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YSM Issue 90.2

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INN VATI N<br />

STATION<br />

Fighting Battery Fires with Microfibers<br />

►BY ALAN LIU<br />

From the phone you’re holding to high-powered electric<br />

cars, lithium-ion batteries are found in nearly every<br />

rechargeable electric device. Since their invention in the<br />

1970s, they have been widely used in household gadgets. In<br />

contrast to typical single-use alkaline batteries, lithium-ion<br />

batteries contain a much denser concentration of energy<br />

stored in rechargeable cells. However, because of their highenergy<br />

concentration, these batteries tend to heat up quickly<br />

as they discharge, becoming dangerous fire hazards. In the<br />

past couple of months, these risks have been highlighted by<br />

the Samsung Note 7 explosions, when those phones ignited<br />

right in their users’ palms, and by the hoverboard fires, which<br />

led to bans of hoverboards in many public places—including<br />

Yale’s campus. New research at Stanford may provide the ideal<br />

solution to these unintentional dangers.<br />

While scientists have already found some ways to lower<br />

heat generation of charging and discharging batteries,<br />

these methods often don’t protect against other issues like<br />

manufacturing inconsistencies. For example, in the Samsung<br />

Note 7 explosions, already-existing heat reduction systems<br />

were unable to get around a structural issue: there was a weak<br />

spot in the separator between the positive and negative ends<br />

of the battery. This separator was designed to keep the two<br />

ends, storing positive and negative ions, from touching each<br />

other, so that the battery wouldn’t instantly discharge all of its<br />

stored energy. This situation is akin to a pile of baking soda<br />

wrapped in tissue paper, hanging above a jar of vinegar. A hole<br />

or a weak spot in the paper would cause all of the baking soda<br />

to fall out and fall into the vinegar, creating an ever-expanding<br />

pile of foam. The tissue paper acted as a separator that kept the<br />

baking soda apart from the vinegar. Similarly, in the battery,<br />

if the separator had a weak spot, the ions would spill over and<br />

mix, creating a short circuit that would heat up the flammable<br />

liquid inside the lithium-ion battery. The entire battery would<br />

then ignite in an explosive reaction.<br />

Another option to reduce the risk of fire is to dilute the<br />

flammable liquids inside the battery with anti-flammable<br />

ones like triphenyl phosphate (TPP). However, this severely<br />

deteriorates the conductivity of the liquid inside the battery,<br />

reducing overall efficiency. Although a shorter battery life<br />

is much better than third-degree burns, in the increasingly<br />

competitive market for smartphones and consumer electronics,<br />

every advantage is a valuable one. Recent advances in battery<br />

innovation may provide a way to salvage this advantage.<br />

In January 2017, researchers in the Yicui lab at Stanford<br />

made lithium-ion batteries less flammable without hurting<br />

their performance by developing their own custom separators.<br />

The separators were woven from sophisticated microfibers<br />

with nanometer-scale diameters. In contrast to classical<br />

separators, these new ones contain the anti-flammable TPP<br />

as a built-in safety mechanism. To create this fine thread,<br />

the researchers used electric force to solidify a mixture of<br />

chemicals containing TPP in midair as it fell from the tip of a<br />

syringe. They then tested this thread to ensure the presence of<br />

two distinct layers: the inner layer contains TPP, and the outer<br />

layer is thick enough to almost completely stop TPP from<br />

leaking into the electrolytes. In addition, the thin outer shell<br />

is designed to melt away if the battery becomes excessively<br />

hot. In that case, TPP flows out of the thread and completely<br />

dissolves in the liquid to reduce the heat, similarly to how<br />

an automatic sprinkler system activates to put out fires. This<br />

solution addresses the need for a reliable thermal failsafe<br />

that doesn’t affect battery performance, making it ideal for<br />

consumer electronics like phones or hoverboards.<br />

Here at Yale, Jaehong Kim, a professor in the Department<br />

of Chemical and Environmental Engineering, is performing<br />

similar research, working on a separator that is similar, but<br />

is used for water filtration and treatment instead of battery<br />

safety. Kim’s work focuses on helping the membrane maintain<br />

functionality and increasing its durability through a selfhealing<br />

feature. If a membrane used for treating drinking<br />

water is damaged, it creates risks such as the outbreak of<br />

waterborne pathogens. Repairing these filters often requires a<br />

system shutdown to replace the membrane, which is especially<br />

a concern in places without the infrastructure to support such<br />

delays. Although the aftereffects aren’t as explosive as battery<br />

malfunctions, an outbreak of disease could be even more<br />

disastrous for affected communities.<br />

For both membranes and battery separators, one thing is<br />

clear: we should not need to sacrifice safety to achieve efficiency.<br />

www.yalescientific.org<br />

March 2017<br />

Yale Scientific Magazine<br />

35

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