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mycorrhizal associations have been known to causeyield penalties (Ryan et al. 2002, 2005).Arbuscular mycorrhizal fungi have a symbiotic(defined in the broadest terms as two ormore organisms living together) associationwith the root of a living plant and are primarilyresponsible for nutrient transfer.Organic phosphorus sources are relatively slowrelease,but it is not easy to predict exactly whensoluble phosphorus will become available. Toensure a more reliable supply of phosphorus it isbest to apply a combination of mineral and <strong>organic</strong>sources. Soils with a high tendency to adsorb orfix phosphorus are likely to require phosphorusfertiliser application to meet crop requirementseven when <strong>soil</strong> tests suggest sufficient levels ofphosphorus exist.Diffusive Gradient in Thin-Films (DGT) is a newmethod of measuring <strong>soil</strong> phosphorus (Mason et al.2010) and is shown to be more accurate than otherconventional methods in estimating the phosphorusrequirement of crops. It provides an improvedmeasure of the phosphorus available for plantuptake and determines the likely yield responsefrom additional fertiliser (see http://<strong>soil</strong>quality.org.au/factsheets/dgt-phosphorus for further information).SULPHURSulphur is essential for plant protein production andsulphur deficiency can lower grain quality. Sulphur isalso critical for effective nitrogen fixation in legumes.Cereals typically require twice the amount of sulphuras phosphorus. As sulphur is relatively immobile inplants, a sustained supply of the mineral is requiredfrom the <strong>soil</strong>.Sulphur and <strong>organic</strong> <strong>matter</strong>Most sulphur in <strong>soil</strong> is bound in <strong>soil</strong> <strong>organic</strong> <strong>matter</strong>for surface <strong>soil</strong>s (0-10 cm). The ratio of carbon tonitrogen to phosphorous to sulphur in <strong>soil</strong> <strong>organic</strong><strong>matter</strong> is usually about 108:8:1:1 (108 units ofcarbon, eight units of nitrogen and one unit ofphosphorous and sulphur). Many <strong>soil</strong>s also containgypsum in their sub<strong>soil</strong> layers.Sulphate (SO 4-2) is mineralised when <strong>soil</strong> <strong>organic</strong><strong>matter</strong> is broken down and is the most plant-availableform of sulphur in well aerated <strong>soil</strong>s. Sulphate ismade available to plants from <strong>organic</strong> <strong>matter</strong> with acarbon to sulphur ratio of less than 200:1. Residueswith a carbon to sulphur ratio of more than 400:1usually result in sulphur immobilisation (Delgadoand Follet 2002). Sulphate not taken up by plants isvulnerable to leaching and in coarse textured <strong>soil</strong>sunder high rainfall sulphur is often deficient.Sulphur deficiencies in the <strong>soil</strong>Historically, sulphur deficiency has been rarein Australia because of the widespread use ofsuperphosphate fertilisers containing sulphur.However, in recent years sulphur deficiency hasbecome more evident with the switch to low-sulphatephosphate fertilisers and the increasing adoptionof canola, which has a high sulphur requirement.Sulphur deficiency is particularly apparent in <strong>soil</strong>swith high nitrogen availability, which increases yieldpotential and therefore sulphur demand. Removalof sulphur in <strong>organic</strong> <strong>matter</strong> via the harvest of cropsand pastures can be rectified with a replacementstrategy of between 2-5 kg of sulphur per tonne ofgrain or biomass removed (or in the case of canola10 kg of sulphur per tonne of removed grain orbiomass).POTASSIUMBetween 95-98 per cent of the potassium in <strong>soil</strong>is unavailable to plants and exists as a structuralcomponent of <strong>soil</strong> minerals until broken downby weathering processes. Instead, plants largelyacquire potassium in the form of exchangeablepotassium, or dissolved potassium available in <strong>soil</strong>solution. Available <strong>soil</strong> potassium results from thenet effects of supply processes, including mineralweathering, addition of fertilisers and mineralisationof <strong>organic</strong> inputs against losses associated withleaching, erosion, plant uptake and fixation.Soil <strong>organic</strong> <strong>matter</strong> increases the <strong>soil</strong>’s cationexchange capacity and in doing so increasesthe amount of soluble potassium, calcium andmagnesium available for release during mineralisation(Delgado and Follet 2002). Potassium is alsoreleased relatively quickly from crop residues tocontribute to the non-exchangeable, exchangeableand <strong>soil</strong> solution potassium pools. However, unlikenitrogen and phosphorous, available potassium inmany situations appears more closely linked to <strong>soil</strong>type (clay complex) than <strong>soil</strong> <strong>organic</strong> <strong>matter</strong>.37MANAGING SOIL ORGANIC MATTER: A PRACTICAL GUIDE

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