Coke - Timcal

EC safety data sheetTrade name: TIMREX CokeCurrent version : 1.5.0, issued: 23.04.2012 Replaced version: 1.4.1, issued: 14.02.2012 Region: GBSECTION 4: First aid measures4.1 Description of first aid measuresGeneral informationIn case of persisting adverse effects, consult a physician. Remove contaminated clothing and shoes immediately, andlaunder thoroughly before reusing.After inhalationRemove affected person from the immediate area. Ensure supply of fresh air.After skin contactWash off immediately with soap and water.After eye contactSeparate eyelids, wash the eyes thoroughly with water (15 min.).After ingestionRinse mouth thoroughly with water. Seek medical advice immediately. Never give anything by mouth to anunconscious person.4.2 Most important symptoms and effects, both acute and delayedNo data available.4.3 Indication of any immediate medical attention and special treatment neededNo data available.SECTION 5: Firefighting measures5.1 Extinguishing mediaSuitable extinguishing mediaFoam; Water spray jet; Dry chemical extinguisher; Carbon dioxideUnsuitable extinguishing mediaNo data available.5.2 Special hazards arising from the substance or mixtureWhen exposed to high temperatures may produce hazardous decomposition products such as carbon monoxide,carbon dioxide and smoke.5.3 Advice for firefightersUse self-contained breathing apparatus. Wear protective clothing.SECTION 6: Accidental release measures6.1 Personal precautions, protective equipment and emergency proceduresFor non-emergency personnelRefer to protective measures listed in sections 7 and 8. Avoid contact with skin, eyes and clothing. Ensure adequateventilation. Avoid dust formation.For emergency respondersNo data available. Personal protective equipment (PPE) - see Section 8.6.2 Environmental precautionsDo not discharge into the drains/surface waters/groundwater.6.3 Methods and material for containment and cleaning upTake up mechanically. When picked up, treat material as prescribed under heading "Disposal considerations".6.4 Reference to other sectionsNo data available.Page 2 of 8

trueEC safety data sheetTrade name: TIMREX CokeCurrent version : 1.5.0, issued: 23.04.2012 Replaced version: 1.4.1, issued: 14.02.2012 Region: GBSECTION 7: Handling and storage7.1 Precautions for safe handlingAdvice on safe handlingProvide good ventilation of working area (local exhaust ventilation, if necessary). If workplace exposure limits areexceeded, respiratory protection approved for this particular job must be worn.General protective and hygiene measuresDo not eat, drink or smoke during work time. Keep away from foodstuffs and beverages. Avoid contact with eyes andskin. Remove soiled or soaked clothing immediately. Wash hands before breaks and after work. Do not inhale dust.Provide eye wash fountain in work area.Advice on protection against fire and explosionDust can form an explosive mixture with air. Take precautionary measures against static charges. Keep away fromsources of heat and ignition.7.2 Conditions for safe storage, including any incompatibilitiesTechnical measures and storage conditionsKeep container tightly closed and dry.Requirements for storage rooms and vesselsContainers which are opened must be carefully resealed and kept upright to prevent leakage. Always keep incontainers of same material as the original one.Advice on storage assemblyNone known7.3 Specific end use(s)No data available.SECTION 8: Exposure controls/personal protection8.1 Control parametersOccupational exposure limit valuesNo Substance name CAS no. EC no.1 DUSTList of approved workplace exposure limits (WELs) / EH40total inhalable dustTWA 10 mg/m³List of approved workplace exposure limits (WELs) / EH40respirable dustTWA 4 mg/m³8.2 Exposure controlsAppropriate engineering controlsNo data available.Personal protective equipmentRespiratory protectionIf workplace exposure limits are exceeded, a respiration protection approved for this particular job must be worn. Incase of dust formation, take appropriate measures for breathing protection in the event workplace threshold valuesare not specified. Dust maskRespirator FFP2SL (EN 149)Eye / face protectionSafety glasses with side protection shield (EN 166)Hand protectionSufficient protection is given wearing suitable protective gloves checked according to i.e. EN 374, in the event of riskof skin contact with the product . Before use, the protective gloves should be tested in any case for its specific workstationsuitability (i.e. mechanical resistance, product compatibility and antistatic properties). Adhere to themanufacturer’s instructions and information relating to the use, storage, care and replacement of protective gloves.Protective gloves shall be replaced immediately when physically damaged or worn. Design operations thus to avoidpermanent use of protective gloves.Page 3 of 8

20 30720n.a.4 20003 6002 0,01EC safety data sheetTrade name: TIMREX CokeCurrent version : 1.5.0, issued: 23.04.2012 Replaced version: 1.4.1, issued: 14.02.2012 Region: GBAppropriate MaterialOtherNormal chemical work clothing.Environmental exposure controlsNo data available.rubberSECTION 9: Physical and chemical properties9.1 Information on basic physical and chemical propertiesForm/ColourPowdergrey to blackOdourodourlessOdour thresholdNo data availablepH valueNo data availableBoiling point / boiling rangeNo data availableMelting point / melting rangeValue appr. 2000 °CDecomposition point / decomposition rangeNo data availableFlash pointNot applicableIgnition temperatureValue > 600 °CReference substancedispersed dust cloudValue > 365 °CReference substancedeposited dustAuto-ignition temperatureNo data availableOxidising propertiesNo data availableExplosive propertiesNo data availableFlammability (solid, gas)No data availableLower flammability or explosive limitsNo data availableUpper flammability or explosive limitsNo data availableVapour pressureValue < 0,01 mbarReference temperature 20 °CPage 4 of 8

