SDB Matthes MD 1000 30-04-10 GB - MATTHES · Maschinen ...

DR 

Safety Data Sheet 

according to 1907/2006/EC, Article 31 

Page 1/5 

Printing date 30.04.2010 Revision: 30.04.2010 

1 Identification of the substance/preparation and of the 

company/undertaking 

· Product details 

· Trade name: MD 1000 

· Application of the substance / the preparation 

High alkaline degreasing-material 

for the preparation of iron-materials 

· Manufacturer/Supplier: 

Matthes Maschinen Industrietechnik 

Bollenhöhe 5 Tel.: 02104-23370-0 

40822 Mettmann Fax.: 02104-23370-11 

· Further information obtainable from: 

Department of laboratory. 

Data-leaf for med. Serves available under: Phone s. address 

· Information in case of emergency: Department of laboratory. 

2 Hazards identification 

· Hazard description: 

C Corrosive ?@A 

· Information concerning particular hazards for human and environment: 

The product has to be labelled due to the calculation procedure of the 

"General Classification guideline for preparations of the EU" in the 

latest valid version. 

R 35 Causes severe burns. 

· Classification system: 

The classification is according to the latest editions of the EU-lists, 

and extended by company and literature data. 

3 Composition/information on ingredients 

· Chemical characterization 

· Description: 

Mixture of substances listed below with nonhazardous additions. 

· Dangerous components: 

CAS: 13845-36-8 

EINECS: 237-574-9 

phosphate Xi; R 36/38 10-30% 

CAS: 1310-58-3 

EINECS: 215-181-3 

potassium hydroxide C, Xn; R 22-35 10-30% 

· Additional information: see data sheet 

4 First-aid measures 

· General information: 

Immediately remove any clothing soiled by the product. 

· After inhalation: 

Supply fresh air; consult doctor in case of complaints. 

· After skin contact: 

Immediately rinse with water. 

If skin irritation continues, consult a doctor. 

· After eye contact: 

Rinse opened eye for several minutes under running water. Then consult 

a doctor. 

(Contd. on page 2) 

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Page 2/5 


Trade name: MD 1000 

(Contd. of page 1) 

· After swallowing: 

Drink plenty of water and provide fresh air. Call for a doctor 

immediately. 

Do not induce vomiting; call for medical help immediately. 

5 Fire-fighting measures 

· Suitable extinguishing agents: 

Water 

Water haze 

Use fire extinguishing methods suitable to surrounding conditions. 

· Protective equipment: Adjust to environment-fire 

6 Accidental release measures 

· Person-related safety precautions: 

Wear protective equipment. Keep unprotected persons away. 

Avoid contact with eyes and skin. 

· Measures for environmental protection: 

Prevent seepage into sewage system, workpits and cellars. 

· Measures for cleaning/collecting: 

Absorb with liquid-binding material (sand, diatomite, acid binders, 

universal binders, sawdust). 

Dispose contaminated material as waste according to item 13. 

clean up with water 

7 Handling and storage 

· Handling: 

· Information for safe handling: 

Store in cool, dry place in tightly closed receptacles. 

· Information about fire - and explosion protection: 

No special measures required. 

· Storage: 

· Requirements to be met by storerooms and receptacles: 

Store only in the original receptacle. 

· Information about storage in one common storage facility: 

Do not store together with acids. 

· Further information about storage conditions: 

Keep receptacle tightly sealed. 

8 Exposure controls/personal protection 

· Additional information about design of technical facilities: 

No further data; see item 7. 

· Ingredients with limit values that require monitoring at the workplace: 

1310-58-3 potassium hydroxide 

WEL Short-term value: 2 mg/m³ 

· Additional information: 

The lists valid during the making were used as basis. 

· Personal protective equipment: 

· General protective and hygienic measures: 

Avoid contact with the eyes and skin. 

The usual precautionary measures are to be adhered to when handling 

chemicals. 

Keep away from foodstuffs, beverages and feed. 

Wash hands before breaks and at the end of work. 


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· Respiratory protection: 

Use suitable respiratory protective device in case of insufficient 

ventilation. 

· Protection of hands: Protective gloves 

· Material of gloves PVC gloves 

· Penetration time of glove material 

The exact break trough time has to be found out by the manufacturer of 

the protective gloves and has to be observed. 

· Eye protection: Safety glasses 

9 Physical and chemical properties 

· General Information 

Form: Fluid 

Colour: Light yellow 

Odour: Mild 

· Change in condition 

Melting point/Melting range: Undetermined. 

