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Safety aspects for Transportation of Dangerous Goods

Table.4 Mixed loading

Table.4 Mixed loading table according to ADR Labels 1 1.4 1.5 1.6 2.1, 2.2, 2.3 1 1.4 1.5 1.6 2.1, 2.2, 2.3 3 4.1 See a a a ADR 3 4.1 4.1 + l 4.1 + 1 X 4.2 4.3 5.1 5.2 d a a a a 4.2 4.3 5.1 5.2 5.2 + 1 d 6.1 6.2 7 A, B, C 8 9 a a a a a a a a a a a a X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X 5.2 + 1 X X 6.1 6.2 7A, B, C 8 9 b a a a a a b c b b X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X X b b c b b 10. In Emergency Situation Organic Peroxides can be safely transported in spite of the hazards arising from high reactivity, if the relevant regulations are followed and sufficient measures are retrieved. You will have enough of time to notice the divergence in the initial stages for emergency precautions. Deviations from normal shipping positions should be regarded potentially hazardous and should be treated therefore. Divergence could be such as: Abnormal elevation of observed temperature above Ts. Defective in any alarm / Cooling units Any spillages Smell, smoke, or abnormal sounds from the container or fire. In case of divergence, make sure that you call, immediately handle or recall the emergency intervention number immediately indicated in the shipping documents!

The emergency response number can be reached 24 hours a day. You will receive technical assistance and advice according to the pre-defined emergency procedures. If in doubt, stand at a safe and secure distance and prepare fire fighting equipment. When you call the emergency response line, you must provide the following information: Name and position of the land Container ID Product type (UN number), product name and quantity The nature and development of the event Corrective measures made If stored temperature values are available Current temperature of the crab Contact information See also the emergency procedures for organic peroxide (IMDG 7.3.2. and 7.3.5) but in all cases contact the emergency response number! Precautions to be taken when deviation from normal state In case of any leakage or spillage 1. Try to stop the leak if possible. 2. Clean the spill as soon as possible, no matter how small the chemicals are to be spilled. 3. If the spilled liquid is a flammable liquid, the environment is immediately ventilated. If the spilled liquid vapor is irritating or toxic, a full face mask is used. 4. Flammable - No sparking equipment is used when flammable and explosive liquids and dusts are cleaned. Eliminate all magmatic sources. No smoking. 5. Clean the dust with a wet broom or vacuum. 6. Small Spill: If the product is soluble in water, dilute with distilled water and clean by dipping. Alternatively, if not water-soluble, absorb debris with an inert, dry material and place in a suitable waste disposal container. 7. Large Spill: Empty the area if the leak can not be stopped. Wash spilled material in a wastewater treatment plant or continue as follows; Collect spillage and absorb in sand, earth or other nonflammable material. Place wastes in labeled and stamped containers. Clean contaminated items and areas thoroughly, taking into account environmental regulations. Contaminated absorbent material may present similar hazards, such as in spilled material. Wash contaminated area with plenty of water. Once you have a crush, clean yourself up. Dangerous for the environment. Do not empty the sewer. Dispose of the wastes at a licensed waste disposal facility in accordance with local Waste Disposal Marines requirements. Unusual temperature arising above TS, any alarm or faulty cooling unit: If temperature is checked frequently, deviation will be noticed at an early stage and as a result there will be enough time for emergency precautions. Always call your emergency number.

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