njit-etd1961-002 - New Jersey Institute of Technology

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TABLE OF CONTENTSNomenclatureivSummaryviIntroduction 1Method of Calculation 2Results 8Discussion 9AppendixSection I Data from Literature 12Section II Sample Calculations 13Section III Tables and Graphs 21References 49
λr PΦNOMENCLATUREDDcDr= density in gm/cc= critical density in gm/cc= reduced density, D/DcDSLDSV= density of saturated liquid, gm/cc= density of saturated vapor, gm/ccH* = enthalpy of ideal gas in cal/g-moleHSLΔH*= enthalpy of saturated liquid, cal/g-mole= difference between ideal enthalpies at-19°C. and a higher temperature,cal/g-mole= heat of vaporization, cal/g-moleMP= molecular weight= pressure in atmospherec P= critical pressure, atm.= reduced pressure, P/P c= atomic and structural constant in Eq. (2)due to -CHO group.R= gas constant, 1.987 cal/g-mole/°K= 82.06(((cc)(atm.))/((g-mole)(°K)))S* = entropy of ideal gas, cal/g-mole/°KSSL = entropy of saturated liquid, cal/g-mole/°KSSV= entropy of saturated vapor, cal/g-mole/°Kiv
Page 4 and 5: APPROVAL OF THESISFORDEPARTMENT OF
Page 8 and 9: NOMENCLATURE (Coned.)ΔS*= differen
Page 10 and 11: INTRODUCTIONFormaldehyde is produce
Page 12 and 13: 3is calculated by summing atomic an
Page 14 and 15: Al [ (¹ - Tr1)- 1.-2 = T1 - TTr2)0
Page 16 and 17: (V) The values of the saturated liq
Page 18 and 19: Prior to the present correlation of
Page 20 and 21: 11The generalized compressibility f
Page 22 and 23: SECTION IDATA FROM LITERATURE
Page 24 and 25: SECTION IISAMPLE CALCULATIONS
Page 26 and 27: αc14(0) Critical compressibility f
Page 28 and 29: 16Saturated vapor volumes were calc
Page 30 and 31: ¹8Correcting the entropy of the id
Page 32 and 33: 20Correcting the deviation of the e
Page 34 and 35: 21TABLE 2THERMODYNAMIC PROPERTIES O
Page 36 and 37: 2³THERMODYNAMIC PROPERTIES OF SUPE
Page 38 and 39: 1. .A25THERMODYNAMIC PROPERTIES OF
Page 40 and 41: 27THERMODYNAMIC PROPERTIES Or SUPER
Page 42 and 43: 29THERMODYNAMIC PROPERTIES 01, nPER
Page 44 and 45: 31THERMODYIAAMIC PROP ERT1EF or Sli
Page 46 and 47: 33THER1,101riNAM IC PROPERTIES OF :
Page 48 and 49: 35THE ,,,Lv,TIC PROPETI i EL' .L- S
Page 50 and 51: 37THERMODYNAMIC PROPERTIES OF SUP'R
Page 52 and 53: 39THERMODYNAMIC PROPERTIES OF SUPER
Page 54 and 55: 41THERMODYNAMIC PROPERTIES OF SUPER
Page 56 and 57:
43THERMODYNAMIC PROPERTIES 02 SUzER
Page 58:
45THERMODYNAMIC PROPERTIES OF SUPER
Page 63:
REFERENCES(16) Walker, J. Frederic,
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