njit-etd1961-002 - New Jersey Institute of Technology

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SECTION IISAMPLE CALCULATIONS
c =p13The critical properties were calculated as follows:(A) Critical pressure P c by Lydersen's method8, 10Mc o + I. 2where P c = critical pressure in atmosphereM = molecular weight = 30.03= atomic and structural constant= 0.33P 30.03c = 2 - 66.897 atm.(0.33 + 0.34)(B) Critical temperature Tc by Lydersen's method8,¹0TbT c(εΔT)²T c =where T c = critical temperature in °KTb = normal boiling point = 253.96 ° KT= structural contribution from-CHO group = 0.048253.96414.49°K0.567 + 0.048 - (0.048)²(C) Critical volume by Lydersen's method 8V c = 40 +where V c = critical volume in cc/g-moleΔv = atomic and atomic group contributionto V c = 73 for -CHOgroupV c= 40 + 73 = 113 cc/gm-mole
Page 4 and 5: APPROVAL OF THESISFORDEPARTMENT OF
Page 6 and 7: TABLE OF CONTENTSNomenclatureivSumm
Page 8 and 9: NOMENCLATURE (Coned.)ΔS*= differen
Page 10 and 11: INTRODUCTIONFormaldehyde is produce
Page 12 and 13: 3is calculated by summing atomic an
Page 14 and 15: Al [ (¹ - Tr1)- 1.-2 = T1 - TTr2)0
Page 16 and 17: (V) The values of the saturated liq
Page 18 and 19: Prior to the present correlation of
Page 20 and 21: 11The generalized compressibility f
Page 22 and 23: SECTION IDATA FROM LITERATURE
Page 26 and 27: αc14(0) Critical compressibility f
Page 28 and 29: 16Saturated vapor volumes were calc
Page 30 and 31: ¹8Correcting the entropy of the id
Page 32 and 33: 20Correcting the deviation of the e
Page 34 and 35: 21TABLE 2THERMODYNAMIC PROPERTIES O
Page 36 and 37: 2³THERMODYNAMIC PROPERTIES OF SUPE
Page 38 and 39: 1. .A25THERMODYNAMIC PROPERTIES OF
Page 40 and 41: 27THERMODYNAMIC PROPERTIES Or SUPER
Page 42 and 43: 29THERMODYNAMIC PROPERTIES 01, nPER
Page 44 and 45: 31THERMODYIAAMIC PROP ERT1EF or Sli
Page 46 and 47: 33THER1,101riNAM IC PROPERTIES OF :
Page 48 and 49: 35THE ,,,Lv,TIC PROPETI i EL' .L- S
Page 50 and 51: 37THERMODYNAMIC PROPERTIES OF SUP'R
Page 52 and 53: 39THERMODYNAMIC PROPERTIES OF SUPER
Page 54 and 55: 41THERMODYNAMIC PROPERTIES OF SUPER
Page 56 and 57: 43THERMODYNAMIC PROPERTIES 02 SUzER
Page 58: 45THERMODYNAMIC PROPERTIES OF SUPER
Page 63: REFERENCES(16) Walker, J. Frederic,

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