U_90162,04 2,06800 8503 2000 67EC safety data sheetTrade name: TIMREX CokeCurrent version : 1.5.0, issued: 23.04.2012 Replaced version: 1.4.1, issued: 14.02.2012 Region: GBVapour densityNo data availableEvaporation rateNo data availableRelative densityNo data availableDensityValue 2,04 - 2,06 g/cm³Reference temperature 25 °CBulk densityValue 800 - 850 kg/m³Solubility in waterRemarksSolubility(ies)No data availablePartition coefficient: n-octanol/waterNo data availableViscosityNo data availableinsoluble9.2 Other informationOther informationFlammability BZ1: not burning (100 °C), source of ignition: glowing platinium wire, 1000 °C approx.Impact sensitivity: not impact sensitiveSECTION 10: Stability and reactivity10.1 ReactivityNo data available.10.2 Chemical stabilityNo data available.10.3 Possibility of hazardous reactionsNo data available.10.4 Conditions to avoidNo data available.10.5 Incompatible materialsNone known.10.6 Hazardous decomposition productsNo hazardous decomposition products known.SECTION 11: Toxicological information11.1 Information on toxicological effectsAcute oral toxicityLD50 > 2000 mg/kgSpeciesratMethod OECD 401Page 5 of 8

91410 4 11320EC safety data sheetTrade name: TIMREX CokeCurrent version : 1.5.0, issued: 23.04.2012 Replaced version: 1.4.1, issued: 14.02.2012 Region: GBAcute dermal toxicityNo data availableAcute inhalational toxicityNo data availableSkin corrosion/irritationDuration of exposure 4 hSpeciesrabbitMethod OECD 404Evaluationnon-irritantSerious eye damage/irritationSpeciesrabbitMethod OECD 405Evaluationslightly irritantRespiratory or skin sensitisationNo data availableGerm cell mutagenicityNo data availableReproduction toxicityNo data availableCarcinogenicityNo data availableSTOT-single exposureNo data availableSTOT-repeated exposureNo data availableAspiration hazardNo data availableDelayed and immediate effects as well as chronic effects from short and long-term exposureContact with the skin and eyes may cause mechanical irritation. Inhalation of dusts may irritate the respiratory tract.SECTION 12: Ecological information12.1 ToxicityFish toxicityNo data availableDaphnia toxicityNo data availableAlgae toxicityNo data availableBacteria toxicityNo data available12.2 Persistence and degradabilityBiodegradabilityEvaluationnot degradablePage 6 of 8

710EC safety data sheetTrade name: TIMREX CokeCurrent version : 1.5.0, issued: 23.04.2012 Replaced version: 1.4.1, issued: 14.02.2012 Region: GB12.3 Bioaccumulative potentialNo data available.12.4 Mobility in soilNo data available.12.5 Results of PBT and vPvB assessmentNo data available.12.6 Other adverse effectsNo data available.12.7 Other informationOther informationDo not discharge product unmonitored into the environment.SECTION 13: Disposal considerations13.1 Waste treatment methodsProductAllocation of a waste code number, according to the European Waste Catalogue, should be carried out in agreementwith the regional waste disposal company.PackagingResiduals must be removed from packaging and when emptied completely disposed of in accordance with theregulations for waste removal. Incompletely emptied packaging must be disposed of in the form of disposal specifiedby the regional disposer.SECTION 14: Transport information14.1 Transport ADR/RID/ADNThe product is not subject to ADR/RID/ADN regulations.14.2 Transport IMDGThe product is not subject to IMDG regulations.14.3 Transport ICAO-TI / IATAThe product is not subject to ICAO-TI / IATA regulations.14.4 Other informationNo data available.14.6 Special precautions for userNo data available.14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC CodeNot relevantSECTION 15: Regulatory information15.1 Safety, health and environmental regulations/legislation specific for the substance or mixtureEU regulationsCouncil Directive 96/82/EC on the control of major-accident hazards involving dangerous substancesRemarksAnnex I, part 1 + 2: not mentioned. With regard to possibly appropriatedecomposition products see Chapter 10.Page 7 of 8

EC safety data sheetTrade name: TIMREX CokeCurrent version : 1.5.0, issued: 23.04.2012 Replaced version: 1.4.1, issued: 14.02.2012 Region: GBNational regulationsNational chemical inventoriesEINECS/ELINCS (European listedCommunity)TSCA (USA)listedDSL/NDSL (Canada)DSL listedECL (Corea) listed KE-06252AICS (Australia)listedIECSC / NEPA (China)listedNZIoC (New Zealand)listed15.2 Chemical safety assessmentNo data available.SECTION 16: Other informationSources of key data used to compile the data sheet:EC Directive 67/548/EC resp. 99/45/EC as amended in each case.Regulation (EC) No 1907/2006 (REACH), 1272/2008 (CLP) as amended in each case.EC Directives 2000/39/EC, 2006/15/EC, 2009/161/ECNational Threshold Limit Values of the corresponding countries as amended in each case.Transport regulations according to ADR, RID, IMDG, IATA as amended in each case.The data sources used to determine physical, toxic and ecotoxic data, are indicated directly in the correspondingchapter.Department issuing safety data sheetUMCO Umwelt Consult GmbHGeorg-Wilhelm-Str. 183 , D-21107 HamburgTel.: +49 40 / 79 02 36 300 Fax: +49 40 / 79 02 36 357 e-mail: umco@umco.deThis information is based on our present state of knowledge. However, it should not constitute a guarantee for anyspecific product properties and shall not establish a legally valid relationship.Page 8 of 8