2 UN proper shipping nameADR/RID: FLAMMABLE LIQUID, N.O.S. (Titanium tetraisopropanolate, n-Butanol)IMDG: FLAMMABLE LIQUID, N.O.S. (Titanium tetraisopropanolate, n-Butanol)IATA-DGR: Flammable liquid, n.o.s. (Titanium tetraisopropanolate, n-Butanol)14.3 Transport hazard class(es)ADR/RID: 3 IMDG: 3 IATA-DGR: 314.4 Packaging groupADR/RID: III IMDG: III IATA-DGR: III14.5 Environmental hazardsADR/RID: no IMDG Marine pollutant: no IATA-DGR: no14.6 Special precautions for userno data available15. REGULATORY INFORMATION15.1 Safety, health and environmental regulations/legislation specific for the substance or mixtureNotification statusAICS:DSL:ENCS:IECSC:ISHL:KECI:NZIoC:PICCS:On the inventory, or in compliance with the inventoryAll components of this product are on the Canadian DSL list.On the inventory, or in compliance with the inventoryOn the inventory, or in compliance with the inventoryNot in compliance with the inventory - Titanium(IV) butoxide, TitaniumtetraisopropanolateOn the inventory, or in compliance with the inventoryOn the inventory, or in compliance with the inventoryOn the inventory, or in compliance with the inventory16. OTHER INFORMATIONText of H-code(s) and R-phrase(s) mentioned in Section 3Acute Tox.Eye Irrit.Flam. Liq.H226H302H315H319H331H335H336Skin Irrit.STOT SEAcute toxicityEye irritationFlammable liquidsFlammable liquid and vapour.Harmful if swallowed.Causes skin irritation.Causes serious eye irritation.Toxic if inhaled.May cause respiratory irritation.May cause drowsiness or dizziness.Skin irritationSpecific target organ toxicity - single exposureFurther informationCopyright 2012 Sigma-Aldrich Co. LLC. License granted to make unlimited paper copies for internal useonly.The above information is believed to be correct but does not purport to be all inclusive and shall be usedonly as a guide. The information in this document is based on the present state of our knowledge and isFluka - 86910 Page 7 of 8

applicable to the product with regard to appropriate safety precautions. It does not represent anyguarantee of the properties of the product. Sigma-Aldrich Corporation and its Affiliates shall not be heldliable for any damage resulting from handling or from contact with the above product. See www.sigmaaldrich.comand/or the reverse side of invoice or packing slip for additional terms and conditions of sale.Fluka - 86910 Page 8 of 8