Boiling point/Boiling range: Undetermined. 

· Flash point: Not applicable. 

· Self-igniting: Product is not selfigniting. 

· Danger of explosion: Product does not present an explosion 

hazard. 

· Density at 20°C: 1.45-1.50 g/cm3 

· Solubility in / Miscibility with 

water: Fully miscible. 

· pH-value (10 g/l) at 20°C: 12-13 

10 Stability and reactivity 

· Thermal decomposition / conditions to be avoided: 

No decomposition if used according to specifications. 

· Dangerous reactions Strong exothermic reaction with acids. 

· Dangerous decomposition products: 

No dangerous decomposition products known. 

11 Toxicological information 

· Acute toxicity: 

· LD/LC50 values relevant for classification: 

1310-58-3 potassium hydroxide 

Oral LD50 365 mg/kg (rat) 

· Primary irritant effect: 

· on the skin: Strong caustic effect on skin and mucous membranes. 

· on the eye: Strong caustic effect. 

· Sensitization: No sensitizing effects known. 

· Additional toxicological information: 

The product shows the following dangers according to the calculation 

method of the General EU Classification Guidelines for Preparations as 

issued in the latest version: 

Corrosive 

Swallowing will lead to a strong caustic effect on mouth and throat and 

to the danger of perforation of esophagus and stomach. 


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12 Ecological information 


· Information about elimination (persistence and degradability): 

· Other information: 

As the demands of the tensid-regulation, to the cleaner-law, the 

product is over 90 % biodegradable. 

· Ecotoxical effects: 

· Other information: 

Could damage fish, plancton and fixed Organism by pH-shift. 

· General notes: 

Must not reach sewage water or drainage ditch undiluted or 

unneutralized. 

Water hazard class 1 (German Regulation): slightly hazardous for water 

Do not allow undiluted product or large quantities of it to reach 

ground water, water course or sewage system. 

13 Disposal considerations 

· Product: 

· Recommendation 

Must not be disposed together with household garbage. Do not allow 

product to reach sewage system. Must be specially treated adhering to 

official regulations. 

· Waste disposal key: 110107 alkali 

· Uncleaned packaging: 

· Recommendation: 

Disposal must be made according to official regulations. 

Empty contaminated packagings thoroughly. They may be recycled after 

thorough and proper cleaning. 

· Recommended cleansing agents: 

Water, if necessary together with cleansing agents. 

14 Transport information 

· Land transport ADR/RID (cross-border) 

daco} 

· ADR/RID class: 8 Corrosive substances. 

· Danger code (Kemler): 80 

· UN-Number: 1814 

· Packaging group: II 

· Hazard label 8 

· Description of goods: 1814 KALIUMHYDROXIDLÖSUNG, Gemisch 

· Tunnel restriction code E 

· Maritime transport IMDG: 

daco} 

· IMDG Class: 8 

· UN Number: 1814 

· EMS Number: F-A,S-B 

· Marine pollutant: No 


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· Proper shipping name: POTASSIUM HYDROXIDE SOLUTION 

· Air transport ICAO-TI and IATA-DGR: 

daco} 

· ICAO/IATA Class: 8 

· UN/ID Number: 1814 

· Proper shipping name: POTASSIUM HYDROXIDE SOLUTION 

15 Regulatory information 


· Labelling according to EU guidelines: 

The product has been classified and marked in accordance with EU 

Directives / Ordinance on Hazardous Materials. 

· Code letter and hazard designation of product: 

C Corrosive ?@A 

· Hazard-determining components of labelling: 

potassium hydroxide 

· Risk phrases: 

35 Causes severe burns. 

· Safety phrases: 

23 Do not breathe gas/fumes/vapour/spray (appropriate wording to 

be specified by the manufacturer). 

26 In case of contact with eyes, rinse immediately with plenty of 

water and seek medical advice. 

36/37/39 Wear suitable protective clothing, gloves and eye/face 

protection. 

45 In case of accident or if you feel unwell, seek medical advice 

immediately (show the label where possible). 

60 This material and its container must be disposed of as 

hazardous waste. 

16 Other information 

This information is based on our present knowledge. However, this shall 

not constitute a guarantee for any specific product features and shall 

not establish a legally valid contractual relationship. 

· Relevant R-phrases 

22 Harmful if swallowed. 

35 Causes severe burns. 

36/38 Irritating to eyes and skin. 

· Department issuing MSDS: Dept. Laboratory 

· Contact: Herr Matthes 

GB

SDB Matthes MD 1000 30-04-10 GB - MATTHES · Maschinen ...

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